Vapor Or Gas Barrier, Polymer Derived From Vinyl Chloride Or Vinylidene Chloride, Or Polymer Containing A Vinyl Alcohol Unit Is Sandwiched Between Layers (continuous Layer) Patents (Class 428/36.7)
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Patent number: 8263206Abstract: The invention relates to a perforated film composition, comprising at least three layers, and wherein at least one layer is a inner layer with a softening and/or melting temperature, lower than the respective softening and/or melting temperatures of at least two outer layers, located at opposite surfaces of the inner layer, and where upon exposure to elevated temperature, the inner layer softens or melts to such an extent, that upon exposure to a compression force, a sufficient number of perforations seal in the inner layer, to impart an increased moisture barrier to the overall film composition. The invention also relates to a method of forming such a perforated film composition, packages prepared from the same, and a method of filling packages prepared from the perforated film composition.Type: GrantFiled: July 7, 2006Date of Patent: September 11, 2012Assignee: Dow Global Technologies LLCInventors: Kurt Kronawittleithner, Herbert Bongartz, Anne Descheemaeker
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Publication number: 20120219670Abstract: A method of manufacturing a multilayer or a monolayer plastic container is disclosed. The container has a barrier layer manufactured from (i) a polyester resin, preferably an aromatic polyester resin such as a polyethylene terephthalate, (ii) a polyamide material, preferably an aromatic polyamide material, and (iii) an oxygen scavenging material, preferably a transition method. The present invention also provides containers having a multilayer or a monolayer body. In the preparation of the barrier layer. a preform first is prepared by an injection-molding process wherein a preblend containing a diluent polyester, polyamide material, and an oxygen scavenging material is added to a base polyester during the injection molding process. The preform then is expanded to form a container.Type: ApplicationFiled: May 9, 2012Publication date: August 30, 2012Applicant: VALSPAR SOURCING, INC.Inventors: Paul E. Share, Keith Pillage
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Patent number: 8247051Abstract: A coating composition is provided for use in laminate substrates useful in packaging of liquids and solids where the coating provides and increased resistance to the permeability of gases such as oxygen and carbon dioxide. In one embodiment the coating composition is a dispersion or a solution that comprises at least one hydroxyl functional polyetheramine, phosphoric acid and a defoamer. The backbone of the polyetheramine has diglycidyl ether linkages that comprise about 5 to about 70 mole percent resorcinol diglycidyl ether. The coating composition can be applied to substrates by coating applications such as spraying, rolling reverse and direct, rolling direct and reverse gravure, kiss coat, flow coating, brushing, dipping and curtain-wall coating, for example.Type: GrantFiled: August 1, 2006Date of Patent: August 21, 2012Assignee: The Glidden CompanyInventors: Daniel Bode, Cathy Li, Kenneth J. Gardner
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Publication number: 20120177857Abstract: The invention describes a flexible tubular article for transport of volatile hydrocarbons comprising: (a) an inner layer of a polyvinylidene difluoride (PVDF) polymer or a polyvinylidene difluoride copolymer; (b) an intermediate thermoplastic polyurethane (TPU) layer extruded in tubular form over the inner PVDF layer, and (c) a polyvinyl chloride polymer extruded in tubular form over the outside surface of the intermediate layer and being coextensive therewith. The tubular articles of the invention have a maximum permeation rating of 15 g/m2/day under SAE J1737 test conditions.Type: ApplicationFiled: January 9, 2012Publication date: July 12, 2012Inventors: Wayne Edward Garver, Mark Fisher Colton
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Patent number: 8211519Abstract: A composition for forming a gas-barrier material, comprising a polycarboxylic acid-type polymer (A) and at least a bifunctional alicyclic epoxy compound (B). The composition for forming a gas-barrier material features excellent gas-barrier property, retort resistance and flexibility, can be cured at a low temperature in a short period of time without affecting the plastic base material, and contributes to improving the productivity.Type: GrantFiled: January 9, 2008Date of Patent: July 3, 2012Assignees: Toyo Seikan Kaisha, Ltd., Kansai Paint Co., Ltd.Inventors: Yusuke Obu, Hiroshi Sasaki, Kashiko Kawai, Hideki Masuda, Hideki Matsuda, Naoki Horike, Takahiro Hidaka, Koichi Tamura
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Patent number: 8210390Abstract: Container with an opening and closing element (5) for wine or a similar beverage, comprising three distinct elements (2-4) made of plastic and assembled by welding, these being a flexible laminate (2) that forms the side wall of the said container, an end wall (4) and a shoulder (3) comprising a neck; characterized in that at least one of the three elements (2-4) is oxygen impermeable and in that at least one other element (2-4) is oxygen permeable.Type: GrantFiled: November 27, 2007Date of Patent: July 3, 2012Assignee: Aisapack Holding S.A.Inventors: Jacques Thomasset, Stéphane Mathieu
