Particles (e.g., Pigment, Etc.) Present In Ink Receptive Layer Patents (Class 428/32.34)
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Patent number: 6896942Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.Type: GrantFiled: March 18, 2003Date of Patent: May 24, 2005Assignee: W. R. Grace & Co. -Conn.Inventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 6893692Abstract: An ink jet recording sheet is provided which on recording produces an image with excellent gloss, and which is capable of producing a vivid full color image with a high print density. The ink jet recording sheet comprises a support, and an ink receiving layer containing ?-alumina provided on top of this support, wherein the ink receiving layer contains at least 20% by weight of ?-alumina. The ink receiving layer may also contain ?-alumina and/or ?-alumina. Furthermore, the ink receiving layer preferably contains from 65 to 97% by weight of the alumina mixture.Type: GrantFiled: January 22, 2003Date of Patent: May 17, 2005Assignee: Tomoegawa Paper Co., Ltd.Inventors: Senichi Yoshizawa, Minoru Tsuchida
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Patent number: 6893691Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.Type: GrantFiled: March 18, 2003Date of Patent: May 17, 2005Assignee: W. R. Grace & Co.-Conn.Inventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 6890609Abstract: A substrate for ink-jet printing which is coated or impregnated with a water dissipatable nitrile polymer having a Mn of less than 25,000 comprising 5 to 70% w/w of nitrile monomers. Also processes for ink-jet printing and printed substrates.Type: GrantFiled: July 19, 2001Date of Patent: May 10, 2005Assignee: Avecia LimitedInventors: Paul Wight, Philip MacFaul, Stephen George Yeates, Tom Annable
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Patent number: 6871950Abstract: Disclosed herein is an image-transfer medium, comprising an ink vehicle-absorbing layer, which is subjected to a release treatment, and coloring material-retaining layer.Type: GrantFiled: February 11, 1999Date of Patent: March 29, 2005Assignee: Canon Kabushiki KaishaInventors: Masahiko Higuma, Yuko Sato, Yoshiyuki Shino
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Patent number: 6869658Abstract: A printable recording material and the method of using the same. The material includes a substrate and at least one functional coating on at least one side of the substrate insuring printability. The coating includes a binder and inorganic pigments in an amount of at least 50% by weight based on the dry weight of the coating. An image can be embedded in the coating.Type: GrantFiled: September 12, 2001Date of Patent: March 22, 2005Assignee: Zanders Feinpapier AGInventor: Franz Josef Becker
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Patent number: 6869647Abstract: Ink-receiving print media products having multiple capabilities including (A) minimal drying time; (B) improved smear-fastness; (C) a high level of water-fastness; (D) the ability to generate high-definition images; and (E) excellent ink compatibility. The media products have at least one ink-receiving layer on a substrate (e.g. paper pre-coated with one or more binders and/or pigments). The ink-receiving layer includes a pigment (boehmite, pseudo-boehmite, or mixtures thereof) optimally combined with a special binder blend [polyvinyl alcohol, a poly(vinyl acetate-ethylene) copolymer, and a poly(vinyl pyrrolidone-vinyl acetate) copolymer]. Also included is a special dye fixative (namely, a cationic emulsion polymer) which provides enhanced water-fastness. This fixative is of a particular type (a quaternary amine) that also allows high pigment levels to be employed (at least about 65% by weight) which further promotes the foregoing benefits.Type: GrantFiled: August 30, 2001Date of Patent: March 22, 2005Assignee: Hewlett-Packard Development Company L.P.Inventors: Loretta Ann Grezzo Page, Richard J. McManus
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Patent number: 6866902Abstract: An ink recording element is described comprising a support having thereon at least one image-receiving layer comprising polymeric particles in a polymeric binder, wherein the polymeric particle is stabilized by a hydrophobically-capped oligomeric acrylamide dispersant.Type: GrantFiled: April 9, 2002Date of Patent: March 15, 2005Assignee: Eastman Kodak CompanyInventors: Jeanne E. Kaeding, Jeffrey W. Leon, Christine J. Landry-Coltrain, Alan R. Pitt, Trevor J. Wear, Gregory E. Missell, Dennis E. Smth
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Patent number: 6866903Abstract: An ink recording element having a support having thereon a hydrophilic absorbing layer, an inner layer of a poly(vinyl alcohol-ethylene oxide) copolymer, and a polymeric overcoat layer of a cellulose ether.Type: GrantFiled: December 11, 2002Date of Patent: March 15, 2005Assignee: Eastman Kodak CompanyInventors: Charles E. Romano, Jr., Lori J. Shaw-Klein
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Patent number: 6863939Abstract: The present invention relates to an inkjet recording element comprising a microvoided layer comprising a continuous phase polyester matrix having dispersed therein crosslinked organic microbeads and non-crosslinked polymer particles that are immiscible with the polyester matrix of said microvoided layer.Type: GrantFiled: December 20, 2002Date of Patent: March 8, 2005Assignee: Eastman Kodak CompanyInventors: Thomas M. Laney, Kenneth W. Best, Jr.
