Abstract: An assembly and method is provided for improved vacuum retention in evacuated biological sample collection primary containers. Such primary containers include but are not limited to blood collection tubes, evacuated blood collection tubes, centrifuge tubes, culture bottles, and syringe barrels. In one embodiment an evacuated blood collection tube is enclosed within an evacuated secondary container which is made from a gas barrier material.

Abstract: This invention relates to a vulcanizable layered composition comprising at least two layers and at least one tie layer, wherein the first layer of the two layers comprises an fluid permeation prevention layer, the second layer of the two layers comprises at least one high diene rubber, and the tie layer comprises a mixture of: (1) about 50 to about 95 weight % of at least one halogenated isobutylenecontaining elastomer; (2) about 5 to about 50 weight % of at least one high diene elastomer; (3) about 20 to about 50 weight % of at least one filler; (4) about 0 to about 30 weight % of at least one processing oil; and (5) at least about 0.2 to about 15 parts per hundred of rubber (phr) of a curing system for the elastomers; wherein said fluid permeation prevention layer comprises a polymer composition having an air permeation coefficient of 25×10?12 cc·cm/cm2 sec cmHg (at 30° C.

Abstract: The present invention relates to a gas barrier composite film for a hydrothermally processable package, wherein at least one gas barrier layer containing a gas barrier resin and an inorganic layered compound is interposed between a base film layer and a sealing material layer, and an adhesive layer is further formed on both sides of the gas barrier layer by applying an adhesive composition comprising: a base material mainly comprising a polyurethane resin having at least one functional group selected from the group consisting of an amino group, a hydroxyl group, and a carboxyl group; and a curing agent comprising an isocyanate curing agent and an epoxy curing agent, at the following functional group ratio: I/P=0.3 to 30.0 E/P=1.5 to 25.

Abstract: Packaging/storage shaped articles, for example, opaque bottles suited for storing and shielding such products as milk away from the adverse effects of visible and UV radiation, are manufactured by first providing/formulating precursor compositions which include a polyester or polylactone thermoplastic matrix having at least one mineral filler distributed therethrough, the mineral filler containing a titanium oxide and/or zinc sulfide and also having from 2% to 40% by weight of the composition, and thence converting the composition into such packaging/storage shaped article, notably by injection-blow molding.

Abstract: A composition comprises an ethylene copolymer having copolymerized units of ethylene and vinyl acetate, alkyl acrylates, alkyl methacrylates, acrylic acid and ionomers thereof, methacrylic acid and ionomers and a potassium-containing component comprising a potassium-neutralized ionomer and optionally an organic acid or salt thereof and/or a polyol. Also disclosed is an article comprising or produced from the composition, which includes films, sheets and shaped articles.

Abstract: Multi-layer films particularly suited for packaging applications, including a core layer, a tie layer made from at least 10 wt % of a first polymer and a service layer, wherein the tie layer is a sealable layer and may provide a hermetic seal when sealed to itself. The films of this invention may be suitable for use in preparing hermetically sealed packages. Optionally, the multi-layer film may have a skin layer and/or a second skin layer. Embodiments may have the advantage of improved seal strength, hermeticity, hot tack, reduced-temperature sealability, and improved packaging machine operating speed.

Abstract: Provided are partially or fully neutralized mixtures of carboxylate functionalized ethylene high copolymers or terpolymers (Mw between 80,000 and 500,000 Da) with carboxylate functionalized ethylene low copolymers (Mw between 2,000 and 30,000 Da). The compositions are used in films, multilayer structures and other articles of manufacture. The compositions are preferably used on a surface of the articles.

Abstract: A multilayered flexible laminate is disclosed that includes a first lamina having a inlet channel; a second lamina having a outlet channel; the first and second laminas joined to one another about an unbonded valve region having open and closed orientations; wherein the inlet channel and the outlet channels are in gaseous communication when the valve region is in the open orientation.

Abstract: An easy opening heat-shrinkable bag adapted to be heat sealed to a closed condition to contain and protect a product disposed therein, whereby, at least one heat seal is peelable and readily openable by application of force.

