Silicon Containing Patents (Class 428/149)
  • Patent number: 4550049
    Abstract: A laminated film comprising (A) a layer composed of a thermoplastic resin and (B) a layer composed of a thermoplastic resin containing fine particles therein, wherein a discontinuous skin having a height of 50 to 1,000 .ANG. is formed on the outer surface of the layer (A) and the outer surface of the layer (B) has a surface Ra value of 0.005 to 0.040.mu.. The laminated film is very valuable as a base film of a magnetic recording tape having a ferromagnetic metal thin film formed on the surface of the layer (A), especially a video tape, because it has good running properties and is excellent in electromagnetic transformation performance.
    Type: Grant
    Filed: March 9, 1983
    Date of Patent: October 29, 1985
    Assignee: Toray Industries, Inc.
    Inventors: Masaaki Ono, Yasuki Miura, Masahiko Motegi, Kazuo Okabe
  • Patent number: 4548855
    Abstract: Disclosed is a polyester film for a magnetic recording medium, which is comprised of a polyester film, a discontinuous film layer or layers adhering closely to one surface or both the surfaces of the polyester film, and fine particles present in the discontinuous film layer or layers and on the or each surface of the discontinuous film layer or layers, or on the exposed surface or surfaces of the polyester film in the portions where the discontinuous film layer or layers are not present. The discontinuous film layer or layers have a thickness of not larger than 500 angstroms and are composed mainly of a water-soluble polymer.
    Type: Grant
    Filed: October 28, 1983
    Date of Patent: October 22, 1985
    Assignee: Toray Industries, Inc.
    Inventors: Masaaki Ono, Masahiko Motegi, Kazuo Okabe
  • Patent number: 4544595
    Abstract: A pre-fabricated roofing and siding panel with simulated shingles or tiles has an exterior insulating layer composed of approximately 80% by volume hollow glass biosilicate beads suspended in a polyurethane foam. The exterior layer is bonded to a decking layer of a light honeycomb fiberglass sheet in a process where the decking layer is placed in the bottom of a mold and a mixture of the glass bubbles and a two component polyurethane foam is injected into the mold. To provide the panels strength and moisture integrity at their abutting edges, an improved dual interlocking construction is provided at the panel edges. An interlocking rib and groove are provided at the top and bottom edges of the decking layer to interlock the panel in a perpendicular plane, while a separate barrier ridge and groove are provided in the exterior layer to interlock the panel in the plane of the panel.
    Type: Grant
    Filed: May 19, 1983
    Date of Patent: October 1, 1985
    Inventor: Garry Tomason
  • Patent number: 4542059
    Abstract: A recording medium made of a substrate coated with a layer containing both a filler and a binder is characterized in that irregular shapes of filler particles appear at the surface of the coating layer.
    Type: Grant
    Filed: August 17, 1983
    Date of Patent: September 17, 1985
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shigeo Toganoh, Ryuichi Arai
  • Patent number: 4520062
    Abstract: Highly abrasion-resistant transfer coatings are provided on a wide variety of substrates, thermoplastic or thermosetting, by transfer coating from a mold surface or a flexible web, such as by use of a heat transfer tape, an ultra-thin coating consisting essentially of a non-resinous binder material such as microcrystalline cellulose together with mineral abrasive particles, preferably alumina or a mixture of silica and alumina which have been heated together at a temperature of at least 140.degree. F., the ultra-thin coating also preferably containing a silane and a small quantity of a sticking agent such as a thermoplastic or thermosetting resin.
    Type: Grant
    Filed: September 2, 1983
    Date of Patent: May 28, 1985
    Assignee: Nevamar Corporation
    Inventors: Israel S. Ungar, Herbert I. Scher, Nelson L. O'Neill
  • Patent number: 4517235
    Abstract: Highly abrasion-resistant transfer coatings are provided on a wide variety of substrates, thermoplastic or thermosetting, by transfer coating from a mold surface or a flexible web, such as by use of a heat transfer tape, an ultra-thin coating consisting essentially of a non-resinous binder material such as microcrystalline cellulose together with mineral abrasive particles, preferably alumina or a mixture of silica and alumina which have been heated together at a temperature of at least 140.degree. F., the ultra-thin coating also preferably containing a silane and a small quantity of a sticking agent such as a thermoplastic or thermosetting resin.
