Alkali Or Alkaline Earth Or Compound Reactant Patents (Class 423/244.07)
  • Publication number: 20110123422
    Abstract: Herein is disclosed a flue gas scrubbing composition, a method of using the flue gas scrubbing composition, and a method of entombing mercury collected with the flue gas scrubbing composition. The flue gas scrubbing composition includes an admixture of a mercury sorbent material that comprises a clay, copper, and sulfur; and lime that comprises calcium oxide and/or calcium hydroxide. The method of collecting mercury from a flue gas includes injecting the flue gas scrubbing composition of any one of the preceding claims into a flue duct comprising the flue gas; reacting the mercury sorbent material with mercury in the flue gas to form a mercury-sorbed material and thereby reducing the concentration of mercury in the flue gas; reacting the lime with SO2, SO3, and/or HCl in the flue gas to form a calcium sulfate and/or a calcium chloride; and collecting a mixture that includes the mercury-sorbed material.
    Type: Application
    Filed: January 31, 2011
    Publication date: May 26, 2011
    Applicant: AMCOL INTERNATIONAL CORPORATION
    Inventor: Zhen Wang
  • Patent number: 7947242
    Abstract: A cement kiln chlorine/sulfur bypass system wherein the equipment cost is suppressed and the sulfur included in a combustion gas bled from a cement kiln is separated and effectively utilized. The cement kiln chlorine/sulfur bypass system comprises an air bleed means for bleeding a kiln exhaust gas passage, which runs from the end of the cement kiln to a bottom cyclone, of a part of the combustion gas, a separating means for separating dust in the gas bled by the air bleed means into coarse particles and fine particles, and a wet dust collector for collecting dust from the gas containing the fine particles separated by the separating means. The separating means is preferably a classifier in which the cut size is changeable. The wet dust collector is preferably a mixing scrubber.
    Type: Grant
    Filed: August 13, 2003
    Date of Patent: May 24, 2011
    Assignee: Taiheiyo Cement Corporation
    Inventors: Shinichiro Saito, Naoki Ueno, Hiroshi Harada, Soichiro Okamura, Takayuki Suzuki
  • Publication number: 20110079364
    Abstract: A method of offsetting losses of ammonia from a pulping mill comprising cooking a lignocellulosic material in a cooking liquor, wherein cooking in the cooking liquor separates the lignocellulosic material into a pulp, capturing a vapor of the cooking liquor, condensing the vapor of the cooking liquor to yield a spent cooking liquor condensate, washing the pulp in a wash liquid, wherein washing the pulp removes at least a portion of the spent cooking liquor from the pulp, capturing the wash liquid, removing ammonia from the wash liquid to yield a regenerated ammonia, regenerating the cooking liquor from the spent cooking liquor condensate and the regenerated ammonia, combusting a waste material and a concentrated spent cooking liquor, wherein combusting the waste material and the concentrated spent cooking liquor yields a flue gas and heat, transferring the heat from combusting the waste material and the concentrated spent cooking liquor to water to generate steam, removing a sulfur-containing compound from th
    Type: Application
    Filed: October 5, 2009
    Publication date: April 7, 2011
    Applicant: TIN INC., D/B/A TEMPLE-INLAND
    Inventors: Thomas Frank Stroup, David Michael Goodman, Robert Edward Stone
  • Patent number: 7910075
    Abstract: A method of protecting a NOx reducing catalyst 140 from fouling, where the NOx reducing catalyst 140 is downstream of a circulating fluidized bed (CFB) boiler 120 and upstream of a particulate removal device 150. The method includes introducing a SOx removing reagent 212 in a calcium to sulfur molar ratio greater than that required for SO2 removal from a flue gas 122 generated by a CFB 120, thereby preventing SO3 formation and fouling of the NOx reducing catalyst 140.
    Type: Grant
    Filed: July 22, 2009
    Date of Patent: March 22, 2011
    Assignee: ALSTOM Technologies Ltd.
    Inventors: Lawrence J. Czarnecki, Mikael Larsson
  • Patent number: 7906088
    Abstract: Mixing small amounts of an inorganic halide, such as NaCl, to basic copper carbonate followed by calcination at a temperature sufficient to decompose the carbonate results in a significant improvement in resistance to reduction of the resulting copper oxide. The introduction of the halide can be also achieved during the precipitation of the carbonate precursor. These reduction resistant copper oxides can be in the form of composites with alumina and are especially useful for purification of gas or liquid streams containing hydrogen or other reducing agents. These reduction resistant copper oxides can function at near ambient temperatures.