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Patent number: 6861109Abstract: A recording material for back-printing contains (i) a back-printing sheet comprising a transparent substrate, an ink-absorbing layer that is provided on the transparent substrate, and a porous ink-receiving layer that is provided on the ink-absorbing layer and has filler dispersed in a binder resin, and (ii) a back-printing sheet cover film having a cover substrate, and an adhesive layer that has an adhesive resin and is formed on the cover substrate, the refractive index of the filler and the refractive index of the adhesive resin are different to one another. Specifically, the difference between the refractive index of the filler and the refractive index of the adhesive resin is at least 1.0.Type: GrantFiled: January 16, 2003Date of Patent: March 1, 2005Assignee: Sony Chemicals Corp.Inventors: Hideaki Takahashi, Jun Takahashi, Akio Ito, Yukiko Murasawa
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Patent number: 6861115Abstract: This invention pertains to an ink jet recording medium comprises a flexible substrate and a coating composition coated on at least one surface of the substrate, wherein the coating composition comprises the product formed from the contact between fumed silica particles and at least one aminoorganosiloxane. The invention also pertains to a method for the preparation of such an ink jet recording medium and to methods for the preparation of a coating composition and a dispersion useful in the preparation of such an ink jet recording medium.Type: GrantFiled: May 18, 2001Date of Patent: March 1, 2005Assignee: Cabot CorporationInventors: Michael D. Morris, Michael S. Darsillo, David J. Fluck, Jason R. Hilton, Rudiger Laufhutte, Michael A. Lucarelli
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Patent number: 6861110Abstract: An ink-jet recording sheet comprising a reflective support having thereon a porous ink absorbing layer containing a dye or a pigment, wherein a color difference ?abL defined by the following formula is not more than 7: ?abL=[(a1?a2)2+(b1?b2)2+(L1?L2)2]1/2 wherein (L1, a1, b1) and (L2, a2, b2) each are a set of coordinates (L*, a*, b*) defined in a CIELAB color space and measured on a surface of the reflective support adjacent to the ink absorbing layer and on an outermost surface of the ink absorbing layer respectively, and a2 is in a range of ?2 to 2 and b2 is in a range of ?4 to 4.Type: GrantFiled: January 27, 2003Date of Patent: March 1, 2005Assignee: Konica CorporationInventors: Keiji Obayashi, Osamu Hatano
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Patent number: 6855383Abstract: A printing medium has a base layer, an ink receptive layer coated on the base layer, and an undercoating layer formed between the base layer and the ink receptive layer. The undercoating layer has a highly glossy resin property. Accordingly, regardless of a type of a material that is used in the base layer, the printing medium always offers rapid ink absorption, a vivid color image, excellent color fixation, a high water and light resistance, and high glossiness.Type: GrantFiled: November 19, 2002Date of Patent: February 15, 2005Assignee: Samsung Electronics Co., Ltd.Inventors: Taek-yong Jung, Seung-min Ryu, Jae-hwan Kim
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Patent number: 6852422Abstract: Printable packaging paper for flexible packaging. A flexible overall print coating makes a first surface suitable for conventional printing. The print coating comprises clay, binder comprising acrylic and optionally PVOH, and microsphere shells, some optionally deformed. A barrier coating comprising PVOH, optionally acrylic, can be on the second surface. A multiple layer packaging structure can comprise such coated substrate and second and third strength layers of paper, and a flexible polyolefin barrier layer, all on the barrier coating side of the substrate, joined to the barrier coating. The flexible print coating can include titanium dioxide.Type: GrantFiled: June 17, 2002Date of Patent: February 8, 2005Assignee: Appleton Papers, Inc.Inventors: David Paul Kendall, James Richard Hillend
