Forming Compound Containing Plural Metals Patents (Class 423/71)
  • Patent number: 11618221
    Abstract: The present invention relates to an additive for laser-markable and/or laser-weldable polymer materials, and in particular to the use of pigments which comprise niobium-doped titanium dioxide as laser absorbing additive in polymer materials, to polymer materials which comprise a laser absorbing additive of this type and to a laser-marked or laser-welded product comprising at least one polymer material and niobium-doped titanium dioxide containing pigments as laser absorbing additive.
    Type: Grant
    Filed: November 20, 2017
    Date of Patent: April 4, 2023
    Assignee: Merck Patent GmbH
    Inventors: Atsuko Nishimagi, Kazuhisa Azuma, Ryuta Suzuki
  • Patent number: 8853116
    Abstract: A method of forming composition-modified barium titanate ceramic particulate includes mixing a plurality of precursor materials and a precipitant solution to form an aqueous suspension. The plurality of precursors include barium nitrate, titanium chelate, and a metal or oxometal chelate. The precipitant solution includes tetraalkylammonium hydroxide and tetraalkylammonium oxalate. The method further includes treating the aqueous suspension at a temperature of at least 150° C. and a pressure of at least 200 psi, and separating particulate from the aqueous suspension after treating.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: October 7, 2014
    Assignee: EEStor, Inc.
    Inventors: Richard D. Weir, Carl W. Nelson
  • Patent number: 8496893
    Abstract: A furnace assembly includes first and second sections. The first section includes first and seconds ends, a first joint disposed at the first end, a conical portion at a second end, a first filter disposed between the first and second ends, and a lumen extending through the first section in fluid communication with the first filter. The second section includes first and second ends, a second joint disposed at the first end, an opening disposed at the second end and to receive the conical portion of the first section, a second filter disposed between the first and second ends, and a lumen extending through the second section in fluid communication with the second filter. When engaged, the first and second sections form a chamber between the first and second filters. The chamber is in fluid communication with the respective first ends of the first and second sections.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: July 30, 2013
    Assignee: EEStor, Inc.
    Inventor: Richard D. Weir
  • Patent number: 8398952
    Abstract: The present invention is to provide a method of manufacturing a potassium titanate adapted for a friction material of a friction slide member. The present invention includes the steps of uniformly mixing an aggregate or a granulation of a titanium compound and a potassium compound with a vibration rod mill to form a mixture and sintering the mixture for reaction one another in order to manufacture a desired potassium titanate with ease and low cost.
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: March 19, 2013
    Assignee: Toho Titanium Co., Ltd.
    Inventors: Koji Tanimizu, Naomichi Hori, Nobuo Kamishima
  • Patent number: 8383534
    Abstract: The invention is to provide a process capable of producing aluminium magnesium titanate having a small coefficient of thermal expansion at a firing temperature lower than 1500° C. The production process of the invention comprises maintaining a pre-mixture containing a titania source powder, an alumina source powder, a magnesia source powder and a silica source powder within a temperature range of from 1100° C. to 1350° C. for at least 3 hours, followed by heating up to a temperature not lower than 1400° C. and firing at the temperature. The silica source powder is preferably a powder of alkali feldspar. Aluminium magnesium titanate is prepared according to the production process of the invention, and the resulting aluminium magnesium titanate is ground to give an aluminium magnesium titanate powder.
    Type: Grant
    Filed: January 19, 2009
    Date of Patent: February 26, 2013
    Assignees: Sumitomo Chemical Company, Limited, E.I. du Pont de Nemours and Company
    Inventors: Tetsuro Tohma, Keiichiro Suzuki, Satoko Iwato, Rina Yamanaka
  • Patent number: 8241595
    Abstract: A potassium titanate, method for manufacturing the potassium titanate, a friction material using the potassium titanate and a resin composition using the potassium titanate are disclosed. The potassium titanate is represented by K2TinO(2n+1) (n=4.0-11.0) and has the highest X-ray diffraction intensity peak (2?) in the range of 11.0°-13.5° with its half width being not less than 0.5°.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: August 14, 2012
    Assignee: Otsuka Chemical, Co., Ltd.
    Inventor: Nobuki Itoi
  • Patent number: 8221713
    Abstract: A method for making a mono-dispersed metal titanate includes the steps of: (a) mixing titanate ester, metal salt, and rare earth metal salt in a molar ratio of 1:1:x in a reaction medium comprised of ethanol and water to form a solution, wherein x is in the range from 0 to 0.1; (b) heating the solution, under an alkaline condition to form a white sediment; (c) filtering out liquid part of the solution to obtain the white sediment, (d) washing the white sediment, and (e) drying the white sediment to obtain mono-dispersed metal titanate.
    Type: Grant
    Filed: December 14, 2007
    Date of Patent: July 17, 2012
    Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.
