Solid-walled Microcapsule Formed By In Situ Polymerization Patents (Class 427/213.34)
  • Patent number: 7736691
    Abstract: The present invention relates to functional organic particles having functional nanoparticles dispersed in an organic polymeric matrix, wherein the distribution of the functional nanoparticles is increased in the direction toward increasing the particle diameter from the center of the functional organic particles, and to a method for preparing the same.
    Type: Grant
    Filed: February 21, 2008
    Date of Patent: June 15, 2010
    Assignee: LG Chem, Ltd.
    Inventors: Chang Soon Lee, Woong Ki Lee, Woo Cheul Jung
  • Patent number: 7718572
    Abstract: An aqueous microcapsule suspension liquid exhibiting an excellent (long-term) storage stability and allowing easy re-dispersion and dilution with water even after such a storage, is produced by adding a microorganism-fermented polysaccharide of succinoglycan type as a thickening agent into a microcapsule slurry, or by adding such a microorganism-fermented polysaccharide as a thickening agent to a microcapsule slurry after uniform dilution with water.
    Type: Grant
    Filed: June 11, 2001
    Date of Patent: May 18, 2010
    Assignee: Kureha Corporation
    Inventors: Yutaka Igari, Tsuneo Okamoto, Yuzi Hori
  • Patent number: 7700333
    Abstract: This invention relates to a method for immobilizing cells under laminar flow conditions in a matrix formed by biocompatible charged polymers, to a flow device for the use with the method of the present invention, and to uses of the polymer matrices containing the cells immobilized using the method of the present invention.
    Type: Grant
    Filed: July 26, 2004
    Date of Patent: April 20, 2010
    Assignee: Agency for Science Technology & Research
    Inventors: San San Susanne Ng, Hanry Yu
  • Publication number: 20100056668
    Abstract: An opacifying pigment encapsulated in polymer including a pigment particle having an average particle diameter of from 0.005 to 5 microns and an index of refraction of at least 1.8; an aminophosphorus acid-functional first polymer having been used to disperse the pigment particle in an aqueous medium; and a second polymer that at least partially encapsulates the dispersed pigment particle is provided. A process for forming the opacifying pigment encapsulated in polymer and compositions including the particles are also provided.
    Type: Application
    Filed: August 19, 2009
    Publication date: March 4, 2010
    Inventor: Ward Thomas Brown
  • Patent number: 7662444
    Abstract: A liquid crystal microcapsule, comprising a liquid crystal and a polyurea film encapsulating the liquid crystal, wherein at least one of an alkyl group and a fluoroalkyl group is bonded directly or indirectly via a urethane bond to the polyurea. A method of producing a liquid crystal microcapsule, comprising: forming a polyurea and the film thereof by allowing an aligner, which is a compound having a hydroxyl group and at least one of an alkyl group and a fluoroalkyl group, to react with a polyisocyanate, a polyamine, and water; and encapsulating a liquid crystal with the film. A liquid crystal display device using the liquid crystal microcapsule.
    Type: Grant
    Filed: July 13, 2005
    Date of Patent: February 16, 2010
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Naoki Hiji, Shigeru Yamamoto
  • Patent number: 7658998
    Abstract: The present invention relates to a method for preparing an injectable composition of microparticles for the sustained release of a biologically active agent. The microparticles include a biocompatible polymer and a biologically active agent. The invention provides an improved process for the preparation of microparticles, wherein the physical characteristics of the microparticles, for example, the morphology, density and size, are independent of the process used to prepare the initially formed polymer/drug matrix. The method includes the steps of (a) providing a polymer/biologically active agent matrix; (b) compressing the polymer/biologically active agent matrix, thereby forming a compressed matrix; and (c) fragmenting the compressed matrix, thereby forming an injectable microparticle composition. The polymer/drug matrix can be provided by any suitable method.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: February 9, 2010
    Assignee: Alkermes Controlled Therapeutics, Inc.
    Inventors: Josiah Brown, Warren E. Jaworowicz, Gregory C. Troiano
  • Publication number: 20090311336
    Abstract: A particle having an average diameter from 80 to 500 nm and having a core containing at least one compound having a ?max in the range from 250 to 400 nm and a cross-linked polymeric shell.
