Metal Oxide Containing Coating Patents (Class 427/453)
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Patent number: 7544393Abstract: The susceptor of a plasma treating device, or the electrostatic chuck of a substrate table, is formed by ceramic thermal spray method. A thermally sprayed ceramic layer is pore-sealed by methacrylic resin. Resin raw material mainly containing methyl methacrylate is applied to and impregnated into the thermally sprayed ceramic layer and then is cured to thereby fill pores between ceramic particles in the thermally sprayed ceramic layer with methacrylic resin. Methacrylic resin raw material solution, which does not produce pores at curing, can complete perfect pore sealing.Type: GrantFiled: January 12, 2006Date of Patent: June 9, 2009Assignee: Tokyo Electron LimitedInventors: Shinji Muto, Chihiro Taguchi, Nobuyuki Okayama
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Patent number: 7544394Abstract: In accordance with an embodiment of the invention, an article is provided. The article comprises a substrate comprised of silicon containing material, an environmental barrier coating (EBC) overlying the substrate and a thermal barrier coating (TBC) on the environmental barrier coating. The thermal barrier coating comprising a compound having a rhombohedral phase.Type: GrantFiled: September 5, 2007Date of Patent: June 9, 2009Assignee: General Electric CompanyInventors: Brett Allen Rohrer Boutwell, Irene Spitsberg, Christine Govern, Bangalore A. Nagaraj, Brian Thomas Hazel, Ramgopal Darolia, Curtis Alan Johnson, Yan Gao, Mark Daniel Gorman
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Publication number: 20090136695Abstract: A method for the manufacture of a hydrogen-permeable membrane, which includes a proton-conducting ceramic material and a electron-conducting metallic component. The membrane is deposited by means of plasma spraying as a layer on a substrate, wherein a starting material is sprayed onto a surface of the substrate in the form of a process beam and wherein the starting material is injected into a plasma at a low process pressure, which is 10 000 Pa at the most, which defocuses the process beam at a low process pressure, and is melted partly or completely there.Type: ApplicationFiled: August 14, 2008Publication date: May 28, 2009Inventors: Rajiv J. Damani, Amo Refke
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Publication number: 20090136677Abstract: Metal-containing complexes of a tridentate beta-ketoiminate, one embodiment of which is represented by the structure: wherein M is a metal such as calcium, strontium, barium, scandium, yttrium, lanthanum, titanium, zirconium, vanadium, tungsten, manganese, cobalt, iron, nickel, ruthenium, zinc, copper, palladium, platinum, iridium, rhenium, osmium; R1 is selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, and aryl, having 1 to 10 carbon atoms; R2 is selected from the group consisting of hydrogen, alkyl, alkoxy, cycloaliphatic, and aryl; R3 is linear or branched selected from the group consisting of alkylene, fluoroalkyl, cycloaliphatic, and aryl; R4 is a branched alkylene bridge with at least one chiral center; R5-6 are individually linear or branched selected from the group consisting of alkyl, fluoroalkyl, cycloaliphatic, aryl, and can be connected to form a ring containing carbon, oxygen, or nitrogen atoms; n is an integer equal to the valence of the metal M.Type: ApplicationFiled: November 27, 2007Publication date: May 28, 2009Applicant: AIR PRODUCTS AND CHEMICALS, INC.Inventors: Xinjian Lei, Daniel P. Spence, Hansong Cheng
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Patent number: 7537806Abstract: In accordance with an embodiment of the invention, a thermal barrier coating for inclusion in a thermal barrier coating system is provided. The thermal barrier coating comprises a compound having a rhombohedral phase. In accordance with another embodiment of the invention, a thermal barrier coating is provided that comprises a compound having the formula of: A4B3O12, wherein A is at least one rare earth element; and B is selected from the group consisting of Zr, Hf and mixtures thereof.Type: GrantFiled: September 5, 2007Date of Patent: May 26, 2009Assignee: General Electric CompanyInventors: Brett Allen Rohrer Boutwell, Ramgopal Darolia, Curtis Alan Johnson, Irene Spitsberg, Mark Daniel Gorman, Yan Gao
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Publication number: 20090126604Abstract: A flame spray pyrolysis process for the preparation of ultrafine titania particles coated with a smooth, homogeneous coating of one or more metal oxides is provided. The metal oxide coating is achieved by contacting the titania particles with a metal oxide precursor downstream of the titania formation zone, after the titania particles have formed. The process provides titania particles with a high rutile content and a smooth and homogeneous coating of a metal oxide.Type: ApplicationFiled: November 16, 2007Publication date: May 21, 2009Inventors: M. Kamal Akhtar, Sotiris Emmanuel Pratsinis, Martin Christian Heine, Alexandra Teleki Harsanyi, Reto Strobel
