Ester (e.g., Polycarbonate, Polyacrylate, Etc.) Patents (Class 428/1.33)
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Patent number: 7462306Abstract: A cellulose acylate film that has: an in-plane retardation Re and a retardation Rth in a thickness direction at a wavelength of 590 nm, which are satisfied with ranges of expressions (I) to (III); a coefficient of a thermal expansion of from 20 ppm/° C. to 100 ppm/° C.; and a haze of from 0.01 to 0.8, and a polarizing plate and a display device using the same. 20?Re?50??Expression (I) 70?Rth?200??Expression (II) 1.0?Rth/Re?3.0??Expression (III) In the foregoing expressions, each of Re and Rth is a value at 25° C. and 60% RH, and has a unit of nm.Type: GrantFiled: November 2, 2005Date of Patent: December 9, 2008Assignee: Fujifilm CorporationInventor: Nobutaka Fukagawa
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Publication number: 20080280072Abstract: A dope containing a retardation controller, cellulose ester, and a solvent is prepared. In a first film producing apparatus, the dope is cast onto a casting drum whose surface is cooled to form a casting film in a gel state. The casting film is peeled off from the casting drum, and the peeled casting film is dried until a residual solvent amount reaches 10 wt. %. Cellulose ester contained in the casting film is crystallized by heating the casting film to a temperature of not less than 170° C. and not more than 250° C., and the casting film is stretched in the width direction. Thus, a film is produced. An absolute value |P1| of a degree of orientation of the polymer in the in-plane direction of the produced film satisfies 0?|P1|?0.050.Type: ApplicationFiled: March 19, 2008Publication date: November 13, 2008Applicant: FUJIFILM CORPORATIONInventors: Toshinao ARAI, Hidekazu YAMAZAKI
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Patent number: 7445821Abstract: Disclosed is a cellulose ester film containing cellulose ester and microparticles having an average primary particle diameter of from 0.1 to 1.0 ?m, wherein a relative standard deviation of a primary particle diameter of the microparticles is from 1 to 20%, and wherein the cellulose ester film has a surface with a peak density of from 1,000 to 8,000 (1/mm2).Type: GrantFiled: June 1, 2005Date of Patent: November 4, 2008Assignee: Konica Minolta Opto, Inc.Inventor: Isamu Michihata
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Patent number: 7435458Abstract: An optically anisotropic film is disclosed. The film comprises a fatty acid cellulose ester film support having an acetyl group and a propionyl group, and a liquid crystal layer containing a liquid crystal compound, or a resin layer containing polyimide, polyamidoimide, polyamide, polyether imide, polyether ether ketone, polyether ketone, polyketone sulfide, polyether sulfone, polysulfone, polyphenylene sulfide, polyphenylene oxide, polyethylene terephthalate, polybutylene terephthalate, polyethylene naphthalate, polyacetal, polycarbonate, polyallylate, acrylic resin, polyvinyl alcohol, polypropylene, cellulose based plastics, epoxy resin, or phenol resin.Type: GrantFiled: March 20, 2007Date of Patent: October 14, 2008Assignee: Konica CorporationInventors: Toshiaki Shibue, Makoto Honda, Nobuo Kubo, Noriyasu Kuzuhara, Hiroki Umeda, Sota Kawakami, Takatoshi Yajima
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Patent number: 7416765Abstract: A polymerizable liquid crystalline composition comprises a side chain liquid crystalline polymer obtained by radical-copolymerizing a (meth)acrylic compound has an optically active site and a (meth)acrylic compound having an oxetanyl group, and a cation generator and thus have no functional group the synthesis of which is difficult, such as an epoxy group. The use of the polymerizable liquid crystalline composition provides a cholesteric liquid crystal film which is excellent in a capability of retaining the orientation after being aligned and fixed in a liquid crystal orientation and in mechanical strength without the necessity of a complicated operation such as photo irradiation under an inert gas atmosphere.Type: GrantFiled: March 20, 2007Date of Patent: August 26, 2008Assignee: Nippon Oil CorporationInventors: Takashi Seki, Tooru Nakamura, Hitoshi Mazaki
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Patent number: 7410680Abstract: The present invention relates to a retardation film obtained by subjecting a film formed from a cellulose derivative to an orientation treatment, wherein a hydroxyl group of cellulose is substituted by at least one kind of aliphatic acyl group having 5 to 20 carbon atoms, and a degree of substitution by said hydroxyl group is 1 to 3. According to the present invention, a retardation film having various wavelength dispersion characteristics, positiveness or negativeness in birefringence and viewing angle characteristics, in particular, an achromatic retardation film and a retardation film having a high birefringent property and the like can be obtained by preparing a retardation film using a properly selected said cellulose derivative as a raw material of the film.Type: GrantFiled: August 26, 2004Date of Patent: August 12, 2008Assignees: Nippon Kayaku Kabushiki Kaisha, Polatechno Co., Ltd.Inventors: Hideyoshi Fujisawa, Kouichi Tanaka
