Metal Base Patents (Class 427/376.8)
  • Patent number: 8822872
    Abstract: Disclosed are an electrode wire for electro-discharge machining and a method for manufacturing the same. The electrode wire includes a core wire including a first metal including copper, a first alloy layer formed at a boundary region between the core wire and a second metal plated on an outer surface of the core wire due to mutual diffusion between the core wire and the second metal, and a second alloy layer formed due to diffusion of the first metal to the second metal. A core wire material is erupted onto a surface of the electrode wire for electro-discharge machining, which includes the core wire, the first alloy layer, and the second alloy layer, along cracks appearing on the second alloy layer, so that a plurality of grains are formed on the surface of the electrode wire.
    Type: Grant
    Filed: April 9, 2012
    Date of Patent: September 2, 2014
    Inventors: Ki-Chul Seong, Hyun-Soo Seong, Hyun-Kook Seong
  • Patent number: 8661675
    Abstract: In supplying flux to a brazing heat exchanger member, a given amount of the flux is stably adhered to brazing portions without interposing any substance which becomes unnecessary for the brazing such as binder. In manufacturing a heat exchanger member, particles containing flux are injected to a surface of a substrate made of aluminum or its alloy at a temperature lower than a melting point of the flux by 30° C. or more to collide against the surface at an average speed of 100 m/sec or higher to thereby mechanically adhere the particles thereto.
    Type: Grant
    Filed: December 11, 2008
    Date of Patent: March 4, 2014
    Assignee: Showa Denko K.K.
    Inventors: Kazuhiko Minami, Ichiro Iwai
  • Publication number: 20130220523
    Abstract: A method for forming protective coatings on equipment is disclosed. The coating is formed from a single-component Fe-based alloy composition comprising at least two refractory elements selected from Cr, V, Nb, Mo and W in an amount of up to 30% each and a total concentration of up to 40%. In one embodiment, the single-component coating layer is applied by thermal spraying, followed by heat treatment for at least a portion of the refractory elements to fuse into the substrate forming a metallurgical bond. The coating has an adhesion strength of at least 7,000 psi measured according to ASTM D4541. The coating is further characterized as being impermeable to corrosive environments showing no pin holes in the ferroxyl test according to ASTM A967 Practice E.
    Type: Application
    Filed: February 29, 2012
    Publication date: August 29, 2013
    Applicant: c/o Chevron Corporation
    Inventors: Justin Lee Cheney, Grzegorz Jan Kusinski
  • Publication number: 20130157072
    Abstract: There are provided a sliding member that is enhanced in adhesiveness between the surface of a base member formed of aluminum or aluminum alloy and silver coating with a simple construction, and a method of manufacturing the sliding member. In a piston 1 having a sliding face 22 which slides in a cylinder bore 3, a silver coating layer 21 constituting the sliding face 22 is provided on the outer peripheral surface 11 of a main body 10 formed of aluminum alloy, and the silver coating layer 21 is formed by coating slurry having silver particles 23 dispersed in terpineol on the outer peripheral surface 11 of the main body 10 and heating the coated slurry and the main body 10 to remove terpineol in the slurry and fuse the silver particles 23 with one another.
    Type: Application
    Filed: July 26, 2011
    Publication date: June 20, 2013
    Applicant: HONDA MOTOR CO., LTD.
    Inventors: Ryotaro Takada, Yoshitaka Tsujii, Mayumi Saruyama
  • Patent number: 8445057
    Abstract: There is provided a conductive material comprising a base material made up of a Cu strip, a Cu—Sn alloy covering layer formed over a surface of the base material, containing Cu in a range of 20 to 70 at. %, and having an average thickness in a range of 0.1 to 3.0 ?m, and an Sn covering layer formed over the Cu—Sn alloy covering layer having an average thickness in a range of 0.2 to 5.0 ?m, disposed in that order, such that portions of the Cu—Sn alloy covering layer are exposed the surface of the Sn covering layer, and a ratio of an exposed area of the Cu—Sn alloy covering layer to the surface of the Sn covering layer is in a range of 3 to 75%.
    Type: Grant
    Filed: August 16, 2010
    Date of Patent: May 21, 2013
    Assignee: Kobe Steel, Ltd.
