Cross-linked Or Infusible Coating Patents (Class 427/388.2)
  • Patent number: 8142897
    Abstract: The invention relates to an aqueous, chromium-free and curable corrosion protection agent for the first coating of metal surfaces, said agent containing at least one organic polymer or copolymer of at least partially acylated vinyl amines, for improving the properties of adhesion of the cured first coating to the metallic surface and to further organic coatings. The invention also relates to a method for producing a first coating comprising the agent according to the invention, and for applying further organic coatings, in particular those based on polyurethane resins and/or based on isocyanates and diols or polyols, and to a metal strip produced in this way or a metal sheet cut off same, which can optionally be shaped.
    Type: Grant
    Filed: April 27, 2011
    Date of Patent: March 27, 2012
    Assignee: Henkel KGaA
    Inventors: Andreas Schmidt, Ard De Zeeuw
  • Patent number: 8137755
    Abstract: The invention is a high-strength, pre-coated, aluminum or aluminum-alloy component comprising an aluminum or aluminum-alloy article having ultra-fine, submicron grain microstructure and an organic coating of phenolic resin applied to the surface of the article. The article is prepared from a coarse grain aluminum or aluminum-alloy material that is cryomilled into an ultra-fine, submicron grain material, degassed, and densified. The densified material is formed into an article, and coated with an organic coating containing phenolic resin prior to installation or assembly.
    Type: Grant
    Filed: April 20, 2005
    Date of Patent: March 20, 2012
    Assignee: The Boeing Company
    Inventors: Steven G. Keener, Patrick B. Berbon
  • Patent number: 8133541
    Abstract: This invention relates to hydroxyalkylated chitosan solution characterized in that a hydroxyalkylated chitosan and an organic acid or its derivative are contained in an aprotic polar solvent. This invention also relates to a coating process of a substrate, which is characterized by a step of causing the hydroxyalkylated chitosan solution to adhere onto a surface of the substrate, and another step of heating the substrate, which has been obtained in the first-mentioned step, at 100° C. or higher for 1 second or longer. This invention can provide a one-pack solution of a chitosan derivative, which is free from crosslinking and stable at room temperature, can form a chitosan coating excellent in waterproofness after heated and dried, and is suited for the coating of a hydrophobic or lipophilic surface. This invention also provides a coating process of a substrate, which makes use of the one-pack solution.
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: March 13, 2012
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Shinya Tsuchida, Nobuyuki Kobayashi, Takanori Sannan
  • Publication number: 20120042694
    Abstract: An acrylate-based curable printing medium is disclosed. Acrylates, in the form of monomers, dimers, trimers and oligomers, as well as resins, form an interpenetrating polymer network by crosslinking, which is effected by heat, and optionally peroxide curing agents. Formulations can be tailored to achieve desired properties of the cured polymer including film hardness, burnout properties, and adhesion to glass. Such properties are adjusted by manipulating the relative proportions of the acrylic monomers, oligomers and resins that are used as a ceramic medium or vehicle.
    Type: Application
    Filed: August 18, 2010
    Publication date: February 23, 2012
    Applicant: FERRO CORPORATION
    Inventors: Terry J. Brown, Kimberly Stewart, Thirumalai Duraisamy
  • Patent number: 8092770
    Abstract: This invention relates to an amorphous non-glassy ceramic composition that may be prepared by curing, calcining and/or pyrolyzing a precursor material comprising silicon, a Group III metal, a Group IVA metal, and/or a Group IVB metal.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: January 10, 2012
    Assignee: Sigma-Aldrich Co. LLC
    Inventors: William R. Betz, Christopher M. Linton
  • Publication number: 20110274939
    Abstract: A hydrophilizing agent that maintains a favorable wettability for dew condensation even after a long-term use; a hydrophilizing method; and an aluminum-containing metal material treated by the hydrophilizing method and having excellent wettability for dew condensation are provided. The hydrophilizing agent contains a modified polyvinyl alcohol obtained by graft polymerization of at least one type of N-vinyl lactam onto polyvinyl alcohol, thereby having a polymer and/or copolymer of the N-vinyl lactam in a side chain and a water-soluble cross-linking agent which can bind to a lactam moiety and/or a hydroxyl group of the modified polyvinyl alcohol. By applying and drying the hydrophilizing agent, a hydrophilic film having excellent wettability for dew condensation is formed.
    Type: Application
    Filed: January 21, 2010
    Publication date: November 10, 2011
    Applicants: DENSO CORPORATION, NIHON PARKERIZING CO., LTD.
