Ammonium Compound Reactant Patents (Class 423/243.06)
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Patent number: 11224835Abstract: This disclosure provides a method for treating natural gas comprising causing at least some of a sour natural gas stream comprising hydrocarbon gas and hydrogen sulfide to contact an amine or pass through a separation system. A sweet natural gas stream comprising hydrocarbon gas and a waste gas stream comprising hydrogen sulfide are formed by contacting the sour natural gas with an amine or by passing it though a separation device. At least some of the hydrogen sulfide in the waste gas stream is oxidized, forming an exhaust gas stream comprising sulfur dioxide, which is then contacted with water or reactant and water solution or slurry to destroy or convert SO2 into a less environmentally harmful compound.Type: GrantFiled: May 25, 2018Date of Patent: January 18, 2022Assignee: Fisher AGC, LLCInventor: John Fisher George, III
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Patent number: 11027234Abstract: Apparatus and methods for oxidizing an ammonia desulfurization solution. The apparatus may include an oxidation air system. The apparatus may include an oxidation tank. The apparatus may include in the tank, a gas-liquid dispersion enhancer. The enhancer may include a sieve plate layer that includes a sieve plate. The sieve plate layer may be one of a plurality of sieve plate layers. The plurality may include two or three sieve plate layers. The apparatus may include an oxidation enhancing device mated to the tank. The oxidation enhancing device may include an acoustic wave generating device. The oxidation enhancing device includes an ultrasonic wave generating device. The ultrasonic generating device may be configured to provide a sound intensity in the range 12 to 40 Watts/Liter. The ultrasonic generating device may be configured to provide to a liquid sound intensity in the range 12 to 40 Watts/Liter.Type: GrantFiled: June 13, 2018Date of Patent: June 8, 2021Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Lifang Qi, Yongying Luo
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Patent number: 10953365Abstract: Apparatus and methods for treating acid gas, which utilizes multi-stage absorption cycle of ammonia desulfurization to treat acid tail gas after pre-treatment of the acid gas, thereby achieving the purpose of efficient and low-cost treatment of acid tail gas. The parameters of the acid tail gas may be adjusted by a regulatory system such that the enthalpy value of the acid tail gas is in the range of 60-850 kJ/kg dry gas, for example, 80-680 kJ/kg dry gas or 100-450 kJ/kg dry gas, to meet the requirements of ammonia desulfurization, and achieve the synergy between the acid gas pre-treatment and ammonia desulfurization. Furthermore, hydrogen sulfide may be converted into sulfur/sulfuric acid plus ammonium sulfate at an adjustable ratio.Type: GrantFiled: January 13, 2020Date of Patent: March 23, 2021Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Lifang Qi
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Patent number: 10730009Abstract: A process for purifying exhaust air from a granulation plant for producing a urea-containing granulate includes contacting a gas stream containing a urea-containing dust and ammonia with a sulfuric acid solution or a nitric acid solution in a scrubbing process. The scrubbing process involves scrubbing the gas stream with a first weakly acidic scrubbing solution in a first scrubbing stage and scrubbing the gas stream exiting the first scrubbing stage with a second scrubbing solution having a lower pH than the first weakly acidic scrubbing solution in a second scrubbing stage. The acidic scrubbing solution generated in the second scrubbing stage may be recycled into the first scrubbing stage via a conduit and used therein as the first weakly acidic scrubbing solution. A pre-scrubbing stage for scrubbing dust out of the gas stream may additionally be arranged upstream of the first scrubbing stage.Type: GrantFiled: February 22, 2018Date of Patent: August 4, 2020Assignees: THYSSENKRUPP FERTILIZER TECHNOLOGY GMBH, THYSSENKRUPP AGInventors: Thomas Gerner, Rositsa Marianova Rieks
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Patent number: 10561982Abstract: Apparatus and methods for desulfurization of a sulfur-oxide containing gas by treatment with ammonia containing liquids. The apparatus and methods may utilize two distinct circuits of two different ammonia containing liquids which are applied in two distinct chambers. The gas may be cooled prior to entry into the circuits. There may be fluid communication between the two circulation circuits.Type: GrantFiled: July 26, 2019Date of Patent: February 18, 2020Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Changxiang Xu, Xiangjun Xu, Yongying Luo
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Patent number: 10478775Abstract: The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants, etc.Type: GrantFiled: July 19, 2017Date of Patent: November 19, 2019Assignee: The Babcock & Wilcox CompanyInventors: Prasanna Seshadri, Richard DeVault
