Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.

Abstract: A process for coating a surface includes preparing a coating mixture by mixing a selected solvent with a silicone rubber adhesive sealant and applying the mixture to the surface. The mixture may be applied as a very thin layer to a woven fabric so that the coating layer has pore spaces corresponding to gaps in the weave of the fabric, so as to provide a semipermeable membrane. In another arrangement, the coating material includes hollow microspheres or capillary tubing of various types, so as to provide improved insulation without adding substantial weight to the surface.

Abstract: Disclosed is a method to obtain a film of composite material based on particles of conductive polymer, stabilized by a highly steric or highly ionic surfactant. The efficient stabilization of the particles makes it possible to control the progress of the dielectrical properties of the materials as a function of the conductive entity content, leading to the preparation of films with variable impedance. The method can be applied to the making of coatings that meet goals related to electromagnetic wide-band attenuation. FIG. 2 .

Abstract: A process for the production of a conductive layer on a substrate, said conductive layer comprising a network of crystal needles of conductive radical cation salts based on tetrathiotetracenes, tetraselenotetracenes or tetratellurotetracenes and chlorine, bromine, iodine or copper dichloride, and said network is embedded in a polymer matrix, by coating at least one side of said substrate with a) a suspension of crystal needles of the radical cation salts of formula I in an inch solvent which may additionally contain a thermoplastic polymer or at least one starting compound for a thermosetting polymer, or b) a solution (b1) of a tetrathiotetracene, tetraselenotetracene or tetratellurotetracene, (b2) of a monomeric, oligomeric or polymeric organic compound which contains chlorine, bromine or iodone and, when heated with these tetracenes, forms a radical cation salt, or of anhydrous CuCl.sub.2, a CuCl.sub.2 aquo complex or a CuCl.sub.

Abstract: A method of making a coated abrasive article having an electrically conductive backing is taught, wherein electrically conductive material is incorporated into a coated abrasive backing. The coated abrasive article made by this method has a reduced tendency to accumulate static electric charge in the abrasive article during abrading of a workpiece.

Abstract: A method of producing fibers which are electrically conductive and which also exhibit anti-bacterial properties. The method involves treating the fibers in one or more baths which contain a solution of copper ions and an anti-bacterial compound such as iodine. The resulting fibers with the adsorbed copper and iodine ions exhibit the desired properties when dried.

Abstract: This invention relates to a process for forming polyaniline films or coatings on a substrate and to composite articles formed by said process.

Abstract: A method for imparting ballistic resistant characteristics to a textile fabric by placing a polymer film on the fibers of a high tenacity fiber fabric which has a coefficient of friction higher than the coefficient of friction of the high tenacity fibers. The fabric, after the placement of the polymer film is subjected to a high velocity air stream to break up any fiber-to-fiber bonds in the fabric.

Abstract: This invention relates to a process for forming polyaniline films on a substrate and to composite articles formed by said process.

Abstract: There is disclosed a composite of 1) a polymer containing repeating units derived from a vinyl carboxylic ester having at least one organo terminated poly(alkylene oxide) side chain with the proviso that the poly(alkylene oxide) is present in an amount greater than 35 mole percent of the total of all backbone monomer units and alkylene oxide units in the polymer and 2) a metal oxide wherein the metal oxide comprises between about 1 and about 60 percent by weight of the composite. The composites can be made by a process comprising the steps of:combining the described polymer and a metal oxide precursor in a solvent solution;casting or coating the resulting solution onto a substrate;curing the resulting sample to form a composite of the polymer and the metal oxide.Optionally, the composite can be removed from the substrate to form a transparent free standing film. These composites have a variety of desirable properties.

Abstract: A method of producing fibers which are electrically conductive and which also exhibit anti-bacterial properties. The method involves treating the fibers in one or more baths which contain a solution of copper ions and an anti-bacterial compound such as iodine. The resulting fibers with the absorbed copper and iodine ions exhibit the desired properties when dried.

Abstract: A conductive polymeric material such as a textile fabric having a conductive polymer film may be treated with a solution containing a chemical reducing agent to reduce its conductivity. By selectively reducing portions of the conductive polymer in varying degrees, a gradient of conductivity may be produced in the material. After the conductive polymer has been reduced to a target level, the reducing solution may be removed with a hot water rinse.

