Abstract: A method for applying a thermal spray coating onto a substrate (24) includes the steps of providing chamber apparatus (10) including a chamber (16) having a gas flow assembly (23) that includes a gas injector (27) and a spray nozzle (30) therein for introducing, a gas and spray coating. The chamber has an adjustably sized restricted opening (18) that is continuously open to the ambient atmosphere (21) that is exterior of the chamber (16). The total gas flow is maintained from the gas flow assembly (23) at a predetermined rate based on the size of the restricted opening (18) and the amount of oxygen that is desired to be present during the spraying of the coating and thereafter until the spray coating solidifies on the substrate. Gas flow from the spray nozzle (30) is determined by optimum process parameters for coating specified materials. If the gas flow from the nozzle (30) is insufficient to provide the total gas flow, the gas injector (27) supplements the total gas flow.

Abstract: After primary blasting is applied to the outer circumferential surface of a cylindrical valve lifter the upper end of which is closed with an abrasive to form a rough surface, a secondary blasting is applied to the rough surface with an abrasive which has particle size smaller than that of the first abrasive. Smaller irregularities are formed on the rough surface, and a coated layer is formed by thermal spraying on the surface, thereby increasing adhesive strength of the coated layer by anchoring effect.

Abstract: An impervious corrosion resistance nickel-chromium coating on a metallic substrate, such as an iron-containing alloy substrate that protects the substrate from a corrosive media and the process for producing the coating on the substrate.

Abstract: An evaporation material is used in manufacturing a VTR tape, a vertical magnetic recording thin film or the like. The evaporation material is a wire comprising a cobalt metal, a cobalt nickel alloy containing not more than 30 weight % of nickel, or a cobalt-chromium alloy containing not more than 30 weight % of chromium. This wire has a diameter of at least 1.0, mm and not more than 10 mm, a tensile strength of at least 400 MPa and not more than 1500 MPa, and a elongation and a reduction of area of at least 5%. The evaporation material has a prescribed crystal structure, with a face centered cubic lattice ratio of at least 0.1 and not more than 1.

Abstract: A method for manufacturing a composite part is provided. A polymer material s formed into a shape whose outer surface has a desired part configuration. A base coating is applied to substantially all of the outer surface leaving at least one access to the polymer material. The base coating includes a selected metal existing as a constituent thereof. The same selected metal is then sprayed in atomized form on the base coating covered outer surface. The selected metal in atomized form molecularly bonds only to the selected metal existing as a constituent of the base coating. The polymer material is then contacted with a polymer solvent by means of the access. The polymer solvent molecularly breaks down the polymer material such that it exits the access. As a result, the selected metal in atomized form bonded with the selected metal existing as a constituent of the base coating forms a metallic shell substantially void of the polymer material.

Abstract: A method of making quasicrystalline alloy particulates wherein an alloy is superheated and the melt is atomized to form generally spherical alloy particulates free of mechanical fracture and exhibiting a predominantly quasicrystalline in the atomized condition structure. The particulates can be plasma sprayed to form a coating or consolidated to form an article of manufacture.

Abstract: A metallized epoxy die formed by depositing boron nitride and iron oxide particle layers on the pattern used to form the die and spraying molten metal onto the particle layers followed by casting the epoxy against the exposed surface of the sprayed metal.

Abstract: The finishes of the present invention consist essentially of metal alloys having the general formula:T.sub.a Cr.sub.b Zr.sub.c B.sub.d M.sub.e M'.sub.f X.sub.g I.sub.h (I)in which a+b+c+d+e+f+g+h =100 atomic percent;T is Ni, Co, Ni--Co or any combination of at least one of Ni and Co with Fe, wherein 3<Fe<82 at. % and 3<a<85 at. %;M is one or more elements of the group consisting of Mn, Cu, V, Ti, Mo, Ru, Hf, Ta, W, Nb, Rh, wherein 0<e<12 at. %;M' is one or more rare earths, including Y, wherein 0<f<4 at. %;X is one or more metalloids of the group consisting of C, P, Ge and Si, wherein 0<g<17 at. %;I represents inevitable impurities, wherein h<l at. %, and 5.ltoreq.b.ltoreq.25, 5.ltoreq.c.ltoreq.15, and 5.ltoreq.d.ltoreq.18.Powders obtained from these alloys that are deposited on substrates by thermal projection provide finishes having increased hardness in addition to high ductility and excellent resistance to corrosion.

