Particles (e.g., Pigment, Etc.) Present In Ink Receptive Layer Patents (Class 428/32.34)
  • Patent number: 6896942
    Abstract: A coating composition comprising cationic colloidal silicas and ink jet recording sheets prepared from such coatings is described. The coating comprises binder and polydispersed cationic colloidal silica. The cationic colloidal silica preferably has an average particle size in the range of about 1 to about 300 nanometers. It has been discovered that if a cationic polydispersed colloidal silica is employed in a glossy coating formulation, the coating provides a specular gloss of at least 30 at 60° C., even at a relatively high silica solids to binder solids ratio of 1:1 or greater, but also a coating having good to excellent printability characteristics.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 24, 2005
    Assignee: W. R. Grace & Co. -Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6893692
    Abstract: An ink jet recording sheet is provided which on recording produces an image with excellent gloss, and which is capable of producing a vivid full color image with a high print density. The ink jet recording sheet comprises a support, and an ink receiving layer containing ?-alumina provided on top of this support, wherein the ink receiving layer contains at least 20% by weight of ?-alumina. The ink receiving layer may also contain ?-alumina and/or ?-alumina. Furthermore, the ink receiving layer preferably contains from 65 to 97% by weight of the alumina mixture.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: May 17, 2005
    Assignee: Tomoegawa Paper Co., Ltd.
    Inventors: Senichi Yoshizawa, Minoru Tsuchida
  • Patent number: 6893691
    Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.
    Type: Grant
    Filed: March 18, 2003
    Date of Patent: May 17, 2005
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Daniel Ray Fruge, Demetrius Michos
  • Patent number: 6890609
    Abstract: A substrate for ink-jet printing which is coated or impregnated with a water dissipatable nitrile polymer having a Mn of less than 25,000 comprising 5 to 70% w/w of nitrile monomers. Also processes for ink-jet printing and printed substrates.
    Type: Grant
    Filed: July 19, 2001
    Date of Patent: May 10, 2005
    Assignee: Avecia Limited
    Inventors: Paul Wight, Philip MacFaul, Stephen George Yeates, Tom Annable
  • Patent number: 6871950
    Abstract: Disclosed herein is an image-transfer medium, comprising an ink vehicle-absorbing layer, which is subjected to a release treatment, and coloring material-retaining layer.
    Type: Grant
    Filed: February 11, 1999
    Date of Patent: March 29, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masahiko Higuma, Yuko Sato, Yoshiyuki Shino
  • Patent number: 6869658
    Abstract: A printable recording material and the method of using the same. The material includes a substrate and at least one functional coating on at least one side of the substrate insuring printability. The coating includes a binder and inorganic pigments in an amount of at least 50% by weight based on the dry weight of the coating. An image can be embedded in the coating.
    Type: Grant
    Filed: September 12, 2001
    Date of Patent: March 22, 2005
    Assignee: Zanders Feinpapier AG
    Inventor: Franz Josef Becker
  • Patent number: 6869647
    Abstract: Ink-receiving print media products having multiple capabilities including (A) minimal drying time; (B) improved smear-fastness; (C) a high level of water-fastness; (D) the ability to generate high-definition images; and (E) excellent ink compatibility. The media products have at least one ink-receiving layer on a substrate (e.g. paper pre-coated with one or more binders and/or pigments). The ink-receiving layer includes a pigment (boehmite, pseudo-boehmite, or mixtures thereof) optimally combined with a special binder blend [polyvinyl alcohol, a poly(vinyl acetate-ethylene) copolymer, and a poly(vinyl pyrrolidone-vinyl acetate) copolymer]. Also included is a special dye fixative (namely, a cationic emulsion polymer) which provides enhanced water-fastness. This fixative is of a particular type (a quaternary amine) that also allows high pigment levels to be employed (at least about 65% by weight) which further promotes the foregoing benefits.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: March 22, 2005
    Assignee: Hewlett-Packard Development Company L.P.
    Inventors: Loretta Ann Grezzo Page, Richard J. McManus
  • Patent number: 6866902
    Abstract: An ink recording element is described comprising a support having thereon at least one image-receiving layer comprising polymeric particles in a polymeric binder, wherein the polymeric particle is stabilized by a hydrophobically-capped oligomeric acrylamide dispersant.
