Abstract: The present disclosure relates to a method that includes depositing a spalling layer onto a surface that includes a substrate, depositing a device comprising a III-V material onto the spalling layer, resulting in the forming of a stack, and dividing the stack substantially at a plane positioned within the spalling layer to form a first portion that includes the substrate and a second portion that includes the PV device, where the spalling layer includes a first layer configured to provide a compressive stress and a second layer configured to provide a tensile stress, the first layer and the second layer form an interface, the dividing occurs as result of the interface, and the compressive stress and the tensile stress are strain-balanced so that a total strain within the spalling layer is approximately zero.

Abstract: Methods for die attachment of multichip and single components including flip chips may involve printing a sintering paste on a substrate or on the back side of a die. Printing may involve stencil printing, screen printing, or a dispensing process. Paste may be printed on the back side of an entire wafer prior to dicing, or on the back side of an individual die. Sintering films may also be fabricated and transferred to a wafer, die or substrate. A post-sintering step may increase throughput.

Abstract: A bonding material using silver nanoparticles considerably changes in coating-material property in response to a slight change in composition, and the stability thereof has been insufficient for large-amount application. A bonding material which uses silver nanoparticles, meets the requirements for mass printing, attains dimensional stability, and gives a smooth printed surface is provided. The bonding material includes silver nanoparticles which have at least an average primary particle diameter of 1 nm to 200 nm and have been coated with an organic substance having 8 or less carbon atoms, a dispersion medium, and a viscosity modifier composed of an organic substance, and has a viscosity (measured at a shear rate of 15.7 [1/s]) of 100 Pa·s or lower and a thixotropic ratio (measured at a shear rate of 3.1 [1/s]/measured at a shear rate of 15.7 [1/s]) of 4 or lower.

Abstract: A method of smoothing the surface of a ceramic matrix composite part presenting a surface that is undulating and rough. The method includes forming a ceramic coating on the surface of the part, the coating being made by applying a liquid composition on the surface of the part, the composition containing a ceramic-precursor polymer and a factory solid filler, curing the polymer, and transforming the cured polymer into ceramic by heat treatment. The method further includes impregnating the ceramic coating with a liquid metallic composition.

Abstract: The invention relates to sputter targets and methods for depositing a layer from a sputter target. The method preferably includes the steps of: placing a sputter target in a vacuum chamber; placing a substrate having a substrate surface in the vacuum chamber; reducing the pressure in the vacuum chamber to about 100 Torr or less; removing atoms from the surface of the sputter target while the sputter target is in the vacuum chamber (e.g., using a magnetic field and/or an electric field). The deposited layer preferably is a molybdenum containing alloy including about 50 atomic percent or more molybdenum, 0.5 to 45 atomic percent of a second metal element selected from the group consisting of niobium and vanadium; and 0.5 to 45 atomic percent of a third metal element selected from the group consisting of tantalum, chromium, vanadium, niobium, and titanium.

Abstract: A multi-walled titanium-based nanotube array containing metal or non-metal dopants is formed, in which the dopants are in the form of ions, compounds, clusters and particles located on at least one of a surface, inter-wall space and core of the nanotube. The structure can include multiple dopants, in the form of metal or non-metal ions, compounds, clusters or particles. The dopants can be located on one or more of on the surface of the nanotube, the inter-wall space (interlayer) of the nanotube and the core of the nanotube. The nanotubes may be formed by providing a titanium precursor, converting the titanium precursor into titanium-based layered materials to form titanium-based nanosheets, and transforming the titanium-based nanosheets to multi-walled titanium-based nanotubes.

Abstract: Provided is a process for producing satisfactory particles held in porous silica. The process comprises (a) the step of preparing porous silica, (b) the step of bringing the porous silica into contact with a liquid which contains either a metal or a compound that has the metal as a component element and infiltrating the liquid into the pores of the porous silica, and (c) the step of subjecting, after the step (b), the impregnated porous silica to a heat treatment to thereby form fine particles comprising the metal or the metal compound in the pores of the porous silica. When porous silica is synthesized by hydrolyzing an alkoxysilane in a solvent-free system, it is possible to synthesize porous silica having a fine pore diameter. Use of this porous silica as a template facilitates formation of particles (e.g., W, Cu, Cr, Mn, Fe, Co, or Ni or an oxide of any of these metals) that show peculiar properties not observed in the bulk material.