Abstract: A method for coating metal cookware includes (a) roughening and cleaning a cooking surface of the metal cookware's inner wall by spraying aluminum oxide of 60-80 mesh onto the inner wall surface; (b) applying a mechanically resistant layer onto the roughened and cleaned cooking surface of the metal cookware by electric-arc spraying at a temperature of 4500.degree.-8000.degree. C., under a pressure of 5-8 kg/cm.sup.2, and with a voltage of 30-40 V and a direct current of 100-300 A, the mechanically resistant layer being made of a metallic material, and (c) applying a lubricative layer, which consists essentially of PTFE (polytetrafluoroethylene), onto the mechanically resistant layer by spray coating until the lubricative layer has a thickness of about 23-36 .mu.m and whereby a pencil hardness of 8-9H is achieved.

Abstract: High performance clutch assembly having a refractory metal carbide thermal spray coated onto the clutch disc engagement surfaces and method.

Abstract: A manufacturing method for immersion members for molten metal baths, wherein a thermal sprayed coating including 1-50 wt % of tungsten boride, 3-25 wt % of one or more of Ni, Co, Cr, and Mo as a metal phase, and a remainder including tungsten carbide, is formed on the surface of a immersion member for use in molten metal baths, and subsequently, impregnation processing is conducted with respect to the thermal sprayed coating in a processing fluid having as a main component thereof chromic acid (H.sub.2 CrO.sub.4 and H.sub.2 Cr.sub.2 O.sub.7), and subsequently, baking processing is conducted. In accordance with this manufacturing method, a surface layer possessing fine microstructure and high bond strength not conventionally available is provided, and it is possible to manufacture a superior immersion member for use in molten metal baths which has superior resistance to corrosion, resistance to corrosive peeling, and resistance to abrasion, and to which metals do not easily adhere.

Abstract: Particles such as magnetic iron oxide capable of being magnetized are crushed to obtain minute magnetic particles each size of which is not larger than 10 .mu.m. The minute magnetic particles are mixed as they are dispersed with such a binding material as cobalt or nickel. Thermal spraying particles each size of which is not smaller than 10 .mu.m are obtained from the mixture. Then, the thermal spraying particles are sprayed upon such a member as a turbine shaft to form a magnetic film on the member with plasma spraying method.

Abstract: An apparatus (10) for applying a thermal spray coating onto a substrate (24) includes a chamber (16) having an open bottom portion (18), a gas source for releasing a gas lighter than oxygen into the chamber (16) and displacing the oxygen from the chamber (16), and a spray gun (30) for spraying coating through the gas in the chamber (16) and onto the substrate (24).A method is also provided including the steps of displacing oxygen from the chamber (16) with the gas, and spraying the coating through the gas and onto the substrate (24) disposed within the chamber, the gas preventing oxidation between the substrate (24) and layers of the coating.

Abstract: The method of treating the surfaces of malleable light metal cylinder bores or other objects by blasting the surfaces with extremely high water jets for preparing such surfaces for subsequent coating with wear-resistant materials such as a thermal spray coating. The water not only cleans the surface but roughens it to produce a pitted surface with undercuts so that coating material fills the pits and undercuts to provide a smooth layer of coating material with a strong mechanical/adhesive bond.

