Silicon Compound Containing Coating Patents (Class 427/219)
  • Patent number: 9957403
    Abstract: The present invention relates to a composition comprising a) a stable aqueous dispersion of inorganic pigment particles hydrophobically modified with covalently bonded polysiloxane or silyl groups; and b) a polymeric anionic dispersant; wherein the hydrophobically modified inorganic pigment particles have an average particle size in the range of from 200 nm to 10 ?m, and the solids content of the hydrophobically modified inorganic pigment particles is from 10 to 80 weight percent, based on the weight of inorganic pigment particles and water. The composition of the present invention provides a way to improve water resistance in coatings formulations.
    Type: Grant
    Filed: July 21, 2016
    Date of Patent: May 1, 2018
    Assignees: The Regents of the University of California, Dow Global Technologies LLC, Rohm and Haas Company
    Inventors: Joseph Jankolovits, Alexander Katz, James C. Bohling, Clayton J. Radke, Antony K. Van Dyk, John A. Roper, III
  • Publication number: 20150000565
    Abstract: Disclosed is a method of surface coating pigment particles, comprising treating uncoated titanium dioxide particles with a reaction product of a silicon oxide with an alkaline earth metal salt to form a coating comprising an oxide of silicon and the alkaline earth metal. The particles may also be treated with aluminum compounds to produce an aluminum oxide in the coating.
    Type: Application
    Filed: June 26, 2013
    Publication date: January 1, 2015
    Inventors: Joseph T. Valko, Michael Zalich, Peter Kamarchik
  • Patent number: 8920926
    Abstract: Algae-resistant roofing granules include a mineral core and an exterior coating including clay, colloidal silica, phosphate, a metal oxide, and a photocatalytic particulate having an average size under 100 nm. By varying the proportions of the components to the binder for the exterior coating, improved control of the pot life of the coating composition can be achieved, and the binder can be formulated to accommodate different manufacturing conditions.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: December 30, 2014
    Assignee: CertainTeed Corporation
    Inventors: Keith C. Hong, Ming Liang Shiao, Gregory F. Jacobs
  • Publication number: 20140371370
    Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerisable therewith to said dispersion; and polymerising vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.
    Type: Application
    Filed: December 18, 2012
    Publication date: December 18, 2014
    Inventors: Jérome Vinas, Pierre-Emmanuel Dufils, Jérome Garnier, Patrick Lacroix-Desmazes, Alex Van Herk, Jérome Warnant, Yves Vanderveken
  • Patent number: 8907006
    Abstract: Liquid silicone rubber base polymer compositions having improved color are prepared by reaction of fumed silica reinforcing filler with a silazane, and without drying the silazane-treated filler, an aliphatically unsaturated silicone is added, heated to above 80° C., and then further aliphatically unsaturated silicone is added. The compositions have improved whiteness and color reproducibility.
    Type: Grant
    Filed: July 10, 2013
    Date of Patent: December 9, 2014
    Assignee: Wacker Chemical Corporation
    Inventor: Helio Rincon
  • Patent number: 8883312
    Abstract: Zinc oxide particles having high transparency in visible light and high shielding properties in a ultraviolet region, with surface treatment of inactivating photocatalytic activity applied thereto, and a dispersion thereof. A manufacturing method of surface treated zinc oxide particles, including: a first step of mixing a dispersion liquid with zinc oxide particles dispersed in a solvent, and silicone resin having polysiloxane bond with at least one or more silicon atoms having a silanol group (Si—OH) and/or alkoxy silyl group (Si—OR, wherein R is alkyl group); obtaining a mixed solution containing a surface treated zinc oxide particles precursor, with the silicone resin adsorbed on the surface of each zinc oxide particle and the solvent, and drying and solidifying the mixed solution by applying heat treatment thereto, to thereby manufacture a dried body; and a second step of pulverizing the dried body, to thereby manufacture the surface treated zinc oxide particles.
    Type: Grant
    Filed: February 9, 2012
    Date of Patent: November 11, 2014
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Kayo Yabuki, Atsushi Tofuku
  • Patent number: 8859096
    Abstract: The invention relates to granular pumice, wherein the surface is covered with a hydrophobic coating.
