Heat Sealable Patents (Class 428/347)
  • Patent number: 4687701
    Abstract: The inked element which is preferably in ribbon form comprises a flexible plastics carrier of a thickness of from 5 to 15.mu., covered with a thermotransferable coating which is 2 to 6.mu. in thickeness. The mixture of the coating comprises a blend of thermoplastic resins of non-polymeric type with natural or synthetic waxes with a melting point of between 60.degree. and 80.degree. C. The waxes and the resins are so selected as to be compatible with each other and to provide a melting point of between 60.degree. and 80.degree. C. and a melt viscosity of between 50 to 1000 cps. The ribbon makes it possible to print at a printing rate of 40 to 120 characters/sec on papers having a Bendtsen roughness of 10 to 100 ml/min. The ribbon can be prepared with bands of different colors for multi-color printing.
    Type: Grant
    Filed: March 28, 1984
    Date of Patent: August 18, 1987
    Assignee: Ing. C. Olivetti & C., S.p.A.
    Inventors: Franco Knirsch, Giovanni Gianolini
  • Patent number: 4684554
    Abstract: Tamper-resistant inner seals that bond firmly to the lips of lidded and capped glass and plastic containers. The innerseals incorporate a metallic foil having a heat sealable adhesive applied to one surface thereof. The heat-sealable adhesive comprises a parafin wax or blend of paraffin wax and microcrystalline wax, polystyrene or derivative thereof, rosin or derivative thereof, and at least one high molecular weight polymeric material selected from the group consisting of ethylene/acrylic acid copolymers, ethylene/vinyl acetate copolymers, ethylene/methacrylate copolymers, and ethylene/vinyl acetate/methacrylic acid terpolymers, and blends thereof.
    Type: Grant
    Filed: April 12, 1985
    Date of Patent: August 4, 1987
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: David T. Ou-Yang
  • Patent number: 4670335
    Abstract: A blanking strip, made of paper or film, for the partial blanking of objects to be electroplated, such as printed circuit boards, coated with an adhesive composition based on a plastomer, a hard resin and a plasticizer.
    Type: Grant
    Filed: November 12, 1985
    Date of Patent: June 2, 1987
    Assignee: Beiersdorf Aktiengesellschaft
    Inventor: Klaus Grah
  • Patent number: 4666772
    Abstract: Heatsealable opaque multilayer films, particularly wrapping films, having a high sealing strength, at low sealing temperature, favorable optical properties and machine compatibility based on a film of a propylene polymer and a linear statistical ethylene copolymer of low density as the heat sealing layer.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: May 19, 1987
    Assignee: Wolff Walsrode Aktiengesellschaft
    Inventors: Ingo Schinkel, Jurgen Bohner
  • Patent number: 4652490
    Abstract: A heat shrinkable and heat sealable laminated packaging material comprising a heat shrinkable film which is endowed with a heat shrinkability by biaxial stretching in advance of lamination, such as biaxially stretched polyamide film or biaxially stretched polypropylene film, and a heat shrinkable polyolefin sealant film which is endowed with a heat shrinkability by stretching in advance of lamination, such as biaxially stretched linear low density polyethylene film, the sealant film being laminated on one or both surfaces of the heat shrinkable film. The laminated packaging material imparts a tight appearance to a finish package in heat shrink packaging due to its excellent heat shrinkability.
    Type: Grant
    Filed: August 27, 1985
    Date of Patent: March 24, 1987
    Assignee: Kohjin Co., Ltd.
    Inventors: Masanobu Arita, Hisao Tanaka, Yukio Mogami
  • Patent number: 4643945
    Abstract: A polymer blend which is useful for forming heat sealable plastic film which comprises from about 60% to about 40% by weight of a polypropylene terpolymer comprising about 0.1 to about 10.0 mole percent ethylene, about 0.1 to 10.0 mole percent 1-butene, and the balance propylene, and 40% to 60% of a copolymer of ethylene and alpha olefins containing four or more carbon atoms wherein the ethylene content has from about 90.0 to about 99.9 mole percent.