    Type: Grant
    Filed: August 26, 2009
    Date of Patent: March 15, 2011
    Assignee: UOP LLC
    Inventors: Vladislav I. Kanazirev, Peter Rumfola, III
  • Patent number: 7887769
    Abstract: A method of removing sulfur dioxide from flue gases using calcium and magnesium scrubbing components and treatment of oxidized effluent from such a system includes passing classified oxidized effluent to a regeneration tank and adding lime to produce a regenerator discharge containing magnesium hydroxide, gypsum and crystalline inert material. Gypsum is separated from the discharge and a magnesium hydroxide stream passed to a concentration system to produce a concentrated solids stream of magnesium hydroxide, residual minor amount of gypsum and crystalline inert material. A portion of the resultant stream is returned to the sulfur dioxide removal system while a portion is passed to the oxidizer. Further portions may be fed to a power plant boiler or to the flue gas stream between a solids collection device and the wet scrubber.
    Type: Grant
    Filed: December 1, 2009
    Date of Patent: February 15, 2011
    Assignee: Carmeuse Lime, Inc.
    Inventor: Kevin J. Smith
  • Publication number: 20110014106
    Abstract: Combustion flue gas containing SOX is treated to remove SOX using a dry particulate sorbent injection procedure in which a sodium-based sorbent precursor is calcined immediately prior to its introduction into the flue gas stream, to activate the sorbent for reaction with SOX. The sorbent precursor is a NaHCO3-containing compound, and trona is preferred as the sorbent precursor.
    Type: Application
    Filed: July 13, 2010
    Publication date: January 20, 2011
    Applicant: FMC CORPORATION
    Inventors: Henry A. Pfeffer, David E. Smith, William C. Copenhafer, Ann Copenhafer
  • Patent number: 7854911
    Abstract: A method of removing SOx from a flue gas stream including SOx includes providing a source of trona and injecting the trona as a dry sorbent into the flue gas stream. The temperature of the flue gas is at an elevated temperature greater than 400° F., preferably between about 600° F. and about 900° F. The trona is maintained in contact with the flue gas for a time sufficient to react a portion of the trona with a portion of the SOx to reduce the concentration of the SO2 and/or SO3 in the flue gas stream.
    Type: Grant
    Filed: March 27, 2009
    Date of Patent: December 21, 2010
    Assignee: Solvay Chemicals, Inc.
    Inventor: John Maziuk, Jr.
  • Patent number: 7850936
    Abstract: A system for removing sulfur dioxide (SO2) from SO2 laden flue gas resulting from the burning of fossil fuel, includes an absorber and first and second separators. The absorber captures SO2 from a flow of the SO2 laden flue gas with a sorbent. The first separator separates a first portion of the sorbent with captured SO2 both from a second portion of the sorbent with captured SO2 and from the flue gas. The second separator separates the second portion of sorbent from the flue gas.
    Type: Grant
    Filed: February 16, 2009
    Date of Patent: December 14, 2010
    Assignee: ALSTOM Technology Ltd
    Inventors: Armand A. Levasseur, George D. Mylchreest
  • Publication number: 20100285222
    Abstract: In a method for reducing the pollution of buildings with gaseous acidic sulfur compounds, interior building walls, floors, or ceilings are provided with a coating composition containing an alkaline-earth hydroxide in an amount from 5 to 90 wt % with respect to the weight of the coating composition in a binder matrix, and the coating containing calcium hydroxide is allowed to react with the gaseous acidic sulfur compounds to form solid crystalline reaction products. In one embodiment, the coating composition may also contain 1 to 30 wt. % of at least one alkali-metal hydroxide. In another embodiment, the coating composition may also contain 1 to 5 wt. % zinc oxide. One or more diffusion-tight layers may be employed.
    Type: Application
    Filed: July 1, 2009
    Publication date: November 11, 2010
    Inventors: Jochen Billecke, Rüdiger Oberste-Padtberg, Jõrg Sieksmeier
  • Publication number: 20100254873
    Abstract: Disclosed is a method of using lime residuals from a water treatment plant that includes collecting lime residuals from a water treatment plant, transporting the lime residuals to a power plant, pumping the lime residuals into a limestone slurry storage tank and utilizing the lime residuals in a flue gas desulphurization process.
    Type: Application
    Filed: April 1, 2009
    Publication date: October 7, 2010
    Inventors: James H. Irvine, John N. Seibel, Linda B. Seibel
  • Publication number: 20100233055
    Abstract: An air quality control system (AQCS) (4) useful for processing a gas stream (DG), such as a flue gas stream emitted from a fossil fuel fired boiler (2), combustion process or the like, for at least partial removal of acidic and like contaminants. The air quality control system (4) includes a plurality of integrated components (12) equipped with both a dry scrubber system (8) and a fabric filter (10). The air quality control system (4) such as described possesses increased “turn down” capabilities thus increasing the efficiency thereof.