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Patent number: 8206799Abstract: The invention relates to a stretched plastic tube obtainable from a polymer composition comprising a copolyester elastomer, and comprising two end-parts and an elongated part between the end-parts wherein at least one end-part is a stretched end-part obtained by mechanically stretching of at least a section of that end part, characterized in that the stretched end-part comprises an outer surface layer area consisting of a first thermoplastic polymer composition (A) comprising a first copolyester elastomer (A-1) and 0-0.2 wt. % carbon black relative to the total weight of the thermoplastic polymer composition (A). The invention also relates to a Plastic tube obtainable from a polymer composition comprising a copolyester elastomer, wherein the plastic tube is a plastic tube comprising: (i) an outer surface layer consisting of a first thermoplastic polymer composition (A) comprising a first copolyester elastomer (A-1) and 0-0.2 wt.Type: GrantFiled: January 16, 2007Date of Patent: June 26, 2012Assignee: DSM IP Assets B.V.Inventors: Lambert Van Lumig, Jacob Koenen, Dirk G. Blom, Paul W. J. Van Den Heuvel
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Patent number: 8178180Abstract: The invention relates to a heat-sealable packaging material and a sealed package formed from the same, especially for packaging foodstuffs. The packaging material comprises a base layer of paper or board and polymeric heat-sealable layers on one side of the base layer or, preferably, on both sides thereof. According to the invention, at least two layers of ethylene vinyl alcohol copolymer (EVOH) with different fractions of ethylene monomer are arranged on the packaging material to provide an oxygen barrier. The layers can locate against each other without a tie layer between them. The heat-sealable polymer can be a polyolefin, and, in addition, other polymeric barrier layers can be incorporated into the material to improve its oxygen, fat and aroma tightness.Type: GrantFiled: July 26, 2007Date of Patent: May 15, 2012Assignee: Stora Enso OyjInventors: Tapani Penttinen, Kimmo Nevalainen
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Patent number: 8137780Abstract: A plastic hollow body, in particular plastic pipe, the wall of which is constructed from cylindrical layers bonded to one another, wherein at least one layer is a layer made of a thermosetting material produced in the centrifugal process and the plastic hollow body includes multiple layers of thermosetting material and multiple layers of thermoplastic material.Type: GrantFiled: October 27, 2005Date of Patent: March 20, 2012Assignee: Knoch, Kern & Co.Inventors: Guntram Bock, Jürgen Miethlinger, Rainer Borth
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Patent number: 8133417Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.Type: GrantFiled: April 29, 2011Date of Patent: March 13, 2012Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
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Patent number: 8124204Abstract: There is provided a multilayer bottle comprising a barrel portion including an outermost layer, an innermost layer and at least one barrier layer interposed between the outermost layer and the innermost layer, which satisfies the requirements represented by the following formulae (1) to (3) at the same time: OTR?0.2 cc·mm/(m2·day·atm)??(1) where OTR represents an average oxygen transmission rate of the barrier layer of the barrel portion; 20?(Average degree of orientation of barrier layer of barrel portion)?45; and??(2) 0?b/a×100?200??(3) where “a” represents an average thickness (?m) of the barrier layer of the barrel portion; and “b” represents an average thickness (?m) of the barrier layer of a bottom portion of the bottle. The multilayer bottle is free from delamination owing to impact upon dropping even when the bottle is formed with irregularities and bends and therefore exhibits a large freedom of design choice.Type: GrantFiled: July 6, 2006Date of Patent: February 28, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Jun Mitadera, Tomomichi Kanda, Kazunobu Maruo, Masashi Kurokawa
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Patent number: 8124208Abstract: A multi-layer tube containing: (1) a barrier layer made of laminated fluoro resin, and (2) at least one outer layer. The barrier layer has a thickness no greater than 20% of the average thickness of the multi-layer tube, and consists of a homo polymer of chlorotrifluoroethylene having a melting point no greater than 220° C., a melt flow rate (MFR) between 0.1 and 10 g/10min at a temperature of 230° C., and a tensile modulus between 750 and 1500 MPa. The outer layer consists of a styrene elastomer. Optionally, an oxygen barrier layer is included between the outer layer and the barrier layer. The barrier layer and the outer layer are integrally laminated with each other by forming the barrier layer and the outer layer in a co-extrusion manner with an adhesive resin being interposed between the barrier layer and the outer layer.Type: GrantFiled: April 20, 2009Date of Patent: February 28, 2012Assignee: Kyoraku Co., Ltd.Inventors: Takehiko Sumi, Tetuaki Eguchi, Daisuke Yamazaki