    Inventors: Ya-Dong Li, Zi-Yang Huo, Chen Chen
  • Patent number: 8137646
    Abstract: A mixture of zirconium hydroxides or zirconium basic carbonate with vanadium oxide (V205) co-reacts in high temperature aqueous slurry to form respectively an amorphous material, believed to be based on a zirconium analog of a zeolite structure, and a solid solution of zirconium oxide with vanadium oxide. The subject compositions, free of hexavalent chromium, are highly effective in providing blister-free corrosion prevention in typical coil and aerospace grade epoxy primer and color coat combinations.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: March 20, 2012
    Assignee: The Shepherd Color Company
    Inventor: Simon Boocock
  • Patent number: 8062620
    Abstract: The present invention relates to a process for the conversion of cobalt(II)hydroxide into cobalt(III)oxidehydroxide (CoOOH) by reaction of the cobalt(II)hydroxide with oxygen in the presence of certain metal compounds. The invention further relates to the use of cobalt(III)oxidehydroxide thus prepared in the preparation of catalysts or catalysts precursors, especially catalysts or catalyst precursors for the conversion of synthesis gas into normally liquid and normally solid hydrocarbons and to normally liquid or solid hydrocarbons, optionally after additional hydrotreatment, obtained in such a conversion process.
    Type: Grant
    Filed: November 28, 2005
    Date of Patent: November 22, 2011
    Assignee: Shell Oil Company
    Inventors: Ronald Jan Dogterom, Heiko Oosterbeek, Marinus Johannes Reynhout
  • Patent number: 8048389
    Abstract: The present invention provides a cerium oxide-zirconium oxide-based mixed oxide having superior platinum dispersibility and a suitable OSC, and a simple production process thereof. The cerium oxide-zirconium oxide-based mixed oxide comprises cerium oxide and zirconium oxide, wherein (1) the weight ratio of CeO2:ZrO2 is 60:40 to 90:10, and (2) the cerium oxide and the zirconium oxide are present as a mixture, the zirconium oxide being composed of a solid solution in which tetragonal or cubic zirconium oxide contains cerium.
    Type: Grant
    Filed: September 21, 2010
    Date of Patent: November 1, 2011
    Assignee: Daiichi Kigenso Kagaku Kogyo Co., Ltd.
    Inventors: Hiroshi Okamoto, Masatoshi Maruki
  • Patent number: 7931886
    Abstract: According to the present invention there is provided a process for the agglomeration of titania slag particles comprising providing titania slag at a d50 particle size of below 106 ?m; mixing the slag particles with an organic binder; and agglomerating the mixture of the slag particles and organic binder into agglomerated particles with a d50 particle size in the range from 106 ?m to 1000 ?m. The agglomerated particles have a (TiO2 and FeO)/C mass ratio of more than 3.4. The invention also relates to such agglomated slag particles and a chloride process for the production of TiO2 wherein such agglomerated titania slag particles are used.
    Type: Grant
    Filed: September 14, 2005
    Date of Patent: April 26, 2011
    Assignee: Kumba Resources Limited
    Inventors: Pieter Adriaan Botha, Gert Hendrik Jacobus Coetzee, legal representative, Deon Bessinger, Benjamin Alexander Dippenaar
  • Patent number: 7914755
    Abstract: Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and the use of a nonmetal-ion-containing strong base can be used in a coprecipitation procedure for the preparation of ceramic powders. Examples of the precipitants used include tetraalkylammonium hydroxides. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.
    Type: Grant
    Filed: March 7, 2006
    Date of Patent: March 29, 2011
    Assignee: EEStor, Inc.
    Inventors: Richard D. Weir, Carl W. Nelson
  • Patent number: 7820586
    Abstract: The invention concerns a composition based on zirconium and cerium oxides in an atomic ratio Zr/Ce>1, and further comprising lanthanum oxide or an oxide of a rare earth other than cerium and lanthanum. The invention is characterized in that after calcination for 6 hours at 1150 .C it has a specific surface area of not less than 10 m;/g. The composition is obtained by forming a mixture containing a sol of a zirconium compound and cerium, lanthanum, said rare earth compounds, contacting said mixture with a basic compound solution, while heating and calcining the resulting precipitate. The composition can be used as catalyst.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: October 26, 2010
    Assignee: Rhodia Operations
    Inventor: Catherine Hedouin
  • Patent number: 7744845
    Abstract: A process is disclosed for the preparation of lithium zirconate and doped lithium zirconates for use as regenerable carbon dioxide sorbants by wet mixing zirconium hydroxide with lithium carbonate and then calcining the mixture. Due to the improved physical properties resulting from the disclosed preparation process, the lithium zirconates produced by this process are capable of absorbing carbon dioxide at high rates and in large amounts.