    Type: Application
    Filed: February 10, 2010
    Publication date: September 16, 2010
    Applicant: ALSTOM TECHNOLOGY LTD
    Inventors: Lawrence H. Gatton, JR., Alan W. Ferguson, Per H. F. Landmer
  • Patent number: 7785552
    Abstract: A method of removing SO3 from a flue gas of a boiler. The method includes the following steps: injecting chloride salts into a stream of the flue gas at a position located downstream of an air pre-heater—the position is selected so that the flue gas has a temperature at the position of substantially between 100° C. and 400° C.; reacting chloride salts with the SO3 to form a sulfate-containing reaction product; and collecting the sulfate-containing reaction product in a particulate collector downstream of the boiler. A purge stream from a wet flue gas desulfurization system may be used as a source of the chloride salts. Additional chlorides may be added to the purge stream as necessary.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: August 31, 2010
    Assignee: ALSTOM Technology Ltd
    Inventor: Leif A. V. Lindau
  • Patent number: 7776298
    Abstract: The invention relates to a process and a device for the removal of dust, HF, HCl, SO2, SO3, heavy metals, heavy-metal compounds, polyhalogenated hydrocarbons and polycyclic hydrocarbons from combustion flue gases by treating the pollutant-containing combustion flue gases with a sorbent in a circulating fluidized bed. The process is characterized in that the sorbent used is a mixture of Ca(OH)2, at least one naturally occurring zeolite and a carbon-containing substance, in that the treatment of the pollutant-containing combustion flue gases with the sorbent is carried out at from 120 to 180° C.
    Type: Grant
    Filed: July 8, 2002
    Date of Patent: August 17, 2010
    Assignee: Lentjes GmbH
    Inventors: Hansjörg Herden, Barbara Roth, Robert Mergler, Berthold Stegemann, Harald Sauer
  • Patent number: 7776301
    Abstract: Calcium bromide is a component of sorbent compositions that can be added on to coal to reduce the amount of sulfur gases released into the atmosphere from a coal burning facility. The sorbent components are added onto coal before the coal is added into the furnace and combusted. The fuel being burned is any fuel that contains sulfur, such as lignite, bituminous, and anthracite coal. The sorbent can contain other components such as silica, alumina, cement kiln dust, lime kiln dust, Portland cement, and aluminosilicate clay. Sulfur emissions are monitored during combustion of the fuel, and the rate of sorbent addition can be changed or a adjusted based on the monitored sulfur levels.
    Type: Grant
    Filed: February 12, 2010
    Date of Patent: August 17, 2010
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Patent number: 7758827
    Abstract: Sorbent components containing calcium, alumina, silica, and halogen are used in combination during coal combustion to produce environmental benefits. Sorbents are added to the coal ahead of combustion and/or are added into the flame or downstream of the flame, preferably at minimum temperatures to assure complete formation of the refractory structures that result in various advantages of the methods. When used together, the components ? reduce emissions of mercury and sulfur; ? reduce emissions of elemental and oxidized mercury; ? increase the efficiency of the coal burning process through de-slagging of boiler tubes; ? increase the level of Hg, As, Pb, and/or Cl in the coal ash; ? decrease the levels of leachable heavy metals (such as Hg) in the ash, preferably to levels below the detectable limits; and ? make a highly cementitious ash product.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: July 20, 2010
    Assignee: NOx II, Ltd.
    Inventor: Douglas C. Comrie
  • Patent number: 7758836
    Abstract: A system and method for removing sulfur-containing contaminants from indoor air includes a panel system having a first layer and a second layer. The first layer can include a base media onto which sodium bicarbonate is attached. The second layer can include a base media onto which activated carbon is attached. Indoor air including sulfur-containing contaminants can contact and pass through the first layer. Sulfuric acid can react with the sodium bicarbonate to produce sodium sulfate, which can, in turn, act as a drying agent for organic sulfur-containing contaminants in the indoor air, such as carbon disulfide and carbonyl sulfide. As a result of such drying, the second layer can more effectively trap and/or bind (adsorb) the organic sulfur-containing contaminants so that these contaminants are removed from the contaminated air. The treated air can be returned to an indoor space of the structure.
    Type: Grant
    Filed: May 27, 2009
    Date of Patent: July 20, 2010
    Inventors: Ronald G. Huggins, Carl M. Sabatello, Paul T. Sabatello
  • Patent number: 7708964
    Abstract: Pollution control substances may be formed from the combustion of oil shale, which may produce a kerogen-based pyrolysis gas and shale sorbent, each of which may be used to reduce, absorb, or adsorb pollutants in pollution producing combustion processes, pyrolysis processes, or other reaction processes. Pyrolysis gases produced during the combustion or gasification of oil shale may also be used as a combustion gas or may be processed or otherwise refined to produce synthetic gases and fuels.