    Inventors: Toshihisa Kataoka, Shinji Aoyagi, Masato Otake
  • Patent number: 8053032
    Abstract: The invention relates to a method for production of a zeolite layer on a substrate containing metal, comprising the following method steps: production of an aqueous suspension, comprising several components, one component comprises at least one cross-linking element from the third, fourth or fifth main group of the periodic table, the substrate containing metal comprises at least one of the cross-linking elements, introduction of the substrate containing metal to the aqueous suspension, heating the aqueous suspension and the substrate containing the metal present therein for the in-situ crystallisation of a zeolite layer on the substrate containing metal, whereby the cross-linking elements in the substrate containing metal are extracted and included in the zeolite layer, a cross-linking element present in the suspension for formation of the zeolite layer is present at a concentration so low that a crystallisation in the suspension is largely or completely avoided and said element is principally provided by th
    Type: Grant
    Filed: October 29, 2005
    Date of Patent: November 8, 2011
    Assignee: SorTech AG
    Inventors: Wilhelm Schwieger, Selvam Thangaraj, Franziska Scheffler, Ralph Herrmann, Marthala Reddy, Walter Mittelbach, Jürgen Bauer, Ferdinand Schmidt, Hans-Martin Hennig
  • Patent number: 8039056
    Abstract: A polymer thin film in which cylindrical phases are distributed in a continuous phase and are oriented in a pass-through-direction of the film includes at least: a first block copolymer including at least a block chain A1, as a component of the continuous phase, composed of polymerized monomers a1, and a block chain B1, as a component of the cylindrical phases, composed of polymerized monomers b1; and a second block copolymer including at least a block chain A2, as a component of the continuous phase, composed of polymerized monomers a2, and a block chain B2, as a component of the cylindrical phases, composed of polymerized monomers b2, with the second copolymer having a degree of polymerization different from that of the first copolymer. A film thickness of the polymer thin film and an average center distance between adjacent cylindrical phases have a relation represented by a predetermined expression.
    Type: Grant
    Filed: January 25, 2008
    Date of Patent: October 18, 2011
    Assignee: Hitachi, Ltd.
    Inventors: Hirokazu Hasegawa, Mikihito Takenaka, Feng Chen, Hiroshi Yoshida
  • Patent number: 8012599
    Abstract: The surface-treated steel sheet has a zinc-based plated steel sheet, a surface-treatment coating being formed on the surface of the zinc-based steel sheet by applying and drying a surface treatment coating composition thereon, and a top coating being formed by applying and drying a coating composition for top coating on the surface-treatment coating. The surface treatment coating composition contains a water-epoxy resin dispersion, a silane coupling agent, and phosphoric acid and/or a hexafluorometal acid. The coating composition for top coating contains a high molecular weight epoxy group-containing resin having number average molecular weights ranging from 6000 to 20000.
    Type: Grant
    Filed: October 26, 2007
    Date of Patent: September 6, 2011
    Assignees: JFE Steel Corporation, Kansai Paint Co., Ltd.
    Inventors: Tatsuya Miyoshi, Kenichi Sasaki, Naoto Yoshimi, Akira Matsuzaki, Kazuhisa Okai, Takao Ooshima, Takashi Nakano, Masahiro Murata, Syoichi Tanaka
  • Publication number: 20110163106
    Abstract: Disclosed are Bisphenol A (BPA), Bisphenol F, Bisphenol A diglycidyl ether (BADGE), and Bisphenol F diglycidyl ether (BFDGE)-free coating compositions for metal substrates including an under-coat composition containing a polyester (co)polymer, and an under-coat cross-linker; and an over-coat composition containing a poly(vinyl chloride) (co)polymer dispersed in a substantially nonaqueous carrier liquid, an over-coat cross-linker, and a functional (meth)acrylic (co)polymer. Also provided is a method of coating a metal substrate using the BPA, BPF, BADGE and BFDGE-free coating system to produce a hardened protective coating useful in fabricating metal storage containers. The coated substrate is particularly useful in fabricating multi-part foodstuffs storage containers with “easy-open” end closures.
    Type: Application
    Filed: March 18, 2011
    Publication date: July 7, 2011
    Applicant: VALSPAR SOURCING, INC.
    Inventors: Peter Mayr, Paul R. Cooke, Trevor Alan Fielding, Ronald L. Goodwin, Gregory Paulson, James Robinson, Anthony Violleau
  • Publication number: 20110111130
    Abstract: The invention describes a method of coating coils, comprising the following steps: (1) applying an aqueous primer coating composition (B) comprising at least one crosslinkable binder system (BM), at least one filler component (BF), at least one corrosion control component (BK), and volatile constituents (BL), to the optionally cleaned metal surface, the coating composition (B) having an organic solvent content of not more than 15% by weight, based on the volatile constituents (BL) of the coating composition (B), (2) drying the integrated pretreatment film formed from the primer coating composition (B), (3) applying a topcoat film (D) to the integrated pretreatment film dried as per step (2), and (4) jointly curing the films of coating composition (B) and topcoat (D).
    Type: Application
    Filed: April 30, 2009
    Publication date: May 12, 2011
    Applicant: BASF COATINGS GMBH
    Inventors: Markus Hickl, Alexandra Steffens
  • Patent number: 7820227
    Abstract: A method for biolithographical deposition of molecules is provided. According to an embodiment of the method, a reactive layer (e.g., a polysaccharide mass) having a surface region coated with a biologically compatible resist is provided. A portion of the biologically compatible resist is selectively removed to expose an exposed portion of the reactive layer. Molecules, such as biomolecules and/or cellular species, are then conjugated to the exposed portion of the reactive layer. Also provided are materials and devices related to the method.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: October 26, 2010
    Assignees: University of Maryland, College Park, University of Maryland, Baltimore County
    Inventors: Gregory F. Payne, Gary W. Rubloff, Hyunmin Yi, Rohan Fernandes, Li-Qun Wu, Reza Ghodssi, William E. Bentley
  • Publication number: 20100266855
    Abstract: The present invention relates to an adhesion-promoting agent that contains at least 1.5 isocyanate groups per molecule and at least one urea linked silane group, coating compositions containing the adhesion promoting agent and methods for adhering protected coatings to a substrate. The adhesion-promoting agent is especially useful as an additive to the crosslinking component of a two component coating composition. The coating composition is especially useful for use as a protective coating on a previously coated or uncoated substrate such as an automobile.