    Type: Application
    Filed: June 9, 2009
    Publication date: December 17, 2009
    Inventors: Charles Elwood Jones, Morris Christopher Wills
  • Patent number: 7629049
    Abstract: A polymer system and device with a hemocompatible film or coated polymers is provided, the polymer system comprises an organic phase and an aqueous phase, the organic phase comprises polymerizable monomers and at least one initiator and the aqueous phase comprises at least one dispersing agent, at least one free radical inhibitor and at least one buffering agent, the organic phase is immiscible in the aqueous phase, and the dispersing agent forms a hemocompatible surface on the polymer, and the device comprises a housing for containing the polymer system.
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: December 8, 2009
    Assignee: Medasorb, Inc.
    Inventors: Robert L. Albright, Vincent J. Capponi, Thomas D. Golobish
  • Publication number: 20090291309
    Abstract: The present invention relates to aminoplast-membrane single-core or multi-core microcapsules whose core is comprised of at least two organic and/or inorganic compounds. The invention also relates to methods of preparing said microcapsules.
    Type: Application
    Filed: November 30, 2005
    Publication date: November 26, 2009
    Inventors: Fabien Salaün, Eric Devaux, Serge Bourbigot, Pascal Rumeau
  • Patent number: 7588780
    Abstract: Embolic polymer particles are described.
    Type: Grant
    Filed: August 9, 2002
    Date of Patent: September 15, 2009
    Assignee: Boston Scientific Scimed, Inc.
    Inventors: Marcia Buiser, Marc Bellisario, David Knapp, Stephan Mangin, Janel Lanphere
  • Patent number: 7572397
    Abstract: Microcapsules comprising one or more lipophilic substances as core material and a polymer as capsule shell, which are obtainable by free-radical polymerization of an oil-in-water emulsion comprising from 30 to 100% by weight, based on the total weight of the monomers, of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid (monomer I), from 0 to 80% by weight, based on the total weight of the monomers, of a bifunctional or polyfunctional monomer (monomers II) which is insoluble or sparingly soluble in water and from 0 to 40% by weight, based on the total weight of the monomers, of other monomers (monomers III), the lipophilic substance and solid inorganic particles having a mean particle size of from 45 to 1000 nm, and a process for producing them are described. They can be used in binding building materials, textiles and gypsum plasterboard.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: August 11, 2009
    Assignee: BASF Aktiengesellschaft
    Inventors: Ekkehard Jahns, Hans-Juergen Denu, Joachim Pakusch, Horst Seibert
  • Patent number: 7541060
    Abstract: Disclosed is a technique for producing bichromal balls that are adapted for use in high temperature applications. The bichromal balls find particular application in signs and display devices that can be used in environments in which the temperature exceeds 40° C.
    Type: Grant
    Filed: August 17, 2004
    Date of Patent: June 2, 2009
    Assignee: Xerox Corporation
    Inventors: San-Ming Yang, Thomas Edward Enright, Aurelian Valeriu Magdalinis, Ahmed Abd Alzamly, Man-Chung Tam, Carol Ann Jennings, Peter M. Kazmaier, Marko D. Saban, Michael Steven Hawkins
  • Patent number: 7527809
    Abstract: A structure containing polyhydroxyalkanoate and a magnetic substance includes an external phase part containing polyhydroxyalkanoate and an internal phase part contained in the external phase part, at least one of the external phase part and the internal phase part containing a magnetic substance. Accordingly, provided is a microcapsule, which can be suitably used for formation of an active ingredient of a sustained release pharmaceutical preparation or an ultrasonic contrast agent.
