Abstract: Described herein is an anti-reflective film including: a hard coating layer; and a low-refractive layer containing a binder resin and hollow inorganic nanoparticles and solid inorganic nanoparticles dispersed in the binder resin. The hollow and solid inorganic particles are dispersed in the low-refractive layer such that the amount of the solid inorganic nanoparticles positioned close to an interface between the hard coating layer and the low-refractive layer is larger than that of the hollow inorganic nanoparticles. Also described is a manufacturing method of the anti-reflective film including: applying a resin composition containing a photopolymerizable compound or a (co)polymer thereof, a fluorine-containing compound including a photoreactive functional group, a photoinitiator, hollow inorganic nanoparticles, and solid inorganic nanoparticles on a hard coating layer, and drying the applied resin composition at a temperature of 35° C. to 100° C.; and photocuring the dried resin composition.

Abstract: The present invention provides a method for the preparation of an asymmetric membranes. More particularly, the new method relates to the use of a crosslinker contacted via vapour or liquid phase with the surface layer of a cast polymer film, followed by the immersion of said film in a coagulation bath. The formation of a crosslinked skin layer and the solidification of the membrane bulk can thus be decoupled in time.

Abstract: The invention relates to macroporous, hydrophobic and isotropic polyvinylidene fluoride (PVDF) membranes having improved properties and to a new method for preparing the same.

Abstract: Hydrophobic flat membrane made from a vinylidene fluoride polymer with a wall, a first surface, and a second surface. The membrane has on its first surface a network structure with open pores and on its second surface a continuous skin in which pores are formed, and adjacent to the skin of the second surface a supporting layer with an isotropic pore structure across the wall thickness, wherein the supporting layer extends over at least 80% of the wall thickness and wherein the pores of the supporting layer have an average diameter of less than 1 ?m. The weight average of the molecular weight MW of the vinylidene fluoride polymer lies in the range from 300 000 to 500 000 daltons, and the polydispersivity MW/MN is greater than 5.5. The pores in the skin of the second surface have a closed perimeter in the plane of the skin and an average ratio of the extension in the direction of the longest axis thereof to the extension in the direction of the shortest axis thereof of at most 5.

Abstract: The present invention relates to an antireflection film being capable of realizing high scratch resistance and antifouling property while simultaneously having low reflectivity and high light transmittance, and further being capable of enhancing screen sharpness of a display device, and a method for preparing the antireflection film.

Abstract: The present invention relates to an antireflection film being capable of realizing high scratch resistance and antifouling property while simultaneously having low reflectivity and high light transmittance, and further being capable of enhancing screen sharpness of a display device, and a method for preparing the antireflection film.

Abstract: The present invention relates to an antireflection film being capable of realizing high scratch resistance and antifouling property while simultaneously having low reflectivity and high light transmittance, and further being capable of enhancing screen sharpness of a display device.

Abstract: One aspect of the present invention concerns a porous hollow fiber membrane containing a vinylidene fluoride-based resin. The hollow fiber membrane has a gradient structure in which a pore diameter of pores in the hollow fiber membrane gradually becomes smaller at least toward one of inner and outer peripheral surface sides and is hydrophilized by containing a crosslinked body of a polyvinylpyrrolidone-based resin.

Abstract: A coated substrate is provided that comprises: a substrate; and a barrier coating comprising a compound having the formula: Ln2ABOs, where Ln comprises scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, or mixtures thereof; A comprises Si, Ti, Ge, Sn, Ce, Hf, Zr, or a combination thereof; and B comprises Mo, W, or a combination thereof. In one embodiment, B comprises Mo.

Abstract: Coated articles are provided comprising: (a) a substrate; (b) a porous sol-gel layer superimposed on at least one surface of the substrate; wherein the porous sol-gel layer comprises a hydrolyzed tetraalkoxysilane; and (c) a sealant layer superimposed on at least one surface of the porous sol-gel layer; wherein the sealant layer comprises an alkyltrihalosilane. The coated articles demonstrate superior abrasion resistance due to a glass-like layer formed from the combination of the porous sol-gel layer and sealant layer.