    Inventors: Motohiko Suzuki, Hiroshi Sakamoto, Yukio Sugishita, Riichi Tsuno
  • Patent number: 8431191
    Abstract: This invention introduces a method for treating a surface of an electrically conductive object with a refractory metal. In one embodiment, the refractory metal is tantalum and the object is a titanium substrate. A surface layer of mixed tantalum and titanium oxides is created by first heating the object and tantalum chloride in a reaction chamber and subsequently heat treating the object in an oxygen containing environment. The electrically conductive object can in a non-limiting way be DSA solutions (Dimensionally Stable Anodes), fuel cells or connector plates.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: April 30, 2013
    Assignee: Tantaline A/S
    Inventors: Bo Gillesberg, Soeren Eriksen
  • Patent number: 8313623
    Abstract: A cathode for electrolytic processes, particularly suitable for hydrogen evolution in chlor-alkali electrolysis comprises a metal substrate provided with a catalytic coating made of two layers containing palladium, rare earths (such as praseodymium) and a noble component selected between platinum and ruthenium. The rare earth percent amount by weight is lower in the outer layer than in the inner layer.
    Type: Grant
    Filed: April 5, 2012
    Date of Patent: November 20, 2012
    Assignee: Industrie de Nora S.p.A.
    Inventors: Antonio Lorenzo Antozzi, Alice Calderara, Marianna Brichese
  • Patent number: 8309178
    Abstract: Provided are methods and initial structures for fabricating corrosion resistant steels that incorporate an aluminum rich corrosion resistant surface layer. The initial structures utilize layering and/or patterning for reducing the effective diffusion length Deff to a value well below the total thickness of the aluminum alloy protective layer X1 by providing vertical and/or lateral laminated structures that provide ready sources of Fe atoms during subsequent heat treatment processes.
    Type: Grant
    Filed: July 23, 2009
    Date of Patent: November 13, 2012
    Assignee: Honda Motor Co., Ltd.
    Inventors: Alan Seid, Masayuki Narita
  • Patent number: 8133544
    Abstract: A high-strength quenched formed body containing a layer on the surface of an after-quenching formed-body steel material in which layer Zn is a major component and which layer contains 30% by mass or less of Fe, and which layer is present in an amount of 30 g/m2 or more. A quenched formed body is produced by quenching a zinc-plated steel material which includes a zinc-plated layer containing each of Al and Si having alloying-retarding function and readily-oxidizing function independently or compositely, in an amount of 0.15% by mass or more, after heating it to 800° C. or more and 950° C. or less in an oxidizing atmosphere containing 0.1% by volume or more of oxygen.
    Type: Grant
    Filed: September 13, 2010
    Date of Patent: March 13, 2012
    Assignees: Aisin Takaoka Co., Ltd., Nippon Steel Corporation
    Inventors: Shinichi Suzuki, Toshimasa Tomokiyo, Shuuji Souma, Katsuji Nakashima, Masashi Ozawa, Kiyohito Kondou
  • Patent number: 8128887
    Abstract: A coating applied to at least a portion of the surfaces of reactors, reactor internals, other reactor components, and/or heater tubes is provided in order to minimize the formation of metal catalyzed coke in hydrocarbon conversion processes operating at temperatures at about 350° C. (662° F.) or greater and in reducing environments. These coatings may comprise Nickel coatings or complexes thereof, such as Ni—Al, Ni—Cr/Cr carbide, as well as aluminum painted coatings that are applied in a reduction cure process (e.g., application temperatures of about 600° C. (1112° F.)). Additionally, where H2S is necessary for the process, such as to minimize thermal cracking, the coatings also reduce corrosion of base metal due to sulfidation attack and eliminate the requirement of continuous replacement of reactor internals and other components.
    Type: Grant
    Filed: September 5, 2008
    Date of Patent: March 6, 2012
    Assignee: UOP LLC
    Inventors: Steven A. Bradley, Robert B. James, Jr., David W. Alley
  • Patent number: 8101285
    Abstract: A metallic material for a connecting part, having a rectangular wire material of copper or a copper alloy as a base material, and formed at an outermost surface thereof, a copper-tin alloy layer substantially composed of copper and tin, wherein the copper-tin alloy layer of the outermost surface further contains at least one selected from the group consisting of zinc, indium, antimony, gallium, lead, bismuth, cadmium, magnesium, silver, gold, and aluminum, in a total amount of 0.01% or more and 1% or less in terms of mass ratio with respect to the content of the tin.