    Type: Grant
    Filed: March 4, 2011
    Date of Patent: October 14, 2014
    Assignees: Evonik Degussa GmbH, ROTEC Rohstoff-Technik GmbH & Co. Kg
    Inventors: Markus Roos, Guido Runkel
  • Patent number: 8815339
    Abstract: Disclosed herein are a surface modifier for metal oxide particles and a method of modifying the surface of metal oxide particles using the same. The surface modifier consists either of an alkylsilanepolyol containing a cyclic alkyl group capable of imparting steric hindrance or of a mixture of said alkylsilanepolyol with alkylalkoxysilane, and the method of modifying the surface of metal oxide particles comprises coating the surface modifier on the hydrophilic surface of the metal oxide particles through chemical bonding so as to impart hydrophobicity or amphiphilicity (hydrophilicity and hydrophobicity) and reactivity to the surface of the metal oxide particles.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: August 26, 2014
    Assignee: Korea Institute of Science and Technology
    Inventors: Bok Ryul Yoo, Joon Soo Han, Weon Cheol Lim, Yong Su Jung
  • Patent number: 8808447
    Abstract: The present invention relates to a pigment paint for an exterior material and to a method for manufacturing the same. The pigment paint comprises: a flake matrix, a first metal oxide layer coated on the upper portion of the transparent matrix, an oxide layer containing MgO—SiO2 coated on the upper portion of the first metal oxide layer, and a second metal oxide layer coated on the upper portion of the oxide layer. In order to ensure humidity resistance and weather resistance required for a lustrous pigment paint for exterior materials, a cerium layer and an aluminum oxide layer are further coated. Properties such as high luminance, high chromaticity, and high gloss, which could not be achieved using conventional techniques, can be achieved and a pigment paint having a multi-colored pearl luster can be provided.
    Type: Grant
    Filed: March 8, 2012
    Date of Patent: August 19, 2014
    Assignee: CQV Co., Ltd.
    Inventors: Jae-Il Jeong, Nam-Il Lee, Sang-Keun Park, Jin-Hyung Lee, Kwang-Choong Kang, Byung-Ki Choi, Kwang-Soo Lim, Kil-Wan Chang
  • Patent number: 8728573
    Abstract: Particulate mineral materials comprising at least one coating comprising at least one metal compound are disclosed. In one embodiment, the at least one metal compound is a metal silicate compound. In another embodiment, the at least one metal compound is a metal oxide compound. In one embodiment, the particulate mineral material is perlite. In another embodiment, the particulate mineral material is perlite microspheres. In a further embodiment, the particulate mineral material is diatomite. Methods of making particulate mineral materials coated with at least one metal compound are also disclosed. In one embodiment, the at least one metal compound may be injected into a perlite expander to form a metal compound coated perlite material. In another embodiment, the at least one metal compound may be applied through a low temperature coating process to the at least one particulate mineral material. Uses for metal compound coated particulate mineral materials are also disclosed.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: May 20, 2014
    Assignee: Imerys Filtration Minerals, Inc.
    Inventors: Bo Wang, Michael Greene
  • Patent number: 8703017
    Abstract: A method of modifying a phosphor and a phosphor composition and a manufacturing method of the same and a phosphor solution are provided. The phosphor composition includes a silicone resin and a modified phosphor. The modified phosphor includes a phosphor and a nano-silica particle. The nano-silica particle is adhered to the phosphor. A weight ratio of the modified phosphor to the silicone resin is substantially between 1:0.005 and 1:0.1.
    Type: Grant
    Filed: December 27, 2011
    Date of Patent: April 22, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Kuo-Tung Huang, Yu-Ying Hsu, Bee-Yu Wei
  • Patent number: 8637116
    Abstract: A coating composition including an inorganic sol material and an organic colorant is applied to mineral particles and cured at a temperature less than 200 degrees Celsius provides roofing granules with improved luster.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: January 28, 2014
    Assignee: CertainTeed Corporation
    Inventors: Ming Liang Shiao, Van Nhan Nguyen, Emmanuel Garre
  • Patent number: 8629076
    Abstract: A metal oxide-carbon composite includes a carbon aerogel with an oxide overcoat. The metal oxide-carbon composite is made by providing a carbon aerogel, immersing the carbon aerogel in a metal oxide sol under a vacuum, raising the carbon aerogel with the metal oxide sol to atmospheric pressure, curing the carbon aerogel with the metal oxide sol at room temperature, and drying the carbon aerogel with the metal oxide sol to produce the metal oxide-carbon composite. The step of providing a carbon aerogel can provide an activated carbon aerogel or provide a carbon aerogel with carbon nanotubes that make the carbon aerogel mechanically robust. Carbon aerogels can be coated with sol-gel silica and the silica can be converted to silicon carbide, improving the thermal stability of the carbon aerogel.