Abstract: A reclosable packaging comprising a packaging tray that is made of a multilayer film and a lid which is made of a multilayer film. The tray and the lid are joined together in the edge area of the packaging tray via a sealing seam. The multilayer film of the packaging tray or lid is provided with a contact adhesive layer and a migration barrier layer having a thickness of preferably <2 ?m.

Abstract: Sheet molding composition formulation includes a thermoset cross-linkable polymeric resin. A moisture reducing polymeric additive includes at least one of polystyrene; poly C1-C4 alykylmethacrylate; a copolymer of styrene with at least one of butadiene, acrylonitrile and vinyl chloride; or a combination of polystyrene, polyaklymethacrylate and or a styrene copolymer. Moisture reducing polymeric additive is present within the formulation from between 1 and 20 total weight percent. An article formed from such a sheet molding composition formulation defines an article shape and has a surface that sets the article shape with less than 0.5 total weight percent water after 96 hours exposure and 100° F. 100% humidity. The article shape is amendable to receiving a vapor barrier coating applied to the articles shape surface. A powder prime coating over lies the barrier coating and achieves surface finish results comparable to article shapes formed of steel.

Abstract: There is provided, in a simple manner, a synthetic resin container which improves a vapor barrier property while maintaining a gas barrier property against oxygen or the like at a high level. The present invention is a PET bottle having a barrier film 2 formed on an inner surface of a wall portion 1 constituting a container body made of PET resin by a plasma CVD method with organic silicon compound gas and oxygen gas as raw materials, the barrier film containing silicon oxide in which a compositional ratio of oxygen among silicon, oxygen and carbon is not less than 50 atom % and a compositional ratio of carbon among silicon, oxygen and carbon is not less than 3 atom % and not more than 20 atom %. Preferably, compositional ratio of carbon in the barrier film 2 is not more than 8 atom %.

Abstract: A coating compositions for providing substrates with oxygen barrier properties is disclosed. The substrate may be, for instance, a film, such as a polyester film. The coating composition includes a copolymer of maleic acid and acrylic acid and a copolymer of vinyl alcohol and a vinylamine. The barrier coating formed from the coating composition is typically less than about 1 micron in thickness and provides reduced oxygen transmission even at relatively high relative humidities.

Abstract: A film comprises a barrier layer including PVdC or EVOH, a skin layer, and an intermediate layer comprising at least about 50% of propylene/ethylene copolymer. The film has at least about 10% free shrink in at least one direction at 85° C. The film is useful in making barrier shrink bags.

Abstract: A RF weldable tubing is provided. The tubing has inner layer including a PVDF copolymer, or an ethylene alpha-olefin homopolymer, or an ethylene alpha-olefin polymer that may include a grafted polyethylene. The tubing may have an inter gas barrier layer sandwiched between the outer layer and an outermost layer including a TPU copolymer. The inter gas barrier layer may include an EVOH copolymer. A method of making such a tubing is also provided.

Abstract: Disclosed is a gas barrier film having, on one surface of a substrate film, a gas-barrier layer comprising at least one organic region and at least one inorganic region, and having, as a barrier property-having layer, only a layer comprising a barrier property-having resin as the main ingredient of the layer on the other surface of the substrate film. The gas barrier film has can effectively prevent moisture penetration through the other surface thereof not having the gas-barrier layer.

Abstract: The present invention provides novel multilayered plane or tubular food package casings or films for foodstuff packages, such as sausage casings or the like, having a lamination structure of at least six, preferably at least seven layers.

Abstract: A dual ovenable film having a first layer comprising one or more polyamides and a second layer comprising one or more polyamides. The first layer forms the first outer surface of the film. The second layer has a melting point of at least about 210° C. The film is capable of forming a water-containing package by providing two 4 inch by 6 inch sheets of the film each having four perimeter sides, placing the sheets in superimposed, coextensive arrangement having the first layers of the films in contact with each other, and heat sealing three perimeter sides of the sheets together using a ?-inch wide sealing bar at a temperature of 290° F., a dwell time of 0.5 seconds, and a sealing pressure of 40 psig to form an open pouch having heat seals along three of the four perimeter sides. The open pouch can be filled with 100 milliliters of distilled water at a temperature of 73° F.