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Publication number: 20090123735Abstract: Components of semiconductor processing apparatus are formed at least partially of erosion, corrosion and/or corrosion-erosion resistant ceramic materials. Exemplary ceramic materials can include at least one oxide, nitride, boride, carbide and/or fluoride of hafnium, strontium, lanthanum oxide and/or dysprosium. The ceramic materials can be applied as coatings over substrates to form composite components, or formed into monolithic bodies. The coatings ca protect substrates from physical and/or chemical attack. The ceramic materials can be used to form plasma exposed components of semiconductor processing apparatus to provide extended service lives.Type: ApplicationFiled: January 7, 2009Publication date: May 14, 2009Applicant: Lam Research CorporationInventor: ROBERT J. O'DONNELL
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Publication number: 20090120790Abstract: Components of semiconductor processing apparatus axe formed at least: partially of erosion, corrosion and/or corrosion-erosion resistant ceramic materials. Exemplary ceramic materials can include at least one oxide, nitride, boride, carbide and/or fluoride of hafnium, strontium, lanthanum oxide and/or dysprosium. The ceramic materials can be applied as coatings over substrates to form composite components, or formed into monolithic bodies. The coatings can protect substrates from physical and/or chemical attack. The ceramic materials can be used to form plasma exposed components of semiconductor processing apparatus to provide extended service lives.Type: ApplicationFiled: January 7, 2009Publication date: May 14, 2009Applicant: Lam Research CorporationInventor: ROBERT J. O'DONNELL
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Publication number: 20090123659Abstract: A modified flame-spraying method for producing self-cleaning surfaces by a dry coating process penetrates particles in a hot air or flame stream into the softened substrate surface. The process can be applied to textiles and other articles having plastic surfaces.Type: ApplicationFiled: November 25, 2008Publication date: May 14, 2009Applicant: CREAVIS Gesellschaft fuer Tech. und Innovation mbHInventors: Markus Oles, Edwin Nun
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Patent number: 7527583Abstract: A paper machine press roll comprises a core roll and a ceramics sprayed film formed on an outer periphery of the core roll, in which values of Rk and Vo which are characteristic evaluation parameters of a plateau-structure surface of the ceramics sprayed film are Rk?8.0 ?m and Vo?0.030 mm3/cm2. (Vo=(100?Mr2)×Rvk/2000 (mm3/cm2) where Rk, Mr2 and Rvk are a core level difference, a core load length ratio and a projecting valley depth, respectively which are defined in JIS B0671-2-2002 (ISO13565-2-1996).Type: GrantFiled: March 21, 2005Date of Patent: May 5, 2009Assignee: Yamauchi CorporationInventor: Atsuo Watanabe
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Patent number: 7527874Abstract: A method of forming a vibration damping coating on a metallic substrate, eg a titanium alloy aerospace component, comprises applying to the metallic substrate a coating comprising a spinel having regions of relative oxide or nitride imbalance.Type: GrantFiled: October 8, 2003Date of Patent: May 5, 2009Assignee: Rolls-Royce PLCInventors: Mark Henry Shipton, Sophoclis Patsias
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Publication number: 20090110903Abstract: A thermally sprayed alumina-based coating is deposited onto a thermal barrier coating to provide an article such as a turbine engine component with both CMAS mitigation and antifouling. The alumina-based coating increases a melting point of the CMAS to a temperature greater than an operating temperature of the turbine engine component. The surface roughness of the thermally sprayed alumina based coating in less than 4.0 micrometers to 0.75 micrometers. The alumina based coatings include at least 60 weight percent alumina based on a total weight of the alumina-based coating.Type: ApplicationFiled: October 24, 2007Publication date: April 30, 2009Applicant: GENERAL ELECTRIC COMPANYInventor: Joshua L. Margolies
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Patent number: 7524791Abstract: A method for producing a substrate having a carbon-doped titanium oxide layer, which is excellent in durability (high hardness, scratch resistance, wear resistance, chemical resistance, heat resistance) and functions as a visible light responding photocatalyst, is provided. The surface of a substrate, which has at least a surface layer comprising titanium, a titanium alloy, a titanium alloy oxide, or titanium oxide, is heat-treated in a combustion gas atmosphere of a gas consisting essentially of a hydrocarbon, or in a gas atmosphere consisting essentially of a hydrocarbon, such that the surface temperature of the substrate is 900 to 1,500° C.; or a combustion flame of a gas consisting essentially of a hydrocarbon, is directly struck against the surface of the substrate for heat treatment such that the surface temperature of the substrate is 900 to 1,500° C., thereby forming a carbon-doped titanium oxide layer, whereby the substrate having the carbon-doped titanium oxide layer is obtained.Type: GrantFiled: December 8, 2004Date of Patent: April 28, 2009Assignee: Central Research Institute of Electric Power IndustryInventor: Masahiro Furuya
