Abstract: A method of manufacturing a catalytic sieve includes providing starting materials of an aggregate, a cementing agent, a sublimation agent and water. The sublimation agent (between 25% and 50% by weight of the cementing agent) is selected from molybdenum disulfide, tungsten disulfide, vanadium disulfide, copper sulfate, and combinations thereof. The aggregate contains at least 2% by weight of at least one transition metal. The method includes mixing the starting materials to achieve a mixture, placing the mixture into a form, and curing the mixture in the form to allow the mixture to become a solidified unit defined by a minimum dimension of thickness, length, width or diameter. The method further includes placing the solidified unit into a kiln, heating the kiln to 1115°-1350° C., maintaining the kiln at the temperature for between 10-60 minutes per centimeter of the minimum dimension, and removing the solidified unit from the kiln.

Abstract: A catalytic oxidation system for efficient conversion and removal of volatile organic compounds (VOCs) in a coal chemical industry is provided. The catalytic oxidation system includes a reactor and a first temperature control system, where the reactor is provided with a waste gas inlet and a waste gas outlet and is provided with a preheating zone, a reaction zone, and a heat recovery zone sequentially in a flow direction of a waste gas, and a catalyst is filled in the reaction zone; and the first temperature control system includes a first serpentine pipe buried in the catalyst and a first steam drum arranged outside the reactor, the first steam drum and the first serpentine pipe are connected through a pipeline to form a circulation line, and a temperature in the reaction zone is adjusted to 150° C. to 350° C. by controlling a pressure of the first steam drum.

Abstract: A process for recovering at least one fluid (e.g. xenon gas and/or krypton gas, etc.) from a feed gas can include utilization of a compression system, primary heat exchanger unit, a pre-purification unit (PPU), and other units to separate and recover at least one desired fluid. In some embodiments, fluid flows output from a first heat exchanger or separation system of the plant can be split so that a portion of a stream is output for downstream processing to purify xenon (Xe) and/or krypton (Kr) product flow(s) while another portion of the stream is recycled to a compression system or the PPU to undergo further purification and heat exchange so that the product output for downstream processing has a higher concentration of Xe or Kr. Some embodiments can be configured to provide an improved recovery of Xe and/or Kr as well as an improvement in operational efficiency.

Abstract: The present disclosure relates to systems and methods useful for providing one or more chemical compounds in a substantially pure form. In particular, the systems and methods can be configured for separation of carbon dioxide from a process stream, such as a process stream in a hydrogen production system. As such, the present disclosure can provide systems and method for production of hydrogen and/or carbon dioxide.

Abstract: Apparatus and methods for a gas furnace are disclosed. The gas furnace includes a variable combustion control which monitors the temperature of the burner and modifies one of the amount of combustion air supplied and the amount of gas fuel supplied to the mixing chamber. The described systems can dynamically accommodate differences in air quality and gas fuel supply to provide an optimum BTU output irrespective of differences in geographic location of usage. The gas furnace can include a dynamic response unit which predicts an optimum rate of heating to maintain a target room temperature, thereby preventing unnecessary shut down and costly re-ignition sequences, and maintaining the gas furnace at an optimum BTU output level.

Abstract: A method for enhancing degradation of ester volatile organic compounds with a cerium oxide supported palladium single atom catalyst under low-temperature microwave comprises the steps of firstly preparing a single atom catalyst Pd/CeO2, adding the catalyst Pd/CeO2 into a reaction cavity, initiating microwave radiation to enhance the catalysis reaction, and quickly introducing an ester compound with a concentration of 50˜5000 mg/m3 and a space velocity of 2000˜100000 h?1 into the reaction cavity from a vapor phase sampling port to react when the reaction temperature is 10˜80° C. A catalyst packed column is provided in the reaction cavity, the vapor phase sampling port is defined at the bottom of the reaction cavity, and an exhaust port is defined at the top of the cavity. The microwave method can enhance and activate active sites, prevent the aging of active sites, and enable the chemical reaction rate to be increased by more than 17.9%.

