Pigment Containing Coating Patents (Class 427/218)
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Patent number: 4835023Abstract: An ornamental article comprising a natural ornamental material such as pearl and a cured coating membrane of a composition based on organic materials which is coated on the surface of said natural ornamental material in a thickness from 0.01 .mu.m to 30 .mu.m, with improved properties such as surface luster and resistivity to scratch, light, chemicals, etc.Type: GrantFiled: July 1, 1986Date of Patent: May 30, 1989Assignee: Toray Industries, Inc.Inventors: Takashi Taniguchi, Hiroshi Hosono, Itaru Nakamura
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Patent number: 4724161Abstract: Phosphors are coated and deaggregated by treatment with ultrasonic energy during the coating step. The phosphor aqueous dispersion is continuously passed through an ultrasonic chamber at a rate of flow so as to prevent aggregated phosphor particles from settling out and avoiding deaggregation.Type: GrantFiled: September 15, 1986Date of Patent: February 9, 1988Assignee: RCA CorporationInventors: Maurice D. Coutts, Stephen S. Trond
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Patent number: 4720378Abstract: Coated articles, for example colored pharmaceutical tablets, bearing highlighted intagliations. The articles are colored intagliated articles bearing at least one film coat comprising at least one optically anisotropic substance, for example magnesium carbonate, and at least one film coating agent. Process for manufacturing said articles.Type: GrantFiled: July 22, 1986Date of Patent: January 19, 1988Assignee: Imperial Chemical Industries PLCInventors: Sidney F. Forse, Raymond C. Rowe
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Patent number: 4695478Abstract: A catholuminescent material consisting essentially of particles of copper-activated zinc sulfide cathodoluminescent phosphor having at least a partial coating of a mixture of a blue pigment of cobalt aluminate and a red pigment of iron oxide wherein the weight ratio of said blue pigment to said red pigment is from about 3.5:1 to about 4.5:1 and the weight percent of said pigments are from about 0.2% to about 2% by weight of catholuminescent phosphor. A process for producing said pigmented phosphor comprises forming the appropriate aqueous slurries by proper pH control and then by the addition of collodial silica, the pigment is coated onto the phosphor particles.Type: GrantFiled: June 6, 1986Date of Patent: September 22, 1987Assignee: GTE Products CorporationInventors: Harry O. Schulze, Ronald E. Karam
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Patent number: 4684540Abstract: A pigmented silicate coated phosphor is disclosed and a process for producing the phosphor. The process involves preparing a relatively uniform aqueous mixture of particles of a phosphor, particles of a deagglomerated pigment, and a free flowing agent and then adding a precipitating agent to the mixture in an amount sufficient to cause the free flowing agent and pigment to co-precipitate upon and coat the phosphor, followed by separating the pigmented phosphor from the resulting liquor. A relatively uniform mixture is formed of the resulting dried phosphor, a water soluble silicate, and water the water being in an amount of sufficient to allow the silicate to coat the surface of the phosphor particles. The mixture is heated at a sufficient temperature for a sufficient time with sufficient agitation to produce the final non-agglomerated silicate coated pigmented phosphor.Type: GrantFiled: January 31, 1986Date of Patent: August 4, 1987Assignee: GTE Products CorporationInventor: Harry O. Schulze
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Patent number: 4675251Abstract: Spherical particles having sizes below 1 .mu.m, or at maximum of 3.04 .mu.m, a narrow size size distribution consisting, or consisting essentially, of TiO.sub.2 coated by a uniform layer having a thickness up to 400 .ANG. consisting essentially .alpha.-, or .gamma.-Fe.sub.2 O.sub.3, or magnetite, or mixtures thereof, said particles being prepared by a process consisting, or consisting essentially, in the precipitation of the oxide from Fe (III) salt solutions on the surface of solid pre-formed TiO.sub.2 particles having a narrow size distribution and a number average diameter below 1 .mu.m or .ltoreq.3 .mu.m, the Fe (III) concentration being .ltoreq.40% by weight calculated on TiO.sub.2, the pH of the suspension ranging from 1.0 to 2.8, extremes excluded, by heating the suspensions to temperatures of from 80.degree. to 100.degree. C., and by aging them under such conditions for at least 30 minutes.Type: GrantFiled: February 18, 1986Date of Patent: June 23, 1987Assignee: Montedison S.p.A.Inventors: Egon Matijevic, Paola Gherardi