    Type: Grant
    Filed: September 29, 2010
    Date of Patent: January 24, 2012
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Kengo Mitose, Shuichi Kitagawa, Yoshiaki Ogiwara
  • Patent number: 7959711
    Abstract: A method of manufacturing such gas separation membrane system that includes applying to a surface of a porous substrate a layer of a nanopowder of a gas-selective metal and, thereafter, heat-treating the resultant surface treated porous substrate to yield a heat-treated and surface-treated porous substrate suitable for use as a gas separation membrane system.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: June 14, 2011
    Assignee: Shell Oil Company
    Inventors: John Charles Saukaitis, Alan Anthony Del Paggio
  • Patent number: 7892605
    Abstract: A high-strength quenched formed body containing a layer on the surface of an after-quenching formed-body steel material in which layer Zn is a major component and which layer contains 30% by mass or less of Fe, and which layer is present in an amount of 30 g/m2 or more. A quenched formed body is produced by quenching a zinc-plated steel material which includes a zinc-plated layer containing each of Al and Si having alloying-retarding function and readily-oxidizing function independently or compositely, in an amount of 0.15% by mass or more, after heating it to 800° C. or more and 950° C. or less in an oxidizing atmosphere containing 0.1% by volume or more of oxygen.
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: February 22, 2011
    Assignees: Aisin Takaoka Co., Ltd., Nippon Steel Corporation
    Inventors: Shinichi Suzuki, Toshimasa Tomokiyo, Shuuji Souma, Katsuji Nakashima, Masashi Ozawa, Kiyohito Kondou
  • Patent number: 7829142
    Abstract: Disclosed herein is a method for aluminiding an internal passage of a metal substrate comprising injecting a slurry composition that comprises a powder comprising aluminum, a binder selected from the group consisting of colloidal silica, an organic resin, and a combination thereof, into the internal passage; applying compressed air to the internal passage to facilitate distribution of the slurry composition throughout the internal passage; and, heat treating the slurry composition under conditions sufficient to remove volatile components from the composition, and to cause diffusion of aluminum into a surface of the internal passage.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: November 9, 2010
    Assignee: General Electric Company
    Inventors: Lawrence Bernard Kool, Michael Howard Rucker
  • Patent number: 7759614
    Abstract: Apparatus, for the localised treatment of part of a blade (14), comprises an enclosure (16) that is placed in a spaced relationship around the blade (14). Nozzles (20) extend through the enclosure (16) and direct a flow of gas onto both sides of the blade (14). The gas may be heated or cooled prior to delivery to the nozzles (20). The gas jets impinge upon the blade (14) to treat it.
    Type: Grant
    Filed: May 23, 2006
    Date of Patent: July 20, 2010
    Assignee: Rolls-Royce plc
    Inventors: Daniel Clark, Steinar J Walloe
  • Patent number: 7721425
    Abstract: A method of connecting an electronic part, containing: forming an electroless nickel plating coat containing phosphorous on a substrate metal layer which constitutes a connecting terminal of an electronic part; and carrying out connecting to the nickel plating coat through a lead-free solder, wherein a half-width of X-ray diffraction of a (111) plane of Ni crystal in the nickel plating coat is 5 degrees or less.
    Type: Grant
    Filed: July 30, 2003
    Date of Patent: May 25, 2010
    Assignee: The Furukawa Electric Co., Ltd.
    Inventor: Junya Hirano
  • Publication number: 20100080918
    Abstract: The present invention provides a surface treatment method for magnesium alloy, which comprising the following steps: 1) preparation; 2) fusion and uniformly coating; 3) heat diffusion, and 4) finish; so a coating alloy is placed on a magnesium alloy substrate, and the magnesium alloy substrate is heated so that the coating alloy is uniformly melted on the magnesium alloy substrate; when heating up to a preset temperature, the coating alloy generates heat diffusion on the magnesium alloy substrate; the coating alloy finally forms a corrosion-resistant hard layer on the magnesium alloy substrate. So, this invention features simple treatment process, stable structure and environmental-friendliness in a wide range of applications.
    Type: Application
    Filed: March 12, 2009
    Publication date: April 1, 2010
    Inventors: Shih-Ying Chang, Hsien-Hsueh Lee, Wei-Shen Chen, Yi-Yuan Ke
  • Publication number: 20100061902
    Abstract: A coating applied to at least a portion of the surfaces of reactors, reactor internals, other reactor components, and/or heater tubes is provided in order to minimize the formation of metal catalyzed coke in hydrocarbon conversion processes operating at temperatures at about 350° C. (662° F.) or greater and in reducing environments. These coatings may comprise Nickel coatings or complexes thereof, such as Ni—Al, Ni—Cr/Cr carbide, as well as aluminum painted coatings that are applied in a reduction cure process (e.g., application temperatures of about 600° C. (1112° F.)). Additionally, where H2S is necessary for the process, such as to minimize thermal cracking, the coatings also reduce corrosion of base metal due to sulfidation attack and eliminate the requirement of continuous replacement of reactor internals and other components.
    Type: Application
    Filed: September 5, 2008
    Publication date: March 11, 2010
    Inventors: Steven A. Bradley, Robert B. James, JR., David W. Alley
  • Patent number: 7615255
    Abstract: Methods and articles are disclosed. The methods are directed to depositing nickel duplex layers on substrates to inhibit tin and tin alloy surface oxidation and improve solderability of the substrates.