Abstract: A thin layer lithium-ion type battery comprising, on a substrate (20, 30), a cathode current collector layer (22, 36) and an active portion constituted by a stack of a cathode layer (23, 35) made of material suitable for inserting lithium ions, an electrolyte layer (24, 34), and an anode layer (25, 33), wherein the cathode layer presents, across its thickness, porosity that varies between its interface with the cathode current collector layer and its interface with the electrolyte layer, the variation in the porosity being non-zero so as to improve cohesion at both interfaces.

Abstract: A method of manufacturing a semiconductor device includes irradiating the semiconductor body with particles through a first side of the semiconductor body, removing at least a part of impurities from an irradiated part of the semiconductor body by out-diffusion during thermal treatment in a temperature range between 450° C. to 1200° C., and forming a first load terminal structure at the first side of the semiconductor body.

Abstract: Embodiments provided herein describe antireflective coatings and methods for forming antireflective coatings. A substrate is provided. A first antireflective layer is formed over the substrate. The first antireflective layer has a first refractive index. A second antireflective layer is formed on the first antireflective layer. The second antireflective layer has a second refractive index. The first antireflective layer and the second antireflective layer jointly form an antireflective coating. The antireflective coating is graded such that the antireflective coating comprises at least three sub-layers, each of the at least three sub-layers having a unique refractive index.

Abstract: The present invention provides a method for producing a porous glass layer easily, wherein a ripple is suppressed. A method for manufacturing an optical member provided with a porous glass layer on a base member includes the steps of forming an intermediate layer containing at least one of silicon, potassium, and aluminum on the base member, forming a phase-separable glass layer on the intermediate layer, forming a phase-separated glass layer on the base member by heating the intermediate layer and the phase-separable glass layer at a temperature higher than or equal to the glass transition temperature of the phase-separable glass layer, and forming a porous glass layer on the base member by subjecting the phase-separated glass layer to an etching treatment.

Abstract: Prepare a polymeric nanofoam using a continuous extrusion process by providing a polymer melt of a polymer composition in an extruder, introducing carbon dioxide to a concentration above the solubility in the polymer melt, cooling the polymer melt without increasing the pressure to achieve conditions where all of the carbon dioxide is soluble in the polymer composition and then extruding the polymer composition and carbon dioxide mixture through an extrusion die so as to experience a pressure drop of at least five MegaPascals at a rate of at least ten MegaPascals per second and allowing the polymer composition to expand into a polymeric nanofoam.

Abstract: An optical member including a porous glass layer on a base member is provided, wherein the reflectance is reduced and a ripple is suppressed. The optical member is provided with a base member and a glass layer holding a transparent material in the inside of a porous structure disposed on the base member, wherein in the thickness direction of the glass layer, the porosity in the base member side with respect to the center line of the glass layer in the thickness direction is smaller than the porosity in the side opposite to the base member with respect to the center line of the glass layer in the thickness direction.

Abstract: A layered structure for an organic light-emitting diode (OLED) device, the layered structure including a light-transmissive substrate and an internal extraction layer formed on one side of the light-transmissive substrate, in which the internal extraction layer includes (1) a scattering area containing scattering elements composed of solid particles and pores, the solid particles having a density that decreases as it goes away from the interface with the light-transmissive substrate, and the pores having a density that increases as it goes away from the interface with the light-transmissive substrate, and (2) a free area where no scattering elements are present, formed from the surface of the internal extraction layer, which is opposite to the interface, to a predetermined depth.

Abstract: The invention relates to a novel process for commercial production of bulk functionally graded materials (FGM) with a per-determined axial, radial, and spherical gradient profiles. The process is based on the reiterated deformation of the layers of variable cross-section thicknesses made of different materials. That allows significant savings of time, energy and materials. Metals, ceramics, glasses and polymers in different combinations can be brought together with a continuous or stepwise gradual change from one material to another. The invention can be applied to industrial production of functionally graded materials with different types of gradient profiles, which cannot be produced by the existing technologies and which are sought by many key industries. The mechanical, thermal and optical responses of materials produced by the proposed methods are of considerable interest in optics, optoelectronics, tribology, biomechanics, nanotechnology and high temperature technology.

