Abstract: This invention relates to a 0.5 to 7 wt. % solids hair fixative composition having superior moisture resistant hold and minimal tack duration which provides a stiff film on artificial or human hair and superior hair combability, which composition essentially contains a resin mixture of (a) a terpolymer derived from about 17 to about 30 wt. % N-vinyl pyrrolidone, from about 60 to about 80 wt. % N-vinyl caprolactam and from about 3 to about 6 wt. % di-C.sub.1 -C.sub.4 alkyl amino-C.sub.1 -C.sub.4 alkyl-acrylate or methacrylate having a number average molecular weight of between about 20,000 and about 200,000 and (b) a N-vinyl pyrrolidone/vinyl acetate copolymer having a number average molecular weight of between about 10,000 and about 100,000; combined in a weight ratio of 1.4-6:1 (a) to (b).

Abstract: A polyurethane, soluble or dispersible in water, prepared from an organic diisocyante, a diol, and a 2,2-hydroxymethyl-substituted carboxylic acid is neutralized with a cosmetically acceptable organic or inorganic base and formulated into a hair fixative composition containing low amounts of volatile organic solvent.

Abstract: A low volatile organic compounds hair spray microemulsion in the form of a stable, clear, single phase system in which the particles therein have a diameter of less than 1 micron, consisting essentially of, by weight,(a) an ethyl half-ester of a copolymer of maleic anhydride and an alkyl vinyl ether in an amount of less than 20%, optionally neutralized up to 20 mole %,(b) an ethoxylated glycerol fatty acid ester as the surfactant having a hydrophobic-lipophilic balance of 10-18, in an amount of at least 0.1%,(c) ethanol in an amount of 55% or less, and(d) water to 100%.

Abstract: Low VOC hair spray resin compositions containing homogeneous terpolymers of vinyl pyrrolidone, vinyl caprolactam and 3-(N-dimethylaminopropyl) methacrylamide are described. The hair spray compositions are made using a solution of the terpolymer which is clear and low in viscosity, and which provides a spray of relative small particle size. The hair spray compositions exhibit an effective high humidity curl retention property.

Abstract: Aqueous, acrylic hair fixative compositions are disclosed which utilize a partially-neutralized acrylic hair fixative polymer. The polymer is neutralized in a solvent system in which water is always the major solvent constituent and organic solvents are optional. Methods of making the hair fixative compositions which require water as the primary solvent utilized to prepare the hair fixative compositions are also disclosed.

Abstract: A hair spray composition of 80% or less VOC includes a fixative which is the half-ester of a copolymer of maleic anhydride and methyl vinyl ether having advantageous physical and performance properties even at low fixative levels. The copolymer is made by polymerizing the monomers at a selected temperature in the presence of a predetermined amount of a polymerization initiator whose decomposition fragments are soluble in hydroalcoholic solutions containing high levels of water. The composition is clear and without precipitate formation, has a low weight average molecular weight and a narrow molecular weight distribution or polydispersity, affording a low solution viscosity. The composition also forms a spray pattern of small particle size, providing clear, hard fixative films with superior adhesion to the hair of the user, an advantageous high humidity curl retention (hold), and low tack and dry times, in both pump and aerosol products.

Abstract: The invention concerns the use of combinations of active substances, consisting of (a) a cationic derivative of a protein hydrolyzate and (b) a carbohydrate and/or (c) a cationic, anionic or ampholytic polymer, in hair-cleaning and hair-care agents, thus improving the qualities of the hair, in particular its brittleness and its ease of combing when dry.

Abstract: Ampholyte terpolymer conditioning additives for hair care products are disclosed which improve wet and dry hair combability, especially detangling and reduced static flyaway, sheen, and fixative properties, especially curl retention. The ampholyte terpolymers may have a weight average molecular weight of from about 10 thousand to 10 million, and comprise (a) from at least 1 to as much as 95 weight percent of a nonionic monomer, (b) from at least 5 to as much as 80 weight percent of a cationic monomer, and (c) from at least 1 to as much as 75 weight percent of an anionic monomer. In a preferred embodiment, the amount of the cationic and anionic components is such that the overall % net charge of the ampholyte terpolymer is between -5.0 and +5.0. The ampholyte terpolymers are added to hair care product formulations in amounts ranging from 0.1-10% by weight. They are particularly compatible with anionic surfactant shampoos, providing clear formulations without the loss of conditioning properties described above.

