Abstract: A process for cleaning process gas removes sulfur oxides (SOx), nitrogen oxides (NOx), and particulate matter (PM) to produce a tail gas substantially free of these pollutants. The process oxidizes and absorbs SOx and NOx for storage as liquid acids. In some embodiments a PM removal stage and/or a SOx removal stage are provided in a close-coupled higher-pressure environment upstream from a turbocharger turbine. The process has example application in cleaning exhaust gases from industrial processes and large diesel engines such as ship engines.
Abstract: Carbon monoxide and carbonyl sulfide emissions are reduced in manufacturing processes, including titanium tetrachloride production processes. Gas is contacted with CO, COS, and an oxygen-containing gas with a suitable catalyst. The catalyst may be a metal oxide catalyst containing bismuth, cobalt and nickel, a xerogel or aerogel catalyst containing Au, Rh, Ru and Co in aluminum oxide/oxyhydroxide matrices, or a supported metal catalyst that contains at least one metal from the group Pd, Rh, Ru and Cu. In the latter case, the catalyst support is contains alumina or carbon. A catalyst composite of Au, Rh, Ru and Cr, and cerium oxide and lanthanum oxide may also be used.
Type:
Grant
Filed:
June 16, 2003
Date of Patent:
August 28, 2007
Assignee:
E.I. du Pont de Nemours and Company
Inventors:
Dale Robert Coulson, Norman Herron, Kostantinos Kourtakis, Stephen E. Lyke
Abstract: A process for treating a dust containing, gaseous or liquid feed stream in a reactor containing a plurality of particle beds, which have the capability, once the pressure drop across a bed has reached a maximum allowable level, to distribute most of the feed stream to a point directly upstream of each of the subsequent beds in a series, stepwise manner. The beds contain particles in the form of pellets, cylinders, granules, rings, or mixtures thereof, and at the end of an operation period, the primary fraction of the feed flow is directed through the downstream-most bed in the reactor. By providing for removal of dust in each of the beds, the process enables the reactor to operate with a conventional pressure drop profile, but for an extended on-stream period of time.
Abstract: A catalyst for reacting SO2 with molecular oxygen to form SO3 is suited for a continuous operation at temperatures of 700° C. and above, when the same consists of a carrier and an active component connected with the carrier, the active component consists of 10 to 80 wt-% iron, the carrier has a BET surface of 100 to 2000 m2/g and an SiO2 content of at least 90 wt-%, and the weight ratio carrier:active component is 1:1 to 100:1.
Type:
Grant
Filed:
October 12, 2000
Date of Patent:
December 31, 2002
Assignee:
Metallgesellschaft Aktiengesellschaft
Inventors:
Egon Winkler, Georg Schmidt, Achim Hollnagel, Dietrich Werner, Nikola Anastasijevic, Franz-Ferdinand Schüth, Anette Wingen
Abstract: Reactor pressure vessel with reactant fluid injectors for forming a liquid environment of an oxygen carrier fluid, sulphur and water in the presence of a catalyst to yield sulphuric acid and heat exchangers to capture generated heat.
Type:
Grant
Filed:
April 17, 1978
Date of Patent:
January 29, 1980
Inventors:
Xerxes T. Stoddard, Vasper A. Vaseen, Ruel C. Terry
Abstract: Novel processes for converting sulfurous anhydride to sulfuric anhydride and vice versa, which processes are carried out in the gaseous phase with a catalyst comprising iron, copper, and at least one alkali metal selected from among sodium and potassium, the catalyst simultaneously having good activity at 600.degree. C. and withstanding temperatures up to 850.degree. C. without degradation.