Anti-fouling Composition (e.g., Paints, Etc.) Patents (Class 424/78.09)
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Patent number: 12161977Abstract: Disclosed are devices, methods and/or systems for use in protecting items and/or structures that are exposed to, submerged and/or partially submerged in aquatic environments from contamination and/or fouling due to the incursion and/or colonization by specific types and/or kinds of biologic organisms and/or plants, including the protection from micro- and/or macro-fouling for extended periods of time of exposure to aquatic environments.Type: GrantFiled: April 30, 2021Date of Patent: December 10, 2024Assignee: BIOFOULING TECHNOLOGIES, INC.Inventors: Brian McMurray, Cliff Sharpe, Mike Termini, Emily Ralston, Abraham Stephens, Ed Dormier, Lindsey Calcutt, Joseph Basista
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Patent number: 11812749Abstract: In an aspect, a method of making a composite comprises mixing titanium dioxide in a aqueous solution comprising an acid to form a titanium dioxide mixture; mixing an aniline monomer and an oxidizing agent with the titanium dioxide mixture to form a reaction mixture; and polymerizing the aniline monomer to form the composite comprising polyaniline and the titanium dioxide; wherein the titanium dioxide has an average particle size of 0.5 to 100 nm; and wherein the acid is free of a (C8+ alkyl) benzene sulfonic acid or a derivative thereof. In another aspect, a composite comprises a plurality of titanium dioxide having an average particle size of 0.5 to 100 nm; a polyaniline; at least one of hydrochloric acid or 2-acryamido-2-propanesulfonic acid or a derivative thereof; wherein the composite is free of a (C8+ alkyl) benzene sulfonic acid or a derivative thereof.Type: GrantFiled: May 14, 2021Date of Patent: November 14, 2023Assignee: THE UNIVERSITY OF MASSACHUSETTSInventors: Sanjeev K. Manohar, Carl Lawton, Lekha Papammagari
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Patent number: 11732144Abstract: Provided is an antifouling coating composition, which can form a coating film having good hardness and good physical properties and having a wear degree appropriate for expressing a long-term antifouling effect, has a viscosity not being excessively high, and makes it possible to reduce a content of volatile organic compounds, and a polymer-containing composition which is suitable for obtaining the antifouling coating composition. The polymer-containing composition contains a (meth)acryl-based copolymer (A-1), in which the (meth)acryl-based copolymer (A-1) contains a constitutional unit (U11) or a constitutional unit (U12) having carboxylate forming an ionic bond with a divalent metal atom, and has a weight-average molecular weight of 1,000 to 5,000, and the polymer-containing composition has a coating film hardness (Martens hardness) equal to or higher than 2.5 N/mm2.Type: GrantFiled: February 4, 2021Date of Patent: August 22, 2023Assignee: Mitsubishi Chemical CorporationInventors: Kana Taniguchi, Sho Katsumata, Junichi Nakamura, Nobuaki Kanazawa
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Patent number: 11415261Abstract: The present invention is directed to a coated conduit comprising: a) a conduit having an interior and exterior surface; and b) a cured coating formed from a reaction mixture that is applied to at least one surface of the conduit. The reaction mixture comprises: i) a filler material comprising fibers ranging in length from 0.1 to 15.54 cm and having an aspect ratio of at least 5; and ii) a reactive component that demonstrates a tack-free time of less than five minutes at a temperature of 20 to 25° C. The present invention is also directed to a method of repairing or reinforcing a conduit, comprising: (a) applying a curable coating composition to at least one surface of the conduit, wherein the curable coating composition is formed from the reaction mixture described above; and (b) allowing the curable coating composition to at least partially cure by exposing the composition to ambient conditions.Type: GrantFiled: August 19, 2020Date of Patent: August 16, 2022Assignee: PPG Industries Ohio, Inc.Inventors: Brandon Cash, Cynthia Kutchko, Howard L. Senkfor, Edward R. Millero, Jr., Kurt G. Olson, James C. Watson
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Patent number: 11414508Abstract: A (meth)acrylic copolymer of the present invention includes at least one constituent unit (A) selected from the group consisting of a constituent unit (A1) having at least one structure (I) represented by Formula (1), Formula (2), or Formula (3), a constituent unit (A2) containing a triorganosilyloxycarbonyl group, and a constituent unit (A3) having at least one structure (III) represented by Formula (4) or Formula (5), a constituent unit (B) derived from a specific polysiloxane block-containing polymerizable monomer (b), and a constituent unit (C) derived from a macromonomer (c).Type: GrantFiled: September 25, 2019Date of Patent: August 16, 2022Assignee: Mitsubishi Chemical CorporationInventors: Kana Taniguchi, Junichi Nakamura, Sho Katsumata