Abstract: A gas storage cylinder or gas storage cylinder liner, formed from a polymer composite, containing at least one polymer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m2/g to 2600 m2/g.

Abstract: A long life balloon formed from a lamination. The lamination includes a polyester film with a total thickness of 4 ?m to 12 ?m. The polyester film includes a biaxially oriented polyester core layer and at least one amorphous copolyester skin layer. The lamination also includes a sealant layer and a gas barrier layer on an opposite side of the polyester film from the sealant layer. The oxygen transmission rate of the balloon is less than 0.1 cc/100 sqin/day, a bonding strength of the gas barrier layer to the surface of the polyester film is more than 300 g/in at dry conditions, a sealing strength of the balloon is more than 3.5 kg/in, and a floating time of the balloon is more than 20 days.

Abstract: An extruded multilayer seal member having an expanded temperature range and an improved compression set resistance wherein the seal member comprises a first fluoroelastomer as the inner layer of the multilayer seal member and a second elastomer as the outer layer of the multilayer seal member; and a method for manufacturing the multilayer seal member which comprises extruding a multilayer tubular structure, crosslinking the extruded multilayer tubular structure on a mandrel, cutting the multilayer tubular structure to provide a plurality of uniform seal members and recovering the seal members, are described.

Abstract: A gas barrier packaging laminate having durability to stress crack formation and yet a bending stiffness and good integrity between the laminate layers, includes outer layers of heat-sealable polyolefin, two polymer carrier layers each being coated with a SiOx gas barrier layer, and an intermediate polymer layer that includes at least first and second part-layers. The first part-layer has a higher stiffness than the second part-layer, and the second part-layer has higher elastomeric properties than the first part-layer. A stiff structural sandwich construction is formed by the two stiff carrier layers separated by the intermediate layer that is also shock absorbing to prevent stress-cracking of the SiOx layers. A packaging container manufactured from the packaging laminate and a method of manufacturing of the packaging laminate are also disclosed.

Abstract: A fuel container with high fuel barrier properties is provided. The fuel container is a coextrusion blow-molded fuel container having a container body made of a layered structure. The layered structure comprises: a barrier layer made of a barrier resin (A); and an inner layer and an outer layer made of a thermoplastic resin (B) that is different from the barrier resin (A); wherein a ratio (X/Y) of a distance (X) between end portions of the barrier layer at a pinch-off part of the fuel container and an average thickness (Y) of the container body is at least 1/10000 and at most 1/10; and wherein a ratio (Y1/Y) between a total thickness (Y1) of the layers of the container body that are located on the inside with respect to the barrier layer and an average thickness (Y) of the container body is at least 3/10 and at most 7/10.

Abstract: An injection molded article formed from a polypropylene polymer and having an in mold label located inside the article is disclosed. The article may contain a product such as a product that contains an organic solvent.

Abstract: The invention relates to a plastic tube comprising a tube body consisting of a multi-layer film (5) that includes at least one gas- and water-tight barrier film (7). The barrier film (7) has a polyglycolic acid (PGA) layer (9), at least one side of which is connected to a thermoplastic plastic layer (13, 15) by means of a layer (11, 12) consisting of an adhesion promoter. The adhesion promoter (11, 12) comprises a metal compound and has a layer thickness of between 100 and 500 nm.

Abstract: The object is to provide a thin film having high barrier properties and high translucency with no safety and health problems, which is capable of suppressing degradation due to moisture, oxygen and carbon dioxide gas and degradation due to the diffusion of impurities such as alkali metals and alkali earth metals, a deposition apparatus of the thin film, and products coated with the thin film by the deposition apparatus. Another object is to provide an extended usable range of the products of an environmentally friendly biodegradable material and a prolonged quality preservation period. The feature is that a single layer or laminated layer of a layer expressed by AlNxOy or layer expressed by AlxNy is deposited (coated) over the inner surface of a packaging film. The single layer or laminated layer thereof has high translucency, being capable of enhancing the barrier properties against moisture, oxygen and carbon dioxide gas, the heat resisting properties, and the mechanical strength.