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Publication number: 20090101502Abstract: A thermal shock resistant sensor element that includes a sensor element having a gamma alumina coating on at least a portion thereof. The thermal shock resistant sensor element may be thermal shock resistant at temperatures greater than about 600° C. A method of making a thermal shock resistant element that includes plasma spraying gamma alumina onto a sensor element to form a thermal shock resistant element. The thermal shock resistant sensor element may be thermal shock resistant at temperatures greater than about 500° C. A thermal shock resistant sensor element that includes a sensor element having an alumina coating on at least a portion thereof. The thermal shock resistant sensor element may be thermal shock resistant at temperatures greater than about 500° C. and may demonstrate a Si poisoning resistance after exposure to the Gas Burner Test (850° C.) for at least about 60 hours.Type: ApplicationFiled: May 30, 2008Publication date: April 23, 2009Applicant: ROBERT BOSCH GMBHInventors: James Richard Waldrop, Juergen Sindel, Juergen Reiss, Jeffrey McCollum, Heiner Scheer
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Publication number: 20090068373Abstract: A recipe and two sequential processes for fabrication of electrode substrates of solid oxide fuel cells (SOFCs) are described in this invention. The typical recipe consists of 50˜86 wt % electrolyte (8YSZ) or 50˜80 wt % anode electrode (NiO/8YSZ), 12˜22 wt % MEK (solvent 1), 5˜9 wt % EtOH (solvent 2), 1˜2 wt % TEA (dispersant), 0.5˜2 wt % DBP (plasticizer 1), 0.5˜2 wt % PEG (plasticizer 2), 3˜6 wt % PVB (binder), and 0.1˜10 wt % graphite (pore former). Two sequential processes include: 1. The process for preparation of the green tape slurry from materials of the recipe, 2. The synergistic process for fabrication of a high integrity membrane electrode assembly (MEA) of SOFC from the prepared electrode substrates.Type: ApplicationFiled: September 11, 2007Publication date: March 12, 2009Inventors: MAW-CHWAIN LEE, WEI-XIN KAO, TAI-NAN LIN, YANG-CHUANG CHANG, CHUN-HSIU WANG
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Patent number: 7494723Abstract: A member is obtained by forming a Y2O3 black spray coating on a surface of a substrate or covering the surface of the substrate with a Y2O3 black spray coating through an undercoat or a middle layer. This coating has good heat characteristics and is good in the resistance to damaging through a high hardness. The Y2O3 black spray coating is produced by subjecting white Y2O3 powdery material to a plasma spraying in an inert gas atmosphere containing substantially no oxygen or by forming a Y2O3 white spray coating and then irradiating an electron beam or a laser beam to this coating to melt at least a part of the white coating under heating to thereby smoothen denseness and blacken the surface of the coating.Type: GrantFiled: July 29, 2005Date of Patent: February 24, 2009Assignee: Tocalo Co., Ltd.Inventors: Yoshio Harada, Takema Teratani
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Publication number: 20090036289Abstract: An optical composite material comprises an amorphous optical material (6) with a first refractive index (na), into which crystalline nanoparticles (7) having a second, higher refractive index (nn) are embedded, wherein the amorphous material (6) and the nanoparticles (7) are resistant to UV radiation. A microlithography projection exposure apparatus comprises a projection objective (2) with at least one optical element (3) which is, in particular, operated in transmission and consists of an optical composite material of this type. In a method for producing the optical composite material, crystalline nanoparticles are introduced into the amorphous optical material during flame deposition in a soot or direct process.Type: ApplicationFiled: February 22, 2006Publication date: February 5, 2009Applicant: Carl Zeiss SMT AGInventors: Eric Eva, Wilfried Clauss
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Publication number: 20080318757Abstract: The invention is to processes for producing a nanoglass powder batches and to powder batches formed by such processes. In one embodiment, the process comprises the steps of providing a precursor medium comprising a first metal oxide precursor to a first metal oxide, a second metal oxide precursor to a second metal oxide, and a liquid vehicle; and flame spraying the precursor medium under conditions effective to form aggregated nanoglass particles comprising the first and second metal oxides, wherein the aggregated nanoglass particles have an average primary particle size of from 25 nm to 500 nm. The aggregated nanoglass particles preferably have an average aggregate particle size of from 50 nm to 1000 nm and may be amorphous or crystalline.Type: ApplicationFiled: June 19, 2008Publication date: December 25, 2008Applicant: CABOT CORPORATIONInventors: George FOTOU, Mark HAMPDEN-SMITH, Mark KOWALSKI, Hyungrak KIM, Toivo KODAS, Ned HARDMAN
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Patent number: 7468213Abstract: A heat-insulating material has a melting point above 2500° C., a thermal expansion coefficient in excess of 8×10?6 K?1, and a sintering temperature greater than 1400° C. It has a perovskite structure of the general formula A1+r(B?1/3+xB?2/3+y)O3+z where A=at least one element of the group (Ba, Sr, Ca, Be), B?=at least one element of the group (Mg, Ca, Sr, Ba, Be), B?=at least one element of the group (Ta, Nb), r, x, and z?0, and ?0.1<r, x, y, z<0.1; or of the general formula A1+r(B?1/2+xB?1/2+y)O3+z where A and B? are as above and B?=at least one element of the group (Al, La, Nd, Gd, Er, Lu, Dy, Tb), and ?1.0<r, x, y, z<0.1.Type: GrantFiled: June 10, 2003Date of Patent: December 23, 2008Assignee: Forschungszentrum Julich GmbHInventors: Robert Vassen, Sigrid Schwartz-Lückge, Wolfgang Jungen, Detlev Stöver
