By Burning Or Catalytically Combusting Component Patents (Class 423/245.3)
  • Patent number: 8236261
    Abstract: A method of providing an exhaust treatment device is disclosed. The method includes applying a catalyst including gold and a platinum group metal to a particulate filter. The concentration of the gold and the platinum group metal is sufficient to enable oxidation of carbon monoxide and nitric oxide.
    Type: Grant
    Filed: October 6, 2011
    Date of Patent: August 7, 2012
    Assignee: Caterpillar Inc.
    Inventors: Christie Susan Ragle, Ronald G. Silver, Svetlana Mikhailovna Zemskova, Colleen J. Eckstein
  • Patent number: 8231851
    Abstract: An exhaust gas containing a perfluoride compound (PFC) and SiF4 is conducted into a silicon remover and brought into contact with water. A reaction water supplied from a water supplying piping and air supplied from an air supplying piping are mixed with the exhaust gas exhausted from the silicon remover. The exhaust gas containing water, air, and CF4 is heated at 700° C. by a heater. The exhaust gas containing PFC is conducted to a catalyst layer filled with an alumina group catalyst. The PFC is decomposed to HF and CO2 by the catalyst. The exhaust gas containing HF and CO2 at a high temperature exhausted from the catalyst layer is cooled in a cooling apparatus. Subsequently, the exhaust gas is conducted to an acidic gas removing apparatus to remove HF. In this way, the silicon component is removed from the exhaust gas before introducing the exhaust gas into the catalyst layer.
    Type: Grant
    Filed: September 16, 2002
    Date of Patent: July 31, 2012
    Assignees: Hitachi, Ltd., Hitachi Information & Control Solutions, Ltd., Hitachi Kyowa Engineering Co., Ltd.
    Inventors: Kazuyoshi Irie, Toshihiro Mori, Hisao Yokoyama, Takayuki Tomiyama, Toshihide Takano, Shin Tamata, Shuichi Kanno
  • Patent number: 8226912
    Abstract: A gaseous mixture, comprising CO2, H2, H2S and optionally CO, is separated into an H2 or H2 and CO product stream (H2/CO product stream), and a CO2 enriched stream containing at least one combustible component selected from H2S, H2, CO and any additional combustible components present in the gaseous mixture. A support fuel stream, comprising one or more combustible components, is combusted to form a stable flame, and the CO2 enriched stream and flame are contacted in the presence of sufficient O2 to combust all or substantially all of the combustible component(s) present in said CO2 enriched stream. A CO2 product stream is formed from said combustion effluent. The support fuel stream may be generated from the process of generating or separating the gaseous mixture or from the H2/CO product stream. Where the CO2 enriched stream contains H2S, the support fuel stream may also be a stream obtained off-site that comprises H2S.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: July 24, 2012
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Jeffrey William Kloosterman, Kevin Boyle Fogash, Andrew David Wright
  • Patent number: 8221687
    Abstract: A system and a method are provided for removing greenhouse gases, particulates and pollutants from the atmosphere utilizing a greenhouse gas collection apparatus. An atmospheric mixture is collected and progressively treated in first, second and third tube furnaces and a scrubber to produce an effluent for treatment in a chemical processing plant. The first tube furnace oxidizes hydrocarbons, the second tube furnace oxidizes any remaining nitrous and nitric oxides, and the third tube furnace oxidizes sulfur dioxide. The scrubber precipitates carbon dioxide as calcium carbonate. A vacuum pump draws the atmospheric mixture through tube furnaces and the scrubber.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: July 17, 2012
    Inventor: Ernest John Shearing
  • Patent number: 8178065
    Abstract: A photocatalyst is provided that comprises activated carbon produced from date pits, impregnated with TiO2. The activated carbon can have a porous surface that can attract and trap pollutants flowing in air or water. The photocatalyst can be made by a method that includes preparing activated carbon by calcining date pits to form a precursor material, and then impregnating the precursor material with titanium dioxide.
