Resin Hair Settings Patents (Class 424/DIG2)
  • Patent number: 4243657
    Abstract: A hair cosmetic composition comprising a cosmetic base containing 0.5 to 40% by weight of a diol derivative having the formula (I): ##STR1## wherein X.sub.1 is R--or ##STR2## in which R is branched alkyl having 6 to 12 carbon atoms, X.sub.2 is --H or ##STR3## in which R is branched alkyl having 6 to 12 carbon atoms, R.sub.1 is H, CH.sub.3, C.sub.2 H.sub.5 or C.sub.3 H.sub.7, R.sub.2 is H, CH.sub.3, C.sub.2 H.sub.5 or OH, and n and m each is an integer of from 1 to 3,or a branched aliphatic alcohol having the formula (II): ##STR4## wherein R.sub.3 is linear or branched alkyl having 8 to 10 carbon atoms and R.sub.4 is linear or branched alkyl having 6 to 8 carbon atoms,said hair cosmetic composition also having incorporated therein from 0.5 to 10% of a methylpolysiloxane having the formula (III): ##STR5## wherein l is an integer of from 3 to 14.
    Type: Grant
    Filed: September 1, 1978
    Date of Patent: January 6, 1981
    Assignee: Kao Soap Co., Ltd.
    Inventors: Takeo Okumura, Atsuo Ishida, Shizuo Hayashi
  • Patent number: 4243548
    Abstract: The subject of the invention is a pressurised aerosol formulation, which is in the form of a mixture, to be sprayed as a cosmetic, room or medicinal spray, of a propellant gas and organic solvents, as the propellant, and also active compounds and solvents for the active compounds, wherein the improvement comprises that the mixture is in the form of a homogeneous solution and this contains at least 50 percent by weight, preferably at least 55 percent by weight, of non-combustible constituents--relative to the total weight of the mixture--and contains, as the propellant gases, carbon dioxide and dimethyl ether, and, as non-combustible constituents, at least water, carbon dioxide, methylene chloride and/or 1,1,1-trichloroethane. This pressurized aerosol formulation is during transport, on storage and in use a product of low accident risk for the indicated purpose.
    Type: Grant
    Filed: November 27, 1978
    Date of Patent: January 6, 1981
    Assignee: Hans Schwarzkopf GmbH
    Inventors: Dieter Heeb, Uwe Bergemann, Claus-Dieter Frenzel
  • Patent number: 4240450
    Abstract: New compositions for the treatment of keratin material, in particular human hair, skin and nails are provided comprising a combination of a cationic polymer with an anionic polymer. Surprisingly the anionic polymer can be retained well on the hair, even after rinsing, when applied with the cationic polymer.
    Type: Grant
    Filed: March 14, 1978
    Date of Patent: December 23, 1980
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4223009
    Abstract: Hair preparations containing a copolymer of about 99.5 to 45.1 mole percent vinyl pyrrolidone and about 0.5 to 4.9 mole percent diloweralkylaminoalkyl acrylate or methacrylate, and method of setting and conditioning hair therewith.
    Type: Grant
    Filed: June 10, 1977
    Date of Patent: September 16, 1980
    Assignee: GAF Corporation
    Inventor: Paritosh M. Chakrabarti
  • Patent number: 4221729
    Abstract: Indoaniline of the formula ##STR1## wherein R.sub.1 represents hydrogen, halogen, alkyl or alkoxy; R.sub.2 and R.sub.3 represent alkyl; R.sub.4, R.sub.5 and R.sub.6 each independently represent hydrogen, halogen, alkyl, alkoxy, acylamino, ureido or carbalkoxyamino and R.sub.5 can also represent amino, alkylamino, hydroxyalkylamino or carbamylalkylamino, the alkyl and alkoxy groups above being able to contain 1 to 6 carbon atoms and the acyl group from 2 to 7 carbon atoms with the condition that R.sub.5 does not represent hydrogen, chlorine, methyl or methoxy and when R.sub.5 represents acetylamino, R.sub.6 does not represent hydrogen; it being understood that the above compounds can be present in the tautomeric form of that represented by formula (I). The indoaniline is usefully employed in dye compositions for keratinic fibers, especially living human hair.