Abstract: A method of forming binderless clad powders using a high energy ball mill, preferably an attritor-type ball mill, is described. The binderless clad powders are formed by combining and processing a core material powder and a coating material (either a powder with significantly smaller particle size than the core material powder or a brittle material that will quickly form a powder with significantly smaller particle size than the core material powder) in a high energy ball mill for a relatively short time (generally less than one hour The processing time employed is such that the particle size of the core material powder is not significantly reduced but that the clad powders are formed. At least one of the two materials (i.e., core forming material or coating forming material) must be deformable within the high energy ball mill. Such binderless clad powders are suitable for use as thermal spray powders and which can be thermally sprayed to form coatings on a various substrates.

Abstract: A method of thermally spraying a solid lubricant (i.e. graphite or BN) impregnated metal matrix onto a metal target, using the steps of: (a) creating a flame or arc into which a consummable strand is fed, the strand being constituted as a hollow sheath of metal and a core therein comprising essentially solid lubricant powder particles, the flame or arc melting the metal of such strand; (b) applying a pressurized jet of atomizing gas to the melt and included graphite particles to project a spray of molten heavy metal and graphite particles generally homogeneously distributed throughout such spray, said graphite being protected against ablation during transit from the flame or arc to the target; and (c) surface heat treating essentially only the deposit to precipitate additional graphite while densifying the metal and controlling microstructure.

Abstract: The method for preparing a coating with a continuous compositional gradient includes introducing at least first and second powders into a plasma torch at separately controllable variable feed rates for each powder and co-depositing the at least first and second powders on the substrate and adjusting the relative feed rates of the first and second powders such that a smooth continuous compositional grading is achieved in the coating. The compositional gradient can follow a linear, exponential or variable function. A sublayer may be deposited onto the substrate prior to deposition of the compositionally graded layer. Additional materials that impart other desirable properties to the layer can be added with the layer or applied after deposition of the layer. Choice of atmosphere during deposition include vacuum, inert atmosphere, and oxidizing, carburizing and boriding atmospheres.

Abstract: A method of making an anti-friction coating on a metal surface subject to sliding wear, including the steps of: forming an encapsulated powder having grains made of a core of solid lubricants including at least graphite and MoS.sub.2 (others may include BN, NaF, LiF, CaF.sub.2, and WS.sub.2), and a thin shell of fusable soft metal such as Ni, Co, Fe, Zn, Sn, Mg, or Cu; plasma spraying the powder onto a light metal surface, such as a cylinder bore wall of an internal combustion engine, to form a coating; and finish-smoothing the coating to a uniform thickness of about 25-175 microns. Some core particles may be hard, wear-resistant particles such as SiC, NiCrAl, FeMn, FeCrAl, FeWNiVCr, NiCrMoVW, FeCrMoWV, CoFeNiCrMoWV, NiCrMoV, and CoMoCrVW.

Abstract: A coated metal substrate with a ceramic composition and method which involves applying several layers of the following materials:a. stainless steelb. thermal shock resistant ceramic coating; andc. abrasion resistant ceramic material.Each layer of each material is applied by flame spray means to the metallic substrate which is at a temperature above 250.degree. F. but below 500.degree. F., which is then cooled to a temperature below 250.degree. F. before applying the next layer. Zirconium oxide is a preferred thermal shock resistant ceramic coating and aluminum oxide is the preferred abrasion resistant ceramic material.

Abstract: An impervious corrosion resistance nickel-chromium coating on a metallic substrate, such as an iron-containing alloy substrate that protects the substrate from a corrosive media and the process for producing the coating on the substrate.

Abstract: A method of improving the erosion resistance of the surface of a metal substrate by the technique of applying a dense and adherent alloy coating comprised of niobium carbide in a ductile matrix such as cobalt-chromium to the substrate surface using a hypersonic flame spray gun.

