Particles (e.g., Pigment, Etc.) Present In Ink Receptive Layer Patents (Class 428/32.34)
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Patent number: 7297365Abstract: A method of manufacturing a recorded matter having an ink-receiving layer of a porous structure. The ink-receiving layer has an image region where an image is formed with a coloring material. The method includes the steps of (i) applying an ink to the ink-receiving layer to obtain an image region where an image is formed with a coloring material contained in the ink, (ii) applying a liquid comprising a non-volatile liquid not dissolving the coloring material to the ink-receiving layer, and (iii) forming a portion in which all or substantially all of the coloring material distributed in a thickness direction of the ink-receiving layer is embedded in the non-volatile liquid by rubbing the non-volatile liquid after it is applied. The non-volatile liquid contains an ester of a saturated fatty acid and an alcohol.Type: GrantFiled: April 28, 2005Date of Patent: November 20, 2007Assignee: Canon Kabushiki KaishaInventors: Takayuki Ishikawa, Keiichi Murai, Hiroshi Tajika, Takao Yamamoto
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Patent number: 7297382Abstract: An improved ink-jet recording material is disclosed comprising a support and at least one ink receiving layer containing a water-soluble or water-dispersible polymer, characterized in that said polymer comprises a repeating monomeric unit having a moiety capable of chelating boric acid by means of at least one nitrogen containing functional group and at least one hydroxyl group thereby forming a five- or six-membered ring.Type: GrantFiled: November 5, 2003Date of Patent: November 20, 2007Assignee: AGFA-GevaertInventors: Hubertus Van Aert, Johan Loccufier, Stefaan Lingier
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Publication number: 20070237911Abstract: A production method of a coating liquid for an ink receiving layer, capable of suppressing viscosity increase of the coating liquid, a coating liquid for an ink receiving layer obtained by the method, an ink jet recording medium produced using this coating liquid, and a production method thereof. 1. A production method of a coating liquid for an ink receiving layer, the production method including: dispersing in a liquid at least silica fine particles synthesized by a gas phase method and an amino acid having only one carboxyl group per molecule, to obtain a silica dispersion; adding a water soluble binder to the silica dispersion.Type: ApplicationFiled: April 9, 2007Publication date: October 11, 2007Applicant: FUJIFILM CorporationInventor: Ryoichi Nakano
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Publication number: 20070231511Abstract: A high quality ink jet recording medium with a printed image non-vulnerable and excellent in scratch resistance is obtained with an ink jet recording using a water pigment ink. An ink jet recording medium having a substrate and an ink receiving layer including an inorganic particle and a binder on the substrate is provided. A surface of the ink receiving layer has (a) a projected valley portion depth (Rvk) of not less than 20 nm and not more than 100, (b) an arithmetic average roughness (Ra) of not less than 5 nm and not more than 100 nm, and (c) an average spacing (S) of local peaks of not more than 1.0 ?m.Type: ApplicationFiled: March 29, 2007Publication date: October 4, 2007Applicant: CANON KABUSHIKI KAISHAInventors: Teruaki Okuda, Yoshiyuki Nagase, Nobuo Tokutake, Asako Watanabe
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Patent number: 7273643Abstract: An article having multiple spectral deposits is provided. The article can include a support and a single nanomorphic marking material adapted to reflect light having a first spectral content and adapted to reflect light having a second spectral content. The article can include a support and a nanomorphic marking material held by the support that luminesces at a plurality of wavelengths. The article can include a support and marking material having a first particle size and a second particle size. The first particle size reflects a first spectrum and the second particle size reflects a second spectrum. The article can include a support and a marking material held by said support with the marking material including a nanocrystalline particulate having a measurable property non-characteristic of the same marking material in a bulk state.Type: GrantFiled: June 24, 2003Date of Patent: September 25, 2007Assignee: Eastman Kodak CompanyInventors: David J. Nelson, Sridhar Sadasivan, Ramesh Jagannathan, Seshadri Jagannathan, Glen C. Irvin, Jr., Rajesh V. Mehta