    Type: Grant
    Filed: August 25, 2006
    Date of Patent: June 29, 2010
    Assignee: Magnesium Elektron Limited
    Inventor: Hazel Stephenson
  • Patent number: 7741396
    Abstract: Disclosed herein is a composition comprising a polymeric material; and non-linear dielectric ceramic fillers; wherein the non-linear dielectric ceramic fillers have a dielectric constant that is greater than or equal to about 100 and wherein the dielectric constant of the composition is tunable. Disclosed herein too is a composition comprising a polymeric material; and perovskites; wherein the dielectric constant of a composition is tunable and further wherein the composition has a dielectric constant of about 2 to about 100. Disclosed herein too is a method comprising blending a polymeric resin with non-linear dielectric ceramic fillers to form a composition; wherein the non-linear dielectric ceramic fillers have a dielectric constant of greater than or equal to about 100 and wherein the dielectric constant of the composition is tunable.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: June 22, 2010
    Assignee: General Electric Company
    Inventors: Qi Tan, Patricia Chapman Irwin
  • Patent number: 7700057
    Abstract: The invention provides a method for the Industrial purification of a titanium feed stream of purity P1, by the formation of a titanium-double-salt precipitate of purity P2 and a titanium solution with purity P3, wherein P2>P1>P3, the method comprising the steps of: i. forming, from the feed, a medium comprising water, titanium ion, a cation selected from the group consisting of ammonium, cations of alkali metals, protons and a combination thereof, and an anion selected from the group consisting of OH, SO4, HSO4, halides and a combination thereof, which formed medium is further characterized by the presence of (a) a double-salt precipitate comprising titanium ion, at least one of the cations and at least one of the anions; and (b) a titanium solution; and wherein the concentration of the anion in the titanium solution is higher than 15% and the ratio between the concentrations of the cation and the anion in the titanium solution is higher than 0.2 and lower than 1.6; and ii.
    Type: Grant
    Filed: October 15, 2006
    Date of Patent: April 20, 2010
    Assignees: Joma International AS, Asher Vitner Ltd.
    Inventors: Asher Vitner, Aharon Eyal, Revital Mali
  • Patent number: 7700038
    Abstract: A formed article for making alloying additions to metal melts includes particles of at least one master alloy and a binder material binding the particles of the master alloy in the formed article. The binder material changes form and frees the master alloy particles when the formed article is heated to a predetermined temperature, preferably a temperature greater than 500° F. A method for making an alloy also is provided. The method includes preparing a melt comprising a predetermined quantity of a master alloy wherein the master alloy is added to the melt or the melt starting materials in the form of particles of the master alloy bound into at least one formed article by a binder material that decomposes at a predetermined temperature, preferably a temperature greater than 500° F., and releases the particles of master alloy.
    Type: Grant
    Filed: March 21, 2005
    Date of Patent: April 20, 2010
    Assignee: ATI Properties, Inc.
    Inventors: Timothy F. Soran, Matthew J. Arnold
  • Patent number: 7662475
    Abstract: The invention relates to an alkaline-earth metal carbonate powder comprising a core consisting essentially of at least one alkaline-earth metal carbonate and a shell consisting essentially of at least one Group IV transition metal compound, to the method for manufacturing the same and to an improved method for preparing highly crystalline alkaline-earth metal containing mixed oxide powder. The highly crystalline mixed oxides obtained by means of the process according to the invention are used as starting material for high-performance dielectric, especially multi-layer capacitors, and for high performance dielectrics.
    Type: Grant
    Filed: July 26, 2005
    Date of Patent: February 16, 2010
    Assignee: Solvay (Société Anonyme)
    Inventors: Rocco Alessio, Vincenzo Buscaglia, Maria Teresa Buscaglia
  • Patent number: 7582276
    Abstract: The invention relates to nanoscale rutile or oxide powder that is obtained by producing amorphous TiO2 by mixing an alcoholic solution with a titanium alcoholate and with an aluminum alcohalate and adding water and acid. The amorphous, aluminum-containing TiO2 is isolated by removing the solvent, and is redispersed in water in the presence of a tin salt. Thermal or hydrothermal post-processing yields rutile or oxide that can be redispersed to primary particle size. The n-rutile or the obtained oxide having a primary particle size ranging between 5 and 20 nm can be incorporated into all organic matrices so that they remain transparent. Photocatalytic activity is suppressed by lattice doping with trivalent ions. If the amorphous precursor is redispersed in alcohol, or not isolated, but immediately crystallized, an anatase is obtained that can be redispersed to primary particle size.
    Type: Grant
    Filed: August 30, 2002
    Date of Patent: September 1, 2009
    Assignee: ITN Nanovation AG
    Inventor: Ralph Nonninger
  • Patent number: 7575731
    Abstract: The present invention relates to fine particles of a tin-modified rutile-type titanium dioxide obtained through the reaction of an aqueous solution of a titanium compound having a Ti concentration of 0.07 to 5 mol/l at a pH in the range of ?1 to 3 in the co-presence of a tin compound at a molar ratio of tin to titanium (Sn/Ti) of 0.001 to 2, wherein said fine particle has an Sn/Ti composition molar ratio of 0.001 to 0.5, and a short axis and a long axis of a crystal grain diameter thereof have a length of 2 to 20 nm.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: August 18, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Tomonori Iijima, Norio Nakayama, Toyoharu Hayashi
  • Patent number: 7566439
    Abstract: A ceramic powder having a perovskite structure is manufactured by synthesizing a ceramic powder by a dry synthesis process and then heat-treating the synthesized ceramic powder in a solution. The dry synthesis method includes a solid phase synthesis method, an oxalate method, a citric acid method and a gas phase synthesis method.
