Flame Ionization Detector Patents (Class 422/54)
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Patent number: 11726060Abstract: A flame ionization detector includes a burner to combust an oxygen-containing sample gas in a gas flame in the presence of air and while supplying a hydrogen-containing combustion gas. A measurement device measures an ion current from the gas flame to an electrode, and a temperature sensor measures a temperature of the gas flame. An evaluation device evaluates the measured ion current and compensates during evaluation of the measured ion current for a cross-sensitivity of the ion current to oxygen in the sample gas using the measured temperature of the gas flame.Type: GrantFiled: July 22, 2019Date of Patent: August 15, 2023Assignee: SIEMENS AKTIENGESELLSCHAFTInventors: Ricardo Calvo, Hans-Günther Kleih, Josef Richter, Andreas Sutter
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Patent number: 11428675Abstract: In the present system and method, a conduit from a LC device continuously transports solvent, buffers, and analytes to the inlet of a solvent removal and analyte conversion device which evaporates the solvents, leaving non-volatile analytes for detection. The device comprises a rotating disk. The liquid chromatograph device can be any device using liquid chromatography to separate molecules. The solvents in the LC effluent can include, but are not limited to, water, methanol, acetonitrile, tetrahydrofuran, and acetone. After removal of the volatile components, the non-volatile analytes are converted with a concentrated energy source so that they may be detectable.Type: GrantFiled: July 29, 2019Date of Patent: August 30, 2022Assignee: Activated Research Company, LLCInventors: Andrew Jones, Tommy Saunders, Mike Hofflander
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Patent number: 11168629Abstract: The present invention is one that accurately measures an exhaust gas component regardless of variation in atmospheric pressure around a test object that is a vehicle or part of it, and an exhaust gas analysis apparatus that measures component concentration in exhaust gas discharged from the test object that is the vehicle or part of it. The exhaust gas analysis apparatus includes: an exhaust gas detector that mixes the exhaust gas and reactive gas together and detects the resulting phenomenon; a pressure gauge that measures the atmospheric pressure at the time of measurement of the exhaust gas or pressure at a predetermined point inside the exhaust gas analysis apparatus as measured pressure; and a correction part that, on the basis of the measured pressure by the pressure gauge, corrects the measurement error of the exhaust gas detector associated with a variation in the supply amount of the reactive gas.Type: GrantFiled: September 9, 2019Date of Patent: November 9, 2021Assignee: HORIBA, LTD.Inventors: Naoto Mizutani, Masahiro Nishikawa, Haruhisa Mohara, Shun Fukami, Yosuke Kondo
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Patent number: 11150227Abstract: A microwave resonator flame ionization detector assembly includes a microwave resonator disposed proximate a flame to evaluate an ion concentration in a flame effluent. A resonant frequency of the microwave resonator is detected, and a reflection coefficient of the resonator is used to determine an electric permittivity of a material in which the resonator is immersed. The electric permittivity depends on an ion concentration proximal to the resonator, and the ion concentration is related to the concentration of hydrocarbons present in the flame.Type: GrantFiled: September 28, 2018Date of Patent: October 19, 2021Assignee: Rosemount Inc.Inventor: Curtis W. Belknap, Jr.
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Patent number: 10942155Abstract: A system and method of determining levels of contaminants in a base gas. A gas chromatography column is used as part of a cold trap. A sample of a base gas is fed through the gas chromatography column. Due to the temperature of the gas chromatography column, some of the contaminants concentrate. A purified carrier gas is directed through the reinforced tube assembly after contaminants have collected. The gas chromatography column is heated to a second temperature that releases at least some of the concentrated contaminants. The contaminants mix with the purified carrier gas to create a contaminated carrier gas. The contaminated carrier gas is directed to one or more testing units that analyze the contaminated carrier gas to quantify the contaminants.Type: GrantFiled: October 21, 2019Date of Patent: March 9, 2021Assignee: Power & Energy, Inc.Inventor: Peter R. Bossard
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Patent number: 10934155Abstract: A fluidic interconnect includes a first interface including a liquid port, a gas port, and a cradle; a second interface including a liquid port, a gas port, and a swing bar to engage the cradle, a weight of a container attached to one of the first or second interfaces to drive the liquid port of the first interface into connection with the liquid port of the second interface and the gas port of the first interface into connection with the gas port of the second interface.Type: GrantFiled: September 30, 2019Date of Patent: March 2, 2021Assignee: LIFE TECHNOLOGIES CORPORATIONInventors: Todd Roswech, Jonathan Schultz, Chun Ho