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Patent number: 11254823Abstract: An object of the present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that retains a high antifouling performance for a prolonged period of time and has an excellent damage resistance. Another object of the present invention is to provide an antifouling coating film formed with the antifouling coating composition, a substrate with an antifouling coating film and a method for producing the same, and an antifouling method using the antifouling coating film. The antifouling coating composition of the present invention contains a hydrolyzable polymer (A) containing a metal ester group, zinc oxide (B), and medetomidine (C), and has a content of the zinc oxide (B) in a solid content of the antifouling composition of 27 to 60% by mass.Type: GrantFiled: November 15, 2016Date of Patent: February 22, 2022Assignee: CHUGOKU MARINE PAINTS, LTD.Inventors: Jyunji Niimoto, Yusuke Hayashi, Satoshi Masuda, Hideyuki Tanaka
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Patent number: 11098205Abstract: The present invention is to provide an antifouling coating composition capable of forming an antifouling coating film that exhibits a high antifouling performance even in a marine area having a heavy fouling load by animal species such as barnacles, has excellent slime resistance, and is prevented from cracking. Further, the present invention is also to provide an antifouling coating film, a substrate with an antifouling coating film and a method of producing the substrate, and an antifouling method, each using the composition. The antifouling coating composition of the present invention contains a polyorganosiloxane block-containing hydrolyzable copolymer (A) and medetomidine (B), wherein the polyorganosiloxane block-containing hydrolyzable copolymer (A) contains (i) a constituent unit derived from a hydrolyzable group-containing monomer (a1) and (ii) a constituent unit derived from a polyorganosiloxane block-containing monomer (a2).Type: GrantFiled: November 9, 2016Date of Patent: August 24, 2021Assignee: CHUGOKU MARINE PAINTS, LTD.Inventors: Jyunji Niimoto, Soichiro Tanino
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Patent number: 10954394Abstract: Provided is an antifouling coating composition, which can form a coating film having good hardness and good physical properties and having a wear degree appropriate for expressing a long-term antifouling effect, has a viscosity not being excessively high, and makes it possible to reduce a content of volatile organic compounds, and a polymer-containing composition which is suitable for obtaining the antifouling coating composition. The polymer-containing composition contains a (meth)acryl-based copolymer (A-1), in which the (meth)acryl-based copolymer (A-1) contains a constitutional unit (U11) or a constitutional unit (U12) having carboxylate forming an ionic bond with a divalent metal atom, and has a weight-average molecular weight of 1,000 to 5,000, and the polymer-containing composition has a coating film hardness (Martens hardness) equal to or higher than 2.5 N/mm2.Type: GrantFiled: December 4, 2018Date of Patent: March 23, 2021Assignee: Mitsubishi Chemical CorporationInventors: Kana Taniguchi, Sho Katsumata, Junichi Nakamura, Nobuaki Kanazawa
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Patent number: 10792883Abstract: The present invention is directed to a coated conduit comprising: a) a conduit having an interior and exterior surface; and b) a cured coating formed from a reaction mixture that is applied to at least one surface of the conduit. The reaction mixture comprises: i) a filler material comprising fibers ranging in length from 0.1 to 15.54 cm and having an aspect ratio of at least 5; and ii) a reactive component that demonstrates a tack-free time of less than five minutes at a temperature of 20 to 25° C. The present invention is also directed to a method of repairing or reinforcing a conduit, comprising: (a) applying a curable coating composition to at least one surface of the conduit, wherein the curable coating composition is formed from the reaction mixture described above; and (b) allowing the curable coating composition to at least partially cure by exposing the composition to ambient conditions.Type: GrantFiled: August 17, 2017Date of Patent: October 6, 2020Assignee: PPG Coatings Europe B.V.Inventors: Brandon Cash, Cynthia Kutchko, Howard L. Senkfor, Edward R. Millero, Jr., Kurt G. Olson, James C. Watson
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Patent number: 10590333Abstract: Surfactant compositions for enhancing oil and/or gas production from certain subterranean formations (e.g., unconventional reservoirs), and related methods of use, are provided. In one embodiment, the methods comprise: providing a treatment fluid comprising a carrier fluid and a cationic surfactant comprising at least two hydrophobic heads that each comprise a quaternary cationic moiety; and introducing the treatment fluid into at least a portion of a subterranean formation.Type: GrantFiled: December 22, 2014Date of Patent: March 17, 2020Assignee: Multi-Chem Group, LLCInventors: Kai He, Funian Zhao, Liangwei Qu, Liang Xu