    Type: Grant
    Filed: May 28, 1976
    Date of Patent: September 9, 1980
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 4217914
    Abstract: A quaternized polymer for use as a hair or skin cosmetic agent, has recurring units of the formula ##STR1## wherein R is lower alkyl or --CH.sub.2 --CH.sub.2 OH;R' is an aliphatic, alicyclic or arylaliphatic radical containing up to 20 carbon atoms, or R and R' together with the nitrogen atom to which they are attached form a heterocycle capable of containing a heteroatom other than nitrogen;A is(1) o-, m- or p-xylylidene of the formula ##STR2## ##STR3## wherein x, y and t are whole numbers ranging from 0 to 11 so the sum (x+y+t) is greater than or equal to 0 and lower than 18, and E and K represent hydrogen or an aliphatic radical having less than 18 carbon atoms,(3) --(CH.sub.2).sub.n --S--(CH.sub.2).sub.n --,(4) --(CH.sub.2).sub.n --O--(CH.sub.2).sub.n --,(5) --(CH.sub.2).sub.n --S--S--(CH.sub.2).sub.n --,(6) --(CH.sub.2).sub.n --SO--(CH.sub.2).sub.n --,(7) --(CH.sub.2).sub.n --SO.sub.2 --(CH.sub.2).sub.
    Type: Grant
    Filed: November 8, 1977
    Date of Patent: August 19, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 4213960
    Abstract: The invention relates to cosmetic compositions for conditioning the hair, which contain polyaminoamides and quaternary ammonium homopolymers or compolymers.
    Type: Grant
    Filed: March 1, 1978
    Date of Patent: July 22, 1980
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Claire Fiquet, Chantal Fourcadier, Claude Dubief, Daniele Cauwet
  • Patent number: 4210161
    Abstract: A creme rinse composition is provided for application to the hair for ease in combing and static control and to provide body and setting properties thereto comprising an aqueous composition containing from about 0.02 to about 2 weight percent of an anionic polymer and from about 0.1 to about 5 weight percent of a cationic surfactant capable of forming a water insoluble reaction product with said anionic polymer.
    Type: Grant
    Filed: July 3, 1978
    Date of Patent: July 1, 1980
    Assignee: Helene Curtis Industries, Inc.
    Inventor: Julius Wagman
  • Patent number: 4210755
    Abstract: Aminated .gamma.-dialdehyde and the quaternary ammonium salts thereof are prepared by acid hydrolysis of their respective corresponding 2,5-dialkoxy 3-amino 4-hydroxy tetrahydrofurans or by acid hydrolysis of their respective corresponding tetraalkyl acetals. The aminated .gamma.-dialdehydes and the quaternary ammonium salts thereof are usefully employed in cosmetic compositions to tan the skin or to strengthen or restructure the hair.
    Type: Grant
    Filed: July 10, 1978
    Date of Patent: July 1, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Georges Rosenbaum
  • Patent number: 4208402
    Abstract: A process for improving the appearance of oily hair or skin, including the scalp, comprises applying thereto an effective amount of an aqueous or hydroalcoholic solution of gelatin present in an amount of about 0.5 to 1.5 percent by weight thereof.
    Type: Grant
    Filed: January 10, 1977
    Date of Patent: June 17, 1980
    Assignee: L'Oreal
    Inventors: Pierre Bore, Lucienne Tourenq
  • Patent number: 4201766
    Abstract: A cosmetic composition for the hair comprises in combination at least one crosslinked polyamino-amide and at least one cationic polymer having recurring units of the formula ##STR1## wherein R.sub.3 and R.sub.4 each independently represent alkyl having 1-3 carbon atoms,R.sub.1 and R.sub.2 each independently represent alkyl having 1-3 carbon atoms or hydroxy alkyl having 1-3 carbon atoms, or when R.sub.2 =R.sub.4 =CH.sub.3 and R.sub.1 =R.sub.3, R.sub.1 and R.sub.3 can represent alkyl having 4-8 carbon atoms, or when R.sub.2 =R.sub.4 =R.sub.1 =CH.sub.3, R.sub.3 can represent benzyl, cyclohexyl or alkyl having 4-12 carbon atoms,X.sup..crclbar. is an anion,A and B each independently represent linear or branched alkylene having 2-20 carbon atoms in the chain, or A represents --(CH.sub.2).sub.n --Z--(CH.sub.2).sub.n --, --CH.sub.2 --C.sub.6 H.sub.4 --CH.sub.2 -- or --CH.sub.2 --CH(OH)--CH.sub.2 --, n being 2 or 3 and Z representing --O-- or --NH--CO--NH--.