    Type: Application
    Filed: December 22, 2008
    Publication date: October 21, 2010
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventor: David M. Zukowski
  • Publication number: 20100252310
    Abstract: A crosslinkable and polymerizable composition containing a monomer and a cross-linking agent is applied onto a metal foil to form a coated film of the composition, and heat is applied to the coated film to firstly bulk polymerize the entire coated film of the crosslinkable and polymerizable composition. Then, by applying heat to the coated film from the metal foil side, cooling a surface far from the metal foil as needed, and subjecting a limited region adjacent to the metal foil in the thickness direction of the coated film to a cross-linking reaction, a composite for multilayer circuit board is obtained, in which the metal foil layer, a hard resin layer containing a hard resin obtained by bulk polymerization reaction and cross-linking reaction, and an adhesive resin layer containing an adhesive resin obtained by bulk polymerization reaction are laminated in this order.
    Type: Application
    Filed: July 25, 2008
    Publication date: October 7, 2010
    Inventors: Kiyoshige Kojima, Junji Kodemura
  • Publication number: 20100255206
    Abstract: The present invention relates to a method of applying atmospheric corrosion control coats to metallic surfaces, using copolymers comprising as monomeric building blocks monomers containing nitrile groups, monomers containing acidic groups, and vinylaromatic monomers. It relates, furthermore, to preparations for applying corrosion control coats.
    Type: Application
    Filed: June 18, 2008
    Publication date: October 7, 2010
    Applicant: BASF SE
    Inventors: Guido Vandermeulen, Konrad Roschmann, Stephan Amthor, Marc Schroeder, Alexsandro Berger, Frank Klippel
  • Patent number: 7799386
    Abstract: Method for production of a coating on a solid substrate comprising the steps of applying a liquid coating composition comprising a polyfunctional resin, a fatty acid or derivative thereof acting as a reactive diluent and optionally a curing agent and/or one or more additives, wherein the resin comprises functional groups capable of reacting with carboxyl or acyl groups of the fatty acid or derivative thereof, onto the substrate, and curing the coating by heat activation. The invention further relates to the liquid coating composition as well as a substrate comprising a coating obtained by heat activation of such a coating composition.
    Type: Grant
    Filed: November 25, 2004
    Date of Patent: September 21, 2010
    Assignee: Svenska Lantmannen ek for
    Inventors: Mats K. G. Johansson, Martin Svensson, Per-Erik Sundell
  • Patent number: 7790222
    Abstract: A method for producing a cable including at least one transmissive element, for example, an element transmitting electrical energy or optionally optical signals as well, and an expanded and cross-linked coating layer in a radially outer position with respect to the at least one transmissive element, the coating layer having a composition including an expandable and cross-linkable polymeric material. The method includes a) extruding the composition; b) forming a coating layer made of expandable and cross-linkable polymeric material with the composition thus extruded; c) expanding the coating layer made of expandable and cross-linkable polymeric material; and d) cross-linking the coating layer made of expandable and cross-linkable polymeric material. The expanding and cross-linking steps c) and d) are carried out by heating the coating layer made of expandable and cross-linkable polymeric material at atmospheric pressure by means of a suitable heating fluid.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: September 7, 2010
    Assignee: Prysmian Cavi e Sistemi Energia S.R.L.
    Inventors: Luca Balconi, Alberto Bareggi, Sergio Belli
  • Publication number: 20100166972
    Abstract: The present invention discloses an aqueous coating composition, comprising: (A) a water-soluble resin and (B) a cross-linking agent. The water-soluble resin after amination is evenly dispersed in a water-soluble solvent and the water-soluble resin is selected from the group consisting of the following or combination thereof: acrylic resin, alkyd resin, epoxy resin, polyurethane resin and polyester resin. The cross-linking agent at least has the function of promoting the reaction and enhancing the interaction force between the water-solution resin and a coating substrate. The function of the cross-linking agent is to have the water-soluble resin be dried naturally or compulsorily.
    Type: Application
    Filed: December 4, 2009
    Publication date: July 1, 2010
    Applicants: Huai Mao Corporation, Dongweipaint Co., Ltd. Of Foshan City
    Inventors: JUNG-HUA WENG, YU-CHIH WANG, SUNG-YI WENG, CHENG-HUNG WENG
  • Patent number: 7740790
    Abstract: A method of making a thermotropic liquid crystal polymer film includes continuously heat treating of the thermotropic liquid crystal polymer film 2 while the latter is jointed to a sheet-like support member 4, and subsequently separating the heat-treated thermotropic liquid crystal polymer film 2 from the support member 4. The continuous heat treatment of the thermotropic liquid crystal polymer film 2 then jointed to the support member 4 is carried out for a predetermined heating time within the range of 5 to 60 seconds at a predetermined heating temperature T° C. equal to or higher than the melting point Tm° C. of the thermotropic liquid crystal polymer film less 15° C. (i.e., Tm?15° C.), but lower than the melting point Tm° C. (thus, Tm?15° C.?T° C.<Tm° C.), to thereby increase the thermal expansion coefficient of the thermotropic liquid crystal polymer film.