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Patent number: 10487216Abstract: Provided are a coating composition containing a silicon atom-containing resin and an anti-sagging agent, a coating film formed from the same, an in-water structure and a ship including the coating film. In the coating composition, the silicon atom-containing resin includes a constituent unit (A) derived from a monomer (a) having at least one kind of silicon atom-containing group selected from the group consisting of groups represented by the formula (I), the formula (II), the formula (III), and the formula (IV), the monomer (a) has a molecular weight of greater than or equal to 400 and less than or equal to 2500, and the content of the anti-sagging agent is greater than or equal to 0.7 parts by mass and less than or equal to 3.6 parts by mass with respect to 100 parts by mass of the silicon atom-containing resin.Type: GrantFiled: March 30, 2018Date of Patent: November 26, 2019Assignee: NIPPON PAINT MARINE COATINGS CO., LTD.Inventors: Yusuke Takao, Tomohiro Tsuji, Wataru Kitamura, Yasuhisa Nagase, Hirokazu Kaji
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Patent number: 10385151Abstract: A material non-adhesive to a biological substance containing: a polymer compound (A) which includes a repeating unit derived from a sulfobetaine monomer represented by Formula (I) or (II). In the formulae, R1 represents a methyl group, an ethyl group, an n-propyl group, or an isopropyl group, a plurality of R1's may be the same as or different from each other. R2 represents a hydrogen atom or a methyl group. n represents an integer of 2 to 4. L represents a linear or branched alkylene group having 3 or 4 carbon atoms.Type: GrantFiled: April 28, 2017Date of Patent: August 20, 2019Assignee: FUJIFILM CorporationInventor: Kiyotaka Fukagawa
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Patent number: 10246628Abstract: Compounds comprising multiple hydrophilic heads and a lipophilic tail may be contacted with a metal or other surface so as to adhere to the surface and inhibit corrosion, among other things. Suitable hydrophilic heads may include quaternary ammonium cation moieties, phosphonium cation moieties, and combinations thereof. Such corrosion-inhibiting compounds may be introduced into a wellbore penetrating at least a portion of a subterranean formation, for instance in oil and/or gas recovery operations and the like, whereupon the compound may adhere to a metal or other surface downhole so as to inhibit corrosion of the surface. These compounds may be employed in various other environments, such as any metal or other surface that may be exposed to corrosive conditions.Type: GrantFiled: March 22, 2017Date of Patent: April 2, 2019Assignee: MULTI-CHEM GROUP, LLCInventors: Liangwei Qu, Nathan Darrell Davis, Funian Zhao, Qiang Fu
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Patent number: 9688873Abstract: The present invention is directed to curable film-forming compositions comprising acrylic polymers, and to coated substrates comprising the curable film-forming composition applied to at least one surface of the substrates. The acrylic polymers comprise epoxy functional groups and polydialkylsiloxane functional groups. The present invention is also drawn to methods of mitigating dirt build-up on a substrate, comprising applying to at least a portion of the substrate the curable film-forming composition described above and at least partially curing the curable film-forming composition.Type: GrantFiled: July 9, 2014Date of Patent: June 27, 2017Assignee: PPG Industries Ohio, Inc.Inventors: Shanti Swarup, W David Polk
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Patent number: 9655831Abstract: The present invention relates to a bar soap composition that contains zinc pyrithione (ZPT) and a metal-pyridine oxide complex, preferably a zinc-pyridine oxide complex. The bar soap may be characterized by enhanced discoloration resistance, extended shelf life, and/or increased anti-microbial efficacy.Type: GrantFiled: February 26, 2014Date of Patent: May 23, 2017Assignee: The Procter & Gamble CompanyInventors: Chunpeng Jiang, Brian Joseph Limberg, Edward Dewey Smith, III, Juan Wang, Zhe Liu, Enjun Cheng, Casey Patrick Kelly, Jason Edward Cook, Patrick Christopher Stenger
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Patent number: 9650659Abstract: The present invention discloses a microfluidic photoreaction system and a method for screening a single cell organism having changed light-response characteristics. According to the present invention, an improved single cell organism can be effectively screened based on phototaxis using a microfluidic system. Specifically, easy monitoring at the cellular level is possible, and a mutant strain having an increased response and/or sensitivity to light can be easily and rapidly screened by various analyses, including statistical analysis of collected results. Thus, the present invention can be effectively used to investigate the correlation between phototaxis and photoconversion efficiency and to screen a single cell organism having increased photosynthetic efficiency.Type: GrantFiled: January 14, 2014Date of Patent: May 16, 2017Assignee: KOREA UNIVERSITY RESEARCH AND BUSINESS FOUNDATIONInventors: Sang Jun Sim, Young Hwan Kim, Ho Seok Kwak
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Patent number: 9637679Abstract: Compounds comprising multiple hydrophilic heads and a lipophilic tail may be contacted with a metal or other surface so as to adhere to the surface and inhibit corrosion, among other things. Suitable hydrophilic heads may include quaternary ammonium cation moieties, phosphonium cation moieties, and combinations thereof. Such corrosion-inhibiting compounds may be introduced into a wellbore penetrating at least a portion of a subterranean formation, for instance in oil and/or gas recovery operations and the like, whereupon the compound may adhere to a metal or other surface downhole so as to inhibit corrosion of the surface. These compounds may be employed in various other environments, such as any metal or other surface that may be exposed to corrosive conditions.Type: GrantFiled: May 5, 2014Date of Patent: May 2, 2017Assignee: Halliburton Energy Services, Inc.Inventors: Liangwei Qu, Nathan Darrell Davis, Funian Zhao, Qiang Fu