    Type: Grant
    Filed: April 30, 2004
    Date of Patent: May 5, 2009
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuya Yano, Tsuyoshi Nomoto, Shinya Kozaki, Takeshi Imamura, Tsutomu Honma
  • Patent number: 7521085
    Abstract: A coating composition is prepared by polymerizing an addition polymer with a Tg of at least about 60° C. in the presence of a particulate pigment having substantially primary aggregate particles to form encapsulated pigment particles, isolating and drying the encapsulated pigment product, and combining the dried encapsulated pigment product with a coating vehicle.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: April 21, 2009
    Assignee: BASF Corporation
    Inventors: Jon R. Hall, Zenon Paul Czornij
  • Patent number: 7517587
    Abstract: The invention relates to macromolecules auto-assembled and photopolymerised around carbon nanotubes. Said macromolecules are essentially formed from rings of lipid compounds, polymerised about the nanotubes, said polymerised compounds being obtained from lipid molecules with one or two chains A, bonded to a group Z where A is a chain, CH3—(CH2)m—C?C—C?C—(CH2)n—, where n and m, independently=whole numbers from 1 to 16 and Z is a polar head group embodied by a —COOH, —CO—NH—Y, —NH2 or N+(R)3, where R is an alkyl with C1, to C4 and Y is a —(CH2)4—C(R1)—N(CH2—COOH)2 group with R=H, or a COOH group, where A is a single lipid chain or a group of structure (I) or (II), where R2=a COOH, or —CO—NH—Y1 group with Y1=a —(CH2)4—C (R3)—N(CH2COOH)2 group with R3=H or a COOH group, where Z and R2 can also be neutral polar head groups of the sugar or polysaccharide type.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: April 14, 2009
    Assignees: Centre National de la Recherche Scientifique (C.N.R.S.), Universite Louis Pasteur
    Inventors: Charles Mioskowski, Stéphane Rickling, Patrick Schultz
  • Publication number: 20090092837
    Abstract: The present invention relates to magnetic beads in the form of composite beads with an inner core of metal particles, which are coated with an inert synthetic polymer and thereafter a hydrophilic porous polymer, preferably dextran. This provides porous biocompatible beads without metal leakage. This construction also allows for simple and convenient handling of cell expansion media by magnetism.
    Type: Application
    Filed: March 20, 2007
    Publication date: April 9, 2009
    Applicant: GE HEALTHCARE BIO-SCIENCES AB
    Inventors: Andreas Axen, Eva Holmgren, Nils Norrman, Tobias E. Soderman
  • Publication number: 20090075856
    Abstract: A shelf-stable liquid agent or detergent containing a bleaching agent in the form of a finely particulate bleaching agent encapsulated in a crosslinkable polymer matrix.
    Type: Application
    Filed: November 19, 2008
    Publication date: March 19, 2009
    Applicant: Henkel AG & Co. KGaA
    Inventors: Peter Schmiedel, Heinz-Juergen Voelkel, Heribert Kaiser, Wolfgang von Rybinski, Soeren Hoelsken, Volker Blank, Bernhard Guckenbiehl
  • Publication number: 20090062462
    Abstract: An object of the present invention is to provide an encapsulated product having excellent properties, for example, the core substance is not limited. An encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer contacts the core substance through an ionic surfactant a and comprises at least (1) a repeating structural unit derived from an ionic polymerizable surfactant B and/or ionic monomer and (2) a repeating structural unit derived from an ionic polymerizable surfactant C having an electric charge the same as or opposite the electric charge of the ionic surfactant; or an encapsulated product comprising a core substance encapsulated with a wall material mainly comprising a polymer, wherein the polymer comprises a repeating structural unit comprising a hydrophobic monomer and is present between (1) an ionic surfactant b and (2) an ionic surfactant c.
    Type: Application
    Filed: October 18, 2005
    Publication date: March 5, 2009
    Inventor: Toshiyuki Miyabayashi
  • Patent number: 7488513
    Abstract: A method of producing microcapsules having an electrophoretic particle dispersion encapsulated comprises the steps of: emulsifying and dispersing a hydrophobic dispersion having electrophoretic particles dispersed in a hydrophobic medium by using a high-speed rotating stirring apparatus wherein the circumferential speed at the end of a stirring part is 2 m/s to 90 m/s, and the distance (a) between the end of the stirring part and that immobile part of the stirring apparatus which is nearest to the end of the stirring part is 0 mm<(a)<20 mm; and forming microcapsules of the emulsified and dispersed hydrophobic dispersion under stirring with a stirring blade.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: February 10, 2009
    Assignee: Toyo Ink Mfg. Co., Ltd.
    Inventors: Yoshiyuki Sakai, Kazuhiro Jonai, Toshiyuki Uemura
  • Publication number: 20090017304
    Abstract: An organic-inorganic composite particle containing an inorganic particle having a plurality of polymer particles attached to the inorganic particle and a polymer layer encapsulating the attached polymer particles. A process is provided for the organic-inorganic composite particle. The organic-inorganic composite particle is useful in the preparation of dried coatings that have improved hiding, whiteness, or gloss.