    Type: Grant
    Filed: November 30, 2006
    Date of Patent: July 28, 2009
    Assignee: Taiyo Yuden Co., Ltd.
    Inventors: Chie Kawamura, Atsushi Tanada, Hirokazu Chazono
  • Patent number: 7553474
    Abstract: It is an object to provide a method for producing stable alkaline metal oxide sols having a uniform particle size distribution. The method comprises the steps of: heating a metal compound at a temperature of 60° C. to 110° C. in an aqueous medium that contains a carbonate of quaternary ammonium; and carrying out hydrothermal processing at a temperature of 110° C. to 250° C. The carbonate of quaternary ammonium is (NR4)2CO3 or NR4HCO3 in which R represents a hydrocarbon group, or a mixture thereof. The metal compound is one, or two or more metal compounds selected from a group of compounds based on a metal having a valence that is bivalent, trivalent, or tetravalent.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: June 30, 2009
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Yutaka Ohmori, Hirokazu Kato, Yoshinari Koyama, Kenji Yamaguchi
  • Patent number: 7547490
    Abstract: The invention concerns a process for producing a spinel compound of formula Li4Ti5O12, comprising a step of preparing a mixture of an organo-lithium compound selected from lithium alcoholates with an organo-titanium compound selected from titanic acid esters, in a liquid medium, and a step of hydrolyzing the mixture of said compounds. The invention also concerns a Li4Ti5O12 particulate material which may be produced according to the previous cited process and which has a BET surface area of at least 10 m2/g. The material is particularly useful in the manufacture of Lithium Ion batteries.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: June 16, 2009
    Assignee: Altairnano Inc.
    Inventors: Timothy Spitler, Jan Prochazka, Ladislav Kavan, Michael Graetzel, François Sugnaux
  • Patent number: 7541016
    Abstract: A lithium titanate has the following formula: Li4Ti5O12?x wherein x is greater than 0. The lithium titanate is formed by providing a mixture of titanium dioxide and a lithium-based component. The mixture is sintered in a gaseous atmosphere comprising a reducing agent to form the lithium titanate having the above formula. A lithium-based cell includes an electrolyte, an anode, and a cathode, with at least one of the anode and the cathode comprising the lithium titanate having the above formula. The lithium titanate is deficient of oxygen, which increases electronic conductivity of the lithium titanate by at least three orders over electronic conductivity of a stoichiometric lithium titanate, while avoiding loss of reversible electric power-generating capacity that typically occurs when doping is used to replace titanium in the lithium titanate with atoms that provide higher electronic conductivity.
    Type: Grant
    Filed: August 4, 2006
    Date of Patent: June 2, 2009
    Assignee: EnerDel, Inc.
    Inventors: Vadim Gorshkov, Oleg Volkov
  • Patent number: 7465333
    Abstract: A precursor halide compound is reduced to a predetermined product at substantially ambient conditions. The halide is added to an anhydrous liquid reaction medium containing one or more alkali metals or alkaline earth metals as reductants. The metal reductants are dispersed as very small globules in the liquid by cavitation of the liquid, such as by application of high intensity ultrasonic vibrations or high-shear mixing to the reaction vessel. Continued cavitation of the liquid medium affects low temperature reduction of the precursor halide(s) to produce a metal, metal alloy, metal compound, ceramic material, metal matrix-ceramic composite material, or the like. The practice may be applied, for example, to titanium tetrachloride, alone or with other chlorides, to produce titanium metal, titanium alloys (for example Ti-6Al-4V), and titanium compounds (TiSi2).
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: December 16, 2008
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Ion C. Halalay, Michael P. Balogh, Michael K. Carpenter
  • Publication number: 20080295645
    Abstract: A precursor halide compound is reduced to a predetermined product at substantially ambient conditions. The halide is added to an anhydrous liquid reaction medium containing one or more alkali metals or alkaline earth metals as reductants. The metal reductants are dispersed as very small globules in the liquid by cavitation of the liquid, such as by application of high intensity ultrasonic vibrations or high-shear mixing to the reaction vessel. Continued cavitation of the liquid medium affects low temperature reduction of the precursor halide(s) to produce a metal, metal alloy, metal compound, ceramic material, metal matrix-ceramic composite material, or the like. The practice may be applied, for example, to titanium tetrachloride, alone or with other chlorides, to produce titanium metal, titanium alloys (for example Ti-6Al-4V), and titanium compounds (TiSi2).