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Patent number: 6846524Abstract: An inkjet recording medium comprising at least one ink receiving layer on a support, wherein the ink receiving layer which is the outermost layer comprises a pigment and an aqueous polyurethane resin as principal components, the proportion of said aqueous polyurethane resin relative to said pigment in the ink receiving layer which is the outermost layer is 5-80 wt %, said aqueous polyurethane resin is formed by reaction of an active hydrogen compound and an aliphatic and/or alicyclic polyisocyanate compound, said active hydrogen compound contains 40-80 wt % of a polyether polyol compound having a number average molecular weight of 500-3000, and the minimum film-forming temperature of said aqueous polyurethane resin is ?10-50 degree C.Type: GrantFiled: March 25, 2002Date of Patent: January 25, 2005Assignee: Nippon Paper Industries Co., Ltd.Inventors: Yuji Ozawa, Toshikazu Teramasa, Masashi Seki, Tadashi Saito
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Patent number: 6846526Abstract: An ink jet recording element comprising a support having thereon a porous image-receiving layer comprising particles, a poly(vinyl alcohol) binder and a crosslinking agent, the particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 300 nm, and the crosslinking agent being present in an amount of at least about 20 weight % of the poly(vinyl alcohol) binder.Type: GrantFiled: January 26, 2001Date of Patent: January 25, 2005Assignee: Eastman Kodak CompanyInventors: Alexandra D. Bermel, Lori J. Shaw-Klein
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Patent number: 6844035Abstract: Ink-receiving print media products capable of producing high quality printed images which are light-fast, humid-fast, have low coalescence (graininess) levels, and are characterized by other beneficial attributes. The print media products have at least one ink-receiving layer supported by a substrate. The ink-receiving layer includes a binder blend designed to achieve the aforementioned goals, namely, gelatin, a poly(vinyl alcohol-polyethylene oxide) copolymer, and a poly((styrene)-(n-butyl acrylate)-(methyl methacrylate)-(2-(tert-butylamino) ethyl methacrylate)) copolymer. One or more optional pigments and/or additional binders can also be included within the ink-receiving layer. The ink-receiving layer may optionally be employed in combination with one or more additional material layers thereover or thereunder which can contain, for example, one or more pigments and/or binders.Type: GrantFiled: February 9, 2004Date of Patent: January 18, 2005Assignee: Hewlett-Packard Development Company, L.P.Inventors: Bor-Jiunn Niu, Stefan Schuttel, Meinrad Schaer
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Patent number: 6844034Abstract: Printable, coated plastic substrates are disclosed. Plastic substrates are preferably films substrates, which are coated with a printable coating composition layer which comprises: an anionic acrylic polymer; and epoxy acrylate in an amount sufficient to improve ink adhesion in said coating composition. The anionic acrylic polymer can be cross-linked to an extent sufficient to improve the resistance of said coating to isopropyl alcohol and/or hot water, using a cross-linking agent.Type: GrantFiled: April 6, 2001Date of Patent: January 18, 2005Assignee: ExxonMobil Oil CorporationInventor: Robert E. Touhsaent
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Patent number: 6841206Abstract: An improved medium for ink jet recording is disclosed. Apart from a pigment and an optional binder, the ink receiving layer contains a film-forming latex being a polymer containing repeating units derived from a particular monomer type. Preferred monomers are vinyl ester monomers most preferably derived from versatic acid. The medium is particularly suited for outdoor use.Type: GrantFiled: November 12, 2001Date of Patent: January 11, 2005Assignee: Agfa-GevaertInventors: Dirk Quintens, Hubertus Van Aert
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Patent number: 6840992Abstract: The present invention provides a coating for inkjet media, which includes at least one hydrophobic filler particle; and a binder. Another embodiment of the invention provides an inkjet media, which includes the above-described coating coated on a substrate. Another embodiment of the invention provides a method of inkjet printing, which includes inkjet printing at least one inkjet ink onto a substrate coated with the above-described coating.Type: GrantFiled: April 11, 2001Date of Patent: January 11, 2005Assignee: Degussa AGInventors: Holger Glaum, Astrid Mueller