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Patent number: 9416282Abstract: The disclosure described herein includes antifouling compositions, methods of antifouling by adhesion suppression and methods of selecting an antifouling composition which suppresses marine animal adhesion or reduces the strength of marine animal adhesion by reducing or quenching the oxidative adhesion chemistry of the marine animal.Type: GrantFiled: May 16, 2012Date of Patent: August 16, 2016Assignee: Purdue Research FoundationInventors: Jonathan Wilker, Joshua Cloud, Christopher Clark, Thomas McCarthy
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Patent number: 9376575Abstract: The present invention is directed to a water-based paint composition for concrete and masonry surfaces, a method of coating a concrete or masonry surface, and a corresponding method of preparing a coated concrete or masonry surface. The paint composition includes about 10-50% by weight water, about 5-40% by weight colloidal silica particles, about 40-85% by weight of an inorganic pigment, and about 1-10% by weight of a polymer binder. The paint composition provides the coated surfaces with excellent resistance to a wide variety of weather conditions, and alleviates health and safety concerns associated with long-term exposure to conventional organic-based paints.Type: GrantFiled: March 27, 2015Date of Patent: June 28, 2016Assignee: MAGNECO/METREL, INC.Inventors: Charles W. Connors, Jr., Michael W. Anderson
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Patent number: 9045650Abstract: A film-forming polymer with improved chemical stability in antifouling coating applications, said polymer bearing pendant to its backbone a salt of (i) a basic group with a first pKa of the conjugate acid of at least 4.0 and (ii) an organic acid with a first pKa of 2.0 or less; said basic group being covalently bonded to the polymer backbone.Type: GrantFiled: August 10, 2009Date of Patent: June 2, 2015Assignee: AKZO NOBEL COATINGS INTERNATIONAL B.V.Inventors: Alistair Andrew Finnie, Clayton Price, Richard Mark Ramsden
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Patent number: 8999315Abstract: Bis-quaternary ammonium salts of formula wherein Y is a group of formula NR11R12+X? or NR7; n is 0 or 1; p is 1 or 2; r and q are independently 2, 3 or 4; X is an anionic counterion and R1R2R3N— and R4R5R6N— are independently selected from groups of formula —N(R13)2R8, —N(R14)3, —N(R13)3, —N(R13)2(CH2)qOC(O)R9, and wherein R7, R11 and R12 are independently selected from C1-C18 alkyl; R8, R9, R10 and R15 are independently selected from C8-C18 alkyl and C8-C18 alkenyl; R13 is C1-C4 alkyl; R14 is C2-C4 hydroxyalkyl; and R11 is selected from C2-C4 hydroxyalkyl, C2-C4 aminoalkyl and groups of formula —CH2)rNHC(O)R15 are effective inhibitors of corrosion and biofouling of metallic surfaces in contact with gas- and oil-field fluids.Type: GrantFiled: July 15, 2004Date of Patent: April 7, 2015Assignee: Nalco CompanyInventors: Kevin M. Henry, Keith D. Hicks
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Patent number: 8974775Abstract: There is provided herein a functionalized ionic silicone composition comprising a silicone of the formula (I): M1aM2bM3cD1dD2eD3fT1gT2hT3iQj??(I) which contains a monovalent radical bearing ion-pairs and having the formula (II): -A-Ix?Mny+; where A is a spacing group having at least 2 spacing atoms selected from a divalent hydrocarbon or hydrocarbonoxy group, where I is an ionic group such as sulfonate —SO3?, carboxylate —COO?, phosphonate —PO32? group and phosphate —OPO32?, where M is hydrogen or a cation independently selected from alkali metals, alkali earth metals, transition metals, metals, quaternary ammonium and phosphonium groups; or, zwitterions having the formula (III): —R?—NR?2+—R??—I??(III) where I is defined as above, and where the subscript a, b, c, d, e, f, g, h, i, j are zero or positive subject to the following limitations: 2?a+b+c+d+e+f+g+h+i+j?6000, b+e+h>0 and c+f+i>0.Type: GrantFiled: January 4, 2012Date of Patent: March 10, 2015Assignee: Momentive Performance Materials Inc.Inventors: Anubhav Saxena, Alok Sarkar, Sandip Tiwari
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Publication number: 20150056156Abstract: The method for making a marine antifouling coating comprising a hydrophobic polymeric material formed by reacting a mixture comprising at least one ethylene propylene diene terpolymer (EPDM). The terpolymer component can comprises from 4 weight percent to 50 weight percent of random covalently linked monomers of ethylene and propylene and 0.25 weight percent to 15 weight percent of the polymer component is a non-conjugated diene, a first co-agent of polybutadiene, a second co-agent of an acrylate or methacrylate in a solvent with at least one peroxide.Type: ApplicationFiled: October 31, 2014Publication date: February 26, 2015Inventors: Zhiyong Zhu, Harold William Young, JR.