Abstract: This invention relates to a novel palladium catalyst for the substantially complete oxidative removal of methane from exhaust streams at low operating temperatures compared to other current palladium catalysts and to methods of preparing the catalyst. Use of the catalyst to remove methane from vehicle exhaust streams, crude oil production and processing exhaust streams, petroleum refining exhaust streams and natural gas production and processing exhaust streams.

Abstract: Ionization systems and methods include moving air into contact with one or more ion generators and then past an ozone removal assembly to remove at least some ozone from the air. The air may be moved by a fan and may be filtered before contacting the one or more ion generators. The amount of one or more of the following of the air may be measured: the amount of ions, particulates, temperature, humidity, and other relevant factors. The ionization amount may be adjusted based on one or more of the measured amounts. The one or more ion generators and ozone removal assembly may be constructed as part of a single unit so they can be removed and replaced easily.

Abstract: NOx abatement compositions include cobalt oxide (Co3O4) doped with cerium, and have an overall formula Co3-xCe-O4, with cerium occupying tetrahedral and/or octahedral sites in the spinel structure. The NOx abatement compositions possess NOx storage and NOx direct decomposition activity. Dual stage NOx abatement devices include an upstream portion having the NOx abatement composition to adsorb and store NOx at low temperature, and then release the NOx at higher temperature to a downstream catalytic conversion portion.

Abstract: The invention provides a process for preparing a methane oxidation catalyst comprising a mechanochemical treatment, a methane oxidation catalyst thus prepared and a method of oxidizing methane.

Abstract: A mixed oxide catalyst for the oxidative coupling of methane can include a catalyst with the formula AaBbCcDdOx, wherein: element A is selected from alkaline earth metals; elements B and C are selected from rare earth metals, and wherein elements B and C are different rare earth metals; the oxide of at least one of A, B, C, and D has basic properties; the oxide of at least one of A, B, C, and D has redox properties; and elements A, B, C, and D are selected to create a synergistic effect whereby the catalytic material provides a methane conversion of greater than or equal to 15% and a C2+ selectivity of greater than or equal to 70%. Systems and methods can include contacting the catalyst with methane and oxygen and purifying or collecting C2+ products.

Abstract: A transmission having a pressure controlled vent system, including a vent tube configured to engage a transmission such that a first opening of the vent tube is in fluid communication with an upper portion of a transmission cavity, a second end defining a second opening configured to be in fluid communication with an external atmosphere, and a bifurcated portion between the first end and the second end. The bifurcated portion includes a first tube segment and a second tube segment in parallel with the first tube segment. A pressure relief valve disposed in-line within the first tube segment and a vacuum relief valve disposed in-line within the second tube segment. The pressure relief valve cooperates with the vacuum relief valve to maintain a predetermined range of pressure differential between the first opening and the second opening. The vent tube may also include a moisture and/or a transmission fluid separator.

Abstract: In a method for removing methane from feed gas having a methane concentration of 2 mole % or less, the feed gas is optionally mixed with make-up methane or air and passed through a heat exchanger to heat the gas to an oxidation reactor inlet temperature T1. The heated stream is passed to the reactor where the methane is oxidised. A gas stream including the products of the oxidation reaction are removed with the gas stream being at a reactor outlet temperature T2 higher than the inlet temperature T1. The gas stream is then passed through the heat exchanger against the reactor stream to recover heat from the gas stream removed in the reactor and to heat the reactor stream. The outlet temperature T2 is measured and the inlet temperature T1 is controlled by adjusting the relative amount of make-up methane and/or air added to the feed gas.

Abstract: An oxidation catalyst for treating an exhaust gas produced by a stoichiometric natural gas (NG) engine comprising a substrate and a catalytic material for oxidising hydrocarbon (HC), wherein the catalytic material for oxidising hydrocarbon (HC) comprises a molecular sieve and a platinum group metal (PGM) supported on the molecular sieve, wherein the molecular sieve has a framework comprising silicon, oxygen and optionally germanium.