    Type: Grant
    Filed: November 16, 1982
    Date of Patent: May 14, 1985
    Assignee: Nevamar Corporation
    Inventors: Israel S. Ungar, Herbert I. Scher, Nelson L. O'Neill
  • Patent number: 4495247
    Abstract: A primer composition for fluorocarbon polymer coatings which cures at ambient temperatures and contains a fluorocarbon polymer of vinylidene fluoride and hexafluoropropylene and has a weight average molecular weight of about 50,000-300,000;a metallic oxide such as magnesium oxide which is an acid acceptor andan amino alkyl alkoxy silane; preferably, the primer contains a reinforcing pigment such as titanium dioxide;The primer is used in combination with fluorocarbon polymer coatings to provide corrosion and abrasion resistant coatings for equipment used in chemical plants, oil refineries, oil drilling platforms, and for the interior of smoke stacks of large utility companies.
    Type: Grant
    Filed: June 30, 1983
    Date of Patent: January 22, 1985
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Joseph A. Vasta
  • Patent number: 4489117
    Abstract: A super high density magnetic recording medium is provided, which comprises a polyester film and a discontinuous film formed on at least one surface of the polyester film. The discontinuous film has a thickness of smaller than 500 angstroms and is composed mainly of a water-soluble polymer, a silane coupling agent, and if desired, a silicone resin. A high density magnetic recording medium is also provided, which comprises a ferromagnetic metal thin film formed on the discontinuous film layer of the polyester base film. The polyester base film is especially suitable for formation of a metallized video tape, and this tape is excellent in the slip characteristics and abrasion resistance and advantageous in that noises and drop-out are reduced.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: December 18, 1984
    Assignee: Toray Industries, Inc.
    Inventors: Masaaki Ono, Masahiko Motegi, Kazuo Okabe
  • Patent number: 4474933
    Abstract: The present invention relates to resin mixtures which are fluid at temperatures up to 100.degree. C. and which crosslink either at elevated temperature or under the influence of moisture. Thermal crosslinking takes place at temperatures of 100.degree. C. and up, preferably at about 120.degree. C. The mixtures contain one or more mutually compatible polymers containing hydroxyl groups, in which at least 5% and not more than 90% of the hydroxyl groups are replaced by alkoxysilyl groups. The introduction of the alkoxysilyl groups is accomplished by the reaction of a diisocyanate with a hydroxyl group on the polymer, on the one hand, and with an aminosilane or mercaptosilane ester on the other. On the basis of their fluid-to-viscous consistency at room temperature or moderately elevated temperature, the resins can be applied in a thin coating and easily crosslinked in situ.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: October 2, 1984
    Assignee: Dynamit Nobel AG
    Inventors: Hans Huber, Eduard Hansel, Gerhard Geier
  • Patent number: 4443510
    Abstract: A multilayer reflective tape for use on roadways to provide temporary marking and demarcation of traffic lanes is disclosed. The tape has a thin malleable strip of aluminum, the top of which is coated with a high visibility paint in which reflective glass beads are embedded. Bonded to the bottom of the aluminum strip is a nylon felt scrim, the bottom of which is provided with a pressure-sensitive adhesive.
    Type: Grant
    Filed: September 23, 1982
    Date of Patent: April 17, 1984
    Assignee: Lukens General Industries, Inc.
    Inventor: Charles W. Watt
  • Patent number: 4430375
    Abstract: An abrasion-resistant laminate is prepared by providing an ultra thin coating of mineral particles and micro crystalline cellulose on the surface of conventional printed paper, followed by impregnating the paper with a conventional laminating resin, and then using the print paper so obtained in a laminating process without the necessity of using an overlay sheet.