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Patent number: 10823711Abstract: This invention relates to a micro-device for detecting volatile compounds comprising: an input (E) and an output (S); collection means (2) for taking a gas sample containing at least one compound to be detected; sampling means enabling a gas volume of 100 mL or less to be sampled, arranged after the collection means; injection means (3) of said gas sample; separation means (5) of the compound to be detected in the gas sample; compound detection means (6); and a gas circulation circuit (1) located downstream of the collection means and passing through the sampling means, injection means (3), separation means (5) and detection means (6); characterized in that the gas circulation circuit (1) has a volume of between 0.2 cm3 and 2.0 cm3.Type: GrantFiled: December 4, 2015Date of Patent: November 3, 2020Assignees: Universite de Strasbourg, Centre National de la Recherche ScientifiqueInventors: Stéphane Le Calve, Rouba Nasreddine, Vincent Person, Christophe Serra
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Patent number: 10775338Abstract: The invention relates to an electrochemical gas sensing apparatus for sensing one or more analytes, such as NO2 and/or O3, in a sample gas and a method of using same. The apparatus uses Mn2O3 as a filter for ozone. The Mn2O3 may take the form of a powder which may be unmixed, mixed with various PTFE particles sizes, formed into a solid layer deposited onto a membrane and/or pretreated with NO2.Type: GrantFiled: January 9, 2017Date of Patent: September 15, 2020Assignee: ALPHASENSE LIMITEDInventors: John Saffell, Ronan Baron, Marlene Hossain
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Patent number: 10753913Abstract: Certain configurations of a gas chromatography system comprising an internal gas generator are described. In some instances, the gas chromatography system may comprise an internal hydrogen generator to provide hydrogen gas to a chromatography column for separation of analyte species. In certain examples, the gas chromatography system can be operated without any external gas inputs.Type: GrantFiled: June 28, 2016Date of Patent: August 25, 2020Assignee: PerkinElmer Health Sciences, Inc.Inventor: Andrew Tipler
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Patent number: 10151733Abstract: The present disclosure relates to an oxidizer, and related methods, for oxidizing polar modifiers in chromatographic mobile phases. The oxidizer enables the use of flame-based detection in chromatographic separations, such as carbon dioxide based chromatography, which employ polar modifiers, such as methanol. Upon exiting a chromatographic column, the mobile phase containing the polar modifier is flowed through an oxidizer that contains a catalyst to oxidize at least a portion of the polar modifier to a species that does not interfere with the function of the flame-based detector. The oxidizer allows for flame-based detection, such as flame ionization detection, in applications in which a polar modifier with a reduced form of carbon is used.Type: GrantFiled: September 12, 2014Date of Patent: December 11, 2018Assignee: Waters Technologies CorporationInventors: Michael O. Fogwill, Joseph D. Michienzi, James P. Murphy
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Patent number: 10132785Abstract: In a gas analysis apparatus including analyzers that need ignition, such as FIDs, in order to make it possible to surely ignite the analyzers while downsizing the entire apparatus, the apparatus includes first and second analyzers to accept a sample gas, a first gas line provided with the first analyzer, a second gas line provided with the second analyzer and joined downstream of the first analyzer in the first gas line. At least one of the first analyzer and the second analyzer is configured to cause pressure fluctuations in the gas line including the analyzer when analyzing the sample gas. A first backflow prevention mechanism is disposed between another of the analyzers and a junction of the gas lines. The first backflow prevention mechanism is configured to prevent a fluid from flowing backward from the one of the analyzers through the junction toward the another of the analyzers.Type: GrantFiled: May 11, 2017Date of Patent: November 20, 2018Assignee: Horiba, Ltd.Inventors: Shun Fukami, Haruhisa Mohara, Shintaro Aoki
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Patent number: 10024768Abstract: System, method, and apparatus embodiments characterize potential air emissions during the pig receiver depressurization. The mass flow rate, pressure, and temperature of exhaust gas released from the pig receiver are ascertained using a mass flow meter, pressure gauge, and temperature gauge, respectively. A flow meter and control valve regulate flow of exhaust gas through a sampling line and into a grab sample collection train. The grab sample collection train includes grab sample containers (e.g., piston cylinders, double-ended cylinders, and evacuated canisters) that collect exhaust gas samples over a range of pressures. The exhaust gas samples are used to determine the concentrations of gas components in the exhaust gas over the range of pressures. These concentrations are interpolated and/or extrapolated to provide a concentration versus pressure curve for each identified component in the exhaust gas.Type: GrantFiled: June 17, 2017Date of Patent: July 17, 2018Assignee: MarkWest Energy Partners, L.P.Inventor: David Johnsen