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Patent number: 8119082Abstract: Plastic test tube for taking blood samples, comprising a hollow tubular body and an adhesive protective film able to adhere to the tubular body. The tubular body is made of polyethylene terephthalate and has: a tubular wall which delimits a working volume and defines an outer surface; an open mouth for insertion of liquids at a first end of the wall; and a bottom for closing a second end of the wall. The adhesive protective film is able to adhere to the wall of the tubular body over at least a portion of the outer surface. The test tube is characterized in that the wall of the tubular body has a thickness in the range of 1 to 3 mm and in that the protective film is defined by a layer of polypropylene, polyethylene or copolymers thereof. The layer has a thickness in the range of between 40 and 60 ?m and is able to form a liquid barrier.Type: GrantFiled: December 6, 2006Date of Patent: February 21, 2012Assignee: Vacutest Kima S.r.l.Inventors: Renzo Chiarin, Ulisse Chiarin
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Patent number: 8101255Abstract: A motor vehicle fuel conveying multi-layer co-extruded tube (1) comprising at least an innermost first layer (2) of a polyamide resin (P9T) consisting of a dicarboxylic acid component and a diamine component, wherein 60÷100% of the dicarboxylic acid component is terephthalic acid and 60÷100% of the diamine component is selected from 1,9-nonanediamine and 2-methyl-1,8-octanediamine; an intermediate second layer (3) of polyamide 6 (PA 6); an intermediate co-polyamide (CoPA)-based tie layer (4); and an external fourth layer of polyamide 12 (PA12).Type: GrantFiled: September 26, 2006Date of Patent: January 24, 2012Assignee: Dytech-Dynamic Fluid Technologies S.p.A.Inventors: Roberto Defilippi, Mario Zasa
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Publication number: 20120015122Abstract: A molded multi-layer article has an interior layer contained within inner and outer layers. The article is molded by co-injecting the inner, outer, and interior layer materials into a mold defining a cavity. The interior layer material is caused to flow along a steam line offset from the zero velocity gradient of the combined material flow in a manner so that the interior layer material flow stream does not flow along or cross the zero velocity gradient yet has a greater flow velocity than the average flow velocity of the combined flow front. These methods and apparatus can mold four or more multilayer articles at once, each having an interior layer extending throughout 95% or more of the sealable portion of the article. The interior layer of a resultant article can extend throughout 99% or more of the sealable portion of the article.Type: ApplicationFiled: July 15, 2011Publication date: January 19, 2012Applicant: KORTEC, INC.Inventor: Paul M. Swenson
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Patent number: 8092877Abstract: The present invention relates to polymer structures such as thermoplastic films having improved aroma barrier properties and methods for making the polymeric structures, which may be in the form of a resealable container. Aroma barrier is improved by incorporating a barrier layer of polymeric material including at least about 10 mole percent of polymerized cyclo-olefin moieties.Type: GrantFiled: April 1, 2003Date of Patent: January 10, 2012Assignees: Topas Advanced Polymers, Inc., Pactiv CorporationInventors: Randy D. Jester, Barbara Canale-Schmidt, William P. Belias, Paul N. Chen
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Patent number: 8092880Abstract: A fuel hose includes a laminated structure of a tubular resin layer and an adjoining rubber layer, the rubber layer being formed by a rubber composition containing the following (A) to (F) as essential components, and the resin layer being formed by a material containing a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer or a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride-perfluoroalkyl vinyl ether quaterpolymer as a main component: (A) a blend of acrylonitrile-butadiene rubber and polyvinyl chloride; (B) at least one selected from the group consisting of 1,8-diazabicyclo[5.4.0]undecene-7 salt, 1,5-diazabicyclo[4.3.0]nonene-5 salt, 1,8-diazabicyclo[5.4.0]undecene-7 and 1,5-diazabicyclo[4.3.0]nonene-5; (C) zeolite; (D) magnesium oxide; (E) laminar mineral; and (F) basic silica.Type: GrantFiled: March 23, 2007Date of Patent: January 10, 2012Assignee: Tokai Rubber Industries, Ltd.Inventors: Shinji Iio, Kazutaka Katayama, Hiroaki Ito