    Type: Grant
    Filed: September 23, 2004
    Date of Patent: June 22, 2010
    Assignee: Kuraray Co., Ltd.
    Inventors: Minoru Onodera, Tatsuya Sunamoto
  • Patent number: 7722922
    Abstract: An coating apparatus, wherein the apparatus applies a coating, onto a surface of an aluminum alloy member for a heat exchanger to be assembled by brazing, with a top-feed-type roll transfer system having at least three rolls, the coating being obtained by mixing into an organic binder a metal powder, a flux powder, a powder mixture thereof, or a compound containing a metal component and a flux component, wherein rotation directions of transfer rolls of the apparatus arranged above a surface to be coated of an aluminum alloy extruded member that moves in a horizontal direction, satisfy a relationship in which a rotation direction of a coated-metal roll for coating, which rotates in a direction opposite to a moving direction of the extruded member, and a rotation direction of a metal roll for adjusting an adhesion amount of the coating by contacting with the above roll, are opposite to each other; and a method of producing an aluminum alloy heat exchanger member using the apparatus; and an aluminum alloy heat e
    Type: Grant
    Filed: April 17, 2006
    Date of Patent: May 25, 2010
    Assignee: Furukawa-Sky Aluminum Corp.
    Inventors: Hirokazu Yamaguchi, Toshiki Maezono, Takashi Kashima, Masami Kojima, Yoji Hirano
  • Publication number: 20100124615
    Abstract: A process for producing a crosslinkable resin formed product is disclosed which comprises providing a polymerizable composition containing a cycloolefin monomer, a metathesis polymerization catalyst, a chain transfer agent, and a crosslinking agent, and heating the polymerizable composition to 50° C. or more to effect ring-opening metathesis bulk polymerization, the temperature of the polymerizable composition before heating being maintained at ?10° C. to +20° C. According to the present invention, a process for efficiently producing a crosslinkable resin formed product which exhibits excellent flowability when melted by heat and does not produce voids(blurs) inside a laminate or impair flatness when laminated on a substrate is provided.
    Type: Application
    Filed: February 6, 2007
    Publication date: May 20, 2010
    Applicant: ZEON CORPORATION
    Inventors: Tomoyoshi Ohtaki, Kazuyuki Onishi, Narumi Suzuki, Kiyoshige Kojima, Junji Kodemura
  • Patent number: 7713585
    Abstract: The invention relates to the use of a composition comprising a chlorinated polyester resin in which the polyester satisfies formula (I) below: together with a crosslinking catalyst and a crosslinking accelerator in order to plug a crack affecting the wall of a metal device intended to contain a radioactive acid material. It is especially applicable in the maintenance of metal equipment of nuclear installations, in particular equipment that is for irradiated nuclear fuel reprocessing.
    Type: Grant
    Filed: February 20, 2006
    Date of Patent: May 11, 2010
    Assignees: Commissariat a l'Energie Atomique, Compagnie Generale des Matieres Nucleaires
    Inventors: David Descarsin, Jacques Raby, Raphael Robin, Christelle Vittoz
  • Publication number: 20100092664
    Abstract: A self curing, two component penetrating densifying sealant and coating composition that imparts protection and reinforcement to porous substrates, such as wood and concrete, as well as non porous substrates, such a metal surfaces, whether or not corroded, and concrete surfaces.
    Type: Application
    Filed: October 10, 2008
    Publication date: April 15, 2010
    Inventors: Simon Palushaj, Ronald J. Lewarchik
  • Patent number: 7674498
    Abstract: Porous ceramic catalyst supports or filters to be provided with catalyst coatings via oxide washcoating processes are pre-coated with cross-linked polymer barrier layers to prevent washcoat nanoparticle intrusion into the microcracked and/or microporous surfaces of the ceramics, the barrier coatings being formed by thermally cross-linking hydrocarbon polymers that are vaporizable at moderate washcoat stabilization or catalyst activation temperatures and that preferentially block the micropore/microchannel pore volume of the article.
    Type: Grant
    Filed: August 3, 2006
    Date of Patent: March 9, 2010
    Assignee: Corning Incorporated
    Inventors: Tinghong Tao, Jianguo Wang
  • Patent number: 7674874
    Abstract: Methods of making a coating composition including a film-forming material having a covalently bonded phosphorous atom, the phosphorous atom having at least one covalently bonded oxygen atom. Coating compositions can be used to coat a substrate, such as a metal substrate, by electrodeposition. Applied coatings containing the film-forming resins can be cured to form crosslinked films on substrates.
    Type: Grant
    Filed: February 8, 2007
    Date of Patent: March 9, 2010
    Assignee: BASF Coatings AG
    Inventors: Sergio Gonzalez, Timothy S. December
  • Publication number: 20100028697
    Abstract: The present invention relates to the use of branched, amorphous, polyester-based macropolyols for coating metal strips, to methods of coating metal strips and to the coated metal strips thus obtained. The coating comprises branched polyesters having trifunctional branching agent contents of between 10 and 25 mol %, based on the alcohol component, and the molecular weight of the polyester is between 2500 and 4500 g/mol.