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Patent number: 9970864Abstract: A method and a system for detecting the presence of propellant gas in a gaseous sample exploit laser light especially in the 3.30-3.5 ?m range. The propellant can be propane, n-butane, i-butane, dimethyl ether, methyl ethyl ether, HFA 134a, HFA 227, or any other propellant exhibiting absorption in the requisite wavelength range. The presence of the application of this method in leak testing of propellant-containing containers such as aerosols or fuel canisters, permits high-speed, high accuracy leak detection capable of replacing existing testing methods.Type: GrantFiled: May 2, 2012Date of Patent: May 15, 2018Assignee: WILCO AGInventors: Lukas Emmenegger, Jana Jágerská, Béla Tuzon
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Patent number: 9921139Abstract: A portable, hand-held sampler for collection of aquatic biotic samples. A pump with an exhaust tube and a water intake tube is attached to a frame. A battery is attached to the frame and electrically connected to the pump. A handle is attached to the bottom of the frame for an operator to hold the sampler in one hand. A switch is electrically connected to the pump and to the battery and attached to the frame near the handle for the operator to control activation of the pump with the same single hand. A venturi tube assembly with a sample intake tube is attached to the exhaust tube. The pump draws water into the water intake tube and sample material into the sample intake tube and the venturi tube diverts the sample material away from the pump and into a sample collection reservoir to prevent damage to the sample material.Type: GrantFiled: November 5, 2013Date of Patent: March 20, 2018Assignee: The United States of America as Represented by the Secretary of the Department of the InteriorInventor: Marc A. Blouin
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Patent number: 9903001Abstract: A system and methods for detection of a nucleic acid including forming a plurality of nucleic acid detection complexes are described, each of the complexes including a nucleic acid analyte, a detection agent and a functionalized probe. The method further including binding the nucleic acid detection complexes to a plurality of functionalized particles in a fluid sample and separating the functionalized particles having the nucleic acid detection complexes bound thereto from the fluid sample using a density media. The nucleic acid analyte is detected by detecting the detection agent.Type: GrantFiled: July 12, 2013Date of Patent: February 27, 2018Assignee: National Technology & Engineering Solutions of Sandia, LLCInventors: Chung-Yan Koh, Ulrich Y. Schaff, Gregory Jon Sommer
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Method for the production of a flame ionization detector and corresponding flame ionization detector
Patent number: 9891195Abstract: A flame ionization detector having at least one combustion chamber, at least one conduit for directing a gas or gas mixture, and at least one electrode structure, and a process for forming the flame ionization detector by providing two or more green ceramic films, forming geometric structures in said green ceramic films, depositing at least a portion of an electrically conductive structure on at least one of said green ceramic films, stacking said green ceramic films, laminating said green ceramic films, and sintering said laminated green ceramic films to form said flame ionization detector.Type: GrantFiled: November 19, 2012Date of Patent: February 13, 2018Assignee: KROHNE Messtechnik GmbHInventor: Winfried Kuipers -
Patent number: 9448211Abstract: A method and system of measuring non-methane hydrocarbons in exhaust gas. The method includes sampling exhaust gas, wherein the exhaust gas includes native carbon dioxide, non-methane hydrocarbons and methane. The native carbon dioxide present in the exhaust gas is removed followed by oxidation of the non-methane hydrocarbons to produce carbon dioxide. The concentration of carbon dioxide is then measured and provides a direct indication of the non-methane hydrocarbon concentration.Type: GrantFiled: December 4, 2013Date of Patent: September 20, 2016Assignee: SOUTHWEST RESEARCH INSTITUTEInventor: Imad Said Abdul-Khalek
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Patent number: 9034654Abstract: A method for analyzing the liquefied petroleum gas includes the following steps. Provide a sample of the liquefied petroleum gas, and one main component group of the liquefied petroleum gas includes at least one sub component group. Analyze the sample of the liquefied petroleum gas so as to obtain a first measured THC corresponding to the main component group and a second measured THC corresponding to the sub component group. Obtain a regressed THC according to the second measured THC and a predetermined relationship of THC. Obtain a result of THC according to the first measured THC, the regressed THC, and a predetermined range of THC. The predetermined range of THC corresponds to the main component group. The device for analyzing the liquefied petroleum gas includes an inlet, a multiposition valve, a first column, a second column, an analyzing apparatus, and a computing unit.Type: GrantFiled: March 16, 2013Date of Patent: May 19, 2015Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Hsiu-Li Su, Huan-Yi Hung, Han-Wen Chu, Tsung-Chou Hsu, Yao-Ting Huang