Abstract: Substantially homogeneous copolymers comprising 20-99% of vinyl pyrrolidone (VP) and 1-80% of N-3,3-dimethylaminopropyl methacrylamide, (DMAPMA), preferably 50-95% VP and 5-50% DMAPMA, and, most preferably, about 80:20, by weight, having a weight average molecular weight of about 200,000 to 1,500,000, as a clear, low viscosity aqueous solution of the homogeneous copolymer, at a 5-20% solids level, preferably about 10-15%, by weight of the solution, having a viscosity of about 5,000 to 80,000 cps, preferably about 10,000 to 70,000 cps. The solution obtained herein has lower viscosity and better clarity, and provides hair care products with enhanced curl retention (hold), when compared to non-homogeneous copolymers of the same composition, or related existing commercial products.

Abstract: Low VOC hair spray fixative compositions containing a fixative which is a tetramer of vinyl pyrrolidone, vinyl caprolactam, 3-(N-dimethylaminopropyl) methacrylamide and a C.sub.8 -C.sub.18 alkyl acrylamide or acrylate, in predetermined compositional ranges of each monomer, and molecular weight, are described. The hair spray compositions herein are clear and low in viscosity, and form a spray of relatively small particle size which spreads evenly on the hair of the user as clear films which exhibit an effective high humidity curl retention property, good stiffness, and low tack and short drying times.

Abstract: A hairspray composition is described that includes a nonionic polymer and an anionic polymer. The nonionic polymer is formed from monomers having at least one unneutralized carboxylic acid. The anionic polymer is identical to the nonionic one, except that all of the carboxylic acid groups are in salt form. Advantageously, the composition further includes an acrylic resin, most especially an amphoteric one. Best results are achieved when the acrylic resin is neutralized with a relatively small cation such as potassium and a second cation of a water soluble fatty amine. These compositions employ water as the carrier and dimethyl ether as propellant.

Abstract: Hair spray compositions in aqueous based systems containing 80% or less of volatile organic compounds exhibit a loss of spray performance properties resulting from viscosity and surface tension increases. The addition of 0.6 to 5% of one or more hydrophobic additives selected from the group consisting of hexamethyl disiloxane, bisphenyl hexamethicone and isocetyl alcohol improves the spray characteristics by eliminating foaming at the spray actuator and on the hair.

Abstract: A low volatile organic compound hair spray composition in the form of a stable, clear, single phase microemulsion in which the particles therein have a diameter of less than 1 micron, consisting essentially of by weight,(a) a butyl half-ester of a copolymer of maleic anhydride and ethyl vinyl ether in an amount of about 2-10%, optionally neutralized up to 20 mole %,(b) poly(methyl vinyl ether) as a surface active polymer in an amount of at least 0.75 to 1 part of (a);(c) a secondary surfactant that is a polyethoxylated glyceryl fatty acid ester in an amount of at least 0.1%, and which has a hydrophilic-hydrophobic balance of greater than 10,(d) ethanol in an amount of 20 to 50%, and(e) water to 100%.

Abstract: A cosmetic composition for setting the hair contains, in an aqueous or weakly hydroalcoholic medium, (a) 0.5 to 40 percent by weight relative to the total weight of the composition of a hydrodispersible polycondensate having sulfonate functions, and (b) 0.5 to 15 percent by weight relative to the total weight of the composition, of a hydrosoluble copolymer having at the same time patterns derived from vinyl acetate, at least one monomer having a neutralized carboxylic acid function and at least one monomer having cyclic ester function, the total neutralization amount of the said copolymer being greater than 80 percent. This composition exhibits excellent setting power while being removed very satisfactorily by washing with a shampoo.

Abstract: A hair setting agent composition is disclosed, which comprises: (A) 0.01 to 10% by weight of a water-dispersible polyester resin; (B) 0.01 to 10% by weight of at least one silicone derivative; and (C) 0.1 to 40% by weight of a C.sub.8-40 hydrocarbon oil. The hair setting agent composition according to the present invention exhibits excellent hair setting properties and set retaining properties and provides hairs with a nonsticky smooth finish touch and a natural gloss.