Abstract: The present provides a bondably coated metallic member comprising a metallic member having a low surface energy polymeric coating, said low surface energy polymeric coating having been surface activated on at least a portion thereof, and having on said surface-activated portion a bondable high surface energy polymeric coating. The present invention also provides a bondably-coated metallic pipe comprising metallic pipe having a low surface energy mainline polymeric coating thereon extending over the pipe except at a bare zone adjacent each end of the pipe that is free from said main-line coating; a portion of said mainline coating adjacent each bare zone having been surface activated and having on said surface activated portion a bondable high surface energy polymeric coating.

Abstract: A polyester container having an enhanced level of crystallinity in the sidewall while maintaining a low level of crystallinity in a thickened base portion. The container is particularly useful as a refillable container which can withstand higher caustic wash temperatures and exhibits reduced flavor carryover, or as a hot-fill container. The container, which can be monolayer or multilayer, is also useful as a carbonated beverage, O2 or CO2 barrier, or beer container.

Abstract: A waste containment composite material has a low strength water impermeable barrier layer, a high strength water sensitive layer, and a printed polymer reinforcement pattern applied to the water sensitive layer as a mechanical support layer. Examples of barrier layers include wax, polylactic acid, and other polymers. Examples of water sensitive layers include polyvinyl alcohol. The printed pattern of low permeability polymer support network is applied during the blowing process of the dual layer material.

Abstract: A transparent article includes a continuous polyester matrix having at least one incompatible filler dispersed therein. The incompatible filler provides domains in the polyester matrix, each domain having a particular dimension, thus providing a range of dimensions for the domains in the article. To create haze, the dimensions are within the range of from about 380 nm to about 720 nm. Once the range of dimensions is determined, a light absorbent composition can be found which absorbs light at a range of wavelengths that at least substantially covers the range of dimensions of the domains. In doing so, it has been found that the haze of the article can be substantially masked. Method for producing the article and for masking the haze are also provided.

Abstract: A container, according to various embodiments of the invention, includes a co-extruded, blow molded wall that comprises: (1) a first, inner surface layer, (2) a second, interior layer; and (3) a third layer. In one embodiment, the inner surface layer comprises an extrusion blow-molding-capable grade of PET; the second, interior layer comprises adhesive; and the third layer comprises a polyolefin and the regrind material from one or more containers similar to the blow molded container. In various embodiments, the third layer is an outer surface layer of the blow molded wall. Alternatively, the container may further comprise a fourth (e.g., exterior surface) layer that comprises a polyolefin. In other embodiments, the inner surface layer comprises an extrusion blow-molding-capable grade of PET; the second, interior layer comprises a barrier material, such as polyamide resin, EVOH, or a compatible oxygen scavenger; and the third layer comprises an extrusion blow-molding-capable grade of PET.

Abstract: To provide a water-soluble film roll 3 having end faces 4 with masking materials 5 adhered thereto. By using the water-soluble film roll 3 and paying out a water-soluble film 1 while holding the masking materials 5 adhered to the end faces 4, it is possible to prevent moisture from adhering to the end faces 4 and to prevent the water-soluble film 1 from rupturing due to welding of the film 1 with itself. In this connection, the masking materials 5 are preferably a plastic film capable of being adhered to the end faces 4 with a pressure-sensitive adhesive.

Abstract: An environmentally friendly plastic container that can be subjected to waste disposal with ease is proposed. The container is obtained by blow-molding a hollow preform, and the container itself is formed of a biodegradable plastic material.