    Type: Grant
    Filed: March 16, 2010
    Date of Patent: May 15, 2012
    Assignee: The National Titanium Dioxide Co. Ltd. (CRISTAL)
    Inventors: Yousef Saleh Al-Zeghayer, Sami M. Bashir, Ahmed V. Yaser, Hassan M. El Dekki, Waheed A. Al-Masry, Fadi M. Trabzuni
  • Patent number: 8173087
    Abstract: Provided are exhaust systems and components suitable for use in conjunction with gasoline direct injection (GDI) engines to capture particulates in addition to reducing gaseous emission such as hydrocarbons, nitrogen oxides, and carbon monoxides. Exhaust treatment systems comprising a three-way conversion (TWC) catalyst located on a particulate trap are provided. An exemplary particulate trap is a soot filter. Additional treatment components can be added downstream of the particulate trap, including NOx traps and SCR catalysts. The TWC catalyst can be coated on both the inlet side and the outlet side of the particulate trap. Alternatively, an oxidation catalyst can be deposited on a particulate trap. Methods of making and using the same are also provided.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: May 8, 2012
    Assignee: BASF Corporation
    Inventors: Junmei Wei, Knut Wassermann, Yeujin Li
  • Patent number: 8153090
    Abstract: A system to control the emissions of a fluid stream in a cyclical fashion utilizing an up-flow cycle and a down-flow cycle. The system may include a first inlet and a first outlet at a first end of the system and a second inlet and a second outlet at a second end of the system, a catalyst zone between the first end and second end, two heat transfer zones, at least one heat transfer zone positioned between the catalyst zone and the first end of the system and between the catalyst zone and the second end of the system, and two heating zones, at least one heating zone positioned between the catalyst zone and each of the at least one heat transfer zones. The symmetrical arrangement permits a bi-directional fluid cycle to recover a portion of the energy supplied to the system during each cycle.
    Type: Grant
    Filed: October 6, 2010
    Date of Patent: April 10, 2012
    Assignee: OnQuest, Inc.
    Inventor: Anu Vij
  • Patent number: 8142747
    Abstract: A system for NOx reduction in combustion gases, especially from diesel engines, incorporates an oxidation catalyst to convert at least a portion of NO to NO2, a particulate filter, a source of reductant such as NH3 and an SCR catalyst. Considerable improvements in NOx conversion are observed.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: March 27, 2012
    Inventors: Anders Andreasson, Guy Richard Chandler, Claus Friedrich Goersmann, James Patrick Warren, Georg Huethwohl
  • Patent number: 8142744
    Abstract: An air pollution control system includes an emission treatment system configured to receive flue gas, to reduce at least one pollutant therefrom, and to output emission treated flue gas. A first air heater in fluid communication with the emission treatment system includes a heat exchanger for heating forced air introduced thereto above a base temperature and thereby cooling emission treated flue gas from the emission treatment system to a stack discharge temperature. A second air heater in fluid communication with the first air heater to receive heated forced air therefrom includes a heat exchanger for heating forced air introduced thereto to a preheat temperature for combustion in a boiler and thereby cooling flue gas introduced from a boiler to the second air heater to an emission treatment temperature. The second air heater is in fluid communication with the emission treatment system to introduce cooled flue gas thereto.
    Type: Grant
    Filed: March 17, 2011
    Date of Patent: March 27, 2012
    Assignee: Babcock Power Environmental Inc.
    Inventors: Richard F. Abrams, Mark R. Lewis, Jeffrey Penterson
  • Publication number: 20120051992
    Abstract: A method of providing an exhaust treatment device is disclosed. The method includes applying a catalyst including gold and a platinum group metal to a particulate filter. The concentration of the gold and the platinum group metal is sufficient to enable oxidation of carbon monoxide and nitric oxide.
    Type: Application
    Filed: October 6, 2011
    Publication date: March 1, 2012
    Applicant: Caterpillar Inc.
    Inventors: Christie Susan Ragle, Ronald G. Silver, Svetlana Mikhailovna Zemskova, Colleen J. Eckstein
  • Publication number: 20120051993
    Abstract: A method for volatile compound (VC) mitigation in a syngas production process is provided. This method includes providing a hydrocarbon reforming syngas production plant, this plant includes a reformer system comprising a primary fuel and oxidant stream, where part of this system is at low pressure, a steam inlet stream, and a primary combustion system for providing heat to the reformer system and producing a reformer flue gas stream, and a gaseous vent stream mainly composed of water and containing VC. This method also includes introducing at least a portion of the vent stream into one or more of the following: the primary fuel and oxidant stream; the steam inlet stream; the reformer flue gas stream.
    Type: Application
    Filed: August 25, 2010
    Publication date: March 1, 2012
    Applicants: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude, Air Liquide Large Industries U.S. LP, Lurgi GmbH
    Inventors: William D. Lindberg, Alexander Rösch, Michael B. Wakim
  • Publication number: 20120039781
    Abstract: The present invention is directed to a process and a reactor for removing organic compounds from gas flows, in which process the said gas flow is passed through a first compartment of a multi-compartment reactor, which reactor comprises at least one first compartment and at least one second compartment, which first and second compartments are in heat exchanging relationship with each other through a joint, gas-tight wall, and in which first compartment the gas flow is heated by heat exchange with the said second compartment, passing the heated gas flow to the second compartment, further heating the gas flow entering the second compartment either by adding additional combustible gas or electric heating, and passing the heated gas through the second compartment over a catalytic oxidation catalyst to combust the organic compounds, whereby both the first and the second compartment are filled with porous sintered metal material, which is in heat exchanging relationship to the said joint wall, whereby the metal mat
    Type: Application
    Filed: February 25, 2010
    Publication date: February 16, 2012
    Inventors: John Wilhelm Geus, Marinus Franciscus Johannes Evers
  • Patent number: 8105562
    Abstract: The invention relates to a method and an apparatus for treating exhaust gases comprising organosilicon components or accompanying substances. The invention more specifically relates to the use of bulk regenerator materials as storage materials allowing periodic removal, purification, and redelivery to the system. The invention solves the problem of clogged regenerator-storage materials during regenerative post-combustion of exhaust gases containing organosilicon components.