    Type: Grant
    Filed: August 28, 2006
    Date of Patent: November 10, 2009
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventors: Danny Lau, Raymund W. M. Kwok
  • Publication number: 20090232431
    Abstract: In the case of a plain bearing having at least one support part (25), which is composed of an iron-containing base material, of a bearing sleeve (24) which is provided at the raceway side with a coating (8, 26) which is composed of a coating material, is formed as a melted-on layer and is metallurgically connected to the base material by means of an FeSn2-containing connecting zone (9), it is possible to obtain a long service life in that the thickness of the FeSn2-containing connecting zone (9) is at most 10 ?m.
    Type: Application
    Filed: April 25, 2007
    Publication date: September 17, 2009
    Applicant: SMS DEMAG AG
    Inventors: Konrad Roeingh, Karl Keller
  • Publication number: 20080241412
    Abstract: A member for a plasma etching device, which comprises a device substrate comprising quartz glass, aluminum, alumite or a combination thereof and, formed on the surface thereof, a coating film of yttrium oxide or YAG having a film thickness of 10 ?m or more and a variation in the thickness of 10% or less, and preferably a surface roughness (Ra) of 1 ?m or less; and a method for manufacturing the member for a plasma etching device, which comprises a step of plasma-spraying yttrium oxide or YAG to the surface of said device substrate or a step of fusing yttrium oxide or YAG with an oxyhydrogen flame, followed by coating the surface with the fused product, or a step of applying a solution containing yttrium, a yttrium compound or YAG on the above surface, followed by heating to fuse the resultant coating, or a combination of the above steps, thereby forming a coating film of yttrium oxide or YAG having a film thickness 10 ?m or more and a variation in the thickness of 10% or less, and preferably a surface roughne
    Type: Application
    Filed: November 6, 2007
    Publication date: October 2, 2008
    Applicant: Shin-Etsu Quartz Products Co., Ltd.
    Inventors: Kyoichi Inaki, Itsuo Araki
  • Publication number: 20080193655
    Abstract: The invention relates to a method for hot-dip coating hot-rolled steel strip, during which the steel strip passes through a pickling station, a rinsing station, a drying station, a heating furnace and then through a molten bath. The final thickness and the thickness tolerance of the hot-dip coated steel strip are achieved by a controlled thickness reduction in a roll stand in the process line. The achievement of the finished thickness is controlled by at least one thickness measuring unit at the outlet of the roll stand, and deviations upward or downward therefrom are fed back in the form of an actuating signal for actuating the roll stand in order to appropriately increase or decrease the thickness reduction. The invention also relates to an installation for producing a steel strip of the aforementioned type.
    Type: Application
    Filed: March 9, 2006
    Publication date: August 14, 2008
    Inventors: Hans-Georg Kloeckner, Andreas Gramer
  • Publication number: 20070202349
    Abstract: An exemplary copper-silver alloy wire includes a conductive core containing copper, and a copper-silver cladding layer surrounding the conductive core. An exemplary method for manufacturing the copper-silver alloy wire including steps of: providing a conductive core containing copper; forming a silver layer surrounding the conductive core; and heating the silver layer and peripheral portions of the conductive core so as to form a copper-silver cladding layer at an interface between the silver layer and the conductive core. The copper-silver alloy wire has high electrical conductivity, low current loss and high anti-interference.
    Type: Application
    Filed: September 22, 2006
    Publication date: August 30, 2007
    Applicant: HON HAI PRECISION INDUSTRY CO., LTD.
    Inventor: GA-LANE CHEN
  • Patent number: 7150897
    Abstract: According to the present invention there is now provided a cemented carbide body provided with at least one wear resistant layer, which body contains a toughness increasing surface zone. Increase in toughness is obtained due to the presence of a surface zone having increased WC grain size and/or increased Co content. The invention is most suitable for WC—Co cemented carbides. A method for making such bodies is also disclosed.
    Type: Grant
    Filed: November 23, 2001
    Date of Patent: December 19, 2006
    Assignee: Sandvik Intellectual Property AB
    Inventor: Marian Mikus
  • Patent number: 6932897
    Abstract: A method for plating a titanium-containing metal, comprising the steps of: (a) surface treating the titanium-containing metal in a solution consisting essentially of an aqueous solvent and hydrochloric acid for a period of time sufficient to activate the surface of the titanium-containing metal; (b) plating the surface of the surface treated titanium-containing metal with a metallic coating in an electrolyte bath; and (c) non-oxidatively heat treating the plated titanium-containing metal for a period of time sufficient to cause diffusion bonding between the metallic coating and the titanium-containing metal. The present invention also provides parts made in accordance with the methods disclosed herein.
