Particles Applied Patents (Class 427/71)
  • Publication number: 20020001669
    Abstract: A preparation method of an oxygen-introduced rare earth activated alkaline earth metal fluorohalide stimulable phosphor is disclosed, comprising (a) preparing a reactant solution having a barium concentration of not less than 3.3 mol/l in a reaction vessel, (b) forming a precursor of the stimulable phosphor, and (c) removing a solvent from a mother liquor.
    Type: Application
    Filed: April 20, 2001
    Publication date: January 3, 2002
    Inventors: Hideaki Wakamatsu, Hiroto Itoh, Hiroyuki Nabeta, Kanae Kawabata
  • Publication number: 20010045186
    Abstract: The present invention is directed towards a method of preventing fine particles, especially liming material, from becoming air borne, and the addition of desirable chemical compounds to the particles. The method comprises feeding fine particles of solid to an enclosed inclined chute and locating at least a first inclined shelf and a subsequent inclined shelf within the chute, each shelf having an inclined top surface, a bottom surface and a leading edge. An addition funnel fitted with air pads may be used at the top of the chute to facilitate the even and continuous addition of particulates to the chute. Once the particles are fed to the top of the chute, they fall on the top surface of the first inclined shelf and slide down the inclined top surface by force of gravity until falling from the leading edge, thus forming a vertical free flow of particles.
    Type: Application
    Filed: May 11, 1999
    Publication date: November 29, 2001
    Inventors: GREGORY B. PENDLETON, FRED R. HUEGE
  • Patent number: 6287629
    Abstract: A method of producing a color cathode ray tube occurs by forming pigment-coated particles by applying pigment coatings to green, blue, and/or red fluorescent particles, such that the coatings cover about half of each particle; forming a black matrix film having light transmission window portions on the inner surface of a glass panel; and applying the pigment-coated particles to the light transmission window portions so that substantially all of the pigment coating on each particle is located between the phosphor it coats and the inner surface of the glass panel.
    Type: Grant
    Filed: May 11, 2000
    Date of Patent: September 11, 2001
    Assignee: NEC Corporation
    Inventor: Nobumitsu Aibara
  • Patent number: 6242043
    Abstract: A method of providing moisture resistance of inorganic particles such as alkaline earth metal aluminate phosphors comprising firing the phosphor in the presence of ammonium fluoride or ammonium difluoride at a temperature of at least 500° C. The phosphor particles become coated with a moisture-impervious coating that does not degrade the luminescence of the phosphors and can withstand complete immersion in water for long periods of time.
    Type: Grant
    Filed: December 28, 1999
    Date of Patent: June 5, 2001
    Assignee: Sarnoff Corporation
    Inventor: Steven Lipp
  • Publication number: 20010002277
    Abstract: A method of forming a zinc or indium oxide layer at the surface of phosphors deposited by serigraphy on a substrate, including the steps of adding the grains to a solution of a serigraphy binder in water, dissolving in the solution a zinc or indium nitrate, performing the serigraphy deposition, and annealing.
    Type: Application
    Filed: November 2, 1999
    Publication date: May 31, 2001
    Inventor: REMI VALERO
  • Patent number: 6187487
    Abstract: A method for developing an electrostatic latent charge image formed on a photoreceptor 36 which is disposed on an interior surface of a faceplate panel 12 of a CRT 10 utilizes a developer 40 having a developing chamber 42 with a sidewall 50 closed by a bottom end 44 and a panel support 46 at the other end. An opening 48 is formed through the panel support 46 to provide access to and support for the faceplate panel 12. A panel grid 74 is disposed in proximity to said interior surface of said faceplate panel 12 and operated at a first potential to control the electric field from the latent charge image. A tank grid 56 is disposed within said developer 40 and spaced from the sidewall 50, the bottom 44 and the panel grid 74. A triboelectric gun 84 is disposed within the developer 40 for imparting a desired charge polarity to the screen structure material and for distributing the charged screen structure material onto the latent charge image.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: February 13, 2001
    Inventors: James Regis Matey, Eugene Samuel Poliniak, Brian Thomas Collins, Peter Michael Ritt
  • Patent number: 6162490
    Abstract: A system and method for applying a thick layer of luminescent emissive material, such as phosphor, to a substrate, such as a data storage cartridge, is provided whereby a luminescent emissive material is mixed with a binder, the mixture is dispensed onto a mesh screen placed over a substrate, and the mixture is then pushed through the mesh screen and applied to the substrate at a predetermined thickness. The predetermined thickness of the deposited phosphor layer is preferably between about 8 and 12 mils.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: December 19, 2000
    Assignee: Iomega Corporation
    Inventors: Todd L. Graves, Wayne A. Sumner
  • Patent number: 6022652
    Abstract: A method for creating a faceplate of a display provides a faceplate substrate with a faceplate interior side and a faceplate exterior side. A plurality of barriers are formed on the faceplate interior side, with the barriers defining a plurality of subpixel volumes. Phosphor containing photopolymerizable material mixtures of red, green and blue, are deposited into subpixel volumes, and create a faceplate interior side/phosphor interface. At least a portion of the phosphor containing photopolymerizable material mixture is exposed with sufficient actinic light through the faceplate interior side/phosphor interface to polymerize a selected depth of the phosphor containing photopolymerizable material mixture in the subpixel volumes, and form a polymerized phosphor containing material in a plurality of subpixel volumes. Non-polymerized phosphor containing photopolymerizable material is removed from the polymerized phosphor containing material.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: February 8, 2000
    Assignee: Candescent Technologies Corporation
    Inventors: Duane A. Haven, Paul M. Drumm, Robert M. Duboc, Jr.