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Publication number: 20150050232Abstract: A marine antifouling coating comprising a hydrophobic polymeric material formed by reacting a mixture comprising at least one ethylene propylene diene terpolymer, wherein the terpolymer component comprises from 4 weight percent to 50 weight percent of random covalently linked monomers of ethylene and propylene and 0.25 weight percent to 15 weight percent of the polymer component is a non-conjugated diene, a first co-agent of polybutadiene, a second co-agent of an acrylate or methacrylate in a solvent with at least one peroxide. The marine antifouling coating is used for application to a surface of a marine vessel.Type: ApplicationFiled: October 31, 2014Publication date: February 19, 2015Inventors: Zhiyong Zhu, Harold William Young, JR.
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Patent number: 8900641Abstract: An antimicrobial composition prepared by mixing a polymer-ammonium salt formulation comprising one or more polymers and one or more ammonium salts with alkali and a chlorine source in a molar ratio of chlorine (as Cl2) to ammonium ion of about 1:10 to about 10:1 and methods of using the composition to control biofouling of aqueous systems.Type: GrantFiled: February 13, 2009Date of Patent: December 2, 2014Assignee: Nalco CompanyInventors: Manian Ramesh, Cathy C. Doucette, Andrew J. Cooper
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Publication number: 20140348776Abstract: The invention provides a composition comprising: (a) about 0% to 99% by weight of at least one resin wherein the resin is selected from the group consisting of epoxy, latex, polyurethane, polyurea, polyspartic, or alkyd resins; (b) about 1%-99% by weight of tristyrenated phenol or distyrenated phenol; and (c) optionally about 2% to 98% by weight of an additional solvent.Type: ApplicationFiled: April 22, 2014Publication date: November 27, 2014Inventors: Charles Francis Palmer, JR., Gerald Vandezande
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Publication number: 20140341962Abstract: A composition is provided with increased release comprising an encapsulated active and one or more metal additive. Also provided is a coating composition comprising an encapsulated active, and one or more metal additive, and one or more binder polymer, one or more binder precursor, or a mixture thereof, and one or more pigment. Also provided is a method of making such compositions. Also provided is a method of providing a surface that resists marine fouling wherein said method comprises applying a layer of such compositions to a substrate and drying said layer or allowing said layer to dry.Type: ApplicationFiled: December 27, 2012Publication date: November 20, 2014Inventors: John W. Ashmore, Boris Polanuyer, David Laganella
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Publication number: 20140322287Abstract: Antimicrobial and antithrombogenic polymer or polymeric blend, compounds, coatings, and materials containing the same, as well as articles made with, or coated with the same, and methods of making the same exhibiting improved antimicrobial properties and reduced platelet adhesion. Embodiments include polymers with antimicrobial and antithrombogenic groups bound to a single polymer backbone, an antimicrobial polymer blended with an antithrombogenic polymer, and medical devices coated with the antimicrobial and antithrombogenic polymer or polymeric blend.Type: ApplicationFiled: April 28, 2014Publication date: October 30, 2014Inventors: Simon Onis, Fanny Burrows, Krishan Kapoor, Alan Rhodes, Ajay Luthra
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Publication number: 20140299538Abstract: Disclosed are methods of preparing antifouling and chlorine-resistant coatings on reverse osmosis membranes with initiated chemical vapor deposition. The coatings enhance the stability and lifetime of membranes without sacrificing performance characteristics, such as permeability or salt retention.Type: ApplicationFiled: April 7, 2014Publication date: October 9, 2014Applicant: Massachusetts Institute of TechnologyInventors: Karen K. Gleason, Rong Yang
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Publication number: 20140287016Abstract: The invention provides methods of immobilizing an active agent to a substrate surface, including the steps of, depositing a primer compound on a substrate, thereby forming a primed substrate, contacting the primed substrate with a solution of a compound including a trihydroxyphenyl group, thereby forming a trihydroxyphenyl-treated primed substrate, and contacting the trihydroxyphenyl-treated primed substrate with a solution of an active agent, thereby immobilizing the active agent on the substrate. Further provided are methods of immobilizing an active agent on a substrate, including the steps of providing a substrate, combining a solution of a compound including a trihydroxyphenyl group with a solution of an active agent, thereby forming a solution of an active agent-trihydroxyphenyl conjugate, and contacting the primed substrate with the solution of the active agent-trihydroxyphenyl conjugate, thereby immobilizing the active agent on the substrate.Type: ApplicationFiled: March 14, 2014Publication date: September 25, 2014Applicants: BAXTER INTERNATIONAL INC., NORTHWESTERN UNIVERSITY, BAXTER HEALTHCARE SAInventors: Ton That Hai, John-Bruce Devault Green, Timothy Michael Fulghum, Phillip Byron Messersmith, Tadas Stanislovas Sileika
