Abstract: Impurities such as oxygen and moisture can be removed from sulfur hexafluoride by contacting the impure gas with the reaction product of sulfur hexafluoride and a lithium-substituted macroreticulate polymer.

Abstract: Highly purified rare gas (helium, neon, argon, krypton, xenon, etc.) is obtained by removing impurities contained therein, such as nitrogen, hydrocarbon, carbon monoxide, carbon dioxide, oxygen, hydrogen and water, at relatively low temperatures by the use of a getter. This getter is a two-component alloy of zirconium and vanadium, or a multi-component alloy containing, as well as zirconium and vanadium, at least one of chromium, nickel and cobalt.

Abstract: High capacity solid state compositions comprising cyanocobaltate complexes have been developed which are capable of reversibly chemically binding oxygen to selectively remove oxygen from an oxygen-containing fluid stream. The cyanocobaltate complexes which make up the compositions comprise a cobalt (II)-containing anion having from 3 to 5 cyanide ligands wherein at least one cyanide stretching mode, as measured by infrared spectroscopy, is between 2074 cm.sup.-1 and 2140 cm.sup.-1. Additionally, these complexes have a charge-balancing cation having a molecular volume in excess of 40.ANG..sup.3.

Abstract: There are disclosed saltmen-type metallo Schiff base complexes and oxygen-sorbing and -desorbing solutions of the same, pressure- and temperature-swing oxygen separation processes using the complexes and solutions, and methods of regenerating such complexes and solutions.

Abstract: An ozone filter for decomposing ozone in the air is disclosed. The ozone filter is composed of a carrier formed by paper made of inorganic fibers having a porosity of 70 to 95%. The carrier is impregnated with a solution of fine powder-like activated manganese dioxide dispersed in water and having a particle size of 0.3 to 50 .mu.m and a specific surface area of not less than 100 m.sup.2 /g in an amount of not less than 40 g/m.sup.2, on a dry white base of activated manganese dioxide, which is allowed to adhere to the carrier, and is then dried. The ozone filter thus produced is more active and has a longer life with a reduced pressure loss than conventional ozone filters.

Abstract: An oxygen-absorbing composition containing particulate annealed electrolytically reduced iron of between about 100 mesh and 325 mesh in an amount of about up to 99.6% by weight, a salt such as sodium chloride in an amount by weight of about up to 3.5%, and optionally a water-attracting and supplying component such as silica gel of a mesh size of between about 30 mesh and 325 mesh in an amount by weight of up to about 80%. A packet for absorbing oxygen including a stain and grease resistant envelope containing the oxygen-absorbing composition. A grease and stain resistant laminate consisting of plies of various plastics and grease and stain resisting paper.

Abstract: Impurities such as oxygen and moisture can be removed from sulfur hexafluoride by contacting the impure gas with the reaction product of sulfur hexafluoride and a lithium-substituted macroreticulate polymer.

Abstract: In the process for the production of oxygen by adsorption, the following combination of steps are used: the number of adsorbers is at least three; the time of pumping y under sub-atmospheric pressure during step b) is higher than dephasing T/n, and at least equal to the time x of the production step; the phase of pumping of the column of adsorbent material is carried out by using on said adsorption column successively at least two systems of pumping wherein one is in operation from the start of the pumping operation, another one is adapted to operate until pumping is over.

Abstract: The present invention relates to specific activated carbon materials including from 1 to 5% by weight of nitrogen, from 3 to 30% by weight of oxygen and from 40 to 95% by weight of carbon, and having an average pore radius of from 15 to 30 .ANG., with the proviso that mesopores occupy at least 50% by volume based on the total pore volume, and also relates a process for the preparation thereof, and to the use thereof as catalysts.

Abstract: Regeneration of an ozone decomposing reactor which comprises:a catalyst structure composed of a carrier having at least one passage extending therethrough for allowing an ozone containing fluid to pass through the catalyst structure and a catalyst and an electroconductive material carried in or on the carrier; andelectrodes attached to the catalyst structure to electrify the structure, whereby to decompose ozone at elevated temperatures and regenerating deactivated structure by electrifying and heating.The carrier is either a ceramic honeycomb mold or a fiber board.