Abstract: A thermally curable polymer thick film compositions comprising, by weight:(a) about 3-15 parts of at least one poly(hydroxystyrene) resin;(b) a crosslinking resin selected from the group consisting of:(i) about 5-25 parts of at least one blocked isocyanate resin; or(ii) about 2-10 parts of at least one melamine-formaldehyde resin;(c) an effective amount of at least one organic solvent capable of substantially dissolving (a) and (b) ingredients;(d) conductive particulate matter selected from the group consisting of:(i) about 50-80 parts silver flake;(ii) a graphite/carbon black mixture consisting of:(aa) about 15-45 parts graphite; and(bb) about 1-10 parts carbon black; or(iii) a mixture of (i) and (ii).

Abstract: A textile material, such as fibers, filaments, yarns and fabrics made therefrom, is rendered electrically conductive by a polypyrrole film deposited on the textile material by chemical oxidation of pyrrole in an aqueous solution also containing an oxidizing agent and anthraquinone-2-sulfonic acid as a dopant.

Abstract: A method and apparatus for coating photoreceptors used in copying machines. Prior to coating, an elastically deformable material is placed about the external surface of a mandrel to accommodate the belt. The thickness of the material is such that when the belt is pushed over the mandrel the deformable material is deformed and engages the interior surfaces of the belt facing the mandrel. As a result of heating and cooling steps involved during the coating process, the belt contracts and expands differently than the mandrel. The deformable material deforms accordingly to maintain consistent contact throughout between it and the undersurface of the belt.

Abstract: A coated cellulosic web product and coating composition which provides enhanced toner adhesion for documents printed using noncontact printing devices such as laser printers is provided. The toner adhesion enhancing coated cellulosic product includes a cellulosic web having first and second major surfaces with at least one of the major surfaces having coated thereon a polymeric toner adhesion-enhancing composition comprising a generally transparent copolymer of styrene and acrylic acid having a glass transition temperature of between about -16 and 22 degrees C and from about 1 to about 5% by weight zinc as a cross-linking agent for said copolymer. The web may be either continuous or in sheet form. The toner adhesion-enhancing composition may also optionally include a coloring agent and a plasticizing agent.

Abstract: Fabrics are made electrically conductive by contacting the fiber under agitation conditions with an aqueous solution of an aniline compound, oxidizing agent and a doping agent or counter ion and then depositing onto the surface of individual fibers of the fabric a prepolymer of the aniline compound so as to uniformly and coherently cover the fibers with a conductive film of the polymerized aniline compound and wherein, furthermore, the oxidizing agent is a vanadyl compound whereby the reaction rate is controlled such that the prepolymer is uniformly and coherently adsorbed onto the surface of the textile material, thereby providing improved films of electrically conductive polymerized compound on the textile material.

Abstract: A thin film of an electrically conductive material (16) is applied to form an electrically conductive surface (22) on a surface (18) of a polymer coated fabric (14). The method involves coating a woven glass fiber fabric (14) with a polymer solution (6), curing the polymer solution on the glass fiber fabric and then depositing the electrically conductive material onto the cured polymer surface, typically by a sputtering technique, to form a flexible, electrically conductive fabric (24). This method helps to ensure that when the electrically conductive material is applied, the electrically conductive surface formed is continuous and is of a controlled, generally constant, thickness. The substantial continuity of the electrically conductive surface is maintained even when the electrically conductive fabric is flexed during subsequent manufacturing operations.

Abstract: There is disclosed an improved process for preparing a superconducting composition having the formula MBa.sub.2 Cu.sub.3 O.sub.x wherein M is selected from the group consisting of Y, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tn, Yb and Lu; x is from about 6.5 to about 7.0; said composition having a superconducting transition temperature of about 90.degree. K.; said process consisting essentially of preparing a precursor solution, drying the solution to obtain a solid material, and heating and cooling the solid material under specified conditions to obtain the desired product. In another embodiment, a shaped superconducting MBa.sub.2 Cu.sub.3 O.sub.x article is prepared by impregnating an article of cellulose material with the precursor solution, drying the impregnated article, and heating and cooling the impregnated article under prescribed conditions to obtain the desired product.

Abstract: Fabrics are made electrically conductive by contacting the fiber under agitation conditions with an aqueous solution of an aniline compound, oxidizing agent and a doping agent or counter ion and then depositing onto the surface of individual fibers of the fabric a prepolymer of the aniline compound so as to uniformly and coherently cover the fibers with a conductive film of the polymerized aniline compound and wherein, furthermore, the oxidizing agent is a vanadyl compound whereby the reaction rate is controlled such that the prepolymer is uniformly and coherently absorbed onto the surface of the textile material, thereby providing improved films of electrically conductive polymerized compound on the textile material.