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Patent number: 8828414Abstract: Provided are biocidal compositions comprising 2,6-dimethyl-m-dioxane-4-ol acetate and a non-formaldehyde releasing biocidal compound selected from the group consisting of: a brominated nitroalkanol, a 2-halo-2-(halomethyl)glutaronitrile, and 2-phenoxyethanol. The compositions are useful for controlling microorganisms in aqueous or water containing systems.Type: GrantFiled: March 26, 2009Date of Patent: September 9, 2014Assignee: Dow Global Technologies LLCInventors: Kathy J. Ji, Donald J. Love, Jon B. Raymond
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Patent number: 8815271Abstract: This document discloses molecules having the following formula (“Formula One”): and processes related thereto.Type: GrantFiled: October 31, 2011Date of Patent: August 26, 2014Assignee: Dow AgroSciences, LLC.Inventors: Maurice C. H. Yap, Ann M. Buysse, Daniel Knueppel, Yu Zhang, Negar Garizi, Noormohamed M. Niyaz, Christian T. Lowe, Ricky Hunter, Tony K. Trullinger, David A. Demeter, Dan Pernich, Carl Deamicis, Ronald Ross, Jr., Timothy C. Johnson
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Patent number: 8795787Abstract: The invention relates to a carrier comprising at least one substrate, which has a coating in at least certain regions produced from individual modules by plasma polymerization, and the coating has one or more free spaces in at least certain regions for accommodating at least one solution containing a biological sample.Type: GrantFiled: October 10, 2008Date of Patent: August 5, 2014Assignee: Greiner Bio-One GmbHInventor: Heinrich Jehle
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Publication number: 20140147480Abstract: A copolymer comprising trans-1,3,3,3-tetrafluoropropene units and vinylidene fluoride units, and methods of making the same. A method of preventing biofouling on an article of manufacture, comprising applying such copolymer to the article of manufacture. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising applying such a copolymer to a support. A method of preventing accumulation of ice on an article of manufacture, comprising applying such a copolymer to an article of manufacture. A method of preparing a polymer, comprising a step of adding trans-1,3,3,3-tetrafluoropropene/vinylidene fluoride copolymer as a polymer processing additive/aid to said polymer.Type: ApplicationFiled: November 11, 2013Publication date: May 29, 2014Applicant: Honeywell International Inc.Inventors: Changqing Lu, Andrew J. Poss, Rajiv R. Singh, David Nalewajek, Cheryl Cantlon
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Patent number: 8722579Abstract: An aqueous composition for treatment of water comprising: (a) an N,N-dimethyl-2-hydroxypropylammonium chloride polymer; (b) lanthanum chloride; and (c) a dimethylamine epichlorohydrin ethylenediamine polymer; and a method of treating water using the composition.Type: GrantFiled: February 10, 2012Date of Patent: May 13, 2014Assignee: Waterco LimitedInventors: Robert Ian Anderson, Paul Seidl
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Patent number: 8703112Abstract: This invention provides low odor stable coating compositions, and methods of their production. The stable aqueous coating compositions and paints comprise one or more emulsion-polymerized addition polymer and one or more carboxylesterase enzyme having an ester hydrolysis activity in the composition of less than 0.03 micromole/minute, wherein the aqueous coating composition has a headspace volatile organic compound (VOC) content, as measured by headspace gas chromatography-mass spectrometry (GC-MS) at 33° C., of less than 10 ppm of the one or more organic carboxylester with a normal boiling point of less than 150° C. and more than 50 ppm of the one or more mono-alcohol with a formula molecular weight of less than 76.Type: GrantFiled: October 1, 2010Date of Patent: April 22, 2014Assignee: Rohm and Haas CompanyInventors: James Bohling, Paul Doll, David Frattarelli, Alvin Maurice
