Pigment Containing Coating Patents (Class 427/218)
  • Patent number: 4835023
    Abstract: An ornamental article comprising a natural ornamental material such as pearl and a cured coating membrane of a composition based on organic materials which is coated on the surface of said natural ornamental material in a thickness from 0.01 .mu.m to 30 .mu.m, with improved properties such as surface luster and resistivity to scratch, light, chemicals, etc.
    Type: Grant
    Filed: July 1, 1986
    Date of Patent: May 30, 1989
    Assignee: Toray Industries, Inc.
    Inventors: Takashi Taniguchi, Hiroshi Hosono, Itaru Nakamura
  • Patent number: 4724161
    Abstract: Phosphors are coated and deaggregated by treatment with ultrasonic energy during the coating step. The phosphor aqueous dispersion is continuously passed through an ultrasonic chamber at a rate of flow so as to prevent aggregated phosphor particles from settling out and avoiding deaggregation.
    Type: Grant
    Filed: September 15, 1986
    Date of Patent: February 9, 1988
    Assignee: RCA Corporation
    Inventors: Maurice D. Coutts, Stephen S. Trond
  • Patent number: 4720378
    Abstract: Coated articles, for example colored pharmaceutical tablets, bearing highlighted intagliations. The articles are colored intagliated articles bearing at least one film coat comprising at least one optically anisotropic substance, for example magnesium carbonate, and at least one film coating agent. Process for manufacturing said articles.
    Type: Grant
    Filed: July 22, 1986
    Date of Patent: January 19, 1988
    Assignee: Imperial Chemical Industries PLC
    Inventors: Sidney F. Forse, Raymond C. Rowe
  • Patent number: 4695478
    Abstract: A catholuminescent material consisting essentially of particles of copper-activated zinc sulfide cathodoluminescent phosphor having at least a partial coating of a mixture of a blue pigment of cobalt aluminate and a red pigment of iron oxide wherein the weight ratio of said blue pigment to said red pigment is from about 3.5:1 to about 4.5:1 and the weight percent of said pigments are from about 0.2% to about 2% by weight of catholuminescent phosphor. A process for producing said pigmented phosphor comprises forming the appropriate aqueous slurries by proper pH control and then by the addition of collodial silica, the pigment is coated onto the phosphor particles.
    Type: Grant
    Filed: June 6, 1986
    Date of Patent: September 22, 1987
    Assignee: GTE Products Corporation
    Inventors: Harry O. Schulze, Ronald E. Karam
  • Patent number: 4684540
    Abstract: A pigmented silicate coated phosphor is disclosed and a process for producing the phosphor. The process involves preparing a relatively uniform aqueous mixture of particles of a phosphor, particles of a deagglomerated pigment, and a free flowing agent and then adding a precipitating agent to the mixture in an amount sufficient to cause the free flowing agent and pigment to co-precipitate upon and coat the phosphor, followed by separating the pigmented phosphor from the resulting liquor. A relatively uniform mixture is formed of the resulting dried phosphor, a water soluble silicate, and water the water being in an amount of sufficient to allow the silicate to coat the surface of the phosphor particles. The mixture is heated at a sufficient temperature for a sufficient time with sufficient agitation to produce the final non-agglomerated silicate coated pigmented phosphor.
    Type: Grant
    Filed: January 31, 1986
    Date of Patent: August 4, 1987
    Assignee: GTE Products Corporation
    Inventor: Harry O. Schulze
  • Patent number: 4675251
    Abstract: Spherical particles having sizes below 1 .mu.m, or at maximum of 3.04 .mu.m, a narrow size size distribution consisting, or consisting essentially, of TiO.sub.2 coated by a uniform layer having a thickness up to 400 .ANG. consisting essentially .alpha.-, or .gamma.-Fe.sub.2 O.sub.3, or magnetite, or mixtures thereof, said particles being prepared by a process consisting, or consisting essentially, in the precipitation of the oxide from Fe (III) salt solutions on the surface of solid pre-formed TiO.sub.2 particles having a narrow size distribution and a number average diameter below 1 .mu.m or .ltoreq.3 .mu.m, the Fe (III) concentration being .ltoreq.40% by weight calculated on TiO.sub.2, the pH of the suspension ranging from 1.0 to 2.8, extremes excluded, by heating the suspensions to temperatures of from 80.degree. to 100.degree. C., and by aging them under such conditions for at least 30 minutes.
