Abstract: A housing includes a plastic substrate, an active layer formed on the plastic substrate, and an exterior layer formed on the active layer. The active layer contains polysiloxane and cetyl trimethyl ammonium bromide. The exterior layer contains silicon dioxide or titanium dioxide, and cetyl trimethyl ammonium bromide.

Abstract: The present invention provides two-component polyurethane compositions that are substantially free of VOCs and comprising, as one component, polyisocyanate compositions and, as a second component, a polyol which is chosen from a cycloaliphatic diol or polyol having a molecular weight of from 100 to 500 and containing one or more 4 to 7 member aliphatic ring and an oligomeric diol or polyol comprising the condensation reaction product of from 30 wt. % to 78 wt. %, based on the total weight of reactants used to make the oligomer, and an acrylic or vinyl emulsion polymer.

Abstract: The present invention is directed to a method of mitigating ice build-up on a substrate, comprising applying to the substrate applying to the substrate a curable film-forming composition comprising: (a) a resinous component comprising: (i) a polyepoxide; (ii) a polysiloxane; and (iii) an organooxysilane; (b) a polyamine and/or an aminosilane; (c) at least one additional polysiloxane different from the polysiloxane of (ii) above, and (d) optionally a catalyst. The film-forming compositions can be applied directly to the surface of the substrate or onto a primer coat on the substrate.

Abstract: A method for manufacturing a hose with a protector layer 2 on the outer periphery of a tubular polyamide resin layer 1 includes steps of: preparing a rubber composition for forming the protector layer by separately preparing a first rubber material containing components (A) to (C) and a second rubber material containing components (a) and (b) but substantially free of a sulfur vulcanization agent and mixing them in a mixer; and forming the protector layer 2 by continuously vulcanizing unvulcanized rubber after continuous extrusion of the rubber composition onto the outer periphery of the previously formed polyamide resin layer 1. (A) Ethylene-propylene rubber (B) Sulfur vulcanization agent (C) Thiuram vulcanization accelerator (mp. 66 to 105° C.) (a) Ethylene-propylene rubber (b) Vulcanization accelerator (mp. 120° C. or higher).

Abstract: Solvent-containing clearcoat coating composition comprising (A) an OH-functional (meth)acrylate (co)polymer comprising (A1) 30%-99% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and glass transition temperature Tg of 15° C. to 100° C., and (A2) 1%-70% by weight, based on the mass of the nonvolatile fraction of (A), of at least one OH-functional (meth)acrylate (co)polymer having an OH number of 60-200 mg KOH/g and a glass transition temperature Tg of ?100° C. to ?20° C., (B) a crosslinker component comprising functional groups reactive toward OH, (C) 0.02%-1.2% by weight, based on the mass of the nonvolatile fraction of (A), of at least one polyamide and (D) 0.04%-2.9% by weight, based on the mass of the nonvolatile fraction of (A), of at least one urea adduct of a polyisocyanate and benzylamine.

Abstract: Disclosed is a primer having from 50 to 90 mass % of (A) a chlorinated polyolefin resin having a chlorine content of from 5 to 50 mass % and a weight average molecular weight of from 1,000 to 100,000, from 45 to 5 mass % of (B) a blocked polyisocyanate compound, from 45 to 5 mass % of (C) a polyol resin having a hydroxyl group value of from 30 to 120 mgKOH/g and a weight average molecular weight from 5,000 to 50,000, from 0.5 to 12 mass % of (D) a diol having a weight average molecular weight of from 120 to 1,000 and from 0.01 to 1.5 mass % of (E) a hardening catalyst, wherein the proportions are with respect to the total mass of the resin solid fraction of the (A), (B), and (C) components.

