Abstract: A monovalent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with an organic hydroperoxide in the presence of a Group VIII noble metal catalyst in a liquid medium and in the presence of a promoter comprising a member selected from the group consisting of alkali metal compounds and heterocyclic tertiary amines, to oxidize the thallium (I) compound to a thallium (III) compound.

Abstract: A monovalent thallium compound is converted to a trivalent thallium compound by treating the thallium (I) compound with molecular oxygen in the presence of a Group VIII noble metal catalyst to oxidize the thallium (I) compound to a thallium (III) compound.

Abstract: A method of increasing to a predetermined value the pressure exerted on materials treated in high pressure chambers. A first pressure-exerting force is used to act on the material throughout the entire treatment process and a second pressure-exerting force is used to act on a limited amount of a pressure compensating medium. The two pressure-exerting forces are interdependent whereby any tendency to change of the pressure exerted on the material inside the pressure chamber automatically brings about a proportional change of the pressure of the compensating medium, whereby the pressure in the high-pressure chamber is maintained at the desired level. The method is primarily but not exclusively intended for the production of synthetic diamonds.

Abstract: A hydrated metal salt is dehydrated to its anhydrous form by dissolving the metal salt hydrate in an organic solvent; and contacting the solvent solution of metal salt hydrate with a molecular sieve of a pore size sufficient to permit the absorption of water molecules but of a size too small to absorb solvent molecules.

Abstract: During use of a contact apparatus to remove harmful components, such as sulfur and nitrogen oxides, from waste gas, dust particles are deposited on the interior of the gas-solid contact zone and reduce efficiency of the apparatus. The dust particles can be removed by passing through the contact apparatus a current of a carrier gas supporting solid particles of, for example, siliceous sand. The particles have a diameter of 50 to 2000 .mu.m and the actual linear velocity of the carrier gas in the gas-solid contact zone is from 2 to 15 m/sec. The carrier gas can be the waste gas itself so that dust removal can be carried out without interrupting use of the apparatus. The solid particles can be removed from the carrier gas and recycled for further dust removal.

Abstract: Sulfur compounds contained in fuel gases produced from the gasification of coal or petroleum residua area removed at about 1600.degree. F temperature by contacting the gas with an absorbent material comprising a strong, macroporous particulate solid support containing molten metal carbonate, such as potassium carbonate, within its pores. Following such contacting and reaction of the sulfur compounds in the hot gas with the supported metal carbonate absorbent, it is regenerated by being contacted at high temperatures with steam and CO.sub.2 to remove the sulfur, which is recovered as H.sub.2 S. The metal carbonate absorbent material is reused by again contacting it with the hot fuel gas for sulfur removal, after which the sulfur-free fuel gas is burned in a combustion process such as a gas turbine to produce power.

Abstract: A solid, particulate reactant is continuously added to a first zone and a liquid reactant is continuously added to a second zone. A conduit between the zones allows the solid and liquid reactants to pass counter-currently between the zones, the reaction being accomplished on contact between the reactants. During steady state operation, a clear layer is established in each zone above a slurry layer of the particles in solution. The clear layer is withdrawn from the top of each zone and introduced at the bottom thereof causing agitation in the slurry layer which promotes the reaction. The solid reactant is withdrawn from the second zone while the spent liquid reactant is withdrawn from the first zone.

Abstract: A process of reacting finely divided material in a fluidized bed supported by a circular grate in relative circular motion with regard to a cell enclosing an auxiliary bed which has a bottom in free communication with the main fluidized bed and which is in hydrostatic equilibrium with the latter, whereby slag settled on the grate is sorted and extracted.

Abstract: Endothermic processes are carried out in a fluidized-bed reactor which is connected to a holding reactor, solids being recirculated between the two reactors. The primary fluidized-bed reactor uses a fast-fluidized bed system in which the solids concentration decreases continuously from the bottom to the top of the reactor. After the necessary residence time in the holding reactor, solids are discharged. Solids are entrained with the gas stream from the primary reactor and are separated therefrom to be delivered to the holding reactor. The reaction is controlled by regulating the rate of recirculation of solids from the holding reactor to the fast fluidized bed reactor.

