Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.

Abstract: In hexaboride particles having particles of a hexaboride of at least one element (X) selected from Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Sr and Ca, or a dispersion of such particles, the surfaces of the hexaboride particles have physically been coated with a surface treatment agent containing silicon, selected from a silazane type treatment agent, a chlorosilane type treatment agent, an inorganic treatment agent having at least one alkoxyl group in the molecular structure, and an organic treatment agent having at least one alkoxyl group at a molecular terminal or in the side chain, or have been coated with the surface treatment agent, having chemically combined with hexaboride particles on the surfaces of the hexaboride particles.

Abstract: A powder containing particles with a core of titanium dioxide and a coating of silicon dioxide in an amount of between 0.5 and 40 wt. %, the particles have a BET surface of between 5 and 300 m2/g, and the particles are primary particles that have a coating of silicon dioxide and a core of titanium dioxide.

Abstract: Hydrophobic inorganic fine particles characterized by being a mixture of at least small-particle-diameter inorganic fine particles having an average primary particle diameter of 5 to 25 nm and having a maximum peak particle diameter of 20 nm or less and large-particle-diameter inorganic fine particles having an average primary particle diameter which is 1.5 to 100 times the average primary particle diameter of the small-particle-diameter inorganic fine particles; the mixture being a mixture having been treated in the same treating tank to subject both the small-particle-diameter inorganic fine particles and large-particle-diameter inorganic fine particles simultaneously to hydrophobic treatment.

Abstract: A process for producing a vacuum ultraviolet ray-excited light-emitting phosphor comprising the steps of mixing a phosphor with a aluminum-based coupling agent, and calcining the mixture.

Abstract: The invention relates to a construction-material body or coating, containing a hydraulic agglutinant, aggregate material and glass granulate as the principal components. The surface of said glass granulate is coated with a protective layer, which contains at least one organic silicon compound and/or at least one duroplastic.

Abstract: The invention relates to a method for the post-treatment of titanium dioxide, in order to produce particularly weather-resistant titanium dioxide pigments with good optical properties. The method is characterized in that, together with the hydrous oxides of tin and zirconium, at least one other from the group comprising aluminium, silicon and titanium is additionally precipitated onto the particle surface. The post-treatment components are added to the aqueous TiO2 suspension either in the acidic range (pH value of 3 at most) or in the alkaline range (pH value of 10 at least). The pH value is subsequently set to between 6 and 8. Final tempering of the pigment at elevated temperatures from over 125° C. to up to 500° C. can improve the tone b. The pigment is particularly suitable for use in paints, coatings and plastics.

Abstract: A method for producing nanoscale titanium dioxide particles which are coated with an oxide, a hydroxide or an oxide hydroxide of Al, Ce, Zr and/or Si wherein the enzymatic precipitant system urease/urea is used. Said coated titanium dioxide particles can have an average size of less than 50 nm, the coating providing effective protection against photocatalytic reactions. The coated particles are suitable, in particular, as UV absorbers in a transparent organic matrix.

Abstract: Transparent articles comprising transparent, nonmetallic substrate and a transparent film stack is sputter deposited on the substrate. The film stack is characterized by including at least one infrared reflective metal film, a dielectric film over the metal film, and a protective silicon nitride film of 10 ? to 150 ? in thickness over the said dielectric film. The dielectric film desirably has substantially the same index of refraction as does silicon nitride and is contiguous with the silicon nitride film.

Abstract: Water soluble hybrid phthalocyanine derivatives useful in competitive and noncompetitive assays immunoassays, nucleic acid and assays are disclosed and claimed having (1) at least one donor subunit with a desired excitation peak; and (2) at least one acceptor subunit with a desired emission peak, wherein said derivative(s) is/are capable of intramolecular energy transfer from said donor subunit to said acceptor subunit. Such derivatives also may contain an electron transfer subunit. Axial ligands may be covalently bound to the metals contained in the water soluble hybrid phthalocyanine derivatives. Ligands, ligand analogues, polypeptides, proteins and nucleic acids can be linked to the axial ligands of the dyes to form dye conjugates useful in immunoassays and nucleic acid assays.