Abstract: Compositions, suitable for coating surfaces, methods for their preparation and for coating surfaces therewith, where said compositions comprise: (a) 100,000 parts by weight of a primer composition comprising a binder material (a1), a primer solvent (a2) and a UV absorber (a3), wherein the primer composition is suitable as an adhesion-promoting agent between a thermoplastic substrate and a siloxane-based top coat; (b) 0 to 900,000 parts by weight of a solvent, and (c) 1 to 3000 parts by weight of a compound according to the general formula (I): wherein X represents a moiety selected from the group consisting —OR6, —OCH2CH2OR6, —OCH2CH(OH)CH2OR6 and —OCH(R7)COOR8, wherein R6 represents a branched or unbranched C1-C13 alkyl, C2-C20 alkenyl, C6-C12 aryl or —CO—C1-C18 alkyl, R7 represents H or a branched or unbranched C1-C8 alkyl, and R8 represents a C1-C12 alkyl, a C2-C12 alkenyl or a C5-C6 cycloalkyl, and wherein the composition has a viscosity of 40 s to 140 s measured in accordance with DIN EN ISO 2431 at

Abstract: A method of making a polyurethane coating can comprise: mixing an unblocked isocyanate component with a polyol component in the presence of a hydroxyl-free solvent and a catalyst to form a reaction mixture; depositing the reaction mixture onto a polymer substrate; and curing the reaction mixture on the substrate to form a polyurethane coated substrate. The polyurethane coated substrate can have a percent thinning of greater than or equal to 10%, e.g., without cracking or delamination when measured on a rectangular block having 90° angles.

Abstract: The present invention relates to a porous ABPBI (phosphoric acid doped poly(2,5-benzimidazole)) membrane and process of preparing the same. A stable porous ABPBI (Phosphoric Acid Doped Poly(2,5-benzimidazole)) membrane stable to acids, bases, solvents and autoclaving is disclosed. The membrane finds use for separation of solutes in solution in acids, bases and solvents.

Abstract: The invention provides a plastic eraser comprising a vinyl chloride resin as a base resin and a combination of 4,5-epoxy-1,2-cyclohexanedicarboxylic acid bis(2-ethylhexyl) and diethylene glycol dibenzoate as plasticizers, wherein the plastic eraser comprises the base resin in an amount of 25-60% by weight, and the combination of plasticizers in an amount of 30-60% by weight, and wherein the proportion of the diethylene glycol dibenzoate in the combination of plasticizers is 5-60% by weight, and wherein the plastic eraser has a hardness in the range of 55-75, and a gel hardness in the range of 3.0-6.0 kgf.

Abstract: Disclosed are multi-staged acrylic based core-shell polymers comprising a linear core polymer and at least one subsequently polymerized shell polymers is crosslinked. The core-shell polymers surprisingly provide desirable rheological, clarity, and aesthetic properties in aqueous surfactant containing compositions, particularly at low pH.

Abstract: Disclosed herein are polyurethane golf ball compositions. The compositions are prepared by adding a UV absorber to a polyol prior to reacting the polyol with an isocyanate to form a prepolymer, which is then reacted with a curing agent to form the polyurethane.

Abstract: Disclosed are methods to form coatings on a substrate, the coatings comprising a blend of a poly(vinyl alcohol) composition comprising a poly(vinyl alcohol) characterized by a hydrolysis level of from about 85 to about 93 mole % and a 4 weight % aqueous viscosity at 20° C. of about 16 to about 75 centipoise; and an ionomer comprising a parent acid copolymer that comprises ethylene and about 18 to about 30 weight % of acrylic acid or methacrylic acid, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising potassium cations, sodium cations or combinations thereof. Multilayer structures comprising the blend composition on a substrate are also disclosed.

Abstract: Disclosed herein are biodegradable compositions, materials, gloves and methods thereof.

Abstract: Provided are polymer-aerogel composite coatings, devices and articles including polymer-aerogel composite coatings, and methods for preparing the polymer-aerogel composite. The exemplary article can include a surface, wherein the surface includes at least one region and a polymer-aerogel composite coating disposed over the at least one region, wherein the polymer-aerogel composite coating has a water contact angle of at least about 140° and a contact angle hysteresis of less than about 1°. The polymer-aerogel composite coating can include a polymer and an ultra high water content catalyzed polysilicate aerogel, the polysilicate aerogel including a three dimensional network of silica particles having surface functional groups derivatized with a silylating agent and a plurality of pores.

Abstract: A composition comprises a fluoropolymer such as an elastomeric fluoropolymer and at least 1 weight % of a fluoro-functionalized near-infrared radiation absorber. This composition can be formed into laser-engraveable layers for various elements that can be laser-engraved to provide relief images. The resulting laser-engraved elements can take various forms including flexographic printing members, and can be used to apply various inks to receiver materials in an imagewise fashion.

