Oxygen Containing Patents (Class 423/277)
  • Patent number: 11718555
    Abstract: A method of forming a dissolvable part of amorphous borate includes: preparing a mixture comprising one or more boron compounds and one or more alkali compounds, at least one of the one or more boron compounds and the one or more alkali compounds being hydrous; heating the mixture to a melting temperature for a predetermined time to melt the mixture and release water from the mixture to form an anhydrous boron compound that is moldable, wherein the amount of alkali compound being selected to achieve an alkali oxide content of between about 10 to 25%; with the anhydrous boron compound at a molding temperature, molding the anhydrous boron compound in a mold; and cooling the anhydrous boron compound to form a solid.
    Type: Grant
    Filed: December 30, 2021
    Date of Patent: August 8, 2023
    Assignee: 1824930 Alberta Ltd.
    Inventors: Wesley James Wall, Adam Wall, Ray Whitaker
  • Patent number: 11196048
    Abstract: Provided is a positive electrode active material that has high output characteristics and battery capacity when used for a positive electrode of a nonaqueous electrolyte secondary battery and can inhibit gelation of positive electrode mixture paste. A method for producing the positive electrode active material is also provided. A positive electrode active material for a nonaqueous electrolyte secondary battery contains a lithium-nickel-cobalt-manganese composite oxide represented by General Formula (1): Lii+sNixCoyMnzBtM1uO2+? and having a hexagonal layered crystal structure. The lithium-nickel-cobalt-manganese composite oxide contains a secondary particle formed of a plurality of flocculated primary particles and a boron compound containing lithium present at least on part of surfaces of the primary particles. A water-soluble Li amount present on the surfaces of the primary particles is up to 0.1% by mass relative to the entire amount of the positive electrode active material.
    Type: Grant
    Filed: September 13, 2017
    Date of Patent: December 7, 2021
    Assignee: SUMITOMO METAL MINING CO., LTD.
    Inventors: Mitsuru Yamauchi, Tetsufumi Komukai
  • Patent number: 10998542
    Abstract: A positive electrode active material according to the present invention is a positive electrode active material that is used in a positive electrode for a lithium ion secondary battery. This positive electrode active material includes positive electrode active material particles A represented by Formula (A): Li?NixCoyM1(1-x-y)O2 (where 0<??1.15, 0.90<x?0.98, 0<y?0.10, and 0<(1-x-y)), and positive electrode active material particles B represented by Formula (B): Li?NiaCobM2(1-a-b)O2 (where 0<??1.15, 0.70?a?0.90, 0<b?0.20, and 0<(1-a-b)). M1 and M2 each independently represent one element or two or more elements selected from the group consisting of Li, B, Mg, Al, Fe, and Mn.
    Type: Grant
    Filed: December 26, 2017
    Date of Patent: May 4, 2021
    Assignee: Envision AESC Energy Devices Ltd.
    Inventor: Masaaki Matsuu
  • Patent number: 10947151
    Abstract: A method of forming a macrocomposite including dispersing or immersing a first material in a second material. The first material includes a stone and the second material a glass; or the first material may be glass and the second material stone. The macrcocomposite may further include metal. Preferably, the macrocomposite does not include an organic resin, an adhesive, or a polymer.
    Type: Grant
    Filed: April 20, 2017
    Date of Patent: March 16, 2021
    Assignee: Upterior, LLC
    Inventors: Agnieszka Zielinska, Anna Zielinska, Marian Klisch
  • Patent number: 10818951
    Abstract: A hydrogen fuel, sustainable, closed clean energy cycle based on green chemistry is presented for large scale implementation using a cost effective electrolytic cell. A chemical reaction between salinated (sea) or desalinated (fresh) water (H2O) and sodium (Na) metal produces hydrogen (H2) fuel and sodium hydroxide (NaOH) byproduct. The NaOH is reprocessed in a solar powered electrolytic Na metal production plant that can result in excess chlorine (Cl2) from sodium chloride (NaCl) in sea salt mixed with NaOH, used to effect freezing point lowering of seawater reactant for hydrogen generation at reduced temperatures. The method and molten salt electrolytic cell enable natural separation of NaCl from NaOH, thereby limiting excess Cl2 production. The recovered NaCl is used to produce concentrated brine solution from seawater for hydrogen generation in cold climates, or becomes converted to sodium carbonate (Na2CO3) via the Solvay process for electrolytic production of Na metal without Cl2 generation.
    Type: Grant
    Filed: May 12, 2018
    Date of Patent: October 27, 2020
    Inventor: Alvin Gabriel Stern
  • Patent number: 10662069
    Abstract: A new family of crystalline microporous metallophosphates designated AlPO-90 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation, M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-90 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for the efficient adsorption of water vapor in a variety of applications, such as adsorption heat pumps.