    Type: Grant
    Filed: September 3, 1985
    Date of Patent: February 17, 1987
    Assignee: Enron Chemical Company
    Inventor: Webster W. Kiang
  • Patent number: 4621019
    Abstract: A non-photosensitive transfer resist sheet material comprises in sequence(a) a carrier support(b) a release layer(c) a flexible, water-insoluble, aqueous-alkaline-soluble, non-photosensitive resist layer comprising a thermoplastic organic polymer,wherein said resist is able to adhere to a surface against which it is pressed at a temperature above 60.degree. C. The resist is useful as a protective layer in etching and coating processes in electronic circuitry technology.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: November 4, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: John P. Vikesland
  • Patent number: 4596732
    Abstract: A transversely pleated, longitudinally heat-shrinkable tape is made from a heat-shrinkable polymeric film. One side of the tape may be adhesive-coated, and the other side may be coated with a thermochromic paint. The tape is wrapped around a substrate, and is particularly adapted, by reason of the pleats, to be wrapped around a substrate of non-uniform cross-section, e.g. a splice in a telephone cable. On heating the tape to its recovery temperature, the pleats disappear and the tape shrinks longitudinally to tightly cover the substrate. The tape may additionally comprise integral heating means.
    Type: Grant
    Filed: January 10, 1984
    Date of Patent: June 24, 1986
    Assignee: Raychem Corporation
    Inventor: Stephen H. Diaz
  • Patent number: 4590125
    Abstract: Multi-layer structures, such as films of low coefficient of friction also having antistick characteristics over a wide temperature range during heat-sealing are disclosed. In accordance with a preferred embodiment, the films comprise an amide-containing polypropylene base layer and two heat sealable skin layers of a low stereoregularity polyolefin and microcrystalline wax. Methods for forming such structures are also disclosed.
    Type: Grant
    Filed: January 24, 1985
    Date of Patent: May 20, 1986
    Assignee: Mobil Oil Corporation
    Inventors: Riccardo Balloni, Jay Keung
  • Patent number: 4590497
    Abstract: A thermosensitive recording label includes a thermosensitive color-forming layer disposed on one side of a substrate and a heat reflecting layer disposed on another side of the substrate and a delayed action adhesive disposed on the heat reflecting layer. The thermosensitive recording label may be manufactured and used without a backing sheet, thus considerably reducing the weight and volume of the label. In use, the thermosensitive recording label is drawn from a roll or stack and the delayed action adhesive activated by a heat lamp, or the like, to place it in a tacky condition for placement on goods. The heat reflecting layer disposed between the delayed action adhesive and the thermosensitive color-forming layer prevents activation of the color-forming layer during heating of the delayed action adhesive.
    Type: Grant
    Filed: November 5, 1984
    Date of Patent: May 20, 1986
    Assignee: Ricoh Electronics, Inc.
    Inventors: Tomoo Shibata, Wissam J. Jurdi, Minoru Nomura
  • Patent number: 4586975
    Abstract: A length of material (10) is provided with an indented zone (18) which receives an adhesive layer (24). The outer surface (26) of the adhesive layer (24) is coplanar with the outer surface (12) of the length of material (10) thus providing a check processing tab (44) having a uniform cross sectional configuration. The check processing tabs are wound into rolls (30) and are ultimately adhesively secured to checks (34) with the outer surface (12) of the check processing tab (44) positioned in the same plane as the reverse side (46) of the check (34) and subtantially offset from the face (48) thereof.
    Type: Grant
    Filed: September 27, 1984
    Date of Patent: May 6, 1986
    Assignee: Check-Strip Ltd.
    Inventor: Steven C. Derby
  • Patent number: 4578309
    Abstract: A laminated material comprises a layer (2) of a microcellular material capable of changing color upon the application of heat and pressure and having a layer of adhesive (3) bonded thereto. The laminated material can be used in a method of applying a decorative layer or motif (13) to a substrate (11) using a die (5). The die includes shaped projections (10) for heating and compressing the discrete areas of the microcellular material in order to change its color, and includes severing edges (9) for cutting the decorative layer or motif (13) from the laminated material.
    Type: Grant
    Filed: July 30, 1984
    Date of Patent: March 25, 1986
    Inventor: Ernest H. Worth
  • Patent number: 4568602
    Abstract: Sheet material useful for making bonded electrical connections, especially to sets of small side-by-side terminal pads. In one typical form, the sheet material is an elongated tape comprising an elongated insulating backing; a plurality of narrow spaced parallel elongated electrically conductive stripes on the backing; and electrically conductive adhesive disposed over the stripes comprising a layer of adhesive material in which are contained a monolayer of electrically conductive elements which are thinner than the adhesive layer. The surface of the adhesive layer that contacts a substrate is configured so that at least a portion of the area of the surface is recessed below other areas of the surface, whereby when the adhesive layer is heated and pressed against a substrate, adhesive material may be displaced into the recessed areas and allow the electrically conductive elements to be brought into close electrical association with the substrate.