    Type: Grant
    Filed: April 9, 2002
    Date of Patent: March 15, 2005
    Assignee: Eastman Kodak Company
    Inventors: Jeanne E. Kaeding, Jeffrey W. Leon, Christine J. Landry-Coltrain, Alan R. Pitt, Trevor J. Wear, Gregory E. Missell, Dennis E. Smth
  • Patent number: 6866903
    Abstract: An ink recording element having a support having thereon a hydrophilic absorbing layer, an inner layer of a poly(vinyl alcohol-ethylene oxide) copolymer, and a polymeric overcoat layer of a cellulose ether.
    Type: Grant
    Filed: December 11, 2002
    Date of Patent: March 15, 2005
    Assignee: Eastman Kodak Company
    Inventors: Charles E. Romano, Jr., Lori J. Shaw-Klein
  • Patent number: 6863939
    Abstract: The present invention relates to an inkjet recording element comprising a microvoided layer comprising a continuous phase polyester matrix having dispersed therein crosslinked organic microbeads and non-crosslinked polymer particles that are immiscible with the polyester matrix of said microvoided layer.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: March 8, 2005
    Assignee: Eastman Kodak Company
    Inventors: Thomas M. Laney, Kenneth W. Best, Jr.
  • Patent number: 6861109
    Abstract: A recording material for back-printing contains (i) a back-printing sheet comprising a transparent substrate, an ink-absorbing layer that is provided on the transparent substrate, and a porous ink-receiving layer that is provided on the ink-absorbing layer and has filler dispersed in a binder resin, and (ii) a back-printing sheet cover film having a cover substrate, and an adhesive layer that has an adhesive resin and is formed on the cover substrate, the refractive index of the filler and the refractive index of the adhesive resin are different to one another. Specifically, the difference between the refractive index of the filler and the refractive index of the adhesive resin is at least 1.0.
    Type: Grant
    Filed: January 16, 2003
    Date of Patent: March 1, 2005
    Assignee: Sony Chemicals Corp.
    Inventors: Hideaki Takahashi, Jun Takahashi, Akio Ito, Yukiko Murasawa
  • Patent number: 6861115
    Abstract: This invention pertains to an ink jet recording medium comprises a flexible substrate and a coating composition coated on at least one surface of the substrate, wherein the coating composition comprises the product formed from the contact between fumed silica particles and at least one aminoorganosiloxane. The invention also pertains to a method for the preparation of such an ink jet recording medium and to methods for the preparation of a coating composition and a dispersion useful in the preparation of such an ink jet recording medium.
    Type: Grant
    Filed: May 18, 2001
    Date of Patent: March 1, 2005
    Assignee: Cabot Corporation
    Inventors: Michael D. Morris, Michael S. Darsillo, David J. Fluck, Jason R. Hilton, Rudiger Laufhutte, Michael A. Lucarelli
  • Patent number: 6861110
    Abstract: An ink-jet recording sheet comprising a reflective support having thereon a porous ink absorbing layer containing a dye or a pigment, wherein a color difference ?abL defined by the following formula is not more than 7: ?abL=[(a1?a2)2+(b1?b2)2+(L1?L2)2]1/2 wherein (L1, a1, b1) and (L2, a2, b2) each are a set of coordinates (L*, a*, b*) defined in a CIELAB color space and measured on a surface of the reflective support adjacent to the ink absorbing layer and on an outermost surface of the ink absorbing layer respectively, and a2 is in a range of ?2 to 2 and b2 is in a range of ?4 to 4.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: March 1, 2005
    Assignee: Konica Corporation
    Inventors: Keiji Obayashi, Osamu Hatano
  • Patent number: 6855383
    Abstract: A printing medium has a base layer, an ink receptive layer coated on the base layer, and an undercoating layer formed between the base layer and the ink receptive layer. The undercoating layer has a highly glossy resin property. Accordingly, regardless of a type of a material that is used in the base layer, the printing medium always offers rapid ink absorption, a vivid color image, excellent color fixation, a high water and light resistance, and high glossiness.