    Type: Application
    Filed: August 17, 2006
    Publication date: December 4, 2008
    Applicant: GM Global Technology Operations, Inc.
    Inventors: Ion C. Halalay, Michael P. Balogh, Michael K. Carpenter
  • Patent number: 7455713
    Abstract: A titanium halide and, optionally, other precursor halides compound are reduced to a predetermined titanium product, suitably at or near ambient conditions. Titanium tetrachloride, for example, is added to an anhydrous liquid reaction medium containing one or more alkali metals or alkaline earth metals as reductants. The metal reductants are dispersed as very small globules in the liquid by cavitation of the liquid reaction medium, such as by application of high intensity ultrasonic vibrations or high-shear mixing to the reaction vessel. Continued cavitation of the liquid medium affects relatively low temperature reduction of the precursor halide(s) to produce a titanium-containing product such as titanium metal, a titanium alloy or compound, or a titanium matrix-ceramic composite material, or the like.
    Type: Grant
    Filed: August 17, 2006
    Date of Patent: November 25, 2008
    Assignee: GM Global Technology Operations, Inc.
    Inventors: Ion C. Halalay, Michael P. Balogh
  • Patent number: 7318897
    Abstract: The present invention provides a method of removing spectator ions and contaminants from aqueous suspensions of solid particles. In accordance with the method of the invention, the solid particles are transported across a phase boundary into a non-polar organic solvent, leaving the spectator ions and contaminants in the aqueous phase. To facilitate the efficient transportation of the solid particles across the phase boundary, the surface of the solid particles is coated with an amphiphilic polyelectrolyte. If desired, the solid particles can be recovered from the organic phase by evaporating the organic solvent.
    Type: Grant
    Filed: August 13, 2004
    Date of Patent: January 15, 2008
    Assignees: Ferro Corporation, The Penn State Research Foundation
    Inventors: Xiangdong Feng, Christopher J. Szepesi, Heber E. Rast, III, Mike S. H. Chu, James H. Adair
  • Patent number: 7247283
    Abstract: The invention concerns a process for preparing an oxide based on zirconium and titanium in which a liquid medium containing a zirconium compound and a titanium compound is formed; said medium is then heated; the precipitate obtained from the end of the preceding step is recovered and optionally, said precipitate is calcined. The invention also concerns an oxide based on zirconium and titanium. Said oxide can comprise in the range 30% to 40% by weight of titanium oxide and in this case it has a pure ZrTiO4 type structure or a mixture of phases of structure type ZrTiO4 and structure type anatase. Said oxide can also comprise in the range 10% to 20% by weight of titanium oxide and it then has a specific surface area of at least 40 m2/g after calcining for 5 hours at 800° C.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: July 24, 2007
    Assignee: Rhodia Electronics and Catalysis
    Inventor: Catherine Hedouin
  • Patent number: 7223378
    Abstract: Process for preparing barium titanate or strontium titanate by reacting titanium alkoxides with barium hydroxide hydrate or strontium hydroxide hydrate in a C1–C8-alcohol or a glycol ether at from 50 to 150° C.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: May 29, 2007
    Assignee: BASF Aktiengesellschaft
    Inventor: Hans-Josef Sterzel
  • Patent number: 7220398
    Abstract: Liquid feed flame spray pyrolysis of solutions of a metal oxide precursor which is an alkoxide or C1-6 carboxylate and at least one second metal oxide precursor and/or second metal compound dissolved in oxygenated solvent by combustion with oxygen lead to the formation of sub-micron mixed-metal oxide powders not accessible by other processes or by the pyrolysis of metal chlorides or nitrates. The powders have numerous uses in advanced materials applications including particulate solid state lasers, advanced ceramic materials, and as catalysts in organic synthesis and automobile exhaust systems.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: May 22, 2007
    Assignee: TAL Materials & The Regents of the University of Michigan
    Inventors: Anthony C. Sutorik, Richard M. Laine, Julien Marchal, Tyrone Johns, Thomas Hinklin
  • Patent number: 7211230
    Abstract: The present invention discloses a process for producing nanometer powders, comprising the following steps: (a) providing reactant solution A and reactant solution B that can rapidly react to form precipitate; (b) continuously adding said solution A and solution B into a mixing and reacting precipitator with a stator and a rotor in operation, respectively; and (c) post-treating the precipitate-containing slurry discharged continuously from the mixing and reacting precipitator. The present process could produce nanometer powders with adjustable particle size, good homogeneity in size and good dispersity. The method also has the characteristics of high production yield, simplicity in process and low consumption of energy. It could be applied to produce various nanometer powders of metals, oxides, hydroxides, salts, phosphides and sulfides as well as organic compounds.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: May 1, 2007
    Assignee: Anshan University of Science and Technology
    Inventors: Yingyan Zhou, Shoushan Gao, Hongxia Li, Kaiming Wang, Xiaoqi Li, Lixiang Li, Chuangeng Wen
  • Patent number: 7182930
    Abstract: A method of fabricating barium titanate powders uses titanium tetrachloride and barium hydroxide as reactants in a reaction solution. The pH value of the reaction solution is adjusted to strongly alkaline range by adding potassium hydroxide. Nitrogen is charged into a reaction tank at normal pressure, and the reaction solution is heated at 80–102°. The solution is intensively stirred at constant temperature, and then subjected to a hydro-thermal reflux. Then, the solution is treated through an ion exchange resin and dried to obtain a cubic BaTiO3 powders.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: February 27, 2007
    Assignee: Chung Shan Institute of Science and Technology
    Inventors: Ming-Tseh Tsay, Zong-Whie Shih, Pao-Yen Lin
  • Patent number: 7179441
    Abstract: The present invention relates to a method for preparing barium titanate based powder. More particularly, the present invention provides a method for preparing barium titanate powder comprising the following steps of precipitation of barium titanyl oxalate (BaTiO(C2O4)2.4H2O) with spraying a mixture of an aqueous barium chloride (BaCl2.2H2O) and titanium tetrachloride (TiCl4) to an aqueous solution of oxalic acid, via a nozzle; wet pulverization by using a beads mill after adding an additive such as an amine; dry; pyrolysis; and re-pulverization.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: February 20, 2007
    Assignees: Samsung Fine Chemicals Co., Ltd., Samsung Electro-Mechanics Co., Ltd.