Abstract: A porous polyimide film having a three-layer structure that comprises two surface layers (a) and (b) and a macrovoid layer sandwiched between the surfaces layers (a) and (b). The macrovoid layer has a partition wall bonding to the surface layers (a) and (b), and multiple macrovoids each surrounded by the partition wall and the surface layers (a) and (b) and having a mean pore size in the film plane direction of from 10 to 500 ?m. The partition wall of the macrovoid layer has a thickness of from 0.1 to 50 ?m and has multiple pores having a mean pore size of from 0.01 to 50 ?m. The surface layers (a) and (b) each have a thickness of from 0.1 to 50 ?m, at least one of the surface layers has multiple pores having a mean pore size of from more than 5 ?m to 200 ?m, and the other surface layer has multiple pores having a mean pore size of from 0.01 to 200 ?m.

Abstract: In one embodiment, an aerogel includes a layer of shaped particles having a particle packing density gradient in a thickness direction of the layer, wherein the shaped particles are characterized by being formed in an electrophoretic deposition (EPD) process using an impurity. In another embodiment, a method for forming a functionally graded porous nanostructure includes adding particles of an impurity and a solution to an EPD chamber, applying a voltage difference across the two electrodes of the EPD chamber to create an electric field in the EPD chamber, and depositing the material onto surfaces of the particles of the impurity to form shaped particles of the material. Other functionally graded materials and methods are described according to more embodiments.

Abstract: The invention relates to a method for producing a ceramic layer (18) on a surface formed from a Ni base alloy (17), comprising the following steps: producing on the surface a ceramic layer (18) containing ZrO2 as a main constituent; producing a gas phase having a temperature in the range from 400 to 900° C., in which a vapour formed from a salt melt (8) with the components alkali chloride, alkali sulphate and ZnCl2 is contained in a carrier gas formed from an inert gas with an addition from 0.5 to 10% by weight HCl; and bringing the ceramic layer (18) into contact with the gas phase for a period of time that is sufficient for an intermediate layer (19) having a thickness of at least 0.1 ?m to form between the ceramic layer (18) and the surface.

Abstract: The invention relates to foamed thermoplastic material articles of manufacture having an internal layered cellular structure (with segmented and varying physical properties across one or more dimensions). In one embodiment, the invention is directed to a multi-layer foamed polymeric article of manufacture having a plurality of discrete physical properties segmented across one or more dimensions, comprising: a non-laminated multi-layer polymeric object having at least one discrete outer layer positioned adjacent to a plurality of discrete inner foamed layers, wherein the at least one discrete outer layer and the plurality of discrete inner foamed layers are integral with one another, and wherein the at least one discrete outer layer has an outer layer physical property and each of the plurality of discrete inner foamed layers has a respective inner foamed layer physical property, wherein the outer layer physical property and the inner foamed layer physical property are different from each other.

Abstract: A thermal barrier tile (34) with a braze layer (46) co-sintered to a ceramic layer (48) is brazed to a substrate (26) of a component for fabrication or repair of a thermal barrier coating (28) for example on a gas turbine ring segment (22, 24). The tile may be fabricated by disposing a first layer of a metal brazing material in a die case (40); disposing a second layer of a ceramic powder on the metal brazing material; and co-sintering the two layers with spark plasma sintering to form the co-sintered ceramic/metal tile. A material property of an existing thermal barrier coating to be repaired may be determined (90), and the co-sintering may be controlled (93) responsive to the property to produce tiles compatible with the existing thermal barrier coating in a material property such as thermal conductivity.

Abstract: A membrane for use in a high temperature gas processing system and method for making the same. The membrane includes a dense, gas impermeable layer and a first and second porous layer, wherein each of the first and second porous layers is a ceramic oxide material having a non-symmetrical load bearing skeleton of a plurality of pores having a graded porosity. Each porous layer provides a reduction of an oxygen partial pressure gradient across the dense layer and reduces resultant stresses in the dense layer that are small compared to its strength thereby improving long term mechanical durability of the dense layer.