    Type: Grant
    Filed: February 27, 1978
    Date of Patent: May 6, 1980
    Assignee: L'Oreal
    Inventors: Jean-Francois Grollier, Chantal Fourcadier
  • Patent number: 4199562
    Abstract: Sequenced oligomer surfactant has the formula: P--O----C.sub.2 H.sub.3 (CH.sub.2 B)O--.sub.n' [C.sub.2 H.sub.3 (CH.sub.2 A)O].sub.m --C.sub.2 H.sub.3 C.sub.2 B)O].sub.n Q wherein one of P and Q represents hydrogen and the other represents alkyl having 1-20 carbon atoms; A represents R--CH.sub.2 -- or R'--O-- wherein R is alkyl having 4-16 carbon atoms and R' is alkyl having 4-20 carbon atoms; B is selected from OH, R.sub.1 R.sub.2 N, R.sub.1 R.sub.2 N.fwdarw.O, R.sub.1 R.sub.2 N--O.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar., R.sub.1 R.sub.2 R.sub.3 N.sup..sym. Z.sup..crclbar. and R.sub.4 S.fwdarw.(O)a, wherein R.sub.1 and R.sub.2 represent alkyl or hydroxyalkyl, R.sub.3 is methyl or ethyl, R.sub.4 is alkyl, hydroxyalkyl or dihydroxyalkyl, Z.sup..crclbar. is an anion selected from HSO.sub.3.sup..crclbar., CH.sub.3 SO.sub.3.sup..crclbar., CH.sub.3 SO.sub.4.sup. .crclbar. and CH.sub.3 --C.sub.6 H.sub.4 --SO.sub.3.sup..crclbar., R.sub.1 R.sub.2 N.sup..sym. HV.sup..crclbar. and R.sub.
    Type: Grant
    Filed: July 14, 1977
    Date of Patent: April 22, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag
  • Patent number: 4197865
    Abstract: A quaternized polymer having recurring units of the formula ##STR1## wherein X.sup..crclbar. represents an anion derived from an organic or mineral acid;R'.sub.2 is an aliphatic radical having a maximum of 20 carbon atoms;R'.sub.1 is an aliphatic, alicyclic or arylaliphatic radical containing a minimum of 2 carbon atoms and a maximum of 20 carbon atoms, or R'.sub.1 and R'.sub.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: April 15, 1980
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 4196190
    Abstract: Acrylic polymer solutions having superior properties when used as hair setting or holding resins are disclosed. Specific polymers disclosed are derived from (1) alkyl acrylates with 2-8 carbon alkyl groups, (2) methyl methacrylate, (3) hydroxyethyl methacrylate, and (4) methacrylic acid in proportions yielding a film forming resin readily soluble in shampoo, with a Tg between about 40.degree. C. and 80.degree. C., a molecular weight between about 25,000 and 250,000 and not more than 50 ppm of unreacted alkyl acrylate monomer.
    Type: Grant
    Filed: January 9, 1978
    Date of Patent: April 1, 1980
    Assignee: Rohm and Haas Company
    Inventors: David R. Gehman, William A. Kirn
  • Patent number: 4195077
    Abstract: Compositions are provided which protect keratinous material such as skin and hair from the deleterious effects of detergents and adverse climatic conditions. Said compositions contain a modified protein and a surface active agent.
    Type: Grant
    Filed: June 26, 1978
    Date of Patent: March 25, 1980
    Assignee: The Procter & Gamble Company
    Inventors: Robert A. Marsh, Gordon J. Mackie, Peter Hale
  • Patent number: 4189468
    Abstract: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di-carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis-primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of (a') simple bi-functional compounds selected from bis-halohydrins, bis-azetidinium, bis-haloacyl diamine and alkyl bis-halides, (b') oli
    Type: Grant
    Filed: February 27, 1978
    Date of Patent: February 19, 1980
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag, Jean-Francois Grollier, Alexandre Zysman
  • Patent number: 4186188
    Abstract: Polypeptides with sterically unhindered positive charges can be incorporated into a cosmetic formulation for human hair, skin and nails. The polypeptides, which can be prepared by trypsin catalyzed hydrolysis of proteins, have the formula: ##STR1## wherein n is an integer sufficient to provide a molecular weight of the polypeptide of from about 200 to about 2,000 each R.sub.1 is independently a side group attached to the alpha carbon of a naturally occurring amino acid; and R.sub.
    Type: Grant
    Filed: October 25, 1977
    Date of Patent: January 29, 1980
    Assignee: Redken Laboratories, Inc.
