Reaction Tubes Containing Structured Catalyst Patents (Class 422/653)
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Patent number: 10472235Abstract: A method of manufacturing synthesis gas by catalytic partial oxidation can prevent formation of hot spots from taking place when driving mixture gas to pass through a catalyst-filled layer at high velocity. The method comprises converting mixture gas of source gas containing lower hydrocarbons and oxidative gas containing oxygen into synthesis gas containing hydrogen and carbon monoxide as main components thereof by causing mixture gas to flow through a fixed bed catalyst layer arranged in a reactor. The method of manufacturing synthesis gas by catalytic partial oxidation is conducted such that the mixture gas is made to flow to the catalyst layer under the condition that the Reynolds number does not exceed 20 at the inlet of the catalyst layer.Type: GrantFiled: March 23, 2016Date of Patent: November 12, 2019Assignees: CHIYODA CORPORATION, JAPAN OIL, GAS AND METALS NATIONAL CORPORATIONInventors: Shigeru Kado, Kohei Urasaki, Kyoji Ishikawa, Hironori Kawai, Yusuke Nakajima
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Patent number: 10239826Abstract: A method for producing isocyanates by reacting primary amines with phosgene in a stoichiometric excess in the gas phase, wherein the excess phosgene is subsequently recovered and recirculated back into the reaction. particular a method for the feedback-controlled recirculation of the recovered phosgene, particularly when the phosgene stream that should be recovered is distributed between multiple gas-phase reactors operated in parallel.Type: GrantFiled: July 12, 2016Date of Patent: March 26, 2019Assignee: COVESTRO DEUTSCHLAND AGInventors: Friedhelm Steffens, Bastian Mahr
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Patent number: 9023300Abstract: A reactor (1) for preparing phosgene by gas-phase reaction of carbon monoxide and chlorine in the presence of a solid-state catalyst, which is provided in a plurality of catalyst tubes (2) which are arranged parallel to one another in the longitudinal direction of the reactor (1) and are welded at each of their two ends into a tube plate (3), with introduction of the starting materials at the upper end of the catalyst tubes (2) and discharge of the gaseous reaction mixture at the lower end of the catalyst tubes (2), in each case via a cap, and also with introduction and discharge facilities for a liquid heat transfer medium (7) in the space (4) between the catalyst tubes (2) within the shell, where the flow of the heat transfer medium (7) in the space (4) between the catalyst tubes (2) within the shell is meandering as a result of deflection plates (5), each alternative deflection plate (5) leaves two openings (6) having the shape of a segment of a circle free on opposite sides at the interior wall of the reaType: GrantFiled: December 16, 2009Date of Patent: May 5, 2015Assignee: BASF SEInventors: Gerhard Olbert, Wolfgang Gerlinger, Byoung-Yeon Kim
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Patent number: 9005538Abstract: The invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5%-40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) of between 3.0 to 4.5 mm-1, and the remaining catalyst particles have an average S/V of between 4.5 to 8.0 mm-1, and wherein the difference between the average S/V of the particles at the upstream end and the remaining fixed bed volume is at least 0.5 mm-1. Additionally the fixed bed volume at the upstream end shows a full-bed apparent catalytic activity per volume unit lower than the full-bed apparent catalytic activity per volume unit in the remaining fixed bed volume and/or the weight of catalytically active metal per weight unit at the upstream end is more than 70% lower than in the remaining fixed bed volume.Type: GrantFiled: June 27, 2012Date of Patent: April 14, 2015Assignee: Shell Oil CompanyInventors: Robert Martijn Van Hardeveld, Thomas Joris Remans, Erwin Roderick Stobbe
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Patent number: 8980194Abstract: The present invention pertains to a reactor tube comprising a fixed bed of Fischer-Tropsch catalyst particles, wherein the catalyst particles in 5% to 40% of the fixed bed volume at the upstream end have an average outer surface to volume ratio (S/V) in the range of between 3.0 to 4.5 mm?1, and the catalyst particles in the remaining fixed bed volume have an average outer surface to volume ratio (S/V) in the range of between 4.5 to 8.0 mm?1, and wherein the difference between the average S/V of the particles at the upstream end and the average S/V of the particles in the remaining fixed bed volume is at least 0.5 mm?1.Type: GrantFiled: December 15, 2010Date of Patent: March 17, 2015Assignee: Shell Oil CompanyInventors: Alouisius Nicolaas Renée Bos, Peter John Van Den Brink, Thomas Joris Remans, Erwin Roderick Stobbe, Dominik Johannes Michael Unruh, Ronald Vladimir Wisman