    Type: Grant
    Filed: February 18, 1986
    Date of Patent: June 23, 1987
    Assignee: Montedison S.p.A.
    Inventors: Egon Matijevic, Paola Gherardi
  • Patent number: 4565581
    Abstract: Nacreous pigments having improved light fastness are based on mica platelets coated with titanium dioxide and, optionally other additional metal oxides. These pigments carry an additional thin manganese oxide layer. The pigments are prepared in a process wherein mica is coated in aqueous suspension with one or more titanium dioxide hydrate layers and, optionally, with further metal oxide layers, mixed with the titanium dioxide hydrate or separately therefrom, and then is washed, dried and calcined. The process further comprises precipitating an additional layer of manganese hydroxide onto the base pigment, either directly after coating with the titanium dioxide hydrate and/or metal oxide layers or after the calcination thereof. The flakes are the washed, dried and calcined.The new pigment can be used for pigmenting plastics, lacquers, paints and cosmetics, inter alia.
    Type: Grant
    Filed: December 27, 1982
    Date of Patent: January 21, 1986
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Horst Bernhard
  • Patent number: 4515827
    Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.
    Type: Grant
    Filed: June 17, 1982
    Date of Patent: May 7, 1985
    Assignee: GTE Products Corporation
    Inventors: Robert E. Dodds, David J. Harrigan
  • Patent number: 4513025
    Abstract: A single particle penetration phosphor employs La.sub.2 O.sub.2 S:Tb particles as a core particle having a thin layer of La.sub.2 O.sub.2 SO.sub.4 :Tb formed thereon by oxidation to provide a barrier which must be penetrated by excitation electrons to produce narrow bandwidth green spectral emission from the particle. The thin barrier is in turn coated by a layer of YVO.sub.4 :Eu particles which produce narrow bandwidth red spectral emission upon electron excitation. The barrier layer increases the voltage turn on characteristic of the green carrier host thereby causing the electron irradiated phosphor to radiate in the red spectrum for low voltages and in the green spectrum for higher voltages. Additionally, methods are disclosed for synthesizing the above single particle penetration phosphor.
    Type: Grant
    Filed: May 11, 1982
    Date of Patent: April 23, 1985
    Assignee: Sperry Corporation
    Inventors: Thomas E. Clark, Charles T. Burilla
  • Patent number: 4455362
    Abstract: In a process for the preparation of an electrostatographic toner material comprising encapsulating a core material containing colorant with a shell material in an aqueous medium to prepare encapsulted toner particles and drying the so prepared encapsulted toner particles, the improvement which comprises washing the encapsulated toner particles with an aqueous solution of a surface active agent in advance of subjecting them to the drying procedure.
    Type: Grant
    Filed: November 24, 1982
    Date of Patent: June 19, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Naoi, Fujio Kakimi
  • Patent number: 4398119
    Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.
    Type: Grant
    Filed: September 19, 1980
    Date of Patent: August 9, 1983
    Assignee: GTE Products Corporation
    Inventors: Robert E. Dodds, David J. Harrigan
  • Patent number: 4391875
    Abstract: The abrasion resistance and tensile strength of asbestos is significantly improved by the addition of significant amounts of metal oxides, such as iron oxide, under conditions to provide at least some surface bonding of the oxides to the surface of the asbestos. The oxides are preferably added during formation of bodies from asbestos dispersions and also impart color to the final product.
    Type: Grant
    Filed: December 11, 1980
    Date of Patent: July 5, 1983
    Assignee: RM Industrial Products Company, Inc.