    Type: Grant
    Filed: November 19, 2002
    Date of Patent: February 15, 2005
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Taek-yong Jung, Seung-min Ryu, Jae-hwan Kim
  • Patent number: 6852422
    Abstract: Printable packaging paper for flexible packaging. A flexible overall print coating makes a first surface suitable for conventional printing. The print coating comprises clay, binder comprising acrylic and optionally PVOH, and microsphere shells, some optionally deformed. A barrier coating comprising PVOH, optionally acrylic, can be on the second surface. A multiple layer packaging structure can comprise such coated substrate and second and third strength layers of paper, and a flexible polyolefin barrier layer, all on the barrier coating side of the substrate, joined to the barrier coating. The flexible print coating can include titanium dioxide.
    Type: Grant
    Filed: June 17, 2002
    Date of Patent: February 8, 2005
    Assignee: Appleton Papers, Inc.
    Inventors: David Paul Kendall, James Richard Hillend
  • Patent number: 6846524
    Abstract: An inkjet recording medium comprising at least one ink receiving layer on a support, wherein the ink receiving layer which is the outermost layer comprises a pigment and an aqueous polyurethane resin as principal components, the proportion of said aqueous polyurethane resin relative to said pigment in the ink receiving layer which is the outermost layer is 5-80 wt %, said aqueous polyurethane resin is formed by reaction of an active hydrogen compound and an aliphatic and/or alicyclic polyisocyanate compound, said active hydrogen compound contains 40-80 wt % of a polyether polyol compound having a number average molecular weight of 500-3000, and the minimum film-forming temperature of said aqueous polyurethane resin is ?10-50 degree C.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: January 25, 2005
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yuji Ozawa, Toshikazu Teramasa, Masashi Seki, Tadashi Saito
  • Patent number: 6846526
    Abstract: An ink jet recording element comprising a support having thereon a porous image-receiving layer comprising particles, a poly(vinyl alcohol) binder and a crosslinking agent, the particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 300 nm, and the crosslinking agent being present in an amount of at least about 20 weight % of the poly(vinyl alcohol) binder.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: January 25, 2005
    Assignee: Eastman Kodak Company
    Inventors: Alexandra D. Bermel, Lori J. Shaw-Klein
  • Patent number: 6844035
    Abstract: Ink-receiving print media products capable of producing high quality printed images which are light-fast, humid-fast, have low coalescence (graininess) levels, and are characterized by other beneficial attributes. The print media products have at least one ink-receiving layer supported by a substrate. The ink-receiving layer includes a binder blend designed to achieve the aforementioned goals, namely, gelatin, a poly(vinyl alcohol-polyethylene oxide) copolymer, and a poly((styrene)-(n-butyl acrylate)-(methyl methacrylate)-(2-(tert-butylamino) ethyl methacrylate)) copolymer. One or more optional pigments and/or additional binders can also be included within the ink-receiving layer. The ink-receiving layer may optionally be employed in combination with one or more additional material layers thereover or thereunder which can contain, for example, one or more pigments and/or binders.
    Type: Grant
    Filed: February 9, 2004
    Date of Patent: January 18, 2005
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Bor-Jiunn Niu, Stefan Schuttel, Meinrad Schaer
  • Patent number: 6844034
    Abstract: Printable, coated plastic substrates are disclosed. Plastic substrates are preferably films substrates, which are coated with a printable coating composition layer which comprises: an anionic acrylic polymer; and epoxy acrylate in an amount sufficient to improve ink adhesion in said coating composition. The anionic acrylic polymer can be cross-linked to an extent sufficient to improve the resistance of said coating to isopropyl alcohol and/or hot water, using a cross-linking agent.
    Type: Grant
    Filed: April 6, 2001
    Date of Patent: January 18, 2005
    Assignee: ExxonMobil Oil Corporation
    Inventor: Robert E. Touhsaent
  • Patent number: 6841206
    Abstract: An improved medium for ink jet recording is disclosed. Apart from a pigment and an optional binder, the ink receiving layer contains a film-forming latex being a polymer containing repeating units derived from a particular monomer type. Preferred monomers are vinyl ester monomers most preferably derived from versatic acid. The medium is particularly suited for outdoor use.