    Inventor: Janet A. Gumprecht
  • Patent number: 4185087
    Abstract: Hair care compositions containing one or more quaternary nitrogen derivatives of trialkylamino hydroxy organosilicon compounds have superior conditioning capability for hair.
    Type: Grant
    Filed: December 28, 1977
    Date of Patent: January 22, 1980
    Assignee: Union Carbide Corporation
    Inventor: Robert J. Morlino
  • Patent number: 4180084
    Abstract: Hair-care compositions in the form of aqueous, alcoholic or aqueous alcoholic solutions, creams, gels, emulsions, or of aerosols which optionally contain a propellant are provided which contain at least one polymeric quaternary ammonium salt which contains cationic units of the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and represent alkyl, cycloalkyl or alkenyl, aryl or aralkyl, or (R.sub.1 and R.sub.2) and/or (R.sub.3 and R.sub.4) together with the nitrogen atom to which they are bonded, form an unsubstituted or substituted heterocyclic ring containing 3 to 6 ring members,A.sub.1 represents an optionally substituted alkylene, cycloalkylene or aralkylene bridging group and A.sub.2 is a group of the formula ##STR2## The compositions are especially useful as shampoos.
    Type: Grant
    Filed: April 25, 1978
    Date of Patent: December 25, 1979
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Wegmuller, Ulrich Horn, Walter Hungerbuhler, Jaroslav Haase
  • Patent number: 4173627
    Abstract: Hair lacquer compositions in pressurized containers are rendered less inflammable consistently throughout the emptying of the container by incorporating bromotrifluoromethane therein in an amount from 5 to 30% by weight based on the weight of the composition and providing the container with a valve provided with an inlet for additional gas.
    Type: Grant
    Filed: April 17, 1978
    Date of Patent: November 6, 1979
    Assignee: L'Oreal
    Inventors: Annie Madrange nee Dermain, Henri M. de Montalembert, Pierre Meurice, Jean-Louis Refregier
  • Patent number: 4172887
    Abstract: A cosmetic composition for the hair comprises at least one water-soluble crosslinked polymer selected from the group consisting of (1) crosslinked polymer obtained by crosslinking a polyamino-polyamide with a crosslinking agent, said polyamino-polyamide being prepared by the polycondensation of (a) an acidic compound selected from the group consisting of (i) organic dicarboxylic acid, (ii) ethylenically unsaturated aliphatic mono- or di- carboxylic acid, (iii) ester of said acids of (i) and (ii), and (iv) mixtures of (i), (ii) and (iii) on (b) a polyamine selected from the group consisting of bis primary and mono- or bis-secondary polyalkylene polyamines, said polyamine (b) being replaceable by a member selected from the group consisting of (1) 0-20 mole percent hexamethylene diamine, (2) 0-40 mole percent bis-primary amine and (3) 0-40 mole percent bis-secondary amine, said crosslinking agent being selected from the group consisting of epihalohydrins, diepoxides, dianhydrides and bis unsaturated derivatives,
    Type: Grant
    Filed: January 26, 1977
    Date of Patent: October 30, 1979
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Henri Sebag, Jean-Francois Grollier, Alexandre Zysman
  • Patent number: 4166845
    Abstract: This invention relates to a high-foaming antidandruff shampoo having desirable cosmetic conditioning properties, which consists essentially of about 10% to 30% by weight of a water-soluble betaine detergent, 1% to 10% by weight of a water-soluble anionic, amine oxide or amphoteric detergent, 1% to 10% by weight of a water-soluble nonionic detergent containing polyoxypropylene groups and polyoxyethylene groups, 0.5% to 5% by weight of an aminopolyureylene resin, and water.
    Type: Grant
    Filed: May 9, 1977
    Date of Patent: September 4, 1979
    Assignee: Colgate-Palmolive Company
    Inventors: Kenneth R. Hansen, Paul S. Grand
  • Patent number: 4165367
    Abstract: Hair preparations containing a copolymer of about 95 to 45 mole percent of vinyl pyrrolidone and about 5 to 50 mole percent of diloweralkylaminoalkyl acrylate or methacrylate, and method of setting and conditioning hair therewith.
    Type: Grant
    Filed: June 10, 1977
    Date of Patent: August 21, 1979
    Assignee: GAF Corporation
    Inventor: Paritosh M. Chakrabarti
  • Patent number: 4157388
    Abstract: Novel polycationic or polyguaternary ammonium ionenes, which generally are hygroscopic, and processes for their preparation, are described. The compounds are useful as conditioning agents for skin, hair, textile products and powders.