  • Patent number: 5955226
    Abstract: There is disclosed a display screen obtained such that a first pigment layer and a resist layer are exposed and developed, then a second pigment layer is formed on the photoresist pattern, and the resultant structure is coated with a resist decomposition agent to remove the photoresist pattern and the second pigment layer formed on the photoresist pattern.
    Type: Grant
    Filed: September 24, 1997
    Date of Patent: September 21, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hidemi Matsuda, Takeo Itou, Makoto Onodera, Yoshinori Takahashi, Norihisa Nakao
  • Patent number: 5919555
    Abstract: An anti-reflection film comprises a transparent support and a low refractive index layer. The low refractive index layer has a refractive index of not higher than 1.45. The low refractive index layer comprises a binder polymer and micro polymer particles. The micro polymer particles are superposed upon each other to form micro voids surrounded by the particles. The micro polymer particles have a mean particle size in the range of 5 to 200 nm. According to the first embodiment of the present invention, the particles comprise a cross-linked polymer. According to the second embodiment of the present invention, the particles comprise a polymer cross-linked to the binder polymer.
    Type: Grant
    Filed: November 5, 1997
    Date of Patent: July 6, 1999
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tomokazu Yasuda, Tsukasa Yamada, Hirohisa Hokazono
  • Patent number: 5882779
    Abstract: A class of high efficiency (e.g., .gtoreq.20%) materials for use as display pixels to replace conventional phosphors in television, monitor, and flat panel displays. The materials are comprised of nanocrystals such as CdS.sub.x Se.sub.1-x, CuCl, GaN, CdTe.sub.x S.sub.1-x, ZnTe, ZnSe, ZnS, or porous Si or Ge alloys which may or may not contain a luminescent center. The nanocrystals may be doped with a luminescent center such as Mn.sup.2+ or a transition metal. The nanocrystals have passivated surfaces to provide high quantum efficiency. The nanocrystals have all dimensions comparable to the exciton radius (e.g., a size in the range of approximately 1 nm to approximately 10 nm). A quantum dot nanocrystal display phosphor that has a size selected for shifting an emission wavelength of a constituent semiconductor material from a characteristic wavelength observed in the bulk to a different wavelength.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: March 16, 1999
    Assignee: Spectra Science Corporation
    Inventor: Nabil M. Lawandy
  • Patent number: 5859494
    Abstract: The present invention relates to a process for manufacture of color cathode-ray tube for preventing the deterioration of color purity of red phosphor while enhancing the brightness and the contrast of color cathode-ray tube, which comprises steps of forming a black matrix film corresponding to 3 colors of green(G), blue(B) and red(R) onto the panel glass by using 0.067-0.075 g atom (content relative to 1 mol of Y.sub.2 O.sub.3) of europium(Eu) as an activator for red phosphor; forming a 3 color fluorescent film onto said black matrix film, wherein said 3 color fluorescent film consists of green phosphor, red phosphor to which predetermined amount of red pigment having 50-70% of reflectance has been adhered, and blue phosphor to which predetermined amount of blue pigment having 50-65% of reflectance has been adhered; coating an organic film on the 3 color fluorescent film; forming a metal reflective film thereon; and thermally decomposing the organic film at high temperature to obtain a fluorescent plane.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: January 12, 1999
    Assignee: LG Electronics Inc.
    Inventor: Hae-Beob Jeong
  • Patent number: 5756241
    Abstract: For the manufacture of a color screen for a cathode ray tube a process is described which uses a single photolithographic mask for defining multiple patterns, so that said single mask may be used for determining the different areas where several different phosphor layers will be located. Masks used for conventional photolithographic processes normally comprise a pattern of regions that are either fully transparent or fully opaque to the radiation used for exposing the resist. The mask used as part of the present invention includes regions that are neither fully transparent nor fully opaque, having, instead, a grey scale of optical densities. Through careful control of both exposure and development time, selected parts of a layer of a positive photoresist, that were exposed through successively denser regions of the mask, can be successively removed.