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Patent number: 4565581Abstract: Nacreous pigments having improved light fastness are based on mica platelets coated with titanium dioxide and, optionally other additional metal oxides. These pigments carry an additional thin manganese oxide layer. The pigments are prepared in a process wherein mica is coated in aqueous suspension with one or more titanium dioxide hydrate layers and, optionally, with further metal oxide layers, mixed with the titanium dioxide hydrate or separately therefrom, and then is washed, dried and calcined. The process further comprises precipitating an additional layer of manganese hydroxide onto the base pigment, either directly after coating with the titanium dioxide hydrate and/or metal oxide layers or after the calcination thereof. The flakes are the washed, dried and calcined.The new pigment can be used for pigmenting plastics, lacquers, paints and cosmetics, inter alia.Type: GrantFiled: December 27, 1982Date of Patent: January 21, 1986Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventor: Horst Bernhard
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Patent number: 4515827Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.Type: GrantFiled: June 17, 1982Date of Patent: May 7, 1985Assignee: GTE Products CorporationInventors: Robert E. Dodds, David J. Harrigan
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Patent number: 4513025Abstract: A single particle penetration phosphor employs La.sub.2 O.sub.2 S:Tb particles as a core particle having a thin layer of La.sub.2 O.sub.2 SO.sub.4 :Tb formed thereon by oxidation to provide a barrier which must be penetrated by excitation electrons to produce narrow bandwidth green spectral emission from the particle. The thin barrier is in turn coated by a layer of YVO.sub.4 :Eu particles which produce narrow bandwidth red spectral emission upon electron excitation. The barrier layer increases the voltage turn on characteristic of the green carrier host thereby causing the electron irradiated phosphor to radiate in the red spectrum for low voltages and in the green spectrum for higher voltages. Additionally, methods are disclosed for synthesizing the above single particle penetration phosphor.Type: GrantFiled: May 11, 1982Date of Patent: April 23, 1985Assignee: Sperry CorporationInventors: Thomas E. Clark, Charles T. Burilla
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Patent number: 4455362Abstract: In a process for the preparation of an electrostatographic toner material comprising encapsulating a core material containing colorant with a shell material in an aqueous medium to prepare encapsulted toner particles and drying the so prepared encapsulted toner particles, the improvement which comprises washing the encapsulated toner particles with an aqueous solution of a surface active agent in advance of subjecting them to the drying procedure.Type: GrantFiled: November 24, 1982Date of Patent: June 19, 1984Assignee: Fuji Photo Film Co., Ltd.Inventors: Takashi Naoi, Fujio Kakimi
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Patent number: 4398119Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.Type: GrantFiled: September 19, 1980Date of Patent: August 9, 1983Assignee: GTE Products CorporationInventors: Robert E. Dodds, David J. Harrigan
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Patent number: 4391875Abstract: The abrasion resistance and tensile strength of asbestos is significantly improved by the addition of significant amounts of metal oxides, such as iron oxide, under conditions to provide at least some surface bonding of the oxides to the surface of the asbestos. The oxides are preferably added during formation of bodies from asbestos dispersions and also impart color to the final product.Type: GrantFiled: December 11, 1980Date of Patent: July 5, 1983Assignee: RM Industrial Products Company, Inc.Inventors: Byeong H. Jo, Jerry Zucker