Abstract: In the recovery of chlorine from iron chloride by causing reaction between an oxidizing gas and a gas containing iron chloride as the predominant constituent within an oxidation furnace, the initial meeting of the two reacting gases is caused to take place in an unobstructed space within the furnace, the oxygen being injected into the furnace in directions and at a velocity such that the resulting turbulent flow due to the initial collision of the two gases will not reach the furnace wall, whereby depositing of Fe.sub.2 O.sub.3 on the furnace wall is reduced to a minimum.

Abstract: Process and apparatus for incinerating contaminated salt-bearing solutions in a fluidized bed to which streams of solution, of fuel required for incineration and of combustion air are injected and the quantities of these streams and the quantity of the fluidized bed material are adjusted to safeguard incomplete combustion in the fluidized bed, to maintain the temperature of the bed below the fusion temperature of the salt and to achieve a post-combustion temperature of 800.degree. C and more of the gas emanating from the fluidized bed and reaching the free space above the bed, i.e. the afterburner.

Abstract: A process for the production of reducing gases and apparatus for use therein is provided. A unique gas mixer and reactor is provided which can be used to effect substoichiometric reactions of gaseous reactants to produce a hydrogen rich gas. The gases which are to be reduced are then admixed with the hydrogen rich gas and the gaseous mixture is passed to a catalytic reactor where the reduction reaction takes place.

Abstract: Movable means are provided interiorly of a rotating confined line on a substantially horizontal plane through which reactant fluids, such as liquids and gases, flow and react, whereby inherently to inhibit the adherence of particulate matter within the line and effect enhanced contact and intermingling of the liquid maintained in the form of a pool therein with the gas during rotation of the line.The movable means comprise relatively solid objects which bounce and tumble within the line to contact the interior of the line. The relatively solid objects, which may be in the form of chains, wires, cables or any other solid media whether consisting of separate or joined components, also function to prevent the liquid, maintained in the pool and/or passing through the line from assuming a dry or precipitate state as it is splashed or otherwise distributed about the entire interior periphery of the line.

Abstract: A fluid-wall reactor for high temperature chemical reactions comprising (A) a porous reactor tube, at least a portion of the interior of which defines a reaction zone, the tube being made of an electrically resistive, porous refractory material; (B) a pressure vessel enclosing the reactor tube to define an inert fluid plenum, the pressure vessel having at least one inlet for admitting the inert fluid which is directed under pressure through the porous tube wall to provide a protective blanket for the inside surface of the reactor tube; (C) means for introducing at least one reactant into the reaction zone, the reactants being directed in a predetermined path axially of the reactor tube and being confined by the protective blanket substantially centrally within the reaction zone; (D) means for passing an electric current through the reactor tube for heating the reactor tube to the temperature level at which it emits sufficient radiant energy to initiate and sustain the desired chemical reaction, the radiant en

Abstract: The present invention is a controllable gas generator which includes an egated container having a top and a bottom. Two different liquids and pellets are utilized, the pellets being nonreactive with and floatable in a first one of the liquids and reactive with and nonfloatable in a second one of the liquids. The first and second liquids are disposed in the container, the first liquid being denser than the second liquid so that the first and second liquids form an interface. A partition is mounted in the container below the level of the interface for dividing the container into top and bottom compartments. The pellets are disposed in the bottom compartment with the first liquid, and a valve is mounted in the partition for dispensing the pellets. With this arrangement, an opening of the valve will allow pellets to exit therethrough and ascend in the first liquid to the interface where the pellets will react with the second fluid to generate gas.

Abstract: Process and apparatus for the production of finely-divided metal oxides by the oxidation of the corresponding metal halide wherein a secondary gas is introduced into a heated primary gas through apertures in the reaction zone wall, the apertures formed with at least two different cross-sectional areas along their length, the small cross-sectional area being at the inlet end of the aperture for the secondary gas.