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Patent number: 7396571Abstract: Provided is a polymeric fluorescent substance showing fluorescence in solid state, which has a specific carrier drift mobility, a specific repeating unit, and specific number-average molecular weight. The polymeric fluorescent substance is excellent in solubility to organic solvents, and has higher efficiency and longer lifetime in applying as a polymer LED.Type: GrantFiled: June 28, 2007Date of Patent: July 8, 2008Assignee: Sumitomo Chemical Company, LimitedInventors: Masato Ueda, Takanobu Noguchi
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Publication number: 20080152844Abstract: A cholesteric polymerizable liquid crystal composition excellent in UV curing property and alignment property is provided. The polymerizable liquid crystal composition contains at least one liquid crystal compound selected from compounds represented by Formula (1-1) and Formula (1-2), at least one liquid crystal compound selected from compounds represented by Formula (2), and 5 to 15% by weight of at least one optically active compound selected from compounds represented by Formula (4) and may contain at least one liquid crystal compound selected from compounds represented by Formula (3). The meanings of the symbols in the Formulae are described in the specification.Type: ApplicationFiled: December 21, 2007Publication date: June 26, 2008Inventors: Kazumi Hagihara, Ryushi Shundo
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Publication number: 20080135098Abstract: A color purity improving sheet that improves color purity while preventing brightness from degrading due to absorption of light of a necessary color. The color purity improving sheet includes a light-emitting layer containing a light-emitting means for absorbing light in a specific wavelength range other than the target wavelength range and converting its wavelength to emit light in the target wavelength range, and a reflective layer. The light-emitting layer has a transmittance of at least 70% at the maximum absorption wavelength of the light-emitting layer. The light-emitting layer and the reflective layer are laminated together in this order in a direction from which light of a backlight is incident. The reflective layer selectively reflects part of light in the specific wavelength range other than the target wavelength range and has been transmitted without being absorbed by the light-emitting means in the light-emitting layer, allowing entrance into the light-emitting layer again.Type: ApplicationFiled: November 26, 2007Publication date: June 12, 2008Applicant: NITTO DENKO CORPORATIONInventors: Akira OOTANI, Megumu NAGASAWA, Michie SAKAMOTO, Yutaka OHMORI, Shuusaku NAKANO
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Patent number: 7378136Abstract: A low fringing film coating includes a transparent polymeric layer having a surface, and a plurality of projections extending away from the surface. The projections have a mean height of 0.05 to 1 ?m and a mean distance between projections of 0.5 to 2 mm. The coating can be produced by coating a polymeric composition onto a substrate. The polymeric composition includes a polymeric material, a good solvent for the polymeric material and a poor solvent or the polymeric material. The solvents are at least partially evaporated to form a low fringing transparent polymeric layer.Type: GrantFiled: July 9, 2004Date of Patent: May 27, 2008Assignee: 3M Innovative Properties CompanyInventors: Richard J. Pokorny, Robert A. Yapel, Jason W. Balich
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Publication number: 20080090028Abstract: A liquid crystal display includes: a backlight module, a LCD panel, a first polarizer, and a second polarizer. The LCD panel is disposed over the emitting surface of the backlight module, the first polarizer is disposed between the backlight module and the LCD panel, and the second polarizer, relative to the first polarizer, is disposed on the other side of the LCD panel. The first polarizer includes a first polarizing layer, a first optical film, and a second optical film. The first optical film is disposed on the one side of the first polarizing layer, and the second optical film, relative to the first optical film, is disposed on the other side of the first polarizing layer. The second optical film is a Polymethyl Methacrylate optical film, and the second optical film is closer to the LCD panel than the first optical film does.Type: ApplicationFiled: August 31, 2007Publication date: April 17, 2008Inventors: Kuang-Rong Lee, Min-Wei Cheng
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Publication number: 20080074575Abstract: The invention relates to a liquid crystal display comprising a multi-layered display unit (1) which is introduced into a housing (20). Said unit comprises, in a successive manner from the visible side to the rear side, a front polarisation filter (11), a liquid crystal layer (12), a rear polarisation filter (13) and a diffusion layer (14) or retro-reflection layer, optionally, with additional layers (15, 16). High luminosity is achieved by virtue of the fact that the diffusion layer or the retro-reflection layer are provided with fluorescent colours (14.1).Type: ApplicationFiled: November 8, 2005Publication date: March 27, 2008Inventors: Wolfram Wiemer, Arno Bohm