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Publication number: 20080311306Abstract: Superfine ceramic thermal spray feedstock compositions and methods of making and using such compositions are provided. In an embodiment, a thermal spray feedstock composition comprises: a superfine ceramic material comprising grains having an average longest dimension of about 100 nanometers to about 500 nanometers; and a grain growth inhibitor comprising a ceramic oxide different from the superfine ceramic material.Type: ApplicationFiled: June 19, 2008Publication date: December 18, 2008Applicant: INFRAMAT CORPORATIONInventors: T. Danny Xiao, Xinqing Ma
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Publication number: 20080307856Abstract: Disclosed is a method of fabricating a carbon monoxide detector and a carbon monoxide detector fabricated using the same. Particularly disclosed is a method of fabricating a carbon monoxide detector, which can operate at room temperature and process high detecting selection, and the detector fabricated using the same. The method comprises: providing a substrate having an upper surface; forming two electrode sets on the upper surface of the substrate, and the two electrode sets combined to provide an interdigitated array electrode; forming a tin dioxide layer, which covers the portion of the two electrode sets and the portion of the upper surface; and forming an organic polymer layer on the surface of the tin dioxide layer.Type: ApplicationFiled: May 16, 2008Publication date: December 18, 2008Applicant: Forward Electronics Co., Ltd.Inventors: Ko-Shao Chen, Shu-Juan Liao, Yun-Huang Chen, Jung-Chien Chang
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Patent number: 7465495Abstract: Disclosed is a composite black oxide particle which is composed of oxide of cobalt, copper and manganese. The copper/cobalt molar ratio is 0.1-0.5, and the manganese/cobalt molar ratio is 0.2-1.0. The composite black oxide particle further contains silicon, and the silicon content to the total oxide particle is 0.1-3 mass %. The surface of the composite black oxide particle is coated with aluminum oxide. The Al content in the surface coating to the entire particle is 0.05-3 mass %.Type: GrantFiled: October 14, 2004Date of Patent: December 16, 2008Assignee: Mitsu Mining & Smelting Co., Ltd.Inventors: Shoichi Fujiyasu, Tomio Hayashi, Koichi Katsuyama, Hiroyuki Shimamura
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Publication number: 20080280058Abstract: A method of preparing nanostructured zinc oxide layers on a substrate by chemical spray pyrolysis at moderate deposition temperatures from 350° C. to 600° C. is disclosed. An aqueous or aqueous alcoholic solution comprising zinc chloride or zinc acetate as precursors is prepared and sprayed onto the preheated substrate so that the precursor reacts to form zinc oxide layer on the substrate. Thiourea or urea may be also added to the solution. Glass, silicon, or metal oxide covered glass can be used as the substrate.Type: ApplicationFiled: April 13, 2006Publication date: November 13, 2008Applicant: TALLINN UNIVERSITY OF TECHNOLOGYInventors: Malle Krunks, Ilona Oja-Acik, Tatjana Dedova
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Patent number: 7449251Abstract: A thermal barrier coating comprises a bond coating 12 made of high temperature corrosion resistance superior to a substrate 11 and a thermal barrier coating 13 made of ZrO2 series ceramics formed on the bond coating. The thermal barrier coating has cracks extending in the direction of the thickness of the barrier coat. Substantially all of the tips of the cracks have a distance between the tips and the boundary at the substrate side.Type: GrantFiled: December 8, 2004Date of Patent: November 11, 2008Assignee: Hitachi, Ltd.Inventors: Hideyuki Arikawa, Akira Mebata, Yoshitaka Kojima, Kunihiro Ichikawa
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Publication number: 20080241412Abstract: A member for a plasma etching device, which comprises a device substrate comprising quartz glass, aluminum, alumite or a combination thereof and, formed on the surface thereof, a coating film of yttrium oxide or YAG having a film thickness of 10 ?m or more and a variation in the thickness of 10% or less, and preferably a surface roughness (Ra) of 1 ?m or less; and a method for manufacturing the member for a plasma etching device, which comprises a step of plasma-spraying yttrium oxide or YAG to the surface of said device substrate or a step of fusing yttrium oxide or YAG with an oxyhydrogen flame, followed by coating the surface with the fused product, or a step of applying a solution containing yttrium, a yttrium compound or YAG on the above surface, followed by heating to fuse the resultant coating, or a combination of the above steps, thereby forming a coating film of yttrium oxide or YAG having a film thickness 10 ?m or more and a variation in the thickness of 10% or less, and preferably a surface roughneType: ApplicationFiled: November 6, 2007Publication date: October 2, 2008Applicant: Shin-Etsu Quartz Products Co., Ltd.Inventors: Kyoichi Inaki, Itsuo Araki