Abstract: A method is disclosed for the electric arc spraying of powder-filled cored wires to apply hard, wear-resistant coatings to various substrates. Inert gas, preferably nitrogen, is supplied to the arc spray gun such that the mass ratio of the wire feed rate to the gas feed rate is preferably between about 0.07 and about 0.11. Operation in this range yields an optimum combination of coating hardness properties and arc spray gun operating characteristics.

Abstract: The oxidation resistance of MCrAlY-type overlay coatings is improved by incorporating small discrete oxide particles into the coating. The particles are preferably yttrium oxide, and the coating is applied by simultaneously plasma spraying MCrAlY-type powder particles and oxide particles onto a substrate in a nonoxidizing atmosphere. Improvements in resistance to rumpling has also been observed in coatings applied according to this invention.

Abstract: A method for the application of a thermal spray coating to the cylinder wall portions of an aluminum engine block casting is disclosed in which the casting is inverted and water is caused to flow through the cooling passages of the engine block in a series flow from one end of a bank of cylinders to the other while the block is supported on a fixture that seals the cooling passage outlets in the head of the block. The fixture further permits the spray of a metallized coating onto the cylinder walls without adherence of the spray to the fixture or to other portions of the block.

Abstract: A method of operation of a plasma torch, an internal burner or the like to produce a hot gas jet stream directed toward a workpiece to be coated by operating the plasma torch or internal burner at high pressure while feeding a powdered material to the stream to be heated by the stream and projected at high velocity onto a workpiece surface.

Abstract: The plasma producing gas consists of a ternary mixture of helium, argon and hydrogen and contains at least about 10% hydrogen, typically 30 to 70% helium, 10 to 50% argon and 10 to 25% hydrogen, preferably 20% (.+-.5%) hydrogen. Use for the plasma projection of metallic oxide.

Abstract: Metallurgical bonded thermally sprayed coatings of exceptional bond strength are provided by a metal surface, prior to thermal spray coating, being electrochemically cleaned, or more desirably being electrochemically cleaned and electrochemically metallized, prior to overlaying with a thermal spray deposited metal coating with after depositing the thermal spray coating proceeding with a post heat treatment.

Abstract: A process for producing a roll stamper which molds a substrate sheet for information recording mediums by continuously transferring preformat patterns on a resin sheet. The roll stamper has the feature that the preformat pattern on the roll stamper has a value b/a of greater than 1, where the length of the preformat pattern in the direction parallel to the direction in which the resin sheet is transported is defined as a and the length in the direction perpendicular thereto as b.

Abstract: A method for forming an abradable composite material and the material so formed. A filler is fed axially into a stream of high-temperature combustion gases such that the filler is entrained in the gaseous stream. The gaseous stream containing the filler is then used to atomize the molten tip of a metal wire which is continuously fed into the gaseous stream. The resultant gaseous stream which contains both the filler and the atomized molten metal is directed to the surface of a target. The filler and the molten metal impact the target and combine to form a substantially continuous metal matrix in which the interstices are filled by the filler. The composite material abrades readily upon frictional contact with a moving part.

Abstract: An article is coated with a thermal barrier coating system to increase its thermal cyclic spallation life. A single layer bond coating is applied to the surface of the article to a surface roughness in the range of 200 to 600 microinches RA by low pressure plasma spraying of coarse MCrAlY alloy particles into the surface. A metal selected from aluminum and its alloys is applied to the bond coating by aluminiding and is diffused into the bond coating to provide an aluminum-rich bond coating metal outer surface, while substantially retaining the surface roughness of about 2300 to 600 microinches RA. A metal oxide thermal barrier coating layer is then applied onto the aluminum-rich bond coating outer surface.

Abstract: A structural component made of a base metal composition on a nickel or cobalt basis is provided with a protective coating against oxidation, corrosion, and thermal fatigue. The protective coating and the base metal are made of chemically the same or identical material, whereby the bonding of the protective coating is increased, the tendency to crack is reduced, and the resistance to thermal fatigue is improved. The grain size of the coating is substantially smaller than the grain size of the base metal composition.