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Patent number: 7307107Abstract: A photopolymerizable composition comprising a polymerizable compound and a photopolymerization initiator, wherein the polymerizable compound is characterized by comprising (a) a bifunctional (meth)acrylic acid (thio)ester compound containing a sulfur atom in the molecule and (b) at least one of a (meth)acrylic acid ester compound represented by the general formula (1) or a bifunctional (meth)acrylic acid ester compound having a urethane linkage: wherein R1 and R2 are each independently a hydrogen atom or a methyl group; R3 and R4 are each independently an alkyl group, an aralkyl group, an aryl group or a halogen atom; m and n are each an integer of 0 to 2; X1 is an alkylidene group having 1 to 3 carbon atoms; and Y1 and Y2 are each independently a poly(oxyalkylene) group with the proviso that at least one of Y1 and Y2 is a poly(oxyalkylene) group having a hydroxy group.Type: GrantFiled: July 17, 2003Date of Patent: December 11, 2007Assignee: Mitsui Chemicals, Inc.Inventors: Masao Imai, Mitsuo Nakamura, Hiroshi Naruse, Osamu Kohgo, Masahiro Enna, Atsuo Otsuji
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Patent number: 7306832Abstract: A manufacturing method of a cellulose ester film satisfying the relationships, Nx>Ny>Nz, and 0.8?Rt/R0?3.5, the method comprising casting a cellulose ester dope containing a solvent of a good solvent and a poor solvent on a support to form a web; peeling the web from the support; transporting the peeled web (step D0); holding the edges in the transverse direction of the web (step A); stretching the resulting web in the transverse direction while applying a tension; reducing the tension in the transverse direction of the web; and drying the stretched web, wherein the residual solvent content of the web is 5 to 90% by weight at the beginning in the step A, and the residual poor solvent content in the residual solvent content of the web is from 15 to 95% by weight at the terminal point in the Step D0.Type: GrantFiled: October 14, 2004Date of Patent: December 11, 2007Assignee: Konica CorporationInventors: Koji Tasaka, Hiroki Umeda, Noriyasu Kuzuhara, Takatoshi Yajima
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Patent number: 7250201Abstract: A production method of cellulose film wherein cellulose film is produced by preparing a polymer solution through dissolving cellulose ester in a solvent containing a prescribed organic solvent as the main component, forming a filmy object from the prepared polymer solution, and evaporating the solvent in the filmy object; the residual amount of the organic solvent is reduced while the film quality is not degraded, and the production efficiency is degraded to a least possible extent; a poor solvent, highest in boiling point among the materials contained in the solvent, is added in the content ranging from 0.1 wt % to 1.0 wt %, taking the total amount of the solvent in the prepared polymer solution to be 100 wt %; and the solubility of cellulose ester in the poor solvent is inferior to the solubility of the cellulose ester in the organic solvent which is the main component of the solvent.Type: GrantFiled: April 11, 2005Date of Patent: July 31, 2007Assignee: Fujifilm CorporationInventors: Hidekazu Yamazaki, Toshikazu Nakamura, Hiroshi Miyachi
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Patent number: 7211316Abstract: Disclosed is an optical multilayer comprising a polymeric substrate having a non-zero out-of plane birefringence and an amorphous polymeric overlayer that comprises an amorphous polymer having a Tg value above 160° C. and having the sign of its out-of-plane birefringence opposite to that of the polymeric substrate so as to provide a total out-of-plane phase retardation of said optical multilayer of between ?30 nm and 30 nm for wavelengths of light between 400 and 700 nm.Type: GrantFiled: October 27, 2003Date of Patent: May 1, 2007Assignee: Nitto Denko CorporationInventors: Tomohiro Ishikawa, James F. Elman, Dennis J. Massa, Erica N. Montbach, David M. Teegarden
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Patent number: 7208205Abstract: A film for a liquid crystal display comprising a fatty acid cellulose ester film having an acetyl group and a propionyl group is disclosed. Sum of degree of acetyl substitution (DSac) and degree of propionyl substitution (DSpr) of the fatty acid cellulose ester film of the film is 2.8 or less, and a retardation value (Rt value) in the thickness direction define by Formula 1 is 60 to 300 nm.Type: GrantFiled: March 24, 2004Date of Patent: April 24, 2007Assignee: Konica CorporationInventors: Toshiaki Shibue, Makoto Honda, Nobuo Kubo, Noriyasu Kuzuhara, Hiroki Umeda, Sota Kawakami, Takatoshi Yajima
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Patent number: 7184112Abstract: A polarizing plate used in a vertical alignment mode liquid crystal display comprising a liquid crystal cell is disclosed, wherein the polarizing plate comprises a polarizing film and a mixed fatty acid cellulose ester film with optical biaxiality provided between the polarizing film and the liquid crystal cell, and wherein the mixed fatty acid cellulose ester film has a retardation in plane R0 of from 31 to 120 nm, and a retardation in the thickness direction Rt of from 60 to 300 nm, in which R0 is represented by the following formula (1) and Rt is represented by the following formula (2): R0=(nx?ny)×d??formula (1) Rt={(nx+ny)/2?nz}×d.Type: GrantFiled: December 5, 2005Date of Patent: February 27, 2007Assignee: Konica CorporationInventors: Noriyasu Kuzuhara, Koji Tasaka, Hiroki Umeda, Takatoshi Yajima