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Patent number: 7264856Abstract: An inkjet recording element comprising, over a porous, ink-receiving layer, a fusible, porous topmost layer comprising a film-forming, hydrophobic binder and fusible, polymeric particles of a non-segmented polyurethane, or salt thereof, comprising repeat units derived from a diisocyanate and a diol component comprising a mixture of diols, said diol mixture comprising: an anionically-substituted diol selected from carboxylic acid-, sulfonic acid-, and phosphonic acid-substituted diol and an ether containing short chain aliphatic diol, wherein the polyurethane has a Tg greater than about 70° C.Type: GrantFiled: March 21, 2005Date of Patent: September 4, 2007Assignee: Eastman Kodak CompanyInventors: Allan Wexler, Paul D. Yacobucci, Kurt M. Schroeder
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Publication number: 20070196598Abstract: An inkjet-recording medium comprising a support and an ink-receiving layer formed thereon containing inorganic fine particles, a water-soluble aluminum compound, a zirconium compound, a cationic modified self-emulsifying polymer, a polyvinyl alcohol having a saponification value of 92 to 98 mol %, and a crosslinking agent, and a method of producing the same.Type: ApplicationFiled: February 21, 2007Publication date: August 23, 2007Applicant: FUJIFILM CORPORATIONInventors: Kazuyuki Koike, Hiroki Kubo, Mitsuhiro Saito, Hirokazu Kito
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Publication number: 20070196597Abstract: The invention provides an inorganic fine particle dispersion having at least an inorganic fine particles, a silane coupling agent, and at least one member selected from the group consisting of a basic inorganic salt and ammonium, the inorganic fine particle dispersion having a pH of 5.0 or less, and a method for forming thereof including at least adjusting the pH by using the basic inorganic salt and/or the ammonium. The invention further provides an ink jet recording medium and a method manufacturing thereof including at least applying an ink-receiving layer coating liquid formed by mixing the inorganic fine particle dispersion and a water-soluble resin onto a support.Type: ApplicationFiled: February 12, 2007Publication date: August 23, 2007Applicant: FUJIFILM CorporationInventors: Kentaro Shiratsuchi, Tomoya Kubota
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Patent number: 7255909Abstract: In one aspect, the invention provides a security laminate comprising a retroreflective layer comprising a plurality of retroreflective microbeads partially embedded in and protruding from a beadbond layer and having image receptive material disposed around the protruding microspheres. In another embodiment, the security laminate further comprises indicia patterns viewable in retroreflective light. In another embodiment, the security laminate is imaged on the image receptive material.Type: GrantFiled: February 6, 2003Date of Patent: August 14, 2007Assignee: 3M Innovative Properties CompanyInventors: Graeme R. Mann, Brian W. Dunne, Paul D. Graham, Thomas Junck, Mark F. Schulz
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Patent number: 7250202Abstract: A recording sheet for ink jet printing comprising a support onto which is coated at least one ink receiving layer and includes a porous inorganic oxide and an aliphatic hydroxycarboxylic acid with at least 2 C atoms.Type: GrantFiled: June 18, 1999Date of Patent: July 31, 2007Inventor: Rolf Steiger
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Publication number: 20070166486Abstract: In an ink-jet recording media, an ink receiving layer formed over a transparent support having a total-light-ray transmittance of 80% or more contains inorganic particles A having an average of agglomerated particle diameters of from 0.5 ?m to less than 1 ?m and inorganic particles B having an average of agglomerated particle diameters of from 7.5 ?m to less than 10 ?m at a ratio A/B of 25/75 to 75/25.Type: ApplicationFiled: January 8, 2007Publication date: July 19, 2007Applicant: FUJIFILM CorporationInventors: Tomoya Kubota, Kentaro Shiratsuchi
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Patent number: 7244478Abstract: A method of manufacturing a recording medium with an excellent productivity is provided. The method provides a recording medium having excellent ink absorbency and coloring property and includes an ink-receiving layer in which a binder is restricted and controlled. The present invention provides a method of manufacturing a recording medium including the steps of: performing a surface treatment on a substrate; and forming an ink-receiving layer using at least a pigment, polyvinyl alcohol, and a coating liquid that contains at least one selected from the group consisting of boric acid and borate. In this method, the surface-treatment step includes a first surface treatment and a second surface treatment. In the first surface treatment, a coating liquid that contains at least one selected from the group consisting of boric acid and borate is applied followed by being dried and solidified.Type: GrantFiled: September 22, 2003Date of Patent: July 17, 2007Assignee: Canon Kabushiki KaishaInventors: Yuji Kondo, Shigehira Iida, Tsuyoshi Santo, Motoaki Sato, Kenichi Yamaguchi