    Type: Grant
    Filed: June 21, 2018
    Date of Patent: May 26, 2020
    Inventors: Benjamin D. Yuhas, Kristine N. Wilson, Mark A. Miller, Mimoza Sylejmani-Rekaliu, John P. S. Mowat
  • Patent number: 10581070
    Abstract: Cathode active materials have composite particles each with a base particle having the following formula: Li?NixMyCozO2, wherein 0.95???1.5, 0.6?x?1.0, 0?y?0.5, 0?z?0.5; x+y+z=1; and M is one of Mn and Al, and coating particles coating each base particle, the coating particles having the following formula: LiaNibMncCodO2, wherein 0.95?a?1.5, 0?b?0.35, 0?c?1.0, 0?d?1.0 and b+c+d=1.
    Type: Grant
    Filed: July 28, 2017
    Date of Patent: March 3, 2020
    Assignee: Apple Inc.
    Inventors: Huiming Wu, Hongli Dai, Chi-Kai Lin, Fiona C. Strobridge
  • Patent number: 10570021
    Abstract: A new family of crystalline microporous metallophosphates designated AlPO-77 has been synthesized. These metallophosphates are represented by the empirical formula HxMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, and E is a trivalent framework element such as aluminum or gallium. The AlPO-77 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.
    Type: Grant
    Filed: July 16, 2018
    Date of Patent: February 25, 2020
    Inventors: Benjamin D. Yuhas, Melissa M. Galey, Mark A. Miller, John P. S. Mowat, Wharton Sinkler, Gregory J. Lewis, Lisa M. Knight
  • Patent number: 10537855
    Abstract: The present invention relates to a method of preparing a decadodecasil 3R (DDR) type zeolite membrane and a membrane prepared thereby, and more particularly, to a method of preparing a hydrophobic decadodecasil 3R (DDR) type zeolite membrane having a continuous out-of-plane orientation by adding a substrate on which a seed layer is formed to a silica source synthetic precursor containing a methyltropinium salt and performing a hydrothermal synthesis, and a method of capturing and removing carbon dioxide using a membrane prepared thereby.
    Type: Grant
    Filed: January 2, 2018
    Date of Patent: January 21, 2020
    Assignee: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATION
    Inventors: Jungkyu Choi, Kwan Young Lee, Eun-Joo Kim
  • Patent number: 10513440
    Abstract: A new family of crystalline microporous metallophosphates designated AlPO-85 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where M is a framework metal alkaline earth or transition metal of valence +2, such as magnesium or zinc, R is an organoammonium cation, and E is a trivalent framework element such as aluminum or gallium. The AlPO-85 compositions are characterized by a new unique ABC-6 net structure, and have catalytic properties suitable for carrying out various hydrocarbon conversion processes, as well as characteristics suitable for adsorption applications.
    Type: Grant
    Filed: July 16, 2018
    Date of Patent: December 24, 2019
    Inventors: Benjamin D. Yuhas, Melissa M. Galey, Mark A. Miller
  • Patent number: 10421664
    Abstract: Provided is a porous lithium composite phosphate-based compound containing lithium and having open pores formed in primary particles. As the open pores are formed in the primary particles themselves, a contact area between an electrolyte and the lithium composite phosphate-based compound is maximized, and low conductivity is compensated for, such that a diffusion rate of lithium ions is remarkably increased, and when the lithium composite phosphate-based compound is used as an active material of a secondary battery, the secondary battery may be charged and discharged at a high speed. Additionally, there are advantages in that an electrode density may be significantly increased in addition to the increase in the diffusion rate of the lithium ions, and charge and discharge cycle characteristics may be significantly stable.
    Type: Grant
    Filed: November 26, 2013
    Date of Patent: September 24, 2019
    Assignee: SK INNOVATION CO., LTD.
    Inventors: Min Gu Kang, Seong Ho Lee, Jung In Yeon, Kook Hyun Han, Jung Hwan Kim
  • Patent number: 10329508
    Abstract: Disclosed is a fuel additive which may remove varnish precursor species in a jet fuel. In particular, the fuel additive may be a multi-functional adsorbent which includes a 2-dimensional or 3-dimensional interconnected mesoporous or mixed micro-/mesoporous framework and a plurality of internal cavities formed in the mesoporous or mixed micro-/mesoporous framework and the internal cavities include charged sites to accommodate fuel contaminants for varnish formation, such as metal ions and heteroatomic contaminants. In addition, methods of preparing the multi-functional adsorbent and methods for removing varnish precursor species with the fuel additive are provided.