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Patent number: 6838132Abstract: The object of the present invention is to provide an ink jet recording sheet which can give an image having an appearance looking like a picture, especially, an oil painting with maintaining sufficient print density. According to the present invention, there is provided an ink jet recording sheet comprising a support and an ink receiving layer provided on one side of the support, where the support is a fabric and the surface of the ink receiving layer has an arithmetical mean roughness of not more than 30 ?m measured in accordance with JIS B0601. The present invention further provides an ink jet recording sheet mentioned above, wherein the ink receiving layer is coated on a pigment layer coated on at least one side of the fabric or on at least one side of the fabric impregnated with a pigment component. The ink receiving layer preferably contains a gas phase method silica.Type: GrantFiled: July 27, 2000Date of Patent: January 4, 2005Assignee: Mitsubishi Paper Mills LimitedInventors: Yuji Iguchi, Katsuaki Arai
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Patent number: 6838133Abstract: A printing paper sheet is provided in which cellulose fibers are coated with solids of a substantially organic solvent-free silicone resin emulsion composition which is obtained by emulsion polymerization of a mixture comprising (a) a singly water insoluble, silanol group-bearing silicone resin and/or a radical polymerizable vinyl group-bearing alkoxysilane and (b) a radical polymerizable vinyl monomer. The paper sheet in which cellulose fibers are coated with the acrylic silicone resin is minimized in deformation or stretching and contraction upon water absorption and thus suited for printing by an ink jet printer. The quality of printed image is equal to ordinary coated paper sheets.Type: GrantFiled: January 22, 2002Date of Patent: January 4, 2005Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kazuyuki Matsumura, Akira Yamamoto
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Patent number: 6838505Abstract: A coating fluid for forming a coating on a support for use in inkjet printing comprises a liquid medium having dispersed therein (a) an inorganic oxide selected from aluminium oxide and silica, (b) a binder polymer, and (c) a polymeric crosslinking agent containing functional groups for reaction with the inorganic oxide. The components (a), (b) and (c) are preferably dispersed in an aqueous liquid and the relative amounts of inorganic oxide to polymeric crosslinking agent are from 500:1 to 15:1 preferably 250:1 to 20:1, the relative amounts of inorganic oxide to binder polymer are from 50:1 to 2:1 preferably 20:1 to 4:1 and the relative amounts of binder polymer to polymeric crosslinking agent are from 40:1 to 2:1 preferably from 20:1 to 3:1 the amounts being by weight on a dry basis.Type: GrantFiled: October 16, 2001Date of Patent: January 4, 2005Assignee: Eastman Kodak CompanyInventors: Malcom D. Purbrick, Ian M. Newington, Julie Baker
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Patent number: 6838136Abstract: The present invention relates to a coating material for producing a porous ink-absorbent coating on a substrate to be used in ink-jet printers, comprising radiation curable material and particulate material in a liquid carrier, wherein the weight ratio of particulate material to radiation curable material is greater than 1:1. Also disclosed is a process for preparing a coated substrate using such a coating material. Advantageously, the coating material of the present invention does not crack upon curing, and conveniently forms a porous coating having a glossy surface, while retaining a porous structure for ink-absorption.Type: GrantFiled: May 31, 2001Date of Patent: January 4, 2005Assignee: Imperial Chemical Industries PLCInventors: Richard Anthony Hann, Barry Pack, Alan Butters, Jeffrey Michael Howell
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Publication number: 20040265515Abstract: An ink-receiving material comprising a support coated on at least one side with an ink-receiving layer, the ink-receiving layer containing silica with a primary particle size between 7 and 40 nm and an at least partially hydrolyzed copolymer comprising vinyl ester and ethylenically unsaturated cationic monomer units hardened with boric acid or a borate, wherein said ethylenically unsaturated cationic monomer units is a quaternary ammonium salt or a quaternary phosphonium salt and said quaternary ammonium salt is an N,N-dialkenyl-N,N-dialkyl-ammonium salt; and a process for the preparation of an ink-receiving material comprising the steps of: coating a support on at least one side with a dispersion containing sub-micron silica particles, an at least partially hydrolyzed copolymer comprising vinyl ester monomer units, ethylenically unsaturated cationic monomer units and boric acid or a borate, thereby preparing an ink-receiving layer hardened with boric acid or a borate, wherein said ethylenically unsaturated cType: ApplicationFiled: June 24, 2004Publication date: December 30, 2004Applicant: AGFA-GEVAERTInventors: Stefaan Lingier, Huub Van Aert