    Type: Grant
    Filed: July 27, 2006
    Date of Patent: May 4, 2010
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Richard D. Boardman, Robert A. Carrington
  • Patent number: 7678354
    Abstract: A process and system for recovering waste heat from a kiln used for lime or cement production. The system unifies the kiln, a waste heat recovery and power generation circuit and a dry scrubber for scrubbing the pollutants from the kiln offgas. Essentially, the system employs the boiler component of the waste heat recovery and power generation circuit as a heat exchanger to recover the waste heat from the kiln, which is used to drive the steam turbines. The heat absorption from the latter stage lowers the temperature of the kiln offgas sufficiently for optimum performance from the scrubber. The presence of lime particles in the offgas effectively protects the boiler tube surfaces from corrosion which would occur at optimum scrubber temperatures, and subsequently provides the lime required as a scrubbing medium for the dry scrubber. Further, the efficient scrubbing allows for the use of any fuel for firing the kiln inclusive of high sulphur content compounds.
    Type: Grant
    Filed: August 4, 2006
    Date of Patent: March 16, 2010
    Assignee: Graymont (QC) Inc.
    Inventors: Merrill Squire, Alain Charette
  • Patent number: 7674442
    Abstract: Processes and compositions are provided for decreasing emissions of mercury upon combustion of fuels such as coal. Various sorbent compositions are provided that contain components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon burning of coal. In various embodiments, the sorbent compositions are added directly to the fuel before combustion; are added partially to the fuel before combustion and partially into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone. In preferred embodiments, the sorbent compositions comprise a source of halogen and preferably a source of calcium. Among the halogens, iodine and bromine are preferred. In various embodiments, inorganic bromides make up a part of the sorbent compositions.
    Type: Grant
    Filed: January 9, 2009
    Date of Patent: March 9, 2010
    Inventor: Douglas C. Comrie
  • Patent number: 7666374
    Abstract: The invention relates to a process for cleaning exhaust gases produced by a sintering process of metal-containing waste. The sintering exhaust gas includes one or more harmful substances which are eliminated in at least two steps by at least one adsorption and/or absorption agent in a single moving bed in a moving bed reactor system. The moving bed includes a particle layer (stage I) disposed above a flow input area and below an adsorption layer (stage II) of the moving bed. One or more harmful substances in the sintering exhaust gas are absorptively or adsorptively bound to potassium and/or sodium compounds and the harmful substances are trapped by adhesion in the flow input area or the Particle layer (stage I) of the moving bed. The substantial removal of NOx and the adsorptive or absorptive removal of dioxins and furans takes place in the adsorption layer (stage II) in the moving bed.
    Type: Grant
    Filed: February 8, 2006
    Date of Patent: February 23, 2010
    Inventor: Horst Grochowski
  • Patent number: 7641878
    Abstract: A system and method for beneficiation of fly ash particles which at least partially reduces sulfur emissions includes at least one mixing reactor with a chamber and at least one exhaust, at least one fly ash source connected to provide fly ash particles to the chamber, at least one sorbent source, and at least one fluid supply system. The sorbent source provides at least one type of sorbent particles to be mixed with the fly ash particles to reduce sulfur emissions. A mass of the fly ash particles in the chamber is greater than a mass of the sorbent particles in the chamber. The fluid supply system provides at least one fluid to the chamber during a beneficiation of at least a portion of the fly ash particles in the chamber.
    Type: Grant
    Filed: February 21, 2006
    Date of Patent: January 5, 2010
    Assignee: PMI Ash Technologies, LLC
    Inventors: Joseph W. Cochran, S. Frank Kirkconnell
  • Patent number: 7618602
    Abstract: A process of using solutions containing thiosulfate and/or chloride salt reagents to remove SO3 and H2SO4 acid gases from a flue gas. The solution is injected into a moving volume of flue gas to achieve a droplet size that enables the solution to dry on contact with the flue gas, generating dried particles of the reagent that react with the SO3 and H2SO4 acid gases yielding a salt precipitate. SO2 present in the flue gas may also be absorbed with the solution, with a subsequent reaction yielding bisulfite species that, upon drying of the droplet, react with the SO3 and H2SO4 acid gases to form salts that are removed from the gas. The removal of these acid gases from a flue gas reduce corrosion of equipment used in coal or oil fired power plants downstream of the injection cite.