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Patent number: 8882863Abstract: A fuel reformulation system for an engine comprising an annular body for a flow of fluids therethrough connected to the engine, a source of fuel for flowing through at least a portion of the annular body, and a catalytic member connected to the annular body for the flow of any fluids thereacross from the annular body.Type: GrantFiled: May 13, 2009Date of Patent: November 11, 2014Assignee: Alliant Techsystems Inc.Inventors: Dean Modroukas, Jason S. Tyll, John C. Leylegian, Florin Girlea, Richard Perlman
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Patent number: 8728417Abstract: The present invention describes a steam reforming furnace for the production of hydrogen, which employs a set of porous burners interposed between the tubes to be heated, improving compactness of the furnace.Type: GrantFiled: March 5, 2008Date of Patent: May 20, 2014Assignee: IFP Energies NouvellesInventors: Fabrice Giroudiere, Beatrice Fischer
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Patent number: 8703076Abstract: A catalyst unit suitable for loading into a tube in a reactor includes a plurality of catalyst particles incorporated within a removable solid matrix, said unit in the form of an elongate body in which the particles are packed together such that the volume shrinkage upon removal of the removable matrix is ?20%. The catalyst particles preferably comprise one or more metals selected from the group consisting of Fe and Co in oxidic or reduced form. The units are particularly suitable for loading catalyst into tubes in a Fischer-Tropsch reactor.Type: GrantFiled: May 25, 2010Date of Patent: April 22, 2014Assignee: Johnson Matthey PLCInventors: Mark McKenna, Alejandro Martin Antonini
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Patent number: 8673245Abstract: A fixed-bed reactor containing a first catalyst layer filled with a first catalyst for producing acrolein from propylene; a second catalyst layer filled with a second catalyst for producing acrylic acid from acrolein; and an inert substance layer provided between the first catalyst layer and the second catalyst layer, and filled with an inert substance of a cylindrical shape having a surrounding wall in which an opening is formed. A process for producing acrylic acid containing the step of producing acrylic acid from propylene by using the aforementioned fixed-bed reactor.Type: GrantFiled: September 9, 2009Date of Patent: March 18, 2014Assignee: Nippon Shokubai Co., Ltd.Inventors: Michio Tanimoto, Nobuyuki Hakozaki
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Patent number: 8496892Abstract: Disclosed is a process and apparatus for the catalytic hydrogenation of fluoro-olefins to fluorocarbons where the reaction is carried out in a multi-tube shell and tube reactor. Reactions involving hydrogenation of fluoro-olefins are typically exothermic. In commercial processes where a fluoro-olefin CnH2n?xFx to CnH2n?x2Fx is hydrogenated (e.g., hexafluoropropylene to 236ea, 1225ye to 245eb, and the like), inadequate management or control of heat removal may induce excess hydrogenation, decomposition and hot spots resulting in reduced yields and potential safety issues. In the hydrogenation of fluoro-olefins, it is therefore necessary to control the reaction temperature as precisely as practical to overcome challenges associated with heat management and safety.Type: GrantFiled: January 31, 2012Date of Patent: July 30, 2013Assignee: Honeywell International Inc.Inventors: Haluk Kopkalli, Yuon Chiu, Orlando George Rodrigues, Gus Cerri, Hsueh Sung Tung, Stephen A. Cottrell
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Patent number: 8356525Abstract: An analyzer comprising: a first measurement unit for measuring samples; a second measurement unit; and a transportation device operable to transport a plurality of sample containers accommodated in a first rack and containing samples and a plurality of sample containers accommodated in a second rack and containing samples, to the first measurement unit and the second measurement unit, wherein the transportation device comprises a first transportation section operable to transport the plurality of sample containers on the first rack to the first measurement unit and the second measurement unit by transporting the first rack on a transport path, and a second transportation section operable to transport the plurality of sample containers on the second rack to the first measurement unit and the second measurement unit by transporting the second rack on the transport path independently from movement of the first rack, is disclosed. A transportation device is also disclosed.Type: GrantFiled: March 6, 2009Date of Patent: January 22, 2013Assignee: Sysmex CorporationInventors: Yuichi Hamada, Kunio Ueno