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Patent number: 7232600Abstract: An ink-jet recording medium having at least a light-reflecting layer and a dye-fixing layer formed in this order on a base material in a multilayer structure, wherein the light-reflecting layer contains two or more pigments different in chemical composition, and wherein the average particle size of a pigment (A) having a highest liquid absorbency in the pigments is smaller than the average particle size of a pigment (B) having a lowest liquid absorbency in the pigments.Type: GrantFiled: February 25, 2002Date of Patent: June 19, 2007Assignee: Canon Kabushiki KaishaInventor: Katsutoshi Misuda
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Patent number: 7223453Abstract: An ink jet recording medium containing a support and an ink receiving layer on the support, in which the ink receiving layer includes at least a complex formed from a metal with a valence of two or more and an acidic group-containing compound having a substituent group containing a nitrogen atom, an oxygen atom or a sulfur atom. The acidic group-containing compound is preferably a compound represented by the following general formula (I).Type: GrantFiled: December 5, 2003Date of Patent: May 29, 2007Assignee: Fujifilm CorporationInventors: Masanobu Takashima, Shigetomo Tsujihata
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Patent number: 7199182Abstract: An aqueous resin composition is provided which does not use a high boiling point solvent, and yet displays favorable long term stability and excellent film formation, and does not suffer from problems such as skin generation. The aqueous resin composition comprises a water soluble magnesium salt (A) and an aqueous polyurethane (B).Type: GrantFiled: June 28, 2001Date of Patent: April 3, 2007Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Yoshimasa Tanaka, Masato Inoue, Masatoshi Matsuo, Yutaka Hashimoto
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Patent number: 7160608Abstract: A coated paper comprised of a paper substrate, at least one surface of which is provided with at least one coating layer, characterized in that the surface of said coating layer has cracks of a width of 0.2 to 3.0 ?m and a length of 3 to 1000 ?m in an amount of 1 to 1000 cracks per mm2 is provided. In another embodiment, a coated paper comprised of a paper substrate, at least one surface of which is provided with at least two coating layers, characterized in that an inner coating layer adjoining said paper substrate comprises a pigment having a crystal structure selected from the group consisting of acicular crystal, spindle-shape crystal, columnar crystal, and rice-shape granulated crystal, and starches, and an outermost coating layer formed on said inner coating layer comprises crack formation promoting particles and a styrene-butadiene copolymer having a glass transition temperature of 20 to 150° C. is provided.Type: GrantFiled: June 25, 2004Date of Patent: January 9, 2007Assignee: Oji Paper Co., Ltd.Inventors: Kenji Yanagisawa, Tomofumi Tokiyoshi, Masayuki Yamamoto, Shigeru Nagashima
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Patent number: 7150901Abstract: An inkjet recording element comprising a porous ink-receiving layer having interconnecting voids is disclosed in which an upper surface of the ink-receiving layer has been subjected to plasma treatment, and wherein the upper surface of the ink-receiving layer, prior to the plasma treatment, has a measured carbon elemental content of at least 40 percent. The invention can provide increased dot spread.Type: GrantFiled: December 5, 2003Date of Patent: December 19, 2006Assignee: Eastman Kodak CompanyInventors: Bruce C. Campbell, Lisa B. Todd, James A. Reczek, Mary Catherine S. Oldfield, Hengzhong K. Zhuang
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Patent number: 7147901Abstract: The object of the present invention is to obtain a double-side ink jet recording sheet at least one side of which has gloss surface and in which scratches caused by rubbing of sheets hardly occur. According to the present invention, there is obtained a double-side ink jet recording sheet comprising a support provided with at least one ink-receiving layer on each of both sides, wherein at least one side has a gloss surface having a 75° specular glossiness of not less than 40% and the ink-receiving layer on the side opposite to the side having gloss surface contains organic particles having an average particle diameter of 2–40 ?m. The outermost layer of the side having the gloss surface is preferably formed by subjecting to pressure-contact specular finishing by cast-coating method.Type: GrantFiled: October 29, 2002Date of Patent: December 12, 2006Assignee: Mitsubishi Paper Mills LimitedInventors: Kunio Kasamatsu, Katsuhiko Kawasaki, Suguru Kashima