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Patent number: 7166339Abstract: A phase retarder comprises one cellulose ester film. The retardation value of the film represented by Re450 measured at the wavelength of 450 nm is in the range of 100 to 125 nm. The retardation value of the film represented by Re590 measured at the wavelength of 590 nm is in the range of 120 to 160 nm. The retardation values represented by Re450 and Re590 satisfy the condition of Re590?Re450?2 nm. An aromatic compound having at least two aromatic rings is incorporated in the film as a retardation increasing agent to obtain ?/4 in the wide wavelength region defined above. A phase retarder can also give ?/2 in a wide wavelength region in the same manner.Type: GrantFiled: April 21, 2000Date of Patent: January 23, 2007Inventors: Hiroyuki Mori, Hiroaki Sata
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Patent number: 7163738Abstract: A method of film fabrication is taught that uses a coating and drying apparatus to fabricate resin films suitable for optical applications. In particular, polyvinyl alcohol films are prepared by simultaneous application of multiple liquid layers to a moving carrier substrate. After solvent removal, the polyvinyl alcohol films are peeled from the sacrificial carrier substrate. Polyvinyl alcohol films prepared by the current invention exhibit good dimensional stability and low birefringence.Type: GrantFiled: July 3, 2002Date of Patent: January 16, 2007Assignee: Eastman Kodak CompanyInventor: Marcus S. Bermel
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Patent number: 7160586Abstract: A cholesteric liquid crystal composition includes a) a cholesteric liquid crystal compound or a cholesteric liquid crystal precursor; and b) a compound of formula (I), formula (II) or formula (III): where, n is 1, 2, 3, or 4; m is 1, 2, or 3; R is an acrylate, methacrylate, acrylamide, isocyanate, epoxy, or silane; R1 is a (C3–C8) alkylene, (C3–C8) alkenylene, or (C3–C8) alkylyne; R2 is a bond, —O—, —C(O)O—, —O(O)C—, —OC(O)O—, —C(O)N—, —CH?N—, —N?CH—, or —NC(O)—; R3 is a cycloalkylene, cycloalkenylene, heterocyclylene, arylene, or hetroarylene; R4 is a bond, (C1–C8) alkylene, (C2–C8) alkenylene, (C2–C8) alkylyne, carbonyl, —O—, —C(O)O—, —O(O)C—, —OC(O)O—, —C(O)N—, —CH?N—, —N?CH—, or —NC(O)—; R5 is a bond, cycloalkylene, cycloalkenylene, hetrocyclylene, arylene, or hetroarylene; R6 is hydrogen, cyano, halo, (C1–C8) alkoxy, (C1–C8) alkyl, nitro, amino, carboxy, mercapto, (C1–C4)thioalkyl, COCH3, CF3, OCF3, or SCF3; R7 is a (C1–C2) alkylene, (C2) alkenylene, or (C2) alkylyne; R8 is is hydrogen, halo, (C1–C8)Type: GrantFiled: August 29, 2003Date of Patent: January 9, 2007Assignee: 3M Innovative Properties CompanyInventors: Marc D. Radcliffe, Richard J. Pokorny, Terence D. Spawn, Steven D. Solomonson
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Patent number: 7153552Abstract: A polarizing plate provided on a surface of a liquid crystal cell of a display, containing a polarizing element, Film A and Film B each provided on each of two surfaces of the polarizing element, wherein: (i) a surface of Film B has an adhesive layer which adheres the polarizing plate to the liquid crystal cell; and (ii) concentrations of a ultraviolet absorber and a stabilizer contained in Film A and Film B, and in-plane and out-of-plane retardation values of Film B, satisfy predetermined conditions.Type: GrantFiled: November 10, 2004Date of Patent: December 26, 2006Assignee: Konica Minolta Opto, Inc.Inventors: Nobuo Kubo, Noriyasu Kuzuhara
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Patent number: 7125591Abstract: To provide hard coat films having high hardness, and uniform durability against scratching and high flatness even with a small thickness and a large width, and to provide a method producing the same. The hard coat films are provided with an actinic ray curable resin on a cellulose ester film thereof, the cellulose ester film containing a UV absorber and 2 or more plasticizers. One of the plasticizers is a polyalcohol ester type and the other one is a non-phosphate ester type. The cellulose ester film is produced by biaxially stretching of a cellulose ester film with a total acyl substitution degree ranging from 2.6 to 2.9, a number average molecular weight ranging from 80,000 to 200,000, and a ratio of a weight-average molecular weight to a number average molecular weight ranging from 1.4 to 3.0.Type: GrantFiled: May 28, 2004Date of Patent: October 24, 2006Assignee: Konica Minolta Opto, Inc.Inventors: Koji Nakajima, Takashi Murakami, Ryohei Enomoto
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Patent number: 7105213Abstract: An optical compensation film comprising a cellulose ester film is disclosed. In the film, (a) each of photoelastic coefficient C(md) in a mechanical direction and photoelastic coefficient C(td) in the transverse direction of the cellulose ester film is 1×10?9 to 1×10?13 Pa?1 and C(md)<C(td), (b) retardation R0 within the plane of the cellulose film defined by Formula (I) is 20 to 70 nm, (c) retardation Rt of the cellulose ester film in a thickness direction, defined by Formula (II) is 70 to 400 nm, and (d) both of a dimensional variation ratio S(md) in the mechanical direction and a dimensional variation ratio S(td) in the transverse direction of the cellulose ester film prior to and after being allowed to stand at ambient conditions of 80° C. and 90 percent relative humidity for 50 hours are ?1 to 1 percent, |S(md)|>|S(td)|, and C(td)×|S(td)|<C(md)×|S(md)|.Type: GrantFiled: March 14, 2005Date of Patent: September 12, 2006Assignee: Konica Minolta Holdings, INCInventors: Koji Tasaka, Takatoshi Yajima, Noriyasu Kuzuhara, Hiroki Umeda