    Type: Grant
    Filed: April 8, 1996
    Date of Patent: May 26, 1998
    Assignee: Industrial Technology Research Institute
    Inventors: Nan-Chou David Liu, Jin-Yuh Lu
  • Patent number: 5728221
    Abstract: A method and apparatus for forming a fluorescent layer for a black-and-white CRT is disclosed including: a first rotation shaft installed perpendicular to the horizontal plane; a rotation table fixed to the first rotation shaft and integrally formed with a sloped portion, the table being rotated along with the first rotation shaft; a second rotation shaft installed perpendicular to the sloped surface of the sloped portion; and a deposition table fixed to the second rotation shaft and in which a bulb can be mounted.
    Type: Grant
    Filed: July 20, 1995
    Date of Patent: March 17, 1998
    Assignee: LG Electronics Inc.
    Inventor: Seoug Wan Kang
  • Patent number: 5707682
    Abstract: A method of manufacturing a phosphor screen (22) on an interior surface (23) of a faceplate panel (12) is characterized by the steps of: forming a light-absorbing matrix (24) on an interior surface (23) of the faceplate panel (12); applying an aqueous surfactant solution thereto to solubilize oily contaminants and emulsify undissolved oily contaminants of the matrix (24); and serially applying three light-emitting phosphors (G, B, R) to the interior surface (23) of the faceplate panel (12) to form the phosphor screen (22).
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: January 13, 1998
    Assignee: Videocolor S.p.A.
    Inventors: Himanshu M. Patel, Antimo Pezzulo
  • Patent number: 5674554
    Abstract: A method for forming a layer of particles on a substrate, such as a layer of phosphor particles on the inside of a CRT, is described. The depends on the use of a double-sided adhesive tape comprising a laminate of a dry adhesive between two protective layers. One of the protective layers is stripped away to expose one surface of the dry adhesive layer which is then pressed up against the substrate surface using a method such as rolling or autoclaving to bring about bubble-free adhesion. The other protective layer is then stripped away, thereby exposing the other surface of the adhesive layer. The particles that will comprise the final layer are then applied to the exposed adhesive surface by means of dusting. This is followed by the removal of any weakly adhering particles from the final particle layer. Finally, the dry adhesive layer is itself removed by means of a heat treatment, leaving in place a uniform layer of particles adhering to the substrate surface.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: October 7, 1997
    Assignee: Industrial Technology Research Institute
    Inventors: Nan-chou David Liu, Jin-Yuh Lu, Lyuji Ozawa
  • Patent number: 5665422
    Abstract: The present invention relates to an ultrafine particle film which is effective for the prevention of electrostatic charge and reflection of visible light and can be applied to a large area, and a process for producing an image display plate to which the ultrafine particle film is applied.This process comprises attaching an object to be coated to a coating solution bath, filling the coating solution bath with a coating solution containing ultrafine particles with a high refractive index, and then exposing the object to be coated, to form an electrically conductive film, the above procedure being repeated by the use of a coating solution containing ultrafine particles with a low refractive index to form a visible light anti-reflection film.
    Type: Grant
    Filed: March 30, 1995
    Date of Patent: September 9, 1997
    Assignee: Hitachi, Ltd.
    Inventors: Yoshishige Endo, Masahiko Ono, Hiromitsu Kawamura, Katsumi Kobara
  • Patent number: 5637357
    Abstract: A technique for uniformly depositing particles, especially phosphor particles, onto a display panel and an apparatus for carrying out this technique are set forth in this application. This technique relies on both electrostatically and pneumatically passing charged particles to the display panel so that a uniform coating takes place both on the flat surfaces and on the curved surfaces.
    Type: Grant
    Filed: December 28, 1995
    Date of Patent: June 10, 1997
    Assignee: Philips Electronics North America Corporation
    Inventors: Gustav A. Stachelhaus, Gary S. Gielincki
  • Patent number: 5629051
    Abstract: A method and apparatus for forming an insulator 62 on one major surface of a uniaxial tension focus mask 25 includes the steps of: positioning a mask sheet 27, having a multiplicity of openings 42 that extend from a first major surface of the mask sheet through a main body portion thereof to an oppositely disposed second major surface, at a distance from a charging gun 72, 172 having a source 74, 174 of a dry-powdered insulative material; charging and directing the dry-powdered insulative material toward the first major surface of the mask to provide a coating of the charged, dry-powdered insulative material thereon, and providing means 70, 272 for preventing the charged, dry-powdered insulative material from extending into the openings 42 and being deposited onto the main body portion of the mask surrounding the openings and the second major surface.