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Patent number: 7141280Abstract: The invention provides an ink receiving medium comprising a macroporous substrate having a fluid management system and having a pigment management system in contact with surfaces of macropores of the substrate therein. In one embodiment, the pigment management system comprises water-soluble multivalent metal salt and the fluid management system comprises surfactant.Type: GrantFiled: July 1, 2004Date of Patent: November 28, 2006Assignee: 3M Innovative Properties CompanyInventors: Mark F. Schulz, Omar Farooq
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Patent number: 7138162Abstract: An ink jet recording element including a support having thereon an image-receiving layer, the ink jet recording element containing a metal hydroxide salt, (M2+)(OH)a(Ap?)b.xH2O; wherein: M2+ is at least one metal ion having a 2+ oxidation state; A is an organic or inorganic anion; p is 1 or 2; and x is equal to or greater than 0; and a and b comprise rational numbers as follows: 0<a<2 and 0<b<2 so that the charge of M2+ is balanced.Type: GrantFiled: June 26, 2002Date of Patent: November 21, 2006Assignee: Eastman Kodak CompanyInventors: Krishamohan Sharma, Christine Landry-Coltrain, Joseph F. Bringley
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Patent number: 7122231Abstract: An ink jet recording element comprising a support having thereon an image-receiving layer, the ink jet recording element containing finely divided particulate material and a metal(oxy)hydroxide complex, Mn+(O)a(OH)b(Ap?)c.xH2O, wherein M is at least one metal ion; n is 3 or 4; A is an organic or inorganic ion; p is 1, 2 or 3; and x is equal to or greater than 0; with the proviso that when n is 3, then a, b and c each comprise a rational number as follows: 0?a<1.5; 0<b<3; and 0?pc<3, so that the charge of the M3+ metal ion is balanced; and when n is 4, then a, b and c each comprise a rational number as follows: 0?a<2; 0<b<4; and 0?pc<4, so that the charge of the M4+ metal ion is balanced.Type: GrantFiled: June 26, 2002Date of Patent: October 17, 2006Assignee: Eastman Kodak CompanyInventors: Krishamohan Sharma, Joseph F. Bringley, Christine Landry-Coltrain
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Patent number: 7105215Abstract: An ink jet recording element comprising a support having thereon an image-receiving layer, the ink jet recording element containing a metal(oxy)hydroxide complex, Mn+(O)a(OH)b(Ap?)c•xH2O, wherein M is at least one metal ion; n is 3 or 4; A is an organic or inorganic ion; p is 1, 2 or 3; and x is equal to or greater than 0; with the proviso that when n is 3, then a, b and c each comprise a rational number as follows: 0?a<1.5; 0<b<3; and 0?pc<3, so that the charge of the M3+ metal ion is balanced; and when n is 4, then a, b and c each comprise a rational number as follows: 0?a<2; 0<b<4; and 0?pc<4, so that the charge of the M4+ metal ion is balanced.Type: GrantFiled: June 26, 2002Date of Patent: September 12, 2006Assignee: Eastman Kodak CompanyInventors: Krishamohan Sharma, Joseph F. Bringley, Paul B. Merkel, Deepak Shukla, Christine Landry-Coltrain
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Patent number: 7087275Abstract: A coating fluid for application to a support to prepare an ink jet recording medium comprises an aqueous dispersion of a synthetic polymer hydrogel and gelatin, the amount of the synthetic polymer hydrogel being from 5 to 50% by weight of the combined weight of synthetic polymer and gelatin. Preferably the coating fluid also contains a mordant, an aliphatic alcohol to assist dispersion of the hydrogel polymer and a particulate material to impart a porous structure to the coating. The invention also provides an inkjet recording medium comprising a support on which is an ink-receiving layer comprising the gelatin and a synthetic polymer hydrogel. The amount of the latter may be from 0.3 to 5 g/square meter.Type: GrantFiled: May 30, 2002Date of Patent: August 8, 2006Assignee: Eastman Kodak CompanyInventors: Julie Baker, Malcolm D. Purbrick
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Patent number: 7087274Abstract: An improved ink-jet printable heat-transfer medium comprising a base substrate having a surface coated with a hot-melt layer and an ink-receptive layer is provided. The ink-receptive layer comprises: i) non-polymeric organic particles that are a reaction product of a diamine and two molecules, each molecule having at least one carboxylic acid group and at least five carbon atoms, ii) thermoplastic polymer particles, and iii) a thermoplastic film-forming binder. The heat-transfer paper can produce printed images having improved color quality, hand, and wash-durability on a variety of fabric materials.Type: GrantFiled: December 21, 2004Date of Patent: August 8, 2006Assignee: Arkwright IncorporatedInventors: Zhong Xu, Robert M. Conforti, William M. Risen, Jr.