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Patent number: 10471383Abstract: Apparatus and methods for denitrification and desulfurization of and dust removal from an FCC tail gas by ammonia-based process. The apparatus may include a first-stage waste heat recovery system a denitrification system, a dust removal and desulfurization system, a tail gas, exhaust system, and an ammonium sulfate post-processing system. The dust removal and desulfurization system may include as deducting tower and an absorption tower disposed separately. The top and the bottom of the absorption tower may be connected respectively to the tail gas exhaust system and the ammonium sulfate post-processing system. The absorption tower may include sequentially, from bottom to top, an oxidation section, an absorption section, and a fine particulate control section. The methods may be implemented with the apparatus.Type: GrantFiled: June 3, 2019Date of Patent: November 12, 2019Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Jun Zhang, Yongying Luo, Qiang Tan, Xiangjun Xu
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Patent number: 10413865Abstract: Apparatus and methods for desulfurization of a sulfur-oxide containing gas by treatment with ammonia containing liquids. The apparatus and methods may utilize two distinct circuits of two different ammonia containing liquids which are applied in two distinct chambers. The gas may be cooled prior to entry into the circuits. There may be fluid communication between the two circulation circuits.Type: GrantFiled: November 13, 2018Date of Patent: September 17, 2019Assignee: Jiangnan Enviromental Protection Group Inc.Inventors: Jing Luo, Changxiang Xu, Xiangjun Xu, Yongying Luo
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Patent number: 10406478Abstract: Apparatus and methods for desulfurization of a sulfur-oxide containing gas by treatment with ammonia containing liquids. The apparatus and methods may utilize two distinct circuits of two different ammonia containing liquids which are applied in two distinct chambers. The gas may be cooled prior to entry into the circuits. There may be fluid communication between the two circulation circuits.Type: GrantFiled: June 26, 2018Date of Patent: September 10, 2019Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Changxiang Xu, Xiangjun Xu, Yongying Luo
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Patent number: 10399033Abstract: Apparatus and methods for desulfurization of a sulfur-oxide containing gas by treatment with ammonia containing liquids. The apparatus and methods may utilize two distinct circuits of two different ammonia containing liquids which are applied in two distinct chambers. The gas may be cooled prior to entry into the circuits. There may be fluid communication between the two circulation circuits.Type: GrantFiled: March 19, 2019Date of Patent: September 3, 2019Assignee: Jiangnan Environmental Protection Group Inc.Inventors: Jing Luo, Changxiang Xu, Xiangjun Xu, Yongying Luo
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Patent number: 9702552Abstract: A method and system for the conversion of waste into energy in a sealed system where combustion does not take place and the operating pressure prior to the inlet of the steam or power generating equipment is maintained below atmospheric pressure. Destruction of the RDF (refuse derived fuel) is accomplished by subjecting the RDF to a high temperature environment under controlled conditions in a purpose designed and built reactor. The high temperature environment, <5000° C., is achieved through the use of one or more non-transferred plasma torches for generation of plasma gas. The plasma gas exiting the torch and provides the thermal energy for the continual gasification of metallurgic coke configured as a carbon bed in the lower part of the reactor, which acts as a thermal catalyst and this provides the thermal energy for the gasification process.Type: GrantFiled: August 13, 2010Date of Patent: July 11, 2017Assignee: GREEN ENERGY AND TECHNOLOGY SDN. BHD.Inventors: Mazlan Ali, Siti Fatimah Mohd Shariff
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Patent number: 9346007Abstract: Contemplated configurations and methods for flue gas treatment comprise a quench section and a scrubbing section that are configured and operated to avoid net condensation of water from the quenched flue gas in the scrubbing section. Consequently, the active agent in the scrubbing medium can be maintained at high concentration and will so allow continuous removal of SOX and NOX to very low concentrations. Moreover, as the scrubbing medium is not diluted by condensate, loss of active agent can be substantially reduced. Especially preferred systems will reduce SO2 concentrations in flue gas to less than 5 ppm, and more typically less than 3 ppm while substantially reducing water and reagent consumption.Type: GrantFiled: December 14, 2006Date of Patent: May 24, 2016Assignee: Fluor Technologies CorporationInventors: Satish Reddy, Jeffrey Scherffius, Valerie Francuz