    Type: Grant
    Filed: March 18, 2011
    Date of Patent: January 14, 2014
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Marcus A. Worsley, Joshua D. Kuntz, Theodore F. Baumann, Joe H. Satcher, Jr.
  • Patent number: 8591990
    Abstract: An arrangement of elongated nanowires that include titanium silicide or tungsten silicide may be grown on the exterior surfaces of many individual electrically conductive microfibers of much larger diameter. Each of the nanowires is structurally defined by an elongated, centralized titanium silicide or tungsten silicide nanocore that terminates in a distally spaced gold particle and which is co-axially surrounded by a removable amorphous nanoshell. A gold-directed catalytic growth mechanism initiated during a low pressure chemical vapor deposition process is used to grow the nanowires uniformly along the entire length and circumference of the electrically conductive microfibers where growth is intended. The titanium silicide- or tungsten silicide-based nanowires can be used in a variety electrical, electrochemical, and semiconductor applications.
    Type: Grant
    Filed: March 25, 2011
    Date of Patent: November 26, 2013
    Assignees: GM Global Technology Operations LLC, The University of Western Ontario
    Inventors: Mei Cai, Xueliang Sun, Yong Zhang, Mohammad Norouzi Banis, Ruying Li
  • Patent number: 8507033
    Abstract: Surface-modified, pyrogenically prepared silica is prepared by subjecting the pyrogenically prepared silica, which is in the form of aggregates of primary particles and possesses a BET surface area of 150±15 m2/g, the aggregates having an average area of 12 000-20 000 nm2, an average equivalent circle diameter (ECD) of 90-120 nm and an average circumference of 1150-1700 nm, to surface-modification in a known way. It can be used as a filler for thickening liquid systems.
    Type: Grant
    Filed: July 1, 2008
    Date of Patent: August 13, 2013
    Assignee: Evonik Degussa GmbH
    Inventors: Juergen Meyer, Mario Scholz, Kai Schumacher
  • Patent number: 8481115
    Abstract: A method for producing coated, fine metal particles each having a Ti oxide coating and a silicon oxide coating formed in this order on a metal core particle by mixing powder comprising TiC and TiN with oxide powder of a metal M meeting the relation of ?GM-O>?GTiO2, wherein ?GM-O represents the standard free energy of forming an oxide of the metal M; heat-treating the resultant mixed powder in a non-oxidizing atmosphere to reduce the oxide of the metal M with the powder comprising TiC and TiN, while coating the resultant metal M particles with Ti oxide; coating the Ti-oxide-coated surface with silicon oxide; and classifying the resultant particles such that they have a median diameter d50 of 0.4-0.7 ?m, and a variation coefficient (=standard deviation/average particle size) of 35% or less, which indicates a particle size distribution range.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: July 9, 2013
    Assignee: Hitachi Metals, Ltd.
    Inventors: Hisato Tokoro, Takashi Nakabayashi, Shigeo Fujii
  • Publication number: 20130164444
    Abstract: A surface-modified titania particle manufacturing method is a method for manufacturing surface-modified titania particles having crystal particles of titanium dioxide and a surface modifier that coats a surface of the crystal particles, including: [1] a first step of preparing a starting solution containing a titanalkoxide compound, an alkoxysilane, an alcohol, an acid, and water; and [2] a second step of performing heating treatment on the starting solution. Furthermore, this method preferably further includes, after the second step, [3] a third step of removing a liquid phase component in the starting solution through evaporation, by reducing a pressure around the starting solution.