    Type: Grant
    Filed: July 25, 2014
    Date of Patent: June 25, 2019
    Assignee: Hamilton Sundstrand Corporation
    Inventors: Susanne M. Opalka, Haralambos Cordatos
  • Patent number: 10276889
    Abstract: Provided is a lithium ion secondary battery including: a positive electrode having a positive electrode active material layer disposed on a positive electrode current collector; a negative electrode having a negative electrode active material layer disposed on a negative electrode current collector; and an electrolyte solution. The positive electrode active material layer includes a positive electrode active material containing a lithium nickel composite oxide. The positive electrode contains an alkaline component by less than 1% relative to a weight of the positive electrode active material. The electrolyte solution includes an additive containing a cyclic carbonate additive with an unsaturated bond. A molar ratio of the cyclic carbonate additive with an unsaturated bond relative to a total molar amount of the additive is 78% or less.
    Type: Grant
    Filed: June 7, 2016
    Date of Patent: April 30, 2019
    Assignee: AUTOMOTIVE ENERGY SUPPLY CORPORATION
    Inventor: Takashi Nakagawa
  • Patent number: 10263244
    Abstract: Provided is a lithium metal composite oxide having a layered structure, which is particularly excellent as a positive electrode active material for batteries that are mounted on electric vehicles or hybrid vehicles. Proposed is a lithium metal composite oxide having a layered structure, which is represented by general formula Li1+x(Mn?Co?Ni?)1?xO2 (0.00?X?0.07, 0.10???0.40, 0.10???0.40, and 0.30???0.75) and has a specific surface area of more than 2.0 m2/g but 5.0 m2/g or less and has an average particle size of the primary particles/crystallite size ratio of 5.7 to 18.5.
    Type: Grant
    Filed: November 26, 2012
    Date of Patent: April 16, 2019
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Tetsuya Mitsumoto, Yasuhiro Ochi, Tomohiro Sakata, Hitohiko Ide, Yoshimi Hata, Shinya Kagei
  • Patent number: 9908782
    Abstract: Methods of preparing boron suboxide are provided herein. In some embodiments, a method for preparing boron suboxide may include loading elemental boron powder into a furnace; purging the furnace by flowing a first gas comprising one of nitrogen or an inert gas into the furnace; heating the boron powder in a reactive atmosphere comprising a mixture of argon and a non-reducing oxygen-containing gas to convert elemental boron powder into boron suboxide powder, wherein the amount of oxygen in the reactive atmosphere is no greater than about 1%.
    Type: Grant
    Filed: February 14, 2013
    Date of Patent: March 6, 2018
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: Robert J. Pavlacka, Gary A. Gilde
  • Patent number: 9868642
    Abstract: A process for synthesizing a DDR framework-type molecular sieve comprises crystallizing a reaction mixture comprising water, a source of silicon, and a structure directing agent, Q, selected from the group consisting of a methyltropinium salt, a 2,6,N,N-tetramethylpiperidinium salt, a 2,N,N-trimethylpiperidinium salt and mixtures thereof, wherein the reaction mixture has a molar ratio of water to silicon from 5 to 80 and a molar ratio of alkali or alkaline earth metal, M, to silicon less than 0.01.
    Type: Grant
    Filed: October 22, 2015
    Date of Patent: January 16, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Allen W. Burton, Eugene Terefenko
  • Patent number: 9768446
    Abstract: This invention provides a method for producing a non-aqueous electrolyte secondary battery. The method comprises constructing a battery cell that comprises a positive electrode comprising a positive electrode active material, a negative electrode comprising a negative electrode active material, and a non-aqueous electrolyte solution comprising a non-aqueous solvent and an oxalatoborate-based compound. The method further comprises charging the battery cell to form on the negative electrode a layer that is derived from the oxalatoborate-based compound and comprises boron and oxalate ions. The method further comprises carrying out a modification treatment to increase the ratio of number of moles mB of boron to number of moles mA of oxalate ions in the layer.
    Type: Grant
    Filed: April 30, 2013
    Date of Patent: September 19, 2017
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroki Nagai, Takumi Tamaki, Hiroshi Onizuka
  • Patent number: 9755223
    Abstract: In a treatment process for a positive electrode active material for a lithium-ion secondary battery, Li compounds such as Li2CO3, LiOH, and the like, present in a positive electrode active material for a lithium-ion secondary battery but unsuitable for a positive electrode material, is removed. In a case wherein the resultant Li compound is used as a positive electrode material of the secondary battery, a discharge capacity and an average discharge voltage of the secondary battery do not decline, and gelation caused by a cleaning treatment is prevented. The positive electrode active material is cleaned with a cleaning fluid containing NH3, and then solid-liquid separation is performed, and a solid component is calcined at 600 to 700° C. in an oxygen atmosphere. The cleaning fluid has a conductivity of 11.6 mS/cm or less, and contains a recovered liquid component and may be repeatedly used as a cleaning fluid.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: September 5, 2017
    Assignee: NIHONKAGAKUSANGYO CO., LTD.