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Patent number: 7105212Abstract: A polymer film is used as an optical compensatory sheet or a support thereof. The polymer film contains a rod-like compound. The rod-like compound in the form of a solution gives an ultraviolet absorption spectrum. In the spectrum, the wavelength of ?max at the maximum absorption peak is shorter than 250 nm. The spectrum of the rod-like compound is measured when the rod-like compound is in the form of solution. The polymer film has an Rth retardation value of Rth450 measured at the wavelength of 450 nm in the range of 30 to 160 nm. The polymer film also has an Rth retardation value of Rth590 measured at the wavelength of 590 nm in the range of 50 to 200 nm. The values of the Rth450 and Rth590 satisfy the condition of Rth590-Rth450?2 nm.Type: GrantFiled: April 18, 2003Date of Patent: September 12, 2006Assignee: Fuji Photo Film Co., Ltd.Inventor: Yoji Ito
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Patent number: 7060333Abstract: A phase difference plate which comprises one sheet of polymer film containing a compound having a rod-shaped molecular structure and exhibiting a maximum absorption wavelength (?max) of less than 250 nm in an ultraviolet spectrum of its solution and which exhibits a retardation value as measured at a wavelength of 450 nm (Re450) of 60 to 135 nm and a retardation value as measured at a wave length of 590 nm (Re590) of 100 to 170 nm, where the relationship: Re590?Re450?2 nm is satisfied. The phase difference plate functions as a ?/4 plate.Type: GrantFiled: March 14, 2002Date of Patent: June 13, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Hiroshi Takeuchi, Hiroaki Sata, Hiroyuki Kawanishi, Takamichi Fujii
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Patent number: 7038744Abstract: A polarizing plate used in a vertical alignment mode liquid crystal display comprising a liquid crystal cell is disclosed, wherein the polarizing plate comprises a polarizing film and a mixed fatty acid cellulose ester film with optical biaxiality provided between the polarizing film and the liquid crystal cell, and wherein the mixed fatty acid cellulose ester film has a retardation in plane R0 of from 31 to 120 nm, and a retardation in the thickness direction Rt of from 60 to 300 nm, in which R0 is represented by the following formula (1) and Rt is represented by the following formula (2): R0=(nx?ny)×d??formula (1) Rt={(nx+ny)/2?nz}×d??formula (2)Type: GrantFiled: December 4, 2002Date of Patent: May 2, 2006Assignee: Konica CorporationInventors: Noriyasu Kuzuhara, Koji Tasaka, Hiroki Umeda, Takatoshi Yajima
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Cellulose ester film, cellulose ester dope, protective film of polarizing plate and polarizing plate
Patent number: 6974608Abstract: Disclosed is a cellulose ester film comprising a polymer prepared by polymerizing at least one ethylenically unsaturated monomer selected from vinyl esters, vinyl esters having a functional group, acrylic esters, and acrylic esters having a functional group, wherein the polymer has a weight average molecular weight of not more than 5,000.Type: GrantFiled: July 10, 2001Date of Patent: December 13, 2005Assignee: Konica CorporationInventors: Kunio Shimizu, Toru Kobayashi -
Patent number: 6956072Abstract: To provide a resin composition, in which a liquid crystal polymer is made into fiber in a molded article to exhibit an extremely high reinforcing effect which has not been available yet, and from which a molded article having an excellent mechanical strength can be manufactured in a stable manner. That is, a thermoplastic resin composition, wherein 100 parts by weight in total consisting of 99-50 parts by weight of a thermoplastic polyester resin (A) not forming an anisotropic molten phase and 1-50 parts by weight of a liquid crystal polymer (B) capable of forming an anisotropic molten phase is blended with 0.001-2.Type: GrantFiled: July 12, 2000Date of Patent: October 18, 2005Assignee: Polyplastics Co., Ltd.Inventors: Keiichi Kanaka, Toshio Shiwaku, Mineo Ohtake
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Patent number: 6942906Abstract: A resin sheet containing dispersed particles which is thin and lightweight, and has excellent mechanical strength and light-diffusing properties. The resin sheets may be used in liquid crystal displays. A resin sheet having a hard coat layer, an epoxy resin layer containing 100 parts by weight of the resin to 200 parts by weight of a diffuser having a refractive index different from that of the epoxy resin and having an average particle diameter from 0.2 to 100 ?m, and a thin metal layer as a reflecting layer, wherein the diffuser localizes so as to have a concentration distribution in the direction of the thickness of the epoxy resin layer. A resin sheet having dispersed particles which is obtained by superposing a reflecting layer, an inorganic gas barrier layer, or a color filter layer thereon. A process for producing the resin sheet having a color filter layer.Type: GrantFiled: November 6, 2003Date of Patent: September 13, 2005Assignee: Nitto Denko CorporationInventors: Yoshimasa Sakata, Toshiyuki Umehara, Kiichi Shimodaira, Kazutaka Hara, Yoshihiro Kitamura, Katsuhiro Nakano