    Type: Application
    Filed: September 15, 2008
    Publication date: January 15, 2009
    Inventors: Anne Denise Koller, Robert Mitchell Blankenship
  • Patent number: 7473467
    Abstract: The invention relates to a complex coacervation process based on the use of type B gelatin as polycationic colloid, for the preparation of “Halal” certified flavor-containing microcapsules.
    Type: Grant
    Filed: September 3, 2002
    Date of Patent: January 6, 2009
    Assignee: Firmenich SA
    Inventors: Anandaraman Subramaniam, Anne Reilly
  • Patent number: 7442410
    Abstract: A process for the microencapsulation of phase transitional paraffin compounds is described. Polypropylene glycols with the average molecule weight over 400 were used as the surface tension modifiers for emulsifying the paraffin compounds. Polyisocyanates capable of being dissolved in the phase change materials were employed to promote the deposition of melamine, partially methylolated melamine and the precondensate of melamine-formaldehyde onto the hydrophobic droplets for the microencapsulation. The prepared emulsion of microencapsulated phase change materials was successfully coated on textile fabrics and the coated products showed improved thermal regulation function.
    Type: Grant
    Filed: December 24, 2002
    Date of Patent: October 28, 2008
    Assignee: Nano-Sports Technologies Ltd.
    Inventors: Jianwei Xing, Yi Li, Edward Newton
  • Publication number: 20080261805
    Abstract: Photocatalytic titanium dioxide particles are disclosed having improved dispersibility into an aqueous solvent not only under neutral physiological conditions in vivo but also over a wide pH range, and improved cell affinity and cell uptake property. The photocatalytic titanium dioxide particles comprise particles comprising photocatalytic titanium dioxide and a cationic hydrophilic polymer modifying surfaces of the photocatalytic titanium dioxide particles, wherein the hydrophilic polymer is bonded to the photocatalytic titanium dioxide particles. The photocatalytic titanium dioxide particles are very useful for medical applications, such as destruction of cancer cells.
    Type: Application
    Filed: March 27, 2006
    Publication date: October 23, 2008
    Applicant: TOTO LTD.
    Inventors: Koki Kanehira, Shuji Sonezaki, Yumi Ogami, Toshiaki Banzai, Junji Kameshima
  • Publication number: 20080258115
    Abstract: Nanoparticles and methods of making nanoparticles are provided. The nanoparticles may include semiconductor nanocrystals. A shell may encapsulate a nanoparticle core, and the shell may include non-organic material and may be silica. The shell may also include additional species such as PEG. In some embodiments, a passivation layer is in contact with the core.
    Type: Application
    Filed: June 23, 2008
    Publication date: October 23, 2008
    Applicant: Singapore Agency for Science, Technology and Research
    Inventors: Jackie Y. Ying, Subramanian T. Selvan, Timothy T. Tan
  • Patent number: 7153754
    Abstract: Methods for forming porous insulative materials for use in forming dielectric structures of semiconductor devices are disclosed. Each insulative material may include a first, substantially nonporous state and a second, porous state. When in the first state, the insulative materials may be processed or support layers or structures which are being processed. When in the second state, the insulative materials have a reduced dielectric constant and, thus, increased electrical insulation properties. Semiconductor device structures including layers or other features formed from one of the insulative materials are also disclosed. Methods for forming the insulative material and for causing the insulative material to become porous are also disclosed.
    Type: Grant
    Filed: August 29, 2002
    Date of Patent: December 26, 2006
    Assignee: Micron Technology, Inc.