Abstract: The invention provides a composite catalyst containing a first component and a second component. The first component contains a ternary mixed metal oxide. The second component contains a platinum group metal. The composite catalyst is useful for catalyzing the low temperature oxidation of carbon monoxide and hydrocarbons.

Abstract: The present invention relates to catalyzed soot filter comprising a porous wall flow substrate, a catalyst for selective catalytic reduction (SCR), a palladium component, and a platinum component, the wall flow substrate comprising an inlet end, an outlet end, a substrate axial length extending between the inlet end and the outlet end, and a plurality of channels defined by internal walls of the wall flow substrate, wherein the plurality of channels comprise inlet channels having an open inlet end and a closed outlet end, and outlet channels having a closed inlet end and an open outlet end, and the SCR catalyst is provided on the entire surface of the inlet channel walls and on at least a portion of the surface of the pores within the channel walls underneath the surface of the channel walls coated with the SCR catalyst.

Abstract: Provided is a cerium-zirconium-based composite oxide having an excellent OSC, high catalytic activity, and excellent heat resistance, and also provided is a method for producing the same. The cerium-zirconium-based composite oxide comprises cerium, zirconium, and a third element other than these elements. The third element is (a) a transition metal element or (b) at least one or more elements selected from the group consisting of rare earth elements and alkaline earth metal elements. After a heat treatment at 1,000° C. to 1,100° C. for 3 hours, (1) the composite oxide has a crystal structure containing a pyrochlore phase, (2) a value of {I111/(I111+I222)}×100 is 1 or more, and (3) the composite oxide has an oxygen storage capacity at 600° C. of 0.05 mmol/g or more, and an oxygen storage capacity at 750° C. of 0.3 mmol/g or more.

Abstract: A cobalt-based nano catalyst including a metal combination as a core and a porous material as a shell. The metal combination includes a first metal component Co, a second metal component selected from Ce, La, and Zr, and a third metal component selected from Pt, Ru, Rh, and Re. The catalyst includes between 10 and 35 wt. % of the first metal component, between 0.5 and 10 wt. % of the second metal component, between 0.02 and 2 wt. % of the third metal component, and a carrier. The carrier is a porous material such as nano silica or alumina. The carrier is in the shape of a spheroid, has a pore size of between 1 and 20 nm and a specific area of between 300 and 500 m2/g. The active component of the catalyst has a particle size of between 0.5 and 20 nm.

Abstract: The present invention is directed to a process and a reactor for removing organic compounds from gas flows, in which process the said gas flow is passed through a first compartment of a multi-compartment reactor, which reactor comprises at least one first compartment and at least one second compartment, which first and second compartments are in heat exchanging relationship with each other through a joint, gas-tight wall, and in which first compartment the gas flow is heated by heat exchange with the said second compartment, passing the heated gas flow to the second compartment, further heating the gas flow entering the second compartment either by adding additional combustible gas or electric heating, and passing the heated gas through the second compartment over a catalytic oxidation catalyst to combust the organic compounds, whereby both the first and the second compartment are filled with porous sintered metal material, which is in heat exchanging relationship to the said joint wall, whereby the metal mat

Abstract: A system for abating waste methane includes a catalytic combustor device configured to catalytically combust waste-associated methane emissions generated by waste in a waste container, where the catalytic combustion is based on a reaction of the methane emissions and a catalyst of the catalytic combustor device in the presence of heat. The system further includes a combustion sensor configured to generate combustion data based on the catalytic combustion, a transmitter, and a processing circuit. The processing circuit is configured to control operation of the catalytic combustor device, determine an amount of methane abated by the catalytic combustor device, where the amount of methane abated is based on the combustion data, and report, via the transmitter, the amount of methane abated by the catalytic combustor device.

Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat with a Cu—Mn spinel structure and an overcoat that includes PGM supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under stoichiometric operating conditions and especially under lean operating conditions, which allows a reduced consumption of fuel. Additionally, disclosed SPGM catalyst system also enhances the reduction of carbon monoxide and hydrocarbon within catalytic converters. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalyst activity compared to commercial PGM catalyst system, showing that there is a synergistic effect among PGM catalyst and Cu—Mn spinel within the disclosed SPGM catalyst system.

Abstract: In one embodiment, a catalyst for ozone oxidation of pollutant components dispersed in a gas is provided. The ozone oxidation catalyst has a porous body formed from a metal body, a ceramic, or polymeric fibers coated with metal. A catalytic noble metal composition is deposited on the surface of the porous body. The catalytic noble metal composition is formed from particles of a noble metal supported by a mesoporous molecular sieve.

Abstract: Disclosed is an apparatus and method for decomposing an ultra-low concentration of volatile organic compounds, which may effectively remove ultra-low concentration of volatile organic compounds by a batch process for separating ultra-low concentration of volatile organic compounds present in an indoor air or the like and oxidizing the corresponding volatile organic compounds at a low temperature.

Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

Abstract: A method for removing tar from a gas by contacting a first gas containing tar with a second gas containing oxygen for time period sufficient to effect oxidation of at least a portion of the tar in the first gas, thus producing an oxidized product gas that contains less tar than the first gas.

Abstract: Provided are a carbon catalyst for decomposing a hazardous substance that effectively decomposes hazardous substances such as aldehydes, a hazardous-substance-decomposing material, and a method of decomposing a hazardous substance. The carbon catalyst for decomposing a hazardous substance is a carbon catalyst having a catalytic activity for decomposing the hazardous substance. The hazardous substance is, for example, a volatile organic compound such as aldehydes or a malodorous substance such as a sulfur compound. The method of decomposing a hazardous substance, is a method including decomposing the hazardous substance with the carbon catalyst for decomposing a hazardous substance or with a hazardous-substance-decomposing material containing the carbon catalyst for decomposing a hazardous substance.

Abstract: Apparatus and method for removal of particles and VOC from an airstream, in which particles carried by the airstream are charged by a corona ionizer and then collected by an electrically enhanced filter downstream of the ionizer. A catalytic filter downstream of the electrically enhanced filter removes VOC as well as ozone generated by the ionizer.

Abstract: For the purification of waste gas containing nitrogen oxides in combination with CO, VOCs or nitrous oxide, in particular waste gas resulting from the production of cement clinker, nitric acid, adipic acid, fertilizers and uranium trioxide, a regenerative thermal post-combustion system with at least two regenerators (A, B) is used by means of which the CO, VOCs and nitrous oxide are thermally purified in the combustion chamber (1) at a temperature of 800 to 1000° C. and the nitrogen oxides are thermally reduced with the SCR catalyst (6) by adding a nitrogen-hydrogen compound, wherein the waste gas already thermally purified is removed from the respective two-part regenerator (A or B) at a suitable place at a temperature of approx. 300° C., guided via the SCR catalyst (6) in a constant direction of flow and subsequently fed back to the remaining section (A?, B?) of the regenerator (A or B).

Abstract: Provided is a method for oxidizing short-chain saturated hydrocarbons in a lean burn exhaust gas, the method involving contacting the exhaust gas with a palladium or palladium/platinum catalyst disposed on a rare-earth stabilized zirconia support.