Abstract: A gas mixer and reactor is provided which includes an elongated gas flow chamber with a nozzle arrangement at its inlet end for passing a first gaseous reactant into the interior of the chamber, toward the outlet of the chamber from points uniformly about the inner periphery of the chamber, and an annular nozzle arrangement near the outlet of the gas flow chamber for directing another gaseous reactant, or reactants, through the outlet of the gas flow chamber and into a thermal reaction chamber which communicates with the outlet of the gas flow chamber. In this manner controlled amounts of gaseous reactants may be thoroughly admixed and reacted to produce an atmosphere of desired composition. Atmospheres for kilns having controlled amounts of free hydrogen, carbon monoxide, oxygen, or carbon for example, are produced by burning controlled ratios of fuel, air and in some cases an inert gas, mixed by the reactor.

Abstract: There is provided a process and apparatus for the production of finely-divided metal and metalloid oxides by flame hydrolysis of corresponding metal and metalloid halides whereby burner fouling is minimized and burner fabrication is facilitated by transpiration of a fuel gas or vapor along the boundaries of each halide-containing stream as it is discharged from the burner into a reaction zone.

Abstract: High temperature chemical reaction processes utilizing fluid-wall reactors can be conducted in fluid-wall reactors by a process which includes the steps of (1) generating a shell of a refractory material which reflects radiation, the volume enclosed by the shell constituting a black body cavity; (2) generating within the black body cavity an annular envelope of an inert fluid which is substantially transparent to radiation, the envelope having substantial axial length and the interior of the envelope defining a reaction chamber; (3) passing at least one reactant into the black body cavity and through the reaction chamber along a predetermined path substantially coincident with the longitudinal axis of the envelope, the reactants being confined within the reaction chamber; and (4) directing high intensity radiant energy into the reaction chamber to coincide with at least a portion of the predetermined path of the reactants, sufficient radiant energy being absorbed within the reaction chamber to raise the tempe

Abstract: A high temperature reactor comprises a tube which defines a reactor chamber; means for introducing the inert fluid into the reactor tube to provide a protective blanket for the inside surface of the tube; means for introducing reactants into the chamber, the reactants being confined centrally within the chamber by the protective blanket; and, means for generating high intensity radiant energy which is directed into the chamber to coincide with at least a portion of the path of the reactants.

Abstract: A water soluble oxidizing material is packaged with gas releasing pest control agents for decomposing residual gas producing agents.

Abstract: To dispose of high-polymer, chlorine-containing plastics, such as PVC, without liberating hydrochloric acid in the atmosphere, the material is placed in a closed vessel and contacted with super-heated steam to split off gaseous hydrochloric acid; the resulting mixture of water vapor, steam and hydrochloric acid is removed, cooled and condensed, so that hydrochloric acid can be derived therefrom; the residue of the material after the hydrochloric acid has been removed can then be safely incinerated with other refuse, etc.

Abstract: A gas phase and a liquid phase pass countercurrently through a reaction vessel, and solid particles move from stage to stage in the reactor concurrently with either the liquid phase or the gas phase. In one embodiment of the invention the liquid phase is a hydrocarbon oil to be treated, for example, desulphurized, the gas phase is hydrogen, and the solid particles are hydrodesulphurization catalyst particles.

Abstract: This invention concerns a process for preparing metal and metal fluoride products. A molten mixture containing a metal oxide, a molten metal fluorinating agent and carbon is reacted to produce a gaseous oxide of carbon, a metal fluorinated product derived from the cation of the metal oxide, and a metal derived from the cation of the metal fluorinating agent.

Abstract: Aqueous solutions and suspensions of solid particles, even those containing less than one percent of organic materials, may be combusted with air, oxygen, or their mixtures in a process which provides for preheating in countercurrent batches of the raw original liquid by either open (direct contact) or closed (heat transfer surface) condensation of steam generated by multiple flash evaporations which cool earlier batches of hot liquid after the wet combustion. Excess heat may often be withdrawn from the process for power generation or other use as high pressure steam, with or without combustion gases and other non-condensibles. No pumps are necessary, liquid batches are pressurized by steam generated in the flash evaporations for which only one pressure vessel is required instead of the many in the continuous processes.

Abstract: Reactions in heterogeneous systems containing reactants in gaseous, liquid and solid phases are carried out in a tower composed of a series of superimposed reaction compartments mutually separated by horizontal shelves, through which the gaseous phase moves countercurrent to the liquid and solid phases and at the same time effects turbulent mixing with the liquid phase. The liquid and solid phases are introduced into the top compartment. The shelves are suitably perforated for upflow of the gas through bodies of mixed liquid and solids which are held on the shelves at levels determined by the heights of overflow pipes which conduct excess reaction mixture from each reaction compartment into the mixture in the compartment next below. Reaction products are taken off from the bottom compartment.