Abstract: A flooring system for use in thermal and/or acoustic floor systems is provided where the flooring system mitigates external forces from a shock/blast wave. The flooring system includes a foam layer and filler material that includes micro and/or nano structures strategically dispersed in the foam layer. The micro and/or nano structures mitigate a magnitude of the external forces propagating through the foam layer.

Abstract: Disclosed herein are emissive ceramic materials having a dopant concentration gradient along a thickness of a yttrium aluminum garnet (YAG) region. The dopant concentration gradient may include a maximum dopant concentration, a half-maximum dopant concentration, and a slope at or near the half-maximum dopant concentration. The emissive ceramics may, in some embodiments, exhibit high internal quantum efficiencies (IQE). The emissive ceramics may, in some embodiments, include porous regions. Also disclosed herein are methods of make the emissive ceramic by sintering an assembly having doped and non-doped layers.

Abstract: A panel for use over a vehicle airbag includes a multi-layer covering disposed over a substrate outer surface. The covering includes a decorative skin layer and a foam layer between the substrate and the skin layer. The covering also includes a tear seam provided at a pre-determined location for an airbag deployment opening. The foam layer has one or more material properties that vary between the substrate and the skin layer. The density of an outside layer of the foam layer may be greater than the density of an inside layer of the foam layer to improve tear seam function. The covering layers may be bonded to each other without the use of additional adhesive material. The tear seam may be formed by laser scoring and may have at least a portion that extends into the foam layer and may further extend into the skin layer.

Abstract: A metal sealing material used in a sealing device which can reduce a gap between a stator and a rotor of a turbine. The metal sealing material used in a sealing device for a stator and a rotor of a turbine includes a surface layer and a lower layer composed of a porous metal layer, wherein the porosity of the surface layer is smaller than the porosity of the lower layer; the porosity of the surface layer is 60 to 65% and the porosity of the lower layer is 67 to 75% or less; and the porous metal layer has a thickness of 0.3 to 3.0 mm and may include, as a main component, an MCrAlY alloy where M is either one of Ni and Co or both thereof, and h-BN as a solid lubricant.

Abstract: The present invention provides an inexpensive optical layered body which does not cause interference fringes but excels in hard coat properties, antistatic properties, and antireflection properties. An optical layered body comprises: a light-transmitting substrate; and a hard coat layer (A) and a hard coat layer (B) on one face of the light-transmitting substrate in this order, wherein the hard coat layer (B) has a region (B1) not containing inorganic fine particles and a region (B2) containing inorganic fine particles, in this order from a portion adjacent to the hard coat layer (A), a boundary between the region (B1) not containing inorganic fine particles and the region (B2) containing inorganic fine particles has irregularities, and the inorganic fine particles have a particle size smaller than a visible light wavelength.

Abstract: A water vapor permeable multi-layer thermal insulation (10) includes two water vapor permeable outer layers (16, 18) encapsulating inner air and water vapor permeable layers (14) of insulation material and at least one inner separating layer (12) of an air-open fibrous material interleaved with the inner thermal insulation layers (14) and having a mean flow pore size that allows water vapor to move from one side of the at least one inner fibrous separating layer to the other and through the inner insulation layers yet restricts mass movement of air from one side to the other of the at least one inner fibrous separating layer (12) to form a barrier to convection.

Abstract: A thermoplastic foil has an embossed three-dimensionally structured surface (2) in the external cover layer. The cover layer is configured as a foamed layer and has a foam density that varies across the layer thickness thereof and increases toward the surface.

Abstract: The present invention relates to an anti-reflective coating film. This anti-reflective coating film shows more improved interface adhesion and scratch resistance, which can be manufactured by a simple process.