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Patent number: 8075964Abstract: The presently disclosed subject matter is directed to a barrier film that maintains an oxygen barrier after being subjected to autoclaving conditions. The film comprises one EVOH layer positioned as a core layer, and one EVOH layer positioned directly adjacent to an outer layer comprising highly permeable material having a moisture vapor permeability greater than about 40 g-mil/100 in2-day-atm. During autoclaving, the barrier properties of the EVOH layer positioned adjacent to the outer layer allows improved recovery of oxygen barrier properties. In addition, during rewetting applications, the internal EVOH layer maintains the oxygen barrier. Also disclosed are methods of making and using the disclosed barrier film.Type: GrantFiled: June 24, 2008Date of Patent: December 13, 2011Assignee: Cryovac, Inc.Inventors: Walter B Mueller, Patrick W. Thompson
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Patent number: 8053051Abstract: To provide an oxygen-absorbing barrier resin composition which has excellent oxygen-barrier properties even under high-humidity conditions and can give a multilayer structure having excellent peel strength; an oxygen-absorbing barrier film comprising the oxygen-absorbing barrier resin composition; a multilayer structure including a layer comprising the oxygen-absorbing barrier film; and a packing container comprising the multilayer structure. The oxygen-absorbing barrier resin composition comprises a resin (A) having an oxygen permeability of at most 100 cc/m2-day-atm and a resin (B) having an oxygen absorption rate of at least 0.001 cc/cm2·day, wherein the resin (B) is dispersed in the matrix of the resin (A) and the resin (B) is in the form of rods in which the average of the maximum diameters of cross sections perpendicular to the lengthwise direction is at most 1.0 ?m.Type: GrantFiled: October 27, 2006Date of Patent: November 8, 2011Assignee: Zeon CorporationInventors: Shizuo Kitahara, Mako Kurakata, Jun Ishihara
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Patent number: 8039073Abstract: The present invention relates to a preformed liner of tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer adhered to the surface of a pipe, and in particular, an oil well pipe, without the need for either a primer layer or an adhesive. The liner comprises an effective amount of metal powder which provides adhesion between the liner and the surface of the pipe. The present invention also relates to a process for making such pipe, where in a preferred embodiment, the liner is co-extruded to form an inner layer and an outer layer. This co-extrusion embodiment is particularly useful in applications where high purity is necessary. In this case, the inner layer comprises an effective amount of metal powder and the outer layer is pure tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer.Type: GrantFiled: December 18, 2006Date of Patent: October 18, 2011Assignee: E.I. du Pont de Nemours and CompanyInventor: Jacob Lahijani
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Patent number: 8039070Abstract: A heat-shrinkable film suitable for forming an easy opening cook-in bag is provided. The film comprises at least five layers, including an inner layer, an inner frangible layer, a barrier layer, an outer frangible layer, and an outer layer. The film is capable of being formed into a bag comprising a lap seal, a top end seal, and a bottom end seal, wherein the seals are heat sealed to a closed condition to contain and protect a product disposed therein. The lap seal, top end seal, and bottom end seal each are able to remain sealed during cook-in conditions. Additionally, the lap seal, top end seal, and bottom end seal each are peelable and easily openable by application of force.Type: GrantFiled: January 21, 2009Date of Patent: October 18, 2011Assignee: Curwood, Inc.Inventors: Bradley Thomas Sawall, Thomas Andrew Schell, Benjamin Ray Stover
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Patent number: 8025973Abstract: The invention relates to the papermaking art and, in particular, to the manufacture of paper substrates, paper-containing articles such as multilayered paper or paperboard packaging, containing a fluorine-containing compound and having enhanced glueability and/or grease resistance.Type: GrantFiled: July 24, 2006Date of Patent: September 27, 2011Assignee: Internatonal Paper CompanyInventors: Richard F Rudolph, Timothy J Bradford, Barry Chapman, Pat Morabito
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Patent number: 7981492Abstract: Multilayer laminates useful in packaging of respiring food products and packages made therefrom. The laminates have a CO2 permeability rate of at least about 10 cm3/100 in2/24 hours and an O2 permeability rate of less than about 5.3 cm3/100 in2/24 hours.Type: GrantFiled: October 28, 2008Date of Patent: July 19, 2011Assignee: Exopack, LLCInventor: Jay D. Hodson
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Patent number: 7976919Abstract: A multilayer blow molded container having a layer structure that a polyglycolic acid layer is provided as a core layer, and thermoplastic polyester resin layers are arranged as inner and outer layers, wherein the core layer formed of the polyglycolic acid layer is not present between the inner and outer layers in at least part of an opening end portion of the container, and the core layer formed of the polyglycolic acid layer is not present between the inner and outer layers in at least part of a bottom of the container, wherein the melt viscosity x of a polyglycolic acid forming the polyglycolic acid layer is 300 to 900 Pa·s as measured at a temperature of 270° C. and a shear rate of 122 sec?1, the melt viscosity y of a thermoplastic polyester resin forming the thermoplastic polyester resin layers is 250 to 600 Pa·s as measured at a temperature of 290° C. and a shear rate of 122 sec?1, and a melt viscosity ratio x/y between both melt viscosities is 0.85 to 1.80, and a production process thereof.Type: GrantFiled: March 31, 2006Date of Patent: July 12, 2011Assignee: Kureha CorporationInventors: Takashi Sato, Satoru Suzuki, Daisuke Itoh