Abstract: A process for separating methane from an oxygen-containing gas mixture which contains methane at a concentration greater than the upper explosive gas mixture limit by pressure swing adsorption without producing an explosive gas mixture. The process includes the steps of feeding the gas mixture into an adsorber which contains an adsorbent which preferentially adsorbs methane until the desired production pressure is attained in the adsorber and then stopping the flow of feed gas into the adsorber and charging methane product gas at the production pressure cocurrently into the adsorber while simultaneously withdrawing nonadsorbed product gas from the nonadsorbed product end of the adsorber. The desorbed product stream is enriched in methane relative to the feed stream and the concentration of methane in the nonadsorbed product stream is less than the minimum flammable mixture concentration.

Abstract: Process for air decontamination consists of circulating air in a soaking chamber through several air-permeable barriers which are continuously bathed in solutions containing various chemical reagents which remove toxic, solid and gaseous pollutants from the air.

Abstract: Nitrogen-sorbing and -desorbing compositions and methods of using the same are disclosed, which are useful for the selective separation of nitrogen from other gases, especially natural gas.

Abstract: Carbon molecular sieves modified by the incorporation of finely divided elemental copper useful for the selective sorption of oxygen at elevated temperatures. The carbon molecular sieves can be regenerated by reduction with hydrogen. The copper modified carbon molecular sieves are prepared by pyrolysis of a mixture of a copper-containing material and polyfurfuryl alcohol to form a sorbent precursor. The sorbent precursors are then heated and reduced to produce copper modified carbon molecular sieves. The copper modified carbon molecular sieves are useful for sorption of all concentrations of oxygen at temperatures up to about 200.degree. C. They are also useful for removal of trace amount of oxygen from gases at temperatures up to about 600.degree. C.

Abstract: A catalyst for decomposing ozone comprising a carrier and a catalytic active substance having ozone resolvability carried thereon in a thickness of 10 to 200 .mu.m. Consequently, ozone can efficiently be removed. The invention also includes the catalytic active substance or ozone adsorption substance which is contained in the carrier, such that the combination of the carrier and its contained material has ozone resolvability or ozone adsorbing ability in itself. Accordingly, the combination of these two features allows the thickness of the catalytic active substance carried on a carrier surface to be reduced to the range from 5 to 100 .mu.m. Thus, improved productivity, durability of the catalyst and ozone removing efficiency are provided.

Abstract: A chemical vapor deposition apparatus having a gas purifier for purifying a raw-material gas such as AsH.sub.3 or PH.sub.3 gas, the gas purifier being constructed as the combination of an organometal and a molecular sieve. Gas of AsH.sub.3, PH.sub.3 or the like is introduced into the organometal whereby impurities such as H.sub.2 O or O.sub.2 contained in the raw-material gas (AsH.sub.3, PH.sub.3, etc) are removed. Further, organometal vapor occured from gas purifier is removed by the molecular sieve.

Abstract: A process for producing a substantially oxygen-free gaseous product such as argon containing not more than one ppm by volume of oxygen is disclosed. The process comprises introducing hydrogen into a gas stream which contains oxygen and moisture, contacting the gas stream with a dessicant to remove substantially all of the moisture therefrom, contacting the substantially anhydrous gas stream with an oxidation catalyst to convert substantially all of the oxygen in the gas stream to water, and contacting the resultant gas stream with a dessicant to remove the water created in the oxidation step. The product stream may be further purified to remove residual hydrogen contained therein.

Abstract: A reflow system for heating solders temporarily attaching electronic components to a circuit board, includes an elongated heating chamber in which a conveyor extending from an inlet to an outlet of the heating chamber, at least one first heating unit, a fan unit and an organic substance decomposition unit are disposed. The conveyor, first heater unit and fan unit are arranged to circulate gas in the heating chamber along a circulation path such that the gas is first heated by the first heater unit, then forced by the fan against the conveyor, and thereafter heated again by the first heater unit. The organic substance decomposition unit is disposed in the circulation path. The solders are heated by hot air. It is possible to heat the solder with hot nitrogen gas in which instance a nitrogen gas supply unit disposed outside the heating chamber is used to fill the heating chamber with nitrogen gas.