    Type: Grant
    Filed: April 3, 2006
    Date of Patent: November 17, 2009
    Assignee: Codan Development LLC
    Inventors: Frank B. Meserole, Robert E. Moser, James H. Wilhelm
  • Patent number: 7595037
    Abstract: Described is a method as well as an apparatus for hydration of a particulate or pulverulent material containing CaO. The method is peculiar in that water is added in a quantity which will ensure that the partial pressure PH2O of the added water as a function of the temperature (° C.) is maintained within the interval defined by the formula (I), where PH2O is the partial pressure of water vapour in atm. and T is the temperature in ° C. Hereby is obtained that the material particles do not lump into agglomerates, and that the particles are hydrated evenly from the outside and inwards so that it is the active surface of the material particles which undergoes hydration in connection with partial hydration. This is due to the fact that the liquid water will not get into contact with the material particles since the water will appear in vapour form within the specified interval.
    Type: Grant
    Filed: February 16, 2005
    Date of Patent: September 29, 2009
    Assignee: FLSMIDTH A/S
    Inventors: Jens Peter Hansen, Lars Skaarup Jensen
  • Patent number: 7591988
    Abstract: In a method for processing flue gases, flue gases from an incineration plant for non-condensable gases of a kraft pulp mill are scrubbed by means of a calcium compound. The calcium compound is lime mud taken from the chemical recirculation of the kraft pulp mill after causticization and before a lime reburning kiln, and it is used in the scrubbing of gas as a substance reacting with sulphur dioxide.
    Type: Grant
    Filed: October 18, 2006
    Date of Patent: September 22, 2009
    Assignee: Metso Power Oy
    Inventors: Risto Hämäläinen, Keijo Salmenoja, Ismo Reilama
  • Publication number: 20090208397
    Abstract: A system for removing sulfur dioxide (SO2) from SO2 laden flue gas resulting from the burning of fossil fuel, includes an absorber and first and second separators. The absorber captures SO2 from a flow of the SO2 laden flue gas with a sorbent. The first separator separates a first portion of the sorbent with captured SO2 both from a second portion of the sorbent with captured SO2 and from the flue gas. The second separator separates the second portion of sorbent from the flue gas.
    Type: Application
    Filed: February 16, 2009
    Publication date: August 20, 2009
    Applicant: ALSTOM Technology Ltd
    Inventors: Armand A. Levasseur, George D. Mylchreest
  • Patent number: 7531154
    Abstract: A method of removing SO2 from a flue gas stream including SO2 includes providing a source of trona and injecting the trona into the flue gas stream. The temperature of the flue gas is between about 600° F. and about 900° F. The trona is maintained in contact with the flue gas for a time sufficient to react a portion of the trona with a portion of the SO2 to reduce the concentration of the SO2 in the flue gas stream.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: May 12, 2009
    Assignee: Solvay Chemicals
    Inventor: John Maziuk, Jr.
  • Patent number: 7524473
    Abstract: Controlling the reductive capacity of an aqueous alkaline slurry (23) in a wet scrubber makes it possible to accurately control the mercury emission from the scrubber to a desired value. One method of controlling the reductive capacity of the slurry is to measure the reduction-oxidation potential (“redox potential”) of the aqueous alkaline slurry (23) and to add or remove substances that affect the redox potential and thus the reductive capacity of the slurry. In wet scrubbers in which limestone is used for absorption of acid gases and where a gypsum slurry is circulated, it has been found to be an attractive solution to control the amount of oxidation air blown into the scrubber in order to control the redox potential and thereby the mercury emissions.
    Type: Grant
    Filed: March 23, 2007
    Date of Patent: April 28, 2009
    Assignee: Alstom Technology Ltd
    Inventors: Leif A. V. Lindau, Fredrik J. Brogaard
  • Patent number: 7514053
    Abstract: Methods for scrubbing gas streams to remove acid gases including sulfur dioxide, mercury-containing substances, and/or nitrogen oxides from the gas stream. The gas stream is contacted with a potassium-based sorbent effective for removing at least a portion of the acid gases. The partially cleaned gas stream is then contacted with an oxidant effective to remove at least a portion of the nitrogen oxides and/or mercury-containing substances after partially removing the acid gas substance.
    Type: Grant
    Filed: April 21, 2005
    Date of Patent: April 7, 2009
    Assignee: EnviroSolv Energy LLC
    Inventors: Dennis W. Johnson, Mark S. Ehrnschwender
  • Publication number: 20090081093
    Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.
    Type: Application
    Filed: September 18, 2008
    Publication date: March 26, 2009
    Inventor: Douglas C. Comrie
  • Patent number: 7507083
    Abstract: Processes and compositions are provided for decreasing emissions of mercury upon combustion of fuels such as coal. Various sorbent compositions are provided that contain components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon burning of coal. In various embodiments, the sorbent compositions are added directly to the fuel before combustion; are added partially to the fuel before combustion and partially into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone. In preferred embodiments, the sorbent compositions comprise a source of halogen and preferably a source of calcium. Among the halogens, iodine and bromine are preferred. In various embodiments, inorganic bromides make up a part of the sorbent compositions.