Abstract: A low cost, two-stage adsorption-desorption method of concentrating dilute supplies of chemicals is provided which uses a minimum of energy in the form of process steam and yields highly concentrated supplies of end products which are suitable for reuse or sale. The methods hereof are particularly adapted for concentrating waste condensates derived from pulp-making operations such as the Kraft or sulfite processes, but in general is also applicable for treating all types of dilute organic or inorganic adsorbable chemicals. The invention involves first adsorbing a chemical fraction from a dilute stream thereof onto activated carbon, followed by regenerating the adsorbed chemicals and concentrating the same by fractional distillation, whereupon the partially concentrated chemicals are again adsorbed, regenerated, subjected to a second fractional distillation concentration step, and recovered.

Abstract: Apparatus and process suitable for oxidising a metal halide in the vapor phase wherein at least part of the wall of the reaction zone is formed from crimped annular plates separated by uncrimped annular plates to form orifices through which at least one of the reactants can be introduced into the reaction zone.

Abstract: This invention concerns a process for preparing metal and metal fluoride products. A molten mixture containing a metal oxide, a molten metal fluorinating agent and carbon is reacted to produce a gaseous oxide of carbon, a metal fluorinated product derived from the cation of the metal oxide, and a metal derived from the cation of the metal fluorinating agent.

Abstract: Apparatus suitable for oxidizing a metal halide in the vapor phase wherein at least part of the wall of the reaction zone is formed from crimped annular plates separated by uncrimped annular plates to form orifices through which at least one of the reactants can be introduced into the reaction zone.

Abstract: An apparatus for catalytically combining hydrogen and oxygen which includes two concentric catalyst chambers arranged so that the outer chamber surrounds the inner chamber and the gas stream passes radially through the outer catalyst chamber.

Abstract: A method of performing chemical reactions with enhanced catalytic activity of a solid body by creating plastic deformations in the surface of the catalyst contacted by the reacting materials. The body of catalytic material is fixedly attached to a substrate or base material capable of being deformed by an electrical or magnetic field. A field is applied of sufficient intensity and proper orientation to deform the base material to an extent producing plastic deformation of the attached catalyst, thereby creating defects in the exposed surface thereof.

Abstract: Hot gases for fluidizing the preheat compartment of a multi-bed fluid bed reactor are cooled by injection of water, or cool air and water, to reduce scaling of the ducts, hot cyclone, hot windbox and the tuyeres in the constriction dome separating the hot windbox from the preheat compartment.

Abstract: A method for continuously carrying out the chemical synthesis of a gas in a wave reactor apparatus of the type wherein reactant gases subjected to compression waves generated by a driver gas may be heated to extremely high temperatures very rapidly and then cooled at extremely rapid rates with very precise control over reaction parameters. The method includes the step of removing the exhaust driver gas from the tubes of the wave reactor at a pressure greater than that which it had upon entering the tubes of the wave reactor prior to compression of the reactant. The driver gas is recirculated without the addition of heat or pump work other than that originating with the reactant gas stream. Apparatus for performing the above method is disclosed including a multi-tube rotor of novel physical dimension and a conduit and manifold system for recirculating the driver gas between tubes of the wave reactor. Particularly disclosed is a conduit and manifold system for staged recirculation of the driver gas.

Abstract: A boron trichloride starting material containing both boron-10 isotopes and oron-11 isotopes is selectively enriched in one or the other of these isotopes by a laser-induced photochemical method involving the reaction of laser-excited boron trichloride with either H.sub.2 S or D.sub.2 S. The method is carried out by subjecting a low pressure gaseous mixture of boron trichloride starting material and the sulfide to infrared radiation from a carbon dioxide TE laser. The wave length of the radiation is selected so as to selectively excite one or the other of boron-10 BCl.sub.3 molecules or boron-11 BCl.sub.3 molecules, thereby making them preferentially more reactive with the sulfide. The laser-induced reaction produces both a boron-containing solid phase reaction product and a gaseous phase containing mostly unreacted BCl.sub.3 and small amounts of sulfhydroboranes.