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Patent number: 8968691Abstract: An object of the present invention is to provide a treatment method and a plant of an exhaust gas in which corrosion resistance of the exhaust gas treatment plant to a sulfuric acid mist after wet type desulfurization is increased. The treatment method of an exhaust gas in the present invention, wherein sulfur oxide is removed by wet type desulfurization of the exhaust gas and a sulfuric acid mist is removed by feeding ammonia into the exhaust gas, is characterized in that an ammonia gas is mixed into the exhaust gas by feeding inorganic ammonium salt to an alkali desulfurizing agent when the desulfurizing agent is sprayed into the exhaust gas to absorb and remove the sulfur oxide in the exhaust gas.Type: GrantFiled: August 2, 2011Date of Patent: March 3, 2015Assignee: Hitachi, Ltd.Inventors: Yoshihiko Mochizuki, Naoyuki Ohashi
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Patent number: 8865097Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.Type: GrantFiled: August 5, 2013Date of Patent: October 21, 2014Inventors: Baoquan Zhang, Xiaoqing Zhang
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Patent number: 8858905Abstract: A system and a process for capture and absorption of sulfur dioxide and carbon dioxide by an ammonia method at normal pressure are disclosed.Type: GrantFiled: February 10, 2012Date of Patent: October 14, 2014Assignee: Anhui Huaihua Co. Ltd.Inventors: Jingyao Xu, Lin Chen, Mingxu Zhang, Song Han, Chuanhao Su, Fanfel Min, Hanxu Li
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Patent number: 8778135Abstract: A circular utilization method in pulping and papermaking processes with straw Primary pulp is obtained by digesting straw raw material according to the ammonium sulfite method. Concentrated black liquor is extruded from the primary pulp; paper pulp and diluted black liquor. The concentrated black liquor and the diluted black liquor are mixed, and a contaminated condensate is obtained. A residual concentrate or the concentrated black liquor is used for preparing a fertilizer. The contaminated condensate is mixed with one or more of the waste material obtained from stock preparation, a crop byproduct or organic waste, and substrate or fertilizer is obtained by fermenting the nitrogen source of the contaminated condensate or ammonium sulfite, or using the contaminated condensate for desulfurizing flue gas. Ammonia and flue gas are reacted to obtain the ammonium sulfite as a digestion agent; and water from recycling is used in corresponding phases of the pulping process.Type: GrantFiled: March 11, 2011Date of Patent: July 15, 2014Assignee: Shandong Tralin Paper Co., Ltd.Inventors: Hongfa Li, Mingxin Song, Songtao Chen, Jihui Yang, Liangjin Guo
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Patent number: 8765089Abstract: A process for reducing nitrogen oxides and halogenated organic compounds in an incineration plant having at least one combustion chamber. The process comprises separating out fly ash using a dust collector. Water is added to and hydrochloric acid separated out in a first acid-operated scrubber. Water and ammonia are added so as to separate out sulphur dioxide in a second neutral or slightly acid-operated scrubber so as to form ammonium sulphite, a portion of the ammonium sulphite thereby reacts with oxygen so as to form an aqueous ammonium sulphate/ammonium sulphite solution. The aqueous ammonium sulphate/ammonium sulphite solution is introduced into an oxygen-containing smoke gas downstream of a secondary gas introduction area so as to decompose the ammonium sulphate and ammonium sulphite so as to form ammonia and sulphur dioxide.Type: GrantFiled: March 8, 2007Date of Patent: July 1, 2014Assignee: Forschungszentrum Karlsruhe GmbHInventor: Hans Hunsinger
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Patent number: 8529852Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, and an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.Type: GrantFiled: March 26, 2012Date of Patent: September 10, 2013Inventors: Baoquan Zhang, Xiaoqing Zhang
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Publication number: 20130089482Abstract: Methods for removing acid gases and recovering water from flue gas. A flue gas is introduced into a water spray tower and is cooled by direct contact with a sprayed aqueous stream to condense a portion of the water vapor in the flue gas. Acid gases present in the flue gas are absorbed into the aqueous mixture, and a chemical added to the stream facilitates conversion of absorbed acid gases. The aqueous stream leaving the spray tower is next treated to remove contaminants, such as carbonates and bicarbonates, thereby producing a cleaned aqueous stream that may be split into a stream that is cooled prior to reuse in the spray tower, as well as a stream that is fed back to the boiler.Type: ApplicationFiled: October 1, 2012Publication date: April 11, 2013Applicant: PHILLIPS 66 COMPANYInventors: Edward G. LATIMER, George F. SCHUETTE, Clint P. AICHELE, Mitchell E. LOESCHER, Randall L. HEALD