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Patent number: 9029028Abstract: A device using needed hydrogen gas flow and electricity for operation obtained from a fuel cell power supply. Also, water generated by the fuel cell may be recycled for hydrogen generation which may be used by the device and in turn expanded by the fuel cell for further electrical power generation. The device may be a gas chromatograph, a fluid calibration mechanism, a flame ionization detector, or the like.Type: GrantFiled: May 23, 2011Date of Patent: May 12, 2015Assignee: Honeywell International Inc.Inventors: Steven J. Eickhoff, Adam McBrady, Ulrich Bonne, Roland A. Wood
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Publication number: 20150078962Abstract: The present disclosure relates to a microfluidic flame ionization detector for use in small scale separations, such as, for example, microfluidic gas chromatography and microfluidic carbon dioxide based fluid chromatography. In some arrangements, the microfluidic counter-current flame ionization detector employs a non-parallel arrangement for the introduction of combustion gases into the combustion chamber. In other arrangements, the detector housing is configured to incorporate at least one of the detector electrodes within the housing using electrically isolating fittings.Type: ApplicationFiled: September 11, 2014Publication date: March 19, 2015Applicant: WATERS TECHNOLOGIES CORPORATIONInventors: Michael O. Fogwill, Joseph D. Michienzi, James P. Murphy, Geoff Gerhardt
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Publication number: 20150079691Abstract: The present disclosure relates to an oxidizer, and related methods, for oxidizing polar modifiers in chromatographic mobile phases. The oxidizer enables the use of flame-based detection in chromatographic separations, such as carbon dioxide based chromatography, which employ polar modifiers, such as methanol. Upon exiting a chromatographic column, the mobile phase containing the polar modifier is flowed through an oxidizer that contains a catalyst to oxidize at least a portion of the polar modifier to a species that does not interfere with the function of the flame-based detector. The oxidizer allows for flame-based detection, such as flame ionization detection, in applications in which a polar modifier with a reduced form of carbon is used.Type: ApplicationFiled: September 12, 2014Publication date: March 19, 2015Applicant: Waters Technologies CorporationInventors: Michael O. Fogwill, Joseph D. Michienzi, James P. Murphy
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Patent number: 8951471Abstract: Certain embodiments described herein are directed to jet assemblies that include a substantially inert fluid flow path. In some examples, a jet assembly includes a fluid flow path comprising a substantially inert metal in a fluid flow path. Devices and systems using the jet assembly are also described. In other embodiments, a brazeless or weldless jet assembly is provided. In some embodiments, the brazeless jet assembly may include an inert material or coating, e.g., a silica coating, in a fluid flow path.Type: GrantFiled: February 26, 2011Date of Patent: February 10, 2015Assignee: Perkinelmer Health Sciences, Inc.Inventor: Rosario Mannino
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Publication number: 20150037210Abstract: A method for producing a functional unit with a gas converter (1) and a flame ionization detector (10) is produced with the gas converter (1) and the flame ionization detector (10) being connected together as parts of a multi-layer ceramic (6).Type: ApplicationFiled: August 1, 2014Publication date: February 5, 2015Applicant: KROHNE Messtechnik GmbHInventor: Winfred Kuipers
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Patent number: 8926900Abstract: Improved system for gas chromatography wherein use is made of a separation column and a TCD (Thermal Conductivity Detector), characterized in that the outflow from the separation column is ionized, and the ionization takes place upstream of the TCD. The ionization of the outflow from the separation column upstream of the TCD is surprisingly found in many cases to have a favorable effect on the response of the TCD. The sensitivity of the TCD is found in many cases to increase substantially. For ionization purposes use can be made of electromagnetic radiation, ionizing radiation or pyrolysis. The degree of ionization is preferably measured by means of measuring means provided for the purpose. The response of the TCD and the measurement data obtained with the measuring means are found together to give in many cases even more and better information relating to components present in the outflow from the separation column.Type: GrantFiled: June 10, 2009Date of Patent: January 6, 2015Assignee: Thermo Fisher Scientific S.p.A.Inventors: Job Elders, Gert-Jan Burger
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Publication number: 20140334978Abstract: The present disclosure may include a device for testing catalysts, and a method for controlling the flow rate and temperature parameters during the process. The device may separate mass flow control through heating elements from the mass flow through the sample, as well as separate banks for mixing oxidizing elements, carbon dioxide, and diluent gas as well as reducing agents, nitric oxide, and diluent gas. The device disclosed here may also use mass control units of a sufficiently high speed so as to allow the desired testing conditions.Type: ApplicationFiled: May 10, 2013Publication date: November 13, 2014Applicant: CDTiInventor: Randal L. Hatfield