Abstract: A process for forming a unidirectionally oriented fiber structure formed of high tenacity fibers. A plurality of yarns of high tenacity fibers are supplied, with the yarns being unidirectionally oriented. The yarns are coated with a liquid having a viscosity of about 5 to about 600 centipoises and tension is applied to the yarns. The yarns are passed through a fiber spreading device and the yarns are dried. The yarns are reduced in thickness and increased in width after passing through the fiber spreading device, with the fibers forming the yarns being spread apart, thus providing a relatively thin unidirectionally oriented fiber structure.

Abstract: A hydrophilizing agent composition comprising a copolymer having an alternating copolymerization ratio of repeating units represented by the following formula (1) and repeating units represented by the following formula (2) of at least 95%, and a solvent: in the formula (1), each of X and Y which are independent of each other, is H, F, CF3 or Cl; in the formula (2), Z is OR1, NHR2, COOR3 or SO3R4, R is a single bond, a bivalent linking group which may contain an ethereal oxygen atom, or a bivalent linking group which may contain a cyclic structure, and each of R1 to R4 which are independent of one another, is H or a monovalent organic group; provided that in the repeating units represented by the formula (2) contained in the copolymer, the proportion of the repeating units wherein each of R1 to R4 is H is at least 50 mol %.

Abstract: An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.

Abstract: In one or more embodiments, the present disclosure provides for a process for preparing a dispersion of starch particles in an aqueous liquid. In one or more embodiments, the process includes introducing a feed starch and the aqueous liquid into a rotor stator mixer, maintaining the feed starch and the aqueous liquid in the rotor stator mixer at a temperature ranging from a gelation temperature to less than a solubilization temperature, and shearing the feed starch into starch particles with the rotor stator mixer to form the dispersion of starch particles in the aqueous liquid. In one or more embodiments, the starch particles produced by this process have an average particle size diameter of no larger than 2 micrometers and the dispersion has 20 to 65 weight percent of the starch particles based on a total weight of the dispersion.

Abstract: Composites and methods for manufacturing composites are provided herein. In one embodiment, a composite structure is provided including a resin composite material and a surface layer disposed on the resin composite material, wherein the surface layer comprises a phenolic resin. In another embodiment, a vessel comprising a composite overwrapped vessel may be improved in regard to high temperature performance by applying thereto a surface layer comprising a phenolic resin.

Abstract: Embodiments include inflatable articles that include an interior surface adapted for being in contact with the inflation gas, the interior surface coated with a parylene barrier. The parylene barrier may be formed of parylene N, parylene C, parylene D, another substituted parylene or combinations thereof. In particular embodiments, the inflatable article is a tire. Other embodiments include inflatable articles having composite layers, wherein at least two of the composite layers include surfaces that interface with one another and a parylene coating applied to at least one of the interfacing surfaces.

Abstract: A method and structure are provided for implementing leak prevention of water cooling hoses. A water cooling hose includes an inner hose layer and an outer hose layer. Potential water leaks are prevented from the water cooling hose or tubing by sealing of the cut end of the tubing after sizing of the water cooling hose has been completed. The cut end of the water cooling hose is dipped into a selected solution bath, and upon removal a seal is formed before hose assembly is provided.

Abstract: Process for the production of a flame-retardant plastics piping system which comprises piping components, in particular piping and connecting elements, such as fittings, valves, screw-threaded elements, containers, pumps, and to which, on the exterior surface of the plastics piping system, an intumescent water- or solvent-based coating comprising a crosslinking binder, in particular at least one of the following binders: vinyl acetate, epoxy resin, acrylate, acrylate mixed resin, polyurethane, polyurethane-acrylate, and various fillers, is applied, where a protective layer is applied over the intumescent coating.

Abstract: A method of manufacturing a turbine blade includes providing a multilayer polymeric film. The multilayer polymeric film includes a first layer including an acrylic-based adhesive, a second layer disposed over the first layer, and a third layer disposed over the second layer. The second layer includes a blend of an acrylic polymer and fluoropolymer. The third layer has at least a portion with a smooth surface. The third layer includes fluoropolymer. The method further includes laminating the multilayer polymeric film over at least a portion of a turbine blade work piece. The first layer contacts the turbine blade work piece.