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Patent number: 7968164Abstract: Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.Type: GrantFiled: February 27, 2006Date of Patent: June 28, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Spencer Allen Gilliam, Marcus David Shelby
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Patent number: 7968163Abstract: A can that features superior resistance against puncture under higher puncture strength, and superior resistance against flange cracking. The resin-coated aluminum seamless can body of the present invention features superior resistance against cracks in the can wall during distribution, and resistance against flange cracking, wherein the inner and/or outer surface of the can of the aluminum seamless can 10 is coated with a layer of thermo-plastic resin, the thickness of the thermoplastic resin layers of the inner surface and the outer surface is a total of 2-50 ?m, with a minimum thickness of the aluminum plate of the side wall of the can 0.Type: GrantFiled: June 22, 2004Date of Patent: June 28, 2011Assignee: Toyo Seikan Kaisha, LtdInventors: Yasufumi Tadaki, Nobuo Tsuchiya, Kazuhiro Nishida, Seitaro Kanazawa
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Patent number: 7964258Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.Type: GrantFiled: February 27, 2006Date of Patent: June 21, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Mark Edward Stewart, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Marcus David Shelby
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Patent number: 7959836Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze, and comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.Type: GrantFiled: March 28, 2006Date of Patent: June 14, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Mark Edward Stewart, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell, Marcus David Shelby
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Patent number: 7959998Abstract: Disclosed are oxygen-scavenging polymer compositions having high transparency and low haze comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, a copolyamide or a transamidized, homogeneous blend of a least two polyamides, and a metal catalyst. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties.Type: GrantFiled: March 28, 2006Date of Patent: June 14, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Mark Edward Stewart, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell, Marcus David Shelby
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Patent number: 7959995Abstract: A deep drawing heat shrinkable multilayer film includes: an intermediate layer made of a vinylidene chloride copolymer resin (a); and a resin layer made of a first thermoplastic resin (b) layered on at least one surface of the intermediate layer. The multilayer film has hot water shrinkabilities in longitudinal and transverse directions at a temperature of 90° C. range from 3% to 35% respectively.Type: GrantFiled: March 30, 2007Date of Patent: June 14, 2011Assignee: Kureha CorporationInventors: Hitoshi Ishii, Seiichi Ibe
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Patent number: 7955674Abstract: Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of at least one polyester comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.Type: GrantFiled: March 28, 2006Date of Patent: June 7, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Spencer Allen Gilliam, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell, Marcus David Shelby
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Patent number: 7955533Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.Type: GrantFiled: February 27, 2006Date of Patent: June 7, 2011Assignee: Eastman Chemical CompanyInventors: Wesley Raymond Hale, Thomas Joseph Pecorini, Mark Edward Stewart, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Marcus David Shelby
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Patent number: 7943218Abstract: A multi-layer film with barrier properties having two or more layers made from a bio-based film is disclosed. In one aspect, the print web comprises a bio-based film. In one aspect, the barrier web comprises a bio-based film. In one aspect, a bio-based adhesive adheres the print web to the barrier web. The bio-based film can include paper, PCR, polylactide or polyhydroxy-alkanoate. Unlike prior art petroleum-based films, the bio-based film of the present invention is made from a renewable resource and is biodegradable.Type: GrantFiled: February 14, 2008Date of Patent: May 17, 2011Assignee: Frito-Lay North America, Inc.Inventors: Anthony Robert Knoerzer, Kenneth Scott Laverdure, Brad Dewayne Rodgers