Abstract: Aqueous acrylic polymer compositions comprising a copolymer of an alkyl acrylate, an alkyl methacrylate and one or more acrylate acids or salts thereof are disclosed. By introducing an alkoxylated surfactant having a surface tension of greater than about 32.2 dynes/cm and less than 48.2 dynes/cm, enhanced freeze-thaw stability can be obtained with the polymer compositions of the present invention. The polymer compositions are compatible in all-aqueous hairspray compositions, as well as those which contain up to about 80 weight percent volatile organic compounds, or more.

Abstract: Aqueous aerosol lacquer contains, in solution in water, a copolymer having repeating units derived from the polymerization of:(i) least one unsaturated sulphonic acid in a proportion of 30 to 90% by weight and having the following general formula: ##STR1## in which: R.sub.1 denotes a hydrogen atom or the CH.sub.3 radical,X denotes --O-- or --NH--, andY denotes a linear or branched alkylene chain containing from 1 to 6 carbon atoms, and(ii) at least one N-monoalkylacrylamide or methacrylamide in a proportion of 10 to 70% by weight and having the following general formula: ##STR2## in which: R.sub.2 denotes a hydrogen atom or --CH.sub.3 radical andR.sub.3 denotes a linear or branched radical containing from 3 to 10 carbon atoms,the sulphonic acid functional groups of the copolymer being neutralized in a proportion of 40 to 70% with triethanolamine, and the propellent agent of the aerosol lacquer being dimethyl ether.

Abstract: Methods and compositions for semi-permanently conditioning hair by treating the hair, preferably following shampooing, with a composition including a low viscosity oil-in-water emulsion of a mixture of two polysiloxane polymers, that is, a hydroxy terminated dimethyl polysiloxane and a methyl hydrogen polysiloxane, the composition being at an acid pH. It is a feature of this invention that the polysiloxane polymers in the hair-treating composition are in an unreacted or non-crosslinked state. After the composition is applied to the hair, the crosslinking of the two polysiloxane polymers takes place on the hair resulting in a semi-permanent conditioning effect. Although some crosslinking of the polymers will occur while drying the treated hair at room temperatures, increased crosslinking occurs when the hair is blow dried using heated air.

Abstract: Microemulsion compositions comprising microemulsifiable high viscosity amino silicone fluids or gums and a surfactant having a high phase inversion temperature, the microemulsions formed therewith, a means for preparing said microemulsions, and personal care products comprising said microemulsions.

Abstract: Provided is a topical personal care composition, having improved drying time, said composition comprising: (a) a polysiloxane-grafted adhesive polymer; (b) a volatile, water insoluble solvent for said polysiloxane-grafted polymer; (c) a nonvolatile drying aid for said polysiloxane-grafted polymer which is soluble in said volatile solvent (b) at 45.degree. C. and is water insoluble at 25.degree. C., and is selected from the group consisting of silicone fluids and waxes having from 1 to about 100 siloxy units, silanes, and silicone resins and mixtures thereof; wherein the weight ratio of said polysiloxane-grafted polymer (a) to said drying aid (c) is about 100:1 or less.

Abstract: Hair fixative carboxylated polymers are stabilized in an aqueous emulsion by neutralization with a cosmetically acceptable organic or inorganic base, require no organic solvent, no propellant when dispensed in non-aerosol containers, and minimal organic propellant when dispensed in aerosol containers.

Abstract: A hair cosmetic is disclosed, which comprises the following components (a) and (b):(a) a poly(N-acylalkyleneimine )-modified silicone block or graph copolymer having a poly(N-acylalkyleneimine) segment and an organopolysiloxane segment at a weight ratio of said poly(N-acylalkyleneimine) segment to said organopolysiloxane segment of from 1/20 to 20/1, and having a molecular weight of from 500 to 500,000,wherein said poly(N-acylalkyleneimine) segment comprises a repeating unit represented by the following formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, a cycloalkyl group having 3 to 22 carbon atoms, an aralkyl group having 7 to 22 carbon atoms or an aryl group having 6 to 22 carbon atoms; and n is 2 or 3; and(b) a film-forming polymer.