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Patent number: 4388149Abstract: The invention relates to a chrysotile asbestos fiber substantially coated on its exterior surface with hydrated titanium dioxide, the titanium dioxide content being from 0.5 to 35% by weight, part of the titanium dioxide being chemically bonded to the asbestos fiber and the remaining titanium dioxide being retained by electrostatic bond, said modified fiber having an Mg:Si ratio of from less than 3:2 to 2:2 when calculated on an atomic number ratio, a Ti:Si ratio of from more than 0:2 to less than 1:2 and said modified fiber being also characterized by an infrared spectrum wherein the relative peaks at 1082, 1025 and 957 cm.sup.-1 have been substantially altered in their intensity and as shown in curves C and D of FIG. 1 , said fiber resisting leaching of the Mg ions by strong acids 3 to 6 times better than natural asbestos fibers and resisting leaching of SiO.sub.2 groups in strong alkali media 1.5 to 3 times better than unmodified chrysotile fibers.Type: GrantFiled: October 13, 1981Date of Patent: June 14, 1983Assignee: Societe Nationale de L'AmianteInventors: Frank M. Kimmerle, Pierre Roberge
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Patent number: 4376656Abstract: Yellow iron oxide pigments having improved heat stability are prepared by subjecting an alkaline slurry of conventional yellow iron oxide, a soluble ferric salt, sodium aluminate, and a third metal component, exemplified by antimony ion or a zinc ion/titanium ion combination, to a hydrothermal (autoclave) treatment at about 100.degree.-240.degree. C. The separated solid product has a heat stability temperature (based on the color change from yellow to red when heated) appreciably higher than that of the starting iron oxide.Type: GrantFiled: October 16, 1981Date of Patent: March 15, 1983Assignee: Titan Kogyo K.K.Inventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi, Yakanori Yamasaki
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Patent number: 4374675Abstract: This invention concerns a new product consisting of TiO.sub.2 particles having pigmentary granulometric and morphological characteristics. It includes a chemically reactive coating consisting of a mixture of oxides and oxychlorides selected from the group consisting of Al.sub.2 O.sub.3 and AlOCl; SiO.sub.2 and SiOCl.sub.2 ; and ZrO.sub.2 and ZrOCl.sub.2.The particles of reactive TiO.sub.2 product are prepared as follows: the surface of the TiO.sub.2 particles is activated by thermally treating the particles in a moving bed with an anhydrous gas at 400.degree.-600.degree. C. The particles are then made to react in a moving bed at 350.degree. C. to 600.degree. C., in the presence of a carrier gas, with an inorganic chloride selected from the group consisting of AlCl.sub.3, SiCl.sub.4 and ZrCl.sub.4.This new product is useful, for instance, in TiO.sub.2 pigments coated with organic molecules which provide an affinity for the vehicles of paints.Type: GrantFiled: January 9, 1981Date of Patent: February 22, 1983Assignee: Montedison, S.p.A.Inventors: Carlo Scotti, Renato C. Pace, Sergio Carra'
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Patent number: 4374676Abstract: Yellow iron oxide pigments having improved heat stability are prepared by mixing a conventional yellow iron oxide pigment with an aqueous alkaline solution of a soluble antimony compound. This yields a yellow pigment whose particle surface is coated with "antimony-bloom", and this product has a higher heat stability temperature than does the starting yellow iron oxide. When the product coated with "antimony-bloom" is subjected to hydrothermal treatment (autoclaving), the resultant material has a yet-higher heat stability temperature. Other, related treatments furnish products with improved heat stability temperatures.Type: GrantFiled: December 7, 1981Date of Patent: February 22, 1983Assignee: Titan Kogyo K.K.Inventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi, Takanori Yamasaki