    Type: Grant
    Filed: August 2, 1984
    Date of Patent: February 4, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert H. Stow
  • Patent number: 4563379
    Abstract: Sealing web of at least one layer on the basis of mixed polymerizates of ethylene and propylene with or without ter-component (EPDM/EPM). Mixed polymerizates with an ethylene content of at least 50 parts by weight are heat-treated with a reinforcement resin and form through heat treatment an interpenetrating network of chemically non-cross-linked EPDM/EPM and cross-linked reinforcement resin, which can be welded together thermally and/or by dissolving or swelling agents.
    Type: Grant
    Filed: May 2, 1984
    Date of Patent: January 7, 1986
    Assignee: Metzeler Kautschuk GmbH
    Inventor: Gerhard Kruger
  • Patent number: 4551380
    Abstract: A three layered heat shrinkable, heat sealable thermoplastic packaging film having a desired combination of physical characteristics is disclosed. The film may be utilized to package a wide variety of items. A preferred embodiment of the film comprises a core layer consisting essentially of a linear low density polyethylene and two surface layers comprising a three component blend of (1) a linear low density polyethylene, (2) a linear medium density polyethylene and (3) a copolymer of ethylene and vinyl acetate.
    Type: Grant
    Filed: May 10, 1984
    Date of Patent: November 5, 1985
    Assignee: W. R. Grace & Co., Cryovac Div.
    Inventor: Julian H. Schoenberg
  • Patent number: 4539259
    Abstract: The stiffness and deadfold properties of laminates used to make toothpaste tubes are improved by including a layer of high density polyethylene as one of the layers of the laminate. The use of high density polyethylene obviates the need to use a layer of paper or thick foil to provide stiffness and deadfold. The laminates containing high density polyethylene also have excellent strength and other properties which make them especially suitable for making tubes used to package toothpaste or other substances.
    Type: Grant
    Filed: July 2, 1984
    Date of Patent: September 3, 1985
    Assignee: Crown Zellerbach Corporation
    Inventor: Edward J. Zuscik
  • Patent number: 4536441
    Abstract: The invention relates to an adhesive tape having a base material which is stretched more highly at right angles to the web direction than in the web direction, contains polypropylene as the main component, and is provided with at least one pressure-sensitive or heat-sealable adhesive layer, characterized in that the base material is foamed and that the stretch ratio in the web direction is 1:1 to 1:4 and at right angles to the web direction is 1:3 to 1:8, the stretch ratio at right angles to the web direction being greater than the stretch ratio in the web direction.
    Type: Grant
    Filed: June 11, 1984
    Date of Patent: August 20, 1985
    Assignee: Beiersdorf Aktiengesellschaft
    Inventors: Gert Schmeer, Eberhard Engelmann, Karl Schafer
  • Patent number: 4535024
    Abstract: A glossy black reflective metal coating with improved durability is prepared as a film of an intrinsically blackened chromium-containing metal. A laminate may be prepared with the metal coating bonded to at least one transferable resin film. A particular laminate includes at least one top coat and at least one base coat, with the metal coating located in sandwich relationship therebetween.
    Type: Grant
    Filed: November 1, 1982
    Date of Patent: August 13, 1985
    Assignee: Transfer Print Foils, Inc.
    Inventor: Harry A. Parker
  • Patent number: 4533586
    Abstract: A web of adhesive labels for use with a machine for applying tax stamps or like adhesive labels to articles such as cigarette packages arranged in two or more rows in a carton, including mechanism for advancing the carton lengthwise with exposed ends of the packages facing upwardly, and a head disposed above the path of carton advance for transporting a corresponding number of rows of spaced-apart labels into contact with the advancing package ends while the labels and packages are moving in the same direction and at the same velocity.
    Type: Grant
    Filed: March 8, 1984
    Date of Patent: August 6, 1985
    Assignee: American Bank Note Company
    Inventors: Richard L. Roule, Peter J. Sorbo, John J. Kimball
  • Patent number: 4532189
    Abstract: A multi-layered thermoplastic film having improved physical characteristics is formulated through utilization of a linear low density polyethylene or linear medium density polyethylene resin as a core and/or an intermediate layer constituent.
    Type: Grant
    Filed: November 18, 1983
    Date of Patent: July 30, 1985
    Assignee: W. R. Grace & Co., Cryovac Div.
    Inventor: Walter B. Mueller
  • Patent number: 4530878
    Abstract: The inter-layer adhesion of laminates comprised of alternating layers of thermoplastic polyester and ethylene-vinyl acetate copolymer is greatly enhanced by a method of treatment of the laminate with a stream of inert gas at elevated temperatures which is described. The treated articles in general exhibit a T-peel strength of 1 in. lb./in..sup.2 and greater, which is far in excess of the peel strengths typical of the untreated article.