    Inventors: Kazuhiro Hamada, Yoshito Sugibuchi, Hajime Kashima
  • Patent number: 9718051
    Abstract: The present invention is directed to an alumino-borosilicate SSZ-57 zeolite having enhanced large pore selectivity. The alumino-borosilicate SSZ-57 zeolite of the present invention is characterized as having substantially all of its aluminum atoms located within regions of the zeolite structure which form the 12 ring channels.
    Type: Grant
    Filed: February 25, 2014
    Date of Patent: August 1, 2017
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey Ian Zones, Cong-Yan Chen, Annabelle Benin
  • Patent number: 9637692
    Abstract: The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: May 2, 2017
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Yoshiyuki Nagayasu, Kazuaki Hayasaka, Hideki Ono, Takaya Matsumoto
  • Patent number: 9598650
    Abstract: The hydroisomerization catalyst of the present invention is a catalyst used for hydroisomerization of a hydrocarbon, including a support including a calcined zeolite modified with at least one metal selected from the group consisting of Na, K, Cs, Mg, Ca, Ba, and K, and having a thermal history that includes heating at 350° C. or more, and at least one inorganic oxide selected from the group consisting of alumina, silica, titania, boria, zirconia, magnesia, ceria, zinc oxide, phosphorus oxide, and a composite oxide containing a combination of at least two or more of these oxides; and at least one metal supported on the support and selected from the group consisting of elements belonging to Groups 8 to 10 of the periodic table, molybdenum and tungsten.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: March 21, 2017
    Assignee: JX NIPPON OIL & ENERGY CORPORATION
    Inventors: Yoshiyuki Nagayasu, Kazuaki Hayasaka, Hideki Ono, Takaya Matsumoto
  • Patent number: 9553312
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery that has a uniform particle size and high packing density, and that is capable of increased battery capacity and improved coulomb efficiency. When producing a nickel composite hydroxide that is a precursor to the cathode active material by supplying an aqueous solution that includes at least a nickel salt, a neutralizing agent and a complexing agent into a reaction vessel while stirring and performing a crystallization reaction, a nickel composite hydroxide slurry is obtained while controlling the ratio of the average particle size per volume of secondary particles of nickel composite hydroxide that is generated inside the reaction vessel with respect to the average particle size per volume of secondary particles of nickel composite hydroxide that is finally obtained so as to be 0.2 to 0.
    Type: Grant
    Filed: February 22, 2013
    Date of Patent: January 24, 2017
    Assignee: SUMITOMO METAL MINING CO., LTD
    Inventors: Mitsuru Yamauchi, Kazuomi Ryoshi, Kensaku Mori
  • Patent number: 9045623
    Abstract: A method of forming boron nitride nanoparticles. A plurality of precursor molecules comprising boron, nitrogen and hydrogen may be decomposed in a first heating zone to form a plurality of gaseous molecules that contain bonded boron and nitrogen, followed by heating to a second, higher temperature thereby causing the gaseous molecules to react and nucleate to form a plurality of boron nitride nanoparticles. Depending on processing temperatures, the boron nitride nanoparticles may include amorphous forms, crystalline forms, or combinations thereof. Precursor molecules may include ammonia borane, borazine, cycloborazanes, polyaminoborane, polyiminoborane, and mixtures thereof. The boron nitride nanoparticles may be incorporated into a variety of dispersions, composites, and coatings; and in one embodiment, may be a component of a propellant, wherein the boron nitride nanoparticles may confer a range of advantages to gun barrels in which such propellants may be fired.
    Type: Grant
    Filed: October 10, 2012
    Date of Patent: June 2, 2015
    Assignee: PH MATTER, LLC
    Inventors: Paul H. Matter, Christopher T. Holt, Michael G. Beachy
  • Patent number: 8962517
    Abstract: Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons. Related methods for use and manufacture of the same are also disclosed.
    Type: Grant
    Filed: November 29, 2012
    Date of Patent: February 24, 2015
    Assignee: Siluria Technologies, Inc.
    Inventors: Fabio R. Zurcher, Erik C. Scher, Joel M. Cizeron, Wayne P. Schammel, Alex Tkachenko, Joel Gamoras, Dmitry Karshtedt, Greg Nyce, Anja Rumplecker, Jarod McCormick, Anna Merzlyak, Marian Alcid, Daniel Rosenberg, Erik-Jan Ras
  • Patent number: 8946452
    Abstract: A crystalline, completely soluble lithium bis(oxalato)horate (LiBOB), to a method for producing the same and to the use of the lithium bis(oxalato)borate.