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Publication number: 20140287518Abstract: The invention relates to a method for determining a concentration of at least one component of gas present in a gas line or in a gas container, wherein gas is led off from the gas line or the gas container at a measurement location and is supplied to at least one gas flame; the ion flow is measured between a gas flame to which gas is supplied and an electrode arrangement; the temperature of a gas flame is measured to which gas is supplied; and the concentration of the at least one component of the gas present in the gas line or in the gas container is determined from the measurement ion flow and the measured temperature or from values related thereto. The invention furthermore relates to gas concentration sensors for carrying out the method in accordance with the invention.Type: ApplicationFiled: March 19, 2014Publication date: September 25, 2014Applicant: SICK AGInventors: Jacques DEPOUTOT, Markus FACKLER, Laila FORNELLI, Iris SIEMESGELUSS, Ingo REINKE, Norbert ROTHKAMP
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Patent number: 8821789Abstract: A sample preparation assembly includes a torch configured for use with an inductively coupled plasma spectroscopy instrument. The torch includes at least two approximately cylindrical tubes arranged substantially concentrically. The sample preparation assembly also includes an injector configured for use with the inductively coupled plasma spectroscopy instrument. The injector includes an injection nozzle and a spray chamber. The sample preparation assembly further includes a heat sink element. The heat sink element includes a securing element. The securing element is configured to mate with a mounting element of the torch to mechanically support the heat sink element.Type: GrantFiled: October 7, 2013Date of Patent: September 2, 2014Assignee: Elemental Scientific, Inc.Inventors: Daniel R. Wiederin, Gary J. Barrett
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Publication number: 20140219868Abstract: The present invention is mainly intended to provide a reaction apparatus that can prevent a problem due to heat generated by heat treatment in a reaction part, and accurately perform detection, and the reaction apparatus is provided with: a reaction part that is introduced with sample gas having passed through a column and reaction gas, and as a result of a reaction between the sample gas and the reaction gas, produces measurement gas containing a predetermined compound; a protruding pipe that is integrally protruded from the reaction part; and a connecting part that is disposed separately from the reaction part and removably fitted with the protruding pipe.Type: ApplicationFiled: January 31, 2014Publication date: August 7, 2014Applicant: HORIBA STEC, CO., LTD.Inventors: Tomohiro SASAKI, Shoji NARUKAMI, Tsuneaki MAEDA
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Publication number: 20140147927Abstract: A method for analyzing the liquefied petroleum gas comprises the following steps. Provide a sample of the liquefied petroleum gas, and one main component group of the liquefied petroleum gas comprises at least one sub component group. Analyze the sample of the liquefied petroleum gas so as to obtain a first measured THC corresponding to the main component group and a second measured THC corresponding to the sub component group. Obtain a regressed THC according to the second measured THC and a predetermined relationship of THC. Obtain a result of THC according to the first measured THC, the regressed THC, and a predetermined range of THC. The predetermined range of THC corresponds to the main component group. The device for analyzing the liquefied petroleum gas comprises an inlet, a multiposition valve, a first column, a second column, an analyzing apparatus, and a computing unit.Type: ApplicationFiled: March 16, 2013Publication date: May 29, 2014Applicant: Industrial Technology Research InstituteInventors: Hsiu-Li Su, Huan-Yi Hung, Han-Wen Chu, Tsung-Chou Hsu, Yao-Ting Huang
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Publication number: 20140119993Abstract: An apparatus for receiving a chemical species is disclosed. The apparatus includes an emission block configured to receive a vapor phase chemical species that is excited by chemical reaction in the emission block to provide an excited species that emits hot. The emission block has an interior portion having a surface. A coating is disposed over the surface and the coating reduces adsorption of the excited species onto the surface.Type: ApplicationFiled: December 18, 2012Publication date: May 1, 2014Applicant: AGILENT TECHNOLOGIES, INC.Inventor: Robert P. RHODES
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Patent number: 8618018Abstract: The invention relates to catalytically active components for thermal ionization detectors for the detection of compounds containing halogen which have an improved structure as well as to a manufacturing method for an oxide ceramic sintering material for the components. It is the object of the invention to manufacture catalytically active components for thermal ionization detectors for gas chromatographic applications which are thermally, mechanically and chemically stable in the long term and which have increased sensitivity to the materials to be detected. In this respect, the sintering material should be adjustable in a controllable manner in the ideal parameter required for the detector. It is proposed in accordance with the invention to use an oxide ceramic sintering material for the components which comprises a crystalline phase and an amorphous glass phase, with it being essential to the invention that the amorphous glass phase is formed with 0.1 to 20% by weight of a cesium compound.Type: GrantFiled: July 30, 2007Date of Patent: December 31, 2013Assignee: Fraunhofer-Gesellschaft zur Forderung der Angewandten Forschung E.V.Inventors: Viktar Sauchuk, Peter Otschik, Klaus Eichler, Mihails Kusnezoff