    Type: Grant
    Filed: September 18, 1995
    Date of Patent: May 13, 1997
    Assignee: Thomson Multimedia, S. A.
    Inventor: Eugene S. Poliniak
  • Patent number: 5624602
    Abstract: The maintenance of a fluorescent lamp containing terbium-activated cerium magnesium aluminate phosphor is improved by combining the phosphor with a small particle size aluminum oxide and wet-milling the phosphor/aluminum oxide mixture before applying the phosphor to the interior of a fluorescent lamp envelope.
    Type: Grant
    Filed: December 30, 1994
    Date of Patent: April 29, 1997
    Assignee: Osram Sylvania Inc.
    Inventors: Joseph J. Lenox, Richard I. Manahan
  • Patent number: 5601751
    Abstract: A process is provided for manufacturing high-purity phosphors having utility in field emission displays. The high-purity phosphor is a host lattice infiltrated by a dopant that activates luminescent properties therein. The lattice and dopant are initially milled together to reduce their average particle size while simultaneously achieving complete mixing between the lattice and the dopant. The resulting mixture is maintained free of a flux or substantially any other treatment agent capable of contaminating the phosphor and placed in a heating vessel formed from a substantially impervious contaminant-free material. The mixture is heated to a high temperature effectuating thorough infiltration of the dopant into the lattice structure. The use of an impervious contaminant-free heating vessel and the exclusion of flux or other treatment agents from the mixture avoids undesirable contamination and undue particle size growth of the phosphor product during the manufacture thereof.
    Type: Grant
    Filed: June 8, 1995
    Date of Patent: February 11, 1997
    Assignee: Micron Display Technology, Inc.
    Inventors: Charles M. Watkins, Surjit S. Chadha
  • Patent number: 5453292
    Abstract: To improve the uniformity and the adhesive strength of luminophore layers, a process is proposed in which the luminophore is enveloped with glass flux and the enveloped luminophore is applied to a luminophore carrier at elevated temperatures by using acrylic resin.
    Type: Grant
    Filed: November 6, 1990
    Date of Patent: September 26, 1995
    Assignee: Licentia Patent-Verwaltungs-GmbH
    Inventors: Klaus Gerland, Klaus Hoffmann, Hermann Widmann
  • Patent number: 5441774
    Abstract: In process for forming a coating of phosphor particles on a fluorescent lamp glass, a polymer is deposited on the phosphor particles and the phosphor particles are entrained in a carrier gas with the polymer in a non-adhering state, and then the phosphor particles are coated on the fluorescent lamp glass with the polymer in an adhering state for retaining the phosphor particles on the fluorescent glass and, the coated fluorescent glass is heated to a temperature above the decomposition temperature of the polymer for removing the polymer and to form a coating of phosphor particles on a fluorescent lamp glass.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: August 15, 1995
    Assignee: Osram Sylvania Inc.
    Inventors: Arunava Dutta, Leonard V. Dullea
  • Patent number: 5418005
    Abstract: A method for reclaiming a pigment-attached red-emitting phosphor recovered from a manufacturing process for a color picture tube, which comprises treating the phosphor with an aqueous solution containing NaOH, NaClO and H.sub.2 O.sub.2 and then treating it with a weak acid, whereby the pigment can be prevented from exfoliation by suppressing the dissolution of the binder which attaches the pigment to the phosphor, and blue- and green-emitting phosphors contained as contaminants in the recovered red-emitting phosphor can be completely removed. The method provides a reclaimed red-emitted phosphor with high luminance and a good coating property.
    Type: Grant
    Filed: September 24, 1993
    Date of Patent: May 23, 1995
    Assignee: Kasei Optonix, Ltd.
    Inventors: Hideo Endo, Shinsuke Aoki, Chihiro Yoshida
  • Patent number: 5358734
    Abstract: A fluorescent lamp comprising a sealed envelope, a pair of opposing electrodes, a fill of inert gas and mercury and a phosphor coating on the internal walls of the envelope wherein the coating contains as at least one element thereof particles of europium activated barium magnesium aluminate having an average particle size of about 4 micrometers, less than about 5% of the particles having a size greater than 15 microns and less than about 5% of the particles having a size less than about 1 micron, said particles having on the external surfaces thereof a coating of sub-micron aluminum oxide having a surface area of from about 80 to about 120 square meters per gram, said coating being sufficient to impart stir in quality to said phosphor.