    Type: Grant
    Filed: June 23, 1977
    Date of Patent: June 5, 1979
    Assignee: The Miranol Chemical Company, Inc.
    Inventor: Arvid Christiansen
  • Patent number: 4155994
    Abstract: A hair conditioning agent comprising the condensation product of 1,4-dichloro-2-butene and 1,4-bis-dimethylamino-2-butene.
    Type: Grant
    Filed: January 21, 1977
    Date of Patent: May 22, 1979
    Assignee: Kewanee Industries, Inc.
    Inventors: John J. Merianos, Harold A. Green, Morris Weinstein
  • Patent number: 4150115
    Abstract: Quaternized polyamine polymers are employed in cosmetic compositions for application to the hair or skin. The polymer has recurring units of the formula: ##STR1## WHEREIN A is polymethylene having 2-10 carbon atoms, B is selected from polymethylene having 3-10 carbon atoms, xylylidenyl group --CH.sub.2 --C.sub.6 H.sub.4 --CH.sub.2 -- ortho, meta or para, --(CH.sub.2).sub.x --O--(CH.sub.2).sub.x -- wherein x is 2 or 3, or --CH.sub.2 --CHOH--CH.sub.2 --; R.sub.1 and R.sub.3 represent an aliphatic radical having 1-12 carbon atoms; R.sub.2 and R.sub.4 represent an aliphatic radical having 1-20 carbon atoms; R.sub.5 is hydrogen or an aliphatic, alicyclic, aryl or arylaliphatic radical containing 1-20 carbon atoms; R.sub.6 is an aliphatic or arylaliphatic radical containing 1-20 carbon atoms; X is a halide anion; Y is selected from a halide anion, SO.sub.4 H.sup..crclbar. or CH.sub.3 SO.sub.4.sup..crclbar. ; and n and p are whole numbers with p being able to be 0, such that the ratio p/n+p ranges from 0 to 0.95.
    Type: Grant
    Filed: November 15, 1976
    Date of Patent: April 17, 1979
    Assignee: L'Oreal
    Inventors: Bernard Jacquet, Gerard Lang
  • Patent number: 4144326
    Abstract: An aqueous creme rinse composition is provided comprising water and from about 0.25 to 5.0 parts by weight of lauryl trimethyl ammonium chloride or bromide, 0.25 to 3.0 parts of dimethyl dialkyl ammonium chloride or bromide and a quaternized hydroxymethyl cellulose.
    Type: Grant
    Filed: February 22, 1977
    Date of Patent: March 13, 1979
    Assignee: American Cyanamid Company
    Inventors: Oscar B. Luedicke, Jr., Francis M. Gichia
  • Patent number: 4128631
    Abstract: This invention relates to a method of imparting a highly lubricated feel to keratinous substrates such as skin or hair or upon mucous membranes. The method is useful in obtaining the desired effect from diverse personal care products as hand and body creams, soap bars, suntan lotion, pre-electric shave skin conditioners, after shave lotions, lip balms, cold creams, bubble baths, cleansing and lotion pads, douches and vaginal lubricants.
    Type: Grant
    Filed: February 16, 1977
    Date of Patent: December 5, 1978
    Assignee: General Mills Chemicals, Inc.
    Inventors: Larry D. Lundmark, Allan Melby, Ho-Ming Chun
  • Patent number: 4118423
    Abstract: Aminated .gamma.-dialdehyde and the quaternary ammonium salts thereof are prepared by acid hydrolysis of their respective corresponding 2,5-dialkoxy 3-amino 4-hydroxy tetrahydrofurans or by acid hydrolysis of their respective corresponding tetraalkyl acetals. The aminated .gamma.-dialdehydes and the quaternary ammonium salts thereof are usefully employed in cosmetic compositions to tan the skin or to strengthen or restructure the hair.
    Type: Grant
    Filed: December 14, 1976
    Date of Patent: October 3, 1978
    Assignee: L'Oreal
    Inventors: Guy Vanlerberghe, Georges Rosenbaum
  • Patent number: 4117853
    Abstract: An improvement in the process of setting hair comprising applying a film of a vinyl acetate copolymerizate consisting essentially of(a) from 65% to 80% by weight of vinyl acetate units,(b) from 10% to 20% by weight of units of a maleic acid diester with a straight-chained alkanol-1 having from about 8 to 10 carbon atoms,(c) from 5% to 20% by weight of units of a mono-olefinically unsaturated ester having from 6 to 8 carbon atoms and a hydrophilic group, and(d) from 3% to 10%, particularly 7%, by weight of crotonic acid and salts thereof,To the hair after setting the same; and hair setting agents in the form of hair sprays and setting lotions containing up to 10% by weight of said vinyl acetate copolymerizate and/or salts thereof.