    Inventors: Jae Chul Jung, Woo Young Yang, Keon Il Kim, Yun Jung Park, Jun Hee Lee, Kang Heon Hur, Seon Cheol Park, Jai Joon Lee
  • Patent number: 7157072
    Abstract: Provided is a cathode composition for lithium secondary battery that includes a lithium-chromium-titanium-manganese oxide that has the formula Li[Li(1-x)/3CrxTi(2/3)yMn2(1-x-y)/3]O2 where 0?x?0.3, 0?y?0.3 and 0.1?x+y?0.3, and layered a-LiFeO2 structure. A method of synthesizing the lithium-chromium-titanium manganese oxide includes preparing a first mixed solution by dispersing titanium dioxide (TiO2) in a mixed solution of chrome acetate (Cr3(OH)2(CH3CO2)7) and manganese acetate ((CH3CO2)2Mn.4H2O), adding a lithium hydroxide (LiOH) solution to the first mixed solution to obtain homogeneous precipitates, forming precursor powder that has the formula Li[Li(1-x)/3CrxTi(2/3)yMn2(1-x-y)/3]O2 where 0?x?0.3, 0?y?0.3 and 0.1?x+y?0.3 by heating the homogeneous precipitates, and heating the precursor powder to form oxide powder having a layered structure.
    Type: Grant
    Filed: July 6, 2004
    Date of Patent: January 2, 2007
    Assignee: Electronics and Telecommunications Research Institute
    Inventors: Xianglan Wu, Yong Joon Park, Kwang Sun Ryu, Soon Ho Chang
  • Patent number: 7132093
    Abstract: The oxide materials are of the class of ternary mesoporous mixed oxide materials including lanthanum, a metal M selected from the group consisting of Cr, Mn, Fe, Co, Ni, Cu and Zn, and zirconium or cerium such a mesoporous La—Co—Zr mixed oxide material designated as Meso LCZ[x] where x is the atomic ratio (La+Co)/La+Co+Zr. They are useful as catalysts since they show high activities for hydrocarbon oxidation and good resistance against poisoning agents. These highly ordered mesoporous mixed oxides are synthesized by: preparing an amorphous solution of a La-M precursor and adding a salt of zirconium or cerium thereto; acidifying the amorphous solution in the presence of a surfactant under conditions to obtain a clear homogeneous solution; adjusting pH of the solution under conditions to form a solid precipitate; separating the solution and surfactant from the precipitate; and calcinating the precipitate.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: November 7, 2006
    Assignee: Université Laval
    Inventors: Serge Kaliaguine, Trong On Do
  • Patent number: 7078009
    Abstract: Lepidocrocite lithium potassium titanate characterized as having a composition represented by the formula K0.5-0.7Li0.27Ti1.73O3.85-3.95, and preferably having an arithmetic mean of major and minor diameters of 0.1–100 ?m, a proportion of a major to minor diameter of from 1 to below 10, a mean thickness of 50–5,000 nm and a flaky shape. A friction material characterized as containing 1–80% by weight of the lepidocrocite lithium potassium titanate as a friction control agent.
    Type: Grant
    Filed: October 28, 2002
    Date of Patent: July 18, 2006
    Assignee: Otsuka Chemical Co., Ltd.