Abstract: Cosmetic compositions are provided containing vinyl-silicone graft or block copolymers of the formula ##STR1##

Abstract: A 0% VOC, single phase hair spray composition of a water-insoluble polymer wherein substantially all the particles therein have a diameter of less than 1 micron, i.e. a microemulsion.

Abstract: An aqueous hair treatment composition is provided that includes a water-soluble polymer having a solution viscosity at 10% in water of less than about 20,000 cps at 25.degree. C., and a latex of water-insoluble polymeric particles dispersed in water and having a glass transition temperature between 250 and 300.degree. K., the average particle size being no higher than about 3 microns. Preferably the latex particles are formed from respective monomers by emulsion polymerization.

Abstract: Methods and compositions for semi-permanently conditioning hair by treating the hair, preferably following shampooing, with a composition including a low viscosity oil-in-water emulsion of a mixture of two polysiloxane polymers, that is, a hydroxy terminated dimethyl polysiloxane and a methyl hydrogen polysiloxane, the composition being at an acid pH. It is a feature of this invention that the polysiloxane polymers in the hair-treating composition are in an unreacted or non-crosslinked state. After the composition is applied to the hair, the crosslinking of the two polysiloxane polymers takes place on the hair resulting in a semi-permanent conditioning effect. Although some crosslinking of the polymers will occur while drying the treated hair at room temperatures, increased crosslinking occurs when the hair is blow dried using heated air.

Abstract: An 80% VOC, single phase aerosol hair spray composition based on greater than 15% hydrocarbons as propellant is described. The composition includes a predetermined small amount of dimethyl ether as cosolvent to assure solubilization of the hair fixative resin, alcohol, water and hydrocarbon components of the composition within a single phase.

Abstract: Aqueous, anionic, acrylic polymer compositions comprising a copolymer of an alkyl acrylate, an alkyl methacrylate and one or more acrylate acids or salts thereof is disclosed. By controlling the particle size of the copolymer and introducing a surfactant, enhanced freeze-thaw stability can be obtained with the polymer compositions of the present invention. The polymer compositions are compatible in all-aqueous hairspray compositions, as well as those which contain up to about 80 weight percent volatile organic compounds, or more.

Abstract: An aqueous composition free of nonaqueous solvents for cleansing, conditioning and styling the hair comprising:(a) 3-40% anionic surfactant,(b) 0.5-20% amphoteric surfactant,(c) 0.1-15% hair styling polymer,(d) 0.001-5% of a cationic conditioning polymer; and(e) 40-95% water.

Abstract: A hairspray/hair setting composition comprising:a) 0.001-20% of a neutralizable hair fixative resin,b) 0.001-8% of a base, andc) 0.001-5% of an acid surfactant precursorin an alcohol or aqueous/alcohol carrier.

Abstract: An aqueous, alcoholic or hydroalcholic composition containing one or more oligomers or prepolymers that are polymerized in-situ, while the oligomer(s) is in contact with the hair, for in-situ formation (polymerization) of a polymer. The oligomer compositions contain essentially no toxic, hazardous or harmful monomer(s), such as resorcinol.

Abstract: An aerosol composition packaged in a steel can is described. The composition includes water, a propellant and as a corrosion inhibitor, a small amount of ammonium benzoate. The corrosion inhibitor can further be supplemented with ammonium hydroxide.

Abstract: By incorporating an alkyl polyol and a water soluble or emulsifiable silicone based compound into a moderately viscous gel-type hair conditioning composition, a hair conditioning gel formulation is attained which is able to be delivered in a spray mist pattern using conventional small diametered pump spray nozzles. Preferably, the alkyl polyol has a carbon content ranging between 2 and 8, and the hydroxyl ion content ranges between 2 and 7 and are not spaced apart by more than 4 carbon atoms. It has been found that by employing this invention, the resulting gel formulation is able to be dispensed consistently, repeatedly and easily in a liquified spray mist through a pump nozzle having apertures ranging between about 0.010 and 0.030 mm.