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Patent number: 7083671Abstract: In accordance with embodiments of the present invention, an ink-jet ink can comprise a liquid vehicle including a halophenol and a metallized dye. Alternatively, a system for printing images with improved ozone fastness can comprise a printing medium including an ink-receiving layer coated thereon, wherein the ink-receiving layer includes semi-metal oxide or metal oxide particulates, and an ink-jet ink configured for printing on printing medium. The ink-jet ink can comprise a liquid vehicle including a protonated phenol devoid of water solubilizing moieties, and a metallized dye.Type: GrantFiled: July 16, 2004Date of Patent: August 1, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Linda C. Uhlir-Tsang, John R. Moffatt
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Patent number: 7083836Abstract: An ink jet recording element comprising a support having thereon, in order, a hydrophilic absorbing layer and a polymeric overcoat layer comprising particles of a substantially amorphous synthetic aluminosilicate. Such recording elements exhibit improved humidity keeping and smudge resistance, while maintaining good differential gloss.Type: GrantFiled: November 10, 2003Date of Patent: August 1, 2006Assignee: Eastman Kodak CompanyInventors: Charles E. Romano, Jr., Richard J. Kapusniak, Lori J. Shaw-Klein, Terry C. Schultz, Peter J. Ghyzel
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Patent number: 7070840Abstract: An inkjet recording sheet has a colorant-receiving layer on a support. The colorant-receiving layer is provided with at least one of compounds represented by the following formulas (1) to (4) and which has either or both of an I/O value of at least 0.5 and a water soluble property. The colorant-receiving layer is also provided with at least one organic mordant selected from polyallylamine, polyvinylamine and derivatives of these.Type: GrantFiled: April 26, 2002Date of Patent: July 4, 2006Assignee: Fuji Photo Film Co., Ltd.Inventors: Hisao Yamada, Kazuyuki Koike, Ryoichi Nakano, Yuichi Wakata
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Patent number: 7056562Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon a ink-receiving layer comprising a hydrophilic polymer and particles of an aluminosilicate in an amount of less than 30 weight percent solids, based on the total weight of the layer. Such recording elements exhibit improved humidity keeping for print sharpness.Type: GrantFiled: January 16, 2004Date of Patent: June 6, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Peter J. Ghyzel, Terry C. Schultz, Lori J. Shaw-Klein
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Patent number: 7052535Abstract: Anti-bronzing compounds are added to inkjet inks to prevent bronzing of the inks when printed on specialty quick-dry inkjet photographic media. These compounds inhibit bronzing by the proper buffering of the dyes relative to the media of interest.Type: GrantFiled: July 28, 2003Date of Patent: May 30, 2006Assignee: Hewlett-Packard Development Company, L.P.Inventors: Linda C. Uhlir-Tsang, John R Moffatt, Mary E Austin
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Patent number: 7052748Abstract: An inkjet recording element comprising a support having thereon, in order, a support having thereon an ink-receiving layer comprising a hydrophilic polymer, a polymeric mordant, and particles of an aluminosilicate. Such recording elements exhibit improved humidity keeping.Type: GrantFiled: January 16, 2004Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Lori J. Shaw-Klein, Terry C. Schultz, Peter J. Ghyzel
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Patent number: 7052749Abstract: An inkjet recording element comprising a support having thereon a subbing layer comprising particles of an aluminosilicate for improved adhesion.Type: GrantFiled: January 16, 2004Date of Patent: May 30, 2006Assignee: Eastman Kodak CompanyInventors: Richard J. Kapusniak, Charles E. Romano, Jr., Lori J. Shaw-Klein, Peter J. Ghyzel, Terry C. Schultz
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Patent number: 7015270Abstract: A stable, aqueous dispersion, which includes: silicon dioxide mixed-oxide particles dispersed in at least one water-soluble cationic polymer having a mass average molar mass of less than 100,000 g/mol, said mixed-oxide including aluminum oxide or titanium dioxide, wherein said particles are produced by flame hydrolysis, wherein said particles have a BET specific surface area of 5 to 600 m2/g and a negative zeta potential, and wherein the dispersion has a positive zeta potential.Type: GrantFiled: January 27, 2003Date of Patent: March 21, 2006Assignee: Degussa AGInventors: Thomas Scharfe, Christoph Batz-Sohn, Wolfgang Lortz