    Type: Grant
    Filed: April 28, 1982
    Date of Patent: July 23, 1985
    Assignee: General Electric Company
    Inventors: Willem F. H. Borman, John Semen
  • Patent number: 4528220
    Abstract: A package for blood and/or intravenous solutions which is nontoxic, autoclavable, retains its strength when dropped, sufficiently flexible and is of substantially reduced material cost which comprises an outer layer blend of propylene-ethylene copolymer and butene-1-ethylene copolymer, which is laminated to an inner layer blend of butene-1-ethylene copolymer and propylene-ethylene copolymer. The copolymers are random and the thickness ratio of the inner layer blend to the outer layer blend is 4:1.
    Type: Grant
    Filed: February 9, 1984
    Date of Patent: July 9, 1985
    Assignee: Shell Oil Company
    Inventor: Charles C. Hwo
  • Patent number: 4521437
    Abstract: Pouches containing a flowable material e.g. milk, ice cream, are made of a sealant film which is from about 50 to 100 parts by weight of a linear copolymer of ethylene and a C.sub.6 -C.sub.10 .alpha.-olefin, and from 0 to 50 parts by weight of at least one polymer selected from linear copolymer of ethylene and a C.sub.4 -C.sub.10 .alpha.-olefin, and a high-pressure polyethylene. The sealant film is selected on the basis of providing (a) pouches with an M-test value substantially better, at the same film thickness, than that obtained with pouches made with film of a specified blend of an ethylene-butene copolymer and a high pressure polyethylene, or (b) an M(2)-test value of less than about 12%, for pouches having a volume of from greater than 1.3 to 5 liters, or (c) an M(1.3)-test value of less than about 5% for pouches having a volume of from 0.1 to 1.3 liters. The M, M(2) and M(1.3)-tests are defined pouch drop tests.
    Type: Grant
    Filed: June 2, 1983
    Date of Patent: June 4, 1985
    Assignee: Du Pont Canada Inc.
    Inventor: William J. Storms
  • Patent number: 4513050
    Abstract: A material for packaging light-sensitive materials composed of a composite sheet comprising a substrate coated with a middle layer(s) and a surface layer(s) is manufactured through melt co-extrusion, said surface layer(s) being of thermoplastic resins which have excellent heat seal properties yet have great neck-in, said middle layer(s) being of thermoplastic resins having small neck-in and excellent adhesion to a substrate, and any of layers of said composite sheet containing light-shielding material.
    Type: Grant
    Filed: April 22, 1983
    Date of Patent: April 23, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mutsuo Akao
  • Patent number: 4508773
    Abstract: Paper products, such as wrapped rolls of newsprint, are provided wherein paper is bonded to paper by a glue formulation that is pumpable at elevated temperatures, which glue formulation includes animal glue, water and a water-soluble salt having an anion that is substantially divalent at the pH of the glue formulation. The paper product is prepared by heating the glue formulation and applying same at an elevated temperature.
    Type: Grant
    Filed: April 27, 1983
    Date of Patent: April 2, 1985
    Assignee: Eschem Inc.
    Inventor: Gary A. Maxwell
  • Patent number: 4502263
    Abstract: A sealable, transparent, polyolefinic multilayer film comprises a base layer formed of a polypropylene polymer and at least one sealable layer, which contains a propylene copolymer, a low-molecular weight resin, a polypropylene homopolymer and a polydiorganosiloxane. The sealing layer is comprised of a combination of(a) from about 68.5 to 89.7% by weight, based on the weight of the sealable layer, of an olefin resin composition, comprising an ethylene-propylene-butylene terpolymer and a propylene-butylene copolymer, corresponding to a content of from about 0.1 to 7% by weight of ethylene, 53 to 89.9% by weight of propylene and 10 to 40% by weight of butylene, based on the weight of the olefin resin composition,(b) from about 5 to 15% by weight, based on the weight of the sealable layer, of a low-molecular weight resin, which compatible with the olefin resin composition,(c) from about 5 to 15% by weight, based on the weight of the sealable layer, of a propylene homopolymer, and(d) from about 0.3 to 1.