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Patent number: 8398945Abstract: Process for scrubbing out ammonia nitrogen and/or ammonium nitrogen and/or urea nitrogen from exhaust gases enriched with these nitrogen compounds in plants for producing ammonia or urea, wherein the nitrogen compounds first form with a hypochlorite-containing solution in a scrubber an intermediate which under acidic or neutral reaction conditions is reacted to form elemental nitrogen and salt, and the reaction of the nitrogen compounds to form elemental nitrogen and salt proceeds in a pH range of 4 to 6.Type: GrantFiled: November 27, 2009Date of Patent: March 19, 2013Assignee: Thyssenkrupp Uhde GmbHInventors: Helmut Gehrke, Dennis Lippmann
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Publication number: 20130004400Abstract: Processes for recovering ammonia from an ammonium sulfate stream include reacting the ammonia sulfate stream with a lime slurry to form a slurry comprising calcium sulfate and ammonia; providing the slurry comprising calcium sulfate and ammonia to a stripper configured to recover the ammonia from the slurry; utilizing a heat source from a chilled ammonia process to the stripper; and extracting an ammonia vapor stream from the stripper. Also disclosed are systems for performing the processes.Type: ApplicationFiled: February 21, 2012Publication date: January 3, 2013Applicant: ALSTOM TECHNOLOGY LTD.Inventors: DAVID JAMES MURASKIN, SANJAY KUMAR DUBE
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Patent number: 8329128Abstract: A gas stream containing carbon dioxide and sulfur dioxide is cleaned by removing, in a sulfur removal stage, sulfur dioxide from the gas stream. Sulfur dioxide is removed from the gas stream by bringing the gas stream into direct contact with ammonia. The used ammonia may be recycled. In a carbon dioxide removal stage, carbon dioxide is removed from the gas stream depleted in sulfur dioxide by bringing the gas stream into contact with an ammoniated liquid. Following sulfur dioxide and carbon dioxide removal, in an ammonia removal stage, ammonia from the gas stream is removed. Ammonia is removed from the gas stream by bringing the gas stream into direct contact with an acidic liquid to absorb into the acidic liquid, ammonia from the gas stream. The used acidic liquid may be recycled.Type: GrantFiled: February 1, 2011Date of Patent: December 11, 2012Assignee: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, David James Muraskin
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Patent number: 8318116Abstract: An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.Type: GrantFiled: April 13, 2011Date of Patent: November 27, 2012Inventor: Liang Hu
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Patent number: 8168148Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.Type: GrantFiled: June 22, 2011Date of Patent: May 1, 2012Inventors: Baoquan Zhang, Xiaoqing Zhang
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Patent number: 8110164Abstract: A flue-gas purification system includes a flue-gas cycling system, a reactor, an absorbent adding system having at least a catalytic absorbent, wherein the catalytic absorbent is being gasified for reacting with the flue-gas in the reactor in a homogenous gas-gas phase reacting manner. Therefore, the purification system has fast reaction rate between the pollutants of the flue-gas and the catalytic absorbent, which is preferably ammonia, to efficiently remove pollutants, so as to effectively purify the flue-gas.Type: GrantFiled: June 28, 2010Date of Patent: February 7, 2012Inventors: Baoquan Zhang, Xiaoqing Zhang
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Patent number: 8048392Abstract: The present invention relates to a method for cleaning off-gas comprising the following steps: 1. Sulphur dioxide is separated from the off-gas by way of at least one first scrubber stage (c) by means of ammonia or ammonium compounds, 2. the off-gas is transferred into a second scrubber stage (d) and 3. in the second scrubber stage the sulphur dioxide not separated in the first scrubber stage (c), is oxidized to sulphuric acid and separated in at least one scrubber (d) and simultaneously, the ammonia released in the first scrubber stage (d) is separated by means of the formed sulphuric acid, whereby ammonium sulphate is formed, 4. the separated stream of the second scrubber stage (d) is transferred into the first scrubber stage (c).Type: GrantFiled: August 22, 2008Date of Patent: November 1, 2011Assignees: Karlsruher Institut für Technologie, Göotaverken Miljö ABInventors: Hans Hunsinger, Martin Karlssson, Sven Andersson, Ulf Hägg