Abstract: A coating method includes depositing substantially pure hafnium metal, that is free of other elements that are present in more than trace amounts as inadvertent impurities, onto a metallic substrate, and heat treating the metallic substrate to react the hafnium metal with at least one other element to form a protective coating on the metallic substrate.

Abstract: The system of the present invention includes a conductive element, an electronic component, and a partial power source in the form of dissimilar materials. Upon contact with a conducting fluid, a voltage potential is created and the power source is completed, which activates the system. The electronic component controls the conductance between the dissimilar materials to produce a unique current signature. The system can also measure the conditions of the environment surrounding the system.

Abstract: A method for modifying the probe tip of a microscope, including the following steps of providing a substrate, providing a metal precursor solution with fluoride ion on the substrate, using the probe tip to dip into the metal precursor solution with fluoride ion on the substrate in order to form a nano-metal particle on the probe tip by the reduction reaction of at least one metal ion in the metal precursor solution. As the result, the probe tip having the nano-metal particle thereon can increase the spatial-resolution of the measuring performance of the field sensitive scanning probe microscope due to the great reduction of stray field effects.

Abstract: A metal organic precursor, including a metal-chelate complex including a chelate including a Groups 3 to 12 metal ion, a chelating ligand, and an anion bound to the chelate, wherein the chelating ligand forms a reducing compound and a volatile material at a temperature of about 160° C. or lower, the anion forms a reducing compound and a volatile material at a temperature of about 180° C. or lower, and the metal-chelate complex is represented by Formula I: [L1-Me]pn+[A]qm???(I) wherein Me is the Groups 3 to 12 metal ion, L1 is the chelating ligand, A is the anion, n, m, p, and q are independently integers of 1 or more, n is the sum of a charge quantity of L1 and a charge quantity of Me, m is a charge quantity of A, and (n×p)=(m×q).

Abstract: A method of imparting high-temperature, degradation resistance to a metallic component involving applying a metal slurry comprising a Co-based metallic composition containing Co, Cr, Mo, Si, and B, a binder, and a solvent to a surface of the component, and sintering the Co-based metallic composition to form a substantially continuous Co-based alloy coating on the surface of the body.

Abstract: A palladium precursor composition includes at least one palladium salt and at least one fluorinated component, wherein if the fluorinated component is not a fluorinated organoamine, the composition further includes an organoamine, and if the fluorinated component is a fluorinated organoamine, the composition may optionally further include one or more additional fluorinated components. Further disclosed is a substantially pinhole-free palladium layer formed from the precursor composition.

Abstract: An infrared energy oxidizing and/or curing process includes an infrared oxidation zone having an infrared energy source operable to emit infrared energy that oxidizes a conductive thin film deposited or established on a glass substrate to establish a light transmissive or transparent conductive thin film for manufacturing of a touch panel. Optionally, the infrared energy curing process provides an in-line infrared energy curing process that oxidizes the conductive thin film on the glass substrate as the glass substrate is moved past the infrared energy source. Optionally, the infrared energy curing process bonds a thick film silver frit electrode pattern to the conductively coated glass substrate. Optionally, the infrared energy curing process reduces the transparent conductive thin film.

Abstract: The present disclosure is directed to cutting tools. The disclosed cutting tools may have a wear resistant coating on a substrate. The substrate may have hard particles cemented in a binder phase. The binder may have a near-surface concentration gradient of at least one platinum group element and/or rhenium. Processes for producing cutting tools are also disclosed.

Abstract: There is disclosed a gold surface for the catalytic release of hydrogen from an alkane thiol. More specifically, the present disclosure provides a large surface area of gold on a carbon fiber scaffold that does not contain any sublayers of metals that can block the catalytic release of hydrogen from alkane thiols or form other reactions that remove the sulfur moiety from alkane thiol. There is further disclosed a method for forming a gold surface onto woven carbon fiber sheets wherein no sublayer or other intermediate material is used.