    Type: Application
    Filed: July 22, 2011
    Publication date: June 27, 2013
    Applicant: HOYA CORPORATION
    Inventors: Shuzo Tokumitsu, Masako Kawakami
  • Patent number: 8465798
    Abstract: Disclosed is a method for manufacturing a fluorescent material. The method includes: putting the fluorescent material into a first solution, and agitating the fluorescent material and the first solution; putting a nano fluorescent material having a nano size into the first solution, and agitating the nano fluorescent material having a nano size and the first solution; and separating supernatant from the first solution including the fluorescent material, and drying the fluorescent material. Disclosed is a light emitting device. The light emitting device includes: a body; a light emitting element mounted on a cavity formed in the body; a resin formed in the cavity; and a fluorescent material added to the resin, wherein a nano fluorescent material having a nano size is adsorbed in the fluorescent material.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: June 18, 2013
    Assignee: LG Innotek Co., Ltd.
    Inventors: Yun Soo Song, Sang Hyuk Lee
  • Patent number: 8394498
    Abstract: Roofing granules include a core having an average ultraviolet transmission of greater than sixty percent and an average near infrared reflectance of greater than sixty percent and a UV coating layer on the exterior surface. The coating provides UV opacity, while the core provides near infrared reflectance.
    Type: Grant
    Filed: December 16, 2008
    Date of Patent: March 12, 2013
    Assignee: CertainTeed Corporation
    Inventors: Ming Liang Shiao, Jennifer A. Sharp, Gregory F. Jacobs
  • Patent number: 8383238
    Abstract: Fine particles of a highly porous, low density material in which the pore chambers have been at least partially evacuated and refilled with a gas having a low thermal conductivity, and the obtained particles are encapsulated with a protective, durable coating. The particles are particularly useful as durable thermal insulating material.
    Type: Grant
    Filed: March 22, 2006
    Date of Patent: February 26, 2013
    Inventor: G. Stuart Burchill, Jr.
  • Patent number: 8282991
    Abstract: Hydrophobized silicon oxide-coated metal oxide particles excellent in dispersibility in fluororesins, durability to fluorinated compounds and ultraviolet-shielding properties, and a fluororesin film excellent in transparency, weather resistance and ultraviolet-shielding properties comprising the hydrophobized silicon oxide-coated metal oxide particles, the hydrophobized silicon oxide-coated metal oxide particles being obtained by a process including a primary and a secondary hydrophobizing treatment.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: October 9, 2012
    Assignee: Asahi Glass Company, Limited
    Inventor: Hajime Katayama
  • Patent number: 8268069
    Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: August 10, 2005
    Date of Patent: September 18, 2012
    Assignee: Merck Patent GmbH
    Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
  • Patent number: 8187705
    Abstract: Manganese vanadium tantalum oxide that can be represented by the formula MnxVyTazOw, where 1?x?3, 0.001?y?3, 0.001?z?2, and w=7, and alternately, x=1.25?x?2.45, 0.1?y?2.39, 0.2?z?1.9, and w=7, methods of producing MnxVyTazOw, a pigment coated with MnxVyTazOw and a chalcogenide glass layer, and a method of producing the coated pigment are described. The disclosed manganese vanadium tantalum oxide has superior near-infrared reflective properties. The disclosed methods of producing the manganese vanadium tantalum oxide provide products with superior phase purity, appearance and performance and take health and safety into consideration. The construction of the disclosed coated pigment combines the reflective properties of the substrate with the near-infrared reflective properties of MnxVyTazOw, while the chalcogenide glass layer provides aesthetic appeal. The disclosed method of producing the coated pigment involves physical vapor deposition of MnxVyTazOw and the chalcogenide glass layer.
    Type: Grant
    Filed: July 15, 2010
    Date of Patent: May 29, 2012
    Assignee: Silberline Manufacturing Company, Inc.
    Inventors: Stewart Warrender, Hai Hui Lin, Parfait Jean Marie Likibi, Rajasekar Pitchimani, Devidas Balu Raskar, David Aldous
  • Patent number: 8114211
    Abstract: The present invention relates to pearlescent pigments based on flake-form substrates which have at least one FeOOH layer and at least one TiO2 layer or at least one TiO2/SiO2/TiO2 layer package, and to the use thereof, inter alia, in paints, coatings, printing inks, powder coatings, plastics and in particular in care and decorative cosmetics.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: February 14, 2012
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Carsten Handrosch, Marcus Mathias, Nicole Schupp, Meike Willius
  • Patent number: 8039048
    Abstract: A process for forming algae-resistant roofing shingles comprises producing algae-resistant granules, and adhering the granules to a shingle stock material. The algae-resistant roofing granules are produced by a process that includes coating mineral particles with a clay-silicate binder including a metal oxide algaecide and small organic particles. The particles are heated to cure the binder, and the organic particles pyrolyse to form pores in the coating. The release of the algaecide is controlled by the structure of the granules.