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Publication number: 20110150733Abstract: A method of heating a used absorption liquid resulting from a carbon dioxide absorption stage in which a CO2 comprising gas stream is contacted with an absorption liquid comprising ammonia, wherein the used absorption liquid is subjected to heat exchange, in a heat exchanger, with a fluid of a desulfurization stage in which a SO2 comprising flue gas is contacted with a reagent composition comprising an alkaline compound.Type: ApplicationFiled: October 29, 2010Publication date: June 23, 2011Applicant: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, David James Muraskin
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Patent number: 7927576Abstract: The present invention relates to a system and process utilizing ammonium thio sulfate solution (ATS) as the primary liquid absorption agent that is re-circulated through an SO2 Contactor/Absorber for high efficiency contacting and absorption of sulfur dioxide, SO2 from a combustion gas stream generated by incineration of a Claus Sulfur Recovery Unit (SRU) off gas stream (often referred to as a Claus tail gas stream) and also additional SO2 generated from incineration of additional sulfur containing streams. ATS is also re-circulated through a separate H2S Contactor/Absorber for absorption of and reaction with a Sour Water Stripper (SWS) off gas stream and additional H2S-Acid Gas (A.G.) streams to produce additional concentrated ATS. The process and equipment also provides the ability to readily switch between using ATS and ABS as the primary absorbent solution for SO2 absorption, depending upon the concentration of SO2 in the off gas feed streams.Type: GrantFiled: November 1, 2010Date of Patent: April 19, 2011Assignee: Tessenderlo Kerley, Inc.Inventor: Mark P. Clarkson
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Publication number: 20110044875Abstract: The present invention relates to a system and process utilizing ammonium thio sulfate solution (ATS) as the primary liquid absorption agent that is re-circulated through an SO2 Contactor/Absorber for high efficiency contacting and absorption of sulfur dioxide, SO2 from a combustion gas stream generated by incineration of a Claus Sulfur Recovery Unit (SRU) off gas stream (often referred to as a Claus tail gas stream) and also additional SO2 generated from incineration of additional sulfur containing streams. ATS is also re-circulated through a separate H2S Contactor/Absorber for absorption of and reaction with a Sour Water Stripper (SWS) off gas stream and additional H2S-Acid Gas (A.G.) streams to produce additional concentrated ATS. The process and equipment also provides the ability to readily switch between using ATS and ABS as the primary absorbent solution for SO2 absorption, depending upon the concentration of SO2 in the off gas feed streams.Type: ApplicationFiled: November 1, 2010Publication date: February 24, 2011Applicant: TESSENDERLO KERLEY, INC.Inventor: Mark P. Clarkson
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Patent number: 7867322Abstract: A gas cleaning system, which is operative for cleaning a process gas containing carbon dioxide and sulphur dioxide, comprises a combined cooling and cleaning system (16), and a CO2-absorber. The combined cooling and cleaning system (16) comprises a first gas-liquid contacting device (50) located upstream of the CO2-absorber and operative for cooling the process gas by means of a cooling liquid, and for absorbing into the cooling liquid sulphur dioxide of the process gas, such that a cooling liquid containing sulphate is obtained. The combined cooling and cleaning system (16) further comprises a second gas-liquid contacting device (94) located downstream of the CO2-absorber and operative for removing ammonia from the process gas, which has been treated in the CO2-absorber, by means of bringing the process gas containing ammonia into contact with the cooling liquid containing sulphate.Type: GrantFiled: January 17, 2008Date of Patent: January 11, 2011Assignee: ALSTOM Technology LtdInventor: Eli Gal
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Patent number: 7867462Abstract: A method and system for controlling emissions with ammonia recovery and fly ash beneficiation in accordance with the present invention includes introducing ammonia to react with at least a portion of sulfur trioxides in an exhaust emission and result in at least one or more ammoniated compounds. At a least a portion of fly ash particles and the ammoniated compounds in the exhaust emission are precipitated and at least the precipitated fly ash particles are beneficiated. At least a portion of the beneficiated fly ash particles which are heated are mixed with the precipitated ammoniated compounds to recover at least a portion of the ammonia. The recovered ammonia is reused in introducing ammonia to react with at least a portion of sulfur trioxides.Type: GrantFiled: September 25, 2006Date of Patent: January 11, 2011Assignee: PMI Ash Technologies, LLCInventor: Joseph W. Cochran