Abstract: Disclosed is an electrostatic recording medium comprising an electroconductive support and a dielectric layer formed on the electroconductive support and containing an insulating resin and a pigment, characterized in that the pigment comprises kaolin having a quartz content of not more than 2% by weight and that the dielectric layer has, on the surface thereof, projections based on the pigment and having an equivalent diameter of 5-15 um as spacers.

Abstract: Disclosed is an electrographic recording receiver for use in a process where styli in a writing head deposit electric charges on an electrographic receiver. The receiver comprises a substrate having a conductive layer on an insulating support, a dielectric layer having an image area on the conductive layer, conductive particles embedded in the image area of the dielectric layer in contact with the conductive layer and extending or protruding through the surface of the dielectric layer to provide an electrical path between a ground and the conductive layer through the conductive particles, and insulating particles embedded in and extending through the surface of the image area of the dielectric layer to a distance greater than the conductive particles to provide a substantially uniform distance between the styli and the dielectric layer. Also disclosed is a method of making such a receiver and a method of forming an electrostatic image on such a receiver.

Abstract: This invention relates to a deactivatable tag useable with an electronic article surveillance system and comprised of planar conductive material cut into a pair of inverse, first and second spiral conductors wrapped about each other and positioned for capacitive and inductive coupling. The invention also relates to method of making tags wherein conductors are cut from a planar web of conductive material in a continuous process in a manner that the cutting results in the formation of two spiral conductors without accompanying waste of conductive material, and thereafter positioning the conductors to provide resonant circuits. The conductors of each pair are connected by welding to provide a reliable circuit. A film of electrostatic-charge-draining material on a web of deactivatable tags prevents their premature deactivation.

Abstract: The present invention provides a multilayer fibrous material suitable for use as an EMI and RFI shielding packaging material and a process for producing the same comprising first and second outer layers formed of paper or paperboard and an inner layer formed of paper or paperboard containing conductive carbon. The invention also provides a method of providing antistatic properties to the packaging material.

Abstract: The invention relates to a process for the preparation of plastic mouldings, preferably plastic films, antistatically treated with a transparent layer of polypyrrole; the process is characterized by a certain combination of special measures which are coordinated with one another.

Abstract: Fabrics are made electrically conductive by contacting the fiber under agitation conditions with an aqueous solution of a pyrrole compound, an oxidizing agent and a doping agent or counter ion and then depositing onto the surface of individual fibers of the fabric a prepolymer of the pyrrole compound so as to uniformly and coherently cover the fibers with a conductive film of the polymerized pyrrole compound and wherein, furthermore, the oxidizing agent is a ferric salt and the aqueous solution further contains a weak complexing agent for ferric ions to effectively control the reaction rate such that the prepolymer is uniformly and coherently adsorbed onto the surface of the textile material, thereby providing improved films of electrically conductive polymerized compound on the textile material.

Abstract: A film of an electrically conductive polymer consists of(A) a layer I which is treated on one side with an aqueous acid and contains incorporated counterions and whose thickness is 1-60% of the total thickness of the film, and(B) an electrochemically reversible oxidizable layer II whose thickness is 40-99% of the total thickness of the film.

Abstract: A method for producing oxidant/dopant reagent solutions which comprises reacting a basic ferric carboxylate, preferably basic ferric acetate, with an alkyl or aryl sulfonic acid, e.g., benzenesulfonic acid, to produce the corresponding ferric sulfonate in solution. Oxidant/dopant solutions can also be prepared containing cupric or ceric sulfonates. The oxidant/dopant solution is employed in situ for reaction with a pyrrole to produce electrically conductive polypyrrole. A porous substrate, such as fiberglass cloth, can be dipped in the oxidant/dopant solution, dried and then treated with a pyrrole to produce an electrically conductive polypyrrole deposit in the interstices of the substrate.

Abstract: This invention relates to a deactivatable tag useable with an electronic article surveillance system and comprised of planar conductive material cut into a pair of inverse, first and second spiral conductors wrapped about each other and positioned for capacitive and inductive coupling. The invention also relates to method of making tags wherein conductors are cut from a planar web of conductive material in a continuous process in a manner that the cutting results in the formation of two spiral conductors without accompanying waste of conductive material, and thereafter positioning the conductors to provide resonant circuits. The conductors of each pair are connected by welding to provide a reliable circuit. A film of electrostatic-charge-draining material on a web of deactivatable tags prevents their premature deactivation.

Abstract: An electrostatic recording material which comprises a support coated in sequence with a conductive layer and a recording layer composed of a dielectric resin and a pigment, wherein at least a part of the pigment component in said recording layer is made of an aluminum hydroxide powder having an average particle size of 1-20 .mu.m is disclosed.