    Inventors: Byeong H. Jo, Jerry Zucker
  • Patent number: 4388149
    Abstract: The invention relates to a chrysotile asbestos fiber substantially coated on its exterior surface with hydrated titanium dioxide, the titanium dioxide content being from 0.5 to 35% by weight, part of the titanium dioxide being chemically bonded to the asbestos fiber and the remaining titanium dioxide being retained by electrostatic bond, said modified fiber having an Mg:Si ratio of from less than 3:2 to 2:2 when calculated on an atomic number ratio, a Ti:Si ratio of from more than 0:2 to less than 1:2 and said modified fiber being also characterized by an infrared spectrum wherein the relative peaks at 1082, 1025 and 957 cm.sup.-1 have been substantially altered in their intensity and as shown in curves C and D of FIG. 1 , said fiber resisting leaching of the Mg ions by strong acids 3 to 6 times better than natural asbestos fibers and resisting leaching of SiO.sub.2 groups in strong alkali media 1.5 to 3 times better than unmodified chrysotile fibers.
    Type: Grant
    Filed: October 13, 1981
    Date of Patent: June 14, 1983
    Assignee: Societe Nationale de L'Amiante
    Inventors: Frank M. Kimmerle, Pierre Roberge
  • Patent number: 4376656
    Abstract: Yellow iron oxide pigments having improved heat stability are prepared by subjecting an alkaline slurry of conventional yellow iron oxide, a soluble ferric salt, sodium aluminate, and a third metal component, exemplified by antimony ion or a zinc ion/titanium ion combination, to a hydrothermal (autoclave) treatment at about 100.degree.-240.degree. C. The separated solid product has a heat stability temperature (based on the color change from yellow to red when heated) appreciably higher than that of the starting iron oxide.
    Type: Grant
    Filed: October 16, 1981
    Date of Patent: March 15, 1983
    Assignee: Titan Kogyo K.K.
    Inventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi, Yakanori Yamasaki
  • Patent number: 4374675
    Abstract: This invention concerns a new product consisting of TiO.sub.2 particles having pigmentary granulometric and morphological characteristics. It includes a chemically reactive coating consisting of a mixture of oxides and oxychlorides selected from the group consisting of Al.sub.2 O.sub.3 and AlOCl; SiO.sub.2 and SiOCl.sub.2 ; and ZrO.sub.2 and ZrOCl.sub.2.The particles of reactive TiO.sub.2 product are prepared as follows: the surface of the TiO.sub.2 particles is activated by thermally treating the particles in a moving bed with an anhydrous gas at 400.degree.-600.degree. C. The particles are then made to react in a moving bed at 350.degree. C. to 600.degree. C., in the presence of a carrier gas, with an inorganic chloride selected from the group consisting of AlCl.sub.3, SiCl.sub.4 and ZrCl.sub.4.This new product is useful, for instance, in TiO.sub.2 pigments coated with organic molecules which provide an affinity for the vehicles of paints.
    Type: Grant
    Filed: January 9, 1981
    Date of Patent: February 22, 1983
    Assignee: Montedison, S.p.A.
    Inventors: Carlo Scotti, Renato C. Pace, Sergio Carra'
  • Patent number: 4374676
    Abstract: Yellow iron oxide pigments having improved heat stability are prepared by mixing a conventional yellow iron oxide pigment with an aqueous alkaline solution of a soluble antimony compound. This yields a yellow pigment whose particle surface is coated with "antimony-bloom", and this product has a higher heat stability temperature than does the starting yellow iron oxide. When the product coated with "antimony-bloom" is subjected to hydrothermal treatment (autoclaving), the resultant material has a yet-higher heat stability temperature. Other, related treatments furnish products with improved heat stability temperatures.
    Type: Grant
    Filed: December 7, 1981
    Date of Patent: February 22, 1983
    Assignee: Titan Kogyo K.K.
    Inventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi, Takanori Yamasaki
  • Patent number: 4374677
    Abstract: Yellow iron oxide pigments having improved heat stability are prepared by subjecting an alkaline slurry of conventional yellow iron oxide, a soluble ferric salt, and sodium aluminate to a hydrothermal (autoclave) treatment at 100.degree.-240.degree. C., separating and slurrying the resultant solid product, and subjecting that product to a second hydrothermal treatment of 250.degree.-350.degree. C. The original iron oxide has a heat stability (based on color change from yellow to red) temperature of about 203.degree. C., while the final product shows a change at 270.degree. C.
    Type: Grant
    Filed: October 5, 1981
    Date of Patent: February 22, 1983
    Assignee: Titan Kogyo K.K. Japan
    Inventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi
  • Patent number: 4331706
    Abstract: This invention relates to a novel composite pigment and method for its manufacture which comprises a finely-divided inert pigment as a core which has deposited on its surface a non-photoconductive grade of zinc oxide, the weight ratio of zinc oxide ranging from about 30% to about 80% of the total weight of the composite pigment and the composite pigment characterized by a specific surface in excess of about 10 square meters/gram. In rubber compounding, the composite pigment reduces the cost of the zinc essential to produce quality products and the composite pigment because it is itself photoconductive is of utility in photoconductive end uses.
    Type: Grant
    Filed: January 9, 1980
    Date of Patent: May 25, 1982
    Assignee: The Sherwin-Williams Company
    Inventor: Robert H. Kindrick
  • Patent number: 4309481
    Abstract: Disclosed is a filter-coated phosphor having phosphor particles coated with filter particles formed of pigments of the same color as that of light emitted from the phosphor, the phosphor particles coated with the filter particles being additionally coated with a borate compound. According to this filter-coated phosphor, the filter particles never exfoliate from the surfaces of the phosphor particles in a slurry, satisfactory dispersibility is obtained in the slurry, and the slurry pH is stable. A phosphor screen of a color picture tube obtained with use of the filter-coated phosphor exhibits highly outstanding contrast and luminous efficiency.
    Type: Grant
    Filed: April 9, 1980
    Date of Patent: January 5, 1982
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Tadashi Wakatsuki, Takeshi Takahara
  • Patent number: 4291112
    Abstract: A toner composition comprised of a resin and a pigment coated with a nitrogen containing compound thereby causing a change in the charge characteristics of the pigment, the nitrogen containing compound being selected from the group consisting of(a) quaternary ammonium compounds of the formula: ##STR1## wherein R is hydrogen, hydrocarbon radicals containing from 1 to about 22 carbon atoms, or mixtures thereof, and A is an anion selected from sulfate, sulfonate, nitrate, borate, chlorate, and halogen;(b) primary, secondary, or tertiary amines of the formula: ##STR2## wherein R is an aliphatic radical containing from about 8 to about 22 carbon atoms, and R.sub.1 and R.sub.2 are hydrocarbon radicals containing from 1 to about 22 carbon atoms; and(c) an alkyl pyridinium compound, and its hydrates.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: September 22, 1981
    Assignee: Xerox Corporation
    Inventor: Chin H. Lu
  • Patent number: 4284696
    Abstract: Disclosed is a light transmission particle containing a colorless sublimable dye, an acyl leucophenoxazine compound suitable for use in the formation of a color image. This particle can produce a clear color image having little fogging and having an excellent resolving power.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: August 18, 1981
    Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.
    Inventors: Eisuke Ishida, Yuji Takashima, Hisanori Nishiguchi, Yoshihide Miyazawa, Katsuichi Motohashi
  • Patent number: 4264677
    Abstract: An europium activated oxysulfide phosphor represented by the formulaLn.sub.2 O.sub.2 S:Eu,(Sm)wherein Ln is at least one element selected from the group consisting of yttrium, gadolinium, lanthanum, lutetium and scandium is colored into red by mixing therewith a proper amount of calcium salt solely or together with strontium salt, and firing the resulting mixture at a temperature within the range of 1000.degree. to 1500.degree. C. By the firing, a CaS:Eu,(Sm) phosphor or a (Ca,Sr)S:Eu,(Sm) phosphor having a red body color is produced in an external portion of the Ln.sub.2 O.sub.2 S:Eu,(Sm) phosphor particle. The red colored phosphor thus obtained is used as a red emitting phosphor of a high contrast cathode ray tube for color television.