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Publication number: 20100296993Abstract: The present invention relates to a method for cleaning off-gas comprising the following steps: 1. sulphur dioxide is separated from the off-gas by way of at least one first scrubber stage (c) by means of ammonia or ammonium compounds, 2. the off-gas is transferred into a second scrubber stage (d) and 3. in the second scrubber stage the sulphur dioxide not separated in the first scrubber stage (c), is oxidised to sulphuric acid and separated in at least one scrubber (d) and simultaneously, the ammonia released in the first scrubber stage (d) is separated by means of the formed sulphuric acid, whereby ammonium sulphate is formed, 4. the separated stream of the second scrubber stage (d) is transferred into the first scrubber stage (c).Type: ApplicationFiled: August 22, 2008Publication date: November 25, 2010Inventors: Hans Hunsinger, Martin Karlssson, Sven Andersson, Ulf Hägg
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Patent number: 7837965Abstract: A process for reducing hydrogen sulfide from a gas comprising contacting the gas with an aqueous scrubbing liquid recycled from a sour water stripper. The aqueous scrubbing liquid comprises ammonia. The contacting of the gas with the aqueous scrubbing liquid thereby produces a semi-sweet gas with reduced concentration of hydrogen sulfide and a rich liquid solution.Type: GrantFiled: December 10, 2008Date of Patent: November 23, 2010Assignee: Thiosolv, LLCInventor: Mark C. Anderson
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Patent number: 7824652Abstract: The present invention relates to a system and process utilizing ammonium thiosulfate solution (ATS) as the primary liquid absorption agent that is re-circulated through an SO2 Contactor/Absorber for high efficiency contacting and absorption of sulfur dioxide, SO2 from a combustion gas stream generated by incineration of a Claus Sulfur Recovery Unit (SRU) off gas stream (often referred to as a Claus tail gas stream) and also additional SO2 generated from incineration of additional sulfur containing streams. ATS is also re-circulated through a separate H2S Contactor/Absorber for absorption of and reaction with a Sour Water Stripper (SWS) off gas stream and additional H2S-Acid Gas (A.G.) streams to produce additional concentrated ATS. The process and equipment also provides the ability to readily switch between using ATS and ABS as the primary absorbent solution for SO2 absorption, depending upon the concentration of SO2 in the off gas feed streams.Type: GrantFiled: January 9, 2009Date of Patent: November 2, 2010Assignee: Tessenderlo Kerley, Inc.Inventor: Mark P. Clarkson
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Patent number: 7780932Abstract: A process for desulfurizing an SO2-comprising gaseous stream comprising the steps of: a. providing an aqueous feed comprising an anion selected from a group consisting of carbonate, bicarbonate, hydroxide, sulfite, and hydrogen sulfite; b. providing an SO2-comprising gaseous feed; and c. contacting the aqueous feed and the gaseous feed to generate a desulfurized gaseous product comprising less than 40% of the feed SO2 content, and an aqueous product; wherein the contacting is carried out in a cyclone unit comprising a housing defined by a cylindrical peripheral wall and provided with at least one inlet opening for receiving fluids thereinto and with at least one swirling means, and wherein the cyclone unit is characterized in that the velocity of the gaseous stream inside the cyclone unit is between 20 m/sec and 120 m/sec.Type: GrantFiled: September 4, 2007Date of Patent: August 24, 2010Assignees: Clue AS, Eyal Research Consultants Ltd.Inventors: Riki Canari, Aharon Eyal
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Patent number: 7771685Abstract: A flue gas desulfurization process and system that utilize ammonia as a reactant, and in which any hydrogen sulfide and/or mercaptans within the ammonia are separated during the desulfurization process so as to prevent their release into the atmosphere. The process and system entail absorbing acidic gases from a flue gas with a scrubbing media containing ammonium sulfate to produce a stream of scrubbed flue gas, collecting the scrubbing media containing the absorbed acidic gases, injecting into the collected scrubbing media a source of ammonia that is laden with hydrogen sulfide and/or mercaptans so that the injected ammonia is absorbed into and reacted with the collected scrubbing media, stripping the hydrogen sulfide and/or mercaptans from the collected scrubbing media by causing the hydrogen sulfide and/or mercaptans to exit the collected scrubbing media as stripped gases, and collecting the stripped gases without allowing the stripped gases to enter the stream of scrubbed flue gas.Type: GrantFiled: April 25, 2008Date of Patent: August 10, 2010Assignee: Marsulex Environmental Technologies, CorpInventor: Eli Gal