Abstract: A barrier composite having reduced blocking is disclosed. The composite may include a substrate, a barrier layer formed from polyvinylidene chloride disposed on the substrate, and an anti-blocking layer disposed on the barrier layer. The anti-blocking layer may be formed from polyvinyl alcohol, and optionally, colloidal silica, wax, or a combination thereof. Alternatively, the anti-blocking layer may be formed from a polymeric carrier material, colloidal silica, and a wax. Methods for forming such composites and for forming a roll of such composites are also disclosed.

Abstract: Bottles made of metallocene polypropylene (mPP) for storage and dispensing reservoirs for fragrance compositions, in particular fragrance oils, are described. The mPP bottles can be used in warmer units for slow release dispensing of the fragrance therein. The metallocene polypropylene bottles can be produced by extrusion or injection blow molding, injection molding, injection stretch blow molding (single or two stage), or other suitable molding process. The mPP bottles may optionally have at least one barrier coating layer and/or adhering layer. The mPP bottles may optionally be fluorinated. The mPP bottles have good clarity and possess the required physical properties needed when the bottles are filled on a production line.

Abstract: A themolaminating film for receiving a blister portion in the construction of a reusable package is described. A base blister portion configured to receive some form of media or material is molded from a formable heat sealable polymer such as PETG. A film consisting of a first layer of an amorphous polyester such as APET for heat sealing to the PETG, a second layer of a polyester such as PET, and an adhesive layer is used to laminate a graphical paper based cover thereby allowing the laminated cover to be heat sealed to the blister portion. In a preferred embodiment, the PET and APET are preferably coextruded.

Abstract: A method of making a composition having the property of being able to store chlorine dioxide includes mixing an aqueous chlorine dioxide solution with a superabsorbent, water-soluble polymer that is substantially unreactive with chlorine dioxide and permitting a mixture formed thereby to form one of a gel and a solid composition. A method of delivering chlorine dioxide includes providing a gel or solid composition as described and degelling the gel or dissolving the solid composition to dispense the chlorine dioxide therefrom. A method of disinfecting a target such as water, wastewater, or a surface comprises delivering chlorine dioxide as above and permitting the polymer to precipitate out of the mixture. Aqueous chlorine dioxide is then recovered and applied to the target.

Abstract: A cushion comprised of at least one chamber comprised of a barrier material, said barrier material comprised of an elastomer, said elastomer being at least semi-permeable to at least a first reactant compound, a second reactant compound disposed within said at least one chamber, wherein said first reactant compound and said second reactant compound react to form a resultant compound, and wherein a rate of diffusion of said resultant compound through said barrier material is less than a rate of diffusion of said first reactant compound through said barrier material. An article of footwear including a cushion, said cushion comprised of at least one chamber comprised of a barrier material, at least a first and a second solid or liquid reactant compounds disposed within said at least one chamber, wherein said first reactant compound and said second reactant compound react to form a resultant gaseous compound.

Abstract: A multiple walled enclosure with low permeation properties and rugged impact resistance useful as a fuel tank or chemical container. The enclosure is made by rotomolding a first charge of thermosetting polymer into an outer layer, then rotomolding a charge of EVOH or other low permeation thermoplastic into a second layer, then rotomolding a second charge of thermosetting polymer into a third layer so that the low permeation thermoplastic layer is fully enclosed by layers of thermoset polymer. The preferred thermosetting polymer is crosslinkable polyethylene and the preferred low permeation thermoplastic is EVOH.

Abstract: Multilayer laminate compositions are provided wherein at least one layer of the laminate comprises a blend of a) an organic acid and ethylene/acid copolymer or ethylene/acid that are at least partially neutralized with a metal ion and b) an ethylene homopolymer or copolymer of ethylene and an alpha-olefin form at least one layer of a multilayer laminate. At least one other layer of the laminate is a gas impermeable composition consisting essentially of a material selected from the group consisting of polyvinylidene chloride, ethylene vinyl alcohol polymers, polyamides, metal foils, metallized films or liquid crystalline polyesters and mixtures thereof. The gas permeable layer is easily peelable and may be separated manually from the gas impermeable layer of the laminate. The laminates are useful in packaging applications, including manufacture of lid stock.