    Type: Grant
    Filed: November 2, 2009
    Date of Patent: October 18, 2011
    Assignee: CertainTeed Corporation
    Inventors: Keith C. Hong, Husnu M. Kalkanoglu, Ming Liang Shiao
  • Patent number: 8029899
    Abstract: The invention relates to coated particles comprising particles and a crosslinked polysiloxane coating and to a process for the manufacture of said coated particles. Further, the invention relates to the use of the coated particles to improve surface properties of articles and to material compositions comprising the coated particles, in particular coating compositions. According to the invention there is provided coated particles comprising particles having a surface with hydroxy functional groups and a crosslinked polysiloxane coating comprising a reaction product of polysiloxane disilanol according to formula I: wherein n is 1 to 25, and wherein each R is a same or different hydrocarbon group, and a coating crosslinking agent, preferably an alkoxysiloxane having 3 or 4 alkoxy groups which polysiloxane coating is at least partly grafted to the particle surface by reaction with the hydroxy functional groups on the particles.
    Type: Grant
    Filed: April 25, 2006
    Date of Patent: October 4, 2011
    Assignee: Nuplex Resins B.V.
    Inventors: Cornelis Adrianus Maria Vijverberg, Jan Andre Jozef Schutyser
  • Patent number: 7951420
    Abstract: A method of preparing a pigment exhibiting a color-shifting effect, including at least heating mica powder suspension in water, adjusting the pH value of the mixture to between 2 and 9, adding a first inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 6 and 14, adding a second inorganic salt solution, maintaining the pH value of the mixture constant, stirring the mixture at constant temperature, adjusting the pH value of the mixture to between 2 and 9, adding a third inorganic salt solution, maintaining the pH value of the mixture constant, and stirring the mixture at constant temperature.
    Type: Grant
    Filed: September 26, 2009
    Date of Patent: May 31, 2011
    Inventors: Jiansheng Fu, Yiting Peng, Xiaohui Tian
  • Patent number: 7943084
    Abstract: The present invention demonstrates a superior, more economical, and scalable process to increase the fluidity of metal powders by surface modification with alkylsilane reagents. This invention discloses that the most efficient process results from treatment with methyltrichlorosilane in hexane. In particular, the fluidity of aluminum powders having mean diameters smaller than 10 micrometers was considerably improved by the process of the present invention. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope of the claims.
    Type: Grant
    Filed: May 23, 2007
    Date of Patent: May 17, 2011
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Curtis E. Johnson, Kelvin T. Higa, Roger M. Sullivan
  • Patent number: 7863215
    Abstract: Disclosed is a photocatalyst comprising a photocatalytically active base, and a silicon oxide film covering the base and substantially having no pores. The alkali metal content of the photocatalyst is not less than 1 ppm but not more than 1,000 ppm. Also disclosed is a method for producing such a photocatalyst wherein when a photocatalytically active base present in an aqueous medium is coated with a silicon oxide film by using a silicate, the pH of the aqueous medium containing both the photocatalytically active base and the silicate is maintained at 5 or below.
    Type: Grant
    Filed: February 14, 2006
    Date of Patent: January 4, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Satoru Miyazoe, Takashi Nabeta, Nobuhiko Horiuchi
  • Publication number: 20100326322
    Abstract: Titanium dioxide particles are coated first with an interstitial coating and then with silicon dioxide or alumina. The coatings are suitably applied via an atomic layer deposition process. The interstitial coating preserves the bright white coloration of the particles after they are coated. The particles therefore can be used as pigments and white fillers in polymers, paints, paper and other applications.