    Type: Grant
    Filed: November 12, 2001
    Date of Patent: January 11, 2005
    Assignee: Agfa-Gevaert
    Inventors: Dirk Quintens, Hubertus Van Aert
  • Patent number: 6840992
    Abstract: The present invention provides a coating for inkjet media, which includes at least one hydrophobic filler particle; and a binder. Another embodiment of the invention provides an inkjet media, which includes the above-described coating coated on a substrate. Another embodiment of the invention provides a method of inkjet printing, which includes inkjet printing at least one inkjet ink onto a substrate coated with the above-described coating.
    Type: Grant
    Filed: April 11, 2001
    Date of Patent: January 11, 2005
    Assignee: Degussa AG
    Inventors: Holger Glaum, Astrid Mueller
  • Patent number: 6838132
    Abstract: The object of the present invention is to provide an ink jet recording sheet which can give an image having an appearance looking like a picture, especially, an oil painting with maintaining sufficient print density. According to the present invention, there is provided an ink jet recording sheet comprising a support and an ink receiving layer provided on one side of the support, where the support is a fabric and the surface of the ink receiving layer has an arithmetical mean roughness of not more than 30 ?m measured in accordance with JIS B0601. The present invention further provides an ink jet recording sheet mentioned above, wherein the ink receiving layer is coated on a pigment layer coated on at least one side of the fabric or on at least one side of the fabric impregnated with a pigment component. The ink receiving layer preferably contains a gas phase method silica.
    Type: Grant
    Filed: July 27, 2000
    Date of Patent: January 4, 2005
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Yuji Iguchi, Katsuaki Arai
  • Patent number: 6838133
    Abstract: A printing paper sheet is provided in which cellulose fibers are coated with solids of a substantially organic solvent-free silicone resin emulsion composition which is obtained by emulsion polymerization of a mixture comprising (a) a singly water insoluble, silanol group-bearing silicone resin and/or a radical polymerizable vinyl group-bearing alkoxysilane and (b) a radical polymerizable vinyl monomer. The paper sheet in which cellulose fibers are coated with the acrylic silicone resin is minimized in deformation or stretching and contraction upon water absorption and thus suited for printing by an ink jet printer. The quality of printed image is equal to ordinary coated paper sheets.
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: January 4, 2005
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Kazuyuki Matsumura, Akira Yamamoto
  • Patent number: 6838505
    Abstract: A coating fluid for forming a coating on a support for use in inkjet printing comprises a liquid medium having dispersed therein (a) an inorganic oxide selected from aluminium oxide and silica, (b) a binder polymer, and (c) a polymeric crosslinking agent containing functional groups for reaction with the inorganic oxide. The components (a), (b) and (c) are preferably dispersed in an aqueous liquid and the relative amounts of inorganic oxide to polymeric crosslinking agent are from 500:1 to 15:1 preferably 250:1 to 20:1, the relative amounts of inorganic oxide to binder polymer are from 50:1 to 2:1 preferably 20:1 to 4:1 and the relative amounts of binder polymer to polymeric crosslinking agent are from 40:1 to 2:1 preferably from 20:1 to 3:1 the amounts being by weight on a dry basis.
    Type: Grant
    Filed: October 16, 2001
    Date of Patent: January 4, 2005
    Assignee: Eastman Kodak Company
    Inventors: Malcom D. Purbrick, Ian M. Newington, Julie Baker
  • Patent number: 6838136
    Abstract: The present invention relates to a coating material for producing a porous ink-absorbent coating on a substrate to be used in ink-jet printers, comprising radiation curable material and particulate material in a liquid carrier, wherein the weight ratio of particulate material to radiation curable material is greater than 1:1. Also disclosed is a process for preparing a coated substrate using such a coating material. Advantageously, the coating material of the present invention does not crack upon curing, and conveniently forms a porous coating having a glossy surface, while retaining a porous structure for ink-absorption.