Abstract: A method of making a grout composition which reduces the amount of bleed water from grout used in bonded post-tensioned concrete applications is provided. The method includes forming the grout composition by combining copolymers with other materials into a hydraulic cementitious composition. The copolymers are formed from structural components a) to c) and optionally d) which are mono-unsaturated compounds, with a generally linear macromolecular structure. By reducing the amount of bleed water in bonded post-tensioned concrete applications the grout composition provides protection from corrosion for the steel members, including stranded tendons and solid bars. The reduction in the amount of bleed water is achieved without significantly increasing the viscosity of the grout mixture thereby allowing good pumpability, placement, and maintenance of other properties such as resistance to volume change, long working time and acceptable strength development.

Abstract: Aerogels having a monolayer coating are described. The aerogel and a monolayer forming precursor are provided in a supercritical fluid, whereupon the aerogel and the monolayer forming precursor are reacted in said supercritical fluid to form a covalent bond between the aerogel and the monolayer forming precursor. Suitable aerogels are ceramic oxides such as silica, alumina, aluminosilicate, and combinations thereof. Suitable monolayer forming precursors include alkyl silanes, chlorosilanes, boranes, chloroboranes, germanes, and combinations thereof. The method may also include providing a surface preparation agent such as water, or hydroetching an aerogel to enhance the coating of the monolayer.

Abstract: A process of producing an organically modified metal oxide wherein an aqueous slurry of a metal oxide which can be peptized in the presence of an acid is admixed with an aqueous slurry of an oregano silage having the formula RySiX4-y, the mixture of the aqueous slurry and the oregano silage being thermally aged to produce a colloidal metal oxide sol which can be dried to produce a powder which is readily discernible in polar compounds such as alcohols, water and the like.

Abstract: A film-forming composition contains surface-treated nanocrystalline particles dispersed in a cross-linkable resin. A substantially transparent, abrasion-resistant film is formed from the film-forming composition. Processes for preparing the film-forming composition and for preparing a substantially transparent, abrasion-resistant film are also included. The surface-treated nanocrystalline particles may be obtained by treating nanocrystalline particles with one or more siloxane species, such as a siloxane star-graft polymer coating.

Abstract: A method for coating moisture sensitive inorganic particles, such as phosphors, comprising mixing the inorganic particles having a particle size of about 1 to 100 micrometers with nanometer-sized coating particles, and firing the mixture to soften or melt the nanometer-sized particles about the inorganic particles, forming a moisture impervious coating. The coated particles are washed to remove excess particles, and dried. Coated moisture sensitive phosphor particles are impervious to moisture.

Abstract: Silylated silica is prepared by silylating silica with an organosiloxane composed of A units of the formula (I) (R13SiO1/2)??(I) and B units of the formulae (IIa-c) (R12SiO2/2), and/or??(IIa) (R1SiO3/2), and/or??(IIb) (SiO4/2)??(IIc), optionally having 1 or 2 attached groups —X on Si atoms, where X is OR, R being hydrogen or a monovalent alkyl radical having 1-4 carbon atoms, halogen, or acetoxy, R1 is a saturated or unsaturated, monovalent, optionally halogenated C1-18 hydrocarbon radical the groups ?SiX or ?SiX2 optionally present in a number C, wherein A, B, and C satisfy the relationships: 1?B?100 or 750<B<10 000, B?A+C, and, when A+C=0, 10?B?100 or 750<B<10 000. The silylated silica has a particularly homogenous coating of silylating agent.

Abstract: Algae-resistant roofing granules consisting of one or two coats of a fired semi-ceramic composition having a metallic copper powder which does not significantly affect the color tint strength of the pigment contained in the coatings.