    Type: Grant
    Filed: February 2, 1979
    Date of Patent: April 28, 1981
    Assignee: Kasei Optonix, Ltd.
    Inventors: Kazuo Koyama, Takashi Miyagawa, Michio Mathuyuki
  • Patent number: 4264700
    Abstract: Toner particles are prepared by a dispersion polymerization technique wherein a solvent for the monomer is included in the preparation of the discontinuous phase, and the solvent is removed prior to polymerization to increase the weight ratio of the magnetic particles present in the completed toner particles.
    Type: Grant
    Filed: October 22, 1979
    Date of Patent: April 28, 1981
    Assignee: Xerox Corporation
    Inventor: Robert D. Bayley
  • Patent number: 4219587
    Abstract: Pigment-coated phosphors which may be used in the production of a cathode-ray tube of a high contrast for a color television receiver can be produced by adding a pigment and an anionic polymer emulsion to an aqueous suspension of a phosphor and then making the system neutral or weakly acidic or adding a cationic polymer emulsion or carrying out both of these steps so that the phosphor and the pigment may be coated with the polymer.
    Type: Grant
    Filed: December 19, 1977
    Date of Patent: August 26, 1980
    Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.
    Inventors: Yoichi Oba, Tsuyoshi Kano, Masaaki Hayashi, Hiroshi Takada, Katuzo Kanda, Shusaku Eguchi
  • Patent number: 4213872
    Abstract: A liquid developer composition for visual development of latent electrostatic images in which the pigment particles dispersed in the liquid carrier is a metal-dithiooxamide product or a pigment coated with said metal-dithiooxamide reaction product whereby the liquid developer composition is relatively free of sludging.
    Type: Grant
    Filed: July 17, 1978
    Date of Patent: July 22, 1980
    Assignee: A. B. Dick Company
    Inventor: Robert N. Cooper
  • Patent number: 4209567
    Abstract: A red emitting phosphor having a low luminous reflectance, comprising a rare earth element-based phosphor body activated by europium and a red pigment coated on the phosphor body, is disclosed, the pigment being formed of indium sulfide or of a combination of indium sulfide and an alkali metal sulfate. The phosphor is produced by coating the phosphor body with a complex compound containing of indium sulfide and an alkali metal sulfide, followed by baking in an oxygen containing atmosphere at 400.degree. to 600.degree. C. so as to convert the complex compound into a red pigment consisting of indium sulfide and an alkali metal sulfate.
    Type: Grant
    Filed: November 16, 1978
    Date of Patent: June 24, 1980
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Takeshi Takahara, Susumu Matsuura, Toshio Nishimura, Nobuo Inoue
  • Patent number: 4206250
    Abstract: A pigment-coated phosphor having good finish sieve passability and capable of forming a fluorescent film with excellent properties can be produced from a process characterized by:(1) the first step of adding to a water suspension of a phosphor and a pigment an anionic polymer emulsion which has a minimum film forming temperature of less than 30.degree. C.;(2) the second step of adding a cationic polymer emulsion which has a minimum film forming temperature of 30.degree. C. or lower;(3) the thrid step of adding an anionic polymer emulsion which has a minimum film forming temperature of 30.degree. C. or higher; and(4) the fourth step of making the mixture system neutral or weakly acidic.
    Type: Grant
    Filed: October 26, 1978
    Date of Patent: June 3, 1980
    Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.
    Inventors: Yoichi Oba, Katuzo Kanda, Shusaku Eguchi, Kazuhito Iwasaki
  • Patent number: 4192691
    Abstract: Unsupported metal oxide platey nacreous pigments are derived from metal oxide coated mica by a unique dissolution process and show higher luster and coverage than the pigment from which they are derived. If the metal oxide coated mica shows a reflection interference color, the unsupported product derived from it shows higher luster and greater reflection color intensity.