    Type: Application
    Filed: March 6, 2009
    Publication date: December 30, 2010
    Inventors: David M. King, Alan W. Weimer
  • Patent number: 7824643
    Abstract: Stable, aqueous dispersion containing silicon dioxide powder having a hydroxyl group density of 2.5 to 4.7 OH/nm2, which is obtained from a silicon dioxide powder produced by a flame hydrolysis process under acid conditions. The dispersion is produced by incorporating the silicon dioxide powder into an aqueous solution by means of a dispersing device. The dispersion can be used to produce glass articles.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: November 2, 2010
    Assignee: Evonik Degussa GmbH
    Inventors: Kai Schumacher, Monika Oswald
  • Patent number: 7811630
    Abstract: Algae-resistant roofing granules are formed by extruding a mixture of mineral particles and a binder to form porous granule bodies, and algaecide is distributed in the pores. Release of the algaecide is controlled by the structure of the granules.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: October 12, 2010
    Assignee: CertainTeed Corporation
    Inventors: Keith C. Hong, Husnu M. Kalkanoglu, Ming L. Shiao, Anne B. Hardy, James A. Salvatore, Andrew G. Johnson, Jr.
  • Publication number: 20100104857
    Abstract: Roofing granules, methods for their preparation, having a Total Solar Reflectance of at least 25% on a substrate or carrier.
    Type: Application
    Filed: January 4, 2010
    Publication date: April 29, 2010
    Inventor: Ingo B. Joedicke
  • Patent number: 7704600
    Abstract: The invention relates to grout powder for admixture with water to produce grout. The grout powder comprises cement powder and is characterized in that the grout powder has been mixed with a fluorochemical compound. The present invention further relates to a method of preparing grout powder for admixture with water to produce grout, comprising mixing grout powder comprising cement powder with a fluorochemical compound. Still further, the invention relates to an alternative method for making the grout powder, which method comprises treating at least one of the components of the grout powder with a fluorochemical compound.
    Type: Grant
    Filed: May 16, 2002
    Date of Patent: April 27, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Rudolf J. Dams, Volker Rinke
  • Patent number: 7704604
    Abstract: The invention relates to a method for forming a silicate coating on particles and to the particles thus obtained, characterized in that a solution containing silicate is added to a dispersion of uncoated particles having a diameter of less than 50 ?m and acoustic excitation occurs.
    Type: Grant
    Filed: September 12, 2005
    Date of Patent: April 27, 2010
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Rüdiger Nass, Detlef Burgard, Christian Schnadinger
  • Patent number: 7691196
    Abstract: Disclosed are yellowing-stable, silver-white effect pigments having high whiteness based on synthetic mica flakes and to the use thereof in paints, lacquers, printing inks, plastics, button pastes, ceramic materials, glasses, for coloring seed, as dopant in laser markings of plastics and papers, as additive for laser welding of plastics, as additive for coloring in the foods and pharmaceuticals sectors and in cosmetic formulations, and for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: June 7, 2007
    Date of Patent: April 6, 2010
    Assignee: Merck Patent GmbH
    Inventors: Gerhard Pfaff, Johann Dietz, Sabine Schoen, Doreen Warthe
  • Patent number: 7687106
    Abstract: Algae-resistant roofing granules are formed by coating mineral particles with a clay-silicate binder including a metal oxide algaecide and small organic particles. When the particles are heated to cure the binder, the organic particles pyrolyse to form pores in the coating. Release of the algaecide is controlled by the structure of the granules.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: March 30, 2010
    Assignee: CertainTeed Corporation
    Inventors: Keith C. Hong, Husnu M. Kalkanoglu, Ming L. Shiao
  • Patent number: 7658863
    Abstract: A Si—C—O composite powder is obtained by curing a reactive silane or siloxane having crosslinkable groups through heat curing or catalytic reaction into a crosslinked product and sintering the crosslinked product in an inert gas stream at a temperature of 700-1,400° C. into an inorganic state. It exhibits satisfactory cycle performance when used as the negative electrode material for non-aqueous electrolyte secondary cells.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: February 9, 2010
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Mikio Aramata, Satoru Miyawaki, Hirofumi Fukuoka
  • Patent number: 7629023
    Abstract: A rust inhibitor which ensures the simplicity of application typical for a coating process and can demonstrate excellent characteristics similar to those obtained with a metal spraying method. The rust inhibitor is manufactured by admixing zinc and aluminum as fine powders of inorganic metals, which are manufactured with a stamping mill to have a flaky shape, to a modified silicone resin solution. A silane-type silicone resin is used for the modified silicone resin solution. For example, a mixed solution of an organosilane-type silicone resin and an oligomer-type silane coupling agent and the like is used.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: December 8, 2009
    Assignee: Primet Technology Inc.