Abstract: A method for coating moisture sensitive inorganic particles, such as phosphors, comprising mixing the inorganic particles which have a particle size of about 1 to 100 micrometers with nanometer sized coating particles, as of silica, and firing to soften or melt the nanometer sized particles, forming a moisture-impervious inorganic coating on the inorganic particles. The coated particles are washed to remove any uncoated particles and dried.

Abstract: A submicron particle forming method includes feeding a first set of precursors to a first energy application zone. Energy is applied to the first set of precursors in the first energy application zone effective to react and form solid particles having maximum diameter of no greater than 100 nanometers from the first set of precursors. The application of any effective energy to the solid particles is ceased, and the solid particles and a second set of precursors are fed to a second energy application zone. Energy is applied to the second set of precursors in the second energy application zone effective to react and form solid material about the solid particles from the second set of precursors with the solid particles with solid material thereabout having maximum diameter of no greater than 100 nanometers. Other aspects are contemplated.

Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.

Abstract: Metal oxide particles having a metal oxide core and a silicon dioxide coating have a low structure. The particle are produced by a base dissolved in water being added under agitation to a dispersion comprising a metal oxide, at least one compound of the type XnSi(OR)4−n, and water, the reaction product being separated out, optionally washed with water and dried. The metal oxide particles coated with silicon dioxide may be used in sun screening agents and in chemical-mechanical-polishing (CMP) applications.

Abstract: In order to state a powdered metal composite material having a high specific electrical resistance and having good mechanical strength, very good resistance to temperature and to fuel, and a starting material and a method for the economical production of such a composite material, a powdered metal composite material having a high specific electrical resistance, which contains at least two oxides encapsulating the powdered metal particles, the oxides forming at least one common phase, and a starting material containing a powdered metal, which contains at least two antitack agents having oxidic pyrolysis residue and oxidic fine powder, and a method for producing such a composite material are made available, which relate to a starting material of the kind named, in which the starting material is pressed to form molded articles, in which the antitack agents are pyrolyzed in a nonreducing atmosphere to form oxides, and the oxides then present are made to react with one another to form at least one common phase.

Abstract: An interface material comprising a resin mixture and at least one solder material is herein described. The resin material may comprise any suitable resin material, but it is preferred that the resin material be silicone-based comprising one or more compounds such as vinyl silicone, vinyl Q resin, hydride functional siloxane and platinum-vinylsiloxane. The solder material may comprise any suitable solder material, such as indium, silver, copper, aluminum and alloys thereof, silver coated copper, and silver coated aluminum, but it is preferred that the solder material comprise indium or indium-based compounds and/or alloys. The interface material, or polymer solder, has the capability of enhancing heat dissipation in high power semiconductor devices and maintains stable thermal performance. The interface material may be formulated by mixing the components together to produce a paste which may be applied by dispensing methods to any particular surface and cured at room temperature or elevated temperature.

Abstract: The invention provides a zinc oxide particle having suppressed surface activity which gives safe and effective UV ray shielding ability (especially at longer wavelengths) to a variety of products such as resin molds, coating compositions or cosmetics, and a process for the production of the same. The zinc oxide particle of the invention has on the surface a cover layer formed of zinc silicate in an amount of 0.5-50% by weight in terms of zinc silicate (Zn2SiO4) relative to the zinc oxide. The zinc oxide particle which contains solid solution iron or cobalt therein as well as a cover layer formed of zinc silicate has effective UV ray shielding ability at much longer wavelengths while it is suppressed in the surface activity.

Abstract: Colored roofing granules and methods for their preparations, having decorative metallic appearance and enhanced stability against discoloration of color containing a silica-encapsulated metallic flake or colored lamellar effect pigment distributed in an insolubilized alkali silicate coating.