    Type: Grant
    Filed: December 7, 2004
    Date of Patent: January 31, 2012
    Assignee: Clausthaler Umwelttechnik-Institut GmbH (CUTEC-Institut)
    Inventors: Otto Carlowitz, Bernd Ruskamp, Olaf Neese, Frank Kriebisch
  • Patent number: 8101146
    Abstract: A system for reducing ammonia (NH3) emissions includes (a) a first component comprising a first substrate containing a three-way catalyst, wherein the first component is disposed upstream of a second component comprising a second substrate containing an ammonia oxidation catalyst, wherein said ammonia oxidation catalyst comprises a small pore molecular sieve supporting at least one transition metal; and (b) an oxygen-containing gas input disposed between the components. For example, a CHA Framework Type small pore molecular sieve may be used. A method for reducing NH3 emission includes introducing an oxygen-containing gas into a gas stream to produce an oxygenated gas stream; and exposing the oxygenated gas stream to an NH3 oxidation catalyst to selectively oxidize at least a portion of the NH3 to N2.
    Type: Grant
    Filed: April 8, 2011
    Date of Patent: January 24, 2012
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Joseph M. Fedeyko, Hai-Ying Chen, Arthur J. Reining
  • Patent number: 8092769
    Abstract: A process and apparatus are described for converting a feed that is substantially comprised of halogenated materials, and especially byproduct and waste chlorinated hydrocarbons as are produced from a variety of chemical manufacturing processes, to one or more higher value products via a partial oxidation reforming reaction step. These products can be in the form of a useful or salable acid product and/or a product synthesis gas comprised of carbon monoxide and hydrogen, or the reaction product including the same hydrogen halide, carbon monoxide and hydrogen components can be employed as a feed in the synthesis of a different useful or salable product.
    Type: Grant
    Filed: May 11, 2007
    Date of Patent: January 10, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Dennis Wade Jewell, John P. Henley, Edward E. Timm, Tarver Gayle Snedecor, Jr., Leopoldo Salinas, III, Charles William Lipp, James Everett Clark
  • Patent number: 8080226
    Abstract: Methods and systems for the destruction of one or more PFCs in a gas stream are provided. The gas stream can come from semiconductor processing, for example. The PFCs in the gas stream are reacted with steam in the presence of a catalyst to fragment the PFCs into other compounds that are readily removed from the gas stream. The catalyst comprises gallium, and can additionally comprise zirconium oxide. The gas stream can also be pre-treated prior to reacting the PFCs with steam to remove substances that could be deleterious to the catalyst.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: December 20, 2011
    Assignee: TecHarmonic, Inc.
    Inventors: Christopher Hertzler, Vivian W. Hui
  • Patent number: 8066963
    Abstract: The exhaust gas of internal combustion engines operated with a predominantly stoichiometric air/fuel mixture contains, as well as the gaseous hydrocarbon (HC), carbon monoxide (CO) and nitrogen oxide (NOx) pollutants, also ultrafine particulates. There is disclosed a catalytically active particulate filter, an exhaust gas cleaning system and a process for cleaning the exhaust gases of predominantly stoichiometrically operated internal combustion engines, as well as the gaseous CO, HC and NOx pollutants, also for removing particulates from the exhaust gas. The particulate filter comprises a filter body and a catalytically active coating consisting of two layers. Both layers contain alumina. The first layer contains palladium. The second layer contains rhodium. The latter is disposed above the first layer.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: November 29, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Raoul Klingmann, Martin Roesch, Dieter Lindner
  • Patent number: 8057767
    Abstract: Chemical species such as nitrogen oxide (NO), carbon monoxide, and low molecular weight hydrocarbons (e.g., C1-C5 and saturated or ethylenically unsaturated) in an oxygen-containing gas stream, such as the exhaust stream from a diesel engine, or other lean burn engine, may be oxidized using a mixture of MnOx with one or more other base metal oxides, with or without palladium. The oxidation is effective at temperatures above about 200° C. to convert about ninety percent or more of the carbon monoxide to carbon dioxide and to consume the hydrocarbons. The oxidation is also effective to convert much of the NO to NO2. In general, the mixed base metal oxides may be used as catalysts for the oxidation of nitrogen oxide in hot gas streams containing oxygen. They may optionally be used in a combination with palladium or platinum. But platinum, which is very expensive, does not have to be used in such oxidation reactions.