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Patent number: 8580570Abstract: A polymer-based PLOT capillary column prepared by in situ copolymerization of a functional monomer, which usually contains the retentive chemistries, and a crosslinking monomer, which enhances the strength of the polymer matrix, is disclosed. Also disclosed is a system comprising the polymer-based PLOT column coupled to a mass flow or concentration sensitive detector, for carrying out a chemical analysis method on samples separated by liquid chromatography using the column, and a process for using the system. Columns of the invention can be prepared in a robust fashion with a very narrow i.d., e.g., 5-15 ?m. Thus, they are suitable for commercial use in ultratrace LC/MS proteomic analysis. Columns according to the invention are characterized by high resolving power and high column-to-column reproducibility. When these columns are coupled on-line with, e.g.Type: GrantFiled: July 15, 2011Date of Patent: November 12, 2013Assignee: Northeastern UniversityInventors: Barry L. Karger, Jian Zhang
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Publication number: 20130295677Abstract: In some embodiments, apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient, to detect the differentiated gas components, and to determine a fingerprint of the differentiated gas components. Other apparatus, systems, and methods are disclosed.Type: ApplicationFiled: July 9, 2013Publication date: November 7, 2013Applicant: HALLIBURTON ENERGY SERVICES, INC.Inventors: Christopher M. Jones, Michael T. Pelletier
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Patent number: 8551401Abstract: A sample preparation assembly includes a torch configured for use with an inductively coupled plasma spectroscopy instrument. The torch includes at least two approximately cylindrical tubes arranged substantially concentrically. The sample preparation assembly also includes an injector configured for use with the inductively coupled plasma spectroscopy instrument. The injector includes an injection nozzle and a spray chamber. The sample preparation assembly further includes a heat sink element. The heat sink element includes a securing element. The securing element is configured to mate with a mounting element of the torch to mechanically support the heat sink element.Type: GrantFiled: May 12, 2010Date of Patent: October 8, 2013Assignee: Elemental Scientific, Inc.Inventors: Daniel R. Wiederin, Gary Barrett
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Publication number: 20130210160Abstract: The invention relates to a device and to a method for the detection of hydrogen in a gas mixture, wherein the device comprises a catalyst unit which is connected to a source and a supply device for CO and/or CO2, respectively, or comprises these and wherein the catalyst unit is connected to a flame ionization detector by a feed line, such that the gas mixture, especially containing an inert carrier gas after passing through the catalyst unit is conducted to the FID. The FID is operated with hydrogen as fuel gas.Type: ApplicationFiled: April 26, 2011Publication date: August 15, 2013Applicant: Carl Von Ossietzky Universitaet OldenburgInventors: Frank Roessner, Stefan Schoenen
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Patent number: 8499614Abstract: The invention relates to a field gas chromatograph with flame ionization for the analysis of a gaseous mixture of hydrocarbons, extracted, in particular, from oil drilling mud. Said mixture consists of a fraction of heavy hydrocarbons (beyond pentane) dissolved in mud in gaseous form. Said field gas chromatograph is made up of two independent analysis circuits, dephased by half a cycle and synchronized one with the other. Said analysis circuits are comprised of at least one sampling cell in a preferred design layout, at least one capillary separation chromatography column, at least one flame ionization detector, and at least one electrometer for the conversion of an electrical current, collected by the flame ionization detector, into a voltage signal describing a chromatogram.Type: GrantFiled: February 4, 2011Date of Patent: August 6, 2013Assignee: Geolog S.r.l.Inventor: Antonio Calleri
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Publication number: 20130122595Abstract: Apparatus and systems, as well as methods, may operate to draw a formation fluid sample into a sampling port included in a down hole tool or tool body, to vaporize some part of the fluid sample to substantially fill an injection port with a gas phase, to differentiate gas components in the gas phase to provide differentiated gas components along a concentration gradient in a receiving section, to detect the differentiated gas components with a detector, and to determine a fingerprint of the differentiated gas components. A reaction section and a vacuum section may be used for waste consumption and/or absorption.Type: ApplicationFiled: January 10, 2013Publication date: May 16, 2013Applicant: Halliburton Energy Services, Inc.Inventor: Halliburton Energy Services, Inc.