    Type: Grant
    Filed: November 24, 1993
    Date of Patent: October 25, 1994
    Assignee: GTE Products Corporation
    Inventors: Joseph J. Lenox, Albert K. Fan
  • Patent number: 5352318
    Abstract: Electrode terminals formed on a pair of a circuit substrate and another circuit substrate or electrical element are mutually connected electrically by the medium of electroconductive particles. Prior to the connection, the electroconductive particles may be charged and dispersed onto a circuit substrate to be selectively attached to the electrode terminals thereon. The selective attachment may be enhanced by masking a part other than the connecting part of the electrode terminals of the circuit substrate with an insulating member or film so as to guide the charged electroconductive particles along electric lines of force directed to the exposed parts of the electrode terminals. The attached electroconductive particles are sandwiched between the pair of circuit substrates, which may be secured to each other by an insulating adhesive or an electroconductive resin.
    Type: Grant
    Filed: February 2, 1993
    Date of Patent: October 4, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hiroshi Takabayashi, Masanori Takahashi
  • Patent number: 5314723
    Abstract: In process for forming a coating of phosphor particles on a fluorescent lamp glass, a polymer is deposited on the phosphor particles and the phosphor particles are entrained in a carrier gas with the polymer in a non-adhering state, and then the phosphor particles are coated on the fluorescent lamp glass with the polymer in an adhering state for retaining the phosphor particles on the fluorescent glass and, the coated fluorescent glass is heated to a temperature above the decomposition temperature of the polymer for removing the polymer and to form a coating of phosphor particles on a fluorescent lamp glass.
    Type: Grant
    Filed: June 9, 1992
    Date of Patent: May 24, 1994
    Assignee: GTE Products Corporation
    Inventors: Arunava Dutta, Lenoard V. Dullea
  • Patent number: 5219606
    Abstract: A method of manufacturing an output phosphor screen for x-ray image intensifier is disclosed. The method includes the steps of dropping a dispersion of infusible spherical silicon resin particles on a water surface to form an aggregate layer of the infusible spherical silicon resin particles on the water surface. Thereafter, the aggregate layer of infusible spherical silicon resin particles in adhered on a face plate. The adhered aggregate layer is the calcinated in an atmosphere containing oxygen at a temperature of not less than 500.degree. C. to change the aggregate layer of infusible spherical silicone resin particles into a layer of spherical silica particles. A phosphor layer is then formed on the spherical silica particle layer.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: June 15, 1993
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Katsuhisa Homma, Masaru Nikaido, Hiroshi Kubo, Tetsu Sano
  • Patent number: 5213894
    Abstract: A red pigment coated phosphor comprises a phosphor for color cathode ray tube and red pigment attached to said phosphor by an organic binder, wherein said organic binder is gellatin and casein. A process for preparation of a red pigment coated phosphor comprises the steps of: preparing three dispersions of red phosphor particles, red pigment particles and organic binder, respectively; uniformly mixing said three dispersions and agitating them sufficiently; adjusting pH of the mixture obtained; and adding a curing agent thereto, washing said mixture and then drying it. The red pigment coated phosphor of the present invention has a good dispersion and a good affinity for phosphor slurry.
    Type: Grant
    Filed: December 19, 1990
    Date of Patent: May 25, 1993
    Assignee: Samsung Electron Devices Co., Ltd.
    Inventor: Ung-su Kim
  • Patent number: 5167913
    Abstract: A method of forming an adherent layer of metallurgy on a ceramic substrate which includes the steps of obtaining a ceramic material containing a polymeric binder and copper metallurgy patterns within the ceramic body. In one embodiment of the invention, the ceramic body also contains MgO.Thereafter, a surface layer of metallurgy is formed on the surface of the ceramic body. In one embodiment, the surface layer is nickel and in another embodiment, the surface layer is copper or gold.Then, the ceramic body undergoes a sintering cycle which includes the steps of pyrolysis, binder burnoff and, lastly, densification and, in some cases, crystallization. During densification and crystallization, there is a predetermined steam atmosphere which meets the following requirements: a partial pressure of oxygen less than that necessary to satisfy the equilibrium equation 4Cu+O.sub.2 =2Cu.sub.2 O; and a partial pressure of oxygen less than or equal to that necessary to satisfy the equilibrium equation 2Ni+O.sub.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: December 1, 1992
    Assignee: International Business Machines Corporation
    Inventors: John Acocella, Philip L. Flaitz, Raj N. Master, Chandrasekhar Narayan, Sarah H. Knickerbocker, Paul H. Palmateer, Sampath Purushothaman, Srinivasa S. N. Reddy
  • Patent number: 5141702
    Abstract: A method for depositing a composite coating on a substrate is provided. The coating contains a mixture of ductile metal particles and a uniformly dispersed polymer particles. The polymer is present in a concentration effective to reduce frictional forces. The coating mixture is compacted such as by isostatic pressing, formed into strips and then clad to the substrate. One preferred coating contains 0.5 weight percent polytetrafluoro-ethylene in a tin matrix.