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: August 23, 2005
    Assignee: Com Dev Ltd.
    Inventors: Florin Burca, John Darmon
  • Patent number: 6913791
    Abstract: A method for surface treating a titanium-containing metal, comprising the steps of: (a) treating at least a portion of a surface of the titanium-containing metal with an anodic activation in an electrolyte bath; and (b) strike plating at least a portion of the surface of the treated titanium-containing metal with a metallic coating in the same electrolyte bath as in step (a), wherein the titanium-containing metal remains submerged in the electrolyte bath during steps (a) and (b).
    Type: Grant
    Filed: March 3, 2003
    Date of Patent: July 5, 2005
    Assignee: COM DEV Ltd.
    Inventors: Florin Burca, John Darmon
  • Patent number: 6893737
    Abstract: A low cost aluminide process for moderate temperature applications. A gas turbine engine component is cleaned and coated with a layer of metal, generally aluminum, containing paint. The metal containing paint layer is heated to a first temperature for a first period of time in an air environment to volatilize the solvents in the paint. The metal containing paint layer is heated to a second temperature for a second period of time in an oxygen-free atmosphere to volatilize the solvents in the paint. The now metal layer and component are heated to a third temperature for a third period of time to interdiffuse the metal and the metal of the component. The component and diffusion layer are then cooled to ambient temperature.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: May 17, 2005
    Assignee: General Electric Company
    Inventors: John F. Ackermann, Paul V. Arszman, Andrew J. Skoog
  • Patent number: 6884524
    Abstract: A low cost chromide and chromide/aluminide process for moderate temperature applications. A gas turbine engine component is cleaned and coated with a layer of metal, generally chromium or chromium and aluminum, containing paint. The metal containing paint layer is heated to a first temperature for a first period of time in an air environment to volatilize the solvents in the paint. The metal containing paint layer is heated to a second temperature for a second period of time in an oxygen-free atmosphere to volatilize the solvents in the paint. The now metal layer and component are heated to a third temperature for a third period of time to interdiffuse the metal and the metal of the component. The component and diffusion layer are then cooled to ambient temperature.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: April 26, 2005
    Assignee: General Electric Company
    Inventors: John F. Ackermann, Paul V. Arszman, Andrew J. Skoog
  • Patent number: 6881439
    Abstract: An aluminiding process that enables the cooling holes of an air-cooled component, such as a hot gas path component of a gas turbine engine, to be machined and then aluminized after all external surface coatings have been deposited. The aluminide coating is deposited using a slurry process capable of forming the aluminide coating on the component without damaging an existing ceramic coating on the component. The process involves applying an activator-free slurry containing aluminum particles that, when the component is sufficiently heated, melt and diffuse into the component surface to form the diffusion aluminide coating.
    Type: Grant
    Filed: December 4, 2002
    Date of Patent: April 19, 2005
    Assignee: General Electric Company
    Inventors: Stephen Daniel Graham, John Herbert Wood, Cyril Gerard Beck, Warren Tan King
  • Patent number: 6833164
    Abstract: A single-step heat treating and surface coating process is provided for steel self-piercing rivets for joining 5xxx and 6xxx aluminum panels. In this process, two coats of zinc and aluminum flakes in an inorganic binder are applied to the steel rivets. After each coating, the rivets are heated to set and cure the coats and to achieve the desired microstructure and hardness level for joining 5xxx and 6xxx aluminum panels. The coating curing step combines the heat treatment with surface coating into a single-step procedure.
    Type: Grant
    Filed: May 6, 2002
    Date of Patent: December 21, 2004
    Assignee: Ford Global Technologies, LLC.
    Inventor: Huimin Liu
  • Patent number: 6821557
    Abstract: Disclosed is a tungsten film coating method using tungsten oxide powders including the steps of contacting the tungsten oxide powders with a metal substrate and carrying out thermal reduction treatment thereon at a temperature of at least 650° C. under a hydrogen atmosphere just to coat the tungsten film on the metal substrate. Accordingly, the present invention enables to provide a simple method of coating a tungsten thin film on a metal substrate using the phenomenon of tungsten migration through vapor phase when thermal reduction treatment is carried out on tungsten oxide powders without using previous chemical or physical vapor depositions requiring expensive precision equipments or causing environmental pollution.