    Type: Grant
    Filed: August 10, 2010
    Date of Patent: November 15, 2011
    Assignee: GM Global Technology Operations LLC
    Inventors: Gongshin Qi, Wei Li
  • Patent number: 8048391
    Abstract: The present invention relates to a gas purifier containing a filtering media having a photocatalytic action, a system for illuminating said media with UV radiation, a time-delay means or a volatile organic compound analyzer, and a means for automatically adjusting the speed of the gas passing through the media or for adjusting the intensity of the UV illumination, said adjusting being carried out as a function of the time determined by the time-delay means or as a function of the content of a volatile organic compound analyzed by the analyzer.
    Type: Grant
    Filed: July 17, 2008
    Date of Patent: November 1, 2011
    Assignee: Saint-Gobain Quartz S.A.S
    Inventor: Laurent Molins
  • Patent number: 8043590
    Abstract: A system for NOx reduction in combustion gases, especially from diesel engines, incorporates an oxidation catalyst to convert at least a portion of NO to NO2, a particulate filter, a source of reductant such as NH3 and an SCR catalyst. Considerable improvements in NOx conversion are observed.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: October 25, 2011
    Assignees: Daimler AG, HJS Emission Technology GmbH & Co., Johnson Matthey PLC
    Inventors: Anders Andreasson, Guy Richard Chandler, Claus Friedrich Goersmann, James Patrick Warren, Georg Huethwohl
  • Publication number: 20110212010
    Abstract: A thermal oxidizer assembly is adapted for mounting onto a furnace, such that a heating chamber of the assembly is in direct flow-through communication with an interior of the furnace and defines a flow path for volatile organic compounds that are released from workpieces being processed within the furnace. A heating module is mounted within the heating chamber of the assembly and is located within the flow path to create turbulent flow therethrough. The assembly is configured to allow a natural draft to pull the volatile organic compounds from the furnace and through the flow path, and the heating module heats the volatile organic compounds, within the heating chamber, to a temperature necessary to destroy greater than approximately 99% of the volatile organic compounds. A flow rate of the volatile organic compounds being pulled along the flow path is, preferably, between approximately five and thirty standard cubic feet per minute.
    Type: Application
    Filed: September 2, 2010
    Publication date: September 1, 2011
    Applicant: DESPATCH INDUSTRIES LIMITED PARTNERSHIP
    Inventor: Jeffry A. Bell
  • Publication number: 20110182792
    Abstract: The present invention provides a method for producing a highly active catalyst for reforming tar-containing gas used to treat crude gas for chemical energy conversion consisting of converting to a fuel composition consisting mainly of methane, hydrogen and the like, by utilizing sensible heat possessed by crude gas generated during thermal decomposition of carbonaceous raw materials, and using the high chemical reaction activity of high-temperature tar contained in and incidental to the crude gas to convert the tar to light hydrocarbons in the presence of a catalyst; a tar reforming method; and, a method for regenerating a catalyst for reforming tar-containing gas.
    Type: Application
    Filed: September 15, 2009
    Publication date: July 28, 2011
    Inventors: Kimihito Suzuki, Kenichiro Fujimoto
  • Patent number: 7981390
    Abstract: Catalyst articles comprising substantially only a palladium precious metal component and related methods of preparation and use are disclosed. Disclosed is a catalyst article comprising a first layer formed on a carrier substrate, wherein the first layer comprises a refractory metal oxide and has a surface that is substantially uniform; and a second layer formed on the first layer, wherein the second layer comprises i) an oxygen storage component that is about 50-90% by weight of the second layer and ii) a palladium component in an amount of about 10-150 g/ft3 of palladium, wherein the palladium component is substantially the only platinum group metal component. One or more improved properties are exhibited by the catalyst article.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: July 19, 2011
    Assignee: BASF Corporation
    Inventors: Michael P. Galligan, Xinsheng Liu, Pascaline H. Tran, Young Gin Kim, Ye Liu
  • Patent number: 7959883
    Abstract: Particulate pollutants such as carbonaceous particles are removed from an engine exhaust stream by passing the exhaust stream through an exhaust gas reactor, the exhaust stream first traversing a charging zone wherein the particles are charged via a corona discharge, and thereafter traversing a downstream collection zone wherein the charged particles are collected and eliminated by a collector/reactor having an oppositely charged reactive collecting surface.