Abstract: A reactive membrane for simultaneous removal of heterogeneous and homogeneous impurities such as moisture, oxygen and organic compounds from gases is provided. The membrane comprises a substrate layer having a plurality of pores therein, at least one layer of carbon on the porous substrate layer and coating the pores thereof, and at least one reactive layer of a metal in reduced form capable of reacting with the impurities and chemically bonded to the carbon layer. A method of forming the same is also provided.

Abstract: Highly purified rare gas (helium, neon, argon, krypton, xenon, etc.) is obtained by removing impurities contained therein, such as nitrogen, hydrocarbon, carbon monoxide, carbon dioxide, oxygen, hydrogen and water, at relatively low temperatures by the use of a getter. This getter is a two-component alloy of zirconium and vanadium, or a multi-component alloy containing, as well as zirconium and vanadium, at least one of chromium, nickel and cobalt.

Abstract: A method for purifying flue-gasses and other hot, oxidative waste gasses originating from industrial installations, combustion furnaces, engines and the like, whereby the hot gas to be purified is passed through at least one spraying chamber or -area and is contacted therein with a gas washing liquid, which is sprayed into the hot gas flow and cools the gas to below 100.degree. C., whereby residual liquids with a high C.Z.V.-value, which comprise complex builders, compounds of heavy metals, sulphur- and nitrogen compounds, and originating amongst others from fixing-baths and the like from the photographic, photochemical and galvanic industries, are used as gas washing liquid.

Abstract: A chemisorptive metal alloy includes from about 30% to about 70% by weight of Ti and/or Zr and from about 30% to about 70% by weight of Cu. Optionally, the alloy may also contain from 0% to about 5% by weight of Fe; from 0% to about 10% by weight of Ni; from 0% to about 5% of V; and from 0% to about 5% of Cr.A method of purifying a reactive gas and removing foreign impurities therefrom includes conducting the impurities containing reactive gas, such as chlorine, hydrogen chloride, silane and dichlorosilane, through a bed of the above described pulverized metal alloy and removing the impurities from the gas by chemisorption on the alloy.

Abstract: The present invention is directed toward an electrolytic ozonier for treating ozone-containing waste gas and a method of treating ozone-containing waste gas using the ozonier, wherein the method includes evolving oxygen and ozone in an anode compartment of an electrolytic cell by electrolysis of water while evolving hydrogen in a cathode compartment; directing the evolved hydrogen into a waste gas treating section that contains a waste gas decomposition catalyst so as to convert the hydrogen to a harmless form by means of the catalyst; bringing the oxygen and ozone into contact with a medium to be treated in an ozone contactor so as to treat the medium; and subsequently directing waste gas containing oxygen and ozone produced as a result of treatment of the medium into the waste gas treating section where they are brought into either direct or indirect contact with the catalyst so that the ozone in the waste gas is converted into a harmless form.

Abstract: Oxygen is separated from an oxygen-containing gas by introducing the gas into a first zone of a gas separation apparatus, the apparatus comprising first and second zones separated by a mixed metal oxide membrane, the membrane having a first surface open to the first zone, a second surface open to the second zone, and an empirical formula ofBiA.sub.x M.sub.y M'.sub.z O.sub.nwhere A is at least one of Mg, Ca, Sr, Ba, Y, Th, U, and the lanthanide elements; M is at least one of Sc, Ti, Cr, Mn, Fe, Ni, Cu and Zn; and M' is at least one of Co, Rh, Pd, Pt or Ru. The oxygen separated from the oxygen-containing gas can be recovered from the second surface of the membrane either as molecular oxygen, or it can be reacted with an oxygen-consuming substance, such as a hydrocarbon gas, which can be introduced into the second zone of the separation apparatus and brought in contact with the second surface of the membrane.

Abstract: A catalyst for the purification of a gas containing ozone or a component of offensive odor is composed of (A) a composite oxide comprising (a) titanium and (b) at least one element selected from the group consisting of Si, Zr, and P and (B) at least one element selected from the group consisting of Mn, Fe, Co, Ni, Ag, Pt, Pd, and Rh.