    Type: Grant
    Filed: April 15, 1983
    Date of Patent: February 7, 1984
    Assignee: Nevamar Corporation
    Inventors: Herbert I. Scher, Israel S. Ungar
  • Patent number: 4427877
    Abstract: Polymers having low surface energy, e.g. fluorocarbon polymers, are rendered printable by conventional methods, e.g. offset printing, by incorporating a suitable particulate filler in the polymer, and shaping the filled polymer under conditions which result in the surface of the shaped polymer having irregularities which correspond to the particles of the filler. Suitable fillers comprise particles having at least two dimensions in the range of 1 to 40 microns; glass fibers are particularly satisfactory. Extruded insulating polymeric jackets for electrical components, e.g. strip heaters and wire and cable, can readily be marked by use of the invention.
    Type: Grant
    Filed: September 28, 1981
    Date of Patent: January 24, 1984
    Assignee: Raychem Corporation
    Inventor: Vijay K. Dhingra
  • Patent number: 4418724
    Abstract: Heat insulating casing for structural components having curved surfaces, including insulating plates formed of compressed material based on pyrogenic silica, reinforcement fibers and on an opacifier, the insulating plates being divided into insulating elements having trapezoidal cross sections, and the insulating elements being combined to form a polygonal insulating shell.
    Type: Grant
    Filed: April 13, 1981
    Date of Patent: December 6, 1983
    Assignees: Kraftwerk Union Aktiengesellschaft, Grunzweig & Hartmann Montage GmbH
    Inventors: Wolfgang-Peter Fricker, Manfred Scholz
  • Patent number: 4405657
    Abstract: A non-skid decorative plastic floor covering comprised of a decorative plastic base having a plurality of slip-resistant elements positioned on the base with a clear or translucent wear layer overlying the slip-resistant elements and the exposed intervening base. The slip-resistant elements comprise particles, preferably inorganic and rounded, embedded in a cured plastic matrix, the particles being distributed throughout the matrix in a substantially abutting relationship with the upper-most layer of particles protruding from the matrix such that the protruding particles impart a rough, irregular non-skid surface texture to the wear layer overlying the slip-resistant elements.
    Type: Grant
    Filed: March 1, 1982
    Date of Patent: September 20, 1983
    Assignee: Armstrong World Industries, Inc.
    Inventors: Jesse D. Miller, Jr., James R. Petzold
  • Patent number: 4404245
    Abstract: A protective sheet for a cassette holding a magnetic recording tape comprises a transparent base which is coated with a hardened surface layer formed by bonding hard fine particles with a binder.
    Type: Grant
    Filed: May 14, 1981
    Date of Patent: September 13, 1983
    Assignee: TDK Electronics Co., Ltd.
    Inventor: Toshihiko Ishida
  • Patent number: 4396657
    Abstract: Yarn arrays bonded with selected adhesives give coated abrasive products with reduced elongation under stress. Best results are obtained using epoxy resins with dicyandiamide, blocked isocyanates and/or imidazole curing agents as saturants for the yarn arrays.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: August 2, 1983
    Assignee: Norton Company
    Inventor: Mohamed M. Ibrahim
  • Patent number: 4395452
    Abstract: An abrasion-resistant laminate is prepared by providing an ultra thin coating of mineral particles and micro crystalline cellulose on the surface of conventional printed paper, followed by impregnating the paper with a conventional laminating resin, and then using the print paper so obtained in a laminating process without the necessity of using an overlay sheet.
    Type: Grant
    Filed: September 2, 1981
    Date of Patent: July 26, 1983
    Assignee: Nevamar Corporation
    Inventors: Herbert I. Scher, Israel S. Ungar
  • Patent number: 4372997
    Abstract: Fire- and heat-resistant sheet material comprises fibrous webs adhered together with asphalt which is filled with inorganic particles, intumescable granules, and a catalyst which catalyzes charring of the asphalt.
    Type: Grant
    Filed: April 9, 1982
    Date of Patent: February 8, 1983
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gary D. Fritze, Joseph Graham
  • Patent number: 4364985
    Abstract: A porous sheet is disclosed that comprises a thin, flexible sheet made of thermoplastic resin having solid particles distributed therein. Small spaces are formed around the particles, such that abrasion or buffing of the opposite surfaces of the sheet causes the formation of a multitude of fine pores that extend through the sheet, making the sheet vapor-permeable but liquid-impermeable.