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Patent number: 7429408Abstract: C12A7 containing oxygen radicals at a high concentration, is provided at a low cost. A method for preparing an oxygen radical-containing calcium aluminate film, characterized in that it comprises subjecting a powder of oxygen radical-containing calcium aluminate to thermal spraying, and preferably the oxygen radical content in the oxygen radical-containing calcium aluminate is at least 1020 cm?3.Type: GrantFiled: January 21, 2004Date of Patent: September 30, 2008Assignee: Denki Kagaku Kogyo Kabushiki KaishaInventors: Takashi Kawasaki, Kazuhiro Ito, Masahiro Ibukiyama
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Patent number: 7422769Abstract: A refractory, oxidation-resistant, and corrosion-resistant protective coating for application to a substrate, in particular for application to parts of turbines or aircraft propulsion engines, is described, including a spray coating made of a thermally sprayed, primarily metallic material, the coating being at least partially subjected to a thermochemical aluminum (Cr, Si) deposition process having a specifically high aluminum deposition activity after the application of the protective coating to the substrate, in such a way that the protective coating has alloy gradients of Al (Cr, Si) which increase from the substrate surface to the coating surface and isolated globulitic metal oxide particles. Furthermore, a method for manufacturing this protective coating and its use are described.Type: GrantFiled: July 14, 2005Date of Patent: September 9, 2008Assignee: Mtu Aero Engines GmbHInventors: Stefan Kassner, Markus Niedermeier, Horst Pillhoefer
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Publication number: 20080213496Abstract: Methods of applying specialty ceramic materials to semiconductor processing apparatus, where the specialty ceramic materials are resistant to halogen-comprising plasmas. The specialty ceramic materials contain at least one yttrium oxide-comprising solid solution. Some embodiments of the specialty ceramic materials have been modified to provide a resistivity which reduces the possibility of arcing within a semiconductor processing chamber.Type: ApplicationFiled: August 2, 2007Publication date: September 4, 2008Inventors: Jennifer Y. Sun, Shun Jackson Wu, Senh Thach, Ananda Kumar, Robert W. Wu, Hong Wang, Yixing Lin, Clifford C. Stow, Jim Dempster, Li Xu, Kenneth S. Collins, Ren-Guan Duan, Thomas Graves, Xiaoming He, Jie Yuan
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Publication number: 20080210514Abstract: The present invention relates to a process for applying a wear-resistant tribological coating to a sliding region of a synchronizer ring in which a thermally sprayed coating contains a maximum of approximately 40% by weight of solid lubricant, as well as to a synchronizer ring sliding region having a coating applied by such a process.Type: ApplicationFiled: March 14, 2008Publication date: September 4, 2008Applicants: DAIMLERCHRYSLER AG, DRAHTWARENFABRIK DRAHTZUG STEIN GMBH & CO., KGInventors: Christof Eberspacher, Martin Gausmann, Stefan Grau, Tilman Haug, Patrick Izquierdo, Hansjoerg Zeller, Jorg Zurn, Wolfgang Reichle, Reinhard Rosert
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Publication number: 20080199722Abstract: This invention relates to coatings for a metal or non-metal substrate comprising (i) a thermal sprayed bondcoat layer applied to said substrate comprising an alloy of MCrAlM? wherein M is an element selected from nickel, cobalt, iron and mixtures thereof, and M? is an element selected from yttrium, zirconium, hafnium, ytterbium and mixtures thereof, and wherein M comprises from about 35 to about 80 weight percent of said alloy, Cr comprises from about 15 to about 45 weight percent of said alloy, Al comprises from about 5 to about 30 weight percent of said alloy, and M? comprises from about 0.01 to about 1.0 weight percent of said alloy, said alloy thermally sprayed from a powder having a mean particle size of 50 percentile point in distribution of from about 5 microns to about 100 microns, said bondcoat having a surface roughness of at least 200 micro-inches, and said bondcoat having a thermal expansion of about 6.5 millimeters per meter or less between a temperature of from about 25° C. to about 525° C.Type: ApplicationFiled: February 7, 2008Publication date: August 21, 2008Inventors: Prasad Shrikrishna Apte, James Patrick Meagher, Shawn W. Callahan
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Publication number: 20080190768Abstract: A gas sensor includes a sensing element, a housing, a metal cover, and an oxide layer. The sensing element generates a signal indicative of an oxygen concentration in a measurement gas. The housing holds therein the sensing element with a portion of the sensing element protruding outside of the housing. The metal cover surrounds the portion of the sensing element and is to be exposed the measurement gas. The metal cover has formed therein a gas passage through which the sensing element is also to be exposed to the measurement gas. The oxide layer is formed on at least a surface of the metal cover. With the oxide layer, during operation, at least the metal cover is prevented from being oxidized by the oxygen contained in the measurement gas. Consequently, the oxygen concentration in the measurement gas can be accurately determined based on the signal generated by the sensing element.Type: ApplicationFiled: February 13, 2008Publication date: August 14, 2008Applicant: DENSO CORPORATIONInventors: Takehito Kimata, Masanobu Yamauchi