    Type: Grant
    Filed: January 9, 2013
    Date of Patent: February 3, 2015
    Assignee: Chemetall GmbH
    Inventors: Rainer Dietz, Ulrich Wietelmann, Uwe Lischka, Thorsten Buhrmester, Klaus Schade
  • Patent number: 8936776
    Abstract: A new family of crystalline microporous metallophosphates designated AlPO-67 has been synthesized. These metallophosphates are represented by the empirical formula R+rMm2+EPxSiyOz where R is an organoammonium cation such as the ETMA+ or DEDMA+, M is a framework metal alkaline earth or transition metal of valence 2+, and E is a trivalent framework element such as aluminum or gallium. The AlPO-67 compositions exhibit the LEV framework topology and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: January 20, 2015
    Assignee: UOP LLC
    Inventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
  • Patent number: 8932545
    Abstract: A method is provided for the synthesis of a mesoporous lithium transition metal compound, the method comprising the steps of (i) reacting a lithium salt with one or more transition metal salts in the presence of a surfactant, the surfactant being present in an amount sufficient to form a liquid crystal phase in the reaction mixture (ii) heating the reaction mixture so as to form a sol-gel and (iii) removing the surfactant to leave a mesoporous product. The mesoporous product can be an oxide, a phosphate, a borate or a silicate and optionally, an additional phosphate, borate or silicate reagent can be added at step (i). The reaction mixture can comprise an optional chelating agent and preferably, the reaction conditions at steps (i) and (ii) are controlled so as to prevent destabilization of the liquid crystal phase. The invention is particularly suitable for producing mesoporous lithium cobalt oxide and lithium iron phosphate.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: January 13, 2015
    Assignee: Qinetiq Limited
    Inventors: Gary Owen Mepsted, Emmanuel Imasuen Eweka
  • Publication number: 20140332785
    Abstract: A method of preparing an organic light-emitting device having excellent sealing characteristics against external environment and flexibility.
    Type: Application
    Filed: July 25, 2014
    Publication date: November 13, 2014
    Inventor: Jin-Woo Park
  • Patent number: 8871178
    Abstract: A new family of crystalline microporous metallophosphates designated AlPO-57 has been synthesized. These metallophosphates are represented by the empirical formula R+rMmn+EPxSiyOz where R is an organoammonium cation such as the DEDMA+, M is a divalent framework metal such as an alkaline earth or transition metal, and E is a framework element such as aluminum or gallium. The microporous AlPO-57 compositions are characterized by a new unique ABC-6 net structure and have catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.
    Type: Grant
    Filed: June 29, 2012
    Date of Patent: October 28, 2014
    Assignee: UOP LLC
    Inventors: Gregory J. Lewis, Lisa M. Knight, Paulina Jakubczak, Justin E. Stanczyk
  • Publication number: 20140252268
    Abstract: Provided is a new 5 V class spinel exhibiting an operating potential of 4.5 V or higher (5 V class) with respect to the Li metal reference potential, having an excellent discharge capacity retention ratio at high temperatures (for example, 45° C.). Suggested is a spinel type lithium-manganese-nickel-containing composite oxide containing a crystalline phase in which a portion of Mn sites in LiMn2O4-? are substituted with Li; another metal element M1 including Ni (here, the M1 represents a metal element including at least one of Ni, Co and Fe), and another metal element M2 (here, the M2 represents a metal element including at least one of Mg, Ti, Al, Ba, Cr and Nb), and the spinel type lithium-manganese-nickel-containing composite oxide comprising a composite oxide phase containing Ni, Mn and B.
    Type: Application
    Filed: August 26, 2013
    Publication date: September 11, 2014
    Inventors: Shinya Kagei, Natsumi Shibamura, Yanko Marinov Todorov, Yoshima Hata
  • Patent number: 8753601
    Abstract: Described is a method for the production of metal salts, wherein the cationic metal is preferably selected from Group I to IV metals and mixtures thereof and the anionic group is selected from phosphates, silicates, sulfates, carbonates, hydroxides, fluorides and mixtures thereof, and wherein said method comprises forming a mixture of at least one metal source that is a metal carboxylate with a mean carbon value per carboxylate group of at least 3 and at least one anion source into droplets and oxiding said droplets in a high temperature environment, preferably a flame. This method is especially suited for the production of calcium phosphate biomaterials such as hydroxyapatite (HAp,Ca10(PO4)6(OH)2) and tricalcium phosphate (TCP,Ca3(PO4)2) that exhibit excellent biocompatibility and osteoconductivity and therefore are widely used for reparation of bony or periodontal defects, coating of metallic implants and bone space fillers.
    Type: Grant
    Filed: December 6, 2010
    Date of Patent: June 17, 2014
    Assignee: Eidgenossische Technische Hochschule Zurich
    Inventors: Wendelin Jan Stark, Sotiris-Emmanuel Pratsinis, Marek Maciejewski, Stefan Fridolin Loher, Alfons Baiker
  • Publication number: 20140151997
    Abstract: Luminescent borates, luminescent materials, and articles incorporating such borates are provided herein. An embodiment of a luminescent borate includes a host borate that has a B9O16-comprising crystal lattice. Neodymium and/or ytterbium are present within the host borate, and one or more substitutable elements are optionally present along with the neodymium and/or ytterbium within the host borate. The one or more substitutable elements are different from neodymium and ytterbium.