    Type: Grant
    Filed: May 29, 1981
    Date of Patent: December 21, 1982
    Assignee: Kao Soap Co., Ltd.
    Inventors: Mitsuru Tokuyama, Kenji Ohki, Masayuki Sagae, Kaoru Tsujii
  • Patent number: 4359497
    Abstract: A paper like butene-1 polymer sheet material is made by extruding a composition comprising (a) about 20 to 97% by weight of a butene-1 polymer having a molecular weight in excess of about 20,000, an isotacticity of at least about 25% and a butene-1 content of at least about 50% by weight, and (b) about 3 to 80% by weight of at least one normally solid filler insoluble in said polymer, to form a sheet, and stretching said sheet at least about 5% beyond its yield strain. The filler may be organic or inorganic and the sheet is preferably stretched at least about 20% beyond its yield point. The sheet is characterized by a novel surface appearance when scanned in an electron microscope, by dimensional stability and by approximately equal strengths in all directions as evidenced by a maximum tensile strength ratio of about 13:1 in mutually perpendicular directions.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: November 16, 1982
    Assignee: Princeton Chemical Research, Inc.
    Inventors: Jules Magder, Murray H. Reich
  • Patent number: 4351866
    Abstract: A flexible strip facing material, formed from particles (2) of hard material bound together and secured on a perforated support (1) by means of a macromolecular binder, is adapted to be stuck by its rear face (5) to a wall or other surface in such a manner as to leave visible the face (4) covered with the particles. The edges (3 and 8) of the material are cut in bevels at the angles A and B in such a manner that when two strips are stuck edge to edge the joint between them remains imperceptible, the angle B being less than the angle A. This material is used as a facing for the protection and decoration of walls of buildings.
    Type: Grant
    Filed: June 26, 1980
    Date of Patent: September 28, 1982
    Inventors: Paul Mennesson, Hugues Moreau
  • Patent number: 4348446
    Abstract: A biaxially oriented polyester film containing fine particles of insoluble inert substance, has a kinetic coefficient of friction of not more than 0.3, and has microscopic protrusions integrated thereto, said protrusion having an peak-to-valley height of not more than 1 micron mostly range of 0.2 to 0.5 micron. The film having improved slipperiness is useful as the base film of magnetic recording tape for a video tape recorder or a computer data storage.
    Type: Grant
    Filed: September 4, 1980
    Date of Patent: September 7, 1982
    Assignee: Teijin Limited
    Inventors: Yukio Mitsuishi, Shigeru Shiozaki, Takao Chujo, Takeyuki Yokoyama
  • Patent number: 4348447
    Abstract: A non-skid decorative plastic floor covering comprised of a decorative plastic base having a plurality of slip-resistant elements positioned on the base with a clear or translucent wear layer overlying the slip-resistant elements and the exposed intervening base. The slip-resistant elements comprise particles, preferably inorganic and rounded, embedded in a cured plastic matrix, the particles being distributed throughout the matrix in a substantially abutting relationship with the upper-most layer of particles protruding from the matrix such that the protruding particles impart a rough, irregular non-skid surface texture to the wear layer overlying the slip-resistant elements.
    Type: Grant
    Filed: February 24, 1981
    Date of Patent: September 7, 1982
    Assignee: Armstrong World Industries, Inc.
    Inventors: Jesse D. Miller, Jr., James R. Petzold
  • Patent number: 4343641
    Abstract: A method of increasing the abrasion resistance of glass articles is disclosed. It has been found that by providing a vitreous substrate with a micro-roughened surface and an overlayer of dry lubricious organic coating, substantially increased lubricity and abrasion resistance is obtained. When the micro-roughened surface is provided by bonding a discontinuous distribution of discrete particulate material to the surface, a substantial increase in abrasion resistance and lubricity is realized even without the overlayer of dry lubricious coating thereby making the present invention particularly adaptable to use in the hot end of a glassware manufacturing process. Further, when the particulate material is fusible at about the annealing temperature of the glassware and is applied at the hot end, the particulate material will protect the glass surface through the hot end by bearing the major part of any loads created by contact between the glassware and other objects in its transport through the hot end.