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Patent number: 7943215Abstract: For the packaging of consumables and feed stuffs, which are to be protected from oxygen, however emit moisture, a multilayer foil is proposed, which includes at least one blocking layer and one sealing layer. The blocking layer is characterized by a high barrier function for gas, in particular oxygen, and a good water vapor permeability. The sealing layer ensures good sealing characteristics and a high water vapor permeability.Type: GrantFiled: March 26, 2008Date of Patent: May 17, 2011Assignees: Hans Alder OHGInventor: Klaus Josef Hoegg
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Patent number: 7938283Abstract: Systems and methods for protected transportation of agricultural commodities are provided. The protected transportation is accomplished through the use of a thin, lightweight hermetic liner inside a shipping container. The liner is sealed at a first end and open at a second end, and the liner is positioned within the shipping container with the sealed first end at a back end of the shipping container and the second open end at a front, open end of the shipping container. A top portion of the liner is held to the ceiling of the shipping container via an attachment mechanism or via inflation of the liner and/or ribs in the liner. The bagged or bulk commodity is introduced through the open end and into the liner. The liner is then hermetically sealed, and the container is closed. After shipping, the agricultural commodity may be removed by unsealing the liner.Type: GrantFiled: June 20, 2008Date of Patent: May 10, 2011Assignee: Grainpro, Inc.Inventors: Philippe Villers, Tom de Bruin, Shlomo Navarro
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Patent number: 7939152Abstract: A heat-shrinkable anti-fomitic device in the form of a bag or tube forms a cover for an object which prevents cross-infection by bacteria and other pathogens that may reside on the object. The heat-shrinkable anti-fomitic device can have a sterile interior that is sealed or stored flat during manufacture to maintain sterility. Therefore, no outer wrapping for the anti-fomitic device is required. The anti-fomitic device is inverted when used to cover the object and results in an ultimate outer surface that is initially sterile. A plurality of such devices can be heat shrunk to an object such that removal of the outer layer will prevent cross contamination. Heat shrink film materials for the coverings/bags serve as a barrier to the transmission of pathogens.Type: GrantFiled: May 30, 2008Date of Patent: May 10, 2011Assignee: M-Tech CorporationInventors: Marvin E. Haskin, Jon L. Roberts, Christopher B. Kilner
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Publication number: 20110104342Abstract: A chlorine-free packaging sheet having a first rigid component, a second rigid component and a multilayer film positioned between the first rigid component and the second rigid component, a package comprising such packaging sheet and a method of manufacturing such sheet. The packaging sheet has a normalized combined tear initiation and propagation resistance in both the machine direction and the transverse direction of less than about 0.115 in*lbf/mil energy to break and less than about 0.800%/mil elongation, and a normalized tear propagation resistance in both the machine direction and the transverse direction of less than about 0.300 in*lbf/mil energy to break and less than about 0.145 lbf/mil peak load.Type: ApplicationFiled: November 3, 2009Publication date: May 5, 2011Inventors: Kevin David Glaser, Matthew LeRoy Mengel, Curtis Randolph Barr
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Patent number: 7927678Abstract: There is provided a multilayer bottle including an outermost layer and an innermost layer which are each made of a thermoplastic polyester resin, and at least one barrier layer interposed between the outermost layer and the innermost layer. The barrier layer contains at least two components including a polyamide obtained by polycondensing a diamine component containing m-xylylenediamine as a main component with a dicarboxylic acid component containing an ?,?-linear aliphatic dicarboxylic acid as a main component, and a thermoplastic resin having a lower molecular weight than that of the polyamide. The multilayer bottle hardly suffers from delamination upon impact or dropping and, therefore, is not required to have a shape with less irregularities or less bends for preventing the delamination, and further has a large freedom of design choice.Type: GrantFiled: December 21, 2006Date of Patent: April 19, 2011Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Jun Mitadera, Tomomichi Kanda, Kazunobu Maruo, Masashi Kurokawa