Abstract: Interference pigment flakes and foils are provided which have luminescent and color-shifting properties. The pigment flakes can have a symmetrical coating structure on opposing sides of a core layer, can have an asymmetrical coating structure with all of the layers on one side of the core layer, or can be formed with encapsulating coatings around the core layer. The coating structure of the flakes and foils includes a core layer, a dielectric layer overlying the core layer, and an absorber layer overlying the dielectric layer. A luminescent material is incorporated into the flakes or foils as a separate layer or as at least part of one or more of the other layers. The pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing.

Abstract: A method of producing dimensionally stable paper and/or paperboard products by treating a hygroreactive cellulosic fiber matrix with a hydrophobic sizing agent solution; and drying the treated fibers using heat and/or pressure so that the hydrophobic sizing agent penetrates the fiber matrix making it hydrophobic.

Abstract: Interference pigment flakes and foils are provided which have luminescent and color-shifting properties. A luminescent material coating structure is provided which partially covers or encapsulates a color-shifting pigment flake, or covers the outer surface of a foil. The pigment flakes can have a symmetrical coating structure on opposing sides of a core layer, can have an asymmetrical coating structure with all of the layers on one side of the core layer, or can be formed with encapsulating coatings around the core layer. The coating structure of the flakes and foils includes a core layer, a dielectric layer overlying the core layer, and an absorber layer overlying the dielectric layer. The luminescent pigment flakes and foils exhibit a discrete color shift so as to have a first color at a first angle of incident light or viewing and a second color different from the first color at a second angle of incident light or viewing.

Abstract: Non-magnetic composite particles composed of non-magnetic core particles having an average particle size of 0.01 to 0.3 &mgr;m, and inorganic fine particles having an average particle size of 0.001 to 0.07 &mgr;m. The fine particles are present in an amount of 0.1 to 20% by weight based on the weight of the non-magnetic particles are on the surface of each non-magnetic particle, and are fixed or anchored on the surface of each non-magnetic particle through a silicon compound.The non-magnetic composite particles have a high polishing effect and a high dispersibility, and are useful as a non-magnetic undercoat layer for a magnetic recording medium.

Abstract: Methods of making a silica-coated carbon product are described. In one method, an aqueous media or solution and a carbon product are contacted with a solution comprising a silicate substantially free of metal ions, for a sufficient time and temperature to form the silica-coated carbon product. A method of making a silica-coated product by contacting the aqueous media and a carbon product with a solution comprising monosilicic acid is also described as well as exchanging metal ions in a solution comprising metallic silicate for hydrogen ions and contacting an aqueous media and a carbon product with the solution to form silica-coated carbon products. Silica-coated carbon products resulting from these methods are also described and include a plurality of silica-coated products wherein each of the silica-coated products are substantially and uniformly coated with silica and in the substantial absence of free silica.

Abstract: Reactive silica particles capable of producing coatings exhibiting excellent scratch resistance, weather resistance, adhesiveness, and curability, while satisfying a wide spectrum of performances from transparency to semi-transparency and providing a glossy surface as well as a frosty surface. Reactive silica particles comprises silica particles and an organic compound chemically bonded to the silica particles via a silyloxy group, wherein the organic compound has a polymerizable unsaturated group, a group represented by the following formula (1), (wherein X is a group selected from —NH—, —O—, and —S— and Y is a group selected from oxygen and sulfur, provided that when X is —O—, Y is a sulfur atom), and a group represented by the following formula (2), (wherein Z is a group selected from oxygen and sulfur).

Abstract: A conductive powder having an organic silicon polymer layer on the surface of each particle and a metal layer enclosing the silicon polymer layer possesses a stronger bond between the particle base and the metal even at elevated temperature and exhibits a high and stable conductivity and heat resistance.

Abstract: Adsorbent particles comprising superparamagnetic and/or low Curie Temperature transition metal-containing cores surrounded by a hydrous siliceous oxide coating can be formed by an aqueous process wherein the core is precipitated from an aqueous solution and a siliceous oxide coating is deposited thereon while complete drying of the core is avoided until after the siliceous oxide is deposited. The resulting siliceous adsorbents exhibit strong superparamagnetic and/or low Curie temperature magnetic properties with low transition metal leachability.