    Type: Grant
    Filed: March 16, 2006
    Date of Patent: March 24, 2009
    Inventor: Douglas C Comrie
  • Patent number: 7481987
    Abstract: A method is provided for reducing the fouling during the removal of sulfur trioxide from a flue gas stream by maintaining the reagent (i. e. sodium sesquicarbonate) in contact with the flue gas for a sufficient time and temperature to react a portion of the reagent with a portion of the sulfur trioxide to substantially avoid formation of liquid phase NaHSO4 reaction product that combines with the fly ash so as to not form a sticky ash residue that adheres to the flue gas duct, wherein the reaction product of the reagent and the sulfur trioxide is selected from the group consisting of Na2SO4, Na2S2O7 and mixtures thereof.
    Type: Grant
    Filed: September 15, 2005
    Date of Patent: January 27, 2009
    Assignee: Solvay Chemicals
    Inventor: John Maziuk, Jr.
  • Patent number: 7481985
    Abstract: The present invention provides for a method and apparatus for purifying carbon dioxide. Sulfur species are efficiently and effectively removed from the carbon dioxide by a series of steps which include heater/heat exchange means, impurity adsorption means and cooling means.
    Type: Grant
    Filed: August 7, 2006
    Date of Patent: January 27, 2009
    Assignee: The BOC Group, Inc.
    Inventors: Ravi Jain, YuDong Chen
  • Patent number: 7476372
    Abstract: A method for reducing acid gases in a flue gas, the method comprising reacting biosolids comprising a scrubbing agent with a flue gas comprising an acid gas, thereby reducing the amount of acid gas in the flue gas is disclosed. Also disclosed is a flue gas scrubbing process comprising: combusting a fossil fuel and biosolids comprising a scrubbing agent, thereby producing a flue gas comprising an acid gas, wherein the flue gas has a reduced amount of acid gas compared with flue gas produced from the combustion of the fossil filet alone. A flue gas scrubbing process comprising providing a stream of biosolids that includes a hydroxide or an oxide of a Group IA or IIA element, providing a flue gas comprising an acid gas, and reacting the biosolids stream with the flue gas so as to reduce the amount of acid gas in the flue gas is also disclosed.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: January 13, 2009
    Assignee: Holloman Corporation
    Inventor: Eric Prim
  • Patent number: 7468170
    Abstract: Sorbent compositions for coal contain nitrogenous components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon combustion. The sorbent compositions are added directly to the fuel before combustion; directly into the fireball during combustion; are added to the fuel before combustion and into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone, preferably where the flue gas temperature is at least 500° C. The sorbent compositions comprise a source of nitrate ions, a source of nitrite ions, or a combination of nitrate and nitrite sources. The sorbents are added as solids or as solutions in water. In various embodiments, the sorbent compositions further comprise a source of halogen such as bromide.
    Type: Grant
    Filed: December 20, 2006
    Date of Patent: December 23, 2008
    Inventor: Douglas C Comrie
  • Patent number: 7435400
    Abstract: A method for increasing the nitrogen oxide emissions by either removing or modifying fuel rich nitrogen oxide (NOx) reduction processes thereby improving combustion efficiencies especially with low volatile low sulfur coals, and remove unburned carbon, reduce sulfur dioxide and reducing carbon dioxide emissions, while using post-primary combustion urea or ammonia injection with or without a reburn fuel NOx reducing process to restore NOx to regulated emission levels. Furthermore, adding lime or limestone to the urea or ammonia solution to further reduce SO2 and to increase the concentration of the carbon free fly ash to cementitious concentrations. Furthermore, by proper number and disposition of the injectors in the post combustion zone and by further water diluting the mixture, this NOx reduction process is effective at substantially higher gas temperatures than conventional Selective Non-Catalytic NOx Reduction and with no ammonia slip. This method significantly increases the profitability of power plants.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: October 14, 2008
    Inventor: Bert Zauderer
  • Publication number: 20080241037
    Abstract: A method of removing SO3 from a flue gas of a boiler. The method includes the following steps: injecting chloride salts into a stream of the flue gas at a position located downstream of an air pre-heater—the position is selected so that the flue gas has a temperature at the position of substantially between 100° C. and 400° C.; reacting chloride salts with the SO3 to form a sulfate-containing reaction product; and collecting the sulfate-containing reaction product in a particulate collector downstream of the boiler. A purge stream from a wet flue gas desulfurization system may be used as a source of the chloride salts. Additional chlorides may be added to the purge stream as necessary.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 2, 2008
    Inventor: Leif A.V. Lindau
  • Publication number: 20080233028
    Abstract: A process for reducing an amount of sulfur trioxide present in a flue gas stream (20), including the steps of processing an alkaline material (24) to comprise a predetermined percentage of particles, based on the mass of alkaline material introduced into a flue gas stream (20), having a size less than a predetermined dimension and introducing the processed alkaline material (24) to the flue gas stream (20), wherein the processed alkaline material (24) reduces the amount of sulfur trioxide present in the flue gas stream (20).