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Patent number: 7727311Abstract: Installation for gas treatment by a liquid phase comprising a) a column (C) that comprises means (1) for introducing gas at one end of said column, means (9) for drawing off gas from the other end of column (C) and, from upstream to downstream in the direction of circulation of the liquid phase: a first internal (2) that comprises means for distribution of a liquid phase, a first bed (6) that comprises a packing or catalytic particles, a second internal (3) that comprises means for separating liquid/gas mixture (19, 20) that is obtained from first bed (6), first means (32, 4) for collecting and evacuating the separated liquid phase, means (100) for passing through internal (3) of the treated gas, and distribution means (31, 101) of a liquid phase with said gas, a second bed (8), second means (10) for collecting and evacuating the liquid phase at the lower outlet of column (C), b) Means for recycling the collected liquid phase.Type: GrantFiled: September 12, 2005Date of Patent: June 1, 2010Assignee: Institut Francais du PetroleInventors: Ludovic Raynal, Eric Lemaire, Jean-Louis Ambrosino
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Patent number: 7718151Abstract: An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.Type: GrantFiled: October 13, 2008Date of Patent: May 18, 2010Inventor: Liang Hu
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Patent number: 7650746Abstract: One aspect of the invention relates an exhaust treatment system having an SCR reactor following a NOx adsorber. Syn gas is used to regenerate the NOx adsorber. Another aspect relates to an LNT/SCR provided with an ammonia source separate from the LNT. A further aspect relates to a system comprising first and second LNTs and one or more SCRs downstream of the LNTs. A still further aspect relates to a device comprising first and second NOx adsorbers contained in a single housing. Another aspect relates to coating a surface of a moving part in an exhaust system with an oxidation catalyst to mitigate fouling. Additional aspects of the invention relate to strategies for controlling one or more of the time to initiate a regeneration cycle, the time to terminate a regeneration cycle, and the reductant injection rate during regeneration of LNT/SCR exhaust treatment systems.Type: GrantFiled: September 20, 2006Date of Patent: January 26, 2010Assignee: Eaton CorporationInventors: Haoran Hu, Thomas R. Stover
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Patent number: 7641876Abstract: One aspect of the invention relates to a method for removing contaminants from a flue gas stream (22). The method includes: removing fly ash from a flue gas stream (22) utilizing a particle collector (24); contacting the flue gas stream with an alkaline reagent in a wet scrubber (26); discharging a purge liquid (30) from the wet scrubber (26); and, combining at least a portion of the purge liquid with at least a portion of fly ash circulating within a dry circulating fluid bed scrubber (48) to form moistened fly ash (60).Type: GrantFiled: March 5, 2009Date of Patent: January 5, 2010Assignee: ALSTOM Technology LtdInventors: Kelly L. Barger, Gregg R. Doule, Michael G. Varner
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Patent number: 7622093Abstract: Zonal injection of varying compositions of chemicals, particularly an ammonia-based reagent and hydrocarbon, through injection lances arranged in a grid formation to define planar zones in a furnace convective pass of a furnace. The supply of chemicals is controlled so as to be individually determined for each discrete zone of the grid depending on conditions in that zone.Type: GrantFiled: October 29, 2008Date of Patent: November 24, 2009Assignee: Doosan Babcock Energy America LLCInventors: Stuart Arrol, Peter Melling, George Anthony Yates, Michael J. Smith, Gerard J. W. C. Hesselmann, Barbara Lefebvre, John Macphail, Keith W. Morris
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Patent number: 7618602Abstract: A process of using solutions containing thiosulfate and/or chloride salt reagents to remove SO3 and H2SO4 acid gases from a flue gas. The solution is injected into a moving volume of flue gas to achieve a droplet size that enables the solution to dry on contact with the flue gas, generating dried particles of the reagent that react with the SO3 and H2SO4 acid gases yielding a salt precipitate. SO2 present in the flue gas may also be absorbed with the solution, with a subsequent reaction yielding bisulfite species that, upon drying of the droplet, react with the SO3 and H2SO4 acid gases to form salts that are removed from the gas. The removal of these acid gases from a flue gas reduce corrosion of equipment used in coal or oil fired power plants downstream of the injection cite.Type: GrantFiled: April 3, 2006Date of Patent: November 17, 2009Assignee: Codan Development LLCInventors: Frank B. Meserole, Robert E. Moser, James H. Wilhelm
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Patent number: 7604788Abstract: The invention provides a process for the removal of polysulfanes from gas streams formed during H2S synthesis.Type: GrantFiled: October 26, 2007Date of Patent: October 20, 2009Assignee: Evonik Degussa GmbHInventors: Alexander Möller, Wolfgang Böck, Wolfgang Taugner, Harald Heinzel, Stephan Rautenberg