Abstract: Iron oxide hydroxide composite particles having an average particle diameter of 0.005 to 1.0 &mgr;m, comprises: iron oxide hydroxide particles as core particles, a coating formed on surface of said iron oxide hydroxide particles, comprising at least one organosilicon compound selected from the group consisting of: (1) organosilane compounds obtainable from alkoxysilane compounds, and (2) polysiloxanes or modified polysiloxanes, and an organic pigment coat formed on said coating layer comprising said organosilicon compound, in an amount of from 1 to 30 parts by weight based on 100 parts by weight of said iron oxide hydroxide particles. The iron oxide hydroxide composite particles of the present invention contain no harmful elements and exhibit not only excellent chemical resistances such as acid resistance and alkali resistance, but also excellent heat resistance.

Abstract: A pigment in thin flakes where spherical silica particles having an average particle size of 20-400 nm are adhered on the surface of a flaky substrate having an average particle size of 0.5-10 &mgr;m and then the said spherical silica particle-adhered surface of the flaky substrate adhered with spherical silica is further coated with ultrafine particles of titanium dioxide.

Abstract: Black iron-based composite particles of the present invention comprise: as a core particle black iron oxide particle or black iron oxide hydroxide particle having an average particle size of 0.08 to 1.0 &mgr;m; a coating layer formed on the surface of the black iron oxide particle or black iron oxide hydroxide particle, comprising at least one organosilicon compound selected from the group consisting of: (1) organosilane compounds obtained from alkoxysilane compounds, (2) polysiloxanes, or modified polysiloxanes and (3) fluoroalkyl organosilane compounds obtained from fluoroalkylsilane compounds; and carbon black coat formed on said coating comprising said organosilicon compound, in an amount of 1 to 30 parts by weight based on 100 parts by weight of said black iron oxide particles or black iron oxide hydroxide particles.

Abstract: A high emittance glass coating material which is applied to a surface of a specific structural body and fired on the surface, for providing on the surface a glass coating having a glass structure in which pigment particles having a predetermined degree of emissivity are dispersed, the high emittance glass coating material being characterized by including: a pigment covering film having a predetermined thickness, which is provided to cover each of the pigment particles, and which includes silicon dioxide (SiO2) such that a content of the silicon dioxide in the pigment covering film is higher than a content of the silicon dioxide in each portion of the glass structure which is adjacent to a corresponding one of the pigment particles.

Abstract: A highly functional film-coated powder which is produced without using the method based on the hydrolysis of a metal alkoxide and without using a metal alkoxide, which is an expensive compound, or a highly flammable organic solvent and which therefore can be obtained at a low overall product cost without necessitating explosion-proof facilities in the production equipment and while attaining easy temperature and humidity regulation; and a process for producing the same. The film-coated powder comprises a base particle having films on the surface thereof, wherein at least one of the films is formed by reaction of a metal salt in an aqueous solvent having a constant pH. By the technique, the surface of base particle can be evenly coated with a solid phase film while inhibiting particle aggregation without precipitating an independent solid phase in the liquid phase.

Abstract: The present invention relates to amorphous inorganic materials having pores of controlled size and shape with one or more spatially organized functional groups formed therein. Much like the active site residues in an enzyme, these functional groups can be positioned in a defined three dimensional relationship within the voids and with respect to each other. By varying both the positions and identities of these functional groups, diverse sets of substrate specific adsorbents and non-biologically-based catalysts can be made.

Abstract: A titanium oxide-filled addition reaction-curable silicone rubber composition including (A) a diorganopolysiloxane containing at least two alkenyl groups in one molecule, (B) an organohydrogenpolysiloxane containing in one molecule at least two silicon-bonded hydrogen atoms, (C) a platinum group metal catalyst, and (D) a titanium oxide powder having been surface-treated with a compound selected from the group consisting of a tetraalkoxysilane and a partial hydrolysis-condensation product of a tetraalkoxysilane; the titanium oxide powder being contained in an amount not less than 15 parts by weight based on 100 parts by weight of the component (A). The composition has a low viscosity and low thixotropic properties and easy to handle, even though it contains titanium oxide in a large quantity, and especially has a superior operability when used as a light-screening agent or a reflecting agent.