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Patent number: 7906217Abstract: A vapor deposited film is formed on a base material surface by a plasma CVD method where an organic metal compound and an oxidizing gas are used as a reactive gas. The vapor deposited film has three sections of a base material side adhesive layer having 5% or more carbon, a barrier intermediate layer having less than 5% carbon, and a surface protection film having 5% or more carbon, by element concentration with respect to the total amount of three elements of a metal element (M), oxygen (O) and carbon (C) derived from the organic metal compound. The vapor deposited film has excellent adhesiveness to the base material, and has excellent resistance to water, especially to alkaline aqueous solutions, as well.Type: GrantFiled: February 7, 2006Date of Patent: March 15, 2011Assignee: Toyo Seikan Kaisha, Ltd.Inventors: Hajime Inagaki, Toshihide Ieki, Satoru Kitou, Ryuta Nakano, Megumi Nakayama
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Publication number: 20110049146Abstract: The use of a colloidal silica having a specific surface area greater than 300 m2/g in a gas barrier coating additionally comprising polyvinyl alcohol and/or ethylene vinyl alcohol copolymer and/or a silylated derivative thereof improves wet bond strength.Type: ApplicationFiled: May 19, 2009Publication date: March 3, 2011Applicant: Sun Chemical B.V.Inventors: Derek Ronald Illsley, Graham Trevor Street
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Patent number: 7887894Abstract: A packaging bag and a drying agent with a moisture absorption indicator function are provided without using a heavy metal harmful to the human body. The packaging bag includes a first packaging material (10) and a second packaging material (20). The first packaging material (10) is provided on an outermost side thereof with a transparent barrier film (12) having a barrier property against water vapor. The second packaging material (20) has a light-reflective or light-absorbing film (24) and a pattern printed layer (23) overlaid on a bag interior side thereof, the pattern printed layer (23) having a printed moisture-absorbing indicator pattern (30). A desiccant-containing resin film (11, 21) which becomes transparent due to moisture absorption is overlaid on a bag interior side of at least one of the first packaging material (10) and the second packaging material (20).Type: GrantFiled: February 3, 2006Date of Patent: February 15, 2011Assignee: Kyodo Printing Co., Ltd.Inventors: Eisuke Chiba, Tatsuya Ogawa, Hiroshi Koyama, Shinichi Koizumi
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Patent number: 7879396Abstract: We have developed an improved vapor-phase deposition method and apparatus for the application of layers and coatings on various substrates. The method and apparatus are useful in the fabrication of biotechnologically functional devices, Bio-MEMS devices, and in the fabrication of microfluidic devices for biological applications. In one important embodiment, oxide coatings providing hydrophilicity or oxide/polyethylene glycol coatings providing hydrophilicity can be deposited by the present method, over the interior surfaces of small wells in a plastic micro-plate in order to increase the hydrophilicity of these wells. Filling these channels with a precise amount of liquid consistently can be very difficult. This prevents a water-based sample from beading up and creating bubbles, so that well can fill accurately and completely, and alleviates spillage into other wells which causes contamination.Type: GrantFiled: January 31, 2005Date of Patent: February 1, 2011Assignee: Applied Microstructures, Inc.Inventors: Boris Kobrin, Jeffrey D. Chinn, Romuald Nowak, Richard C. Yi
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Patent number: 7875330Abstract: A synthetic resin multilayer structure (1) delimited by a top face (2), borders (3, 5) and a bottom face (4) of surface area substantially identical to that of the top face (2), said structure (1) comprising: a first layer (6) defining said faces (2, 4) and said borders (3, 5), a second layer (7), disposed between said faces (2, 4) and said borders (3, 5), of surface area at least equal to that of said faces (2, 4), characterized in that the second layer (7) forms at least one zigzag-shaped double fold (8, 9).Type: GrantFiled: February 26, 2005Date of Patent: January 25, 2011Assignee: Aisapack Holding S.AInventor: Jacques Thomasset
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Patent number: 7862869Abstract: The present invention provides a flexible multilayer packaging film and packages formed therefrom wherein the films include a first film layer comprising a first biaxially-oriented polymer selected from the group consisting of a polyester, a polyolefin, a polyamide, and a blend thereof and a surface-roughened portion, a second film layer comprising an adhesive, a third film layer comprising a barrier material, a fourth film layer comprising a second biaxially-oriented polymer selected from the group consisting of a polyester, a polyolefin, a polyamide, and a blend thereof and at least one score-line; wherein the packages comprise a tear-initiation area and a directional tear zone.Type: GrantFiled: October 20, 2003Date of Patent: January 4, 2011Assignee: Milprint, Inc.Inventors: Daniel S. Papenfuss, Michael Scott Hartman, Amy Lynn Kraimer, Sam Edward Wuest