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Patent number: 6936313Abstract: A resin sheet containing dispersed particles which is thin, lightweight, and has excellent mechanical strength and light-diffusing properties. The resin sheets may be used in liquid crystal displays. A resin sheet having a hard coat layer, an epoxy resin layer containing 100 parts by weight of the resin to 200 parts by weight of a diffuser having a refractive index different from that of the epoxy resin and having an average particle diameter from 0.2 to 100 ?m, and a thin metal layer as a reflecting layer, wherein the diffuser localizes so as to have a concentration distribution in the direction of the thickness of the epoxy resin layer. A resin sheet having dispersed particles which is obtained by superposing a reflecting layer, an inorganic gas barrier layer, or a color filter layer thereon. A process for producing the resin sheet having a color filter layer.Type: GrantFiled: March 5, 2002Date of Patent: August 30, 2005Assignee: Nitto Denko CorporationInventors: Yoshimasa Sakata, Toshiyuki Umehara, Kiichi Shimodaira, Kazutaka Hara, Yoshihiro Kitamura, Katsuhiro Nakano
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Patent number: 6881457Abstract: An optical compensation film comprising a cellulose ester film is disclosed. In the film, (a) each of photoelastic coefficient C(md) in a mechanical direction and photoelastic coefficient C(td) in the transverse direction of the cellulose ester film is 1×10?9 to 1×10?13 Pa?1 and C(md)<C(td), (b) retardation R0 within the plane of the cellulose film defined by Formula (I) is 20 to 70 nm, (c) retardation Rt of the cellulose ester film in a thickness direction, defined by Formula (II) is 70 to 400 nm, and (d) both of a dimensional variation ratio S(md) in the mechanical direction and a dimensional variation ratio S(td) in the transverse direction of the cellulose ester film prior to and after being allowed to stand at ambient conditions of 80° C. and 90 percent relative humidity for 50 hours are ?1 to 1 percent, and |S(md)|>|S(td)|.Type: GrantFiled: February 11, 2004Date of Patent: April 19, 2005Assignee: Konica Minolta Holdings, Inc.Inventors: Koji Tasaka, Takatoshi Yajima, Noriyasu Kuzuhara, Hiroki Umeda
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Patent number: 6844033Abstract: A cellulose ester film and its manufacturing method are disclosed, the cellulose ester film comprising a compound represented by the following formula (1) in an amount of from 1 to 30% by weight, wherein Y represents an ester bond or a divalent organic group containing an ester bond, RTA and Rd independently represent a substituent, and m and n independently represent an integer of 0 to 5, provided that when m or n is not less than 2, plural Ras or Rbs may be the same or different.Type: GrantFiled: February 14, 2002Date of Patent: January 18, 2005Assignee: Konica CorporationInventors: Kunio Shimizu, Takashi Murakami, Toru Kobayashi
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Patent number: 6800220Abstract: The present invention discloses an optically active polyester comprising at least constituent units represented by the general formula (I) and the general formula (II): wherein Ar1 and Ar2 each independently represents a bivalent aromatic group or a bivalent heteroaromatic group, and X1 and X2 each independently represents a hydrogen atom or an electron-withdrawing group, wherein A represents a bivalent substituent.Type: GrantFiled: May 14, 2002Date of Patent: October 5, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Masatoshi Yumoto, Mitsuyoshi Ichihashi, Kouya Kawabata
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Patent number: 6787202Abstract: A polyester film composite material comprising a biaxially oriented polyester film having a thickness of 5 at least 50 gm but not more than 200 gm and an easy-adhesion coating applied onto one or each surface thereof, and having a haze value of less than 2% and a total light transmissivity of at least 90%, and a light-diffusing plate comprising a light-diffusing layer 10 laminated on the surface of the easy-adhesion coating thereof. According to the present invention, a light-diffusing plate having excellent optical properties when used in a liquid crystal display and a substrate 15 therefor are provided.Type: GrantFiled: October 9, 2001Date of Patent: September 7, 2004Assignee: Teijin LimitedInventors: Kei Mizutani, Takashi Saigo, Masayuki Fukuda
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Publication number: 20040161551Abstract: An optical compensation film comprising a cellulose ester film is disclosed. In the film, (a) each of photoelastic coefficient C(md) in a mechanical direction and photoelastic coefficient C(td) in the transverse direction of the cellulose ester film is 1×10−9 to 1×10−13 Pa−1 and C(md)<C(td), (b) retardation R0 within the plane of the cellulose film defined by Formula (I) is 20 to 70 nm, (c) retardation Rt of the cellulose ester film in a thickness direction, defined by Formula (II) is 70 to 400 nm, and (d) both of a dimensional variation ratio S(md) in the mechanical direction and a dimensional variation ratio S(td) in the transverse direction of the cellulose ester film prior to and after being allowed to stand at ambient conditions of 80° C. and 90 percent relative humidity for 50 hours are −1 to 1 percent, and |S(md)|>|S(td)|.Type: ApplicationFiled: February 11, 2004Publication date: August 19, 2004Applicant: Konica Minolta Holdings, Inc.Inventors: Koji Tasaka, Takatoshi Yajima, Noriyasu Kuzuhara, Hiroki Umeda