    Inventors: Warren M. Farnworth, Tongbi Jiang
  • Patent number: 7115303
    Abstract: A process for producing spherical composite cured melamine resin particles excellent in water resistance, in which colloidal silica is localized near the surface thereof, comprising (a) a step of reacting a melamine compound with an aldehyde compound in an aqueous medium under a basic condition in the presence of a suspension of colloidal silica having an average particle size of 5 to 70 nm to produce an aqueous solution of a precondensate of water-soluble melamine resin; and (b) a step of adding an acid catalyst to the aqueous solution produced in the step (a) to separate out spherical composite cured melamine resin particles.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: October 3, 2006
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Masaaki Ozawa, Akira Yoshida
  • Patent number: 7112620
    Abstract: A polymer system with a hemocompatible film or coating is provided, the system comprises an organic phase and an aqueous phase, the organic phase comprises polymerizable monomers and at least one initiator and the aqueous phase comprises at least one dispersing agent, at least one free radical inhibitor and at least one buffering agent, the organic phase is immiscible in the aqueous phase, and the dispersing agent forms a hemocompatible surface on the polymer.
    Type: Grant
    Filed: May 27, 2003
    Date of Patent: September 26, 2006
    Inventor: Robert L. Albright
  • Patent number: 7067324
    Abstract: The present invention provides a method for reducing undesirable light emission from a sample using at least one photon producing agent and at least one photon reducing agent (e.g. dye-based photon reducing agents). The present invention further provides a method for reducing undesirable light emission from a sample (e.g., a biochemical or cellular sample) with at least one photon producing agent and at least one collisional quencher. The present invention also provides a method for reducing undesirable light emission from a sample (e.g., a biochemical or cellular sample) with at least one photon producing agent and at least one quencher, such as an electronic quencher. The present invention also provides a system and method of screening test chemicals in fluorescent assays using photon reducing agents. The present invention also provides compositions, pharmaceutical compositions, and kits for practicing these methods.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: June 27, 2006
    Assignee: Invitrogen Corporation
    Inventors: Tom Knapp, Gregor Zlokarnik, Paul Negulescu, Roger Y. Tsien, Tim Rink
  • Patent number: 7033639
    Abstract: A coating composition including a polyaniline particle and a binder is provided. The polyaniline particle contains a core polymer particle with strong acid groups and an attached polyaniline polymer, and has a particle diameter in a select range. Coatings prepared from the coating composition may be employed to provide corrosion resistance to metal substrates. A process for preparing the polyaniline particle and an article including a coating prepared from the coating composition are also provided.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: April 25, 2006
    Assignee: Rohm and Haas Company
    Inventors: Michael DeWayne Kelly, Thomas Glenn Madle, Paul Ralph Van Rheenen
  • Patent number: 6964836
    Abstract: A process for forming photosensitive microcapsules having discrete capsule walls comprising the steps of forming an emulsion of an oily core material in a continuous aqueous phase containing a carboxyvinyl polymer and enwrapping particles of the oily core material in an amine-formaldehyde condensation product produced by in situ condensation of an amine and formaldehyde wherein the carboxyvinyl polymer comprises a crosslinked polymer of acrylic acid is disclosed.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: November 15, 2005
    Assignee: Eastman Kodak Company
    Inventors: Ibrahim Katampe, Alexander Y. Polykarpov, Joseph C. Camillus
  • Patent number: 6916640
    Abstract: A multi-layered microcapsule has an inner extracellular matrix and an outer shell. The inner extracellular matrix includes a first inner layer of biopolymer and a second intermediate layer of polymer that provides partial immune-protection and holds the first layer in place. The outer shell can form an exoskeleton to provide mechanical stability. Each of the individual layers can be varied to optimize mechanical stability, cell function, and immuno-protection.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: July 12, 2005
    Assignees: Agency for Science, Technology and Research, National University of Singapore
    Inventors: Hanry Yu, Kam W. Leong, Ser-Mien Chia, Andrew C. A. Wan
  • Patent number: 6913825
    Abstract: Nanoparticles, nanocomposites, and methods for making the nanoparticles and nanocomposites are disclosed. Illustrated methods include preparing a nanocomposite particle by binding a silicate compound to the surface of a core particle in an aqueous suspension, adding a silicate source and an organic surfactant template, and stirring the aqueous suspension to obtain silicate growth.