Abstract: A supported catalyst having a support body which is formed by one or more metal foils and which is well suited for catalytically decomposing ozone and for catalytically oxidizing carbon monoxide. Preferred embodiments further include a heat exchanger which permits the supported catalyst to be used as a catalytic heat exchanger, in particularly for treating fresh air for passenger compartments of vehicles.

Abstract: A deoxidizer sheet suitable for preservation of goods such as foods is provided that has a first layer which essentially contains a deoxidation reaction main agent, such as mixture of iron powder and a metal halide, and a fixing material such as natural or synthetic fibers and heat-meltable resin fibers or powder. The deoxidizer sheet also has a pair of second layers heat-bonded to both surfaces of the first layer.

Abstract: A process is provided for selectively separating oxygen from an oxygen-containing fluid stream by bringing said fluid stream into contact with a high capacity solid state cyanocobaltate complex in a non-aluminosilicate environment represented by the chemical formula:A.sub.x/z.sup.z+ [Co(CN).sub.n ].sup.x- .multidot.pSwhere:A is an alkali, alkaline earth, transition, or Group 12 metal atom;z is 1, 2 or 3;n is any number from 3 to 5;x is n-2;p is any number from greater than zero to 6; andS is a ligand which is capable of coordinating with A.sup.z+, Co or both.These complexes chemically bind oxygen to form novel oxygen adducts, thereby selectively removing oxygen from the fluid stream. The bound oxygen may be recovered by increasing the temperature or by reducing the partial pressure of O.sub.2 above the adduct.

Abstract: An apparatus for forming an image by electrostatic charge comprises an image forming part including a photoconductive drum and an electrostatic charger for forming an image by electrostatic charge, and an ozone eliminating filter located in the air flow generated by the rotation of the photoconductive drum. The ozone eliminating filter includes a coating layer made of a coating material to eliminate ozone in the ambient air. The coating material includes an ozone eliminating substance an organic binder and a foaming agent. The ozone eliminating filter may be made of adhesive double-coated tape which includes an ozone eliminating substance on one side.

Abstract: A binuclear metal complex, comprising a metal-complexed ligand which ligand is formed by the reaction of a dialdehyde and a poly primary amine, which complex is capable of reacting reversibly with molecular oxygen.

Abstract: There are disclosed an oxygen absorbent comprising boron or a reducing boron compound, an alkaline substance and a carrier, an oxygen absorbent parcel formed by enclosing said oxygen absorbent in a permeable packaging parcel, a food package and a package of a metallic or electronic product or part containing said oxygen absorbent parcel.

Abstract: Carbon molecular sieves modified by the incorporation of finely divided elemental copper useful for the selective sorption of oxygen at elevated temperatures. The carbon molecular sieves can be regenerated by reduction with hydrogen. The copper modified carbon molecular sieves are prepared by pyrolysis of a mixture of a copper-containing material and polyfunctional alcohol to form a sorbent precursor. The sorbent precursors are then heated and reduced to produce copper modified carbon molecular sieves. The copper modified carbon molecular sieves are useful for sorption of all concentrations of oxygen at temperatures up to about 200.degree. C. They are also useful for removal of trace amount of oxygen from gases at temperatures up to about 600.degree. C.

Abstract: There is disclosed a catalyst structure for ozone decomposition which comprises a thin porous carrier material which has many micropores in the direction of the thickness of the carrier material and has an ozone decomposition catalyst supported thereon.Also disclosed is a method of ozone decomposition using such a catalyst structure, in which preferably the catalyst structure comprises a thin porous carrier material which has many micropores not less than 30 .mu.m in diameter in the direction of the thickness of the carrier material and has an ozone decomposition catalyst supported thereon. The carrier material may be of an electrically resistant material, and may be electrified and heated while a gas containing ozone is forcibly passed therethrough.