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Publication number: 20040265514Abstract: There are disclosed an ink-jet recording material comprising a support and at least one ink-receptive layer provided on the support, wherein at least one of the ink-receptive layers contains inorganic particles having an average secondary particle size of about 500 nm or less, a resin binder having a keto group as a resin binder and a compound having two or more primary amino groups in the molecule, and a method for preparing the same.Type: ApplicationFiled: June 24, 2004Publication date: December 30, 2004Inventors: Hiroshi Sakaguchi, Yukio Tokunaga
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Publication number: 20040265516Abstract: Improved macroporous ink receptor media are disclosed. An inkjet receptive media in accordance with one embodiment of the present invention comprises a web comprising a plurality of fibers and a coating overlaying at least a portion of a plurality of the fibers. In a preferred embodiment, the coating comprises a plurality of organic particles. In a preferred embodiment, the fibers define a plurality of pores. In a preferred embodiment, the web defines a plurality of macropores. The fibers of the web may be woven or non-woven. In a preferred embodiment, the web comprises a nonwoven macroporous material.Type: ApplicationFiled: July 29, 2004Publication date: December 30, 2004Applicant: 3M Innovative Properties CompanyInventors: Mark F. Schulz, David W. Tweeten
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Publication number: 20040258858Abstract: An ink jet recording sheet is disclosed. The sheet has a porous ink receptive layer containing alumina particles or alumina hydrate particles and a hydrophilic binder which has undergone crosslinking employing ionization radiation.Type: ApplicationFiled: June 14, 2004Publication date: December 23, 2004Applicant: KONICA MINOLTA HOLDINGS, INC.Inventors: Manabu Kaneko, Yoshinori Tsubaki
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Patent number: 6830329Abstract: An ink-jet recording medium for use in an ink-jet image forming method in which a transparent film layer formed on a substrate as coating is placed on an ink-receiving layer of the recording medium, and then the side of the substrate is heated to transfer the transparent film layer on the ink-receiving layer, followed by peeling off the substrate to laminate the transparent film layer on the surface of the ink-receiving layer. The ink-receiving layer contains polyvinyl alcohol and a cross-linking agent.Type: GrantFiled: May 1, 2001Date of Patent: December 14, 2004Assignee: Canon Kabushiki KaishaInventor: Tetsu Iwata
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Publication number: 20040247803Abstract: A method for producing an ink-jet recording sheet comprising the steps of:Type: ApplicationFiled: May 28, 2004Publication date: December 9, 2004Applicant: KONICA MINOLTA HOLDINGS, INC.Inventor: Yoshinori Tsubaki
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Patent number: 6824839Abstract: An image transfer assembly (12) receives an image printed from an ink jet printer. The assembly (12) provides a device to transfer the printed image onto an image-receiving surface. The assembly (12) has a flexible substrate (16) on one side, and an upper surface (20) on the other side that is substantially permeable to ink jet printer ink and that is non-tacky prior to printing. The assembly (12) has an adhesive or polymer layer (14) in between the upper surface (20) and the flexible substrate (16). After printing with a water-based ink jet printer ink, the user may apply the assembly (12) to a substrate, such as a window or other surface, and remove the flexible substrate (16), thereby leaving the layer (14) that bears the image on the substrate. In one of several alternative embodiments, the layer (14) is divided into discrete zones that are separated from one another along boundaries.Type: GrantFiled: February 25, 1998Date of Patent: November 30, 2004Assignee: Avery Dennison CorporationInventors: Ghanshyam H. Popat, Fred Miekka, Raymond Kubit, Robert Valadez, Gustav Ray, Shiaonung Su, H. Paul Barker