    Type: Grant
    Filed: October 26, 1978
    Date of Patent: March 11, 1980
    Assignee: The Mearl Corporation
    Inventor: Louis Armanini
  • Patent number: 4176078
    Abstract: A method of coating pigment particles such as magnetite with a fatty acid chrome complex is disclosed. The magnetite pigments coated by this process are found to be particularly suitable for use in formation of field dependent toners.
    Type: Grant
    Filed: June 2, 1977
    Date of Patent: November 27, 1979
    Assignee: Xerox Corporation
    Inventor: Chin H. Lu
  • Patent number: 4175160
    Abstract: The disposition of an array of color phosphor dots on a color cathode ray tube faceplate by conventional photo deposition techniques is facilitated by first coating the individual phosphor particles with polyvinyl alcohol modified with an amino acid such as glutamic or aspartic acid.
    Type: Grant
    Filed: June 22, 1978
    Date of Patent: November 20, 1979
    Assignee: GTE Sylvania Incorporated
    Inventor: Clarence D. Vanderpool
  • Patent number: 4162348
    Abstract: A method for coloring inorganic substrates such as glass beads, glass fibers, mineral wool, rock wool, mineral fiber boards and cloths, concrete molded materials, inorganic pigments and metallic powders, which comprises treating the inorganic substrate with (1) a cationic component comprising(a) a water soluble cationic resin or an aqueous solution of a water soluble cationic resin,(b) an aqueous solution of a water soluble cationic resin and a water soluble cationic dye, or(c) an aqueous dispersion of a water soluble cationic resin, a cationic dispersing agent plus a water insoluble dye or pigment and, optionally, a cationic water soluble dye; andWith (2) an anionic component comprising(d) an aqueous solution of a water soluble anionic dye,(e) an anionic dispersing agent or an aqueous solution of an anionic dispersing agent,(f) an aqueous solution of an anionic dispersing agent and a water soluble anionic dye, or(g) an aqueous dispersion of an anionic dispersing agent plus a water insoluble dye or pigment an
    Type: Grant
    Filed: January 28, 1976
    Date of Patent: July 24, 1979
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shigeru Juzu, Hiroyuki Okazaki, Yasuyuki Suzuki
  • Patent number: 4152483
    Abstract: On the surface of a phosphor, pigment particles are uniformly adhered by a layer of a gelatin-gum arabic mixture. A process for manufacturing such a pigment coated phosphor includes the steps of preparing an aqueous solution of gelatin and an aqueous solution of gum arabic, allowing the phosphor to disperse homogeneously into one of these aqueous solutions, allowing the pigment particles to disperse homogeneously into the other aqueous solution, and mixing the so obtained phosphor and pigment dispersions.
    Type: Grant
    Filed: November 18, 1977
    Date of Patent: May 1, 1979
    Assignee: Dai Nippon Toryo Co., Ltd.
    Inventors: Katuzo Kanda, Noboru Kotera, Seiji Murakami, Thihiro Yoshida, Shusaku Eguchi, Toshiaki Hatsumi, Kazuhito Iwasaki, Isao Iwamoto
  • Patent number: 4148741
    Abstract: A method of toner formation utilizing bead polymerization to produce colored particles which may be directly attrited to toner.
    Type: Grant
    Filed: August 2, 1976
    Date of Patent: April 10, 1979
    Assignee: Xerox Corporation
    Inventor: Robert D. Bayley
  • Patent number: 4146403
    Abstract: Iron oxide coated mica nacreous pigments are improved by interposing a thin layer of titanium dioxide or aluminum oxide between the iron oxide and the mica.