Abstract: A carbon material and a method of manufacturing the same are provided that make it possible to form a layer of a metal that is highly reactive with carbon, such as tungsten, on a carbon substrate while at the same time inhibiting an increase in manufacturing cost and a degradation of processing accuracy. The carbon material has a carbon substrate 2, a first layer 12, and a second layer 13. The first layer contains a carbide of a transition metal. The second layer contains a second metal and/or a carbide of the second metal and a carbide of the transition metal, the second metal being at least one metal selected from the group of metals consisting of Group 4 elements, Group 5 elements, and Group 6 elements. The first and second layers are formed on a surface of the carbon substrate in that order.

Abstract: A coating method includes depositing a reactive material onto a turbine engine component using an ionic liquid that is a melt of a salt, and heat treating the turbine engine component to react the reactive material with at least one other element to form a protective coating on the turbine engine component.

Abstract: A method of manufacturing a decorative article, including a first coating formation step of forming a first coating of primarily TiN on a substrate; a second coating formation step of forming a second coating on the first coating by means of a dry plating method using a target containing 70.0 wt %?85.0 wt % Au and 15.0 wt %?30.0 wt % Cu; a heat treatment step of promoting formation of a solid solution of the constituents of the second coating by applying a heating process that heats the substrate on which the first coating and the second coating are disposed to 300° C.?395° C. and then applying a cooling process; and an acid treatment step that, of the constituents of the second coating to which the heating process was applied, removes the constituents not forming a solid solution by applying an acid treatment.

Abstract: A process for manufacturing electrodes for electrolysis, including the steps of forming an arc ion plating undercoating layer comprising valve metal or valve metal alloy including a crystalline tantalum component and a crystalline titanium component on the surface of the electrode substrate comprising valve metal or valve metal alloy, by an arc ion plating method; heat sintering the electrode substrate to transform only the tantalum component of the arc ion plating undercoating layer into an amorphous substance; and forming an electrode catalyst layer on the surface of the arc ion plating undercoating layer including the valve metal or valve metal alloy including the tantalum component transformed to the amorphous substance and the crystalline titanium component.

Abstract: Methods for coating wires to apply a silver cladding are disclosed herein. Silver nanoparticles are dispersed in a low surface tension solvent to form a coating solution. A wire is drawn through the coating solution to form a coating layer of silver nanoparticles on the wire. The coating layer is then annealed to form the wire with a silver cladding thereon.

Abstract: A method of manufacturing a carbon material that can prevent formation of unevenness of a coating film and degradation in adhesivity of the coating film, by inhibiting a carbon substrate from forming a portion in which a metal carbide layer is not formed. The method is characterized by including a first step of causing metal powder to adhere to a carbon substrate by coating the carbon substrate with a slurry containing the metal powder and polyvinyl alcohol as a binder, and a second step of heat-treating the carbon substrate to which the metal powder has adhered in a vessel containing an atmosphere of hydrogen chloride gas.

Abstract: A paste including metal or metal alloy particles (which are preferably silver or silver alloy), a dispersant material, and a binder is used to form an electrical, mechanical or thermal interconnect between a device and a substrate. By using nanoscale particles (i.e., those which are less than 500 nm in size and most preferably less than 100 nm in size), the metal or metal alloy particles can be sintered at a low temperature to form a metal or metal alloy layer which is desired to allow good electrical, thermal and mechanical bonding, yet the metal or metal alloy layer can enable usage at a high temperature such as would be desired for SiC, GaN, or diamond (e.g., wide bandgap devices). Furthermore, significant application of pressure to form the densified layers is not required, as would be the case with micrometer sized particles.

Abstract: An amorphous lithium lanthanum titanate (LLTO) thin film is produced by the sol-gel method wherein a polymer is mixed with a liquid alcohol to form a first solution. A second solution is then prepared by mixing a lanthanum alkoxide with an alcohol. The first solution is then mixed with the lanthanum based second solution. A lithium alkoxide and a titanium alkoxide are then also added to the lanthanum based second solution. This process produces a batch of LLTO precursor solution. The LLTO precursor solution is applied to a substrate to form a precursor layer which is then dried. The coating techniques that may be used include spin coating, spraying, casting, dripping, and the like, however, the spin coating technique is the preferred method recited herein.