    Type: Grant
    Filed: March 2, 1981
    Date of Patent: August 10, 1982
    Assignee: Ball Corporation
    Inventor: Addison B. Scholes
  • Patent number: 4342804
    Abstract: This under-roofing material for roofs to be covered with tiles, slates and the like consists of a sheet of agglomerated fibres coated on one face with a layer of bitumen just sufficient for constituting when cooled a micro-perforated structure preventing the passage of liquid by capillarity while permitting the passage or air or vapor, this material having a strength sufficient to withstand the fall of objects or personnel during its use, and being essentially liquid-tight and pervious to air and vapors.
    Type: Grant
    Filed: September 25, 1980
    Date of Patent: August 3, 1982
    Assignee: Siplast S.A.
    Inventor: Jean-Yves Meynard
  • Patent number: 4328274
    Abstract: A friction surface sheet material which may be adherently bonded to the patterned surface of a substrate which permits the visual observation of such pattern when attached. The friction surface sheet material comprises a backing layer formed of a dimensionally stable polymeric film such as polyethylene terephthalate. A first and second coating of the first and second transparent binder material adherently bond a multitude of minute transparent glass particles uniformly dispersed over the upper major surface of the backing layer, with the tops of the glass particles projecting above the binder coating to provide a friction surface, and the bottom major surface of the backing layer has thereon a layer of transparent pressure-sensitive adhesive. The glass particles may be glass spheres or fragments obtained by fracturing larger particles of glass.
    Type: Grant
    Filed: August 10, 1979
    Date of Patent: May 4, 1982
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Kent S. Tarbutton, Ronald O. Zemke
  • Patent number: 4327141
    Abstract: An abrasion-resistant laminate is prepared by providing an ultra thin coating of micro-crystalline cellulose overcoated with an ultra thin layer of mineral particles and micro crystalline cellulose on the surface of conventional printed paper, followed by impregnating the paper with a conventional laminating resin, and then using the print paper so obtained in a laminating process without the necessity of using an overlay sheet.
    Type: Grant
    Filed: April 1, 1980
    Date of Patent: April 27, 1982
    Assignee: Nevamar Corporation
    Inventors: Herbert I. Scher, Israel S. Ungar
  • Patent number: 4307142
    Abstract: A fluoroelastomer-hollow glass microsphere coating has been found to provide new and unexpected corrosion resistance to metal surfaces for protection against severely corrosive environments. The coating comprises a fluorocarbon elastomer and 3-50% by volume of hollow glass microspheres or microballoons having a size in the range of about 2-300 microns, preferably 20-200 microns. The hollow glass microspheres or microballoons substantially increases the corrosion resistance of a fluoroelastomeric liquid composition, yielding new and unexpected thermal and chemical resistance, particularly when the coating composition is applied in two or more layers.
    Type: Grant
    Filed: August 8, 1980
    Date of Patent: December 22, 1981
    Assignee: T.C. Manufacturing Company, Inc.
    Inventors: John Blitstein, Donald Kathrein
  • Patent number: 4305987
    Abstract: An abrasion-resistant laminate is prepared by providing an ultra thin coating of mineral particles and micro crystalline cellulose on the surface of conventional printed paper, followed by impregnating the paper with a conventional laminating resin, and then using the print paper so obtained in a laminating process without the necessity of using an overlay sheet.
    Type: Grant
    Filed: April 1, 1980
    Date of Patent: December 15, 1981
    Assignee: Nevamar Corporation
    Inventors: Herbert I. Scher, Israel S. Ungar
  • Patent number: 4282281
    Abstract: Longer-lived pavement markings are provided by adhering to the pavement a sheet material about one-fourth millimeter or more thick that comprises a carboxyl-modified acrylonitrile-butadiene polymer and particulate fillers dispersed in the polymer.
    Type: Grant
    Filed: November 2, 1979
    Date of Patent: August 4, 1981
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John L. Ethen
  • Patent number: 4233352
    Abstract: A slippery and smooth-surfaced polyester film, at least one surface of which is covered with worm-like nodules, useful as a base film for high recording density magnetic tape.