    Type: Application
    Filed: March 14, 2013
    Publication date: June 5, 2014
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventors: James Kane, Carsten Lau, William Ross Rapoport
  • Patent number: 8741250
    Abstract: The present invention relates to a synthetic method for producing a per-hydroxylated icosahedral boron compound via catalytic hydroxylation of icosahedral boron compound using a soft electrophile.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: June 3, 2014
    Assignee: The Curators of the University of Missouri
    Inventors: M. Frederick Hawthorne, Oleg Bondarev
  • Publication number: 20140138583
    Abstract: The present invention provides a fluorescent substance excellent both in quantum efficiency and in temperature characteristics, and also provides a light-emitting device utilizing the fluorescent substance. This fluorescent substance contains an inorganic compound comprising a metal element M, a trivalent element M1 other than the metal element M, a tetravalent element M2 other than the metal element M, and either or both of O and N. In the inorganic compound, the metal element M is partly replaced with a luminescence center element R. The crystal structure of the fluorescent substance is basically the same as Sr3Al3Si13O2N21, but the chemical bond lengths of M1-N and M2-N are within the range of ±15% based on those of Al—N and Si—N calculated from the lattice constants and atomic coordinates of Sr3Al3Si13O2N21, respectively. The fluorescent substance emits luminescence having a peak in the range of 490 to 580 nm when excited with light of 250 to 500 nm.
    Type: Application
    Filed: January 23, 2014
    Publication date: May 22, 2014
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Yumi FUKUDA, Hironori ASAI
  • Publication number: 20140133014
    Abstract: The present invention relates to a borate birefringent crystal applicable to ultraviolet (UV) or deep ultraviolet (DUV) range, with chemical formula of Ba2Mg(B3O6)2. The borate birefringent crystal belongs to a trigonal system, with space group of R-3 wherein a=0.70528(3) nm, c=1.65520(9) nm and Z=12. The barium magnesium borate birefringent crystal is negative uniaxial (ne<no) with a birefringence of 0.077-0.229 and a transmission range of 177-3000 nm. The crystal is easy to cut, grind, polish, and preserve, and is stable in air and is not easy to deliquesce. The barium magnesium borate birefringent crystal can be grown by the Czochralski method, flux method or the method of spontaneous crystallization from a melt, and has larger birefringence (no?ne=0.077-0.229). The crystal has important applications in the fields of optics and communications, e.g. for fabricating the polarizing beam splitter prism.
    Type: Application
    Filed: February 17, 2012
    Publication date: May 15, 2014
    Inventors: Rukang Li, Yingying Ma
  • Patent number: 8691169
    Abstract: It is possible to produce battery grade metallic lithium from naturally occurring or industrial brine by a process comprising the following steps: (i) precipitating magnesium with calcium hydroxide; (ii) removal of boron via extraction of solvents; (iii) precipitation of lithium with sodium carbonate; (iv) transformation of lithium carbonate to bicarbonate of lithium with carbonic acid; (v) decomposition of bicarbonate of lithium into high purity lithium carbonate as a result of heating of the solution. Re-precipitation of lithium carbonate by the formation of bicarbonate of lithium allows for the removal of the majority of contaminants which co-purify with lithium carbonate and yield battery grade highly purified lithium carbonate.
    Type: Grant
    Filed: September 26, 2012
    Date of Patent: April 8, 2014
    Inventors: Waldo Perez, Hugo Adan Carlos Barrientos, Claudio Suarez, Marcelo Bravo
  • Publication number: 20140050646
    Abstract: B3NO3 of the present invention has a rock salt type crystal structure to thereby have a bulk modulus higher than that of c-BN.
    Type: Application
    Filed: August 15, 2012
    Publication date: February 20, 2014
    Applicant: Sumitomo Electric Industries, Ltd.
    Inventor: Akitaka SAWAMURA
  • Patent number: 8609054
    Abstract: A method of forming hydrogen gas comprises the steps of providing a reactor and providing a hydrogen-generating composition to the reactor. The hydrogen-generating composition consists essentially of a borohydride component and a glycerol component. The borohydride, e.g. sodium borohydride, and glycerol components are present in a generally three (3) to four (4) stoichiometric ratio, prior to reaction. The borohydride component has hydrogen atoms and the glycerol component has hydroxyl groups with hydrogen atoms. The method further comprises the step of reacting the borohydride component with the glycerol component thereby converting substantially all of the hydrogen atoms present in the borohydride component and substantially all of the hydrogen atoms present in the hydroxyl groups of the glycerol component to form the hydrogen gas. The reaction between the borohydride component and the glycerol component is an alcoholysis reaction.