Abstract: A process in which a wound roll of biaxially oriented polyester film having a glass transition temperature (Tg (° C.)) is annealed at a temperature Ta (° C.) above Tg where Tg<Ta?Tg+100 (° C.) for a time t after thermal equilibrium where 1 hour?t?72 hours and cooled, for the purpose of improving the shrinkage of said polyester film.

Abstract: A battery separator (13) of the present invention includes a porous film (12) serving as a substrate and a crosslinked polymer layer (11) supported on the porous film (12). The crosslinked polymer layer (11) contains a crosslinked polymer and inorganic particles, and is non-porous. The crosslinked polymer is obtained by reacting a reactive polymer having a functional group in its molecule with a polyfunctional compound reactive with the functional group so as to crosslink at least a part of the reactive polymer. A lithium ion secondary battery of the present invention includes a positive electrode (14), a negative electrode (15), the battery separator (13) of the present invention disposed between the positive electrode (14) and the negative electrode (15), and a non-aqueous electrolyte solution. The battery separator (13) is disposed so that the porous film (12) faces the negative electrode (15) and the crosslinked polymer layer (11) faces the positive electrode (14).

Abstract: The invention relates to a wet chemical method for the surface modification of products made of low-energy synthetic fibres, to the products produced by the method and to the use of the products produced by the method. The material surface is permanently provided with functional groups by contact with an aqueous polyvinylalcohol solution containing silanol(ate) groups. Depending upon the design, the materials have a high water consumption or transmission capacity or exhibit a capillary activity. The range of uses for said surface-modified materials is extended by the possibility of reacting the functional groups, inter alia, with biologically active compounds.

Abstract: The present disclosure is directed to a coating composition having excellent adhesion to primer layers, fast drying, improved flexibility and good pot life. This disclosure is further directed to a coating composition comprising components derived from renewable resources, low Tg acrylic polymers having one or more crosslinkable functional groups and a crosslinking agent having one or more crosslinking functional groups.

Abstract: A housing includes a plastic substrate and a layer formed on the plastic substrate. The layer contains polysiloxane and epoxy resin. The layer is very thin, but evenly forms on the surface of the plastic substrate. The layer has a high hardness and can effectively protect the plastic substrate from abrasion.

Abstract: The present disclosure is drawn to compositions and methods involving coated substrates for liquid electrophotographic printing. Generally, a coated substrate for liquid electrophotographic printing can comprise a polyethylene- or polypropylene-based substrate and a coating adhered to the substrate, the coating comprising a water-based aliphatic polyurethane polymer.

Abstract: A polymeric product including at least two layers, wherein a functional layer includes a polymeric material and at least one anti-microbial substance, and a protective layer, including a polymeric material arranged outside the functional layer and completely covering the functional layer, wherein the protective layer does not include any anti-microbial substances. A method of producing the product, the use of the same and a kit for producing the product.

Abstract: A gas barrier laminate having an undercoating (A) which comprises a main resin, an isocyanate type curing agent and an alkaline compound of a polyvalent metal; and a barrier layer (B) of a polycarboxylic acid polymer forming an ionic crosslinking due to the polyvalent metal among the carboxyl groups; formed on at least one surface of a plastic base material (P), wherein a region (b) free of the alkaline compound of the polyvalent metal is formed in the undercoating (A) on the side of the barrier layer (B), the content of nitrogen in the region (b) being larger than the content of nitrogen in the undercoating (A) other than the region (b), the gas barrier laminate having excellent gas barrier property, retort resistance, producibility as well as excellent flexibility without developing interlayer peeling even if it is folded and featuring excellent interlayer adhesion.

Abstract: This invention relates to electrically conductive polymers grafted to the surface of insulating polymers. Simultaneous polymerization and grafting reactions of conducting precursors form conductive polymer layers that dramatically increase the electrical conductivity of the respective insulating polymer films.

Abstract: Exemplary embodiments provide nanotube-containing coating compositions and methods for making and using the coating compositions. In an exemplary embodiment, the coating composition can include a plurality of nanotubes (e.g., carbon nanotubes (CNTs)) dispersed stably and uniformly in a polymer matrix containing fluoropolymers. The coating composition can further include stabilizers to allow a stable and/or uniform dispersion of the plurality of nanotubes in the fluoropolymers. The nanotube coating composition can be coated on an article surface to improve mechanical robustness, and electrical and thermal conductivity of the coated article. The coated article can be used as a fuser member, a fixing member, a pressure roller, or a release agent donor member in an electrostatographic printing machine or process.