    Type: Grant
    Filed: January 9, 1979
    Date of Patent: November 11, 1980
    Assignee: Toray Industries, Inc.
    Inventors: Masaaki Ono, Kazuo Okabe, Yasuki Miura
  • Patent number: 4218502
    Abstract: Asphalt roofing material is made fire-retardant by inclusion of a layer of intumescable hydrated soluble silicate particles. Preferred soluble silicate particles carry a protective moisture-resistant coating which increases the life of the roofing material, and also makes possible convenient manufacture of the particles. The protective coating includes a metal cation capable of reacting with the silicate ion of the core particle to form a reaction product that is less soluble than the core particle. The reaction is believed to seal any openings in the protective coating, thereby lengthening the effective life of the coating. Besides utility in roofing materials, the coated particles are useful as fire-retardant additives in many other products, including polymeric articles, sheet materials, coating compositions, etc.
    Type: Grant
    Filed: June 19, 1978
    Date of Patent: August 19, 1980
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Joseph Graham, James R. Lodge, deceased
  • Patent number: 4169912
    Abstract: An iron oxide pigment having a coating of a silane of the formulaR.sub.n Si(OR').sub.4-nwhereinR is an, in some cases, branched or oxygen-bridge-containing alkyl or alkenyl moiety of 1 to 18 carbon atoms, or an aryl moiety,R' is an, in some cases, branched and, in some cases, oxygen-bridge-containing alkyl moiety of 1 to 8,N=1 to 3,Or a hydrolysis product thereof; a magnetic tape containing such coated iron oxide pigment and a process for coating such iron oxide pigment. There is particularly disclosed the treatment of iron oxide magnetic pigments to thereby improve their wear resistance and dispersibility in organic mediums.
    Type: Grant
    Filed: November 3, 1977
    Date of Patent: October 2, 1979
    Assignee: Dynamit Nobel Aktiengesellschaft
    Inventors: Eduard Schonafinger, Paul Deigner, Manfred Ohlinger, Helmut Jakusch, Jurgen Amort, Heinz Nestler, Claus-Dietrich Seiler, Otto Ambros
  • Patent number: 4148955
    Abstract: Matt films having a scratch-resistant surface are obtained from moulding compositions reinforced with glass spheres if the extruded film is stretched while still in the melt-fluid state, and then allowed to cool. These films are suitable for use as coating materials, especially for furniture, doors and the like.
    Type: Grant
    Filed: October 13, 1977
    Date of Patent: April 10, 1979
    Assignees: Alkor GmbH, Ciba-Geigy AG
    Inventors: Franz Breitenfellner, Roland Fink
  • Patent number: 4098610
    Abstract: This invention relates to the production of borate-based or silicate-based glasses containing copper which are operable as biocidal additives in marine anti-fouling coatings. Zinc and/or tin may be substituted for a portion of the copper or, if present in combination at high loadings, may be substituted in total for the copper. When dispersed in the standard film forming binders employed in marine paints, the rate of solution of the metal ion in salt water is in excess of 10 mg/m.sup.2 /day.
    Type: Grant
    Filed: May 23, 1977
    Date of Patent: July 4, 1978
    Assignee: Corning Glass Works
    Inventor: Dale R. Wexell
  • Patent number: 3931428
    Abstract: The technique for forming on a substrate an abrasion-resistant layer having super-hydrophobic properties. Applied to the face of the substrate which has an inherently hydrophobic micro-pile formation are hydrophobic fumed silicon dioxide particles dispersed in a hydrophobic solvent. Dissolved in the solvent is a resinous binder in a small but effective amount which, by weight, is substantially less than one half the amount of the particles in the dispersion. Upon volatilization of the solvent, the resultant layer is composed primarily of fumed silicon dioxide particles strongly bonded to the face of the substrate.
    Type: Grant
    Filed: January 4, 1974
    Date of Patent: January 6, 1976
    Assignee: Michael Ebert
    Inventor: Franklin G. Reick