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Publication number: 20080182114Abstract: Disclosed herein are agglomerate blends suitable for application to a surface of a substrate by thermal spray, thereby to produce coatings, typically nanostructured coatings, that exhibit desirable properties such as erosion, abrasion, or corrosion resistance. Such coatings have many useful applications, including but not limited to an enhancement of valve reliability and durability. For example, the nanostructured coatings may be applied to valve components (i.e., balls and seats) via thermal spray processes, wherein the feedstock powder used in thermal spray may be composed, for example, of a chromium oxide composite material that meets the protective requirements against the wear and corrosion of the valve service. The thermal spray process may involve, but is not limited to, either a plasma spray or high-velocity combustion process. Through their enhanced properties, the coatings can provide superior reliability and extended life to components such as valves.Type: ApplicationFiled: January 30, 2008Publication date: July 31, 2008Applicant: Scientific Valve and Seal, L.P.Inventors: George Ea-Hwan Kim, John Blaine Williams
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Patent number: 7404866Abstract: A sliding member includes a superficial portion forming a sliding surface. The superficial portion includes an oxygen-containing alloy containing at least one metallic element selected from the group consisting of molybdenum and tungsten in an amount of from 2 to 80% by weight; and oxygen in an amount of from 0.5 to 15% by weight. The sliding member sustains lubricating characteristics given to the sliding surface over a long period of time to maintain a low friction coefficient and durability.Type: GrantFiled: June 26, 2002Date of Patent: July 29, 2008Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Kazuyuki Nakanishi, Hideo Tachikawa, Hiroyuki Mori, Tadashi Oshima
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Publication number: 20080166493Abstract: Anti-fouling coating compositions and methods of making and using those compositions are provided. In an embodiment, a coating composition comprises ceramic nanoparticles, wherein the coating composition is capable of inhibiting contaminants from adhering to a solid surface.Type: ApplicationFiled: January 9, 2008Publication date: July 10, 2008Applicant: INFRAMAT CORPORATIONInventors: T. Danny Xiao, Xinqing Ma, Kim Arnold Wynns, Meidong Wang, Jinxiang Dai
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Publication number: 20080166574Abstract: A heat insulation material based on ceramic material includes a top layer containing BaZrO3 and Y2O3 doped ZrO2 A heat insulation material preferably consists of at least one adhesion promotion layer, at least one intermediate layer arranged thereon and a top layer arranged thereon, with the adhesion promotion layer consisting of MeCrAlY, where Me is nickel and/or cobalt, the intermediate layer consists of Y2O3 doped ZrO2 and the top layer consists of 15 to 25% by weight BaZrO3 and 75 to 85% by weight Y2O3 doped ZrO2. A method of coating a substrate with a heat insulation material includes the step of applying an aforesaid top layer to an optionally coated substrate by a thermal spray method or an electron beam method, in particular an EB-PVD method.Type: ApplicationFiled: August 28, 2007Publication date: July 10, 2008Applicant: FNE Forschungsinstitut fuer Nichteisen-Metalle Freiberg GmbHInventors: Heino Pachschwoell, Joachim Klose, Christiane Rothe, Stefan Jonas, Thomas Stolte
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Publication number: 20080166548Abstract: A coating material for a thermal barrier coating having excellent corrosion resistance and heat resistance comprises a substrate, an undercoat made of an aluminum-containing heat-resistant alloy, Cr2O3 layer as a middle layer on the undercoat, and a top coat made of ZrO2 based ceramic on the middle coat.Type: ApplicationFiled: March 10, 2004Publication date: July 10, 2008Applicant: Tocalo Co., Ltd.Inventors: Yoshio Harada, Tatsuo Suidzui, Takema Teratani
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Publication number: 20080160206Abstract: The present invention relates to dental composites comprising at least one nanoparticulate mixed oxide (a) of SiO2 with X-ray-opaque metal oxides of one or more elements selected from the group consisting of Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu which has been prepared by flame spraying.Type: ApplicationFiled: December 27, 2007Publication date: July 3, 2008Inventors: Peter BURTSCHER, Lutz MADLER, Norbert MOSZNER, Sotiris E. PRATSINIS, Volker M. RHEINBERGER
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Publication number: 20080145553Abstract: A process for the in-flight surface treatment of powders using a Dielectric Barrier Discharge Torch operating at atmospheric pressures or soft vacuum conditions is described herein. The process comprising feeding a powder material into the Dielectric Barrier Discharge Torch yielding powder particles exhibiting a reduced powder agglomeration feature; in-flight modifying the surface properties of the particles; and collecting coated powder particles. An apparatus for surface treating micro- and nanoparticles comprising a Dielectric Barrier Discharge Torch operating at atmospheric pressure or soft vacuum conditions is also described herein.Type: ApplicationFiled: July 31, 2007Publication date: June 19, 2008Applicant: Tekna Plasma Systems Inc.Inventors: Maher I. Boulos, Ulrich Kogelschatz, Christine Nessim