    Type: Grant
    Filed: August 28, 2009
    Date of Patent: June 14, 2011
    Assignee: Corning Incorporated
    Inventors: Christopher W Drewnowski, Martin Andrew Sala
  • Patent number: 7955578
    Abstract: To provide a method and apparatus for treating a waste gas containing fluorine-containing compounds, according to which PFCs can be decomposed efficiently even at low temperature, and moreover fluorine from the product of the decomposition can be recovered for reuse efficiently. An embodiment of the present invention relates to a method of treating a gas containing a fluorine-containing compound, comprising contacting the gas with a treatment agent comprising a mixture of aluminum hydroxide and calcium hydroxide.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: June 7, 2011
    Assignee: Ebara Corporation
    Inventors: Yoichi Mori, Tadakazu Nishikawa, Masaaki Osato, Saburou Nagano, Yoshihiro Tanabe
  • Patent number: 7951346
    Abstract: Methods and systems for reducing emissions of particulate matter from a gaseous stream are provided. The subject systems include a catalyst that reduces the amount of particulate matter emissions in the gaseous stream. Embodiments of the subject systems may also reduce the amount of particulate matter precursor emissions in the gaseous stream. In some cases, the subject systems and methods include a sorber that facilitates the reduction in particulate matter and particulate matter precursors in the gaseous stream. The subject methods and systems find use in a variety of applications where it is desired to reduce particulate matter emissions from a gaseous stream.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: May 31, 2011
    Assignee: Emerachem, LLC
    Inventors: Tom Girdlestone, Steven De Cicco, William S. Epling, Jerald A. Cole, Gregory J. Wagner
  • Patent number: 7931881
    Abstract: An air pollution control system includes an emission treatment system configured to receive flue gas, to reduce at least one pollutant therefrom, and to output emission treated flue gas. A first air heater in fluid communication with the emission treatment system includes a heat exchanger for heating forced air introduced thereto above a base temperature and thereby cooling emission treated flue gas from the emission treatment system to a stack discharge temperature. A second air heater in fluid communication with the first air heater to receive heated forced air therefrom includes a heat exchanger for heating forced air introduced thereto to a preheat temperature for combustion in a boiler and thereby cooling flue gas introduced from a boiler to the second air heater to an emission treatment temperature. The second air heater is in fluid communication with the emission treatment system to introduce cooled flue gas thereto.
    Type: Grant
    Filed: September 25, 2009
    Date of Patent: April 26, 2011
    Assignee: Babcock Power Environmental Inc.
    Inventors: Richard F. Abrams, Mark R. Lewis, Jeffrey Penterson
  • Patent number: 7922988
    Abstract: A layered three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Engine exhaust treatment system and methods of using the same are also provided. The catalytic material can be provided in layers such that a larger amount of oxygen storage component is provided in a downstream zone as compared to an upstream zone. For example, the upstream zone can be configured to have one, two, or three layers, and the downstream zone can be independently configured to have one, two, or three layers. In one or more embodiments, the catalyst supported on a carrier has three layers, where at least two of the layers are zoned to have an oxygen storage component being present in an upstream zone in an amount that is less than the oxygen storage component present in the downstream zone.
    Type: Grant
    Filed: October 30, 2009
    Date of Patent: April 12, 2011
    Inventors: Michel Deeba, Stephan Siemund, Xinyi Wei, Stefan Kotrel, Knut Wassermann, Glenn Svoboda, Harold Rabinowitz
  • Patent number: 7922987
    Abstract: A diesel particulate filter with an oxidation catalyst comprising platinum and palladium deposited thereon is described. Addition of HC storage components to the oxidation catalyst allows the conversion of hydrocarbons and carbon monoxide to be improved significantly.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: April 12, 2011
    Assignee: Umicore AG & Co. KG
    Inventors: Markus Koegel, Marcus Pfeifer, Gerald Jeske, Frank Walter Schuetze, Stéphanie Frantz, Thomas Kreuzer
  • Publication number: 20110076215
    Abstract: An air pollution control system includes an emission treatment system configured to receive flue gas, to reduce at least one pollutant therefrom, and to output emission treated flue gas. A first air heater in fluid communication with the emission treatment system includes a heat exchanger for heating forced air introduced thereto above a base temperature and thereby cooling emission treated flue gas from the emission treatment system to a stack discharge temperature. A second air heater in fluid communication with the first air heater to receive heated forced air therefrom includes a heat exchanger for heating forced air introduced thereto to a preheat temperature for combustion in a boiler and thereby cooling flue gas introduced from a boiler to the second air heater to an emission treatment temperature. The second air heater is in fluid communication with the emission treatment system to introduce cooled flue gas thereto.
    Type: Application
    Filed: September 25, 2009
    Publication date: March 31, 2011
    Applicant: Babcock Power Environmental Inc.
    Inventors: Richard F. Abrams, Mark Lewis, Jeffrey Penterson
  • Publication number: 20110052469
    Abstract: A system for treating an air stream exhausted from a firing kiln utilized to heat a ceramic substrates includes an outlet assembly and a thermal oxidizer. The outlet assembly may be in fluid communication with the firing kiln, and may be operational to receive an exhaust gas stream and a waste heat stream from the firing kiln. A temperature of the waste heat stream may be greater than the exhaust gas stream such that a temperature of an air stream comprising the waste heat stream and the exhaust gas stream within the outlet assembly is greater than the exhaust gas stream. The thermal oxidizer may be in fluid communication with the outlet assembly to receive the air stream and remove pollutants from the air stream.