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Patent number: 4374677Abstract: Yellow iron oxide pigments having improved heat stability are prepared by subjecting an alkaline slurry of conventional yellow iron oxide, a soluble ferric salt, and sodium aluminate to a hydrothermal (autoclave) treatment at 100.degree.-240.degree. C., separating and slurrying the resultant solid product, and subjecting that product to a second hydrothermal treatment of 250.degree.-350.degree. C. The original iron oxide has a heat stability (based on color change from yellow to red) temperature of about 203.degree. C., while the final product shows a change at 270.degree. C.Type: GrantFiled: October 5, 1981Date of Patent: February 22, 1983Assignee: Titan Kogyo K.K. JapanInventors: Jihei Senda, Yoshihiro Inoue, Toshiaki Uenishi, Hidefumi Harada, Kouji Nakata, Akio Akagi
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Patent number: 4331706Abstract: This invention relates to a novel composite pigment and method for its manufacture which comprises a finely-divided inert pigment as a core which has deposited on its surface a non-photoconductive grade of zinc oxide, the weight ratio of zinc oxide ranging from about 30% to about 80% of the total weight of the composite pigment and the composite pigment characterized by a specific surface in excess of about 10 square meters/gram. In rubber compounding, the composite pigment reduces the cost of the zinc essential to produce quality products and the composite pigment because it is itself photoconductive is of utility in photoconductive end uses.Type: GrantFiled: January 9, 1980Date of Patent: May 25, 1982Assignee: The Sherwin-Williams CompanyInventor: Robert H. Kindrick
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Patent number: 4309481Abstract: Disclosed is a filter-coated phosphor having phosphor particles coated with filter particles formed of pigments of the same color as that of light emitted from the phosphor, the phosphor particles coated with the filter particles being additionally coated with a borate compound. According to this filter-coated phosphor, the filter particles never exfoliate from the surfaces of the phosphor particles in a slurry, satisfactory dispersibility is obtained in the slurry, and the slurry pH is stable. A phosphor screen of a color picture tube obtained with use of the filter-coated phosphor exhibits highly outstanding contrast and luminous efficiency.Type: GrantFiled: April 9, 1980Date of Patent: January 5, 1982Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Tadashi Wakatsuki, Takeshi Takahara
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Patent number: 4291112Abstract: A toner composition comprised of a resin and a pigment coated with a nitrogen containing compound thereby causing a change in the charge characteristics of the pigment, the nitrogen containing compound being selected from the group consisting of(a) quaternary ammonium compounds of the formula: ##STR1## wherein R is hydrogen, hydrocarbon radicals containing from 1 to about 22 carbon atoms, or mixtures thereof, and A is an anion selected from sulfate, sulfonate, nitrate, borate, chlorate, and halogen;(b) primary, secondary, or tertiary amines of the formula: ##STR2## wherein R is an aliphatic radical containing from about 8 to about 22 carbon atoms, and R.sub.1 and R.sub.2 are hydrocarbon radicals containing from 1 to about 22 carbon atoms; and(c) an alkyl pyridinium compound, and its hydrates.Type: GrantFiled: September 11, 1978Date of Patent: September 22, 1981Assignee: Xerox CorporationInventor: Chin H. Lu
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Patent number: 4284696Abstract: Disclosed is a light transmission particle containing a colorless sublimable dye, an acyl leucophenoxazine compound suitable for use in the formation of a color image. This particle can produce a clear color image having little fogging and having an excellent resolving power.Type: GrantFiled: May 15, 1978Date of Patent: August 18, 1981Assignees: Hodogaya Chemical Co., Ltd., Matsushita Electric Industrial Co., Ltd.Inventors: Eisuke Ishida, Yuji Takashima, Hisanori Nishiguchi, Yoshihide Miyazawa, Katsuichi Motohashi