    Type: Application
    Filed: September 13, 2007
    Publication date: February 4, 2010
    Applicant: EVONIK DEGUSSA GmbH
    Inventors: Rene Koschabek, Martin Bartmann, Thorsten Brand, Andreas Schubert
  • Patent number: 7655279
    Abstract: The present invention relates to a composition for treating surfaces, comprising a copolymer as component A, synthesized from (meth)acrylic acid or salts thereof, a carboxylate-containing monomer and/or monomers containing groups containing phosphoric and/or phosphonic acid or salts thereof, and further comonomers if desired, to a passivating layer on a metal surface, which comprises component A, to a process for forming said passivating layer, and to the use of the composition of the invention to passivate a metal surface.
    Type: Grant
    Filed: February 19, 2004
    Date of Patent: February 2, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Frank Dietsche, Helmut Witteler, Matthias Klüglein, Frank Klippel
  • Patent number: 7651735
    Abstract: Methods and a structure. A first film of a first block copolymer is formed inside a trough integrally disposed on an energetically neutral surface layer of a substrate. Line-forming microdomains are assembled of the first block copolymer, and form first self-assembled structures within the first film normal to the sidewalls and parallel to the surface layer. At least one microdomain is removed from the first film such that oriented structures remain in the trough oriented normal to the sidewalls and parallel to the surface layer. A second film of a second block copolymer is formed inside the trough. Line-forming microdomains are assembled of the second block copolymer, and form second self-assembled structures within the second film oriented normal to the oriented structures and parallel to the sidewalls. A second method and a structure are also provided.
    Type: Grant
    Filed: April 3, 2008
    Date of Patent: January 26, 2010
    Assignee: International Business Machines Corporation
    Inventors: Joy Cheng, Ho-Cheol Kim, Robert D. Miller
  • Publication number: 20090324983
    Abstract: A composition for coating metal surfaces based on crosslinking polyester resins as an organic constituent, which, based on its total mass, contains from 4 to 20% by weight of aluminum flakes and not more than 0.1% by weight of compounds containing isocyanate groups. The composition preferably comprises, as an organic binder, at least one hydroxylated polyester resin, preferably having a mean molar mass in the range from 2000 to 15,000, a crosslinking component for the hydroxylated polyester resin and an acidic crosslinking catalyst. A process for applying the composition to metal strip in a belt process is likewise disclosed. The layer application is adjusted within the range from 3 to 30 ?m according to the end use, for which double coating may be advantageous. For example, the composition may serve as a “galvanization replacement”.
    Type: Application
    Filed: June 26, 2009
    Publication date: December 31, 2009
    Applicant: Henkel AG & Co. KGaA
    Inventors: Karsten Hackbarth, Wolfgang Lorenz, Eva Wilke, Marcel Roth, Reiner Wark, Stephan Müller, Guadalupe Sanchis Otero, Manuela Göske-Krajnc, Andreas Kunz
  • Publication number: 20090324974
    Abstract: A process for coating a metallic surface of an aircraft. The process includes applying to the metallic surface a composition that polymerizes to form a polyurea having a tensile strength of more than 3500 psi and at least 700% elongation. The polyurea can be formed from an A-side and a B-side, where the weight percents of components for the A-side are: from about 30 to about 65 percent of polyisocyanate; from about 15 to about 70 percent of a polytetramethylene ether glycol; diluent, from 0 to about 20 percent; where the weight percents of components for the B-side are: from 35 to about 40 percent of one or more aromatic diamines; from about 20 to about 70 percent of one or more amine terminated polyether polyols.
    Type: Application
    Filed: May 15, 2008
    Publication date: December 31, 2009
    Inventor: John W. Bulluck
  • Patent number: 7629029
    Abstract: Compositions and methods of preparing functional thin films or surface coatings with low non-specific binding are described. The thin films contain specified functional groups and non-specific binding repellant components. The thin films are either covalently bound to or passively adsorbed to various solid substrates. The specified functional group provides specified activity for the thin film modified solid surfaces and non-specific binding repellant components significantly reduce the non-specific binding to the thin film modified solid surfaces. Non-specific binding repellant components do not affect specified functional group's activity in the thin films. In these methods, specified functional groups are anchored to the solid substrates through a spacer.
    Type: Grant
    Filed: October 13, 2004
    Date of Patent: December 8, 2009
    Assignee: Accelr8 Technology Corporation
    Inventors: Guoqiang Mao, Steven W. Metzger, Michael J. Lochhead
  • Publication number: 20090246545
    Abstract: There are provided: a method for forming a shining coating film which can form a coating film extremely excellent in a leveling property and a brightness with good workability and can also realize the reduction of environmental burden; and a coated article excellent in a design property obtained by this method. In a method comprising the steps of sequentially coating a shining material-containing solvent type first base coat coating, a shining material-containing solvent type second base coat coating and a top clear coating onto a base material and baking a formed multilayered coating film at the same time, an improvement is made so that the resin composition and coating nonvolatile concentration of the first and second base coat coatings and the amount of nonvolatiles in the first and second base coating films will have specific conditions.
    Type: Application
    Filed: February 24, 2009
    Publication date: October 1, 2009
    Applicants: HONDA MOTOR CO., LTD., NIPPON PAINT CO., LTD., NIPPON BEE CHEMICAL CO., LTD.