Abstract: The present invention concerns a nano-structured composite material based on compositions of manganese and cerium, composed of aggregated composite nanospheres, ranging in size from 1 to 40 nm, of ultrafine crystalline nanoparticles of one or more compounds of cerium, dispersed in a metastable solid mixture of one or more sub-stoichiometric oxides of manganese, said sub-stoichiometric oxides of manganese comprising MeMnOz manganates, wherein 1?z?4, Me being constituted of one or more elements selected amongst alkali metals, alkaline earth metals, transition metals and rare earths, and in particular being constituted of one or more elements selected amongst Ce, V, Ti, Cr, Fe, Cu, Zn, Sn, Ga, Gd, Y, Zr, Al, Si, La, K, Li, Pb, Cs, or mixtures thereof; which can be used in the industry as redox catalyst and/or adsorbing filter of heavy metals, cyanides, sulfur compounds, pigments, dyes, polymers (PEG), phenols, alcohols, aldehydes and ketones, ethers, esters and carboxylic acids which are present both in contamin

Abstract: Synergized Platinum Group Metals (SPGM) catalyst system for TWC application is disclosed. Disclosed SPGM catalyst system may include a washcoat with a Cu—Mn spinel structure and an overcoat that includes PGM supported on carrier material oxides, such as alumina. SPGM catalyst system shows significant improvement in nitrogen oxide reduction performance under stoichiometric operating conditions and especially under lean operating conditions, which allows a reduced consumption of fuel. Additionally, disclosed SPGM catalyst system also enhances the reduction of carbon monoxide and hydrocarbon within catalytic converters. Furthermore, disclosed SPGM catalyst systems are found to have enhanced catalyst activity compared to commercial PGM catalyst system, showing that there is a synergistic effect among PGM catalyst and Cu—Mn spinel within the disclosed SPGM catalyst system.

Abstract: A catalyst for oxidizing carbon monoxide (CO), volatile organic compounds (VOCs), and methyl bromide (CH3Br) is provided. The catalyst comprises a first base metal catalyst supported on an oxygen donating support that is substantially free of alumina, and at least one second base metal catalyst. Also provided is a method for treating the waste stream from a purified terephthalic acid (PTA) process, the method comprising contacting a waste stream containing carbon monoxide (CO), volatile organic compounds (VOCs), and methyl bromide with a catalyst comprising a first base metal catalyst supported on an oxygen donating support that is substantially free of alumina, and at least one second base metal catalyst.

Abstract: Hybrid thermal oxidizer systems and methods for combusting waste gas and heating utility oil using an efficient transfer of heat from fuel gas.

Abstract: Methane is removed from ventilation air by cycling metal or metal oxide particles in a chemical looping process in one or more reactors where the metal particles are alternately reduced and oxidised, and passing ventilation air through one or more of said reactors to convert the air plus methane into reduced air plus water plus carbon dioxide. In one variation, ventilation air methane (VAM) is removed from ventilation air in coal mines using a chemical looping process to move metal or metal oxide particles between reactors such as a hydrogen generator (5) and a regenerator (7) to alternatively reduce and oxidise the particles such that VAM introduced into a combustor (6) provided with hydrogen from the hydrogen generator (5) can be processed in the regenerator (7) to produce air plus water plus carbon dioxide.

Abstract: A system and method of using a double-effect-reactor to dispose incinerated flue gas and improve cement yields. The double-effect-reactor features an incinerated reaction chamber and a gas-solid suspension mixing chamber. The system includes the double-effect-reactor, a high temperature dust-arrester, a system for recovery of thermal energy and dust removal, a triple valve, and an independent chimney. Also disclosed is a method in which combines the double-effect-reactor with a cement production system.

Abstract: A method and apparatus for treatment of unburnts in a flue stream 9 of a chemical looping combustion system. Unburnts present in the flue stream 9 are treated after CO2 is removed from the flue stream in a gas processing unit 13. As shown in FIG. 2, oxidation of the unburnts occurs primarily in an air reactor 2 in the presence of air 1, allowing the system to maintain CO2 capture effectiveness and removing the need for creation of enriched or pure oxygen 11.