Abstract: Accordingly, in various embodiments, the present invention provides methods for making electrochemically active materials. Methods include making an electrochemically active material by reacting a platinum group metal salt in a organic solvent to yield a mixture, then heating the mixture to create a metal-organic solvent complex and an acid, followed by removing at least a portion of the acid, and yielding an electrochemically active material comprising the metal-organic solvent complex. In an exemplary embodiment, the resulting electrochemically active material may be used for coating an electrode.

Abstract: The invention is directed to a method for producing Palladium alloy composite membranes that are useful in applications that involve the need to separate hydrogen from a gas mixture. The method includes providing a substrate for supporting a palladium alloy film, seeding the support surface with palladium crystallites to produce an activated surface, first plating, over the activated surface, a palladium film, second plating, over the palladium film, an alloying material other than silver, and annealing the porous substrate, palladium film, and alloying material so that there is intermetallic diffusion of the alloying material into the palladium film to produce a palladium alloy film over the porous substrate.

Abstract: A method for making a surface-enhanced Raman scattering (SERS) substrate is introduced. The method includes the following steps. A carbon nanotube film structure and a first solution comprising a number of metallic ions are provided. The carbon nanotube film structure includes a number of carbon nanotubes. Standard electrode potentials of the metallic ions are greater than Fermi energies of the carbon nanotubes. At least part of the carbon nanotube film structure is dipped into the first solution.

Abstract: Organometallic coatings or films, substrates coated with such films and methods for applying the films to the substrates are disclosed. The organometallic film or coating is derived from a transition metal compound containing both halide ligands and alkoxide ligands. Coated articles comprising polymer substrates and adhered to the substrate surface an organometallic film in which the metal comprises halide and alkoxide ligands are also disclosed.

Abstract: A gas separation membrane and a method of manufacturing such gas separation membrane that comprises a porous substrate treated with a layer of metal-coated inorganic oxide particles and with the layer of such metal-coated inorganic oxide particles being coated with an overlayer of a gas-selective material.

Abstract: A catalyst support is made by coating a metal substrate with a solution containing a precursor for a ceramic and an amphiphilic compound, and treating the coating such that it forms a micelle structure. The coating is then treated to form a mesoporous ceramic coating on the metal substrate. The micelle structure acts as a template, so that the pores are of regular size. The active catalytic material can then be deposited in the pores. The metal substrate may for example be a corrugated foil, which can enable reaction heat to be dissipated from hot spots.

Abstract: A method of manufacturing such gas separation membrane system that includes applying to a surface of a porous substrate a layer of a nanopowder of a gas-selective metal and, thereafter, heat-treating the resultant surface treated porous substrate to yield a heat-treated and surface-treated porous substrate suitable for use as a gas separation membrane system.

Abstract: A metal organic precursor, including a metal-chelate complex including a chelate including a Groups 3 to 12 metal ion, a chelating ligand, and an anion bound to the chelate, wherein the chelating ligand forms a reducing compound and a volatile material at a temperature of about 160° C. or lower, the anion forms a reducing compound and a volatile material at a temperature of about 180° C. or lower, and the metal-chelate complex is represented by Formula I: [L1-Me]pn+[A]qm???(I) wherein Me is the Groups 3 to 12 metal ion, L1 is the chelating ligand, A is the anion, n, m, p, and q are independently integers of 1 or more, n is the sum of a charge quantity of L1 and a charge quantity of Me, m is a charge quantity of A, and (n×p)=(m×q).

Abstract: A structure and method for forming a relatively thin diffusion barrier/seed bilayer for copper metallization in an electronic device is disclosed. A single layer of an alloy is formed over a dielectric (and possibly the copper layer). The alloy includes a copper platable metal (e.g., ruthenium) and a nitride forming material (e.g., tungsten) and nitrogen. The alloy layer is annealed, and the alloy naturally segregates into two layers. The first layer is a barrier layer including the nitride forming material and nitrogen. The second layer is a seed layer including the copper platable metal.