    Inventors: Yuko Kurimoto, Kazuo Kobayashi
  • Patent number: 7611750
    Abstract: A nanocomposite material and a method of manufacturing the same are disclosed. The nanocomposite material includes a plurality of nanoparticles coated with a metal oxide, and a matrix of the metal oxide immobilizing the nanoparticles that are dispersed therein. The nanocomposite material is manufactured such that macro- or macro-scale cracks are prevented or effectively prevented, light stability is enhanced over a light-emitting period, and light brightness is improved.
    Type: Grant
    Filed: December 4, 2006
    Date of Patent: November 3, 2009
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Dong-kee Yi, Byung-ki Kim, Jae-ho Lee, Eun-joo Jang, Seong-jae Choi
  • Patent number: 7579391
    Abstract: The invention provides titanium dioxide pigments for plastics resin compositions which are excellent in dispersibility, light resistance, and weather resistance and little cause surface imperfection. In particular, the invention provides a titanium dioxide pigment suitable for general-purpose plastics resin compositions which can attain excellent dispersion and lacing resistance even when blended in a high concentration; a titanium dioxide pigment suitable for engineering plastics resin compositions which can attain dispersion properties, silver streaking resistance, inhibition of reduction in molecular weight, and thermal discoloration resistance at high levels; a process for the production of the pigments; and resin compositions containing the pigments. A titanium dioxide pigment for plastics resin compositions, characterized in that each titanium dioxide particle has a dense hydrous silica coat covering its surface and an organic compound coat formed on the silica coat not through an interlayer.
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: August 25, 2009
    Assignee: Ishihara Sangyo Kaisha, Ltd.
    Inventors: Hideo Takahashi, Masaki Shimojoh, Toshihiko Akamatsu, Keisuke Iriyama
  • Patent number: 7575780
    Abstract: A bone-growth stimulating composition for forming a resorbable implant, methods for making such a composition and a corresponding putty/paste material. In some embodiments of the invention, such a material includes a plurality of particles having a predetermined size and comprising a first calcium sulfate compound and a resorbable polymer in a predetermined weight ratio. Methods for making such a material include rotating calcium sulfate powder in a drum at a first predetermined drum speed, spraying of a resorbable polymer solution at a predetermined rate on the calcium sulfate powder over a predetermined period of time and drying the resulting particles. Such compositions allow resorption rates of the implant composition in vivo to be controlled, and my vary between eight and twenty-four weeks (for example), which can be matched to substantially correspond to a rate of bone growth in a particular application.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: August 18, 2009
    Assignee: Orthogen LLC
    Inventors: Harold Alexander, John L. Ricci, Sachin Mamidwar
  • Patent number: 7534489
    Abstract: Composites and methods associated with the same are provided. The composite structures are formed of quantum dots and magnetic nanoparticles. The structures may be coated, for example, with a non-organic shell such as silica. In some cases, the shell may be functionalized or derivatized to include compounds, atoms, or materials that can alter or improve properties such as water solubility, water stability, photo-stability and biocompatibility. A reverse microemulsion process can be used to form the coated composites. The composition and other characteristics of the composites may be controlled to provide desired magnetic and optical properties. The structures may be used in a variety of applications including biological labeling, magnetic resonance imagine (MRI) and drug targeting, amongst others.
    Type: Grant
    Filed: September 24, 2004
    Date of Patent: May 19, 2009
    Assignee: Agency for Science, Technology and Research
    Inventors: Jackie Y. Ying, Subramanian T. Selvan, Dong Kee Yi, Su Seong Lee
  • Patent number: 7485367
    Abstract: The invention provides CaCO3/SiO2.nH2O nanocomposite particles and method of producing the same. A template nucleus is used calcium carbonate and the surface of nucleus is encapsulated by a SiO2.nH2O nanolayer. The invention also provides a CaCO3/SiO2.nH2O nanocomposite particles having hollow structure, in which n=0-2. The nanocomposite particles according to the invention have a number of uses.