    Type: Grant
    Filed: September 14, 1977
    Date of Patent: October 3, 1978
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Gunter Reese, Hermann Kroke, Fanny Scheuermann
  • Patent number: 4115549
    Abstract: A method of setting or coating hair, fur, synthetic or human in a predetermined condition, either straightened or curled, or waterproofed, which comprises coating the hair with a heat-settable coating composition containing a hardening and adhesive agent in oil and aqueous media, either with or without the addition of separate water-proofing agents, softening agents, and the like and then applying heat to the coated hair to set the coated hair in the selected condition.
    Type: Grant
    Filed: April 13, 1976
    Date of Patent: September 19, 1978
    Assignee: Widner College
    Inventor: Howard L. Scott
  • Patent number: 4115548
    Abstract: Compositions are provided which protect keratinous material such as skin and hair from the deleterious effects of detergents and adverse climatic conditions. Said compositions contain a modified protein and a surface active agent.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: September 19, 1978
    Assignee: The Procter & Gamble Company
    Inventors: Robert Anthony Marsh, Gordon John Mackie, Peter Hale
  • Patent number: 4087550
    Abstract: A method and composition for combatting the greasy and unaesthetic appearance of the hair and to improve the appearance of the skin comprises in a carrier at least one active component of the formula ##STR1## wherein R.sub.1 and R.sub.2 are methyl, ethyl, isopropyl, cyclohexyl, benzyl or .beta.-hydroxyethyl, or R.sub.1 and R.sub.2 taken together form --(CH.sub.2).sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --CH.sub.2 --(CH.sub.2).sub.2 --, --(CH.sub.2).sub.2 --O--(CH.sub.2).sub.2 --, ##STR2## and R is (i) linear or branched alkyl having 1-18 carbon atoms, (ii) alkenyl having 3-18 carbon atoms, (iii) alkyl having 2-3 carbon atoms and substituted by 1-2 alcohol functions, (iv) --(CH.sub.2).sub.m --CH(OR.sub.3).sub.2 wherein R.sub.3 is alkyl having 1-4 carbon atoms and m is 1-2, (v) --(CH.sub.2).sub.n R.sub.4 wherein n is 0, 1 or 2 and R.sub.4 is 2-pyridyl or phenyl, (vi) --(CH.sub.2).sub.q R'.sub.4 wherein q is 0 or 1 and R'.sub.
    Type: Grant
    Filed: April 15, 1976
    Date of Patent: May 2, 1978
    Assignee: L'Oreal
    Inventors: Claude Bouillon, Charles Vayssie
  • Patent number: 4087518
    Abstract: Liquid detergent compositions are provided containing a modified protein of pI > pH6 and a mixture of alkyl benzene sulphonate and auxiliary surfactants in which the ratio of alkyl benzene sulphonate to the auxiliary surfactant is greater than 1.5:1. The compositions show enhanced mildness to skin relative to detergent compositions in which the surfactants are at lower ratios.
    Type: Grant
    Filed: March 11, 1976
    Date of Patent: May 2, 1978
    Assignee: The Procter & Gamble Company
    Inventors: Rory James Maxwell Smith, Gordon John Mackie
  • Patent number: 4080465
    Abstract: A method for improving the appearance of the greasy skin of the face of a person having a skin so characterized, which comprises topically applying to the skin of the face an effective amount of a composition containing as an active ingredient a cis or trans 3,4-thiolannediol, its cis or trans S-oxide derivatives or its cis or trans S-dioxide derivatives.
    Type: Grant
    Filed: January 27, 1976
    Date of Patent: March 21, 1978
    Assignee: Societe Anonyme dite: L'Oreal
    Inventors: Claude Bouillon, Michel Colin
  • Patent number: 4076800
    Abstract: Detergent Compositions having a protective effect on keratinous material incorporate a proteinaceous material whose primary amino or carboxylic acid side chain groups have been modified by reaction with C.sub.1 -C.sub.7 acyl- or alkyl- group-containing materials respectively to give a modified protein of isoionic point (pI) less than pH 6. Granular, bar and liquid detergent formulations embodying the invention are disclosed.