    Type: Grant
    Filed: May 19, 2008
    Date of Patent: December 17, 2013
    Assignee: EnerFuel, Inc.
    Inventors: Vesna Stanic, Daniel Augusto Betts Carrington
  • Patent number: 8557449
    Abstract: An air cathode for a metal-air battery is disclosed which contains a catalyst chosen to make the metal air battery more easily rechargeable. This catalyst is based on cobalt phosphate, cobalt borate mixed metal cobalt phosphates, mixed metal cobalt borates, or mixed metal cobalt phosphate borates.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: October 15, 2013
    Inventors: Wilson Hago, Ivan Marc Lorkovic
  • Patent number: 8557209
    Abstract: A method for cyclically preparing elemental boron and coproducing sodium cryolite using sodium fluoborate as an intermediate material, which includes the following steps: A) adding hydrofluoric acid to boric acid or boron oxide to enable a reaction to form fluoboric acid; B) adding a sodium carbonate aqueous solution to the fluoboric acid to enable a reaction to form the sodium fluoborate; C) putting the sodium fluoborate into a reactor, adding aluminum to react with the sodium fluoborate to form the elemental boron and sodium cryolite; D) extracting the sodium cryolite, sending the sodium cryolite to a rotary reaction kettle together with concentrated sulphuric acid to enable a reaction to form hydrogen fluoride gas and aluminum sodium sulphate, collecting the hydrogen fluoride gas and dissolving it into water to obtain the hydrofluoric acid; E) recycling the obtained hydrofluoric acid to Step A to leach the boric acid or boron oxide.
    Type: Grant
    Filed: December 9, 2012
    Date of Patent: October 15, 2013
    Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.
    Inventors: Xuemin Chen, Yueming Yu, Qingdong Ye, Jun Yang, Zhi Zhou
  • Publication number: 20130264482
    Abstract: Provided is a scintillator for neutrons that allows the detection of neutrons with superb sensitivity and that is little affected by background noise derived from ?-rays, and a neutron detector that uses the neutron scintillator. The scintillator for neutrons comprises borate that contains at least Mg and a divalent transition element.
    Type: Application
    Filed: December 15, 2011
    Publication date: October 10, 2013
    Inventors: Hisanori Yamane, Tetsuya Kawano, Akira Yoshikawa, Takayuki Yanagida, Yui Yokota, Yutaka Fujimoto, Kentaro Fukuda, Noriaki Kawaguchi
  • Patent number: 8545785
    Abstract: The present invention provides a barium fluoroborate compound, a nonlinear optical crystal and the preparation method and use thereof. Both of the barium fluoroborate compound and the nonlinear optical crystal have a chemical formula of Ba4B11O20F. The crystal belongs to orthorhombic crystal system, has a space group Cmc21 with unit cell parameters of a=18.802(3) ?, b=10.7143(19) ?, c=8.6113(14) ?, V=1734.7(5) ?3. The crystal has a powder second harmonic generation efficiency of 10 times that of KDP (KH2PO4). The ultraviolet cutoff wavelength is about 170 nm. The barium fluoroborate compound is prepared by a solid-state reaction. The barium fluoroborate nonlinear optical crystal prepared by a high temperature melting liquid method has large hardness and is easy to be cut, polished and stored. This crystal can be used widely in preparing the nonlinear optical devices of the second harmonic generator, the up frequency converter, the down frequency converter or the optical parametric oscillator or the like.
    Type: Grant
    Filed: January 12, 2011
    Date of Patent: October 1, 2013
    Assignee: The XInjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences
    Inventors: Shilie Pan, Hongping Wu, Xueling Hou
  • Publication number: 20130243920
    Abstract: Disclosed is a process and composition for teeth bleaching and color maintenance made up of a solution added to beverages (coffee, tea, wine, sodas). The method and composition offers and option to start breaking down stains prior to penetration in o the tooth enamel. The purpose of this invention is to provide a way to eliminate or reduce the staining effect from beverages such as coffee, tea, wine, juices and sodas. The mixture will include an oxygen releasing agent which may include infusion of oxygen gas, and/or solutions of sodium perborate, carbamide peroxide, chlorine dioxide, or hydrogen peroxide. The mixture is dispensed into drinks that can stain teeth.