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Patent number: 4264677Abstract: An europium activated oxysulfide phosphor represented by the formulaLn.sub.2 O.sub.2 S:Eu,(Sm)wherein Ln is at least one element selected from the group consisting of yttrium, gadolinium, lanthanum, lutetium and scandium is colored into red by mixing therewith a proper amount of calcium salt solely or together with strontium salt, and firing the resulting mixture at a temperature within the range of 1000.degree. to 1500.degree. C. By the firing, a CaS:Eu,(Sm) phosphor or a (Ca,Sr)S:Eu,(Sm) phosphor having a red body color is produced in an external portion of the Ln.sub.2 O.sub.2 S:Eu,(Sm) phosphor particle. The red colored phosphor thus obtained is used as a red emitting phosphor of a high contrast cathode ray tube for color television.Type: GrantFiled: February 2, 1979Date of Patent: April 28, 1981Assignee: Kasei Optonix, Ltd.Inventors: Kazuo Koyama, Takashi Miyagawa, Michio Mathuyuki
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Patent number: 4264700Abstract: Toner particles are prepared by a dispersion polymerization technique wherein a solvent for the monomer is included in the preparation of the discontinuous phase, and the solvent is removed prior to polymerization to increase the weight ratio of the magnetic particles present in the completed toner particles.Type: GrantFiled: October 22, 1979Date of Patent: April 28, 1981Assignee: Xerox CorporationInventor: Robert D. Bayley
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Patent number: 4219587Abstract: Pigment-coated phosphors which may be used in the production of a cathode-ray tube of a high contrast for a color television receiver can be produced by adding a pigment and an anionic polymer emulsion to an aqueous suspension of a phosphor and then making the system neutral or weakly acidic or adding a cationic polymer emulsion or carrying out both of these steps so that the phosphor and the pigment may be coated with the polymer.Type: GrantFiled: December 19, 1977Date of Patent: August 26, 1980Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.Inventors: Yoichi Oba, Tsuyoshi Kano, Masaaki Hayashi, Hiroshi Takada, Katuzo Kanda, Shusaku Eguchi
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Patent number: 4213872Abstract: A liquid developer composition for visual development of latent electrostatic images in which the pigment particles dispersed in the liquid carrier is a metal-dithiooxamide product or a pigment coated with said metal-dithiooxamide reaction product whereby the liquid developer composition is relatively free of sludging.Type: GrantFiled: July 17, 1978Date of Patent: July 22, 1980Assignee: A. B. Dick CompanyInventor: Robert N. Cooper
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Patent number: 4209567Abstract: A red emitting phosphor having a low luminous reflectance, comprising a rare earth element-based phosphor body activated by europium and a red pigment coated on the phosphor body, is disclosed, the pigment being formed of indium sulfide or of a combination of indium sulfide and an alkali metal sulfate. The phosphor is produced by coating the phosphor body with a complex compound containing of indium sulfide and an alkali metal sulfide, followed by baking in an oxygen containing atmosphere at 400.degree. to 600.degree. C. so as to convert the complex compound into a red pigment consisting of indium sulfide and an alkali metal sulfate.Type: GrantFiled: November 16, 1978Date of Patent: June 24, 1980Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Takeshi Takahara, Susumu Matsuura, Toshio Nishimura, Nobuo Inoue
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Patent number: 4206250Abstract: A pigment-coated phosphor having good finish sieve passability and capable of forming a fluorescent film with excellent properties can be produced from a process characterized by:(1) the first step of adding to a water suspension of a phosphor and a pigment an anionic polymer emulsion which has a minimum film forming temperature of less than 30.degree. C.;(2) the second step of adding a cationic polymer emulsion which has a minimum film forming temperature of 30.degree. C. or lower;(3) the thrid step of adding an anionic polymer emulsion which has a minimum film forming temperature of 30.degree. C. or higher; and(4) the fourth step of making the mixture system neutral or weakly acidic.Type: GrantFiled: October 26, 1978Date of Patent: June 3, 1980Assignees: Hitachi, Ltd., Kasei Optonix, Ltd.Inventors: Yoichi Oba, Katuzo Kanda, Shusaku Eguchi, Kazuhito Iwasaki