Abstract: A photodegradation catalyst or a photodegradation catalyst precursor comprises a plurality of domains of an oxide of a first metal distributed in a substrate of a halide or oxyhalide of a second metal, wherein the mole percentage of the halide or oxyhalide of the second metal is above 50%. Additionally, a method of preparing a photodegradation catalyst or a photodegradation catalyst precursor, a photodegradation catalyst or a photodegradation catalyst precursor obtained from the method and a method of treating organic pollutants or substances in air or water by using the photodegradation catalyst or the photodegradation catalyst precursor are illustrated.

Abstract: A method for the thermal post-combustion of waste gases from incomplete combustion or furnace processes, low temperature carbonization gases, landfill gases, smoke gases from ceramic furnace processes, gases from household waste or bio composting facilities, lean gases or other hydrocarbon-containing reducing gases by means of air or other oxidant gases, in which the reducing gas and the oxidant gas are fed separately to the post-combustion in a combustion chamber and thermally post-combusted in the combustion chamber and the reducing gas is heated in a recuperative manner during the supply to the combustion chamber through hot clean gas thermally post-combusted and conveyed out of the combustion chamber, Wherein both the reducing gas as well as the oxidant gas are heated in a recuperative manner flowing parallel via the separate supply to the combustion chamber by the hot clean gas conveyed out of the combustion chamber.

Abstract: The present invention relates to environmental protection field. The present invention provided a method and a system thereof for treating flue gases generated from waste incinerator by using a dual-purpose reactor, wherein said dual-purpose reactor includes a connected incineration chamber and gas-solid suspension chamber. The method and the system of the invention can continuous operate under high temperature and remove acid gases and dioxin or dioxin precursor completely.

Abstract: Methods and apparatus for decontaminating disposable protective products prepared from polyvinyl alcohol (PVA), used in a nuclear power plant, to less than minimum detectable activity (MDA) are disclosed. In the disclosed methods and apparatus, solid protective products made of PVA, generated from a nuclear power plant, are dissolved into a liquid, and then are decontaminated to less than MDA. The PVA solution decontaminated in this way is concentrated to an appropriate concentration or dried, and finally is subjected to self-disposal. This can fundamentally block the generation amount of combustible waste amounting to 50% or more of low and intermediate level waste of nuclear power plants, thereby considerably contributing to a reduction of the operating expenses of the nuclear power plants.

Abstract: In one embodiment, a catalyst for ozone oxidation of pollutant components dispersed in a gas is provided. The ozone oxidation catalyst has a porous body formed from a metal body, a ceramic, or polymeric fibers coated with metal. A catalytic noble metal composition is deposited on the surface of the porous body. The catalytic noble metal composition is formed from particles of a noble metal supported by a mesoporous molecular sieve.

Abstract: Novel methods of electroless plating are described. Catalyst coatings can be applied within microchannel apparatus. Various reactions, including combustion and steam reforming, can be conducted over electroless catalyst coatings.

Abstract: A system and method according to which exhaust is directed from a stationary exhaust source and through a burner, and a combustible fluid is vented from at least one combustible fluid source other than the stationary exhaust source. The combustible fluid is captured and directed to flow from the combustible fluid source and towards the burner, and at least air is mixed with the captured combustible fluid to form a mixture. The mixture is introduced into the burner and burned therein to thereby pre-heat the exhaust flowing therethrough. The pre-heated exhaust contacts a catalyst.

Abstract: A VOC treatment apparatus is provided for treating substantially opaque VOCs and comprises a processing chamber (24) in which VOCs are treated; and a solar energy introducing device (8). The solar energy introducing device (8) comprises a tubular structure having a first end located external to the processing chamber (24) and having a first inlet (14) through which concentrated sunlight is received and a second inlet (16) through which a flow of substantially optically transmittant gas is received. The solar energy introducing device (8) has a second end (18) that opens into the processing chamber (24) and terminates in a nozzle providing an outlet for the substantially optically transmittant gas and the concentrated sunlight. In use the optically transmittant gas exits the second end of the device in a jet to create an optically transmittant zone in the substantially opaque VOCs within the processing chamber (24), in which zone the sunlight can travel.