    Type: Grant
    Filed: May 28, 1991
    Date of Patent: August 25, 1992
    Assignee: Olin Corporation
    Inventors: Bruce M. Guenin, Julius C. Fister
  • Patent number: 5130190
    Abstract: There is provided a process for treating the surface of a fluorescent material comprising the steps of adding a suitable amount of water glass (K.sub.2 O.SiO.sub.2) to a dispersion of a fluorescent material, the mixture of the dispersion and water glass being stirred, adding silica particulates to the mixture, and finally adding a suitable amount of metal salt to the mixture containing the silica particulates, whereby the silica particulates adhere to the surface of the fluorescent material.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: July 14, 1992
    Assignee: Samsung Electron Devices Co., Ltd.
    Inventor: Kim Woochan
  • Patent number: 5077088
    Abstract: A process for preparation of pigment coated phosphor comprises: preparing a phosphor solution by mixing an acryl emulsion and phosphor particles; preparing a pigment solution by mixing polyvinyl alcohol and pigment particles; mixing the two solutions; adding an acid solution to adjust the mixture to a pH of 3 to 7; and adding oxalic acid as a curing agent, thereby attaching the pigment particles to the phosphor particles.
    Type: Grant
    Filed: July 6, 1990
    Date of Patent: December 31, 1991
    Assignee: Samsung Electron Devices Co., Ltd.
    Inventor: Jwa-young Jeong
  • Patent number: 5006366
    Abstract: A photoluminescent material used for detection of infrared light is prepared using a base material, first and second dopants, a carbonate of the base material, and a fusible salt. The base material is an alkaline earth metal sulfide such as strontium sulfide. Strontium carbonate is used to decrease phosphorescence after charging, whereas lithium fluoride is used to allow the material to be fused together. Samarium oxide and europium oxide are used as the first and second dopants for establishing a communication band for luminescence and a trapping level, respectively. The photoluminescent material is made according to a process involving drying the material, heating the material in a graphite crucible to a fusing temperature in a dry inert atmosphere, grinding the material after cooling, and reheating the material to below the fusing temperature, but sufficiently high to repair the crystal surfaces. The material is then placed in a transparent binder and applied to a substrate.
    Type: Grant
    Filed: June 8, 1989
    Date of Patent: April 9, 1991
    Assignee: Quantex Corporation
    Inventor: Joseph Lindmayer
  • Patent number: 4992302
    Abstract: Photoluminescent materials useful for detection of infrared light are prepared using a base material, first and second dopants, barium sulfate and a fusible salt. The base material is an alkaline earth metal sulfide such as strontium sulfide, calcium sulfide, or a mixture of strontium sulfide and calcium sulfide. Barium sulfate is used to increase the brightness of output light, whereas lithium fluoride is used to allow the material to be fused together. Samarium, cerium and europium compounds are used in specific examples as dopants for providing electron traps. The photoluminescent material is made according to a process involving drying the mixture in a dry inert atmosphere, and heating the mixture in the inert atmosphere in a graphite crucible to a fusing temperature. The resultant material can then be applied to a substrate using thin film physical vapor deposition techniques.
    Type: Grant
    Filed: April 14, 1989
    Date of Patent: February 12, 1991
    Assignee: Quantex Corporation
    Inventor: Joseph Lindmayer
  • Patent number: 4973495
    Abstract: According to the present invention, there is provided a method for forming a color tube phosphor screen comprising the steps of forming a light-absorbing matrix having holes on a faceplate, coating a silica colloidal solution or an alumina colloidal solution containing a multivalent metal ion in said holes and washing said holes, and forming phosphor layers of three colors in said washed holes. The color tube phosphor screen formed through the method of the present invention has no phosphor residual, especially pigment residual.
    Type: Grant
    Filed: January 19, 1989
    Date of Patent: November 27, 1990
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Norio Koike, Kazuhiko Shimizu, Ryoichi Ogura
  • Patent number: 4879186
    Abstract: Photoluminescent materials useful for detection of infrared light are prepared using a base material, first and second dopants and a fusible salt. The base material is an alkaline earth metal sulfide such as calcium sulfide. Lithium fluoride is used to enhance the interdiffusion of materials. Samarium and a europium compound are used as the first and second dopants for providing electron traps. The photoluminescent material is made according to a process involving heating of the material to a fusing temperature, grinding the material after cooling, and reheating the material to below the fusing temperature, but sufficiently high to repair the crystal surfaces. The material is then placed in a transparent binder and applied to a substrate, or deposited as a thin film directly on a substrate for different uses.