    Type: Grant
    Filed: September 20, 2002
    Date of Patent: July 5, 2005
    Assignee: University of Notre Dame du Lac
    Inventors: Agnes E. Ostafin, Robert Nooney, Edward Maginn
  • Patent number: 6890592
    Abstract: The present invention teaches an improved process for preparing a population of microcapsules having a substantially uniform size distribution, especially useful for manufacture of carbonless paper. The improved process teaches use of membrane material having a pre-selected pore size in the capsule manufacture process. A core material is provided along with a receiving solution for receiving the core material. The receiving solution is a nonsolvent for the core material. The core material is passed under pressure through the membrane into a moving or turbulent receiving solution forming uniform droplets of core material dispersed in the receiving solution. Wall-forming material is added to the receiving solution for coating the core material droplets. The coating on the droplets is polymerized forming microcapsules. This novel process also lends itself to microcapsule formation in a continuous process.
    Type: Grant
    Filed: March 13, 2002
    Date of Patent: May 10, 2005
    Assignee: Appleton Papers Inc.
    Inventors: Troy Ronald Seehafer, George Arthur Stahler
  • Patent number: 6884829
    Abstract: A polymer with a hemocompatible film or coating is manufactured by a one-step method comprising polymerizing monomer droplets comprising at least one crosslinking agent to form a polymer and simultaneously coating the resulting polymer using at least one dispersing agent to thereby form a hemocompatible coated polymer.
    Type: Grant
    Filed: October 18, 2002
    Date of Patent: April 26, 2005
    Inventor: Robert L. Albright
  • Patent number: 6881810
    Abstract: A microcapsule which includes a polymer as a capsule wall of the microcapsule, in which the polymer is obtained by polymerizing a dendritic branching molecule having a hydroxyl group in a terminal thereof, an isocyanate compound, and a compound having two or more active hydrogen atoms in a molecule thereof. A process for manufacturing a microcapsule includes the step of polymerizing an isocyanate compound, a dendritic branching molecule having a hydroxyl group in a terminal thereof, and a compound having two or more active hydrogen atoms in a molecule thereof, so as to form a capsule wall of the microcapsule.
    Type: Grant
    Filed: July 11, 2003
    Date of Patent: April 19, 2005
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yuki Matsunami, Shintaro Washizu
  • Patent number: 6861064
    Abstract: A novel method of encapsulating an active substance in a biodegradable polymer, which comprises: a) dissolving said biodegradable polymer in an organic solvent therefor; b1) dispersing said active substance in the organic solution obtained in step a) to provide a dispersion with the active substance as the inner phase thereof; or alternatively b2) emulsifying said active substance, dissolved in water or other aqueous solvent therefor, in the organic solution obtained in step a) to provide an emulsion with the active substance as the inner aqueous phase thereof; and c) subjecting the dispersion obtained in step b1), or alternatively the emulsion obtained in step b2), to an encapsulation operation with an aqueous polyethylene glycol solution as a continuous phase to provide micro- or nanoparticles having the active substance encapsulated therein. Sustained release particles obtainable thereby.
    Type: Grant
    Filed: September 24, 1998
    Date of Patent: March 1, 2005
    Assignee: Jagotec AG
    Inventors: Timo Laakso, Mats Reslow
  • Publication number: 20040265589
    Abstract: A microcapsule in which a capsule wall of the microcapsule comprises a first polymer component. A surface of the capsule wall is modified with a second polymer component that is formed from a monomer having an ethylenic unsaturated bond.
    Type: Application
    Filed: April 23, 2004
    Publication date: December 30, 2004
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventors: Satoru Yamada, Yuuichi Fukushige, Kyoko Senga, Naoto Yanagihara
  • Publication number: 20040121072
    Abstract: A process for the microencapsulation of phase transitional paraffin compounds is described. Polypropylene glycols with the average molecule weight over 400 were used as the surface tension modifiers for emulsifying the paraffin compounds. Polyisocyanates capable of being dissolved in the phase change materials were employed to promote the deposition of melamine, partially methylolated melamine and the precondensate of melamine-formaldehyde onto the hydrophobic droplets for the microencapsulation. The prepared emulsion of microencapsulated phase change materials was successfully coated on textile fabrics and the coated products showed improved thermal regulation function.