Abstract: The invention relates to a hydroexpansible composite material, the method of preparing same and a composition for implementing this method, as well as to the uses thereof. The composite material includes a solid flat support having, on at least one of its faces, a coating with a high proportion of a hydroexpansible polymer powder fixed to the support by means of a hydrosoluble binder, the coating being essentially formed of:95 to 55% by weight of hydroexpansible polymer powder;5 to 23% by weight of hydrosoluble binder; and0 to 22% by weight of surfactant.This hydroexpansible material may advantageously be used in medicine, surgery agriculture and especially as sealing agent in cables, particularly electric cables.FIG. 2 shows how, in a cable, this material (11, 13) forms a sealing ring (13) about the point of infiltration of the water, thus preventing its longitudinal propagation.

Abstract: Electroerosion recording materials of superior scratch resistance are provided by incorporating a hard, crosslinked polymer film or layer between the support and the removable, thin conductive layer to reduce plastic deformation of the support under stylus writing pressure. The intermediate polymer layer may be unfilled or filled with solid particles, such as silica particles. The materials may be used in various printing processes including making directly readable images, direct negatives, and offset masters.

Abstract: Processes for the production of antistatic or static dissipative papers. The papers produced may be expeditiously used in dunnage converter machines operable to produce an antistatic (static dissipative) resilient pad-like cushioning dunnage product, for packaging and the like. In one of the processes, liquid antistatic material is applied to a still wet porous paper web produced on a Fourdrinier-type paper making machine, and in predetermined amount for impregnation therein, prior to the completion of the drying of the paper. In another process, a web of dry paper is impregnated with liquid antistatic material, and then the treated web is dried.

Abstract: Fabrics are made electrically conductive by contacting the fabric under agitation conditions with an aqueous solution of a pyrrole or aniline compound, and an oxidizing agent and a doping agent or counter ion; and then epitaxially depositing onto the surface of the individual fibers of said fabric the in status nascendi forming polymer of the pyrrole or aniline compound so as to uniformly and coherently cover the fibers with an ordered conductive film of the polymerized pyrrole or aniline compound. Individual fibers and yarns can be similarly treated and then formed into fabrics. Products made by the process are also described.

Abstract: In an electrostatic recording material being composed of a multi-layered sheet support having an electroconductive layer and a dielectric layer formed successively thereon, the number of projections having a height of 10 .mu.m or more from the flat surface is limited to a maximum of 50 per 0.1 m.sup.2, so that the material has excellent properties and can produce prints of very high quality.

Abstract: An electrostatic recording sheet comprising a support provided thereon a conductive layer and a dielectric layer, in this order, with the dielectrics layer containing polypropylene particles with a specified size distribution and exhibiting excellent moisture resistance and high transparency.

Abstract: Disclosed herein is a process for producing electroconductive fibrous shaped-articles comprising the steps of:soaking water-absorptive fibrous shaped-articles in a palladium hydrosol containing a cationic surfactant, an anionic surfactant, a non-ionic surfactant or a mixture thereof, and after (i) drying the thus treated shaped-articles, (ii) washing the thus treated shaped-articles with water or (iii) washing the thus treated shaped-articles and then drying, subjecting the thus obtained, shaped-articles on which colloidal palladium is adsorbed to chemical plating, thereby obtaining the electroconductive fibrous shaped-articles of which fibers thereof are subjected to metallizing plating.

Abstract: A light-transmissive recording medium comprises a coating layer which has a surface electric resistance not more than 10.sup.14 .OMEGA./cm.sup.2, and has property of trapping a recording agent which is soluble and/or dispersible in an aqueous medium.

Abstract: A method of matting a pre-sensitized printing plate is disclosed. The method is comprised of electrostatically providing fine droplets of an aqueous liquid with a resin dissolved or dispersed therein on the obverse surface or reverse surface of the pre-sensitized printing plate and, thereafter, drying the fine droplets. The method is characterized in that before and/or after the attachment of the droplets the surface of the pre-sensitized printing plate is wet. The method can be continuously performed and provides a matted surface with protuberances firmly adhered to a substrate.

Abstract: An electrophotographic image transfer paper for a copier including a fixing operation, comprises a sheet of raw paper, and a receiving layer on the paper for reducing blistering of the sheet during fixing of an image on the sheet, the receiving layer including a coating on at least one side of the sheet, having a center-line-average surface roughness not more than 2.0 micrometer and an air permeability less than or equal to 4,000 seconds.