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Publication number: 20100323140Abstract: A multilayered container with excellent heat resistance which is obtained by melt molding and has an interlayer made of an oxygen-absorbing barrier resin composition. The multilayered container comprises inner and outer layers comprising an olefin resin and, sandwiched between the inner and outer layers, an interlayer made of an oxygen-absorbing barrier resin composition. The multilayered container is one formed by melt molding. In thermal analysis of a container barrel part, it has a quantity of heat of isothermal crystallization after heating from 30° C. to 130° C. at 100° C./min of 0.5 J/g or larger. In the analysis, the barrel part, after cooling from 200° C. to 130° C. at 100° C./min, gives an isothermal crystallization profile in which the time period to a peak top is shorter than that in a multilayered container including an interlayer consisting only of the base resin (oxygen-barrier resin) constituting the oxygen-absorbing barrier resin composition.Type: ApplicationFiled: December 5, 2007Publication date: December 23, 2010Applicant: Toyo Seikan Kaisha, Ltd.Inventors: Takayuki Ishihara, Atsushi Kikuchi, Hiroaki Gotou, Shinji Tanaka, Kengo Matsumoto
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Patent number: 7851036Abstract: A shoe is fabricated from an upper structure and a sole structure wherein the sole structure contains a gas-filled cushioning device composed of a multi-layer film formed into a gas-filled membrane having an interior compartment enclosing at least one capture gas. The multi-layer film comprises an outer layer of an elastomeric thermoplastic material such as a polyurethane, an inner layer of an elastomeric thermoplastic material such as a polyurethane and a barrier layer interposed therebetween which is derived from a combination of at least one ethylene-vinyl alcohol copolymer and up to about 50 wt. % of an aliphatic thermoplastic urethane.Type: GrantFiled: February 20, 2004Date of Patent: December 14, 2010Assignee: BASF Coatings GmbHInventors: Henry W Bonk, David Goldwasser
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Patent number: 7820261Abstract: The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.Type: GrantFiled: June 26, 2007Date of Patent: October 26, 2010Assignee: Kuraray Co., Ltd.Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Mizuho Maeda
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Patent number: 7811669Abstract: There are provided a gas barrier laminated film, which is transparent while possessing excellent gas barrier properties and, at the same time, has excellent impact resistance, and a process for producing the same. The gas barrier laminated film comprises a base material, a vapor deposited film of an inorganic oxide provided on the base material, and a gas barrier coating film provided on the vapor deposited film. The gas barrier laminated film is characterized in that the base material on its side where the vapor deposited film is provided, has been subjected to pretreatment or primer coating treatment, and the gas barrier coating film has been formed by coating a gas barrier coating liquid onto the inorganic oxide film and then heating the coating.Type: GrantFiled: August 15, 2005Date of Patent: October 12, 2010Assignee: Dai Nippon Printing Co., Ltd.Inventors: Hitoshi Fujii, Norio Akita, Ayumi Shibata, Daidou Chiba, Koichi Mikami, Hisashi Sakamoto
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Patent number: 7811644Abstract: An insulating beverage cup is produced with an air containing film layer disposed on an inner surface of a food or beverage paper stock. The air containing film layer is extruded or laminated to the paper stock. An additional extruded or laminated layer is applied between the air containing film layer and paper stock layer. The insulating coating layer decreases the energy transfer between the beverage and the user's hands allowing the user to hold onto the cup for an extended period of time without causing user discomfort or pain. The exterior surface of the beverage cup remains highly printable and predisposed to high quality graphics.Type: GrantFiled: April 5, 2002Date of Patent: October 12, 2010Assignee: Appleton Papers Inc.Inventors: John Charles DeBraal, John MacKay Lazar
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Patent number: 7811646Abstract: Provided is a modified ethylene-vinyl alcohol copolymer (C) having an ethylen content of 5 to 55 mol %, which contains a specific structural unit (I) in an amount of 0.3 to 40 mol % and may be obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) having a molecular weight of not more than 500. This can be produced by a method for producing the modified ethylene-vinyl alcohol copolymer (C) which comprises melting and kneading an ethylene-vinyl alcohol copolymer (A) with a monofunctional epoxy compound (B) in an extruder. The modified ethylene-vinyl alcohol copolymer (C) is superior to a unmodified ethylene-vinyl alcohol copolymer (A) in transparency, stretchability, flexibility and flexing resistance due to the specific structural unit (I) incorporated therein, and thus, can be used as a barrier material in various applications requiring the above performance capabilities.Type: GrantFiled: May 13, 2002Date of Patent: October 12, 2010Assignee: Kuraray Co., Ltd.Inventors: Kaoru Ikeda, Shinji Tai, Kouta Isoyama, Tomoyuki Watanabe