    Inventors: Emi Nomi, Takeshi Ogawa, Atsuo Magoshi, Koji Nakajima, Masanobu Inoue, Yoshiki Takaira
  • Publication number: 20090214883
    Abstract: Chromium-free, curable corrosion protection composition for primary coating of metallic substrates, which has a pH in the range from 1 to 3 and contains water and a) fluorocomplex ions of titanium and/or zirconium, b), at least one corrosion protection pigment, c) at least one organic polymer which is soluble or dispersible in water in the specified pH range and on its own in aqueous solution at a concentration of 50% by weight has a pH in the range from 1 to 3, process for treating metal strip with this composition and treated metal strip which can be obtained in this way. The organic polymer c) is preferably selected so that it contains at least one monomer selected from among acrylic acid, methacrylic acid, acrylic esters and methacrylic esters as free-radically polymerizable, ethylenically unsaturated monomers and has at least one type of functional groups selected from among epoxy, silane, hydroxy, carboxyl, phosphoric acid and phosphoric ester groups.
    Type: Application
    Filed: February 23, 2009
    Publication date: August 27, 2009
    Inventors: Ard De Zeeuw, Marcel Roth, Jorg Sander
  • Patent number: 7550176
    Abstract: The present invention provides a method of forming a coating film on an aluminum substrate, comprising the steps of: (1) coating an aluminum substrate with a thermosetting polyester resin lustrous powder base coating composition (a) containing a lustrous material, and baking the resulting base coat layer; and (2) coating the base coat layer with a thermosetting acrylic resin clear powder coating composition (b), and baking the resulting clear coat layer to obtain a lustrous multilayer coating film.
    Type: Grant
    Filed: December 19, 2003
    Date of Patent: June 23, 2009
    Assignees: Kansai Paint Co., Ltd., Toyota Jidosha Kabushiki Kaisha
    Inventors: Toshio Ohkoshi, Hiroki Takeda, Yoshinori Kato, Masahiro Nakamura, Masayoshi Harada, Manabu Imose
  • Patent number: 7517559
    Abstract: The present invention relates to inner coatings of metal food containers and packaging and to a process for their production. The coatings are applied to the inside of at least a portion of the surface area of containers that are in direct contact with foods or other consumable products and subsequently cured. The coatings include a) at least one polyisocyanate containing an average of at least two NCO groups per molecule, at least 95% of the NCO groups being blocked with a blocking agent, and b) at least one polyhydroxyl compound containing an average of at least two hydroxyl groups per molecule that react with NCO groups.
    Type: Grant
    Filed: October 20, 2004
    Date of Patent: April 14, 2009
    Assignee: Bayer MaterialScience AG
    Inventors: Christoph Thiebes, Beate Baumbach, Eduard Hänsel, Wolfram Küttner, Christian Wamprecht
  • Patent number: 7503381
    Abstract: There is disclosed a rust prevention and hydrophilization treatment method for a flux-brazed aluminum-made heat exchanger which comprises subjecting the same to a rust prevention treatment by the use of a zirconium base compound and/or a titanium base compound, and thereafter subjecting the same to a hydrophilization treatment by means of a hydrophilization treatment agent composition containing the under-mentioned components: (1) 40 to 90% by mass of polyvinyl alcohol having a degree of saponification of at least 90%; (2) 3 to 40% by mass of polyoxyalkylene-modified polyvinyl alcohol in which 0.01 to 20% of pendant groups are polyoxyalkylene ether groups; (3) 1 to 30% by mass of an inorganic cross-linking agent which reacts with hydroxyl groups of the polyvinyl alcohol and modified polyvinyl alcohol; and (4) 1 to 20% by mass of a guanidine compound and/or a salt thereof.
    Type: Grant
    Filed: August 4, 2005
    Date of Patent: March 17, 2009
    Assignees: Nippon Paint Co., Ltd., Denso Corporation
    Inventors: Toshio Inbe, Norizumi Matsui, Kengo Kobayashi, Osamu Kasebe
  • Publication number: 20090047449
    Abstract: Processes are disclosed for preparing a printable and printed articles by coating a substrate with a composition containing a crosslinkable amine functional polymer and a polyfunctional isocyanate blocked by a blocking agent. The coated substrate is heated to a sufficient temperature to deblock the blocked polyfunctional isocyanate and thereby produce a crosslinked hydrophobic, ink receptive polymer layer on the substrate. Printed articles are prepared by forming an image on the crosslinked hydrophobic, ink receptive layer. In a preferred embodiment, the crosslinked hydrophobic, ink receptive polymer composition is characterized by a solvent resistance fraction of at least 0.6 and a solvent absorbance capacity of at least 300. The substrate of the printed article is preferably polymer, metal, glass, or paper, more preferably polymer film. A process for preparing printable articles wherein the substrate is a fluoropolymer is especially preferred.