    Type: Grant
    Filed: May 31, 2001
    Date of Patent: January 4, 2005
    Assignee: Imperial Chemical Industries PLC
    Inventors: Richard Anthony Hann, Barry Pack, Alan Butters, Jeffrey Michael Howell
  • Publication number: 20040265515
    Abstract: An ink-receiving material comprising a support coated on at least one side with an ink-receiving layer, the ink-receiving layer containing silica with a primary particle size between 7 and 40 nm and an at least partially hydrolyzed copolymer comprising vinyl ester and ethylenically unsaturated cationic monomer units hardened with boric acid or a borate, wherein said ethylenically unsaturated cationic monomer units is a quaternary ammonium salt or a quaternary phosphonium salt and said quaternary ammonium salt is an N,N-dialkenyl-N,N-dialkyl-ammonium salt; and a process for the preparation of an ink-receiving material comprising the steps of: coating a support on at least one side with a dispersion containing sub-micron silica particles, an at least partially hydrolyzed copolymer comprising vinyl ester monomer units, ethylenically unsaturated cationic monomer units and boric acid or a borate, thereby preparing an ink-receiving layer hardened with boric acid or a borate, wherein said ethylenically unsaturated c
    Type: Application
    Filed: June 24, 2004
    Publication date: December 30, 2004
    Applicant: AGFA-GEVAERT
    Inventors: Stefaan Lingier, Huub Van Aert
  • Publication number: 20040265514
    Abstract: There are disclosed an ink-jet recording material comprising a support and at least one ink-receptive layer provided on the support, wherein at least one of the ink-receptive layers contains inorganic particles having an average secondary particle size of about 500 nm or less, a resin binder having a keto group as a resin binder and a compound having two or more primary amino groups in the molecule, and a method for preparing the same.
    Type: Application
    Filed: June 24, 2004
    Publication date: December 30, 2004
    Inventors: Hiroshi Sakaguchi, Yukio Tokunaga
  • Publication number: 20040265516
    Abstract: Improved macroporous ink receptor media are disclosed. An inkjet receptive media in accordance with one embodiment of the present invention comprises a web comprising a plurality of fibers and a coating overlaying at least a portion of a plurality of the fibers. In a preferred embodiment, the coating comprises a plurality of organic particles. In a preferred embodiment, the fibers define a plurality of pores. In a preferred embodiment, the web defines a plurality of macropores. The fibers of the web may be woven or non-woven. In a preferred embodiment, the web comprises a nonwoven macroporous material.
    Type: Application
    Filed: July 29, 2004
    Publication date: December 30, 2004
    Applicant: 3M Innovative Properties Company
    Inventors: Mark F. Schulz, David W. Tweeten
  • Publication number: 20040258858
    Abstract: An ink jet recording sheet is disclosed. The sheet has a porous ink receptive layer containing alumina particles or alumina hydrate particles and a hydrophilic binder which has undergone crosslinking employing ionization radiation.
    Type: Application
    Filed: June 14, 2004
    Publication date: December 23, 2004
    Applicant: KONICA MINOLTA HOLDINGS, INC.
    Inventors: Manabu Kaneko, Yoshinori Tsubaki
  • Patent number: 6830329
    Abstract: An ink-jet recording medium for use in an ink-jet image forming method in which a transparent film layer formed on a substrate as coating is placed on an ink-receiving layer of the recording medium, and then the side of the substrate is heated to transfer the transparent film layer on the ink-receiving layer, followed by peeling off the substrate to laminate the transparent film layer on the surface of the ink-receiving layer. The ink-receiving layer contains polyvinyl alcohol and a cross-linking agent.
    Type: Grant
    Filed: May 1, 2001
    Date of Patent: December 14, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventor: Tetsu Iwata
  • Publication number: 20040247803
    Abstract: A method for producing an ink-jet recording sheet comprising the steps of:
    Type: Application
    Filed: May 28, 2004
    Publication date: December 9, 2004
    Applicant: KONICA MINOLTA HOLDINGS, INC.
    Inventor: Yoshinori Tsubaki
  • Patent number: 6824839
    Abstract: An image transfer assembly (12) receives an image printed from an ink jet printer. The assembly (12) provides a device to transfer the printed image onto an image-receiving surface. The assembly (12) has a flexible substrate (16) on one side, and an upper surface (20) on the other side that is substantially permeable to ink jet printer ink and that is non-tacky prior to printing. The assembly (12) has an adhesive or polymer layer (14) in between the upper surface (20) and the flexible substrate (16). After printing with a water-based ink jet printer ink, the user may apply the assembly (12) to a substrate, such as a window or other surface, and remove the flexible substrate (16), thereby leaving the layer (14) that bears the image on the substrate. In one of several alternative embodiments, the layer (14) is divided into discrete zones that are separated from one another along boundaries.