    Type: Grant
    Filed: January 22, 1988
    Date of Patent: November 7, 1989
    Assignee: Quantex Corporation
    Inventor: Joseph Lindmayer
  • Patent number: 4853079
    Abstract: An electroluminescent panel and method of making the same includes a plurality of layers on a transparent electrode in which each layer is formed with the same compatible polymer carrier resin base material so that the individual layers have an integrated uniformity. A polyester laminating resin is disclosed for the resin base material of each layer which is activated by a small amount of diisocyanate sufficient to provide temperature stability, but insufficient to transform the base material into a urethane.Also disclosed is an electroluminescent lamp which emits light only in discrete areas such as to produce a pattern of light in which the phosphor is applied in a pattern corresponding to the discrete areas which are to be illuminated. Similarly, the electrodes are restricted to the illuminated regions or areas, thereby conserving material as well as reducing the power requirements of the lamp.
    Type: Grant
    Filed: May 10, 1988
    Date of Patent: August 1, 1989
    Assignee: Lumel, Inc.
    Inventors: Nicholas T. Simopoulos, George N. Simopoulos, Gregory N. Simopoulos
  • Patent number: 4839092
    Abstract: Photoluminescent materials useful for detection of infrared light are prepared using a base material, first and second dopants, barium sulfate and a fusable salt. The base material is an alkaline earth metal sulfide or selenide such as strontium sulfide. Barium sulfate is used to increase the brightness of output light, whereas lithium fluoride is used to allow the material to be fused together. Samarium and europium oxide are used as the first and second dopants for providing electron traps. The photoluminescent material is made according to a process involving heating of the material to a fusing temperature, grinding the material after cooling, and reheating the material to below the fusing temperature, but sufficiently high to repair the crystal surfaces. The material is then placed in a transparent binder and applied to a substrate.
    Type: Grant
    Filed: April 3, 1987
    Date of Patent: June 13, 1989
    Assignee: Quantex Corporation
    Inventor: Joseph Lindmayer
  • Patent number: 4806389
    Abstract: A method for preventing the hydration/solubilization of the protective oxide coating of a phosphor is described. The method involves coating of the oxide coated phosphor particles with a continuous hydrophobic coating. After the phosphor particles are coated with the continuous hydrophobic coating and the continuous hydrophobic coating cured, they are added to a water-based suspension and subsequently processed into a lamp.
    Type: Grant
    Filed: March 2, 1987
    Date of Patent: February 21, 1989
    Assignee: GTE Laboratories Incorporated
    Inventors: Thomas E. Peters, Roger B. Hunt, Jr.
  • Patent number: 4772345
    Abstract: A method of manufacturing a phosphor screen of uniform thickness on an inner surface of a panel of a cathode ray tube, comprising the steps of forming a powder-receptive adhesive pattern on the inner surface of a substantially rectangular panel having a skirt portion at the periphery, forming a sealed vessel consisting essentially of a container for containing phosphor powder and the panel by combining integrally the container and the panel so that the openings of both are opposed, and rotating the sealed container about an axis parallel to the inner surface of the panel.
    Type: Grant
    Filed: March 30, 1987
    Date of Patent: September 20, 1988
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Seiji Sagou, Takeo Itou
  • Patent number: 4758449
    Abstract: Making method for a phosphor layer of a small diameter cathode ray tube comprises application of a centrifugal force of above 100G in a direction parallel to the axis of a glass bulb toward its bottom panel to become a face plate, thereby forcedly making sedimentation of phosphor powder onto the inner surface of the bottom panel, and thus, by adoptation of the centrifugal force, a phosphor layer of very fine and dense configuration and uniform thickness is obtainable even using such small medium grain size of phosphor powder of under 4 .mu.m.
    Type: Grant
    Filed: February 19, 1987
    Date of Patent: July 19, 1988
    Assignee: Matsushita Electronics Corporation
    Inventors: Masamichi Kimura, Mutsuo Masuda, Masao Tokunaga, Shigeya Ashizaki
  • Patent number: 4732828
    Abstract: In a method for a phosphor screen of a cathode ray tube including the steps of forming a photo-tacky layer on a panel of a cathode ray tube, exposing the photo-tacky layer to form an adhesive pattern on the layer, and adhering phosphor powder on the adhesive pattern, in which these exposing and adhering steps are repeated. Before next exposing step, the photo-tacky layer is heated and then exposed after cooled. The heating step prevents the sensitivity of the layer from deterioration occurred by the preceding adhering step.
    Type: Grant
    Filed: November 5, 1986
    Date of Patent: March 22, 1988
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Seiji Sagou, Takeo Itou
  • Patent number: 4719386
    Abstract: A photoconverter wherein luminous substances having at least the atomistic property are dispersed among transparent intermediate substances substantially as individually isolated and as fixed together therewith so that, upon incident of light, the photoconverter is excited to cause each exciting photon to emit two or more photons for realizing multi-quantum emission.