Abstract: Composite with a first part composed of a thermoset material and with a second part composed of a thermoplastic material, and with an adhesion-promoter layer located between these, where the first part has been bonded by way of the adhesion-promoter layer to the second part, and where the adhesion-promoter layer comprises pyrolytically deposited semiconductor oxides and/or pyrolytically deposited metal oxides.

Abstract: A plastic substrate has a porous layer on a surface. The porous layer is formed at least partially from a material of the plastic substrate and has pores. The proportion by volume of pores is greater in a first region of the porous layer than in a second region of the porous layer. The second region follows the first region, as seen proceeding from the plastic substrate. The porous layer can be produced by a plasma process that simultaneously effects structuring of the plastic substrate by ion bombardment and coating of the plastic substrate.

Abstract: Optical film having a transparent support and optical functional layer as the outermost layer. The optical functional layer is on or above the transparent support; has a thickness of 50-250 nm; and contains low refractive index fine particles having a refractive index of ?1.45 and arranged substantially in a line on a surface of the optical functional layer on the opposite side of the transparent support, high refractive index fine particles having a refractive index of ?1.55 and unevenly distributed in a lower part of the optical functional layer on the side of the transparent support, and a fluorine-containing compound.

Abstract: Disclosed is a porous polyimide membrane of a three-layer structure having two surface layers (a) and (b) and a macrovoid layer interposed between the surface layers (a) and (b), wherein the macrovoid layer has a partition wall joined to the surface layers (a) and (b) and plural macrovoids surrounded by the partition wall and the surface layers (a) and (b), with an average void diameter in a membrane plane direction of from 10 to 500 ?m; each of the partition wall of the macrovoid layer and the surface layers (a) and (b) has a thickness of from 0.1 to 50 ?m and has plural pores having an average pore diameter of from 0.01 to 5 ?m, the pores being communicated with each other and also communicated with the macrovoids; and the membrane has a total membrane thickness of from 5 to 500 ?m and a porosity of from 70 to 95%.

Abstract: Provided is a porous material excellent in heat insulating property, mechanical property, and surface properties (such as adhesiveness and abrasion property). The porous material is a polymer porous film of a single layer, including a first porosity size changing portion (613) formed of independent porosities each showing a gradual increase in porosity size across a region accounting for 10% or more of a film thickness from a first surface side (611) toward a second surface side (612).

Abstract: The invention disclosed herein relates to relates to foamed thermoplastic material objects and articles of manufacture having an internal layered cellular structure, as well as to methods of making the same. In one embodiment, the invention is directed to a multi-layer foamed polymeric article of manufacture, comprising: a non-laminated multi-layer thermoplastic material sheet, wherein the multi-layer thermoplastic material sheet has first and second discrete outer layers sandwiching a plurality of discrete inner foamed layers, and wherein the two outer layers and plurality discrete inner foamed layers are integral with one another. The thermoplastic material may be a semi-crystalline polymer such as, for example, PET (polyethylene terephthalate), PEEK (polyetheretherketone), PEN (polyethylene napthalate), PBT (polybutylene terephthalate), PMMA (polymethyl methacrylate), PLA (polyactide), polyhydroxy acid (PHA), thermoplastic urethane (TPU), or blends thereof.

Abstract: The present disclosure generally relates to patterned gradient polymer films and methods for making the same, and more particularly to patterned gradient optical films that have regions that include variations in optical properties such as refractive index, haze, transmission, clarity, or a combination thereof. The variation in optical properties can occur across a transverse plane of the film as well as through a thickness direction of the film.

Abstract: A carbon foam article useful for, inter alia, composite tooling or other high temperature applications, which includes a carbon foam having a ratio of compressive strength to density of at least about 7000 psi/g/cc.

Abstract: A structure including a substrate and a coating material. The substrate includes a plurality of voids and a surface on which at least the plurality of voids are formed, and is formed such that a void ratio of the plurality of voids decreases one of 2-dimensionally and 3-dimensionally from an inner side of the substrate toward an outer side thereof. The coating material is formed on the surface of the substrate.