    Type: Grant
    Filed: February 25, 1998
    Date of Patent: November 30, 2004
    Assignee: Avery Dennison Corporation
    Inventors: Ghanshyam H. Popat, Fred Miekka, Raymond Kubit, Robert Valadez, Gustav Ray, Shiaonung Su, H. Paul Barker
  • Publication number: 20040234709
    Abstract: An ink jet recording medium for pigment ink, comprising a support and, superimposed thereon, at least one ink receptive layer, characterized in that at least one of the at least one ink receptive layer is a layer composed of particles of a copolymer of 80° C. or higher glass transition temperature prepared from styrene and/or methyl methacrylate (A) and another copolymerizable monomer (B), the particles having a weight average particle diameter of 50 to 500 nm. This ink jet recording medium for pigment ink is excellent in yellowing resistance, ink absorptivity, color density and water resistance and has glossy surface.
    Type: Application
    Filed: January 16, 2004
    Publication date: November 25, 2004
    Inventors: Tadashi Ishida, Masaya Kusumoto, Yoshihiko Tomita, Sota Ito, Hajime Mizutani, Hiroyuki Onishi, Masaya Shibatani
  • Publication number: 20040228987
    Abstract: An ink-jet recording sheet comprising a support having thereon a porous ink receptive layer which contains inorganic microparticles and a cross-linked resin, wherein the porous ink receptive layer is prepared by a method comprising the steps of: (a) coating a liquid coating composition on the support to obtain a coated layer, the liquid coating composition containing a saponified polyvinyl acetate having a unit represented by General Formula (1) in the molecule; (b) irradiating the saponified polyvinyl acetate in the coated layer with ionization radiation to obtain the cross-linked resin; and (c) drying the coated layer.
    Type: Application
    Filed: April 28, 2004
    Publication date: November 18, 2004
    Applicant: Konica Minolta Holdings, Inc.
    Inventor: Yoshinori Tsubaki
  • Patent number: 6818266
    Abstract: A backprinting recording medium includes a transparent substrate, an ink-absorbing layer formed on the transparent substrate and a porous ink-permeable layer formed on the ink-absorbing layer and produced by dispersing a filler in a binder resin, wherein the binder resin constituting the ink-permeable layer has a glass transition temperature of 10° C. or higher, and a Shore D hardness at 25° C. of 40 or higher.
    Type: Grant
    Filed: December 5, 2000
    Date of Patent: November 16, 2004
    Assignee: Sony Chemicals Corp.
    Inventors: Jun Takahashi, Takashi Nozawa, Hideaki Takahashi
  • Patent number: 6815021
    Abstract: The present invention provides a recording medium for ink jet printers in which superior image recording quality and color stability are exhibited. In a recording medium for ink jet printers in which an ink receiving layer contained at least pigment and binder resin is provided on a supporting material, partially saponified PVA having a degree of saponification of 85.0 to 73.0 mol % and a degree of polymerization of 300 to 1500, is contained in the ink receiving layer as a color stability improving component.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: November 9, 2004
    Assignees: Seiko Epson Corporation, Tomoegawa Paper Co., Ltd.
    Inventors: Takayuki Ishikawa, Nobuhiro Kubota, Minoru Tsuchida, Shigeki Asai, Takeshi Yoshimoto, Kiyoshi Iwamoto, Jun Sugiyama, Hiroyuki Onishi, Yukari Ishikawa
  • Patent number: 6815018
    Abstract: An ink jet recording element having a support having thereon in order: a) at least one porous, ink-retaining layer; and b) a fusible, porous ink-transporting layer of a film-forming, hydrophobic binder and fusible, polymeric particles of a cellulose ester.