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Patent number: 4192691Abstract: Unsupported metal oxide platey nacreous pigments are derived from metal oxide coated mica by a unique dissolution process and show higher luster and coverage than the pigment from which they are derived. If the metal oxide coated mica shows a reflection interference color, the unsupported product derived from it shows higher luster and greater reflection color intensity.Type: GrantFiled: October 26, 1978Date of Patent: March 11, 1980Assignee: The Mearl CorporationInventor: Louis Armanini
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Patent number: 4176078Abstract: A method of coating pigment particles such as magnetite with a fatty acid chrome complex is disclosed. The magnetite pigments coated by this process are found to be particularly suitable for use in formation of field dependent toners.Type: GrantFiled: June 2, 1977Date of Patent: November 27, 1979Assignee: Xerox CorporationInventor: Chin H. Lu
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Patent number: 4175160Abstract: The disposition of an array of color phosphor dots on a color cathode ray tube faceplate by conventional photo deposition techniques is facilitated by first coating the individual phosphor particles with polyvinyl alcohol modified with an amino acid such as glutamic or aspartic acid.Type: GrantFiled: June 22, 1978Date of Patent: November 20, 1979Assignee: GTE Sylvania IncorporatedInventor: Clarence D. Vanderpool
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Patent number: 4162348Abstract: A method for coloring inorganic substrates such as glass beads, glass fibers, mineral wool, rock wool, mineral fiber boards and cloths, concrete molded materials, inorganic pigments and metallic powders, which comprises treating the inorganic substrate with (1) a cationic component comprising(a) a water soluble cationic resin or an aqueous solution of a water soluble cationic resin,(b) an aqueous solution of a water soluble cationic resin and a water soluble cationic dye, or(c) an aqueous dispersion of a water soluble cationic resin, a cationic dispersing agent plus a water insoluble dye or pigment and, optionally, a cationic water soluble dye; andWith (2) an anionic component comprising(d) an aqueous solution of a water soluble anionic dye,(e) an anionic dispersing agent or an aqueous solution of an anionic dispersing agent,(f) an aqueous solution of an anionic dispersing agent and a water soluble anionic dye, or(g) an aqueous dispersion of an anionic dispersing agent plus a water insoluble dye or pigment anType: GrantFiled: January 28, 1976Date of Patent: July 24, 1979Assignee: Sumitomo Chemical Company, LimitedInventors: Shigeru Juzu, Hiroyuki Okazaki, Yasuyuki Suzuki
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Patent number: 4152483Abstract: On the surface of a phosphor, pigment particles are uniformly adhered by a layer of a gelatin-gum arabic mixture. A process for manufacturing such a pigment coated phosphor includes the steps of preparing an aqueous solution of gelatin and an aqueous solution of gum arabic, allowing the phosphor to disperse homogeneously into one of these aqueous solutions, allowing the pigment particles to disperse homogeneously into the other aqueous solution, and mixing the so obtained phosphor and pigment dispersions.Type: GrantFiled: November 18, 1977Date of Patent: May 1, 1979Assignee: Dai Nippon Toryo Co., Ltd.Inventors: Katuzo Kanda, Noboru Kotera, Seiji Murakami, Thihiro Yoshida, Shusaku Eguchi, Toshiaki Hatsumi, Kazuhito Iwasaki, Isao Iwamoto
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Patent number: 4148741Abstract: A method of toner formation utilizing bead polymerization to produce colored particles which may be directly attrited to toner.Type: GrantFiled: August 2, 1976Date of Patent: April 10, 1979Assignee: Xerox CorporationInventor: Robert D. Bayley
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Patent number: 4146403Abstract: Iron oxide coated mica nacreous pigments are improved by interposing a thin layer of titanium dioxide or aluminum oxide between the iron oxide and the mica.Type: GrantFiled: April 27, 1978Date of Patent: March 27, 1979Assignee: The Mearl CorporationInventors: Louis Armanini, Frank Bagala