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Publication number: 20080145556Abstract: A method for manufacturing a substrate mounting table having a mounting surface for mounting a substrate thereon; a plurality of gas injection openings opened on the mounting surface to supply a gas toward the mounting surface; a gas supply channel for supplying a gas to the gas injection openings; and a thermally sprayed ceramic layer covering the mounting surface is provided. The method includes forming a removable film at least on inner wall portions of the gas supply channel facing the gas injection openings; forming the thermally sprayed ceramic layer on the mounting surface; and removing the film.Type: ApplicationFiled: December 12, 2007Publication date: June 19, 2008Applicant: TOKYO ELECTRON LIMITEDInventors: Nobuyuki NAGAYAMA, Takehiro Ueda, Yoshiyuki Kobayashi, Kaoru Oohashi
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Publication number: 20080131752Abstract: A nanostructured composite anode with nano gas channel and an atmosphere plasma spray manufacturing method thereof are disclosed. The anode consists of a porous base material and a composite film with nano gas channels above the porous base material while the composite film has a plurality of nano gas pores and a plurality of nano gas channels. The manufacturing method according to the present invention includes the steps of: provide micron-sized agglomerated and nanostructured powders having mixture of nano oxide particles and a binder; heat the micron-sized agglomerated and nanostructured powders into melt or semi-melt oxide mixture; spray the melt or semi-melt oxide mixture on a porous base material; and generate the nanostructured anode composite film with nano gas channels through hydrogen reduction. The anode of the present invention increases the electrochemical activity and slows down nickel particle aggregation effect under high temperature environment.Type: ApplicationFiled: November 30, 2006Publication date: June 5, 2008Inventor: Changsing Hwang
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Publication number: 20080131750Abstract: A ceramic electrolyte is provided. The ceramic electrolyte has a microstructure, which comprises at least a first region comprising a plurality of microcracks having a first average microcrack length and a first average microcrack width, and a second region comprising a second average microcrack length and a second average microcrack width. The microstructure satisfies the criteria of (a) the first average microcrack length being different from the second average microcrack length; or (b) the first average microcrack width being different from the second average microcrack width. A solid oxide fuel cell comprising a ceramic electrolyte having such a microstructure is provided. A method of making a ceramic electrolyte is also described.Type: ApplicationFiled: November 30, 2006Publication date: June 5, 2008Applicant: GENERAL ELECTRICInventors: Todd-Michael Striker, James Anthony Ruud, Stephane Renou
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Publication number: 20080124548Abstract: Ceramic abradable materials, in particular thermally sprayable ceramic abradable powder materials, and abradable seals formed by thermally spraying the materials include dysprosia (Dy2O3) and zirconia (ZrO2). Coatings are porous whereby the porosity, in part, is induced by plastic or fugitive phases. Abradable seal coatings comprising dysprosia and zirconia exhibit improved thermal shock and sintering resistance and can be worn into tolerance by untreated, bare turbine blades, at least in certain regimes of relative blade speed and coating porosity. Ceramic abradable seal coatings comprising dysprosia and zirconia can be used up to 1200° C.Type: ApplicationFiled: June 7, 2007Publication date: May 29, 2008Inventors: Dieter R. Sporer, Ulrike Taeck, Mitchell R. Dorfman, Andrew R. Nicoll, Massimo Giannozzi, Iacopo Giovannetti
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Patent number: 7364798Abstract: It is to propose an internal member for a plasma treating vessel having excellent resistances to chemical corrosion and plasma erosion under an environment containing a halogen gas and an advantageous method of producing the same, which is a member formed by covering a surface of a substrate with a multilayer composite layer consisting of a metal coating formed as an undercoat, Al2O3 film formed on the undercoat as a middle layer and Y2O3 sprayed coating formed on the middle layer as a top coat.Type: GrantFiled: March 7, 2005Date of Patent: April 29, 2008Assignees: Tocalo Co., Ltd., Tokyo Electron LimitedInventors: Yoshio Harada, Junichi Takeuchi, Nobuyuki Nagayama, Kouji Mitsuhashi
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Functional coatings for the reduction of oxygen permeation and stress and method of forming the same