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Patent number: 7008671Abstract: In order to provide a recorded matter having image fastness to light and gas, disclosed is a recorded matter having an ink-receiving layer of a porous structure, wherein the ink-receiving layer has an image region where an image is formed with a coloring material, wherein the image region has a portion in which all or substantially all of the coloring material distributing in a thickness direction of the ink-receiving layer is embedded in a non-volatile liquid which does not dissolve the coloring material.Type: GrantFiled: December 21, 2001Date of Patent: March 7, 2006Assignee: Canon Kabushiki KaishaInventors: Takayuki Ishikawa, Keiichi Murai, Hiroshi Tajika, Takao Yamamoto
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Patent number: 6994834Abstract: A surface modified fine silica powder which has been treated, preferably, with a treating agent containing an amino group, characterized in that the powder exhibits an adsorption amount for an anion source compound of 150% or more of that of an original powder which has not been treated; and a printing material using the silica powder. The surface modified fine silica powder can provide an excellent printed matter being free from blotting with ink or a cracking of coating film.Type: GrantFiled: September 22, 2000Date of Patent: February 7, 2006Assignee: Nippon Aerosil Co., Ltd.Inventors: Hirokuni Shirono, Masamichi Murota, Yuki Amano
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Patent number: 6994026Abstract: A method for the preparation of a flexographic printing plate is disclosed. In this method an ink jet image is used as mask for the exposure of a flexo plate precursor. The ink jet recording material is composed of several layers and comprises a binder, a cationic mordant and a spacing agent in its top layer.Type: GrantFiled: February 3, 2003Date of Patent: February 7, 2006Assignee: AGFA-GevaertInventors: Frank De Voeght, Peter Slabbinck, Huub Van Aert
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Patent number: 6984033Abstract: An ink jet printing method comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element comprising a support having thereon an image-receiving layer, the ink jet recording element containing a metal hydroxide salt, (M2+)(OH)a(Ap?)b.xH2O; wherein: M2+ is at least one metal ion having a 2+ oxidation state; A is an organic or inorganic anion; p is 1 or 2; and x is equal to or greater than 0; and a and b comprise rational numbers as follows: 0<a<2 and 0<b<2 so that the charge of M2+ is balanced; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.Type: GrantFiled: June 26, 2002Date of Patent: January 10, 2006Assignee: Eastman Kodak CompanyInventors: Joseph F. Bringley, Krishamohan Sharma, Christine Landry-Coltrain
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Patent number: 6984423Abstract: The present invention provides less expensive ink jet recording papers having high glossiness and high durability and being capable of quickly absorbing inks without causing bleeding. Accordingly, the present invention provides an ink jet recording paper having an ink-receiving layer provided on a porous resin film, wherein the porous resin film has a liquid absorption capacity measured in accordance with “Japan TAPPI No.51-87” of 0.5 ml/m2 or above and the ink-receiving layer has a surface glossiness (JIS-Z8741: measuring method at 60°) of 40% or above. It is preferable that the ink jet recording paper contains at least one member selected from among alumina, alumina hydrate and amorphous silica in the ink-receiving layer.Type: GrantFiled: September 16, 2002Date of Patent: January 10, 2006Assignee: Yupo CorporationInventors: Seiichiro Iida, Yasuo Iwasa
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Patent number: 6977100Abstract: An ink-jet recording material having on a support at least one ink-receiving layer comprising pigment and binder, which further contains in the uppermost layer of the ink-receiving layers at least one water-soluble acidic or neutral salt selected from the group consisting of aluminum salts, magnesium salts, sodium salts, potassium salts and zinc salts, and thereby acquires suitability for an ink-jet recording process using pigment ink.Type: GrantFiled: January 12, 2004Date of Patent: December 20, 2005Assignee: Nippon Paper Industries Co., Ltd.Inventors: Noboru Kondo, Teiichi Otani, Atsushi Ono