    Type: Application
    Filed: August 25, 2010
    Publication date: March 3, 2011
    Inventors: Renee Rochelle Sewalt, Michael James Vayansky
  • Patent number: 7892507
    Abstract: The processing of gases, in particular the exhaust gas of an internal combustion/diesel engine, entails catalytically oxidizing the carbon monoxide and hydrocarbons contained therein in an oxygen-rich medium, in the presence of a metal oxidation catalyst that includes a silica-containing zirconia support.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: February 22, 2011
    Assignee: Rhodia Chimie
    Inventors: Emmanuel Rohart, Stéphan Verdier, Aimin Huang
  • Patent number: 7879758
    Abstract: A catalytically active porous element for promoting catalytic gas phase reactions is proposed, said element comprising a porous structural element of sintered ceramic or metallic primary particles, which are selected from fibrous and/or granular particles, a secondary structure of titania nano particles deposited on the surface of said sintered primary particles and a catalytic component deposited on the surface of the titania nano particles. Thereby porous catalytic elements for catalytic gas phase reactions which are useful not only in NOX reduction reactions but also for other catalytic gas phase reactions are provided.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: February 1, 2011
    Assignee: Pall Corporation
    Inventors: Steffen Heidenreich, Manfred Nacken
  • Publication number: 20100322847
    Abstract: The present invention relates to an organotemplate-free synthetic process for the production of a zeolitic material having a BEA framework structure comprising YO2 and optionally comprising X2O3, wherein said process comprises the steps of (1) preparing a mixture comprising seed crystals and at least one source for YO2; and (2) crystallizing the mixture; wherein Y is a tetravalent element, and X is a trivalent element, wherein the zeolitic material optionally comprises at least one alkali metal M, wherein when the BEA framework additionally comprises X2O3; the mixture according to step (1) comprises at least one source for X2O3, and wherein the seed crystals comprise zeolitic material having a BEA framework structure, preferably zeolite Beta.
    Type: Application
    Filed: June 18, 2009
    Publication date: December 23, 2010
    Applicant: BASF SE
    Inventors: Feng-Shou XIAO, Bin XIE, Ulrich MUELLER, Bilge YILMAZ
  • Publication number: 20100310441
    Abstract: Catalysts are provided that are capable of use at low temperatures (<80° C.) to remove volatile organic compounds (VOCs) in an enclosed space. The catalyst is combined with an adsorbent to form a catalytic article. Methods of manufacturing catalytic articles are described in which the catalyst is mixed with discrete particles of adsorbent or supported directly on the adsorbent.
    Type: Application
    Filed: June 3, 2010
    Publication date: December 9, 2010
    Applicant: BASF Corporation
    Inventors: Gerard D. Lapadula, Pascaline Tran, Dana Rehms Mooney, Mark T. Buelow
  • Publication number: 20100303696
    Abstract: A method is described for treating a gas stream containing either fuel only or both fuel and oxidant gases, such as hydrogen, nitrous oxide or a hydrocarbon gas. The gas stream is conveyed through a vacuum pumping arrangement comprising a plurality of pumping stages. Either immediately before or immediately after the final pumping stage, the steps of adding a gaseous oxidant to the gas stream and oxidising the fuel gas are performed. By treating the gas stream in this manner, the risk of uncontrolled combustion of the fuel gas can be minimised.
    Type: Application
    Filed: December 2, 2008
    Publication date: December 2, 2010
    Inventors: James Robert Smith, Gareth David Stanton
  • Publication number: 20100300984
    Abstract: Embodiments of the present disclosure relate to nanostructured carbon supported catalysts, methods of making nanostructured carbon supported catalysts, and methods of using nanostructured carbon supported catalysts.
    Type: Application
    Filed: May 27, 2010
    Publication date: December 2, 2010
    Inventors: James R. Kastner, Praveen Kolar
  • Patent number: 7837966
    Abstract: Ozone and, if necessary, water is added to an exhaust gas, such as air, containing hydrogen- and carbon-containing molecules of a pollutant. The exhaust gas is then continually flowed into one or more oxidizing reaction chamber modules. In the reaction chamber(s) the ozone- and water-containing gas is subjected to intense ultraviolet radiation (wavelength of 254 nm) to promote the formation of hydroxyl radicals to oxidize the pollutant molecules to carbon dioxide and water. The continually discharged gas is analyzed for residual ozone and hydrocarbon content and the analytical data used in feedback control of ozone addition and UV radiation intensity.