    Inventors: Hiroshi Ogawa, Nobuki Itoi, Kousuke Inada
  • Patent number: 7063824
    Abstract: This invention relates to a process of treating a zirconium containing product such as zircon. The process comprises providing an alkali fusion decomposed zircon product (AFDZ) formed from reading zircon with a source of alkali metal at elevated temperatures, and treating the AFDZ to form a solid containing hydrated zirconium oxide and/or hydrated zirconium basic carbonate (hereinafter referred to as the hydrated zirconium product). The process further comprises treating the solid hydrated zirconium product to obtain in situ formation of basic zirconium sulphate as a solid thereon. The invention also relates to such a process for producing zircon derived material suitable for pigments and to such a process to produce opacifier material. The invention also relates to products of such processes.
    Type: Grant
    Filed: June 6, 2000
    Date of Patent: June 20, 2006
    Assignee: University of Pretoria
    Inventors: Gert Hendrik Jacobus Coetzee, legal representative, Willem Johannes De Wet, deceased
  • Patent number: 6986873
    Abstract: A method of producing a single-phase composition Mn+1AzXn, primarily the production of the single-phase material Ti3SiC2, where n lies within a range of 0.8-3.2, where z lies within a range of 0.8-1.2, where M is at least one metal taken from the group of metals Ti (titanium), Sc (scandium), V (vanadium), Cr (chromium), Zr (zirconium), Nb (niobium) and Ta (tantalum), where X is at least one of the non-metals C (carbon) and N nitrogen), and where A is at least one of the chemical elements Si (silicon), Al (aluminum) and Sn (tin) or a compound of those elements, such that the final, desired compound will include the components Mn+1AzXn. A powder mixture of the components is formed and is ignited under an inert atmosphere to prevent promotion of dissociation and to cause the components to react.
    Type: Grant
    Filed: May 23, 2002
    Date of Patent: January 17, 2006
    Assignees: Sandvik AB, Drexel University
    Inventors: Mats Sundberg, Kjell Lindgren, Tamer El-Raghy, Michael Barsoum
  • Patent number: 6893623
    Abstract: A perovskite titanium-containing composite oxide particle having a composition represented by general formula (I), where the specific surface area is about 10 to about 200 m2/g, the specific surface area diameter D1 of primary particles defined by formula (II) is about 10 to about 100 nm, and a D2/D1 ratio of the average particle size D2 of secondary particles to D1 is about 1 to about 10: M(TiO3)??(I) wherein M is at least one of Ca, Sr, Ba, Pb, or Mg, D1=6/?S??(II) wherein ? is the density of the particles, and S is the specific surface area of the particles is disclosed. The present invention has a small particle size and excellent dispersion properties, so that the particle is suitable for application to functional materials.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: May 17, 2005
    Assignee: Showa Denko Kabushiki Kaisha
    Inventors: Masahiro Ohmori, Akihiko Kotera
  • Patent number: 6838404
    Abstract: A method of making a superconducting structure includes depositing a metal alkoxide on a surface of a metal and hydrolyzing the metal alkoxide on the surface to form a pinhole-free film. The metal is a superconductor. The metal alkoxide may be a compound of formula (I): M4(OPrn)16??(I); where M is zirconium or hafnium, and the purity of the compound is at least 97% as measured by NMR spectroscopy.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: January 4, 2005
    Assignee: Board of Trustees of University of Illinois
    Inventors: Patrick J. Hentges, Laura H. Greene, Margaret Mary Pafford, Glenn Westwood, Walter G. Klemperer
  • Patent number: 6706445
    Abstract: An electrochemical active material contains a lithiated zirconium, titanium, or mixed titanium/zirconium oxide. The oxide can be represented by the formula LiM′M″XO4, where M′ is a transition metal, M″ is an optional three valent non-transition metal, and X is zirconium, titanium, or a combination of the two. Preferably, M′ is nickel, cobalt, iron, manganese, vanadium, copper, chromium, molybdenum, niobium, or combinations thereof. The active material provides a useful composite electrode when combined with a polymeric binder and electrically conductive material. The active material can be made into a cathode for use in a secondary electrochemical cell. Rechargeable batteries may be made by connecting a number of such electrochemical cells.
    Type: Grant
    Filed: October 2, 2001
    Date of Patent: March 16, 2004
    Assignee: Valence Technology, Inc.
    Inventors: Jeremy Barker, M. Yazid Saidi, Jeffrey L. Swoyer
  • Patent number: 6685909
    Abstract: Mesoporous nanocrystalline titanium dioxide heterojunction materials and methods of making the same are disclosed. In one disclosed embodiment, materials comprising a core of titanium dioxide and a shell of a molybdenum oxide exhibit a decrease in their photoadsorption energy as the size of the titanium dioxide core decreases.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: February 3, 2004
    Assignee: Battelle Memorial Institute
    Inventors: Scott H. Elder, Yali Su, Yufei Gao, Steve M. Heald
  • Patent number: 6627164
    Abstract: A method of making sodium zirconium carbonate is described which involves forming a mixture of zirconium oxychloride with soda ash and then heating at a sufficient temperature and for a sufficient time to form the sodium zirconium carbonate. Subsequent washing and filtration steps can further form parts of this process. A novel sodium zirconium carbonate is further described which contains from about 2 wt % to about 5 wt % Na+; from about 44 wt % to about 50 wt % ZrO2; from about 12 wt % to about 18 wt % CO32−; and from about 32 wt % to about 35 wt % H2O.