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Patent number: 8354083Abstract: Multi-tubular reactors for fluid processing incorporate reactor tubes containing thermally conductive monolithic catalyst structures with relative dimensions and thermal expansion characteristics effective to establish both a non-interfering or slidably interfering fit between the monolith structures and the reactor tubes at selected monolith mounting temperatures, and geometries at reactor operating temperatures such that the operating gaps between tubes and monoliths under the conditions of reactor operation do not exceed about 250 ?m over tube sections where high heat flux to or from the monoliths is required.Type: GrantFiled: March 16, 2009Date of Patent: January 15, 2013Assignee: Corning IncorporatedInventors: Jeffrey M. Amsden, Achim K. Heibel, Neil E. Partridge
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Patent number: 8257669Abstract: A chemical reactor is provided that includes: a plurality of tubes having a catalytic reactor substrate therein, each of the tubes having an inlet at one end for receiving a fluid flow and an outlet at an opposing end for discharging fluid flow, and a longitudinal axis parallel to the direction of fluid flow through the tube, the longitudinal axis of each tube being parallel to one another; and a plurality of heat exchange fins disposed on and extending radially from the exterior surface of each tube; the heat exchange fins on each tube independently having a profile along a cross-section perpendicular to the longitudinal axis of each tube, and the tubes being arranged with respect to one another, such that the heat exchange fin profiles together form a tessellated pattern in a plane that is perpendicular to the longitudinal axes of the tubes.Type: GrantFiled: December 22, 2010Date of Patent: September 4, 2012Assignee: Delphi Technologies, Inc.Inventor: Paul E. Jankowski
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Patent number: 8216531Abstract: Disclosed are a syngas production process and a reforming exchanger 100. The process involves passing a first portion of hydrocarbon feed mixed with steam and oxidant through an autothermal catalytic steam reforming zone to form a first reformed gas of reduced hydrocarbon content, passing a second portion of the hydrocarbon feed mixed with steam through an endothermic catalytic steam reforming zone to form a second reformed gas of reduced hydrocarbon content, and mixing the first and second reformed gases and passing the resulting gas mixture through a heat exchange zone for cooling the gas mixture and thereby supplying heat to the endothermic catalytic steam reforming zone. The endothermic catalytic steam reforming zone and the heat exchange zone are respectively disposed tube side and shell side within a shell-and-tube reforming exchanger 100.Type: GrantFiled: January 5, 2005Date of Patent: July 10, 2012Assignee: Kellogg Brown & Root LLCInventors: Robert Burlingame, Thomas Czuppon, Larry G. Hackemesser
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Patent number: 8168131Abstract: A syngas reforming reactor has a shell-and-tube configuration wherein the shell-side fluid flow path through the tube bundle has a longitudinal configuration. The reactor can include a shell-side inlet fluid distributor plate below the lower end of the tube bundle.Type: GrantFiled: November 9, 2009Date of Patent: May 1, 2012Assignee: Kellog Brown & Root LLCInventors: Robert Stevens Burlingame, Lloyd Edward Cizmar, Larry Gene Hackemesser, Laura Beth Aguilar
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Patent number: 8097226Abstract: A catalytic reaction device for fluid-solid heterogeneous catalytic reactions including a distributor, flow controllers, parallel reactors, temperature controllers, coolers and product receivers with reactive fluids flowing into the flow controllers to control the total flow of a fluid is provided.Type: GrantFiled: December 13, 2006Date of Patent: January 17, 2012Assignee: Microvast Power Systems Co., Ltd.Inventors: Jiangping Yi, Li Huang, Wensheng Li, Xio Ping Zhou
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Publication number: 20110268631Abstract: A chemical reactor is provided that includes: a plurality of tubes having a catalytic reactor substrate therein, each of the tubes having an inlet at one end for receiving a fluid flow and an outlet at an opposing end for discharging fluid flow, and a longitudinal axis parallel to the direction of fluid flow through the tube, the longitudinal axis of each tube being parallel to one another; and a plurality of heat exchange fins disposed on and extending radially from the exterior surface of each tube; the heat exchange fins on each tube independently having a profile along a cross-section perpendicular to the longitudinal axis of each tube, and the tubes being arranged with respect to one another, such that the heat exchange fin profiles together form a tessellated pattern in a plane that is perpendicular to the longitudinal axes of the tubes.Type: ApplicationFiled: December 22, 2010Publication date: November 3, 2011Applicant: DELPHI TECHNOLOGIES, INC.Inventor: Paul E. Jankowski