    Type: Grant
    Filed: December 16, 1983
    Date of Patent: March 5, 1985
    Assignee: Hoechst Aktiengesellschaft
    Inventors: G/u/ nther Crass, Siegfried Janocha, Wolfgang Dietz, Lothar Bothe
  • Patent number: 4501797
    Abstract: An unbalanced polymeric film has a plurality of adjacent molecularly oriented layers. The first, second, and third layers are molecularly oriented, and are, respectively (1) polypropylene, (2) anhydride modified polypropylene and (3) a barrier layer of either ethylene vinyl alcohol or nylon or a blend of ethylene vinyl alcohol and nylon. A fourth layer is optionally oriented and serves as a heat sealable layer having good adhesion to the barrier layer. In a more sophisticated structure, the fourth layer is oriented and serves an adhesive layer between the barrier layer and a fifth sealant layer. The fifth layer is then optionally oriented. A process for making the films comprises heating the exterior surfaces of the two surface layers to a temperature between 10.degree. and 100.degree. F. below the respective heat sealing temperature of each of the respective surface layers, stretching the so-heated film, annealing the stretched film, and cooling the annealed film.
    Type: Grant
    Filed: December 1, 1982
    Date of Patent: February 26, 1985
    Assignee: American Can Company
    Inventors: Scott S. Super, Joseph C. Hsu, William B. Haffner, Jerry F. Jesse
  • Patent number: 4495232
    Abstract: A stamping foil for forming printed circuit patterns on insulating or poorly conductive substrates comprising an electrically conductive layer made of a highly conductive metal, such as copper, which is endowed with a sufficiently low shear strength, even in thicknesses of 10 microns or more, to permit easy and sharp separation of the activated (imprinted) and non-activated portions of the foil. Such a low shear strength may be achieved with fibrous or fibrous-granular crystallite structures, wherein the fibers are oriented approximately at right angles to the surfaces of the foil, and, in addition, by doping agents containing carbon, nitrogen and sulfur. The foil may comprise a bonding layer for bonding the conductive layer to a substrate, or such a bonding layer may be applied to the surface of the conductive layer before the stamping operation. The conductive layer may be either self-supporting, or it may adhere to a carrier tape through an intermediary separating layer.
    Type: Grant
    Filed: March 29, 1982
    Date of Patent: January 22, 1985
    Assignee: Irion & Vosseler GmbH & Co. & Zahlerfabrik
    Inventors: Herbert Bauser, Edmund Kurz, Bernd Schindler, Klaus Zerweck, Thomas Bolch, Andreas Haller, Theo Mager
  • Patent number: 4490426
    Abstract: A branch-off of at least two substrates leaving an end of a recovered sleeve is effected using a heat activatable sealant, and a thermally conductive member which has a fin-shaped protruberance by means of which heat can be conducted into the crutch region between the substrates to activate the sealant. The thermally conductive member can also function to urge together circumferentially spaced portions of the sleeve to define conduits for the substrates. This urging function can be supplemented or carried out totally by a separate clip.
    Type: Grant
    Filed: July 29, 1983
    Date of Patent: December 25, 1984
    Assignee: N. V. Raychem S.A.
    Inventor: Joris R. I. Franckx
  • Patent number: 4490424
    Abstract: Articles of manufacture are disclosed which are funicularly shaped articles comprising a core of a hot-melt adhesive at least partially encased in a sheath of a plastic resin. Extended lengths of such articles can be wound upon a tubular core for each feed and delivery to a hot-melt adhesive extruder and dispensing apparatus. In a second embodiment of the invention, two or more funicularly shaped elements are encased in an outer plastic resin sheath.
    Type: Grant
    Filed: May 5, 1983
    Date of Patent: December 25, 1984
    Assignee: Protective Treatments, Inc.
    Inventor: Michael J. Gerace
  • Patent number: 4481245
    Abstract: Bituminous sealing elements comprise a visible part and a part which serves for assembly thereof so as to form a continuous membrane. The assembly part is a "jointing zone" formed on the stripped edge of an element on which the edge of the adjacent element is applied by overlapping. To protect this zone, confer thereon the required strength and allow sticking by means of hot bitumen, adhesive or by means of a blowlamp, a web of low-weight porous, volatile non woven fibers, is used buried in the binder of the welding strip.
    Type: Grant
    Filed: October 22, 1982
    Date of Patent: November 6, 1984
    Assignee: Siplast, S.A.
    Inventor: Jean-Yves Meynard
  • Patent number: 4477510
    Abstract: A heat release decal, for decorating a shaped surface of an article, is disclosed. The decal includes a stretchable web, a meltable release layer on the web and a design layer thereover. When heated, the release layer melts, thereby releasing the design layer therefrom. When the decal is heated to above the melt point of the release layer, the design layer becomes tacky. The design layer sticks to the article upon intimate contact. The web, the design layer and release layer are formed of materials which do not migrate into each other upon formation of the decal, or upon application to the article. Each are stretchable to allow the decal to conform to the shape of the article to be decorated.