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Patent number: 4141751Abstract: A silane coupling agent of either ambi or monofunctional type, and/or an isopropyl titanate coupling agent of either ambi or monofunctional type; and/or, a glass resin thermoset silicone coupling agent of either ambi or monofunctional type which is refined siloxane chain/s with select OH groups in a carrier solution is and are sprayed or poured into hydrophilic particulate and/or fibrous, crystalline and/or amorphous inorganic substances or compounds in a high intensity mixing apparatus between about 70.degree. F. and 350.degree. F. and a silane coupling agent of either ambi or monofunctional; and/or an isopropyl titanate coupling agent of either ambi or monofunctional type; and/or, a glass resin thermoset silicone coupling agent of either ambi or monofunctional type which is refined siloxane chain/s with select OH groups in a carrier solution and hydrophilic particulate and/or fibrous, crystalline and/or amorphous inorganic substances are allowed to remain in situ at a temperature between 70.degree. F.Type: GrantFiled: April 13, 1977Date of Patent: February 27, 1979Assignee: Malvern Minerals CompanyInventor: James E. Moreland
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Patent number: 4133774Abstract: Novel pressure fixable direct imaging magnetic toners having a core of magnetic material held together with an adhesive resin, a barrier substantially covering the core, an overcoat of thermoplastic strengthening resin, and an outer conductive layer, together with novel processes for producing such toners, these processes comprising dispersion of the core material followed by agglomeration of the several layers in a single aqueous medium.Type: GrantFiled: September 29, 1977Date of Patent: January 9, 1979Assignee: Reprographic Materials, Inc.Inventors: Carl Brynko, Carl G. Brynko
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Patent number: 4128674Abstract: A pigmented phosphor comprises a core of a phosphor particle having a light modifying layer thereon. The light modifying layer is comprised of a co-precipitated mixture of silica or pyrophosphate and a pigment which modifies the light output of the energized phosphor. The phosphor is coated by first preparing an unique pigment stock suspension containing the pigment, water, and a polyacrylamide dispersant. The stock solution is then diluted and phosphor particles are added thereto and the mixture is vigorously stirred. The pH of the mixture can be adjusted to about 5 by the addition of acetic acid and then a small amount of positively charged colloidal silica or pyrophosphate is added. After mixing, the pH is raised to about 9 by the addition of a base or a salt which causes a gel to form and the silica or pyrophosphate and the pigment to co-precipitate out upon the phosphor particles.Type: GrantFiled: March 31, 1976Date of Patent: December 5, 1978Assignee: GTE Sylvania IncorporatedInventor: Robert A. Hedler
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Patent number: 4098714Abstract: Disclosed is a process for preparing a water softening composition which comprises the steps of:(a) applying to finely divided solid carrier particles of an inorganic material selected, e.g., from the group consisting of aluminosilicates having an Al.sub.2 O.sub.3 content of from 1 to 75% by mole, kieselguhr, a silicic acid composition containing 67 mole % of SiO.sub.2, 1 mole % of Al.sub.2 O.sub.3 and 278 mole % of H.sub.2 O, a silica gel containing 12.24% of SiO.sub.2, 7.35% of N.sub.2 SO.sub.4, 0.41% of Na.sub.2 O and 80% of H.sub.2 O, aluminum oxide, alumina hydrate, bentonite and sodium sulfate, a solution of sodium aluminate having a concentration of from about 0.2% to 25% by weight and a molar ratio Na.sub.2 O/Al.sub.2 O.sub.3 of from about 0.3 to 47, in an amount which is sufficient to coat the particles with an outside layer of sodium aluminate amounting from about 0.5 to about 50% by weight of the particles; and, (b) drying the coated particles at a temperature of from about 20.degree. to 120.Type: GrantFiled: June 18, 1976Date of Patent: July 4, 1978Assignee: Kali-Chemie AGInventors: Helmut Derleth, Maria Hansen, Ingeborg Lange, Artur Kurs