    Type: Grant
    Filed: January 10, 2003
    Date of Patent: November 23, 2004
    Assignee: Agency for Defense Development
    Inventors: Seong Lee, Moon-Hee Hong, Joon-Woong Noh, Eun-Pyo Kim, Yoon-Sik Park
  • Patent number: 6800326
    Abstract: A method for treating surfaces of titanium or titanium alloys which includes the steps of applying a treatment for removing surface adhesion substances from the surface and then forming a transparent protective layer on the surface.
    Type: Grant
    Filed: June 29, 2000
    Date of Patent: October 5, 2004
    Assignee: Seiko Epson Corporation
    Inventor: Akira Uchiyama
  • Patent number: 6770383
    Abstract: To provide a plated material having both high heat-resistance and good insertability/extractability. The plated material comprises an undercoating of any one of metals belonging to group 4, group 5, group 6, group 7, group 8, group 9 or group 10 of the periodic table or an alloy containing any one of those metals as a main component, an intermediate coating of Cu or a Cu alloy, and a top-coating of Sn or an Sn alloy, the undercoating, the intermediate coating and the top-coating being formed on a surface of an electrically conductive base in this order, and the thickness of the top-coating is 1.9 times or more the thickness of the intermediate coating.
    Type: Grant
    Filed: September 18, 2002
    Date of Patent: August 3, 2004
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Hitoshi Tanaka, Akira Matsuda, Satoshi Suzuki, Morimasa Tanimoto
  • Patent number: 6761929
    Abstract: A method is provided for the preparation of metal/porous substrate composite membranes by flowing a solution of metal to be plated over a first surface of a porous substrate and concurrently applying a pressure of gas on a second surface of the porous substrate, such that the porous substrate separates the solution of metal from the gas, and the use of the resulting membrane for the production of highly purified hydrogen gas.
    Type: Grant
    Filed: July 22, 2002
    Date of Patent: July 13, 2004
    Assignee: Research Triangle Institute
    Inventor: Ashok S. Damle
  • Patent number: 6652914
    Abstract: A gas turbine blade which has previously been in service is protected by cleaning the gas turbine blade, and then first depositing a platinum first layer on the airfoil and the platform of the gas turbine blade. Thereafter, a platinum second layer is deposited over the platform but not the airfoil. A platinum-aluminide protective coating is formed by depositing an aluminum-containing layer overlying both the platform and the airfoil and interdiffusing the platinum and the aluminum.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: November 25, 2003
    Assignee: General Electric Aviation Service Operation Pte. Ltd.
    Inventors: Nigel Brian Thomas Langley, Keng Nam Chen, Genfa Hu, Kwok Heng Yow
  • Patent number: 6645560
    Abstract: An environmentally resistant coating (34) for improving the oxidation resistance of a niobium-based refractory metal intermetallic composite (Nb-based RMIC) at high temperatures, the environmentally resistant coating (34) comprising silicon, titanium, chromium, and niobium. The invention includes a turbine system (10) having turbine components (11) comprising at least one Nb-based RMIC, the environmentally resistant coating (34) disposed on a surface (33) of the Nb-based RMIC, and a thermal barrier coating (42) disposed on an outer surface (40) of the environmentally resistant coating (34). Methods of making a turbine component (11) having the environmentally resistant coating (34) and coating a Nb-based RMIC substrate (32) with the environmentally resistant coating (34) are also disclosed.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: November 11, 2003
    Assignee: General Electric Company
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Bernard Patrick Bewlay
  • Publication number: 20030207037
    Abstract: A single-step heat treating and surface coating process is provided for steel self-piercing rivets for joining 5xxx and 6xxx aluminum panels. In this process, two coats of zinc and aluminum flakes in an inorganic binder are applied to the steel rivets. After each coating, the rivets are heated to set and cure the coats and to achieve the desired microstructure and hardness level for joining 5xxx and 6xxx aluminum panels. The coating curing step combines the heat treatment with surface coating into a single-step procedure.
    Type: Application
    Filed: May 6, 2002
    Publication date: November 6, 2003
    Applicant: Ford Global Technologies, Inc.
    Inventor: Huimin Liu
  • Patent number: 6638573
    Abstract: As a method of treating a frame of spectacles which enables fine color modulation with ease, good reproducibility, and at low cost, there is provided a method of treating the surface of a frame of spectacles characterized in that a surface treating composition comprising a metal complex is used to form a coating layer on part or the whole of the surface of the frame of spectacles.