    Type: Grant
    Filed: April 27, 1978
    Date of Patent: March 27, 1979
    Assignee: The Mearl Corporation
    Inventors: Louis Armanini, Frank Bagala
  • Patent number: 4141751
    Abstract: A silane coupling agent of either ambi or monofunctional type, and/or an isopropyl titanate coupling agent of either ambi or monofunctional type; and/or, a glass resin thermoset silicone coupling agent of either ambi or monofunctional type which is refined siloxane chain/s with select OH groups in a carrier solution is and are sprayed or poured into hydrophilic particulate and/or fibrous, crystalline and/or amorphous inorganic substances or compounds in a high intensity mixing apparatus between about 70.degree. F. and 350.degree. F. and a silane coupling agent of either ambi or monofunctional; and/or an isopropyl titanate coupling agent of either ambi or monofunctional type; and/or, a glass resin thermoset silicone coupling agent of either ambi or monofunctional type which is refined siloxane chain/s with select OH groups in a carrier solution and hydrophilic particulate and/or fibrous, crystalline and/or amorphous inorganic substances are allowed to remain in situ at a temperature between 70.degree. F.
    Type: Grant
    Filed: April 13, 1977
    Date of Patent: February 27, 1979
    Assignee: Malvern Minerals Company
    Inventor: James E. Moreland
  • Patent number: 4133774
    Abstract: Novel pressure fixable direct imaging magnetic toners having a core of magnetic material held together with an adhesive resin, a barrier substantially covering the core, an overcoat of thermoplastic strengthening resin, and an outer conductive layer, together with novel processes for producing such toners, these processes comprising dispersion of the core material followed by agglomeration of the several layers in a single aqueous medium.
    Type: Grant
    Filed: September 29, 1977
    Date of Patent: January 9, 1979
    Assignee: Reprographic Materials, Inc.
    Inventors: Carl Brynko, Carl G. Brynko
  • Patent number: 4128674
    Abstract: A pigmented phosphor comprises a core of a phosphor particle having a light modifying layer thereon. The light modifying layer is comprised of a co-precipitated mixture of silica or pyrophosphate and a pigment which modifies the light output of the energized phosphor. The phosphor is coated by first preparing an unique pigment stock suspension containing the pigment, water, and a polyacrylamide dispersant. The stock solution is then diluted and phosphor particles are added thereto and the mixture is vigorously stirred. The pH of the mixture can be adjusted to about 5 by the addition of acetic acid and then a small amount of positively charged colloidal silica or pyrophosphate is added. After mixing, the pH is raised to about 9 by the addition of a base or a salt which causes a gel to form and the silica or pyrophosphate and the pigment to co-precipitate out upon the phosphor particles.
    Type: Grant
    Filed: March 31, 1976
    Date of Patent: December 5, 1978
    Assignee: GTE Sylvania Incorporated
    Inventor: Robert A. Hedler
  • Patent number: 4098714
    Abstract: Disclosed is a process for preparing a water softening composition which comprises the steps of:(a) applying to finely divided solid carrier particles of an inorganic material selected, e.g., from the group consisting of aluminosilicates having an Al.sub.2 O.sub.3 content of from 1 to 75% by mole, kieselguhr, a silicic acid composition containing 67 mole % of SiO.sub.2, 1 mole % of Al.sub.2 O.sub.3 and 278 mole % of H.sub.2 O, a silica gel containing 12.24% of SiO.sub.2, 7.35% of N.sub.2 SO.sub.4, 0.41% of Na.sub.2 O and 80% of H.sub.2 O, aluminum oxide, alumina hydrate, bentonite and sodium sulfate, a solution of sodium aluminate having a concentration of from about 0.2% to 25% by weight and a molar ratio Na.sub.2 O/Al.sub.2 O.sub.3 of from about 0.3 to 47, in an amount which is sufficient to coat the particles with an outside layer of sodium aluminate amounting from about 0.5 to about 50% by weight of the particles; and, (b) drying the coated particles at a temperature of from about 20.degree. to 120.