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Publication number: 20040234709Abstract: An ink jet recording medium for pigment ink, comprising a support and, superimposed thereon, at least one ink receptive layer, characterized in that at least one of the at least one ink receptive layer is a layer composed of particles of a copolymer of 80° C. or higher glass transition temperature prepared from styrene and/or methyl methacrylate (A) and another copolymerizable monomer (B), the particles having a weight average particle diameter of 50 to 500 nm. This ink jet recording medium for pigment ink is excellent in yellowing resistance, ink absorptivity, color density and water resistance and has glossy surface.Type: ApplicationFiled: January 16, 2004Publication date: November 25, 2004Inventors: Tadashi Ishida, Masaya Kusumoto, Yoshihiko Tomita, Sota Ito, Hajime Mizutani, Hiroyuki Onishi, Masaya Shibatani
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Publication number: 20040228987Abstract: An ink-jet recording sheet comprising a support having thereon a porous ink receptive layer which contains inorganic microparticles and a cross-linked resin, wherein the porous ink receptive layer is prepared by a method comprising the steps of: (a) coating a liquid coating composition on the support to obtain a coated layer, the liquid coating composition containing a saponified polyvinyl acetate having a unit represented by General Formula (1) in the molecule; (b) irradiating the saponified polyvinyl acetate in the coated layer with ionization radiation to obtain the cross-linked resin; and (c) drying the coated layer.Type: ApplicationFiled: April 28, 2004Publication date: November 18, 2004Applicant: Konica Minolta Holdings, Inc.Inventor: Yoshinori Tsubaki
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Patent number: 6818266Abstract: A backprinting recording medium includes a transparent substrate, an ink-absorbing layer formed on the transparent substrate and a porous ink-permeable layer formed on the ink-absorbing layer and produced by dispersing a filler in a binder resin, wherein the binder resin constituting the ink-permeable layer has a glass transition temperature of 10° C. or higher, and a Shore D hardness at 25° C. of 40 or higher.Type: GrantFiled: December 5, 2000Date of Patent: November 16, 2004Assignee: Sony Chemicals Corp.Inventors: Jun Takahashi, Takashi Nozawa, Hideaki Takahashi
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Patent number: 6815021Abstract: The present invention provides a recording medium for ink jet printers in which superior image recording quality and color stability are exhibited. In a recording medium for ink jet printers in which an ink receiving layer contained at least pigment and binder resin is provided on a supporting material, partially saponified PVA having a degree of saponification of 85.0 to 73.0 mol % and a degree of polymerization of 300 to 1500, is contained in the ink receiving layer as a color stability improving component.Type: GrantFiled: March 30, 2000Date of Patent: November 9, 2004Assignees: Seiko Epson Corporation, Tomoegawa Paper Co., Ltd.Inventors: Takayuki Ishikawa, Nobuhiro Kubota, Minoru Tsuchida, Shigeki Asai, Takeshi Yoshimoto, Kiyoshi Iwamoto, Jun Sugiyama, Hiroyuki Onishi, Yukari Ishikawa
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Patent number: 6815018Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer; and b) a fusible, porous ink-transporting layer of a film-forming, hydrophobic binder and fusible, polymeric particles of a cellulose ester.Type: GrantFiled: September 30, 2002Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: Allan Wexler, Kevin M. O'Connor, Kurt M. Schroeder
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Patent number: 6815020Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer having: (a) particles having a mean particle size of from greater than 0.04 &mgr;m to about 5 &mgr;m; and (b) water insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.Type: GrantFiled: August 31, 2001Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Elizabeth A. Gallo, John M. Baier
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Patent number: 6811839Abstract: Disclosed herein is a recording medium comprising a base material, and at least one resin selected from a primary amine resin and a secondary amine resin and a hindered amine compound contained in the base material and/or on the surface of the base material.Type: GrantFiled: November 5, 2001Date of Patent: November 2, 2004Assignee: Canon Kabushiki KaishaInventors: Masaaki Hiro, Kenji Shinjo, Katsutoshi Misuda