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Patent number: 8420021Abstract: There is provided an ignition or plasma generation apparatus that eliminates the need for resonance means in a combustion chamber and simplifies the electrode structure within the combustion chamber in an instance where energy from each of a spark discharge and microwaves is used to ignite an air-fuel mixture gas in an internal combustion engine. The ignition or plasma generation apparatus includes a mixing circuit for mixing a high-voltage pulse from a high-voltage pulse generator and microwave energy from a microwave generator; and an ignition plug into which an output from the mixing circuit is supplied, the plug used for introducing the output into a combustion chamber of an internal combustion engine. The output supplied from the mixing circuit to the ignition plug is supplied in a manner in which the microwave energy and the high-voltage pulse are superimposed on each other on a same transmission line.Type: GrantFiled: June 21, 2012Date of Patent: April 16, 2013Assignee: Imagineering, Inc.Inventors: Minoru Makita, Yuji Ikeda
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Patent number: 8409504Abstract: The invention relates to a fluid analysis device that comprises an analyzer and a system for supplying an instrumentation gas to said analyzer, characterized in that the supply system includes at least one mixer generating said instrumentation gas, and at least one purifier located downstream from said at least one mixer and upstream from said analyzer.Type: GrantFiled: November 3, 2008Date of Patent: April 2, 2013Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges ClaudeInventors: Valerie Bossoutrot, Joerg Koppel, Severine Lepic, Herve Paoli
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Patent number: 8329099Abstract: Reigniting a flame in a volatile organic compound (VOC) detector in the event that the flame has gone out. In one implementation, a signal is received at a handheld personal computer indicating that a flame in the VOC detector has gone out. The flame in the VOC detector may then be reignited using the handheld personal computer and a Bluetooth enabled device facilitating communication between the handheld personal computer and the VOC detector.Type: GrantFiled: September 26, 2011Date of Patent: December 11, 2012Assignee: LDARtools, Inc.Inventors: Leo Skiba, Rex Moses, Keith Adams, Jack Clark, Bradley O'Keefe, Kevin Moses, Andrew Reiter
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Patent number: 8305086Abstract: The flame ionization detector, which comprises a supply and an ignition device (7) for the combustible gas, a supply for the sample gas, a combustion chamber (4) in which the sample gas is ionized by the flame, and electrodes (8, 1) to which a voltage is applied in order to generate and measure the ion current, is distinguished in that it is constructed as an integrated planar system of at least three parallel platelet-like substrates (1, 2, 3) which are connected to one another and are processed by microsystem technology methods, with a central substrate (1) comprising nozzles (5, 6) for the gases and the ignition device (7) and a recess which forms a part of the combustion chamber (4), is completed by recesses in the neighboring substrates (2, 3) and is essentially closed together with the nozzle region by these substrates (2, 3), and the neighboring substrates (2, 3) comprise supply channels (10, 11) for the gases.Type: GrantFiled: August 18, 2008Date of Patent: November 6, 2012Assignee: Bayer Technology Services GmbHInventors: Müller Jörg, Winfred Kuipers
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Patent number: 8226901Abstract: There is provided an ignition or plasma generation apparatus that eliminates the need for resonance means in a combustion chamber and simplifies the electrode structure within the combustion chamber in an instance where energy from each of a spark discharge and microwaves is used to ignite an air-fuel mixture gas in an internal combustion engine. The ignition or plasma generation apparatus includes a mixing circuit for mixing a high-voltage pulse from a high-voltage pulse generator and microwave energy from a microwave generator; and an ignition plug into which an output from the mixing circuit is supplied, the plug used for introducing the output into a combustion chamber of an internal combustion engine. The output supplied from the mixing circuit to the ignition plug is supplied in a manner in which the microwave energy and the high-voltage pulse are superimposed on each other on a same transmission line.Type: GrantFiled: July 12, 2008Date of Patent: July 24, 2012Assignee: Imagineering, Inc.Inventors: Minoru Makita, Yuji Ikeda
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Patent number: 8097211Abstract: An analyzer comprising: a first specimen holder configured to hold a plurality of first specimen containers; a conveying assembly for conveying the first specimen containers held in the first specimen holder; a second specimen holder arranged at a position higher than an upper end of the first specimen containers held in the first specimen holder; a holder moving assembly for moving the second specimen holder so as to pass the upper side of at least one of the first specimen containers held in the first specimen holder; a container transferring assembly for transferring at least one of the first specimen containers from the first specimen holder to the second specimen holder; and a controller for controlling the holder moving assembly and the container transferring assembly, is disclosed.Type: GrantFiled: March 6, 2009Date of Patent: January 17, 2012Assignee: Sysmex CorporationInventors: Yuichi Hamada, Masaharu Shibata, Daigo Fukuma