    Type: Application
    Filed: March 19, 2012
    Publication date: September 19, 2013
    Inventor: Dino Shahrier Javaheri
  • Patent number: 8497374
    Abstract: A synthetic process for producing bortezomib comprising converting racemic boronic esters, such as the pinacol ?-aminoboronic ester, into mixtures of diastereomers [6] by reaction with a suitably protected L-phenylalanine derivative (see Scheme 3), such as N—BOC-L-phenylalanine. The protecting group of the L-phenylalanine moiety is then removed, such as by reacting the diastereomers [6] with an acid, such as hydrochloric acid, to form a mixture of amine salt diastereomers [7] which is then subjected to conditions under which the desired diastereomer (R,S)-[7] is selectively isolated, such as by crystallization, chromatography or stereoselective hydrolysis. The separated desired diastereomer (R,S)-[7] is then converted into bortezomib or bortezomib anhydride.
    Type: Grant
    Filed: May 12, 2011
    Date of Patent: July 30, 2013
    Assignee: Scinopharm Taiwan, Ltd.
    Inventors: Julian Paul Henschke, Aiping Xie, Xin Yan Huang, Yung Fa Chen
  • Publication number: 20130165728
    Abstract: Nanowires useful as heterogeneous catalysts are provided. The nanowire catalysts are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane to C2 hydrocarbons. Related methods for use and manufacture of the same are also disclosed.
    Type: Application
    Filed: November 29, 2012
    Publication date: June 27, 2013
    Applicant: SILURIA TECHNOLOGIES, INC.
    Inventor: Siluria Technologies, Inc.
  • Patent number: 8465780
    Abstract: The specification discloses a borate microemulsion product. In one embodiment, the borate microemulsion includes from about 24 to about 32 weight percent emulsified sodium pentaborate; and from about 24 to about 32 weight percent particulate boric acid suspended therein. The microemulsion has a density of about 9.5 to about 10.5 pounds per gallon at about room temperature. In certain embodiments, the microemulsion has a viscosity of about 1200 to about 1520 at a temperature of from about 66° F. to about 70° F. In certain other embodiments, microemulsion has a viscosity of about 1000 to about 3000 at a temperature of from about 70° F. to about 75° F.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: June 18, 2013
    Assignee: Nisus Corporation
    Inventor: Jeffrey Douglas Lloyd
  • Publication number: 20130115751
    Abstract: A composition includes a boron-containing hydrogen silsesquioxane polymer having a structure that includes: silicon-oxygen-silicon units, and oxygen-boron-oxygen linkages in which the boron is trivalent, wherein two silicon-oxygen-silicon units are covalently bound by an oxygen-boron-oxygen linkage therebetween.
    Type: Application
    Filed: January 2, 2013
    Publication date: May 9, 2013
    Applicant: CHEIL INDUSTRIES, INC.
    Inventor: CHEIL INDUSTRIES, INC.
  • Publication number: 20130099174
    Abstract: The present invention generally relates to certain lithium materials, including lithium manganese borate materials. Such materials are of interest in various applications such as energy storage. Certain aspects of the invention are directed to lithium manganese borate materials, for example, having the formula LixMny(BO3). In some cases, the lithium manganese borate materials may include other elements, such as iron, magnesium, copper, zinc, calcium, etc. The lithium manganese borate materials, according to one set of embodiments, may be present as a monoclinic crystal system. Such materials may surprisingly exhibit relatively high energy storage capacities, for example, at least about 96 mA h/g. Other aspects of the invention relate to devices comprising such materials, methods of making such materials, kits for making such materials, methods of promoting the making or use of such materials, and the like.
    Type: Application
    Filed: May 5, 2011
    Publication date: April 25, 2013
    Applicant: MASSACHUSETTS INSTITUTE OF TECHNOLOGY
    Inventors: Gerbrand Ceder, Jae Chul Kim, ByoungWoo Kang, Charles J. Moore, Geoffroy Hautier
  • Patent number: 8415000
    Abstract: Stabilized precursor solutions can be used to form radiation inorganic coating materials. The precursor solutions generally comprise metal suboxide cations, peroxide-based ligands and polyatomic anions. Design of the precursor solutions can be performed to achieve a high level of stability of the precursor solutions. The resulting coating materials can be designed for patterning with a selected radiation, such as ultraviolet light, x-ray radiation or electron beam radiation. The radiation patterned coating material can have a high contrast with respect to material properties, such that development of a latent image can be successful to form lines with very low line-width roughness and adjacent structures with a very small pitch.
    Type: Grant
    Filed: October 28, 2011
    Date of Patent: April 9, 2013
    Assignee: Inpria Corporation
    Inventors: Jason K. Stowers, Alan J. Telecky, Douglas A. Keszler, Andrew Grenville
  • Publication number: 20130078175
    Abstract: The present invention relates to a synthetic method for producing a per-hydroxylated icosahedral boron compound via catalytic hydroxylation of icosahedral boron compound using a soft electrophile.
    Type: Application
    Filed: November 14, 2012
    Publication date: March 28, 2013
    Applicant: THE CURATORS OF THE UNIVERSITY OF MISSOURI
    Inventors: M. Frederick Hawthorne, Oleg Bondarev