Abstract: A clear hair spray composition exhibiting low drying times and low tack during use consisting essentially of, by weight of the composition,(a) 0-10% of a fixative resin that is a linear homopolymer or random copolymer including a monomer selected from the group consisting of a vinyl monomer and an acrylate monomer,(b) 0.01-10% of a hydrolyzed crosslinked maleic anhydride-C.sub.1 -C.sub.5 alkyl vinyl ether copolymer,(c) 10-99.99% water, and(d) 0-80% alcohol.

Abstract: This invention relates to hair spray formulations which eliminate flaking. The hair spray formulations are based on (1) a sulfonate-containing, water-dispersible or water-dissipatible, linear polyester having a glass transition temperature of 33.degree. C. to 60.degree. C., (2) a polyethylene glycol ester of a mixture of caprylic and capric acids, (3) an alpha-hydroxy carboxylic acid having 2 to 6 carbon atoms, and (4) water or a water/alcohol mixture.

Abstract: The hair fixative composition contains from about 2 to about 10 weight %, based on the weight of the composition, of a water-dispersible amorphous thermoplastic hair fixative polyester whose polymer chain is represented by the structure: ##STR1## wherein A is an aromatic dicarboxylic acid moiety, G is an aliphatic or cycloaliphatic glycol residue, on the average there being 5 to 8 sodiosulfo substituents per molecule. The fixative polyester is in colloidal suspension in the composition. The composition further contains from about 0.1 to about 3 weight %, based on the weight of the composition, of a copolymer containing dimethylpolysiloxane and organo-modified methylsiloxane moieties. Such amount is sufficient to cause the composition to spread out on a hair shaft when the composition is applied to same. The composition also contains from 0 to about 25 weight %, based on the weight of the composition, of a lower alcohol and sufficient water to bring the composition to 100 weight %.

Abstract: A hair care composition comprising N-alkoxyalkylamides of the formula: ##STR1## wherein p is a whole number from 1 to about 4, (C.sub.n H.sub.2n) is a straight or branched chain alkyl bridge in which n is a whole number of 1 to about 6, and is preferably 3,(C.sub.m H.sub.2m+1 is a straight or branched chain alkyl radical in which m is a whole number of 1 to about 6 and is preferably 1.

Abstract: A non-foaming, non-viscous, alcohol-free, water-based pressurized hair-fixative spray product for use as the total fill in an aerosol container by delivery from an actuated-valve of predetermined dimensions, particularly the vapor tap and stem orifice sizes.

Abstract: Ampholyte terpolymer conditioning additives for hair care products are disclosed which improve wet and dry hair combability, especially detangling and reduced static flyaway, sheen, and fixative properties, especially curl retention. The ampholyte terpolymers may have a weight average molecular weight of from about 10 thousand to 10 million, and comprise (a) from at least 1 to as much as 95 weight percent of the nonionic monomer acrylamide (AM), (b) from at least 5 to as much as 80 weight percent of the cationic monomer dimethyldiallylammonium chloride (DMDAAC), and (c) from at least 1 to as much as 75 weight percent of the anionic monomer acrylic acid (AA). In a preferred embodiment, the amount of the cationic and anionic components is such that the overall % net charge of the ampholyte terpolymer is between -5.0 and +5.0. The ampholyte terpolymers are added to hair care product formulations in amounts ranging from 0.1-10% by weight.

Abstract: A hair spray composition exhibiting high curl retention, fast drying time, high rinse-out with low flaking and high shine characteristics comprised of fixative resins, silicone plasticizers and neutralizers in a crystal clear formulation which meets or exceeds the currently mandated alcohol requirements in a hand pump spray application.

Abstract: A pretreatment conditioner comprising an aqueous system of from about 0.1 to about 20 weight percent of a cationic cellulose derivative quaternized with fatty C.sub.10 -C.sub.18 alkyl groups, from about 0.05 to about 20 weight percent of a quaternary polymer; and (3) from about 0.02 to about 10 weight percent of a quaternary ammonium salt, with each weight percentage reflecting the active weight percent of the ingredient, based on the total weight of the composition. The composition is useful in a method of pretreatment conditioning of hair comprising applying to hair the composition followed by shampooing with an anionic shampoo.