    Type: Grant
    Filed: January 7, 1976
    Date of Patent: February 28, 1978
    Assignee: The Procter & Gamble Company
    Inventors: Robert Anthony Marsh, Gordon John Mackie, Peter Hale
  • Patent number: 4073898
    Abstract: A composition for treating oily hair or skin to reduce the oily appearance thereof comprises in an appropriate vehicle an active compound having the formula ##STR1## wherein R.sub.3 is lower alkyl containing 1-3 carbon atoms; n= 0 or 1 with the proviso that when n= 0, ##STR2## and when n= 1, R.sub.2 is hydrogen; and HX represents a mineral or organic acid. The composition can be applied topically or be orally administered to a person whose hair or skin has an oily appearance to reduce said oily appearance.
    Type: Grant
    Filed: December 31, 1975
    Date of Patent: February 14, 1978
    Assignee: L'Oreal
    Inventors: Claude Bouillon, Claudine Berrebi
  • Patent number: 4073881
    Abstract: Hair conditioner compositions suitable for use as after-shampoo preparations or before-shampoo preparations which comprise (A) 1 to 40% by weight of a liquid polymer that is obtained by polymerization of .alpha.-olefin having 6 to 18 carbon atoms and has an average of from 24 to 60 carbon atoms and a viscosity of 18 to 200 centistokes at 37.8.degree. C. (100.degree. F.), (B) 0.5 to 25% by weight of a surface active agent, and (C) 20 to 95% by weight of water.
    Type: Grant
    Filed: March 4, 1976
    Date of Patent: February 14, 1978
    Assignee: Lion Fat & Oil Co., Ltd.
    Inventors: Makoto Imai, Teruo Horiuchi, Ichiro Kashiwa
  • Patent number: 4066746
    Abstract: A method of treating hair on the head to reduce the time required for the drying thereof when wet comprising applying to the hair a polymer derived from an (N-alkyl perfluoroalkanesulphonamido)-ethyl acrylate or methacrylate monomer.
    Type: Grant
    Filed: October 16, 1975
    Date of Patent: January 3, 1978
    Assignee: Lever Brothers Company
    Inventors: Martin Callingham, Kenneth Vasey Curry
  • Patent number: 4062939
    Abstract: A hair and scalp conditioning and cleansing composition which contains perfluorocarbon resins as lubricating and/or scouring agents is disclosed.
    Type: Grant
    Filed: December 15, 1975
    Date of Patent: December 13, 1977
    Assignee: Widner College
    Inventor: Howard L. Scott
  • Patent number: 4061150
    Abstract: This invention is concerned with the pretreatment of hair on the human head, preceding shampooing the hair with anionic type hair shampoos, and with compositions for effecting such pretreatment, to obtain highly improved manageability of the hair after shampooing and with improved fullness, compability and other desired properties of the hair. The pretreatment compositions utilize readily water-soluble quaternary ammonium compounds, particularly in combination with certain agents, notably polyethylenimines and N-ethanolacetamide, and desirably together with various supplemental ingredients.
    Type: Grant
    Filed: July 29, 1976
    Date of Patent: December 6, 1977
    Assignee: Alberto-Culver Company
    Inventors: George F. Dasher, Kathleen A. O'Cull, Thomas J. Schamper
  • Patent number: 4059688
    Abstract: Hair fixation with fluorine containing acrylate or methacrylate terpolymers or with mixtures thereof with known non-fluorine containing hair fixing polymers.
    Type: Grant
    Filed: June 29, 1976
    Date of Patent: November 22, 1977
    Assignee: Clairol Incorporated
    Inventors: Ira E. Rosenberg, John A. Ferguson, Norman P. Loveless
  • Patent number: 4057625
    Abstract: Water-in-oil emulsions wherein the emulsifier consists essentially of copolymers of N-vinylpyrrolidone and a vinyl C.sub.5-24 alkylcarboxylate (if desired with vinyl acetate) and the continuous phase is a cosmetically acceptable oily material can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.
    Type: Grant
    Filed: March 25, 1976
    Date of Patent: November 8, 1977
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Hase, Joachim Galinke, Bernd Wegemund
  • Patent number: 4057624
    Abstract: Water-in-oil emulsions wherein the emulsifier is a copolymer of 1 mol of acrylamide with 2 to 20 mols of at least one ethylenically unsaturated ester copolymerizable therewith selected from the group consisting of vinyl alkylcarboxylates, alkyl and cycloalkyl acrylates, and alkly and cycloalkyl methacrylates, wherein the alkyl and cycloalkyl groups contain 6 to 24 carbon atoms, and the continuous phase is a cosmetically acceptable oil, which can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.