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Publication number: 20090257932Abstract: A process for desulfurizing an SO2-comprising gaseous stream comprising the steps of: a. providing an aqueous feed comprising an anion selected from a group consisting of carbonate, bicarbonate, hydroxide, sulfite, and hydrogen sulfite; b. providing an SO2-comprising gaseous feed; and c. contacting the aqueous feed and the gaseous feed to generate a desulfurized gaseous product comprising less than 40% of the feed SO2 content, and an aqueous product; wherein the contacting is carried out in a cyclone unit comprising a housing defined by a cylindrical peripheral wall and provided with at least one inlet opening for receiving fluids thereinto and with at least one swirling means, and wherein the cyclone unit is characterized in that the velocity of the gaseous stream inside the cyclone unit is between 20 m/sec and 120 m/sec.Type: ApplicationFiled: September 4, 2007Publication date: October 15, 2009Applicants: CLUE AS, EYAL RESEARCH CONSULTANTS LTD.Inventors: Riki Canari, Aharon Eyal
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Patent number: 7575732Abstract: Processes for selectively removing sulfur-containing compounds from a gas are described herein. The processes generally include contacting a first gas including carbon dioxide and hydrogen sulfide with a scrub solution including ammonium bisulfite and ammonium sulfite in a first contact zone to produce a first contact zone effluent liquid including ammonium thiosulfate and a first contact zone overhead gas in which the concentration of hydrogen sulfide is substantially reduced.Type: GrantFiled: May 5, 2008Date of Patent: August 18, 2009Assignee: Thiosolv, LLC.Inventors: Mark C. Anderson, Michael F. Ray, Ronald Shafer
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Patent number: 7569198Abstract: The removal of particulates and acidic gases from the effluent from a fluid catalytic cracking process regenerator. The effluent is treated in two contacting stages with an effective amount of both a caustic solution as well as ammonia and the composition of the contacting solutions in the two stages is independently controlled.Type: GrantFiled: July 24, 2007Date of Patent: August 4, 2009Assignee: ExxonMobil Research & Engineering CompanyInventors: Michael W. Bedell, Patrick J. Maher
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Patent number: 7541011Abstract: The present invention is directed to an improved method and system for separating and purifying gas using gas-liquid absorption. According to this invention, the method is carried out in an absorber, where a liquid absorbent, a gas mixture containing a gas to be absorbed were introduced from an inlet. During absorption, the second liquid phase was separated out from the absorbent. The absorbed gas was accumulated in one of liquid phases. After absorption, two liquid phases were separated. One of the liquids with rich absorbed gas was forward to regenerator. After regeneration, the liquid was cycled back to absorber. The liquid phase with lean absorbed gas was back to absorber directly to complete the cycle.Type: GrantFiled: April 7, 2006Date of Patent: June 2, 2009Inventor: Liang Hu
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Publication number: 20080202397Abstract: The present invention is directed to processes and apparatuses for reducing the content of pollutants in a boiler system flue gas resulting from combustion of fuel. The present invention discloses improved slurry injection techniques, re-circulation of flue gas to provide momentum to the injected slurry, a measurement system for obtaining system profile information and a system to optimize the reduction of pollutants in a flue gas by adjusting the injection of slurry suspension based on system profile information.Type: ApplicationFiled: February 21, 2008Publication date: August 28, 2008Inventors: T. Steve Torbov, Terry W. Rettig, Stephen M. Kohan
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Publication number: 20080175778Abstract: The invention provides a process for the removal of polysulfanes from gas streams formed during H2S synthesis.Type: ApplicationFiled: October 26, 2007Publication date: July 24, 2008Applicant: Evonik Degussa GmbHInventors: Alexander Moller, Wolfgang Bock, Wolfgang Taugner, Harald Heinzel, Stephan Rautenberg
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Patent number: 7390470Abstract: Processes for selectively removing sulfur-containing compounds from a gas are described herein. The processes generally include contacting a first gas including carbon dioxide and hydrogen sulfide with a scrub solution including ammonium bisulfite and ammonium sulfite in a first contact zone to produce a first contact zone effluent liquid including ammonium thiosulfate and a first contact zone overhead gas including carbon dioxide.Type: GrantFiled: May 17, 2007Date of Patent: June 24, 2008Assignee: Thiosolv, L.L.C.Inventors: Mark C. Anderson, Michael F. Ray, Ronald Shafer