    Type: Grant
    Filed: June 18, 1976
    Date of Patent: July 4, 1978
    Assignee: Kali-Chemie AG
    Inventors: Helmut Derleth, Maria Hansen, Ingeborg Lange, Artur Kurs
  • Patent number: 4093777
    Abstract: A stabilized cadmium chalcogenide, in which optionally zinc and/or mercury is present in the lattice, carrying at least one coating of a sparingly-soluble sulfide is produced by adding at least one water-soluble salt of an element forming a sparingly-soluble sulfide to an aqueous chalcogenide suspension, mixing with a compound releasing sulfide ions and/or mixing the cadmium chalcogenide suspension with a soluble thio-compound of an element forming a sparingly-soluble sulfide thereby to precipitate a sparingly-soluble sulfide onto the chalcogenide, subsequently filtering, optionally washing, drying and annealing the aftertreated chalcogenide. Suitable sparingly-soluble sulfides are, for example, the sulfides of the elements Zn, Hg, In, Sn, Pb, As, Sb, Bi, V, Mo, W, Cu and Ag.
    Type: Grant
    Filed: October 6, 1975
    Date of Patent: June 6, 1978
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinrich Heine, Peter Woditsch, Theodor Bohmann, Dieter Rade
  • Patent number: 4076551
    Abstract: A process for the preparation of carbon black-containing pigments consists essentially of precipitation of a carbon black-containing metal hydroxide or bismuth oxychloride layer on substrate particles in an aqueous suspension containing carbon black particles of particle size of below 1 mn. and washing, drying and optionally calcining the products. Flaky substrates, e.g., mica flakes coated with TiO.sub.2, are preferably employed. Carbon black-containing pigments obtained have carbon black particles incorporated in a metal hydroxide, metal oxide or bismuth oxychloride layer precipitated on the substrate in the presence of the carbon black.
    Type: Grant
    Filed: December 10, 1976
    Date of Patent: February 28, 1978
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Horst Bernhard, Reiner Esselborn
  • Patent number: 4049845
    Abstract: Method comprises adsorbing colloidal particles of a latex onto phosphor particles, providing filter particles in a liquid medium, optionally adsorbing colloidal particles of a latex onto the filter particles and combining the phosphor particles and filter particles into a single mixture. The foregoing steps, which are conducted in aqueous media, may be carried out in any order. Thereafter, the combined mixture of phosphor particles with adsorbed colloidal particles thereon and filter particles is coagulated while in an aqueous medium.
    Type: Grant
    Filed: March 8, 1976
    Date of Patent: September 20, 1977
    Assignee: RCA Corporation
    Inventors: Gerald Scott Lozier, Phyllis Brown Branin
  • Patent number: 4020231
    Abstract: A composite article comprises a core of a phosphor particle having a light modifying layer thereon. The light modifying layer is comprised of a co-precipitated mixture of a free-flowing agent such as silica or pyrophosphate and a pigment which modifies the light output of the energized phosphor. Also disclosed is a method of making the composite article which comprises the steps of preparing an aqueous mixture of particles of phosphor, particles of a pigment and a positively charged colloidal silica or pyrophosphate and mixing thoroughly. After mixing, a base, in the case of silica, or a salt which will form an insoluble pyrophosphate in the case of the pyrophosphate, is added thereto in sufficient amount to gel the mixture causing the silica or pyrophosphate and the pigment to co-precipitate upon and coat the phosphor particles. After the coating operation the supernatant liquid is removed and the coated phosphor is dried.
    Type: Grant
    Filed: March 31, 1976
    Date of Patent: April 26, 1977
    Assignee: GTE Sylvania Incorporated
    Inventors: Robert A. Hedler, W. Wentworth Slobbe
  • Patent number: 3973055
    Abstract: The dielectric recording media comprise electroconductive substrates coated with dielectric resin binder. The process comprises dispersing an organophilic clay pigment in the dielectric resin binder and coating the electroconductive substrate with the dispersion. The organophilic clay pigment is obtained by treating calcined kaolin clay with an organotitanium compound.
    Type: Grant
    Filed: January 27, 1975
    Date of Patent: August 3, 1976
    Assignee: Monsanto Company
    Inventors: Albert H. Markhart, David R. Cahill