    Type: Application
    Filed: December 24, 2002
    Publication date: June 24, 2004
    Inventors: Jianwei Xing, Yi Li, Edward Newton
  • Patent number: 6753083
    Abstract: A particulate composition comprising particles having a core comprising a hydrophobic polymer within a shell, characterised in that the shell comprises a semi-permeable membrane. Particulate composition can be used for making a stable dispersion of particles uniformly distributed throughout a first hydrophobic liquid, wherein the particles comprise a core within a shell and the core comprises a hydrophobic polymer into has been imbibed a second hydrophobic liquid, Compositions can be used to encapsulate active substances and may be used in sustained release mechanisms.
    Type: Grant
    Filed: October 18, 2001
    Date of Patent: June 22, 2004
    Assignee: Ciba Specialty Chemicals Water Treatments Ltd.
    Inventors: Kishor Kumar Mistry, Janine Andrea Preston, Kenneth Charles Symes
  • Patent number: 6746684
    Abstract: A microcapsule characterized by comprising a solid pesticide as a core material coated with a wall material which is a resin formed by polycondensation of a sparingly water-soluble melamine-formaldehyde resin type prepolymer (said sparingly water-soluble melamine-formaldehyde resin type prepolymer dissolves 2000 g or less of water therein per 100 g of solid component of the prepolymer at +25° C.) in the presence of a dispersant which is a condensation product of naphthalenesulfonic acid and/or alkylnaphthalenesulfonic acid and formaldehyde or a salt thereof, a method for producing said microcapsule, and a method for applying said microcapsule are disclosed.
    Type: Grant
    Filed: October 15, 2001
    Date of Patent: June 8, 2004
    Assignee: Syngenta Crop Protection, Inc.
    Inventors: Kenichi Kitagaki, Hironori Kataoka
  • Patent number: 6737108
    Abstract: A process for producing a MC-type conductive filler includes treating minute metallic particles with a coupling agent, preparing an oil phase of the coupling agent-treated minute metallic particles and a reactive substance A, the reactive substance A directly contacting the metallic particles. Then, an aqueous phase is prepared having a reactive substance B, which is capable of reacting with the reactive substance A, dissolved in water. Thereafter, the oil phase is dispersed in the aqueous phase to form a suspension. In situ reaction of the reactive substances A and B is then caused by applying heat to the suspension or adding a catalyst to the suspension. This forms a coating of a thermosetting insulating resin on the surface of the minute metallic particles. Alternatively, the reactive substance B may not be used.
    Type: Grant
    Filed: May 14, 2002
    Date of Patent: May 18, 2004
    Assignee: Fujitsu Limited
    Inventors: Hiroaki Date, Makoto Usui, Isao Watanabe, Yuko Hozumi
  • Patent number: 6719932
    Abstract: Disclosed are a plurality of particles having a narrow particle size distribution, a processes for forming the same, and films containing the same. The plurality of particles, includes one or more discrete polymer shells, wherein at least one of the polymer shells is crosslinked with at least one monomer containing two or more double bonds polymerizable by free radical means; and a core material encased in the polymer shells, wherein the plurality of particles have a polydispersity of from 1.3 to 1.0.
    Type: Grant
    Filed: September 24, 2002
    Date of Patent: April 13, 2004
    Assignee: Shipley Company, L.L.C.
    Inventors: Richard Roy Clikeman, Morris Christopher Wills, Katerina Elizabeth Dukes
  • Patent number: 6632531
    Abstract: A method of forming, by polymerization in an aqueous dispersion at pressures in excess of one atmosphere, a plurality of porous particles having at least one polymeric phase and, additionally, having a pore filling phase containing a fugitive substance is disclosed. Replacement of the fugitive substance with a gas is further disclosed. Gas-filled porous particles and their aqueous dispersions are also disclosed.
    Type: Grant
    Filed: December 13, 2001
    Date of Patent: October 14, 2003
    Assignee: Rohm and Haas Company
    Inventor: Robert Mitchell Blankenship
  • Patent number: 6630197
    Abstract: The present invention relates to the field of degradation or corrosion prevention or inhibition through the use of bacteria which secrete antimicrobial chemical compositions. In particular, the invention relates to the use of bacteria which, either naturally or through the use of recombinant technology, secrete chemical compositions which inhibit the growth of sulfate-reducing bacteria on metals, concrete, mortar, and other surfaces subject to corrosion.