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Patent number: 4093777Abstract: A stabilized cadmium chalcogenide, in which optionally zinc and/or mercury is present in the lattice, carrying at least one coating of a sparingly-soluble sulfide is produced by adding at least one water-soluble salt of an element forming a sparingly-soluble sulfide to an aqueous chalcogenide suspension, mixing with a compound releasing sulfide ions and/or mixing the cadmium chalcogenide suspension with a soluble thio-compound of an element forming a sparingly-soluble sulfide thereby to precipitate a sparingly-soluble sulfide onto the chalcogenide, subsequently filtering, optionally washing, drying and annealing the aftertreated chalcogenide. Suitable sparingly-soluble sulfides are, for example, the sulfides of the elements Zn, Hg, In, Sn, Pb, As, Sb, Bi, V, Mo, W, Cu and Ag.Type: GrantFiled: October 6, 1975Date of Patent: June 6, 1978Assignee: Bayer AktiengesellschaftInventors: Heinrich Heine, Peter Woditsch, Theodor Bohmann, Dieter Rade
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Patent number: 4076551Abstract: A process for the preparation of carbon black-containing pigments consists essentially of precipitation of a carbon black-containing metal hydroxide or bismuth oxychloride layer on substrate particles in an aqueous suspension containing carbon black particles of particle size of below 1 mn. and washing, drying and optionally calcining the products. Flaky substrates, e.g., mica flakes coated with TiO.sub.2, are preferably employed. Carbon black-containing pigments obtained have carbon black particles incorporated in a metal hydroxide, metal oxide or bismuth oxychloride layer precipitated on the substrate in the presence of the carbon black.Type: GrantFiled: December 10, 1976Date of Patent: February 28, 1978Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: Horst Bernhard, Reiner Esselborn
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Patent number: 4049845Abstract: Method comprises adsorbing colloidal particles of a latex onto phosphor particles, providing filter particles in a liquid medium, optionally adsorbing colloidal particles of a latex onto the filter particles and combining the phosphor particles and filter particles into a single mixture. The foregoing steps, which are conducted in aqueous media, may be carried out in any order. Thereafter, the combined mixture of phosphor particles with adsorbed colloidal particles thereon and filter particles is coagulated while in an aqueous medium.Type: GrantFiled: March 8, 1976Date of Patent: September 20, 1977Assignee: RCA CorporationInventors: Gerald Scott Lozier, Phyllis Brown Branin
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Patent number: 4020231Abstract: A composite article comprises a core of a phosphor particle having a light modifying layer thereon. The light modifying layer is comprised of a co-precipitated mixture of a free-flowing agent such as silica or pyrophosphate and a pigment which modifies the light output of the energized phosphor. Also disclosed is a method of making the composite article which comprises the steps of preparing an aqueous mixture of particles of phosphor, particles of a pigment and a positively charged colloidal silica or pyrophosphate and mixing thoroughly. After mixing, a base, in the case of silica, or a salt which will form an insoluble pyrophosphate in the case of the pyrophosphate, is added thereto in sufficient amount to gel the mixture causing the silica or pyrophosphate and the pigment to co-precipitate upon and coat the phosphor particles. After the coating operation the supernatant liquid is removed and the coated phosphor is dried.Type: GrantFiled: March 31, 1976Date of Patent: April 26, 1977Assignee: GTE Sylvania IncorporatedInventors: Robert A. Hedler, W. Wentworth Slobbe
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Patent number: 3973055Abstract: The dielectric recording media comprise electroconductive substrates coated with dielectric resin binder. The process comprises dispersing an organophilic clay pigment in the dielectric resin binder and coating the electroconductive substrate with the dispersion. The organophilic clay pigment is obtained by treating calcined kaolin clay with an organotitanium compound.Type: GrantFiled: January 27, 1975Date of Patent: August 3, 1976Assignee: Monsanto CompanyInventors: Albert H. Markhart, David R. Cahill