    Type: Application
    Filed: October 22, 2008
    Publication date: February 19, 2009
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventor: Larry Glen Snow
  • Patent number: 7482040
    Abstract: The invention relates to an enamel-like mixture containing resin and inorganic particles for applying a polymeric, corrosion-proof, wear-resistant, deformable and electrically conductive covering to a substrate. Said mixture contains at least 10 wt. % of electrically conductive particles having an electrical conductivity better than that of zinc particles and having a Moh's hardness greater than 4 with regard to the solids contents of the mixture. These electrically conductive particles have a particle size distribution in which 3 to 22 vol. % of the electrically conductive particles, measured with a Mastersizer 2000 equipped with measuring head Hydro 2000S of the company Malvern Instruments, are, in a volume representation, larger than the average layer thickness of the dried and, optionally, also hardened covering determined on recordings made using a scanning electron microscope.
    Type: Grant
    Filed: April 17, 2003
    Date of Patent: January 27, 2009
    Assignee: Chemetall GmbH
    Inventor: Georg Gros
  • Patent number: 7473439
    Abstract: Polymeric film structures incorporating at least one coating comprising a cross-linked EVOH copolymer and coating solutions suitable for use on polymeric films comprising at least one EVOH copolymer and at least one cross-linker are provided. The coated films may be single or multi-layered film structures. The films may also be metallized. The coated films exhibit beneficial water vapor and oxygen transmission rates. The coated films may also exhibit the beneficial barrier characteristics under conditions of high humidity. The coated films are suitable for packaging applications. The coating solutions exhibit beneficial stability characteristics over extended time periods.
    Type: Grant
    Filed: August 15, 2005
    Date of Patent: January 6, 2009
    Assignee: ExxonMobil Oil Corporation
    Inventors: Rhonda E. Rogers Agent, Bruno R. L. Gringoire
  • Patent number: 7470451
    Abstract: The invention relates to a binding agent composition, in particular an adhesive, containing at least one epoxy compound or at least one amino compound comprising at least two amino groups, or at least one hydroxy compound comprising at least two OH groups, or at least one mercapto compound comprising at least two mercapto groups, or at least one isocyanate comprising at least two NCO groups and a compound with chelating properties. The invention also relates to a method for producing binding agent compounds of this type and to the use of the same.
    Type: Grant
    Filed: July 30, 2002
    Date of Patent: December 30, 2008
    Assignee: Henkel AG & Co. KGaA
    Inventors: Rainer Schoenfeld, Gerald Schreiber, Felix Rustemeyer
  • Patent number: 7468197
    Abstract: Disclosed are a flexible metal-clad laminate comprising a metal foil and a heat-resistant resin film layer formed on one side of the metal foil, the heat-resistant resin film layer comprising a crosslinked condensation polymer and having an N-methyl-2-pyrrolidone-insolule content of at least 1%, and a method for producing the flexible metal-clad laminate comprising the steps of applying a heat-resistant resin solution to a metal foil; predrying the metal foil until the heat-resistant resin layer has an residual solvent content of 10 to 40% by weight; and carrying out solvent removal and heat-treatment while controlling the crosslinking reaction of the resin.
    Type: Grant
    Filed: August 11, 2006
    Date of Patent: December 23, 2008
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Tomoharu Kurita, Chyuji Inukai
  • Publication number: 20080311413
    Abstract: The invention provides a coating composition to coat electrical steel sheets, the composition comprising: A) 5 to 45 weight % of at least one binder resin, B) 0.1 to 40, preferably 1 to 30 weight % of nano scaled particles, the particles having an average radius ranging from 1 to 300 nm, C) at least one cross-linking agent in an amount able to cross-link with the binder resin, preferably 0.1 to 30 weight % of at least one cross-linking agent, D) 0.1 to 60 weight % of at least one additive and/or pigment and/or filler, and E) 5 to 70 weight % of water and/or at least one solvent, the weight % based on the total weight of the composition.
    Type: Application
    Filed: June 5, 2008
    Publication date: December 18, 2008
    Inventors: Frank-Rainer Boehm, Barbara Froschauer, Reinhard Wallner, Nicolas van Zijl
  • Publication number: 20080299343
    Abstract: The present invention relates to a composition, which is useful for producing coatings for metal sheet substrates of metal cans for storing and/or transporting food or beverages or a lid thereof, and which comprises the following components: (a) 30 to 90 wt. % of a polyvinylchloride-(PVC)-polymer, (b) 7 to 25 wt. % of an acrylic resin, (c) 3 to 40 wt. % of a crosslinking agent, which is produced from phenol, para-tert.-butylphenol, xylenol or a mixture thereof, and formaldehyde, (d) 0 to 8 wt. % additive, (e) 0 to 50 wt. % pigment and (f) a solvent-component, where all weight percentages are on the basis of the total dry weight of the coating composition (without solvents) and the composition is substantially free of bisphenol-A-diglycidyl-ether (“BADGE”) and also substantially free of bisphenol-A-resins. The composition provides metal can coatings that have suitable flexibility, scratch resistance, adherence and sterilization resistance when processed in contact with food.
    Type: Application
    Filed: May 7, 2008
    Publication date: December 4, 2008
    Inventors: Christian Vogt, Peter Ambrosi, Beate Ries
  • Patent number: 7390847
    Abstract: A composition for the treatment of metal surfaces and for the deposition of metals or metal alloys on plastics surfaces contains a) at least one polymer as component A, composed of the structural element (1) and at least three structural elements selected from the group consisting of b) water or another solvent which is suitable for dissolving, dispersing, suspending or emulsifying the polymer, as component B; c) if required, surface-active compounds, dispersants, suspending media and/or emulsifiers as component C. In a process for the treatment of a metal surface and a process for the deposition of metals or metal alloys on a plastics surface, the metal or plastics surface is brought into contact with a polymer (component A). Furthermore, polymers (component A) are used for the treatment of metal surfaces and for the deposition of metals or metal alloys on a plastics surface, and polymers composed of special components A?a, A?b and A?c.