Abstract: A method for removing efficiently and economically harmful materials from a waste gas exhausted in a process for producing acrylonitrile by ammoxidation of propylene, which comprises dividing the waste gas exhausted after the absorption of acrylonitrile into two flows, mixing the first flow gas with air in an amount necessary for combustion of the combustible gas contained in the whole waste gas, subjecting the main flow gas of the mixed gas thus obtained to heat-exchange with the gas of the outlet of the first catalyst layer, combining the main flow gas with the remainder of the mixed gas, preheating thereby the mixed gas at a temperature of 200.degree. to 450.degree. C, passing the preheated mixed gas through the first catalyst layer wherein at least one noble metal is dispersed on an alumina carrier, and therein burning the gas at a temperature of 650.degree. to 750.degree.

Abstract: A flame reactor burner is provided for reacting hydrogen and bromine to produce hydrogen bromide. Flame stability is enhanced by producing a helical flow of well mixed reactants within the burner, whereby the reactants in intimate contact with each other are propelled in an outward spiral path as they exit from the burner producing a hemispherical flame of high stability.

Abstract: The flow rate of the oxygen-containing gas to a process for the oxidation of the hydrogen sulfide in a sour gas to sulfur is regulated responsive to the lower of the sour gas pressure signal and a signal representing the value of the sour gas flow rate as modified by the ratio of hydrogen sulfide to sulfur dioxide in the gaseous reaction effluent, to maintain the desired ratio of hydrogen sulfide to oxygen fed to the process. The sour gas flow rate can be regulated responsive to the higher of the sour gas pressure signal and the oxygen-containing gas flow rate signal.

Abstract: A plate for fluid bed reactors to insure uniform distribution of the fluidizing gas, comprises a pair of spaced opposed plates having holes therethrough, the holes in one plate being staggered relative to those of the other plate. The peripheral holes are larger than the central holes. The holes in the upper plate have upper frusto-conical parts and lower cylindrical parts, while the holes in the lower plate have upper cylindrical parts and lower frusto-conical parts. The plates have central holes closed by frusto-conical plugs operable from outside the associated apparatus to discharge material from the plate.

Abstract: A continuous process for removing nitrates from nitrate containing aqueous solutions having a pH of about 0-7, which comprises: (1) extracting the nitrate containing aqueous solution with an organic amine salt dissolved in an organic solvent phase whereby the nitrate ion goes into the organic solvent, (2) separating the organic phase, (3) stripping the organic extraction solvent phase from the extraction with a stripping salt solution of pH at least 0.

Abstract: The method and apparatus for the oxidation of naphthalene to phthalic anhydride in multi-tube reactors having fixed bed catalysts therein are improved by removing deposits from the catalysts. These deposits are removed by impulsively decompressing the reactor in the direction of the inlet of the multi-tube reactor.

Abstract: A method for selectively recovering metals from generally sulphidic particulate materials containing metals selected from nickel, copper and precious metals in which the particulate material is preferentially leached in an agitated chloride solution containing cuprous ions by the action of chlorine. The redox potential of the solution increases upon feeding chlorine thereto and decreases upon feeding particulate material thereto, and the rate of feeding of chlorine is controlled relative to the rate of feeding of material to control the redox potential substantially at or below a selected potential at which the metal is leached preferentially with respect to other metals in the material. Nickel is leached preferentially with respect to copper and precious metals in a matte, for example, to produce a nickel-rich solution and to concentrate the precious metals in a nickel-depleted residue.

Abstract: A process for the thermal dissociation of an organic substance containing chlorine in which substantially anhydrous hydrogen chloride is obtained. The substance containing chlorine is introduced in a first stage into a salt melt in the absence of oxygen, hydrogen chloride is discharged from the reaction mixture and then oxygen is supplied to the salt melt in a second stage.