    Type: Grant
    Filed: March 25, 1976
    Date of Patent: November 8, 1977
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Hase, Joachim Galinke, Bernd Wegemund
  • Patent number: 4057622
    Abstract: Cosmetic emulsions containing from 2 to 20% by weight of polymeric emulsifiers capable of forming water-in-oil creams comprising a copolymer of N-vinylimidazole, an alkyl (meth)acrylate and optionally vinyl acetate; 20 to 75% by weight of water; and the remainder to 100% by weight of a cosmetically-acceptable oily substance.
    Type: Grant
    Filed: March 25, 1976
    Date of Patent: November 8, 1977
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Hase, Christian Hase, Joachim Galinke, Bernd Wegemund
  • Patent number: 4057623
    Abstract: Water-in-oil emulsions wherein the emulsifier consists essentially of a copolymer or terpolymer of N-vinylpyrrolidone with a C.sub.6-24 alkyl or cycloalkyl acrylate or methacrylate, and vinyl acetate if desired, and the continuous phase is a cosmetically acceptable oily material which can be prepared easily, safely and inexpensively. The emulsions are substantially odorless and are cosmetically acceptable for the care of the skin.
    Type: Grant
    Filed: March 25, 1976
    Date of Patent: November 8, 1977
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Brigitte Hase, Joachim Galinke, Bernd Wegemund
  • Patent number: 4054147
    Abstract: Diphenylamine of the formula ##STR1## wherein R.sub.1 and R.sub.4 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, amino, lower alkyl amino, acylamino, lower carbamylalkyl amino, lower hydroxyalkyl amino, lower carbalkoxy amino and ureido;R.sub.2 and R.sub.3 each independently represent a member selected from the group consisting of hydrogen, halogen, lower alkyl, lower alkoxy, acylamino and ureido;R.sub.5 represents a member selected from the group consisting of hydrogen, halogen, lower alkyl and lower alkoxy;R.sub.6 represents a member selected from the group consisting of lower hydroxyalkyl, lower amino alkyl, lower acylamino alkyl, lower mesylamino alkyl, lower carbamylalkyl, lower sulfoalkyl, lower piperidinoalkyl, lower morpholinoalkyl, lower mono alkyl lower amino alkyl and lower dialkyl lower amino alkyl; andR.sub.
    Type: Grant
    Filed: February 21, 1975
    Date of Patent: October 18, 1977
    Assignee: L'Oreal
    Inventors: Gregoire Kalopissis, Andree Bugaut, Francoise Estradier
  • Patent number: 4048301
    Abstract: A cosmetic shampoo composition comprises in a carrier for application to the hair at least one detergent and at least one graft cationic copolymer of N-vinylpyrrolidone, dimethylaminoethyl methacrylate and polyethylene glycol.
    Type: Grant
    Filed: May 27, 1976
    Date of Patent: September 13, 1977
    Assignee: L'Oreal
    Inventor: Christos Papantoniou
  • Patent number: 4047537
    Abstract: This invention concerns a treatment which may be applied on practically all hair and which substantially improves the cosmetic properties thereof. More particularly, it contemplates a novel hair grooming aid to beautify hair, particularly living hair, which includes as a necessary ingredient a solid phase of finely divided fibrillatable polytetrafluoroethylene (hereinafter referred to as "PTFE") resin. The invention includes a process of grooming hair comprising applying the grooming aid to hair and brushing the hair at a temperature above the transition temperature at which PTFE fibriliates to form microscopic and submicroscopic fibers, in an amount sufficient to give the hair a natural appearance and to maintain its set for a long time.
    Type: Grant
    Filed: May 23, 1975
    Date of Patent: September 13, 1977
    Assignee: The Harshaw Chemical Company
    Inventor: Glen A. Shaw
  • Patent number: 4047888
    Abstract: A hair dye composition comprises in a cream or gel vehicle or support at least one oxidation dye and at least one graft cationic copolymer of N-vinylpyrrolidone, dimethylaminoethyl methacrylate and polyethylene glycol.
    Type: Grant
    Filed: May 27, 1976
    Date of Patent: September 13, 1977
    Assignee: L'Oreal
    Inventor: Christos Papantoniou