    Type: Grant
    Filed: September 29, 1982
    Date of Patent: October 16, 1984
    Assignee: Corning Glass Works
    Inventors: Ronald E. Johnson, Lung-ming Wu
  • Patent number: 4469742
    Abstract: A pasteurizable and/or cook-in shrink film is provided that includes a first or sealing layer of a nonlipophillic polymeric material having a softening point greater than that of the following shrink layer; a second or shrink controlling layer, melt bonded to the first layer, of an ethylene homopolymer or copolymer; a third or adhesive layer, melt bonded to the second layer, of a chemically modified polyethylene being irradiatively cross-linkable and having functional groups with a relatively strong affinity for the following barrier layer; a fourth or barrier layer, melt bonded to the third layer, of a hydrolyzed ethylene-vinyl acetate copolymer; a fifth or adhesive layer as in said third layer, melt bonded to the fourth layer; and a sixth or abuse layer, melt bonded to the fifth layer. An associated method for making the film is also provided that includes full coextrusion and selective irradiation and orientation.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: September 4, 1984
    Assignee: W. R. Grace & Co., Cryovac Div.
    Inventors: Timothy T. Oberle, Henry G. Schirmer, Norman D. Bornstein, Johnnie J. Walters
  • Patent number: 4465717
    Abstract: An assembly for marking an elongate object, for example a wire or cable, comprises a flexible heat-recoverable marker strip (1) having one surface which is capable of receiving printed characters, and being supported on a rigid carrier strip to prevent premature recovery of the marker strip when heated, for example when heated to render the printed characters indelible. The assembly is characterized in that the other surface of the marker strip (1) is at least partly coated with a heat-activatable adhesive (2), and is provided with one or more areas of pressure-sensitive or contact adhesive (3) capable at least temporarily of securing the marker strip in position about the object after separation from the carrier strip, and preferably also capable of supporting the marker strip on the carrier strip before separation of the marker strip therefrom.
    Type: Grant
    Filed: September 22, 1980
    Date of Patent: August 14, 1984
    Assignee: Raychem Limited
    Inventors: David Crofts, David E. Barnwell
  • Patent number: 4460632
    Abstract: Composites of matter having properties that make them strong adhesives to various substrates, especially to polar substrates. These adhesive blends comprise medium density polyethylene, linear low density polyethylene and a high density polyethylene grafted with or containing in its main chain unsaturated or saturated carboxylic acids or derivatives. The disclosure also includes composite structures having one or more substrates with the adhesive blend adhered thereto and to methods of making these composites.
    Type: Grant
    Filed: June 17, 1983
    Date of Patent: July 17, 1984
    Assignee: Chemplex Company
    Inventors: Ashok M. Adur, Seymour Schmukler, John Machonis, Jr., Mitsuzo Shida
  • Patent number: 4456639
    Abstract: A transparent protective laminating film for forming a sealed protective cover on an identification card or similar document, comprising a base film of biaxially oriented thermoset polyester resin with an inner surface coating of polyethylene or other heat-and-pressure activated thermoplastic resin, has an additional outer surface layer of unoriented embossable thermoplastic polyester resin to permit embossure with a security pattern; the outer surface layer is also receptive to a signature strip formed by embossure, to a pigment signature strip or a resin-oxide magnetic strip applied by hot stamp transfer, or any combination of such strips.
    Type: Grant
    Filed: June 7, 1982
    Date of Patent: June 26, 1984
    Assignee: Sealtran Corporation
    Inventors: Herbert M. Drower, Morton Minkus
  • Patent number: 4444818
    Abstract: A thermosetting adhesive sheet is described, comprising a thermosetting resin sheet-shaped prepreg with a reinforcing material embedded therein, and a flattened tubular material provided on one side of the prepeg, said flattened tubular material being capable of nearly recovering the original tubular form on heating and being narrower in width than the prepreg. The prepreg may be of the two-layer structure comprising a first thermosetting resin composition layer and a second thermosetting resin composition layer.
    Type: Grant
    Filed: January 31, 1983
    Date of Patent: April 24, 1984
    Assignee: Nitto Electric Industrial Co., Ltd.
    Inventors: Takashi Tominaga, Toshihiko Ariyoshi, Eishi Asoshina
  • Patent number: 4443519
    Abstract: A bonded plastic structure which comprises plastic parts of reaction injection molded polyurethane or reaction injection molded nylon coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.