Abstract: Composite materials having a multi-wall carbon nanotube content of from 4 to 15% by weight, based on total weight of the composite, are produced from a dispersion of multi-wall carbon nanotubes (MWCNTs) and a fiber reinforcing material in a carrier fluid which is processed to form a shaped article that may then be infused with a liquid polymer or polymer-forming mixture to form the composite.

Abstract: A method for producing a fibrous material including carbon fibres or glass fibres or plant fibres or polymer-based fibres, that are used alone or in a mixture, and are impregnated by a thermohardenable polymer using a mixture containing a hardener and carbon nanofillers, such as carbon nanotubes (CNT). A mixture containing said nanofillers, such as CNTs, and the hardener is used to introduce said nanofillers into the fibrous material. A continuous production line (L) for producing the material in the form of at least one calibrated and homogeneous strip (20) of reinforcing fibres impregnated with a thermohardenable polymer, includes the device (100) for arranging two series of fibres (1, 2) used to form a strip in such a way as to arrange the two series of fibres such that they are brought into contact with each other by means of two calendering devices.

Abstract: The present invention provides a back sheet for a solar cell, the back sheet including a polymer base and a polymer layer that is disposed by coating on at least one surface of the polymer base material, the polymer layer including an amorphous colloidal silica and, as a binder, at least one of a polymer selected from a fluorine-based polymer or a silicone-based polymer, the polymer formed by coating having excellent uniformity and the back sheet having superior weather resistance compared to conventional back sheets.

Abstract: The invention relates to a membrane including a partition layer, wherein the partition layer contains at least 50 wt % of PVC, and a barrier layer. The barrier layer can be a barrier layer, wherein the barrier layer has a polyamide layer containing more than 50 wt % of copolymer, wherein said polyamide layer is connected to the partition layer by a polyurethane layer, wherein the polyurethane layer contains more than 10 wt % of polyurethane. Alternatively, the barrier layer can be a barrier layer, wherein the barrier layer is made of a composition containing 5-50 wt % of polyurethane and 50-95 wt % of copolymer. The membranes according to the invention have significantly lower plasticizer migration compared to the membranes of the prior art and are characterized by improved aging resistance, in particular with regard to the adhesion of the barrier layer to the partition layer, and impermeability to moisture.

Abstract: There is provided a coating composition having a good wetting property which is capable of forming a coating film exhibiting a high refractive index, a less discoloration, and excellent transparency and uniformity when polymerized and cured. The present invention relates to a coating composition comprising (A) 100 parts by weight of a thiirane ring-containing compound, (B) 0.0001 to 10 parts by weight of a catalyst for accelerating polymerization of the thiirane ring-containing compound, and (C) 0.005 to 4 parts by weight of a modified silicone oil; a coating film produced from the composition; and an optical product provided with the coating film.

Abstract: The waterborne coating composition herein is useful for promoting adhesion of paint to a component such as a plastic automobile part or accessory. The waterborne coating composition is particularly useful for promoting adhesion of paint to a thermoplastic polyolefin surface. The waterborne coating composition is prepared from a mixture comprising at least one chlorinated polyolefin resin and at least one urethane acrylic hybrid resin. The waterborne coating composition provides not only good adhesion of a paint to a thermoplastic polyolefin surface, but also provides good appearance. The waterborne coating composition is also compatible with a wide variety of paint systems and can be rapidly dried under ambient conditions.

Abstract: A multilayer film suitable for sealing containers such as used for food packaging, and methods of making the film, are described. The film is particularly suitable for sealing containers made from polylactic acid (PLA). The multilayer film includes a) a substrate that includes a polymeric base layer; and b) on the substrate, a heatseal layer containing a PLA homopolymer or copolymer. The heatseal layer further includes dispersed therein an adhesion promoter, or alternatively the substrate further includes the adhesion promoter in a layer on a surface of the polymeric base layer between and adjacent the base layer and the heatseal layer. An antifog agent may also be included in the heatseal layer or on the surface of the heatseal layer opposite the substrate.