    Type: Grant
    Filed: February 23, 2005
    Date of Patent: November 23, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Kenneth B. Gross, Daniel Dziedzic, John T. Johnson
  • Patent number: 7820123
    Abstract: As a device for the purification of exhaust gas, a three-way catalyst A purifying hydrocarbon, carbon monoxide and nitrogen oxide in the vicinity of theoretical air-fuel ratio is disposed at an upstream side of the exhaust gas and an adsorption catalyst B provided with zeolite effective for the adsorption of hydrocarbon is disposed at a downstream side of the exhaust gas.
    Type: Grant
    Filed: July 15, 2008
    Date of Patent: October 26, 2010
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Takuya Ikeda, Maki Kamikubo
  • Patent number: 7811539
    Abstract: A filter device and method for using a filter device. The filter device includes a catalyst for catalyzing the reaction of organic molecules, such as an oxidation reaction, and an adsorbent for adsorbing reacted organic molecules. As a result, gaseous contaminants that include organic molecules are reacted to alter the polarity and reduce the molecular weight of the molecules. The reacted molecules are then adsorbed using an adsorbent. The filter and method are particularly useful for reacting and capturing hydrocarbons such as aliphatic hydrocarbons from an enclosed space, such as a disk drive assembly.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: October 12, 2010
    Assignee: Seagate Technology LLC
    Inventors: John S. Deeken, Paul Stasiewicz
  • Publication number: 20100247411
    Abstract: Compositions useful for treating exhaust gases contain zirconium, titanium and tungsten oxides, and optionally the oxide of an element M selected from among silicon, aluminum, iron, molybdenum, manganese, zinc, tin, and rare earths in the following mass proportions of these different elements: titanium oxide: 20%-50%; tungsten oxide: 1%-20%, M-element oxide: 1%-20%; the balance being zirconium oxide; such compositions are prepared by placing in a liquid medium a zirconium compound, a titanium compound, optionally an M-element compound and a basic compound, adding a tungsten compound to the precipitate suspension thus obtained and having a pH value ranging from 1 to 7, maturing the suspension resulting from the preceding step, and optionally separating the precipitate and calcining same.
    Type: Application
    Filed: October 19, 2007
    Publication date: September 30, 2010
    Applicants: RHODIA OPERATIONS, MAGNESIUM ELEKTRON LIMITED
    Inventors: Olivier Larcher, Emmanuel Rohart, Stephan Verdier, Heather Bradshaw, Clive Butler, Deborah Harris, Mairead Feeley, Hazel Stephenson
  • Patent number: 7797931
    Abstract: A catalyst composition is provided for use on a diesel particulate filter which facilitates the oxidation of soot from diesel engine exhaust and which generates low NO2 emissions during regeneration of the filter. The catalyst composition includes a catalytic metal comprising a platinum group metal selected from Pt, Pd, Pt—Pd, or combinations thereof, an active metal oxide component containing Cu and La; and an oxide component selected from oxides of Co, Fe, or combinations thereof. The catalyst composition includes a support selected from alumina, silica, zirconia, or combinations thereof. The catalyst composition may be provided on a diesel particulate filter by impregnating the filter with an alumina, silica or zirconia sol solution modified with glycerol and/or saccharose, impregnating the filter with a stabilizing solution, and impregnating the filter with a solution containing the catalyst metal precursor(s), the active metal oxide precursor(s) and the Co or Fe oxide(s).
    Type: Grant
    Filed: June 21, 2007
    Date of Patent: September 21, 2010
    Assignee: Ford Global Technologies, LLC
    Inventors: Alexei A Dubkov, Albert N Chigapov, Brendan Patrick Carberry
  • Patent number: 7790127
    Abstract: A method of reducing NOx in a lean burn engine exhaust stream from a hydrocarbon burning engine may be first passing the exhaust stream over a thrifted diesel oxidation catalyst that substantially completes the oxidation of carbon monoxide to carbon dioxide and the oxidation of hydrocarbons (HC) to carbon dioxide and water. Next, separate additions of ozone and ammonia or urea may be introduced to the exhaust gas stream upstream of the catalytic reduction reactor at temperatures below 250 degrees Celsius. The additions of ozone and ammonia or urea modify the exhaust gas composition to improve the performance of NOx reduction catalysts in the catalytic reduction reactor. At temperatures above 250 degrees, the ozone addition may be reduced or eliminated, while the ammonia addition can be controlled as a function of the amount of NOx in the exhaust stream and the temperature of the catalytic reduction reactor.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: September 7, 2010
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Jong H. Lee, Byong Kwon Cho
  • Patent number: 7790126
    Abstract: The invention is directed to a method for cleaning exhaust gases of a glass melting process. The raw material for production of the glass is charged to the glass furnace and molten glass is removed from the glass furnace. The exhaust gases of the glass melting process are freed of the pollutant components in a moving bed reactor system on a catalytically active adsorbent and/or absorbent. Catalyst damaging pollutant components are bound by absorption and the particulate components are adhesively removed. Catalytic removal of nitrogen is performed in the layer area adjacent to the immediate oncoming flow area of the catalyst damaging pollutant components. Other pollutant components that do not damage the catalyst, such as dioxins and furans, are removed by absorption in the layer area.