    Type: Grant
    Filed: February 4, 1983
    Date of Patent: April 17, 1984
    Assignee: Monsanto Company
    Inventors: Donald D. Donermeyer, Joseph G. Martins, David A. Fabel
  • Patent number: 4443518
    Abstract: A bonded reinforced plastic structure which comprises reinforced plastic parts of sheet molding compound or bulk molding compound, coated with a primer coat and bonded together with a thermoplastic block copolymer. The primer coat comprises a moisture-curable polyisocyanate. The block copolymer comprises from 40 to 80 weight percent crystalline polyester or polyamide segments and 20 to 60 weight percent amorphous polyamide or polyether segments and has a crystalline melting point of at least 155.degree. C. The bonded structure is adapted to survive the hot environment of paint curing ovens.
    Type: Grant
    Filed: February 4, 1983
    Date of Patent: April 17, 1984
    Assignee: Monsanto Company
    Inventors: Joseph G. Martins, Donald D. Donermeyer, David A. Fabel
  • Patent number: 4440821
    Abstract: Heat shrinkable material comprising a heat shrinkable substrate and a layer of different kinds of adhesives provided on the substrate, which exhibits excellent impact resistance and adhesion properties over a wide temperature range.
    Type: Grant
    Filed: April 17, 1980
    Date of Patent: April 3, 1984
    Assignee: Nitto Electric Industrial Co., Ltd.
    Inventors: Minoru Komura, Yasuhiro Moriyama
  • Patent number: 4427725
    Abstract: A polymeric article, at least part of which is dimensionally-recoverable, preferably heat-recoverable, has, bonded to the surface of a dimensionally-recoverable portion thereof, a pliant, adhesive-receptive polymeric film which is soft at the temperature at which the dimensionally-recoverable portion is recovered, and which is substantially non-curable at ambient temperatures. The polymeric film is preferably based on a film-forming chlorinated resin or a film forming silane.The articles may be recovered over objects such as electrical equipment to provide electrical insulation and may be bonded to the object or other article with an adhesive without the necessity of any special surface treatment immediately before bonding.
    Type: Grant
    Filed: February 11, 1982
    Date of Patent: January 24, 1984
    Assignee: Raychem Limited
    Inventor: David Crofts
  • Patent number: 4427733
    Abstract: Small decorative plates for ornamental use, in particular for the decoration of textiles having an effective inner layer with at least one metallic layer, and two thermically activatable melt adhesive layers forming the outer layers on both sides.
    Type: Grant
    Filed: September 17, 1981
    Date of Patent: January 24, 1984
    Assignee: D. Swarovski & Co.
    Inventors: Martin Poll, Christian Covi
  • Patent number: 4426422
    Abstract: Distortion and chemically resistant heat transfer materials formed by a mixture of at least two interspersed polymers. One of the polymers is a film-forming, multi-aromatic ring condensation product, preferably a saturated aromatic, acid-based polyester. This polymer is reinforced by a second polymer which preferably contains bulky ring structures, such as polymerized rosin esters, but may be essentially linear, for example an ethylene-vinyl acetate copolymer. The materials may be used as a protective and brightener coating for labels, which are heat activated to transfer them from a carrier to a final substrate such as the face of a package. The labels thus coated exhibit improved resistance to adverse chemicals such as alcohols, oils and detergents. The materials may also be used to provide distortion and chemically resistant inks, and distortion and chemically resistant adhesives.
    Type: Grant
    Filed: May 6, 1980
    Date of Patent: January 17, 1984
    Assignee: Dennison Manufacturing Company
    Inventor: George R. E. Daniels
  • Patent number: 4424256
    Abstract: The invention provides improved films and pouches made therefrom for use in sterile packaging, wherein the package and product are sterilized after the process of filling and sealing the pouch. The improved films are a family of foil-based, multiple layer structures incorporating an improved combination of layers which form the sealant layer and the adhesive bonding to the foil layer. The sealant layer is linear low density polyethylene. The layer adjacent the sealant layer is a blend of 20% to 80% propylene ethylene copolymer and 80% to 20% linear low density polyethylene. The foil layer is primed with an anhydride modified propylene-based primer. Additional layers comprising propylene based polymers may be used between the blend layer and the primer.