    Type: Grant
    Filed: January 11, 2002
    Date of Patent: October 28, 2003
    Assignees: Osaka Municipal Government, Hoya Corporation
    Inventors: Masami Nakamoto, Toshihisa Akaba
  • Patent number: 6607787
    Abstract: A process for producing a coating on a refractory structural member, in which a noble metal alloy is applied as a coating material to the refractory structural member. The noble metal alloy contains, among other constituents, an oxidizable substance, which includes boron and/or phosphorus and/or antimony and/or arsenic. The refractory structural member and the coating are heated at least once in an oxygen-containing atmosphere to a temperature T that is greater than or equal to the liquidus temperature TL of the noble metal alloy. The oxidizable substance is oxidized during this heating process, and the oxide that has formed is at least partially vaporized. The temperature T is maintained until the proportion of oxidizable substance in the coating is <0.1 atomic percent, and the coated refractory structural member is then cooled.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: August 19, 2003
    Assignee: W. C. Heraeus GmbH & Co. KG
    Inventors: Wulf Kock, Frank Krüger, David Lupton, Harald Manhardt, Jürgen Merker
  • Patent number: 6602354
    Abstract: A tin layer and a nickel layer are stacked sequentially on a given substrate to form a multilayered film composed of the tin layer and the nickel layer. Then, the multilayered film is heated to a given temperature to form a tin-nickel alloy film through the diffusion of the tin elements of the tin layer into the nickel layer.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: August 5, 2003
    Assignee: Suzuka National College of Technology
    Inventors: Hideyuki Kanematsu, Tatsumasa Kobayashi, Takeo Oki
  • Publication number: 20030124342
    Abstract: An environmentally resistant coating (34) for improving the oxidation resistance of a niobium-based refractory metal intermetallic composite (Nb-based RMIC) at high temperatures, the environmentally resistant coating (34) comprising silicon, titanium, chromium, and niobium. The invention includes a turbine system (10) having turbine components (11) comprising at least one Nb-based RMIC, the environmentally resistant coating (34) disposed on a surface (33) of the Nb-based RMIC, and a thermal barrier coating (42) disposed on an outer surface (40) of the environmentally resistant coating (34). Methods of making a turbine component (11) having the environmentally resistant coating (34) and coating a Nb-based RMIC substrate (32) with the environmentally resistant coating (34) are also disclosed.
    Type: Application
    Filed: December 10, 2002
    Publication date: July 3, 2003
    Inventors: Ji-Cheng Zhao, Melvin Robert Jackson, Bernard Patrick Bewlay
  • Patent number: 6585878
    Abstract: A thermal barrier coating for nickel based superalloy articles such as turbine engine vanes and blades that are exposed to high temperature gas is disclosed. The coating includes a columnar grained ceramic layer applied to a platinum modified Ni3Al gamma prime phase bond coat having a high purity alumina scale. The preferred composition of the bond coat is 5 to 16% by weight of aluminum, 5 to 25% by weight of platinum with the balance, at least 50% by weight, nickel. A method for making the bond coat is also disclosed.
    Type: Grant
    Filed: August 7, 2002
    Date of Patent: July 1, 2003
    Assignee: Honeywell International, Inc.
    Inventors: Thomas E. Strangman, Derek Raybould
  • Patent number: 6537388
    Abstract: Chromium, silicon, aluminum, and optionally manganese are diffused onto the surface of a high temperature alloy product, to provide a coating having improved resistance to carburization and catalytic coke formation and smoother surfaces for high temperature hydrocarbon environments. Preferably, a first layer of chromium or chromium and silicon is deposited and diffusion heat-treated and covered by the second layer of aluminum or aluminum-silicon. The inner layer contains a minimum of 8 weight percent chromium above that contained in the substrate alloy. The outer layer contains a minimum of 20 weight percent aluminum at the coating surface. The coating system is then aged to yield the improved coating that has 60 to 90 weight percent chromium at the surface. Each layer or the combination of layers is diffusion heat treated to cause a diffusion depth ranging from 0.006 inch (0.1524 millimeter) to 0.030 inch (0.762 millimeter) with targeted 0.012 inch (0.3048 millimeter) to 0.015 inch (0.3810 millimeter).
    Type: Grant
    Filed: October 27, 2000
    Date of Patent: March 25, 2003
    Assignee: Alon, Inc.
    Inventors: Kim A. Wynns, George T. Bayer
  • Patent number: 6511630
    Abstract: A method for coating a surface of a substrate, includes providing a substrate having a surface, and coating the surface with a foam suspension containing a powder suspended in a foam to form a coating on the surface. The substrate is then heat treated to densify the coating along the surface.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: January 28, 2003
    Assignee: General Electric Company
    Inventors: Thomas Joseph Cartier, D. Sangeeta, Dong-Sil Park, Theodore Robert Grossman
  • Patent number: 6497920
    Abstract: An internal passage of an article such as a gas turbine airfoil is coated with an aluminum-containing coating. To accomplish this coating process, a coating slurry of a mixture of a carrier component of water and a hectorite clay or a bentonite clay, together with a solids component of a source of aluminum, a halide activator, and an oxide dispersant, is prepared. The coating slurry is applied to the internal passage of the gas turbine airfoil and dried. The gas turbine airfoil and the applied coating slurry are heated to form an aluminum-containing coating bonded to the internal passage of the gas turbine airfoil. Excess coating material is removed from the article internal passage.