Abstract: A unit in the form of a bubble pack for creating an anaerobic gaseous atmosphere in an upright container and for indicating the presence of the anaerobic atmosphere in the container. One bubble of the pack houses acid-containing ampoules while another bubble houses a tablet which generates hydrogen and carbon dioxide when activated by squeezing the first bubble to crush the ampoules and release the acid. Gas flows from the second bubble, through the first bubble and then into the container and enters still another bubble which houses an ampoule containing a redox color indicating liquid. When the latter ampoule is crushed, the liquid moistens an absorbent pad which changes colors as the atmosphere of the container changes from aerobic to anaerobic. The pack also carries catalyst pellets to promote a reaction between the generated hydrogen and the oxygen in the container.

Abstract: What is disclosed is a method of oxygen removal employing at least one solid bed of oxygen removal chemical; for example, Fe.sub.2 S.sub.3 on wood chips. Also disclosed are preferred embodiments in which are employed within the at least one bed a temperature sensor, a controller is connected with the temperature sensor and a gas operated control valve is connected with the controller such that the valve is operated to shut off the valve to the sales line if the temperature sensed is greater than a preset temperature; e.g. 150 degrees Fahrenheit.

Abstract: Hydrogen sulfide can be conveniently removed from streams containing up to about 1,000 ppm of H.sub.2 S by reacting the latter with an olefin using a bed of an acidic solid catalyst in a non-oxidative process for the removal of hydrogen sulfide. The reaction can be effected under relatively mild conditions and is very selective for the removal of hydrogen sulfide without being attended by other unwanted reactions such as oligomerization, disproportionation, and skeletal rearrangement. Levels of hydrogen sulfide in the treated product of no more than about 5 ppm can be readily attained using a broad variety of acidic solid catalysts and unsaturated hydrocarbons, especially olefins.

Abstract: A scavenger for purifying inert gas mixtures to remove Lewis acid and oxidant impurities therefrom, comprising (i) an inert inorganic support, and (ii) an active scavenging species on the support, formed by deposition thereon of an organometallic precursor and pyrolysis thereof at a selected elevated temperature. The organometallic precursor is an alkyl metal compound comprising a metal of Group IA, IIA, and/or IIIA, wherein the pyrolysis temperature may range from about 150.degree. C. to about 250.degree. C., depending on the specific alkyl metal compound employed as the precursor. Also disclosed are: a corresponding method of making the scavenger; a process for purifying inert gases by contacting same with the scavenger; and a vessel containing a bed of the scavenger, useful as an apparatus for purifying inert gases.

Abstract: The present invention is directed to a chemical air separation process using a molten salt solution of alkali metal nitrate and nitrite wherein the materials of construction of the containment for the process are chosen from intermetallic alloys of nickel and/or iron aluminide wherein the aluminum content is 28 atomic percent or greater to impart enhanced corrosion resistance.

Abstract: A gas separation film comprising a perm-selective layer which is formed by reaction in situ of a Schiff base metal complex compound represented by the following formula (I) ##STR1## wherein rings A and B each represent an o-phenylene or o-naphthylene group which may be substituted by at least one group selected from the class consisting of halogen atoms and groups of the formula --X-R in which R represents a saturated or unsaturated aliphatic hydrocarbon group having not more than 22 carbon atoms and X represents a direct bond or a binding member between R and ring A or B, selected from the class consisting of --O--, --COO--, --NHCO-- and --S--, R.sub.o represents a hydrocarbon group having not more than 6 carbon atoms in which adjacent carbon atoms or adjacent carbon atoms via one carbon atom are bound to bonds a and b, and M represents a metal selected from the group consisting of Fe, Co, Cu, Ni, Mn, Cr and Zn,with a polymeric ligand.

Abstract: A process for making high purity argon is disclosed in which crude argon containing less than about 0.8 mol % oxygen is recovered from air in a cryogenic distillation system, the crude argon is purified by removing oxygen in a getter system, and other impurities are removed by cryogenic distillation to yield a high purity argon product. The crude argon purification system is heat integrated with the main cryogenic air separation system. High purity argon can be produced at argon recoveries greater than 90% by utilizing structured packing in at least a portion of the argon sidearm column.

Abstract: A method for purifying a gaseous hydride, which comprises bringing a crude gaseous hydride into contact with at least one material from nickel arsenides, nickel phosphides, nickel silicides, nickel selenides, or nickel borides to remove oxygen contained in the crude gaseous hydride.