    Type: Grant
    Filed: March 31, 1999
    Date of Patent: October 7, 2003
    Assignee: Regents of the University of California
    Inventors: Thomas K. Wood, Arul Jayaraman, James C. Earthman
  • Patent number: 6596204
    Abstract: A process of micro-encapsulating a volatile liquid includes selecting a volatile liquid, such as Isophorone, and porous ceramic particles for encapsulating the volatile liquid. The volatile liquid and porous particles are mixed and a vacuum is applied to the mixture to impregnate the volatile liquid in the porous particles. A polymer catalyst for the polymer resin, such as an epoxy catalyst for use with an epoxy resin, is mixed with the volatile liquid and porous particles to saturate the particles. The polymer resin, such as epoxy resin, is added to the mixture for forming a resin cured shell around the porous particle holding the volatile liquid to form a microencapsulated volatile liquid. The resin is only cured on the outer shell of the porous particle when coming in contact with the catalyst supported with the volatile liquid in the porous particle.
    Type: Grant
    Filed: May 15, 2002
    Date of Patent: July 22, 2003
    Inventor: Phillip G. Landers
  • Publication number: 20030055115
    Abstract: A water-based ink for ink-jet printing, comprising colored particles containing: (a) a core particle having a colorant; and (b) a shell having a resin and encapsulating the core particle, wherein the resin comprises a monomer unit having a hydroxyl group in an amount of 0.1 to 50 weight % based on the total weight of the shell.
    Type: Application
    Filed: September 6, 2002
    Publication date: March 20, 2003
    Inventors: Hidetaka Ninomiya, Hiroaki Ando
  • Patent number: 6531519
    Abstract: A method of preventing the growth of heterotrophic bacteria and the subsequent establishment of a biofilm on the surface and in the micropores of an antimicrobial synthetic ion exchange resin. An antimicrobial synthetic ion exchange resin that prevents the growth of heterotrophic bacteria and the subsequent establishment of biofilm on the surface and in the micropores of the resin. A broad spectrum organic antimicrobial agent that is water insoluble and thus precipitates out and becomes encapsulated within micropores of the resin during suspension polymerization. The antimicrobial agent is submicron sized and has a high surface area. The antimicrobial agent protects the antimicrobial synthetic ion exchange bead from the growth of heterotrophic bacteria and the subsequent establishment of biofilm on the surface and in the micropores of the resin. The antimicrobial agent is nontoxic, noncarcinogenic, substantially nonleaching and durable over the lifespan of the bead.
    Type: Grant
    Filed: December 8, 2000
    Date of Patent: March 11, 2003
    Assignee: Microban Products Company
    Inventor: Arvind S. Patil
  • Patent number: 6503559
    Abstract: The present invention relates to colorant compositions containing neonanoplasts. The colorant compositions exhibit improved color brightness and brilliance due to the incorporation of one or more colorants in the neonanoplasts. The colorant compositions may be printed onto virtually any substrate. The colorant compositions of the present invention have particular utility in the area of printed textiles.
    Type: Grant
    Filed: June 3, 1999
    Date of Patent: January 7, 2003
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Ronald Sinclair Nohr, John Gavin MacDonald
  • Patent number: 6500447
    Abstract: The present invention provides pH-sensitive micro-capsules, compositions containing them, methods for their preparation and methods for their use.
    Type: Grant
    Filed: August 13, 1999
    Date of Patent: December 31, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Robin William Dexter, Brian Eric Benoff
  • Patent number: 6486099
    Abstract: A microcapsule (or microencapsulated product) having a uniform and smooth coating film and also an excellent performance of gradually liberating the content material is produced at a good particle size distribution while suppressing the occurrence of isolated or aggregated film material, aggregated microcapsules and isolated core material. The production process includes: a first coating step of mixing a water-soluble cationic amino resin and an anionic surfactant in the presence of a hydrophobic core material dispersed in an aqueous medium to coat the dispersed core material with a coacervate of the cationic amino resin and the anionic surfactant; and a second coating step of adding an amino resin prepolymer into an aqueous dispersion liquid containing the coated dispersed core material and polycondensating the amino resin prepolymer to further coat the coated dispersed core material with a polycondensate of the amino resin prepolymer.
    Type: Grant
    Filed: January 12, 2001
    Date of Patent: November 26, 2002
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yutaka Igari, Yuzi Hori, Tsuneo Okamoto