    Type: Application
    Filed: March 23, 2007
    Publication date: September 25, 2008
    Inventor: Leif A. V. Lindau
  • Patent number: 7427385
    Abstract: Systems and processes for removing a first sulfur compound from a hydrocarbon stream. The systems and process utilize at least one reaction vessel incorporating a hydrolysis catalyst suitable for hydrolyzing the first sulfur compound to a second sulfur compound. The reaction vessel also incorporates a sorbent material suitable for absorbing the second sulfur compound. Following hydrolysis of the first sulfur compound to the second sulfur compound and absorption of the second sulfur compound, a hydrocarbon-containing stream having a reduced sulfur content is produced. The hydrolysis catalyst and sorbent material may be provided in separate zones within the reaction vessel or provided as a mixture in a single zone. The hydrocarbon-containing stream having a reduced sulfur content is suitable for a variety of uses, including as a feedstreams for hydrogen plants, process gas streams for power generation plants, or for other uses for hydrocarbon-containing stream having reduced sulfur content.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: September 23, 2008
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Glen E. Scheirer, Francis S. Wu, Thomas R. Kiliany
  • Patent number: 7404940
    Abstract: Systems and methods for reduction of pollutants in combustion processes using combined rotating opposed fired air (ROFA) and fuel injection sorbents (FSI) for increased chemical reactivity.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: July 29, 2008
    Assignee: Mobotec USA, Inc.
    Inventors: Brian S. Higgins, Mark Shilling, Edwin Haddad
  • Patent number: 7384615
    Abstract: A method of decreasing pollutants produced in a combustion process. The method comprises combusting coal in a combustion chamber to produce at least one pollutant selected from the group consisting of a nitrogen-containing pollutant, sulfuric acid, sulfur trioxide, carbonyl sulfide, carbon disulfide, chlorine, hydroiodic acid, iodine, hydrofluoric acid, fluorine, hydrobromic acid, bromine, phosphoric acid, phosphorous pentaoxide, elemental mercury, and mercuric chloride. Oil shale particles are introduced into the combustion chamber and are combusted to produce sorbent particulates and a reductant. The at least one pollutant is contacted with at least one of the sorbent particulates and the reductant to decrease an amount of the at least one pollutant in the combustion chamber. The reductant may chemically reduce the at least one pollutant to a benign species. The sorbent particulates may adsorb or absorb the at least one pollutant.
    Type: Grant
    Filed: December 2, 2004
    Date of Patent: June 10, 2008
    Assignee: Battelle Energy Alliance, LLC
    Inventors: Richard D. Boardman, Robert A. Carrington
  • Patent number: 7374737
    Abstract: The invention concerns the use of a composition based on TiO2 as a catalyst for hydrolyzing COS and/or HCN in a gas mixture, said composition comprising at least 1% by weight of at least one sulphate of an alkaline-earth metal selected from calcium, barium, strontium and magnesium.
    Type: Grant
    Filed: October 8, 2002
    Date of Patent: May 20, 2008
    Assignee: Axens
    Inventors: Christophe Nedez, Jean-Louis Ray
  • Patent number: 7361319
    Abstract: The present invention is directed to methods for reducing SOx, NOx, and CO emissions from a fluid stream comprising contacting said fluid stream with a compound comprising magnesium and aluminum and having an X-ray diffraction pattern displaying at least a reflection at a two theta peak position at about 43 degrees and about 62 degrees, wherein the ratio of magnesium to aluminum in the compound is from about 1:1 to about 10:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1:1 to about 6:1. In one embodiment, the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 10:1. In another embodiment, the invention is directed to methods wherein the ratio of magnesium to aluminum in the compound is from about 1.5:1 to about 6:1.
    Type: Grant
    Filed: November 23, 2004
    Date of Patent: April 22, 2008
    Assignee: Intercat, Inc.
    Inventor: Albert Vierheilig
  • Patent number: 7357905
    Abstract: The invention relates to a process for direct oxidation into sulfur and/or into sulfate of sulfur-containing compounds that are contained in an amount that is less than 10% by volume in a gas, in which said gas is brought into contact with an oxidation catalyst that comprises a substrate and an active phase that comprises iron in a proportion of between 2 and 5% by weight of the oxidation catalyst at a temperature of less than 200° C. and in the presence of oxygen.