Abstract: Methods and apparatus for the extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising linear, pentadentate polyalkylamines and transition metal ions. The carrier compounds have the general formula: ##STR1## where, each of R.sub.1 and R.sub.2 is independently an organic group including a sulfur, an oxygen or a nitrogen coordinated to M;each of m, n, o, and p is 1, 2, 3, or 4;X is selected from the group consisting of 2,6-pyridyl, 2,6-piperidyl, 2,5-pyrrolyl, 2,4-imidazolyl, substituted heterocyclic amines, --)--, --S--, ##STR2## and ##STR3## where R.sub.3 is hydrogen, lower alkyl or aralkyl; and M is a transition metal ion.

Abstract: Methods and apparatus for electrochemical extraction of a ligand such as molecular oxygen from a first fluid environment and for release of a ligand such as molecular oxygen, as well as ligand carrier compounds therefor comprising macrocyclic amines having the general formulas: ##STR1## where: A, B, C, D, E, and F are each nitrogen, oxygen, sulfur, or phosphorous;m, n, o, p, q, and r are each typically 2, 3, 4, 5, or 6;the R substituents are each generally H or short chain (linear or branched) alkyl, although R.sub.2 may represent ketyl (.dbd.o); andM is a suitable transition metal ion.

Abstract: A scavenger for purifying inert gas mixtures to remove Lewis acid and oxidant impurities therefrom, comprising (i) an inert inorganic support, and (ii) an active scavenging species on the support, formed by deposition thereon of an organometallic precursor and pyrolysis thereof at a selected elevated temperature. The organometallic precursor is an alkyl metal compound comprising a metal of Group IA, IIA, and/or IIIA, wherein the pyrolysis temperature may range from about 150.degree. C. to about 250.degree. C., depending on the specific alkyl metal compound employed as the precursor. Also disclosed are: a corresponding method of making the scavenger; a process for purifying inert gases by contacting same with the scavenger; and a vessel containing a bed of the scavenger, useful as an apparatus for purifying inert gases.

Abstract: Separation of oxygen from air is performed in a continuous, cyclic manner using vanadium bronze liquid slurries as reversible chemical absorbents, absorbing at elevated temperature and desorbing at lowered temperature.

Abstract: Salts containing cations of the formula: ##STR1## (in which M is Co, Fe, Cr or Mn, X, Y, R.sub.1,The Government has rights in this invention pursuant to Contract Number CHE-75-14837 awarded by the National Science Foundation.

Abstract: An apparatus in the form of a disk for the separation of oxygen from gases, or for the pumping of oxygen, uses a substantially circular disk geometry for the solid electrolyte with radial flow of gas from the outside edge of the disk to the center of the disk. The reduction in available surface area as the gas flows toward the center of the disk reduces the oxygen removal area proportionally to provide for a more uniform removal of oxygen.

Abstract: The present invention relates to a three stage process using copper, copper oxide and molecular sieve adsorbent beds for the sequential removal of oxygen, hydrogen, carbon monoxide, carbon dioxide and water from an inert feed gas. The process is especially suited to the purification of nitrogen gas from an air separation plant, which can be purified from a contaminant level of 30 vppm oxygen+carbon monoxide+hydrogen to less than 10 vppb each of oxygen, carbon monoxide, hydrogen, carbon dioxide and water, without the addition of hydrogen or another reducing gas to the process.

Abstract: The present invention is directed to a process for removing minor amounts of oxygen from inert gas streams to result in very low levels of oxygen contamination in such inert gas streams, wherein the oxygen is removed by the action of stoichiometric quantities of methanol, which react with the oxygen over a catalyst at ambient feed temperature conditions without a requirement for external heating of the reaction.

Abstract: The present invention is directed to a process for producing endothermic gases from methanol and inert gas streams containing minor amounts of oxygen, wherein the oxygen is reacted with stoichiometric excess quantities of methanol over a catalyst as ambient feed temperature conditions without a requirement for external heating of the reaction to produce an endothermic gas containing very low levels of oxygen and methanol and significant quantities of hydrogen, carbon monoxide, water and carbon dioxide.