    Type: Grant
    Filed: December 27, 2002
    Date of Patent: June 24, 2008
    Assignee: BASF SE
    Inventors: Monica Fernandez Gonzalez, Hans-Ulrich Jäger, Peter Neumann, Helmut Witteler
  • Patent number: 7338688
    Abstract: Protective liners or coatings for metal conduits, pipes and tanks subjected to corrosive liquids are disclosed. The liners comprise a composition containing a silylated copolymer of, for example, isobutylene and para-methylstyrene, which are curable by contact with moisture.
    Type: Grant
    Filed: April 8, 2002
    Date of Patent: March 4, 2008
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Hsien-Chang Wang, Wai Keung Wong
  • Patent number: 7335400
    Abstract: A method of irreversibly immobilizing an enzyme in a polyurethane and an enzyme-containing polyurethane having a degree of immobilization of the enzyme of approximately 100%. The synthesis of waterborne polyurethanes in the presence of enzyme has enabled the irreversible attachment of the enzyme to the polymeric matrix. The distribution of immobilized enzyme as well as activity retention are homogeneous within the polyurethane. Decreasing ECC hydrophobicity, via the use of a less hydrophobic polyisocyanate prepolymer during polymerization, significantly enhanced the intrinsic activity of the ECC.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: February 26, 2008
    Assignees: University of Pittsburgh, Bayer Material Science, LLC
    Inventors: Alan J. Russell, Geraldine F. Drevon, Douglas A. Wicks, Karsten Danielmeier
  • Patent number: 7329463
    Abstract: This invention relates to a low camping fluorocarbon thermoplastic random copolymer roller coating having a closely controlled curing agent content.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: February 12, 2008
    Assignee: Eastman Kodak Company
    Inventors: Jiann-Hsing Chen, Joseph A. Pavlisko, Robert A. Lancaster, Nataly Boulatnikov
  • Patent number: 6994888
    Abstract: A protective coating composition in an organic liquid carrier comprising a polymeric film forming binder, the polymeric binder comprising by weight: (a) 50% to 100% of an epoxy-polyester block copolymer being the reaction product of a preformed epoxy resin and a preformed carboxyl functional, and (b) 0 to 50% of a crosslinker where the sum of (a) and (b) is 100%, characterised in that the carboxyl functional polyester prepolymer is the reaction product of one or more polyols with one or more dicarboxylic acids or their anhydrides, where the dicarboxylic acids or anhydrides comprise a mixture of (i) 20% to 45% of an aromatic dicarboxylic acid or its anhydride, (ii) 55% to 80% of cyclohexane dicarboxylic acid, and (iii) 0 to 10% other aliphatic dicarboxylic acid, where the sum of (i), (ii), and (iii) is 100% based on the weight of the dicarboxylic acid and anhydride components.
    Type: Grant
    Filed: July 26, 2002
    Date of Patent: February 7, 2006
    Assignee: Imperial Chemical Industries PLC
    Inventor: Ronald Metcalfe
  • Patent number: 6984236
    Abstract: The above-discussed and other problems and deficiencies of the prior art are overcome or alleviated by the improved bone connective prosthesis and method of forming the same of the present invention, comprising the addition of at least one biocompatible metal coupling agent to a prosthetic element, and then adding the biocompatible copolymerizer 2-hydroxyethyl methacrylate (“HEMA”) to the PMMA film and/or cement in an amount effective to enhance the cohesion between the prosthetic and the bone cement. In general, a PMMA/HEMA film is applied to the prosthetic element in the presence of a silane coupling agent by dipping, painting, spraying, etc.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: January 10, 2006
    Assignee: Faro Technologies, Inc.
    Inventor: Simon Raab
  • Patent number: 6914115
    Abstract: Polyurethane powder coating compositions containing uretdione groups and curing at low temperatures are provided, along with processes for preparing such compositions, and their use as powder coatings, wherein the compositions generally contain: A) a uretdione-containing powder coating hardener derived from aliphatic, (cyclo)aliphatic, cycloaliphatic or aromatic polyisocyanates and hydroxyl-containing compounds, and having a melting point from 40 to 130° C., a free NCO content of less than 5% by weight, and a uretdione content of 6-18% by weight; B) a hydroxyl-containing polymer having a melting point from 40 to 130° C., and an OH number between 20 and 200 mg KOH/gram, and C) a catalyst of the formula [NR1R2R3R4]+[R5]?, in which R1-R4 simultaneously, or independently of one another, are alkyl, aryl, aralkyl, heteroaryl or alkoxyalkyl radicals, and each R1-R4 is aromatic, linear or branched, unbridged or bridged with other radicals, R1-R4.
    Type: Grant
    Filed: November 27, 2002
    Date of Patent: July 5, 2005
    Assignee: Degussa AG
    Inventors: Emmanouil Spyrou, Holger Loesch, Andreas Wenning