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Patent number: 8657943Abstract: 1-OH-2-acyl-sn-glycero-3-phosphocholine compounds and its analogs, pure or mixed, having formula WCH2CHXCH2PO3YCH2CH2Z, where W is preferably a hydroxyl group or an O-acyl group containing from 2 to 22 carbon atoms, and where X is preferably an O-acyl group containing from 2 to 22 carbon atoms or a hydroxyl (OH) and where Y may be an (O?) or OH and where Z is preferably a trimethyl-ammonium group [N+(CH3)3] can be protonated dimethyl ammonium [N+H(CH3)2] group. In the O-acyl groups containing 18 carbon atoms can be observed from 0 to 3 instaurations, useful as biocidal agents; processes for their preparation; and antifouling compositions, preferably paints useful in susceptible fouling surfaces, such as hulls of vessels. Methods to turn a surface into an antifouling surface, to a method to prevent fouling and to the antifouling surfaces comprising a coating of the said antifouling composition.Type: GrantFiled: November 30, 2011Date of Patent: February 25, 2014Assignee: UFRJ, IEAPM, UFFInventors: William Romao Batista, Ricardo Coutinho, Maria Campos Beta Neves, Claudio Cerqueira Lopes, Rosangela Sabbatini Lopes, Vanessa de Almeida Martins, Renato Crespo Pereira
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Publication number: 20140044764Abstract: A copolymer comprising 2,3,3,3-tetrafluoropropene and vinylidene fluoride and having a surface energy of between about 20 and about 30 mJ/m2. A process of preparing a surface having a surface energy of between about 20 and about 30 mJ/m2, comprising a step of applying said copolymer to a support. A method of preventing biofouling on an article of manufacture comprising applying said copolymer to the article of manufacture. An article of manufacture that is at least partly covered with said copolymer.Type: ApplicationFiled: March 7, 2013Publication date: February 13, 2014Applicant: HONEYWELL INTERNATIONAL INC.Inventors: Changqing Lu, Andrew J. Poss, Rajiv R. Singh, David Nalewajek, Cheryl Cantlon
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Publication number: 20140037572Abstract: A compound includes a boron atom attached to at least one C8-C26 fatty acid residue having at least one C?C moiety. Such compounds are polymerizable through the at least one C?C moiety. Polymers thus formed exhibit anti-fouling properties when used as coatings.Type: ApplicationFiled: July 25, 2013Publication date: February 6, 2014Applicant: Empire Technology Development LLCInventors: William Brenden CARLSON, Gregory David PHELAN
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Publication number: 20140037704Abstract: An antifouling composition including a compound having a dioxaborinane moiety is provided. Methods of killing, or deterring the growth of, one or more organisms on an article include coating or impregnating the article with the antifouling composition, where the organisms live in fresh water or salt water.Type: ApplicationFiled: February 7, 2013Publication date: February 6, 2014Applicant: Empire Technology Development LLCInventors: William B. CARLSON, Gregory D. PHELAN
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Publication number: 20140010853Abstract: The invention relates to a coating composition for use as a coating to prevent fouling in a marine environment, comprising: a) a curable polysiloxane polyoxyalkylene block copolymer; b) a catalyst of general formula (i) wherein each R1 is independently a monovalent hydrocarbon group, each R2 is independently selected from a hydrogen atom, a monovalent organic group, a siloxane group, or a silyl group of formula —SiR33, wherein each R3 is independently a monovalent hydrocarbon group, and n is an integer having a value of 0 or greater, and optionally: c) a filler and/or pigment.Type: ApplicationFiled: March 28, 2012Publication date: January 9, 2014Applicant: Akzo Nobel Coatings International B.V.Inventors: David Neil Williams, David Anthony Stark, Lyndsey Tyson
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Patent number: 8618066Abstract: Coating compositions having a peptidic antimicrobial additive and an antimicrobial additive of another configuration are provided. The concentrations of the antimicrobial agents within the coating composition are sufficient to synergistically inhibit microbial growth on an inanimate surface coated with the surface coating composition or within a container storing the coating composition. Methods for making and using such compositions to inhibit microbial growth in stored coatings and on susceptible surfaces are also provided.Type: GrantFiled: October 1, 2007Date of Patent: December 31, 2013Assignee: Reactive Surfaces, Ltd., LLPInventor: C. Steven McDaniel
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Cosmetic composition containing novel fractal particle based gels having improved optical properties
Patent number: 8603505Abstract: A method of instantly reducing the appearance of wrinkles and skin imperfections while smoothing the skin, which comprises applying a cosmetic composition in the form of an oil-in-water emulsion comprising a fractal particle based gel and refractive index matching polymers with respect to at least one of the fractal particles. The composition of the invention provides both optical blurring and skin smoothing effect on the skin.Type: GrantFiled: December 21, 2006Date of Patent: December 10, 2013Assignee: Avon Products, Inc.Inventors: Steven E. Brown, Ernest S. Curtis -