    Type: Grant
    Filed: September 30, 2002
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: Allan Wexler, Kevin M. O'Connor, Kurt M. Schroeder
  • Patent number: 6815020
    Abstract: An ink jet recording element having a support having thereon a porous image-receiving layer having: (a) particles having a mean particle size of from greater than 0.04 &mgr;m to about 5 &mgr;m; and (b) water insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: November 9, 2004
    Assignee: Eastman Kodak Company
    Inventors: Sridhar Sadasivan, Elizabeth A. Gallo, John M. Baier
  • Patent number: 6811839
    Abstract: Disclosed herein is a recording medium comprising a base material, and at least one resin selected from a primary amine resin and a secondary amine resin and a hindered amine compound contained in the base material and/or on the surface of the base material.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: November 2, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Masaaki Hiro, Kenji Shinjo, Katsutoshi Misuda
  • Patent number: 6808769
    Abstract: The present invention provides an aqueous dispersion containing at least two powder types selected from one or more metal oxide powders and/or one or more non-metal oxide powder. The present invention also provides a coating composition containing this dispersion, an inkjet recording medium containing the coating composition, and methods of making the same.
    Type: Grant
    Filed: March 24, 2003
    Date of Patent: October 26, 2004
    Assignee: Degussa AG
    Inventors: Christoph Batz-Sohn, Thomas Scharfe, Wolfgang Lortz
  • Publication number: 20040209017
    Abstract: A method for the preparation of a print medium that helps to reduce unwanted print artifacts such as bronzing, gloss non-uniformity, print smudging, and coalescence. Specifically, a method can comprise a step of preparing a coating composition with an acidic pH and a step of coating a media substrate with the coating composition to form an ink-receiving layer thereon. The coating composition can comprise a dispersion of inorganic particulates, a polymeric binder, and a weak base comprising a salt of an alkali metal and a weak acid. The weak base generates gas bubbles in the coating composition as a result of the acidic pH.
    Type: Application
    Filed: February 6, 2004
    Publication date: October 21, 2004
    Inventors: Peter C. Zahrobsky, Matthew Thornberry, Palitha Wickramanayake, Urs Fuerholz, Linda C. Uhlir-Tsang, Eric L. Burch
  • Publication number: 20040209016
    Abstract: An ink jet recording medium comprising a support and, on the support, at least one layer comprising cationic organic particles which have a glass transition temperature of from 70 to 130° C. and comprise (A) 0.1 to 10% by weight of a monomer having a hindered amine type functional group, (B) 0.1 to 10% by weight of a monomer having a benzotriazole type functional group and (C) 80 to 99.8% by weight of a monomer selected from styrene and acrylic monomers.
    Type: Application
    Filed: January 16, 2004
    Publication date: October 21, 2004
    Inventors: Tadashi Ishida, Masaya Kusumoto, Yoshihiko Tomita, Sota Ito, Hiroyuki Onishi, Masahiro Hanmura
  • Publication number: 20040197498
    Abstract: An ink jet recording sheet is provided that delivers a photoparity image when printed with ink jet printer. The recording sheet comprises a two-layer coating. The bottom layer comprises amorphous silica and the top layer comprises spherical colloidal silica. Both silicas are rendered cationic. The recording sheet provides fast dry time, excellent image quality and superior water resistance and handle ability.
    Type: Application
    Filed: April 3, 2003
    Publication date: October 7, 2004
    Inventors: Yubai Bi, Pierre-Alain Brugger, Martin Staiger, Rolf Steiger, Karl Peternell
  • Publication number: 20040197496
    Abstract: This invention provides a gloss-coated electrophotographic paper with superior runnability and print quality in colour and monochrome copiers and printers. The coated paper product comprises a paper substrate coated on at least one side with a pigmented coating. The pigment coating consists of a mixture of at least three different pigments and a binder. The coating may further include a lubricant. Optionally, the coating formulation may contain an optical brightening agent, a defoamer and a thickener. In addition, the gloss coated electrophotographic paper of this invention provides a superior toner adhesion in colour and monochrome electrophotographic imaging applications.