Patent number: 7361386Abstract: The oxidation behavior of the bond coat is improved using a HVOF nanostructured NiCrAlY coating. NiCrAlY powder is mechanically cryomilled and HVOF sprayed onto Ni-based alloy to form a nanocrystalline bond coat. Oxidation is performed on the coating to form the thermally grown oxide layer (thermally grown oxide). After heat treatment at 1000° C. for 24 and 95 hour, a homogeneous ?-Al2O3 layer is formed on top of the bond coat. The nanostructured characteristic of the coating and the presence of Al2O3 within the cryomilled powders (oxidation occurred during cryomilling process) affects the nucleation of the alumina layer on the top of the coating. The formation of a continuous thermally grown oxide layer protects the coating from further oxidation and avoids the formation of mixed oxide protrusions, such as those presented in the coating sprayed using the as-received powder.Type: GrantFiled: July 22, 2003Date of Patent: April 22, 2008Assignees: The Regents of the University of California, Perpetual TechnologiesInventors: George E. Kim, Julie M. Schoenung, Virgil Provenzano, Enrique J. Lavernia, Leonardo Ajdelsztajn -
Publication number: 20080090071Abstract: The present invention relates to a method of coating a surface with nanoparticles, to a nanostructured coating that can be obtained by this method, and also to a device for implementing the method of the invention. The method is characterized in that it comprises an injection of a colloidal sol of said nanoparticles into a plasma jet that sprays them onto said surface. The device (1) comprises: a plasma torch (3); at least one container (5) containing the colloidal sol (7) of nanoparticles; a device (9) for fixing and for moving the substrate(S); and a device (11) for injecting the colloidal sol into the plasma jet (13) of the plasma torch. The present invention has applications in optical, electronic and energy devices (cells, thermal barriers) comprising a nanostructured coating that can be obtained by the method of the invention.Type: ApplicationFiled: October 20, 2005Publication date: April 17, 2008Applicant: COMMISSARIAT A L'ENERGIE ATOMIQUEInventors: Karine Valle, Philippe Belleville, Karine Wittmann-Teneze, Luc Bianchi, Franck Blein
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Patent number: 7357068Abstract: The invention relates to a material based on an oxide ceramic for the manufacture of a surface layer (5) by means of a thermal coating process including aluminum oxide and zirconium oxide, with the material additionally containing chromium oxide for the simultaneous optimization of the hardness and toughness of the surface layer (5).Type: GrantFiled: January 6, 2006Date of Patent: April 15, 2008Assignee: Sulzer Metco AGInventor: Gérard Barbezat
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Publication number: 20080072790Abstract: Methods of making a metallic or cerment coating include suspending solid fine metal or cerment particles in a liquid to form a liquid feedstock and injecting the liquid feedstock into an high-velocity oxygen fuel flame gun to thermally spray the liquid feedstock on a substrate to form a coating thereon.Type: ApplicationFiled: September 20, 2007Publication date: March 27, 2008Applicant: Inframat CorporationInventors: Xinqing Ma, Jeffrey Roth, T. Danny Xiao
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Patent number: 7339142Abstract: The invention relates to a heating device (1) comprising a metallic substrate (2) whose at least one part is coated with a self-cleaning coating. The inventive coating consists of an external layer (4) contacting ambient air and comprising at least one type of oxidation catalyst selected from platinoid oxides, at least one internal layer (3) which is arranged between the metallic substrate and the external layer and comprises at least one type of oxidation catalyst selected from transition elements oxides of 1b group. The inventive heating device can be embodied, for instance in the form of an iron soleplate consisting of a heating base (6) provided with heating elements (7) or a cooking appliance. Said metallic substrate can be covered with an intermediary enamel layer (5). A method for coating the metallic substrate of a heating device with said coating is also disclosed.Type: GrantFiled: November 20, 2003Date of Patent: March 4, 2008Assignee: SEB S.A.Inventors: Stéphanie Pessayre, Henry Boulud
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Patent number: 7306828Abstract: The present invention is directed towards a ceramic nanocomposite comprising a nanostructured carbon component inside a ceramic host. The ceramic nanocomposite may further comprise vapor grown carbon fibers. Such nanostructured carbon materials impart both structural and thermal barrier enhancements to the ceramic host. The present invention is also directed towards a method of making these ceramic nanocomposites and for methods of using them in various applications.Type: GrantFiled: December 22, 2005Date of Patent: December 11, 2007Assignee: William Marsh Rice UniversityInventors: Enrique V. Barrera, Leonard Lee Yowell, Jr., Brian Mitchell Mayeaux, Erica L. Corral, Joseph Cesarano, III
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Patent number: 7294413Abstract: A protected article includes a substrate having a surface, and a protective system overlying and contacting a first portion of the surface of the substrate. The protective system has a nickel-base superalloy bond coat, an aluminide layer overlying and contacting the bond coat, and a dense vertically microcracked ceramic thermal barrier coating overlying and contacting the aluminide layer.Type: GrantFiled: March 7, 2005Date of Patent: November 13, 2007Assignee: General Electric CompanyInventors: Bangalore Aswatha Nagaraj, D. Keith Patrick, Thomas John Tomlinson, David Walter Parry