Abstract: A graphite-particles-dispersed composite produced by compacting graphite particles coated with a high-thermal-conductivity metal such as silver, copper and aluminum, the graphite particles having an average particle size of 20-500 ?m, the volume ratio of the graphite particles to the metal being 60/40-95/5, and the composite having thermal conductivity of 150 W/mK or more in at least one direction.

Abstract: A method for spalling a layer from an ingot of a semiconductor substrate includes forming a metal layer on the ingot of the semiconductor substrate, wherein a tensile stress in the metal layer is configured to cause a fracture in the ingot; and removing the layer from the ingot at the fracture. A system for spalling a layer from an ingot of a semiconductor substrate includes a metal layer formed on the ingot of the semiconductor substrate, wherein a tensile stress in the metal layer is configured to cause a fracture in the ingot, and wherein the layer is configured to be removed from the ingot at the fracture.

Abstract: A process for manufacturing electrodes for electrolysis, including steps of forming an arc ion plating (AIP) undercoating layer including valve metal or valve metal alloy containing a crystalline tantalum component and a crystalline titanium component on a surface of the electrode substrate comprising valve metal or valve metal alloy, by an arc ion plating method; heat sintering, including the steps of coating a metal compound solution, which includes valve metal as a chief element, onto the surface of the AIP undercoating layer, followed by heat sintering to transform only the tantalum component of the AIP undercoating layer into an amorphous substance, and to form an oxide interlayer, which includes a valve metal oxides component as a chief element, on the surface of the AIP undercoating layer containing the transformed amorphous tantalum component and the crystalline titanium component; and forming an electrode catalyst layer on the surface of the oxide interlayer.

Abstract: A process for protecting a thermal barrier coating (TBC) on a component used in a high-temperature environment, such as the hot section of a gas turbine engine. The process applies a protective film on the surface of the TBC to resist infiltration of contaminants such as CMAS that can melt and infiltrate the TBC to cause spallation. The process generally entails applying to the TBC surface a metal composition containing at least one metal whose oxide resists infiltration of CMAS into the TBC. The metal composition is applied so as to form a metal film on the TBC surface and optionally to infiltrate porosity within the TBC beneath its surface. The metal composition is then converted to form an oxide film, with at least a portion of the oxide film forming a surface deposit on the TBC surface.

Abstract: A method for manufacturing a metal-carrying carbonaceous material is provided. The method comprises immersing a carbonaceous material in a metal-containing aqueous solution under vacuum, with stirring, and/or in the presence of a polar solvent, and then thermally treating the immersed carbonaceous material at a temperature ranging from 120° C. up to a temperature not higher than the melting point of the involved metal under vacuum or in the presence of a protective gas. According to the method, the metal can be effectively carried on a carbonaceous material so as to enhance the applicability of the metal-carrying carbonaceous material.

Abstract: An aqueous phosphoric bonding solution consists essentially of phosphoric acid, a source of magnesium ions, and a leachable corrosion inhibitor. The bonding solution is stable with respect to inorganic metal particles, such as aluminum, which are admixed to the bonding solution for the preparation of a coating slurry. Metal parts coated with the coating compositions have very satisfactory properties such as heat and corrosion resistance.

Abstract: A gas separation membrane and a method of manufacturing such gas separation membrane that comprises a porous substrate treated with a layer of metal-coated inorganic oxide particles and with the layer of such metal-coated inorganic oxide particles being coated with an overlayer of a gas-selective material.

Abstract: An electrode for hydrogen generation can maintain a low hydrogen overvoltage for a long period of time even when electrolysis is conducted there not only with a low current density but also with a high current density. The electrode for hydrogen generation has a coating layer formed on a conductive base member by applying a material not containing any chlorine atom prepared by dissolving lanthanum carboxylate in a nitric acid solution of ruthenium nitrate and thermally decomposing the material in an oxygen-containing atmosphere.

Abstract: A method for fabricating a thermal optical heating element capable of adjusting refractive index of an optical waveguide is disclosed. A silicon block is initially formed on a cladding layer on a silicon substrate. The silicon block is located in close proximity to an optical waveguide. A cobalt layer is deposited on the silicon block. The silicon block is then annealed to cause the cobalt layer to react with the silicon block to form a cobalt silicide layer. The silicon block is again annealed to cause the cobalt silicide layer to transform into a cobalt di-silicide layer.