    Type: Grant
    Filed: October 22, 1985
    Date of Patent: January 12, 1988
    Assignee: Matsushita Electric Works, Ltd.
    Inventor: Makoto Toho
  • Patent number: 4695478
    Abstract: A catholuminescent material consisting essentially of particles of copper-activated zinc sulfide cathodoluminescent phosphor having at least a partial coating of a mixture of a blue pigment of cobalt aluminate and a red pigment of iron oxide wherein the weight ratio of said blue pigment to said red pigment is from about 3.5:1 to about 4.5:1 and the weight percent of said pigments are from about 0.2% to about 2% by weight of catholuminescent phosphor. A process for producing said pigmented phosphor comprises forming the appropriate aqueous slurries by proper pH control and then by the addition of collodial silica, the pigment is coated onto the phosphor particles.
    Type: Grant
    Filed: June 6, 1986
    Date of Patent: September 22, 1987
    Assignee: GTE Products Corporation
    Inventors: Harry O. Schulze, Ronald E. Karam
  • Patent number: 4687825
    Abstract: A method of manufacturing a phosphor screen of a cathode ray tube, comprises forming a pattern having a particle-receptive adhesive surface on an inner surface of a faceplate having a peripheral wall, rotating the faceplate about an axis perpendicular to its inner surface and passing its center, and charging phosphor particles onto the inner surface of the faceplate during or before rotation thereof so as to allow the phosphor particles to slide on the inner surface of the faceplate and to attach to the particle-receptive adhesive surface. The method can form a phosphor film having a uniform and sufficient thickness without an irregularity in the amount of phosphor attached.
    Type: Grant
    Filed: September 16, 1985
    Date of Patent: August 18, 1987
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Seiji Sagou, Takeo Itou
  • Patent number: 4684540
    Abstract: A pigmented silicate coated phosphor is disclosed and a process for producing the phosphor. The process involves preparing a relatively uniform aqueous mixture of particles of a phosphor, particles of a deagglomerated pigment, and a free flowing agent and then adding a precipitating agent to the mixture in an amount sufficient to cause the free flowing agent and pigment to co-precipitate upon and coat the phosphor, followed by separating the pigmented phosphor from the resulting liquor. A relatively uniform mixture is formed of the resulting dried phosphor, a water soluble silicate, and water the water being in an amount of sufficient to allow the silicate to coat the surface of the phosphor particles. The mixture is heated at a sufficient temperature for a sufficient time with sufficient agitation to produce the final non-agglomerated silicate coated pigmented phosphor.
    Type: Grant
    Filed: January 31, 1986
    Date of Patent: August 4, 1987
    Assignee: GTE Products Corporation
    Inventor: Harry O. Schulze
  • Patent number: 4661373
    Abstract: A dispersion electroluminescence element comprising a fluorescent powder layer which is formed on a transparent electrode by coating process and a counter electrode facing said transparent electrode with said fluorescent powder layer interposed therebetween, characterized in that the fluorescent particles in the fluorescent material layer are coated with copper after forming the layer on the transparent electrode and then laminating the counter electrode thereon.
    Type: Grant
    Filed: January 6, 1986
    Date of Patent: April 28, 1987
    Assignee: Alps Electric Co., Ltd.
    Inventors: Yoshinori Kato, Masami Igarashi, Yoshimi Kamijo
  • Patent number: 4614837
    Abstract: A process for placing conductive paths on to the surface of a heat softenable substrate by applying a layer of metal powder to the substrate, compacting the powder in a pre-determined pattern by applying a heated die under pressure, and embedding the compacted powder by the continued application of the die at a pressure less than the compacting pressure.
    Type: Grant
    Filed: April 3, 1985
    Date of Patent: September 30, 1986
    Assignee: Allied Corporation
    Inventors: Robert P. Kane, Edwin D. Lillie, John D. Neidig
  • Patent number: 4528210
    Abstract: An input phosphor screen includes a substrate having a substantially smooth surface, and first and second phosphor layers both vapor-deposited sequentially on the substrate. The first layer is made of phosphor crystal particles having a mean diameter of 15 .mu.m or less. The second layer has a thickness ten or more times that of the first layer and is made of individual columnar crystals of alkali halide grown vertically on the crystal particles, standing close together with fine spaces therebetween. A third layer is preferably deposited on the second layer as a continuous film. These three layers can be deposited by evaporating a phosphor material or materials at a prescribed temperature and at a predetermined degree of vacuum.
    Type: Grant
    Filed: December 28, 1983
    Date of Patent: July 9, 1985
    Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
    Inventors: Takashi Noji, Norio Harao, Yoshiharu Obata