    Type: Grant
    Filed: November 28, 2000
    Date of Patent: September 30, 2003
    Assignee: Renal Solutions, Inc.
    Inventor: Raymond J. Wong
  • Patent number: 6602919
    Abstract: Methods for preparing hydrous zirconium oxide spherules, hydrous zirconium oxide gels such as gel slabs, films, capillary and electrophoresis gels, zirconium monohydrogen phosphate spherules, hydrous zirconium oxide spherules having suspendable particles homogeneously embedded within to form a composite sorbent, zirconium monohydrogen phosphate spherules having suspendable particles of at least one different sorbent homogeneously embedded within to form a composite sorbent having a desired crystallinity, zirconium oxide spherules having suspendable particles homogeneously embedded within to form a composite, hydrous zirconium oxide fiber materials, zirconium oxide fiber materials, hydrous zirconium oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, zirconium oxide fiber materials having suspendable particles homogeneously embedded within to form a composite and spherules of barium zirconate.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: August 5, 2003
    Assignee: UT-Battelle LLC
    Inventor: Jack L. Collins
  • Patent number: 6395241
    Abstract: The process of the present invention relates to a process for recovering the carbide metal from metal carbide scrap wherein the metal is tungsten, titanium, vanadium, chromium or molybdenum, and this process comprises (A) providing a mixture comprising the metal carbide scrap and at least a stoichiometric amount, based on the amount of carbide metal present in the scrap, of an alkali metal hydroxide, (B) heating the mixture in the presence of oxygen at an elevated temperature and pressure for a period of time sufficient to form a water soluble alkali metal salt of the carbide metal, and (C) recovering the water soluble alkali metal salt.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: May 28, 2002
    Assignee: OM Group, Inc.
    Inventors: George P. Kinstle, Alex T. Magdics
  • Publication number: 20010014396
    Abstract: A process for producing an ultrafine mixed-crystal oxide characterized by producing an ultrafine mixed crystal oxide comprising primary particles in a mixed crystal state with a BET specific surface area of 10 to 200 m2/g, comprising the step of subjecting a halogenated metal to high temperature oxidation with an oxidizing gas to produce a metal oxide by a vapor phase production method, wherein said halogenated metal is in the form of a mixed gas (a mixed halogenated metal gas) comprising at least two compounds having a different metal elements selected from the group consisting of chlorides, bromides, and iodides of titanium, silicon, and aluminum, and said mixed halogenated metal gas and said oxidizing gas are independently preheated to 500° C. or more prior to a reaction, a ultrafine mixed crystal oxide obtained by the process, and use of the oxide.
    Type: Application
    Filed: February 5, 2001
    Publication date: August 16, 2001
    Inventors: Jun Tanaka, Shinichiro Tomikawa
  • Patent number: 6106799
    Abstract: A titanate ion exchanger and method of producing same. Solid hydrous titanium oxide in a slurry is reacted with an alkaline agent, such as NaOH, containing an exchangeable cation. A solids fraction containing the titanate product is settled and separated and a granular titanate ion exchanger product recovered from the solids fraction. The ion exchanger is suitable for the separation of radionuclides, such as those containing radioactive strontium, from nuclear waste solutions.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: August 22, 2000
    Assignee: Ivo International Ltd.
    Inventors: Jukka Lehto, Heikki Leinonen, Risto Harjula
  • Patent number: 5945035
    Abstract: The invention relates to electrically conductive pigments which as a conductive layer on a platelet-shaped or needle-shaped substrate have a niobium- and/or tantalum-doped tin oxide or titanium dioxide layer.
    Type: Grant
    Filed: November 14, 1997
    Date of Patent: August 31, 1999
    Assignee: Merck Patent Gesellschaft Mit Beschrankter Haftung
    Inventors: Reiner Vogt, Gerhard Pfaff
  • Patent number: 5573582
    Abstract: The present invention discloses a process for preparing a fine-particulate metal hydroxide comprising aluminum hydroxide as a major component which comprises continuously supplying water and a mixture of an aluminum alkoxide and at least one alkoxide of a metal selected from Mg, Ca, La, Fe, Si, Ti and Zr, to a high shear rate stirring area and a process for preparing a fine-particulate metal oxide comprising aluminum oxide as a major component which comprises drying and then calcining said metal hydroxide at 500.degree.-1500.degree. C.
    Type: Grant
    Filed: June 23, 1995
    Date of Patent: November 12, 1996
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Masamichi Inui, Yoshiaki Takeuchi, Yasushi Teshima, Koji Yamamoto, Makio Kimura, Takahiro Ishida