Abstract: A metal matrix composite is produced by forming a rapidly solidified aluminum base alloy into powder. The powder is plasma sprayed onto at least one substrate having thereon a fiber reinforcing material to form a plurality of preforms. Each of the preforms has a layer of the alloy deposited thereon, and the fiber reinforcing material is present in an amount ranging from about 0.1 to 75 percent by volume thereof. The preforms are bonded together to form an engineering shape.

Abstract: A method of using multilayered member for fusing thermoplastic resin toner images to a substrate in a fuser system of the type wherein a polymeric release agent having functional groups is applied to the surface of the fuser member. The multilayered fuser member has in sequential order a base support member, an adhesive layer comprising a copolymer of vinylidene fluoride and hexafluoropropylene and at least 20% by weight of the adhesive layer of a coupling agent comprising at least one organo functional silane and an activator, a tie coat layer of active ingredients comprising a copolymer of vinylidene fluoride and hexafluoropropylene and an outer elastomeric fusing surface comprising a copolymer of vinylidene fluoride and hexafluoropropylene and containing a metal oxide present in an amount sufficient to interact with a polymeric release agent having functional groups to provide an interfacial barrier layer between said fusing surface and toner.

Abstract: A method of forming high temperature resistant coatings having magnetic particles in a ceramic matrix by plasma spraying. Typically, the surface to be coated is cleaned by a combination of solvent cleaning and abrasion, such as by grit blasting. A mixture of ceramic particles and metal particles is provided and the mixture is plasma sprayed onto the surface using a sufficiently large proportion of metal particles to form a conductive first coating layer. A second layer is plasma sprayed with a mixture having a gradually decreasing metal particle content. A third layer is plasma sprayed using a mixture having a sufficiently low proportion of metal particles as to be dielectric. A pattern of small, spaced, conductive areas is then formed on the surface of the third layer. The resulting coating is durable, high temperature resistant and absorbs incident microwave energy.

Abstract: A process for manufacturing metal and ceramic matrix composite materials. The invention also encompasses various composite products made by the disclosed method. The resulting composite material comprises a reinforcement material in either continuous or discrete form embedded in a matrix material which is either a pure metal, a metal alloy, or a ceramic. The reinforcing material is optionally coated with a barrier coating material. An electric arc or plasma arc is used to spray a thin layer of matrix material over a preplaced layer of reinforcement material. Successive layers are built up until a desired object shape and thickness are achieved. There is an optional final step of high-temperature diffusion annealing or hot isostatic pressing.

Abstract: A method of the thermally spraying a solid lubricant (i.e. graphite or BN) impregnated metal matrix onto a metal target, using the steps of: (a) creating a flame or arc into which a consummable strand is fed, the strand being constituted as a hollow sheath of metal and a core therein comprising essentially solid lubricant powder particles, the flame or arc melting the metal of such strand; (b) applying a pressurized jet of atomizing gas to the melt and included graphite particles to project a spray of molten heavy metal and graphite particles generally homogeneously distributed throughout such spray, said graphite being protected against ablation during transit from the flame or arc to the target; and (c) surface heat treating essentially only the deposit to precipitate additional graphite while densifying the metal and controlling microstructure.

Abstract: A metal fastener, suitable for use in connection with wood construction and coated with a polymeric residue produced by removing water from an aqueous dispersion of a film-forming, thermoplastic, predominantly aliphatic polyurethane resin, so as to thereby reduce penetration force, increase withdrawal force, and protect against corrosion, is disclosed. Before the polyurethane coating is applied, a zinc layer is applied so as to coat the fastener, and a chromate conversion layer is applied so as to coat the zinc layer.

Abstract: A metallic "close-out" layer is applied to the surface of a thermal barrier coating system to seal the ceramic material in the coating. The "close-out" layer is glass-bead preened to densify the surface.