Abstract: Iron oxide hydroxide composite particles having an average particle diameter of 0.005 to 1.

Abstract: Adsorbent particles comprising superparamagnetic and/or low Curie Temperature transition metal-containing cores surrounded by a hydrous siliceous oxide coating can be formed by an aqueous process wherein the core is precipitated from an aqueous solution and a siliceous oxide coating is deposited thereon while complete drying of the core is avoided until after the siliceous oxide is deposited. The resulting siliceous adsorbents exhibit strong superparamagnetic and/or low Curie temperature magnetic properties with low transition metal leachability.

Abstract: A composition, containing carbon black pigment particles of a specific size and an inorganic binder, suitable for use as a color coating on inorganic substrates to provide a greater resistance to fade than conventional coating compositions. The particles have a mean particle size in the range of about 150 nm to about 500 nm and a surface area per weight of particles of about 20 m2/g or less. The composition is useful in producing coated inorganic granules for specific uses, such as roofing granules.

Abstract: A fine powder of hydrophobic titanium oxide, which, when added to toner powder, gives it high flowability and good electrification stability. The titanium oxide is prepared by hydrolyzing a volatile titanium compound while in a high-temperature vapor-phase condition, in the presence of a combustible or incombustible gas, and has a BET specific surface area of from 55 to 150 m2/g and an anatase/rutile crystal structure with a ratio of anatase falling between 0.3 and 0.98. It is processed for surface modification with a silane coupling agent and/or a silicone compound to produce a fine powder of hydrophobic titanium oxide.

Abstract: Algae-resistant roofing granules coated with: a first coat consisting of a fired silicate-clay matrix containing cuprous oxide and zinc sulfide to provide a slow, long-term bimetallic copper and zinc ions release; and a second coat consisting of a fired silicate-clay matrix containing a pigment.

Abstract: The present invention relates to a process for the preparation of organically modified aerogels, comprising a) the preparation of a silicic acid sol having a pH of ≦4.0 from an aqueous water glass solution, with the aid of at least one organic and/or inorganic acid; b) polycondensation of the resulting silicic acid sol to a SiO2 gel by the addition of a base; c) washing the gel obtained in Step b) with an organic solvent until the water content of the gel is ≦5% by weight; d) surface-silylating the gel obtained in Step c), and e) drying the surface-silylated gel obtained in Step d), characterized in that at least one acid forms difficultly soluble salts with the cations of the water glass in the silicic acid sol, and that before Step b) the resulting difficultly soluble salts are extensively precipitated and separated from the silicic acid sol.

Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.

Abstract: Reactive silica particles capable of producing coatings exhibiting excellent scratch resistance, weather resistance, adhesiveness, and curability, while satisfying a wide spectrum of performances from transparency to semi-transparency and providing a glossy surface as well as a frosty surface.

Abstract: A method of manufacturing a magnetic disk includes the steps of depositing a sublayer, a Cr layer and a Co based magnetic layer on a substrate. The sublayer causes the Cr crystals to avoid growing with a predominantly (200) orientation. Because of this the magnetic layer will be isotropic in the film plane and independent of any texture or scratch marks in the substrate.

Abstract: Thermally insulative xerogels and their preparation are described. To obtain these xerogels, an inorganic gel having hydroxyl moieties is reacted with a silicon-nitrogen compound which has a C.sub.1-6 hydrocarbon moiety on the silicon. Shrinkage of the gel during drying the gel is reduced and a more highly porous xerogel is obtained. The more highly porous xerogel has a low thermal conductivity which makes it a good thermal insulation.