Patent number: 8603452Abstract: The invention comprises a biological hydrogel that is chemically stabilized with non-covalent or covalent cross-links. The biological hydrogel is used to coat surfaces of materials for submersion in marine water. Molecular dissolution at the marine water-hydrogel surface prevents attachment of fouling organisms. The rate of dissolution can be controlled by both the concentration of the biopolymer in the hydrogel and the nature and concentration of cross-linker used. Additional components, either molecular or particulate, can be added to the biological hydrogel before or after cross-linking for enhanced properties.Type: GrantFiled: May 2, 2008Date of Patent: December 10, 2013Assignee: University of South FloridaInventor: Thomas J. Koob
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Publication number: 20130315855Abstract: A cross-linkable coating composition comprises (i) one or more silanes having either at least three hydrolysable groups, or at least two hydrolysable groups and at least one organofunctional group capable of forming chemical bonds upon curing, wherein (i.a) the sum of said silanes constitutes at least 20% of the total mass of the coating compositions combined solids and silanes, and (i.b) said silanes are possibly partly or completely hydrolysed and possibly partly condensed, and (ii) at least one low surface energy additive, wherein (ii.a) said low surface energy additive comprises polydimethylsiloxane chemically bonded to at least one functional group, (ii.b) said functional group is configured for the polydimethylsiloxane moiety to cross-link with said coating composition, (ii.c) said polydimethylsiloxane constitutes 0.01% to 15% of the mass of said cured coating, when said coating composition is cured, and (ii.d) said polydimethylsiloxane moiety has a molecular weight of more than 1600 g/mol.Type: ApplicationFiled: December 20, 2011Publication date: November 28, 2013Applicant: Teknologisk InstitutInventors: Claus Bischoff, Stefan Holberg
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Patent number: 8552135Abstract: Linear polydialkoxysiloxanes with 2-8 polymeric units have been reacted with alcohols by a transetherification reaction to provide hydrophilic and water soluble silicone products. The glycerol substituted siloxanes in particular are effective in topically treating skin lesions such as radiation burns. Compositions including the substituted polydialkoxysiloxane products inhibit biofilm formation when used as coatings on hard surfaces.Type: GrantFiled: April 13, 2012Date of Patent: October 8, 2013Assignee: One Unlimited, Inc.Inventor: Leonard William Luria
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Patent number: 8524799Abstract: A biostatic coating comprising a coating composition which on drying produces an intrinsically hydrophobic film. The coating composition includes a biocidal complex A-B in which A is a phenolic biocide and B is selected from polyvinylpyrrolidone (“PVP”), PVP polymers, PVP copolymers and mixtures thereof. The coating composition for example is selected from acrylic and methacrylic polymer based compositions, acrylic and methacrylic copolymer based compositions, vinyl polymer based compositions, vinyl copolymer based compositions, epoxy resins, epoxy esters, and mixtures thereof. Suitable biocides for use in the invention include, but are not limited to complexes of PVP or PVP copolymer with triclosan; diclosan; dichlorophen; orthophenylphenol; orthobenzylparachlorophenol, cresols, xylols, and substituted diphenyl ethers.Type: GrantFiled: May 18, 2004Date of Patent: September 3, 2013Assignee: Novapharm Research (Australia) Pty LtdInventor: Steven Kritzler
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Patent number: 8512722Abstract: The disclosure provides methods and materials suitable for preparing coating layers on substrates. The coatings comprise quaternary amine groups and therefore impart anti-bacterial properties to the substrate. In one embodiment, for example, there is provided a quaternary amine-containing polymeric coating comprising propylene and ethylene repeat units.Type: GrantFiled: July 23, 2010Date of Patent: August 20, 2013Assignees: California Institute of Technology, University of Southern CaliforniaInventors: Choon Woo Lee, Robert H. Grubbs, Mark Humayun
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Publication number: 20130209389Abstract: The present invention provides polishing control components for anti-fouling paints for vessels which comprise rosin or other water-degradable polymers entrapped in gel particles, such as aerogel or aeromosil particles.Type: ApplicationFiled: March 2, 2011Publication date: August 15, 2013Applicants: Enpro ApS, Fibac ApSInventor: Henrik Tofte Jespersen
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Publication number: 20130195790Abstract: Disclosed herein are antifouling compositions including at least one spinosyn active material. These compositions provide protection to surfaces coated or impregnated therewith from attachment of various biofouling organisms. Compositions include, for example, paint, varnish, and sealant formulations.Type: ApplicationFiled: March 13, 2013Publication date: August 1, 2013Applicants: Entarco SAInventors: Entarco SA, Chistine Kritikou