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Patent number: 6958177Abstract: The present invention is to provide a recyclable mage-recording member from which a printed material such as toner can be removed, characterized in that the printed material can be removed selectively.Type: GrantFiled: August 14, 2001Date of Patent: October 25, 2005Assignee: Minolta Co., Ltd.Inventors: Toshimitsu Fujiwara, Chiaki Yamaoka
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Patent number: 6946240Abstract: The present invention relates to an imaging element comprising a support, an imaging layer, and at least one layer comprising a clay nanocomposite wherein said nanocomposite comprises a splayant and at least one natural clay particle having an aspect ratio of from 20:1 to 500:1.Type: GrantFiled: August 4, 2003Date of Patent: September 20, 2005Assignee: Eastman Kodak CompanyInventors: YuanQiao Rao, Joseph S. Sedita
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Patent number: 6936315Abstract: An object of the present invention is to provide an ink jet recording medium for which the problem of bronzing is prevented and an image formed on the ink jet recording medium has good color representation, light-fastness and water resistance. The ink jet recording medium comprises a substrate, and an ink-receiving layer that consists of at least one layer, is provided on the substrate and has an outermost surface, wherein the degree of cationization at the outermost surface is different to, specifically less than, the degree of cationization in the ink-receiving layer other than the outermost surface.Type: GrantFiled: March 26, 2002Date of Patent: August 30, 2005Assignee: Seiko Epson CorporationInventors: Hiroyuki Onishi, Masahiro Hanmura
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Patent number: 6936316Abstract: The present invention features a multi-layer ink-jet recording medium, suitable for recording images with dye and pigmented inks and thereby providing light-emitting, reflective, glossy, metallic-looking or holographic images, comprising a substrate coated with at least two layers comprising: (a) a first transparent ink-receptive layer comprising a polymeric binder and a cross-linker and optionally having a plasticizer and pigment particles such as alumina and silica coated over the substrate, wherein the cross-linker comprises and azetidinium polymer or a salt thereof, and/or a polyfunctinal aziridine or a salt thereof or a polyfunctional oxazoline or a salt thereof; and (b) a second ink-receptive layer comprising an opaque or semi-opaque coating composition, wherein the opaque or semi-opaque coating composition is capable of accepting a printed image and thereby becoming semi transparent or clearly transparent from application of ink-jet printing ink or similar inks, while presenting a light-emitting, reType: GrantFiled: December 9, 2002Date of Patent: August 30, 2005Inventors: Asutosh Nigam, Ravi Renduchintala
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Patent number: 6933024Abstract: The use and preparation of poly(vinylpyrrolidone (PVP)-co-vinylalcohol (PVA)) as inkjet recording material, the method of making PVP/PVA copolymer comprising the steps of: hydrolyzing PVP/polyvinyl acetate (PVAc) copolymer with a mixture comprising water, at least one alcohol and at least one strong base.Type: GrantFiled: July 18, 2002Date of Patent: August 23, 2005Assignee: Hewlett-Packard Development Company, L.P.Inventor: Tienteh Chen
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Patent number: 6924011Abstract: An improved ink jet recording material is disclosed comprising a support and an ink receiving layer. This layer contains a pigment and a polymeric binder comprising a structural unit derived from a monomer represented by following formula (I): wherein, R1 is alkyl, R2 is alkyl or aryl, R3 is hydrogen, alkyl or aryl, L is a linking unit selected from CO—NH, CO—O, and CO, and R4 is hydrogen or alkyl. The material is improved for mechanical strength. The finished ink jet image shows high color densities and high gloss without the occurence of cracking.Type: GrantFiled: May 19, 2003Date of Patent: August 2, 2005Assignee: AGFA GevaertInventors: Huub Van Aert, Stefaan Lingier