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Patent number: 6773497Abstract: A cellulose acylate film formed from a solution of cellulose acylate contains a solvent of the solution at 0.1-0.6 wt. %, and acids at less than 500 ppm. The solvent is composed of at least one of esters and ketones, and further a recycled solvent recycled from the solution. In order to produce the cellulose acylate film, the solution is applied on a dope band moving in a direction, and dried to contain the solvent between 10-80 wt. % to the cellulose acylate. Thus a film-like material is formed from the solution, and peeled from the dope band. Thereafter the film-like material is further dried to form the cellulose acylate film containing the solvent at between 0.1 and 0.6 wt. %.Type: GrantFiled: July 26, 2002Date of Patent: August 10, 2004Assignee: Fuji Photo Film Co., Ltd.Inventor: Yukihiro Katai
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Publication number: 20040121088Abstract: A high temperature liquid crystalline polyester (LCP) composition, and articles made therefrom, that provides “good” to “excellent” wear resistance at PVs (pressure×velocity) of at least 1.75 MPa-m/s (50,000 psi-fpm). The high temperature LCP being a matrix material containing lubricating fillers and having an onset of melting temperature of at least 320° C.Type: ApplicationFiled: September 10, 2003Publication date: June 24, 2004Inventor: Joy Sawyer Bloom
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Publication number: 20040091643Abstract: Disclosed is an optical film that comprises certain radiation cured (meth)acrylate binders and, desirably, irregular semicrystalline asymmetric particles.Type: ApplicationFiled: November 12, 2002Publication date: May 13, 2004Applicant: Eastman Kodak CompanyInventors: Mridula Nair, Tamara K. Jones, Bradley M. Houghtaling, Joseph S. Sedita, Gary A. Rakes
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Patent number: 6731357Abstract: A film employed in a liquid crystal display member is disclosed. The film has film thickness of 20 to 60 &mgr;m and variation in the film thickness within ±3.0 percent of the standard film thickness.Type: GrantFiled: January 27, 2000Date of Patent: May 4, 2004Assignee: Konica CorporationInventors: Noriki Tachibana, Kunio Shimizu, Masahito Takada, Isamu Michihata, Koichi Nagayasu
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Patent number: 6730374Abstract: Disclosed is a triacetyl cellulose film comprising (a) a triphenyl monophosphate compound and (b) an aromatic polyol-bridged polyphosphate compound. Such a film exhibits a reduced rate of water vapor transmission.Type: GrantFiled: December 13, 2001Date of Patent: May 4, 2004Assignee: Eastman Kodak CompanyInventors: William J. Gamble, Joseph L. Lippert
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Patent number: 6623812Abstract: A reflector is disclosed which enables bright image display with a wide angle of view and can be efficiently fabricated by a a simplified process. The reflector includes a resin layer having at its surface microscopic projections and depressions and formed by application of a coating composition containing a binder resin and crosslinked resin particles.Type: GrantFiled: February 22, 2000Date of Patent: September 23, 2003Assignee: Sharp Kabushiki KaishaInventors: Hideto Tanaka, Hiromasa Minamino, Hirokazu Kaji, Masashi Ohata, Mamoru Seio
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Patent number: 6617056Abstract: A transparent conductive laminate in which a crystalline transparent conductive film substantially made of In—Sn—O on a transparent substrate composed of a thermoplastic polymer film, is provided. The crystalline part of the transparent conductive film (ITO-film) has a specific crystalline structure in which the X-ray diffraction intensity from the (222) crystal plane or the (440) crystal plane is highest, and [X440/222], the ratio of the X-ray diffraction intensity from the (440) crystal plane to that from the (222) crystal plane, is within the range of 0.2 to 2.5. The laminate has a low resistivity, and it is useful as an electrode material for a liquid crystal display, an electroluminescence device, a touch panel or the like. The transparent conductive laminate can be manufactured by combining the control of film fabricating atmosphere during sputtering and a heat treatment under specific conditions after film fabricating.Type: GrantFiled: October 23, 2000Date of Patent: September 9, 2003Assignee: Teijin Ltd.Inventors: Hiroshi Hara, Seiji Tsuboi
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Publication number: 20030035906Abstract: A transparent electrically conductive device which includes an indium tin oxide film is improved by providing an indium tin oxide film which contains a graded stack of individual indium tin oxide layers wherein the atomic percent of tin in the layers can be individually selected. Each indium tin oxide layer of the film contains 1-99 atomic percent tin. Each layer is made by a physical vapor deposition process or by sputter coating. Preferably the film which contains a plurality of indium tin oxide layers is applied to a transparent flexible substrate such as a polymeric sheet. Optional primer layers, hardcoat layers and topcoat layers may be included in the device.Type: ApplicationFiled: May 9, 2001Publication date: February 20, 2003Inventors: Hassan Memarian, Hitesh Patel