    Type: Grant
    Filed: September 20, 2004
    Date of Patent: February 3, 2009
    Assignees: Beijing University of Chemical Technology, Nanomaterials Technology PTE Ltd.
    Inventors: Jianfeng Chen, Runjing Liu, Yun Jimmy, Zhigang Shen, Haikui Zou, Fen Guo
  • Patent number: 7393586
    Abstract: A highly oxidation-resistant copper powder for conductive paste, which is a copper powder containing not more than 5 wt % of Si, is characterized in that substantially all of the Si is adhered to the surfaces of the copper particles as SiO2-system gel coating film.
    Type: Grant
    Filed: April 22, 2002
    Date of Patent: July 1, 2008
    Assignee: Dowa Electronics Materials Co., Ltd.
    Inventors: Yoshihiro Okada, Atsushi Ebara
  • Patent number: 7288241
    Abstract: A black composite oxide particle includes a composite oxide having Fe, Mg and Al as metal components. The particle contains Fe, Mg and Al in amounts of 30 to 55 mass %, 1 to 10 mass %, and 1 to 10 mass %, respectively, and has an atomic ratio of Fe3+/Fe2+ of 0.8 to 10. Also described is a method for producing the black composite oxide particle. In an embodiment, the particle includes a hydrated composite oxide represented by an empirical formula: Fe2+aFe3+bMgcAldOe·nH2O. The black composite oxide particle is suitable as a black pigment for a coating material, an ink, toner particles, a rubber and a plastic, and is reduced with respect to the load on the environment and excellent in blackness.
    Type: Grant
    Filed: December 12, 2002
    Date of Patent: October 30, 2007
    Assignee: Mitsui Mining and Smelting Co., Ltd.
    Inventors: Koji Aga, Hiroyuki Shimamura
  • Patent number: 7264672
    Abstract: A process for producing an improved titanium dioxide pigment composite is provided, as are particles produced thereby. The process comprises producing a slurry comprising titanium dioxide particles, leaching alumina from the surface of the titanium dioxide particles in the presence of a soluble phosphate and precipitating aluminum phosphate from the slurry onto the surface of the titanium dioxide particles thereby forming a uniform coating of aluminum phosphate on the surfaces of the titanium dioxide particles. An anionic poly-electrolyte can be added to the resulting slurry. The slurry can then be treated such that the anionic poly-electrolyte forms an additional coating on the aluminum phosphate-coated titanium dioxide particles.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: September 4, 2007
    Assignee: National Titanium Dioxide Co. Ltd. (Cristal)
    Inventors: Fadi Mohammed Saeed Trabzuni, Chathangat Cheroolil Gopalkrishnan
  • Patent number: 7261939
    Abstract: A tablet comprising a core which is at least partially coated with an outer layer obtained by electrostatic deposition of a powder and subsequent fusing of the deposited powder to form a film characterised in that a surface of the tablet coated with said outer layer is contoured to provide higher regions and lower regions, the outer layer having a different colour in said lower regions to the outer layer in said higher regions.
    Type: Grant
    Filed: May 2, 2002
    Date of Patent: August 28, 2007
    Assignee: Phoqus Limited
    Inventors: Martin D. Hallett, Linda A. Reeves, Marshall Whiteman
  • Patent number: 7255735
    Abstract: Pyrogenically prepared surface-modified silicon dioxide-titanium dioxide mixed oxides are prepared by spraying pyrogenically prepared silicon dioxide-titanium dioxide mixed oxides with a surface-modifying agent. The surface-modified pyrogenically prepared silicon dioxide-titanium dioxide mixed oxides can be used in sun protection formulation.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: August 14, 2007
    Assignee: Degussa AG
    Inventors: Jürgen Meyer, Kai Schumacher, Steffen Hasenzahl, Heike Riedemann, Ann Gray
  • Publication number: 20070175363
    Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminium phosphate, aluminium oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminium and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Applicant: Kronos International Inc.
    Inventors: Siegfried Blumel, Lydia Drews-Nicolai, Volker Jurgens, Volker Schmitt