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Patent number: 6921562Abstract: An ink jet recording element having a support having thereon an image-receiving layer, the image-receiving layer containing: a) from about 20 to about 65% by volume of particles; b) from about 25 to about 70% by volume of a polymeric binder; and c) up to about 10% by volume of a cross-linking agent.Type: GrantFiled: December 20, 2002Date of Patent: July 26, 2005Assignee: Eastman Kodak CompanyInventors: Kwok L. Yip, Lori J. Shaw-Klein, Andrew Clarke, Brian G. Price
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Patent number: 6919110Abstract: There are disclosed a packaged product for an ink-jet recording material which has a protective sheet for protecting the surface of the outermost ink-receptive layer of the ink-jet recording material, wherein a protective paper sheet is used as the protective sheet in which a difference between the pH of its surface which makes contact with the surface of the outermost ink-receptive layer and the pH of the surface of the ink-receptive layer is 1.5 or smaller, and a recording method and a recorded material using the ink-jet recording material.Type: GrantFiled: March 1, 2002Date of Patent: July 19, 2005Assignees: Mitsubishi Paper Mills Limited, Seiko Epson CorporationInventors: Masao Oketani, Yukio Tokunaga, Kazuhito Hori
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Patent number: 6908191Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a substrate having thereon: i) a subbing layer of a polymeric binder and a borate or a borate derivative, the borate or borate derivative being present in an amount of from up to about 3 g/m2, and the weight ratio of the polymeric binder to the borate or borate derivative is from about 0.2:1 to about 3:1; and ii) an image-receiving layer of inorganic particles and a cross-linkable polymer containing hydroxyl groups, the cross-linkable polymer being present in an amount of less than about 50 g/m2, and the weight ratio of the cross-linkable polymer to the inorganic particles is from about 5:95 to about 30:70; C) loading the printer with an inkjet ink composition; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.Type: GrantFiled: July 31, 2002Date of Patent: June 21, 2005Assignee: Eastman Kodak CompanyInventors: Yingchun Liu, Alexandra D. Bermel, Gregory E. Missell
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Patent number: 6908648Abstract: An ink-jet recording sheet containing a support having the following layers in the order: (a) a porous layer; and (b) a surface porous layer containing an organic particle A or an organic particle B, the organic particle A being insoluble in water and soluble in or swollen in a water soluble organic solvent having a SP value of 18.41 to 30.69 (MPa)1/2 and a boiling point of not less than 120° C.; the organic particle B comprising a copolymer having a specific recurring unit in an amount of not less than 5 weight % based on the total weight of the copolymer; the organic particle A and the organic particle B each having an average particle size of not more than 100 nm and a glass transition temperature of not less than 70° C., wherein the porous layer or the surface porous layer contains a compound having a polyvalent metal element.Type: GrantFiled: March 13, 2003Date of Patent: June 21, 2005Assignee: Konica CorporationInventor: Kenzo Kasahara
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Patent number: 6902780Abstract: A coating composition comprising relatively low alkali cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and cationic colloidal silica preferably having an average particle size in the range of about 1 to about 300 nanometers and which has a solids to alkali metal ratio of at least the sum of AW(?0.013SSA+9), AW being the atomic weight of alkali metal present in the colloidal silica and SSA being the specific surface area of the silica. It has been discovered that if the alkali metal, e.g., sodium, content of colloidal silica is reduced, coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports provide a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater.Type: GrantFiled: March 18, 2003Date of Patent: June 7, 2005Assignee: W. R. Grace & Co.-ConnInventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 6902779Abstract: Transfer paper suitable for in-jet printing, provided, at least on the side to be printed, with a release or barrier layer, the layer having a porosity of at most 100 ml/min, and a method for manufacturing a transfer paper and a method for printing transfer paper with an ink-jet printer with an aqueous dispersion of a sublimable ink.Type: GrantFiled: July 28, 1999Date of Patent: June 7, 2005Assignee: W. A. Sanders Papierfabriek Coldenhove B.V.Inventors: Anthonie Cornelis de Visser, Cornelis Hendricus Cornelissen, Koert Johannes Sportel