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Publication number: 20110286884Abstract: A device using needed hydrogen gas flow and electricity for operation obtained from a fuel cell power supply. Also, water generated by the fuel cell may be recycled for hydrogen generation which may be used by the device and in turn expanded by the fuel cell for further electrical power generation. The device may be a gas chromatograph, a fluid calibration mechanism, a flame ionization detector, or the like.Type: ApplicationFiled: May 23, 2011Publication date: November 24, 2011Applicant: HONEYWELL INTERNATIONAL INC.Inventors: Steven J. Eickhoff, Adam McBrady, Ulrich Bonne, Roland A. Wood
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Patent number: 8034290Abstract: Reigniting a flame in a volatile organic compound (VOC) detector in the event that the flame has gone out. In one implementation, a signal is received at a handheld personal computer indicating that a flame in the VOC detector has gone out. The flame in the VOC detector may then be reignited using the handheld personal computer and a Bluetooth enabled device facilitating communication between the handheld personal computer and the VOC detector.Type: GrantFiled: January 29, 2007Date of Patent: October 11, 2011Assignee: LDARtools, Inc.Inventors: Leo Skiba, Rex Moses, Keith Adams, Jack Clark, Bradley O'Keefe, Kevin Moses, Andrew Reiter
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Patent number: 7976780Abstract: Methods and apparatus are provided to measure isotopic characteristics of a number of sample types. Embodiments of the invention combine novel and existing components to produce more accurate isotopic information. Further, embodiments of the invention allow for isotopic readings to be taken and analyzed outside of a laboratory. An example of such an embodiment is an apparatus comprising a combustion furnace; a reactant tube passing through the combustion furnace; an injector coupled to one, or a combination of, the combustion furnace, and reactant tube, to introduce a sample; a laser isotopic measurement device coupled to the reactant tube on the exit end; and a processor electrically coupled to one, or a combination of, the injector, the combustion furnace, the reactant tube, and the isotopic measurement device, in which a carrier gas transports the sample through the apparatus.Type: GrantFiled: August 15, 2005Date of Patent: July 12, 2011Assignee: Halliburton Energy Services, Inc.Inventors: Louis W. Elrod, Christopher M. Jones
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Publication number: 20110091983Abstract: Improved system for gas chromatography wherein use is made of a separation column and a TCD (Thermal Conductivity Detector), characterized in that the outflow from the separation column is ionized, and the ionization takes place upstream of the TCD. The ionization of the outflow from the separation column upstream of the TCD is surprisingly found in many cases to have a favourable effect on the response of the TCD. The sensitivity of the TCD is found in many cases to increase substantially. For ionization purposes use can be made of electromagnetic radiation, ionizing radiation or pyrolysis. The degree of ionization is preferably measured by means of measuring means provided for the purpose. The response of the TCD and the measurement data obtained with the measuring means are found together to give in many cases even more and better information relating to components present in the outflow from the separation column.Type: ApplicationFiled: June 10, 2009Publication date: April 21, 2011Inventors: Job Elders, Gert-Jan Berger
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Patent number: 7906071Abstract: A flame photometric detector comprises a burner assembly configured to combust a sample of an effluent, the combusted sample emitting at least one excited molecule, an interchangeable selective optical filter configured to pass a plurality of selected optical wavelengths corresponding to the excited molecule, and a photomultiplier tube configured to quantify the concentration of the excited molecule.Type: GrantFiled: January 12, 2005Date of Patent: March 15, 2011Assignee: Agilent Technologies, Inc.Inventors: Andrew Martin Warchol, Bruce Douglas Quimby, W. Dale Snyder, Paul Craig Dryden
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Publication number: 20100310419Abstract: The invention relates to a fluid analysis device that comprises an analyzer and a system for supplying an instrumentation gas to said analyzer, characterized in that the supply system includes at least one mixer generating said instrumentation gas, and at least one purifier located downstream from said at least one mixer and upstream from said analyzer.Type: ApplicationFiled: November 3, 2008Publication date: December 9, 2010Applicant: L"Air Liquide Societe Anonyme Pour L'Etude Exploitation Des Procedes Georges ClaudeInventors: Valerie Bossoutrot, Joerg Koppel, Severine Lepic, Herve Paoli
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Patent number: 7837935Abstract: Disclosed is a small-sized joint for joining hydrogen gas running route-forming members, which can surely prevent the leakage of hydrogen gas, and a portable hydrogen flame ionization gas detector that can prevent the leakage of hydrogen gas to achieve high safety. The joint comprises a metallic base having an internal space at least one end of which is opened, and a ring-like sealing member composed of an elastic material and arranged at opening edge of the metallic base, wherein a hydrogen gas running route-forming member is fixed in a state inserted into an internal space of the metallic base through the sealing member, and the sealing member is squeezed to gastightly seal the space, whereby one hydrogen gas running route-forming member is removably joined. In the gas detector, the joint is used to form a hydrogen gas running route.Type: GrantFiled: March 29, 2006Date of Patent: November 23, 2010Assignee: Riken Keiki Co., Ltd.Inventors: Haruhiko Kondo, Nobuhisa Kawai, Yukio Nakamura