    Type: Grant
    Filed: September 6, 2000
    Date of Patent: December 24, 2002
    Assignee: General Electric Company
    Inventors: Jeffrey Allan Pfaendtner, Joseph David Rigney, Nripendra Nath Das, Michael James Weimer, John Lewis Lackman
  • Patent number: 6491766
    Abstract: A coating composition and process have been developed to provide an activated coating on nickel screen for use as cathodes in electrolytic cells for the generation of hydrogen and oxygen. Compared to the earlier Classical Pack Cementation process, the disclosed process is less expensive, reduces processing time from 20 hours to a few minutes, eliminates dusts and toxic gases, and provides improved performance in cells for hydrogen and oxygen generation. The coating is characterized by the presence of two activated layers with a high surface area, a multitude of fissures and a nickel to aluminum weight ratio greater than 20/1 in the top layer and greater than 4/1 in the bottom layer adjacent to the nickel substrate.
    Type: Grant
    Filed: October 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Alloy Surfaces Co., Inc.
    Inventors: Alfonso L. Baldi, Frank J. Clark
  • Patent number: 6485792
    Abstract: A method for applying substantially stoichiometric NiAl to the surface of a superalloy substrate. These coatings are applied to substrates subjected to high temperatures and thermal cycling by providing a powder of the substantially stoichiometric material with the desired minor additions of rare earth elements, Cr or Zr. The coatings are applied by a thermal spray process utilizing hydrogen as a fuel while generating a highly reducing flame. The thermal spray method melts the powder and directs it onto the surface of the turbine component that is to be coated. The powder size is carefully controlled to prevent oxidation of the powder while providing a controlled surface finish. The surface roughness of the bond coat is further mechanically worked to a predetermined surface finish prior to application of the ceramic thermal barrier layer by a PVD method.
    Type: Grant
    Filed: August 23, 2000
    Date of Patent: November 26, 2002
    Assignee: General Electric Company
    Inventors: Richard John Grylls, Joseph David Rigney, Matthew David Saylor, Theodore Robert Grossman, Yuk-Chiu Lau
  • Publication number: 20020119338
    Abstract: A turbine engine component includes a substrate and a wear coating on the substrate. The wear coating includes wear-resistant particles in a matrix phase, the wear-resistant particles being formed of chrome carbide or a cobalt alloy. Methods for forming a turbine engine component are also disclosed.
    Type: Application
    Filed: June 29, 1999
    Publication date: August 29, 2002
    Inventors: WAYNE CHARLES HASZ, DAVID EDWARD BUDINGER
  • Patent number: 6440499
    Abstract: A method for producing a corrosion-resistant and an oxidation-resistant coating on a component in which a slurry is formed by mixing a binder solution with (1) a base powder selected from the group consisting of (a) MCrAlY wherein M is Ni or Co or both, (b) NiCrAl and (c) mixtures of (a) and (b) with (2) an added powder of Al, Pt, Pd, Si or mixtures thereof, each of the said powders having a grain size between 5 and 120 &mgr;m. The slurry is applied onto a component made of a superalloy based on nickel or cobalt. The slurry is hardened on the component to form a hardened slurry coating by heating the slurry to a temperature between room temperature and 450° C., and the hardened slurry coating is heated, to produce diffusion thereof into the component, at a temperature between 750° C. and 1250° C.
    Type: Grant
    Filed: September 8, 2000
    Date of Patent: August 27, 2002
    Assignee: MTU Aero Engines GmbH
    Inventors: Gerhard Wydra, Thomas Cosack, Wolfgang Hinreiner
  • Patent number: 6372299
    Abstract: A method for providing a protective coating on a metal-based substrate is disclosed. The method involves the application of an aluminum-rich mixture to the substrate to form a discontinuous layer of aluminum-rich particles, followed by the application of a second coating over the discontinuous layer of aluminum-rich particles. Aluminum diffuses from the aluminum-rich layer into the substrate, and into any bond coat layer which is subsequently applied. Related articles are also described.
    Type: Grant
    Filed: September 28, 1999
    Date of Patent: April 16, 2002
    Assignee: General Electric Company
    Inventors: Anthony Mark Thompson, Dennis Michael Gray, Melvin Robert Jackson