Abstract: A packaging laminate for a retortable packaging container, the packaging laminate (30) including a paper or paperboard layer (31), outer, liquid-tight coatings (32; 33) and an aluminium foil (34) serving as gas barrier between the paper or paperboard layer (31) and one of the two outer liquid-tight coatings (32). In order to compensate for or counteract possible loss of gas tightness because of crack formations or similar untightness in the tensile-sensitive aluminium foil (34), the packaging laminate (30) includes at least one additional layer (35) serving as gas barrier between the paper or paperboard layer (31) and the aluminium foil (34).

Abstract: A technique is provided for decreasing the delamination of multilayered containers formed by coinjection. The multilayered container comprises at least a layer of hydrophilic copolymer and a layer comprising a blend of a polyolefin and an anhydride modified polyolefin. Desirably, the hydrophilic copolymer forms the core layer and the blend of a polyolefin and an anhydride modified polyolefin form the outer skin layers. The containers are suitable for blood collection, however they may be used for other applications as well.

Abstract: A self-adhesive flexible sealing tape, especially on a butyl or acrylic base, possibly a butyl rubber base, intended for sealing purposes and so designed that both the sealing tape and the carrier foil applied to the sealing tape are capable of being stretched, thus enabling the carrier tape to follow the stretching state of the sealing tape.

Abstract: The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in a rigid container, especially a bottle, a tray, a carton, a lidstock associated with a tray, a stand up pouch, or a paperboard container. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of bottled products, and modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package.

Abstract: A plastic, easy-opening closure for a retortable container and a method for sealing are provided. The closure includes a plastic membrane having an outer layer of polypropylene, a first tie layer, an intermediate layer formed of EVOH, a second tie layer, an inner layer formed of polypropylene, and a peel-seal layer. The peel-seal layer can be formed of high density polyethylene or polypropylene with a contaminant dispersed therein so that the closure can be easily removed from the container for opening.

Abstract: Multilayered laminate films for food packaging applications which comprise at least: (a) a layer of oriented or nonoriented polyester terephthalate or oriented or nonoriented polypropylene, (b) a layer comprising at least one metal, and (c) a layer comprising at least one additive suitable for incidental food contact which provides protection against corrosion to a layer containing at least one metal is described.

Abstract: To attain a multilayer tube excellent in chemical resistance, gas barrier property, and cleanness, the present invention provides a multilayer tube (1) comprising: a first layer (10) composed of a fluororesin; and a second layer (30) covering one surface of the first layer (10) and composed of a polyamide-based resin free of an additive.

Abstract: This invention relates to articles made of polyester, preferably polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of thermoplastic material with good gas-barrier characteristics, and novel methods of making such articles. Preferably the barrier-coated articles take the form of preforms coated by at least one layer of barrier material and the containers blow-molded therefrom. Such barrier-coated containers are preferably of the type to hold beverages such as soft drinks, beer or juice. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET as well as key physical properties similar to PET. The materials and methods provide that the barrier layers have good adherence to PET, even during and after the blow molding process to form containers from preforms. Preferred barrier coating materials include poly(hydroxyamino ethers).

Abstract: A resin container is provided which has a container body and a lid for closing the container body. The container body of the resin container is produced by injection-molding an amorphous thermoplastic resin. The container body form has a peripheral rise portion and a recessed flat portion defined by the peripheral rising portion. The peripheral rise portion has a height of 0.5 to 10 mm, and the recessed flat portion has an area of 1 to 100 cm2, an average wall thickness of not more than 0.25 mm and a flatness of not more than 0.5 mm.

Abstract: A multilayer thermoplastic film, and packages made from the film, comprising a layer of ethylene vinyl alcohol (EVOH) as an oxygen barrier layer, a layer of a polymer or copolymer formed by the polymerization reaction with a single site catalyst and ethylene vinyl acetate (EVA) as a sealant layer, and alternatively containing a layer of EVA, said film having improved sealability and improved clarity as compared to conventional films.