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Patent number: 6808769Abstract: The present invention provides an aqueous dispersion containing at least two powder types selected from one or more metal oxide powders and/or one or more non-metal oxide powder. The present invention also provides a coating composition containing this dispersion, an inkjet recording medium containing the coating composition, and methods of making the same.Type: GrantFiled: March 24, 2003Date of Patent: October 26, 2004Assignee: Degussa AGInventors: Christoph Batz-Sohn, Thomas Scharfe, Wolfgang Lortz
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Publication number: 20040209017Abstract: A method for the preparation of a print medium that helps to reduce unwanted print artifacts such as bronzing, gloss non-uniformity, print smudging, and coalescence. Specifically, a method can comprise a step of preparing a coating composition with an acidic pH and a step of coating a media substrate with the coating composition to form an ink-receiving layer thereon. The coating composition can comprise a dispersion of inorganic particulates, a polymeric binder, and a weak base comprising a salt of an alkali metal and a weak acid. The weak base generates gas bubbles in the coating composition as a result of the acidic pH.Type: ApplicationFiled: February 6, 2004Publication date: October 21, 2004Inventors: Peter C. Zahrobsky, Matthew Thornberry, Palitha Wickramanayake, Urs Fuerholz, Linda C. Uhlir-Tsang, Eric L. Burch
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Publication number: 20040209016Abstract: An ink jet recording medium comprising a support and, on the support, at least one layer comprising cationic organic particles which have a glass transition temperature of from 70 to 130° C. and comprise (A) 0.1 to 10% by weight of a monomer having a hindered amine type functional group, (B) 0.1 to 10% by weight of a monomer having a benzotriazole type functional group and (C) 80 to 99.8% by weight of a monomer selected from styrene and acrylic monomers.Type: ApplicationFiled: January 16, 2004Publication date: October 21, 2004Inventors: Tadashi Ishida, Masaya Kusumoto, Yoshihiko Tomita, Sota Ito, Hiroyuki Onishi, Masahiro Hanmura
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Publication number: 20040197498Abstract: An ink jet recording sheet is provided that delivers a photoparity image when printed with ink jet printer. The recording sheet comprises a two-layer coating. The bottom layer comprises amorphous silica and the top layer comprises spherical colloidal silica. Both silicas are rendered cationic. The recording sheet provides fast dry time, excellent image quality and superior water resistance and handle ability.Type: ApplicationFiled: April 3, 2003Publication date: October 7, 2004Inventors: Yubai Bi, Pierre-Alain Brugger, Martin Staiger, Rolf Steiger, Karl Peternell
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Publication number: 20040197496Abstract: This invention provides a gloss-coated electrophotographic paper with superior runnability and print quality in colour and monochrome copiers and printers. The coated paper product comprises a paper substrate coated on at least one side with a pigmented coating. The pigment coating consists of a mixture of at least three different pigments and a binder. The coating may further include a lubricant. Optionally, the coating formulation may contain an optical brightening agent, a defoamer and a thickener. In addition, the gloss coated electrophotographic paper of this invention provides a superior toner adhesion in colour and monochrome electrophotographic imaging applications.Type: ApplicationFiled: August 18, 2003Publication date: October 7, 2004Inventors: Jay C. Song, Jacob P. John, Sen Yang, Timothy J. Bradford
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Publication number: 20040191433Abstract: There is disclosed an comprising a support, and at least one porous ink-receptive layer containing inorganic fine particles and polyvinyl alcohol provided as a main component of a binder on the support, wherein at least one of said ink-receptive layers contains a polymer emulsion containing a polymer compound which shows a hydrophilic property at a temperature region of a predetermined temperature, which is a thermosensitive temperature, or less and shows a hydrophobic property at a temperature region higher than the thermosensitive temperature in an amount of 1 to 25% by weight based on the amount of the polyvinyl alcohol in terms of a solid content.Type: ApplicationFiled: March 25, 2004Publication date: September 30, 2004Inventors: Hiroshi Sakaguchi, Yukihiro Suzuki