Abstract: An aqueous aerosol hair spray styling aid composition and method including a terpolymer of vinylpyrrolidone/ethyl methacrylate/methacrylic acid (at least partially neutralized 30-1004) monomers in an amount of about 1% to about 124 by weight of the composition, particularly about 2% to about 10% by weight of the composition; water in an amount of about 20% to about 804 by weight of the composition; and a dimethyl ether liquefied propellant gas in an amount of about 25% to about 40% based on the total weight of the aerosol composition.

Abstract: Disclosed is a hair setting composition having a thickening system which comprises a nonionic long-chain alkylated water-soluble polymer and a specific cationic quaternary ammonium surfactant component in a compatible diluent. The quaternary surfactant component has an iodine value of less than 15. The composition additionally contains a hair setting agent, a distributing aid, and a mono-long chain, tri-short chain quaternary ammonium surfactant. The compositions are particularly useful in rinse-off hair conditioning and styling compositions.

Abstract: A film-forming resin which is a copolymer comprising specific monomers and a hair dressing composition containing the film-forming resin are disclosed. This film-forming resin is highly compatible in LPG and thus useful in the replacement of conventionally employed Freon gas by LPG. The hair dressing composition shows excellent effects including a good set-retention.

Abstract: A hair protection film of the present invention aims at preventing and curing damage to the hair due to cold permanent wave treatment. The hair protection film for cold permanent wave treatment has a "sandwich" or three layer structure with a center layer coated on both sides with a protective layer. The center layer is formed of a film or a thin layer consisting mainly of at least one of "water-soluble natural sugar", "blood plasma", and "substitute blood plasma", or of a film or a thin film obtained by dispersing an extract of corn grains or a concentrate of brewage in polyvinyl alcohol. The protective layer that coats both surfaces is one of an alkali-soluble coating layer, an acid-soluble coating layer and a heat-soluble coating layer.

Abstract: Cosmetic composition designed to maintain the hair in place, containing, in a cosmetically medium, at least one oxazoline polymer of formula (I): ##STR1## in which R.sub.1 denotes a C.sub.1 -C.sub.4 lower alkyl radical and n has a value such that the molecular weight is equal to at least 10,000 and at least one 2-hydroxy-4-methoxybenzophenone-5-sulphonic acid or its cosmetically acceptable salts.

Abstract: Ampholyte terpolymer conditioning additives for hair care products are disclosed which improve wet and dry hair combability, especially detangling and reduced static flyaway, sheen, and fixative properties, especially curl retention. The ampholyte terpolymers may have a weight average molecular weight of from about 10 thousand to 10 million, and comprise (a) from at least 1 to as much as 95 weight percent of the nonionic monomer acrylamide (AM), (b) from at least 5 to as much as 80 weight percent of the cationic monomer dimethyldiallylammonium chloride (DMDAAC), and (c) from at least 1 to as much as 75 weight percent of the anionic monomer 2-acrylamido-2-methylpropane sulfonic acid (AMPSA), with optionally up to 50% of said anionic monomer AMPSA being replaced with the anionic monomer acrylic acid (AA). The ampholyte terpolymers are added to hair care product formulations in amounts ranging from 0.1-10% by weight.

Abstract: A hair styling composition for imparting body and/or stylability to hair, comprises(a) at least one of surfactant, conditioning agent and water or other volatile solvent, together with(b) a per-alk(en)yl hydrocarbon material.

Abstract: A shampoo composition comprises:(a) a surfactant which is chosen from anionic, nonionic or amphoteric surfactants or mixtures thereof;(b) an aqueous emulsion of a solution of highly viscous silicone in volatile solvent; and(c) a cationic conditioning polymer which is a cationic derivative of guar gum;wherein the average particle size of the highly viscous silicone in the composition is less than 2 .mu.m in diameter.

Abstract: A hair treating method for imparting curl retention to hair in which at least one film forming ingredient is applied to the hair. The improvement utilizes as the film forming ingredient an organosilicon compound which is a hydrocarbon solvent free water soluble pre-hydrolyzed organofunctional silane having silsesquioxane characteristic. Hair care and fixative compositions including the silane are also disclosed.