Abstract: Titanium dioxide is produced by a continuous gaseous oxidation of titanium tetrachloride or a titanium tetrachloride containing gas with oxygen or an oxygen containing gas, the improvement wherein both of said gases are separately preheated and the titanium tetrachloride or titanium tetrachloride containing gas is fed downwardly into the reactor from a burner equipped with a cooling jacket disposed at the upper part of the reactor and the oxygen or oxygen containing gas is fed downwardly through the burner into the reactor for reaction with titanium tetrachloride; and simultaneously, an inert gas and inert refractory particles are injected from the lower part of the reactor toward the inner wall of the reactor so that the inert refractory particles are caused to rise upwardly as a suspension, and the upward flow of the suspension is counter-currently contacted with the downwardly flow of the reaction product so as to rapidly cool the reaction product, and wherein the inert refractory particles injected upward

Abstract: Sulfur isotopes are continuously separated and enriched using a closed loop reflux system wherein sulfur dioxide (SO.sub.2) is reacted with sodium hydroxide (NaOH) or the like to form sodium hydrogen sulfite (NaHSO.sub.3). Heavier sulfur isotopes are preferentially attracted to the NaHSO.sub.3, and subsequently reacted with sulfuric acid (H.sub.2 SO.sub.4) forming sodium hydrogen sulfate (NaHSO.sub.4) and SO.sub.2 gas which contains increased concentrations of the heavier sulfur isotopes. This heavy isotope enriched SO.sub.2 gas is subsequently separated and the NaHSO.sub.4 is reacted with NaOH to form sodium sulfate (Na.sub.2 SO.sub.4) which is subsequently decomposed in an electrodialysis unit to form the NaOH and H.sub.2 SO.sub.4 components which are used in the aforesaid reactions thereby effecting sulfur isotope separation and enrichment without objectionable loss of feed materials.

Abstract: A gas mixer and reactor is provided which is especially suitable as a burner which includes an elongated gas flow chamber with a nozzle arrangement at its inlet end for passing a first gaseous reactant into the interior of the chamber toward the outlet from points uniformly about the inner periphery of the chamber, and an annular nozzle arrangement near the outlet of the gas flow chamber for directing another gaseous reactant or reactants through the outlet of the gas flow chamber and into a thermal reaction chamber which communicates with the outlet of the gas flow chamber. Also provided are processes utilizing the mixer and in particular a process for converting sulfur containing gas into sulfur.

Abstract: A method of manufacturing an airtight-sealed system comprising one or more molten alkalifluorides in the operating condition.The corrosive action of oxygen present in the melt is prevented by adding metallic aluminium and/or zinc to the melt.

Abstract: Solutions of soluble alkali metal silicates of exceptional clarity are prepared by dissolving anhydrous alkali metal silicate glass at atmospheric pressure by a novel process comprising the constant classification of alkali metal silicate glass particles according to size and the constant removal of the polymer-like silicate that forms as a semi-solid on the wetted glass surface. The constant classification of the silicate glass particles and removal of this polymeric silicate to yield nascent glass surfaces can be achieved by charging silicate glass particles to aqueous media in a vibrating or vibro energy mill and subjecting said particles to impacts of varying frequency and amplitude or by subjecting the solution and glass particles, during dissolution, to agitation of different intensity and duration in a vertically stacked series of dissolving chambers.

Abstract: A high-temperature reaction method is disclosed. The method comprises coupling an inductive heating coil to the contents of a reaction vessel, containing at least one conductive reactant with a coupling efficiency that is different than the coupling efficiency between the coil and the contents of the reaction vessel at the completion of the reaction. An alternating voltage is developed across the coil and the current flowing in the coil is monitored. Typically, the monitored current increases as the reaction proceeds until the reaction is completed whereupon a constant current value is obtained.

Abstract: A method for the production of a homogenous gas mixture from two gas streams of different parameters in which an open or free equalizing space downstream of a superimposed catalyst layer is provided. Within such open space is a mixing assembly imposing a little deflection upon the reaction gas stream causing a low pressure drop in the stream with a consequent reduced loss of energy. Quench gas is admitted through a two stage pressure reduction. It is first expanded from a duct surrounding the mixing assembly through a plurality of openings where the gas velocities are reduced and equalized. The second pressure reduction takes place across openings in the mixing assembly. Quench gas and reaction gas are then thoroughly mixed in the mixing assembly and the gas mixture is consequently passed to the entrance of a second catalyst layer downstream.