    Type: Grant
    Filed: January 12, 2006
    Date of Patent: September 7, 2010
    Inventor: Horst Grochowski
  • Patent number: 7785380
    Abstract: Method and apparatus for removing sulfur from a hydrocarbon fuel. The apparatus includes a combustion reactor (3) and a sulfur trap (4) and the combustion reactor (3) is adapted to operate with an air-to-fuel ratio below 1 and in the presence of steam. The sulfur trap (4) is located downstream the combustion reactor (3) and is adapted to remove sulfur compounds formed in the combustion reactor (3).
    Type: Grant
    Filed: February 1, 2008
    Date of Patent: August 31, 2010
    Assignee: Powercell Sweden AB
    Inventors: Bård Lindström, Per Ekdunge
  • Patent number: 7767175
    Abstract: A DPF with an SCR catalyst and a method for selectively reducing nitrogen oxides with ammonia, filtering particulates, and reducing the ignition temperature of soot on a DPF are provided. The catalyst includes a first component of copper, chromium, cobalt, nickel, manganese, iron, niobium, or mixtures thereof, a second component of cerium, a lanthanide, a mixture of lanthanides, or mixtures thereof, and a component characterized by increased surface acidity. The catalyst may also include strontium as an additional second component. The catalyst selectively reduces nitrogen oxides to nitrogen with ammonia and oxidizes soot at low temperatures. The catalyst has high hydrothermal stability.
    Type: Grant
    Filed: July 9, 2009
    Date of Patent: August 3, 2010
    Assignee: Catalytic Solutions, Inc.
    Inventors: Stephen J. Golden, Svetlana Iretskaya
  • Patent number: 7758834
    Abstract: A layered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. In one or more embodiments, the catalyst comprises three layers in conjunction with a carrier: a first layer deposited on the carrier and comprising palladium deposited on a refractory metal oxide and an oxygen storage component; a second layer deposited on the first layer and comprising rhodium deposited on a refractory metal oxide and an oxygen storage component; and a third layer deposited on the second layer and comprising palladium deposited on a refractory metal oxide.
    Type: Grant
    Filed: April 23, 2009
    Date of Patent: July 20, 2010
    Assignee: BASF Corporation
    Inventors: Shau-Lin F. Chen, Harold Rabinowitz, Jin Sakakibara, Tian Luo, Michel Deeba
  • Patent number: 7758832
    Abstract: A method of decomposing NO2 to NO in an exhaust gas of a lean-bum internal combustion engine comprises the steps of contacting an acidic metal oxide selected from the group consisting of zeolites, tungsten-doped titania, silica-titania, zirconia-titania, and mixtures of any two or more thereof with a gas mixture comprising the exhaust gas, adjusting the composition of the gas mixture, by injecting hydrocarbon therein at a rate that changes over the course of a duty cycle so that, on average over the duty cycle, the C1 hydrocarbon:nitrogen oxides ratio of the gas mixture contacting the acidic metal oxide is from 0.1 to 2.0 and passing the effluent gas directly to atmosphere optionally via first contacting the gas mixture with a hydrocarbon oxidation catalyst.
    Type: Grant
    Filed: October 10, 2005
    Date of Patent: July 20, 2010
    Assignee: Johnson Matthey Public Limited Company
    Inventors: Richard Dominic O'Sullivan, Peter Werth
  • Patent number: 7754171
    Abstract: A multilayered, three-way conversion catalyst having the capability of simultaneously catalyzing the oxidation of hydrocarbons and carbon monoxide and the reduction of nitrogen oxides is disclosed. Provided is a catalytic material of at least four layers in conjunction with a carrier, where each of the layers includes a support, at least three layers comprise a precious metal component, and at least one layer comprises an oxygen storage component (OSC). The catalytic material can further comprise a fifth layer, where at least four layers comprise a precious metal component, at least one layer comprises an oxygen storage component, and at least one layer is substantially free of an oxygen storage component.
    Type: Grant
    Filed: January 9, 2008
    Date of Patent: July 13, 2010
    Assignee: BASF Corporation
    Inventors: Shau-Lin F. Chen, Knut Wassermann, Stephan Siemund, Tian Luo, Torsten Neubauer, Jin Sakakibara, Harold Rabinowitz
  • Patent number: 7749473
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-75 having STI framework topology prepared using a tetramethylene-1,4-bis-(N-methylpyrrolidinium) dication as a structure-directing agent and its use in treating engine exhaust.
    Type: Grant
    Filed: June 1, 2007
    Date of Patent: July 6, 2010
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey Zones, Allen Burton