Abstract: Iridescent magnetic pigments are produced by depositing a ferrite layer and a second metal oxide layer in succession on a substrate. The substrate may be platy and is coated with the ferrite, which is then coated with the second metal oxide layer to provide interference color effect. At least one of the layers is magnetic. The magnetic pigment may be used in coatings such as paints.

Abstract: A method for manufacturing metallized aluminum nitride substrate. The method includes: Step A for forming a high-melting point metal layer over a sintered aluminum nitride substrate; Step B for forming over the high-melting point metal layer an intermediate metal layer of at least one selected from the group of: nickel, copper, copper-silver, copper-tin, and gold by plate processing; and Step C for forming a surface metal layer containing silver as a main component over the intermediate metal layer by coating a silver paste whose glass component content is 1 mass % or less and firing under nonoxidizing atmosphere. By this method, it is capable of forming a glass component-free silver layer which is adhered at a high degree of adhesion strength onto the high-melting point metal layer formed over the aluminum nitride substrate as a top face by thick-film method using a silver paste which makes thick-membrane forming easier.

Abstract: An exhaust gas purifying catalyst 1 has a composite compound 2 in which a metal selected from among Al, Ce, La, Zr, Co, Mn, Fe, Mg, Ba and Ti is uniformly dispersed on an oxide selected from among Al2O3, ZrO2 and CeO2, and a precious metal 4 selected from among Pt, Pd and Rh, supported on a compound 3 of the metal, and covered with the composite compound 2.

Abstract: A method for making a thermal interface material includes the steps of: (a) providing an array of carbon nanotubes formed on a substrate, the carbon nanotubes having interfaces defined therebetween; (b) providing a transferring device and disposing at least one low melting point metallic material above the array of carbon nanotubes, using the transferring device; and (c) heating the low melting point metallic material and the array of carbon nanotube to a certain temperature to make the at least one low melting point metallic material melt, then flow into the interspaces between the carbon nanotubes, and combine (e.g., mechanically) with the array of carbon nanotubes to acquire a carbon-nanotube-based thermal interface material.

Abstract: A method for making a gas turbine engine turbine blade comprising an airfoil section a platform section, an under platform section, and a dovetail section, the exterior surface of the dovetail section comprising a shank exterior surface and a serrated exterior surface. The blade further includes a silicon-modified diffusion aluminide layer a surface of a turbine blade section selected from the group consisting of the exterior surface of the under platform section, the exterior surface of the dovetail section, and combinations thereof, the aluminide layer having a concentration of silicon at a surface of the aluminide layer in the range of about 1 weight percent to about 10 weight percent and a concentration of aluminum at the surface of the aluminide layer in the range of about 5 weight percent to about 25 weight percent.

Abstract: Rare earth compositions comprising nanoparticles are described along with various nanotechnology applications of such nanoparticles. The compositions of the nanomaterials discussed may include scandium (Sc), yttrium (Y), lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu).

Abstract: A paste including metal or metal alloy particles (which are preferably silver or silver alloy), a dispersant material, and a binder is used to form an electrical, mechanical or thermal interconnect between a device and a substrate. By using nanoscale particles (i.e., those which are less than 500 nm in size and most preferably less than 100 nm in size), the metal or metal alloy particles can be sintered at a low temperature to form a metal or metal alloy layer which is desired to allow good electrical, thermal and mechanical bonding, yet the metal or metal alloy layer can enable usage at a high temperature such as would be desired for SiC, GaN, or diamond (e.g., wide bandgap devices). Furthermore, significant application of pressure to form the densified layers is not required, as would be the case with micrometer sized particles.

Abstract: A method of forming a hydrogen transport membrane to separate hydrogen from a hydrogen containing feed in which a porous ceramic support is formed to support a dense layer of palladium or an alloy of palladium serving as a hydrogen transport material. Isolated deposits of palladium, a palladium alloy or a component of such alloy are produced on a surface of the porous ceramic support that bridge pores within the porous ceramic support without penetrating the pores and without bridging regions of the surface defined between the pores. The isolated deposits of the metal are produced by an electroless plating process.