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Patent number: 6489377Abstract: The invention relates to a method for producing thermotropic casting resin systems that comprise at least one matrix polymer including at least one thermotropic monomer compound which cannot be mixed with the matrix polymer, whereby the matrix polymer an the thermotropic monomer compound are selected in such a way that their refraction indices are almost the same in a temperatrue range that is below the temperature required for structural change and that reaches the temperature of structural change of the thermotropic monomer compound, the casting resin system being translucent or transparent in this termperature range. After dissolving the monomer thermotropic compund in a matrix solution containing a photohardening oligomer, reactive diluents and photoinitiators and a liquid, photohardenable system is obtained, photoradiation with exclusion of oxygen is carried out for hardening.Type: GrantFiled: January 30, 2001Date of Patent: December 3, 2002Assignee: Fraunhoger-Gesellschaft zur Foerderung der Angewandten Forschung E.V.Inventors: Taner Bicer, Christoph Schwitalla, Holger Goedeke
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Publication number: 20020146518Abstract: A polyester film which is excellent in uniform light diffusibility, heat-resistant dimensional stability and luminance and suitable as a substrate of a light-diffusing plate of a liquid crystal display device. The film comprises a polyester containing polyethylene-2,6-naphthalene dicarboxylate as a main component and has a heat shrinkage in two directions perpendicular to each other in the surface of the film of not higher than 0.3% when heat-treated at 105° C. for 30 minutes, a dimensional change rate in two directions perpendicular to each other in the surface of the film under a stress of 0.37 MPa within a temperature range of 30 to 150° C. of not higher than 1.0%, a density of not lower than 1.350 g/cm3, a total light transmittance of not lower than 87%, a haze value of lower than 1.5% and a thickness of 50 to 150 &mgr;m.Type: ApplicationFiled: February 12, 2002Publication date: October 10, 2002Inventors: Hiroshi Kusume, Koji Furuya
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Cellulose ester film, cellulose ester dope, protective film of polarizing plate and polarizing plate
Publication number: 20020102369Abstract: Disclosed is a cellulose ester film comprising a polymer prepared by polymerizing at least one ethylenically unsaturated monomer selected from vinyl esters, vinyl esters having a functional group, acrylic esters, and acrylic esters having a functional group, wherein the polymer has a weight average molecular weight of not more than 5,000.Type: ApplicationFiled: July 10, 2001Publication date: August 1, 2002Applicant: Konica Corporation.Inventors: Kunio Shimizu, Toru Kobayashi -
Publication number: 20020102368Abstract: A cellulose ester film comprises (a) an ultraviolet absorbent polymer having at least one of repeating units represented by formulae (1) and (2) and repeating units having ultraviolet absorbent structures represented by formulae (3), (4) and (5), (b) an ultraviolet absorbent polymer which is a copolymer of a repeating unit represented by the following formula (6), (7) or (19) with a monomer unit derived from another ethylenically unsaturated monomer, (c) an ultraviolet absorbent polymer which is a copolymer of a monomer represented by formula (8) with a monomer represented by formula (9), or (d) modified cellulose in which an ultraviolet absorbent structure bonds directly or through a spacer to a hydroxy group of cellulose or its derivative.Type: ApplicationFiled: May 8, 2001Publication date: August 1, 2002Applicant: Konica CorporationInventors: Kaori Ono, Isamu Michihata, Osamu Ishige
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Publication number: 20020086163Abstract: A protective film of a polarizing plate comprising a cellulose ester film, wherein a variation in a weight of the cellulose ester film is 0 to 2% under a keeping condition of 80±5° C. and 90±10% RH for 48 hours.Type: ApplicationFiled: December 6, 2001Publication date: July 4, 2002Inventors: Kunio Shimizu, Toru Kobayashi
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Patent number: 6312771Abstract: Disclosed herein is a process for production a color filter for liquid crystal display device by applying inks to a base by an ink-jet printing system to arrange colorants on the base, which comprises the steps of applying inks, which each comprise a homopolymer of a monomer represented by the formula (I) or of the formula (II) wherein R1 is H or CH3, and R2 and R3 are independently H or an alkyl group having 1 to 5 carbon atoms, and/or a copolymer of the monomer with another vinyl monomer and can be cured by light or heat, directly onto the base or onto a resin layer provided on the base by the ink-jet printing system, thereby arranging colorants contained in the inks; and then curing the thus-applied inks by light exposure or heating.Type: GrantFiled: May 5, 1999Date of Patent: November 6, 2001Assignee: Canon Kabushiki KaishaInventors: Akio Kashiwazaki, Katsuhiro Shirota, Koichiro Nakazawa, Shoji Shiba, Masashi Hirose