    Type: Application
    Filed: August 18, 2003
    Publication date: October 7, 2004
    Inventors: Jay C. Song, Jacob P. John, Sen Yang, Timothy J. Bradford
  • Publication number: 20040191433
    Abstract: There is disclosed an comprising a support, and at least one porous ink-receptive layer containing inorganic fine particles and polyvinyl alcohol provided as a main component of a binder on the support, wherein at least one of said ink-receptive layers contains a polymer emulsion containing a polymer compound which shows a hydrophilic property at a temperature region of a predetermined temperature, which is a thermosensitive temperature, or less and shows a hydrophobic property at a temperature region higher than the thermosensitive temperature in an amount of 1 to 25% by weight based on the amount of the polyvinyl alcohol in terms of a solid content.
    Type: Application
    Filed: March 25, 2004
    Publication date: September 30, 2004
    Inventors: Hiroshi Sakaguchi, Yukihiro Suzuki
  • Patent number: 6790491
    Abstract: The invention provides an image receptor medium which comprises a biaxially oriented, melt-processed image receptive film comprising a) an immiscible blend of at least one semicrystalline polymer component and at least one ink absorptive polymer component and b) at least one inorganic filler. The image receptor medium may further comprise one or more additional layers such as support or adhesive layers.
    Type: Grant
    Filed: June 21, 2002
    Date of Patent: September 14, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: John M. Sebastian, Robert D. Taylor, Mary R. Boone, Robert S. Kody, Stephen P. Polski
  • Patent number: 6783229
    Abstract: Provided is a recording medium provided with an ink-receiving layer on at least one surface of a substrate, wherein said ink-receiving layer is composed of a porous layer comprising pigment particles and mutually fused thermoplastic resin particles.
    Type: Grant
    Filed: September 21, 1998
    Date of Patent: August 31, 2004
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tadayoshi Inamoto, Nobuyuki Hosoi, Kenji Shinjo
  • Patent number: 6779885
    Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the porous polymeric particles being prepared in the presence of an anionic or ationic dispersant, and the image-receiving layer containing a surfactant having a charge opposite to that of the dispersant used to make the porous polymeric particles, the surfactant being present in an amount from about 0.04 parts to about 0.30 parts by weight of the dispersant; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: August 24, 2004
    Assignee: Eastman Kodak Company
    Inventors: Gregory E. Missell, Jeanne E. Kaeding, Dennis E. Smith, Paul B. Merkel
  • Patent number: 6780478
    Abstract: A recording sheet for ink jet printing described, which consists of a support having coated onto said support at least one ink receiving layer consisting of one or more binders and a mixture of different water insoluble, inorganic oxides of the elements aluminium or silicium, oxide/hydroxides of the element aluminium or aluminium silicates, wherein at least one of said oxides, oxides/hydroxides or silicates has a pore volume of ≧40 ml/100 g and is present in an amount of at least 8 weight percent relative to the total amount of all the water insoluble, inorganic oxides, oxide/hydroxides or silicates and that the primary particles of the mixture component with the largest volume have an equivalent sphere diameter of less than 20 nm and the primary particles of the mixture component with the smallest volume have an equivalent sphere diameter that is at least {fraction (1/20)} of the equivalent sphere diameter of the primary particles of the mixture component with the largest volume.
    Type: Grant
    Filed: May 29, 2001
    Date of Patent: August 24, 2004
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Rolf Steiger, Pierre-Alain Brugger
  • Patent number: 6777039
    Abstract: An inkjet recording sheet comprising a support and, on a surface of the support, a colorant-receiving layer formed by applying a first coating liquid, adding a second coating liquid, after application of the first coating liquid and before the same shows a decreasing rate of drying, and thereafter hardening and drying the coat layer to form a porous structure. The first coating liquid has a pH value of 5 or lower, and is obtained by adding a solution which includes polyvinyl alcohol, a nonionic surfactant and/or amphoteric surfactant and a high boiling point organic solvent, to a dispersion including a cationic resin and vapor-phase-process silica having a specific surface area of at least 200 m2/g as measured by the BET method. The second coating liquid has a pH value of 8.5 or higher and includes a cross-linking agent capable of cross-linking the polyvinyl alcohol, an organic mordant and a nonionic surfactant.
    Type: Grant
    Filed: April 19, 2002
    Date of Patent: August 17, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuyuki Koike, Takashi Kobayashi, Katsuyoshi Suzuki, Ryoichi Nakano