    Type: Grant
    Filed: July 9, 2004
    Date of Patent: April 15, 2008
    Assignee: Institut Francais du Petrole
    Inventors: Jean-François Chapat, Christophe Nedez, Jean-Louis Ray
  • Patent number: 7332143
    Abstract: NOx and SO3 emissions from combustion of a sulfur containing carbonaceous fuel are reduced simultaneously. The combustion gases comprising NOx and SO2 are mixed with a NOx control agent into the combustion gases at a point upstream of a selective catalytic reduction catalyst for reduction of NOx. Following an SCR catalyst or other equipment that can oxidize SO2 to SO3 and prior to contact with an air heater for heating incoming combustion air, magnesium hydroxide is introduced in amounts and with droplet sizes and concentrations effective to form nano-sized particles in the effluent and reduce SO3 caused by the oxidation of SO2 in the catalyst. Computational fluid dynamics is employed to determine flow rates and select reagent introduction rates, reagent introduction location(s), reagent concentration, reagent droplet size and/or reagent momentum.
    Type: Grant
    Filed: February 6, 2006
    Date of Patent: February 19, 2008
    Assignee: Fuel Tech, Inc.
    Inventors: Christopher R. Symrniotis, William H. Sun
  • Publication number: 20080031794
    Abstract: A process and system for recovering waste heat from a kiln used for lime or cement production. The system unifies the kiln, a waste heat recovery and power generation circuit and a dry scrubber for scrubbing the pollutants from the kiln offgas. Essentially, the system employs the boiler component of the waste heat recovery and power generation circuit as a heat exchanger to recover the waste heat from the kiln, which is used to drive the steam turbines. The heat absorption from the latter stage lowers the temperature of the kiln offgas sufficiently for optimum performance from the scrubber. The presence of lime particles in the offgas effectively protects the boiler tube surfaces from corrosion which would occur at optimum scrubber temperatures, and subsequently provides the lime required as a scrubbing medium for the dry scrubber. Further, the efficient scrubbing allows for the use of any fuel for firing the kiln inclusive of high sulphur content compounds.
    Type: Application
    Filed: August 4, 2006
    Publication date: February 7, 2008
    Applicant: Graymont (QC) Inc.
    Inventors: Merrill Squire, Alain Charette
  • Patent number: 7247285
    Abstract: A method for reducing the cost of emission control by utilizing a combination of low cost, combustion and post-combustion processes to eliminate emissions of sulfur and nitrogen oxides, and trace metals, including mercury, and trace dioxins and furans. These processes are applied sequentially to the combustion flow train of an air-cooled, slagging combustor-boiler, and include two groups of process steps. One group is implemented in the combustor and the other in post combustion zones.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: July 24, 2007
    Inventor: Bert Zauderer
  • Patent number: 7199078
    Abstract: An automobile exhaust system includes a catalytic converter and a modified NOx trap wit improved sulfur tolerance. Sulfur oxide has a deleterious effect on the performance of nitrogen oxide traps. In the modified NOx trap, a sulfur oxide trap is integrated with a nitrogen oxide trap by coating the catalyst contained within a nitrogen oxide trap with a mixed oxide layer of calcium oxide and magnesium oxide. The NOx trap is regenerated by heating at elevated temperature for a short time period.
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: April 3, 2007
    Assignee: Ford Global Technologies, LLC
    Inventors: Amy Berris, Jun Li, Mohinder Singh Chattha, William Lewis Henderson Watkins
  • Patent number: 7179438
    Abstract: The present invention provides methods and apparatus for treating flue gas containing sulfur dioxide using a scrubber, and more particularly relates to recovering gypsum and magnesium hydroxide products from the scrubber blowdown. The gypsum and magnesium hydroxide products are created using two separate precipitation reactions. Gypsum is crystallized when magnesium sulfate reacts with calcium chloride. Magnesium hydroxide is precipitated when magnesium chloride from the gypsum crystallization process reacts with calcium hydroxide. The process produces a high quality gypsum with a controllable pH and particle size distribution, as well as high quality magnesium hydroxide.
    Type: Grant
    Filed: January 3, 2006
    Date of Patent: February 20, 2007
    Assignee: Allegheny Energy, Inc.
    Inventor: Dennis K. Jones
  • Patent number: 7141093
    Abstract: A method of scrubbing a gas stream with re-circulated kiln dust when the kiln dust is hydrated to form a sorbent. The sorbent is re-circulated with un-reacted flue gas stream for scrubbing.
    Type: Grant
    Filed: July 21, 2004
    Date of Patent: November 28, 2006
    Assignee: Graymont QC Inc.
    Inventor: Alain Charette