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Patent number: 6790491Abstract: The invention provides an image receptor medium which comprises a biaxially oriented, melt-processed image receptive film comprising a) an immiscible blend of at least one semicrystalline polymer component and at least one ink absorptive polymer component and b) at least one inorganic filler. The image receptor medium may further comprise one or more additional layers such as support or adhesive layers.Type: GrantFiled: June 21, 2002Date of Patent: September 14, 2004Assignee: 3M Innovative Properties CompanyInventors: John M. Sebastian, Robert D. Taylor, Mary R. Boone, Robert S. Kody, Stephen P. Polski
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Patent number: 6783229Abstract: Provided is a recording medium provided with an ink-receiving layer on at least one surface of a substrate, wherein said ink-receiving layer is composed of a porous layer comprising pigment particles and mutually fused thermoplastic resin particles.Type: GrantFiled: September 21, 1998Date of Patent: August 31, 2004Assignee: Canon Kabushiki KaishaInventors: Tadayoshi Inamoto, Nobuyuki Hosoi, Kenji Shinjo
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Patent number: 6779885Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the porous polymeric particles being prepared in the presence of an anionic or ationic dispersant, and the image-receiving layer containing a surfactant having a charge opposite to that of the dispersant used to make the porous polymeric particles, the surfactant being present in an amount from about 0.04 parts to about 0.30 parts by weight of the dispersant; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.Type: GrantFiled: December 4, 2001Date of Patent: August 24, 2004Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Jeanne E. Kaeding, Dennis E. Smith, Paul B. Merkel
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Patent number: 6780478Abstract: A recording sheet for ink jet printing described, which consists of a support having coated onto said support at least one ink receiving layer consisting of one or more binders and a mixture of different water insoluble, inorganic oxides of the elements aluminium or silicium, oxide/hydroxides of the element aluminium or aluminium silicates, wherein at least one of said oxides, oxides/hydroxides or silicates has a pore volume of ≧40 ml/100 g and is present in an amount of at least 8 weight percent relative to the total amount of all the water insoluble, inorganic oxides, oxide/hydroxides or silicates and that the primary particles of the mixture component with the largest volume have an equivalent sphere diameter of less than 20 nm and the primary particles of the mixture component with the smallest volume have an equivalent sphere diameter that is at least {fraction (1/20)} of the equivalent sphere diameter of the primary particles of the mixture component with the largest volume.Type: GrantFiled: May 29, 2001Date of Patent: August 24, 2004Assignee: Ilford Imaging Switzerland GmbHInventors: Rolf Steiger, Pierre-Alain Brugger
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Patent number: 6777039Abstract: An inkjet recording sheet comprising a support and, on a surface of the support, a colorant-receiving layer formed by applying a first coating liquid, adding a second coating liquid, after application of the first coating liquid and before the same shows a decreasing rate of drying, and thereafter hardening and drying the coat layer to form a porous structure. The first coating liquid has a pH value of 5 or lower, and is obtained by adding a solution which includes polyvinyl alcohol, a nonionic surfactant and/or amphoteric surfactant and a high boiling point organic solvent, to a dispersion including a cationic resin and vapor-phase-process silica having a specific surface area of at least 200 m2/g as measured by the BET method. The second coating liquid has a pH value of 8.5 or higher and includes a cross-linking agent capable of cross-linking the polyvinyl alcohol, an organic mordant and a nonionic surfactant.Type: GrantFiled: April 19, 2002Date of Patent: August 17, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazuyuki Koike, Takashi Kobayashi, Katsuyoshi Suzuki, Ryoichi Nakano