Abstract: Controlledly microporous shaped articles adopted for use, e.g., as electrodes and diaphragms, are produced by consolidating a fibrous matrix with a latex binder material, notably by deposition onto a rigid perforate substrate, the lattice network of said binder material comprising a silica-based derivative, e.g., a precipitated or pyrogenic silica.

Abstract: An electrostatic recording material comprising a substrate treated for low electric resistance and a dielectric layer formed on the substrate and composed of a composition comprising an insulating resin having a volume specific resistance of at least 10.sup.12 .OMEGA.cm and a powder of an acrylonitrile-type polymer having a copolymerized acrylonitrile content of at least 95% by weight and containing substantially no ionic groups, said powder having a volume average particle size of from 1.5 to 4 .mu.m and a content of particles having a size exceeding 8 .mu.m as measured by a particle size distribution measuring apparatus, being at most 0.02% by number.

Abstract: An electrostatic recording medium is disclosed, which comprises a substrate, an electroconductive layer, and a recording layer which are successively overlaid on the substrate, with the surface of the recording layer being studded with at least one component selected from the group consisting of a polymeric electrolyte, an inorganic salt and a surface active agent.

Abstract: Electrosensitive recording using a composite structure formed by a base support for a resinous contrast layer containing amorphous silicon dioxide, polycrystalline silicon dioxide, and a polyolefin, which provide an anti-abrasion characteristic. The contrast layer has an overlying metallic surface that is desirably provided by vapor deposition. The electrostatic structure provides suitable print quality for information recorded by electrically actuated styli and has the property of suitable resistance to unwanted stripping or burnishing of the metallic surface.

Abstract: Transparency sheet material for use in a plain paper electrostatic copiers comprising (a) a flexible, transparent, heat resistant, polymeric film base, (b) an image receiving layer carried upon a first major surface of the film base, and (c) a layer of electrically conductive prime coat interposed between the image receiving layer and the film base. This sheet material can be used in either powder-toned or liquid-toned plain paper copiers for making transparencies.

Abstract: A process for generating electrically conductive patterns on a dielectric substrate, such as an insulating sheet, which comprises applying to preselected areas of the substrate a preselected concentration of an ink in the form of an oxidizing agent, such as a solution of a ferric salt, e.g., ferric chloride or ferric ethylbenzenesulfonate, and which can also contain a suitable binder or thickening agent, to form printed images on the substrate surface. The resulting printed surface of the substrate is then exposed to an excess of reactant, e.g., pyrrole monomer in vapor phase, which reacts with the oxidizing agent to develop conductive images, as by forming polypyrrole, in those printed areas of the substrate containing the oxidizing agent.

Abstract: A solid, composite and conductor material is obtained by impregnating an impregnable solid with a pyrrolic compound, and bringing the so-impregnated solid into contact with an oxidizer solution, so to cause a pyrrolic polymer to form inside the solid material.

Abstract: Production of electrically conductive composite or structural materials comprising a dielectric substrate, e.g. fiberglass fabric, and a layer of a pyrrole polymer on the substrate, by treating the substrate with a solution of a strong oxidant containing a substantially non-nucleophilic anion, e.g. ferric chloride, drying the substrate and exposing the so treated substrate with the vapors of a pyrrole and oxidizing the pyrrole by the strong oxidant and depositing a polypyrrole layer or film on the substrate.

Abstract: Production of electrically conductive polypyrrole powder, by treating a liquid pyrrole with a solution of a strong oxidant, capable of oxidizing pyrrole to a pyrrole polymer, and oxidizing the pyrrole by such strong oxidant in the presence of a substantially non-nucleophilic anion and precipitating a conductive polypyrrole powder. The strong oxidant, e.g., Fe.sup.3+ ion, and non-nucleophilic anion, e.g., sulfate or chloride ion, can be derived from a single compound, e.g., FeCl.sub.3 or Fe.sub.2 (SO.sub.4).sub.3. The anion serves as dopant for the polypyrrole. The reaction can be carried out in aqueous solution or in an organic solvent medium, such as acetonitrile.

Abstract: Production of electrically conductive polypyrrole of enhanced stability by treating a liquid pyrrole with a solution of a strong oxidant, capable of oxidizing pyrrole to a pyrrole polymer, and oxidizing the pyrrole by such strong oxidant in the presence of a relatively large organic dopant anion, and precipitating a conductive polypyrrole. The strong oxidant, e.g., Fe.sup.3+ ion, and dopant anion, which can be an alkyl or aryl sulfonate, e.g., methylbenzenesulfonate, or a perfluorinated carboxylate, e.g., trifluoroacetate, anion, can be derived from a single compound, e.g., ##STR1## the anion serving as dopant for the polypyrrole.