Abstract: Production brines are used to scrub a horizontal stack receiving exhaust from an energy source, controlling, reducing, or both noxious chemicals. Mutual remediation of flows from petroleous production cool and scrub exhausts from flares burning waste hydrocarbons, heaters lowering viscosity of crude oil, engines driving oil pumps or natural gas compressors, and the like. Resulting evaporation of production brines results in distilled water, more concentrated brines to reduce hauling, or, optionally, dehydrated dry waste minerals from the brines. Year-round operation of brine evaporation ponds is facilitated, and may be another source of process pre-heating.

Abstract: The oxidation of nitrogen oxide (NO) in an oxygen-containing exhaust gas flow from a diesel or other lean-burn engine may be catalyzed using particles of co-precipitated and calcined manganese (Mn), cerium (Ce) and zirconium (Zr) mixed oxides. In preferred embodiments, the molar ratios of Mn, Ce and Zr to the total amount of base metals in the ternary mixed oxide catalyst are in the range of 0.25-0.35, 0.40-0.50 and 0.20-0.25, respectively. Further, this ternary mixed oxide catalyst is less susceptible to sulfur poisoning than previously-disclosed binary mixed oxide catalysts. The ternary mixed oxide catalyst may also be regenerated—and the inhibiting effect of SO2 reversed—by briefly exposing the catalyst to a reducing exhaust gas environment.

Abstract: Described is a method for cleaning the exhaust gases of internal combustion engines, which method is suitable for reducing harmful gases and particle emissions. Here, the exhaust gas to be cleaned is conducted, under operating conditions, with a discontinuous profile of the air ratio ? across a wall-flow filter substrate which comprises a catalytically active coating containing one storage material. The storage material is suitable for temporarily storing one or more exhaust-gas components under certain operating conditions and releasing said exhaust-gas components again in a targeted fashion in the event of a suitable change in the operating conditions. The coating is configured such that the component has a gradient of the storage material concentration and/or of the total coating amount, with the highest concentration of the storage material in the longitudinal direction of the component being present on the inflow side.

Abstract: Methods are provided for physically removing all the carbon dioxide from the combustion products of solid, liquid, and gaseous fossil fuels. The combustors operate without excess air to maximize the carbon dioxide at the exhaust, which is compressed with the nitrogen and mixed with pressurized water to dissolve the carbon dioxide in a chamber from which the nitrogen gas is removed. The solution is drained into a second lower pressure chamber from which the carbon dioxide re-evolves as a gas, which is then pressurized for sequestration in limestone formations as calcium bicarbonate. The water is recycled to repeat the separation process, and depressurization of the two gases recovers most of the compression energy.

Abstract: Reactive diluent fluid (22) is introduced into a stream of synthesis gas (or “syngas”) produced in a heat-generating unit such as a partial oxidation (“POX”) reactor (12) to cool the syngas and form a mixture of cooled syngas and reactive diluent fluid. Carbon dioxide and/or carbon components and/or hydrogen in the mixture of cooled syngas and reactive diluent fluid is reacted (26) with at least a portion of the reactive diluent fluid in the mixture to produce carbon monoxide-enriched and/or solid carbon depleted syngas which is fed into a secondary reformer unit (30) such as an enhanced heat transfer reformer in a heat exchange reformer process. An advantage of the invention is that problems with the mechanical integrity of the secondary unit arising from the high temperature of the syngas from the heat-generating unit are avoided.

Abstract: The present invention relates to catalytic compositions for, inter alia, the photocatalytic oxidation of CO, including: a substrate including, at least at a surface thereof, titanium oxide; and, deposited on the titanium oxide on the surface of the substrate, a metal mixture containing: platinum, at least partially in the metal state; and palladium and/or nickel, at least partially in the metal state. More specifically, the invention relates to the use of said compositions for treating gaseous media including CO and organic pollutants, for example indoor air in inhabited buildings or vehicles.