Abstract: Provided are chlorine-free ink and coating compositions that demonstrate improved adherence when applied to untreated flexible plastic film substrates. The provided compositions eliminate the need for a separate step of pre-treating a plastic film before applying an ink or coating composition. Also provided are methods for producing a printed article using the provided ink and coating compositions and methods of adhering chlorine-free inks or coatings that exhibit improved adhesion characteristics to untreated plastic films.

Abstract: Methods for surface treatment of polyester substrates are described. Treatment methods include adherence of a polymer layer on a surface of the polyester so as to increase the hydrophilic properties of the surface. Polymers can be polyelectrolytes that are adsorbed at the surface or polymer brushes that are polymerized at the surface. Further surface functionalization can include the adherence of inorganic nanoparticles to the surface. The polyester substrates can be recycled polyester such as recycled polyethylene terephthalate that has been subjected to a partial saponification reaction during the recycling process.

Abstract: A binder comprising a polymeric binder comprising the products of a carbohydrate reactant and organic acid is disclosed. The binder is useful for consolidating loosely assembled matter, such as fibers. Fibrous products comprising fibers in contact with a carbohydrate reactant and an organic acid are also disclosed. The binder composition may be cured to yield a fibrous product comprising fibers bound by a cross-linked polymer. Further disclosed are methods for binding fibers with the carbohydrate based binder using an organic acid.

Abstract: A plastic composite comprises a first plastic substrate, an adhesive layer formed on the first plastic substrate, and a second plastic substrate formed on the adhesive layer. The first plastic substrate is made of thermoplastic resin material. The second plastic substrate is made of thermosetting resin material. The adhesive layer mainly comprises amino silane coupling agent. A method for manufacturing the plastic composites is also provided.

Abstract: The present invention is a method for forming a golf ball, the method comprising mixing an aqueous polyurethane dispersion with an azridine to form an aqueous polyurethane dispersion/aziridine mixture. Then, adding the aqueous polyurethane dispersion/aziridine mixture to a water tank, to form a PUD/aziridine solution and dipping a polybutadiene core in the PUD/aziridine solution. The PUD/aziridine solution comprises 0.4 percent aziridine, 4 percent aqueous polyurethane dispersion, and 95.6 percent de-ionized water, which forms a dipped polybutadiene core. The dipped polybutadiene core is then dried at room temperature.

Abstract: Sizing compositions to size fibers or particles used in plastic composites are described. The compositions may include a solution with a polymerization compound selected from: (a) at least one non-isocyanate-containing polymerization initiator (PI) for initiating the polymerization of caprolactam monomers; or (b) at least one precursor for a non-isocyanate-containing PI for initiating the polymerization of caprolactam monomers. Methods of making the sizing the composition, as well as methods of making reinforced thermoplastic composites from sized fibers or particles, are also described.

Abstract: The present disclosure relates to a method for producing composite materials containing as a first layer a foamed thermoplastic support and as a second layer polyurethane (PU), the resulting composite materials being characterized by improved foam adhesion, wherein (i) a foamed polycarbonate molding composition is produced by injection molding using chemical or physical foaming techniques, and (ii) the polyurethane reaction system is applied on top and allowed to cure. The disclosure also provides the composite systems produced by this method and their use as a component, in particular in the automotive sector.

Abstract: This invention is directed to a process for the preparation of a crosslinker composition, comprising the steps of providing a mixture of an aliphatic alcohol A having at least one hydroxyl group and from 1 to 10 carbon atoms, with at least one multifunctional aldehyde C having at least two aldehyde groups —CHO to form a mixture AC, heating the mixture AC to convert at least a part of the multifunctional aldehyde C to its hemiacetal or to its acetal to form a mixture (AC)?, adding to the mixture (AC)? least one cyclic urea U or the educts to produce the said cyclic urea U in situ, which cyclic urea U has at least one unsubstituted >NH group, and reacting the mixture thus obtained to form a chemical bond between the nitrogen atom of the at least one unsubstituted >NH group of the at least one cyclic urea U5 and the carbon atom of the least one aldehyde group —CHO of the multifunctional aldehyde C, and coating compositions comprising the said crosslinker composition.