Abstract: In one embodiment, an aerogel includes a layer of shaped particles having a particle packing density gradient in a thickness direction of the layer, wherein the shaped particles are characterized by being formed in an electrophoretic deposition (EPD) process using an impurity. In another embodiment, a method for forming a functionally graded porous nanostructure includes adding particles of an impurity and a solution to an EPD chamber, applying a voltage difference across the two electrodes of the EPD chamber to create an electric field in the EPD chamber, and depositing the material onto surfaces of the particles of the impurity to form shaped particles of the material. Other functionally graded materials and methods are described according to more embodiments.

Abstract: Prepare an article by providing an extruded thermoplastic polymer foam having a cavity defined therein and placing a vacuum insulation panel entirely within the cavity.

Abstract: An example of a nanoballoon thermal protection system includes a refractory ceramic foam having carbide balloons. The foam has a closed cell structure not allowing liquid to penetrate through the foam. Each of the carbide balloons is hollow and has a diameter greater than 0 nm and less than 900 nm. Each of the carbide balloons includes a refractory carbide. In addition, a vehicle with thermal shield includes a surface and a first and second nanoballoon closed cell foam coatings. Each of the foam coatings has a melting point temperature greater than 1000° C. and a density less than 85%. Each of the foam coatings has hollow balloons having a diameter less than 900 nm. Each of the foam coatings includes a closed cell structure not allowing liquid to penetrate through the respective coating. Methods for manufacturing a nanoballoon system and a nanoballoon thermal protection system are also disclosed.

Abstract: A multilayer substrate includes a base layer, a coating layer and an intermediate layer positioned between the base layer and the coating layer. The intermediate layer contains chromium and nitrogen. A content of the chromium in the intermediate layer gradually decreases from the base layer to the coating layer.

Abstract: A gradient optical film and an optical construction including the gradient optical film are described. The gradient optical film includes a binder, a plurality of particles, and a plurality of interconnected voids having a local volume fraction. The local volume fraction of the plurality of interconnected voids varies along a thickness direction of the gradient optical film. The refractive index of the gradient optical film can also varies along a thickness direction of the gradient optical film, as the refractive index can also depend upon the local volume fraction of the plurality of interconnected voids.

Abstract: This invention relates to thermal spray coatings on a metal or non-metal substrate. The thermal spray coating comprises a ceramic coating having a functionally graded porosity across the ceramic coating thickness. The ceramic coating includes an inner layer and an outer layer. The inner layer has a porosity at or near the interface of the inner layer and the metal or non-metal substrate sufficient to provide a compliant ceramic coating capable of straining under thermal expansion mismatch between the ceramic coating and the metal or non-metal substrate at elevated temperature. The outer layer has a decreasing porosity extending from the surface of the inner layer to the surface of the ceramic coating sufficient to provide corrosion resistance and/or plasma erosion resistance to said ceramic coating. This invention also relates to methods of protecting metal and non-metal substrates by applying the thermal spray coatings.

Abstract: This invention provides a tantalum carbide-coated carbon material, which has excellent corrosion resistance to reducing gases and thermal shock resistance at high temperatures, and a process for producing the same. The tantalum carbide-coated carbon material comprises a carbon substrate and a coating film provided on the carbon substrate directly or through an intermediate layer. The coating film is formed of a large number of densely aggregated fine crystals of tantalum carbide. The diffraction line of the (220) plane of tantalum carbide shows the maximum diffraction intensity in an X-ray diffraction pattern of the coating film. More preferably, this diffraction intensity is not less than four times the intensity of a diffraction line showing the second highest diffraction intensity.

Abstract: The invention relates to a method for producing a flameproof polyurethane (PUR) spray foam, especially a rigid PUR spray foam, to a spray foam body so produced and to the use thereof for heat insulation.

Abstract: A zircon body for use in glass manufacturing is provided containing zircon grains and an intergranular phase present between the zircon grains. The intergranular phase may contain silicon oxide. The body may be exposed to a halide to at least partially remove at least a majority of the silicon oxide contained in the intergranular phase from the outer portion or to at least partially remove the intergranular phase along an outer portion of the component.