    Type: Grant
    Filed: August 6, 1982
    Date of Patent: January 3, 1984
    Assignee: American Can Company
    Inventors: Ronald C. Christensen, Roger P. Genske, Dennis E. Kester, William F. Ossian
  • Patent number: 4420518
    Abstract: A package assembly for precisely positioning a charge of hot melt adhesive 37 onto an attachment pad (13, 15, 17) or point of use wherein the adhesive is heated to softening or melt temperature (280.degree. F.-325.degree. F.) and thereafter cooled to resolidifying temperature. A single sided pressure sensitive polyimide film tape 40 serves with another film strip 39 to protect sandwiched adhesive strip 37 until use and to hold the adhesive in precise position until thermally bonded to its point of use. Tab ends 39' and 40' serve as aids in stripping tapes 39 and 40, respectively, from the adhesive charge 37.
    Type: Grant
    Filed: March 24, 1982
    Date of Patent: December 13, 1983
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventor: Donald J. Progar
  • Patent number: 4415623
    Abstract: The present invention relates to the decoration of sheet materials and has particular reference to the application of decorative stones either alone or in combination with embroidery patterns to sheet materials.
    Type: Grant
    Filed: September 29, 1980
    Date of Patent: November 15, 1983
    Assignee: Jacob Schlaepfer & Co. AG
    Inventor: Robert J. Schlaepfer
  • Patent number: 4407872
    Abstract: The sheet material for packaging electronic parts consists of a laminated material which comprises a transparent plastic film layer and a thin metal film layer having a light transmittance of at least 25% and an electric resistance of less than 10.sup.8 ohms/cm.sup.2. The sheet material is heat-sealable at the surface of said metal film layer. An envelope for packaging electronic parts is made of the sheet material by heat-sealing in a state of disposing the plastic film layer outside.
    Type: Grant
    Filed: December 2, 1981
    Date of Patent: October 4, 1983
    Assignee: Ricoh Co. Ltd.
    Inventor: Shigeo Horii
  • Patent number: 4403010
    Abstract: Processes for manufacturing a metal-plastic composite foil having a plastic core covered on both sides with an outer layer of thin metal strip, in particular aluminum thin strip, are already known. However, the use of a so-called triplex composite of the kind just mentioned for relatively large volume containers of full weight up to about 30 kg has been very limited because of the unsatisfactory deep drawing properties of such composites in deep drawing or deep drawing by elongation of the foil (stretching). By means of the invention a process for manufacturing a metal-plastic composite of the so-called triplex composite kind and a metal-plastic composite foil made by this said process have been developed which allow in particular the manufacture of semi-rigid light-weight containers which have a weight of up to about 30 kg when full and this even by cold forming.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: September 6, 1983
    Assignee: Swiss Aluminium Ltd.
    Inventors: Werner Festag, Hans U. Muller, Hans P. Breitler, Max Bolliger
  • Patent number: 4403004
    Abstract: A decorative metallized laminate having improved brilliance, reflectance and weatherability comprises a base layer prepared from a thermo-formable resin film, with both surfaces thereof coated with vapor deposited metal layers. An outer protective capping layer prepared from a film having at least one surface treated for receptivity to adhesive bonding and resistance to attack by ultra-violet radiation, is adhesively bonded to one of the metallized surfaces of the base layer. A pressure and heat sensitive elastomeric adhesive coating is disposed between the capping layer and the metallized surface of the base layer, to form the bond between the two layers. A compatible thermo-formable resin backing layer may be laminated to the free metallized surface of the base layer, to provide a composite laminate suitable for thermo-forming and injection molding to manufacture a variety of products.A method for preparing the metallized laminate is also disclosed.
    Type: Grant
    Filed: October 23, 1981
    Date of Patent: September 6, 1983
    Assignee: Transfer Print Foils, Inc.
    Inventors: Harry A. Parker, Joseph Greenman
  • Patent number: 4390552
    Abstract: A heat-sealing sheet material can be obtained by forming, on one side of a sheet base material such as aluminum foil, a sealant layer composed of a graft copolymer comprising a trunk polymer of a 20 to 60% saponification product of an ethylene/vinyl acetate copolymer having a vinyl acetate content of 15 to 45% by weight and a branch polymer of an unsaturated carboxylic acid in a proportion of 10% by weight or less of the partially-saponified product. This sheet material exhibits excellent heat-sealing strength with respect to glass containers, and, moreover, there is almost no decrease in the sealing strength even when the material has been in contact with water. Accordingly, the sheet material is suitable as a sealing material for the opening rims of glass containers for water-containing food products such as jams and pickles.
    Type: Grant
    Filed: January 25, 1982
    Date of Patent: June 28, 1983
    Assignee: Kabushiki Kaisha Hosokawa Yoko
    Inventor: Susumu Niwa