Vapor Or Gas Barrier, Polymer Derived From Vinyl Chloride Or Vinylidene Chloride, Or Polymer Containing A Vinyl Alcohol Unit Is Sandwiched Between Layers (continuous Layer) Patents (Class 428/36.7)
  • Patent number: 7473451
    Abstract: A fuel container with high fuel barrier properties is provided. The fuel container is a coextrusion blow-molded fuel container having a container body made of a layered structure. The layered structure comprises: a barrier layer made of a barrier resin (A); and an inner layer and an outer layer made of a thermoplastic resin (B) that is different from the barrier resin (A); wherein a ratio (X/Y) of a distance (X) between end portions of the barrier layer at a pinch-off part of the fuel container and an average thickness (Y) of the container body is at least 1/10000 and at most 1/10; and wherein a ratio (Y1/Y) between a total thickness (Y1) of the layers of the container body that are located on the inside with respect to the barrier layer and an average thickness (Y) of the container body is at least 3/10 and at most 7/10.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: January 6, 2009
    Assignee: Kuraray Co., Ltd.
    Inventors: Keizo Michihata, Nahoto Hayashi
  • Publication number: 20080311327
    Abstract: The invention relates to a plastic tube comprising a tube body consisting of a multi-layer film (5) that includes at least one gas- and water-tight barrier film (7). The barrier film (7) has a polyglycolic acid (PGA) layer (9), at least one side of which is connected to a thermoplastic plastic layer (13, 15) by means of a layer (11, 12) consisting of an adhesion promoter. The adhesion promoter (11, 12) comprises a metal compound and has a layer thickness of between 100 and 500 nm.
    Type: Application
    Filed: January 26, 2006
    Publication date: December 18, 2008
    Applicant: ALCAN TECHNOLOGY & MANAGEMENT LTD.
    Inventors: Erwin Pasbrig, Otto Hummel
  • Patent number: 7465482
    Abstract: The object is to provide a thin film having high barrier properties and high translucency with no safety and health problems, which is capable of suppressing degradation due to moisture, oxygen and carbon dioxide gas and degradation due to the diffusion of impurities such as alkali metals and alkali earth metals, a deposition apparatus of the thin film, and products coated with the thin film by the deposition apparatus. Another object is to provide an extended usable range of the products of an environmentally friendly biodegradable material and a prolonged quality preservation period. The feature is that a single layer or laminated layer of a layer expressed by AlNxOy or layer expressed by AlxNy is deposited (coated) over the inner surface of a packaging film. The single layer or laminated layer thereof has high translucency, being capable of enhancing the barrier properties against moisture, oxygen and carbon dioxide gas, the heat resisting properties, and the mechanical strength.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: December 16, 2008
    Assignee: Semiconductor Energy Laboratory Co., Ltd.
    Inventors: Shunpei Yamazaki, Hideaki Kuwabara, Toru Takayama
  • Publication number: 20080286515
    Abstract: A vacuum insulation panel and an insulation structure of a refrigerator applying the same are disclosed. The vacuum insulation panel comprises: a sealing cover (120) having an outermost layer exposed to the outside, a gas shielding layer stacked on the bottom surface of the outermost layer and formed of a thin metal sheet and a metal deposition film, and a heating-fusion bonding layer stacked on the bottom surface of the gas shielding layer and formed of an octane-base material; a core material (110) sealed by the sealing cover (120) in contact with the heating-fusion bonding layer, and provided with an extended insulation portion (130) some parts of which are extended between the bonding portions formed at the sealing cover (120); and a gas permeation preventing layer (125) formed on the sealing cover (120), so that can prevent an external air or moisture from penetrating into a vacuum insulation panel.
    Type: Application
    Filed: October 17, 2006
    Publication date: November 20, 2008
    Inventors: Dong-Ju Jung, Young-Bae Kim, Kyung-Do Kim, Sang-Eui Hong
  • Publication number: 20080280084
    Abstract: Multiple layer structures comprising one or more poly(vinylidene chloride) layers and containers made from the multiple layer structures are provided. In a general embodiment, the present disclosure provides a multiple layer structure comprising one or more PVDC layers comprising a component selected from the group consisting of a poly(vinylidene chloride), a poly(vinylidene chloride) copolymer, and combinations thereof. The multiple layer structure further comprises one or more tie layers attached to the PVDC layer. The tie layer comprises a component selected from the group consisting of (a) polyether polyester copolymers, (b) polyurethanes having a melting temperature above about 121° C., (c) a blend comprising a polyamide and an ethylene copolymer containing an amine reactive functional group, and combinations thereof.
    Type: Application
    Filed: May 9, 2008
    Publication date: November 13, 2008
    Applicants: BAXTER INTERNATIONAL INC., BAXTER HEALTHCARE S.A.
    Inventors: Yuanpang S. Ding, Michael Tung-Kiung Ling, Moh-Ching Oliver Chang, Jean Michel Vallee, Gregg Nebgen
  • Patent number: 7445826
    Abstract: A polyester container having an enhanced level of crystallinity in the sidewall while maintaining a low level of crystallinity in a thickened base portion. The container is particularly useful as a refillable container which can withstand higher caustic wash temperatures and exhibits reduced flavor carryover, or as a hot-fill container. The container, which can be monolayer or multilayer, is also useful as a carbonated beverage, O2 or CO2 barrier, or beer container.
    Type: Grant
    Filed: August 8, 2005
    Date of Patent: November 4, 2008
    Assignee: Graham Packaging PET Technologies Inc.
    Inventors: Wayne N. Collette, Suppayan M. Krishnakumar, Chi Ching Lin
  • Publication number: 20080254245
    Abstract: A container, according to various embodiments of the invention, includes a co-extruded, blow molded wall that comprises: (1) a first, inner surface layer, (2) a second, interior layer; and (3) a third layer. In one embodiment, the inner surface layer comprises an extrusion blow-molding-capable grade of PET; the second, interior layer comprises adhesive; and the third layer comprises a polyolefin and the regrind material from one or more containers similar to the blow molded container. In various embodiments, the third layer is an outer surface layer of the blow molded wall. Alternatively, the container may further comprise a fourth (e.g., exterior surface) layer that comprises a polyolefin. In other embodiments, the inner surface layer comprises an extrusion blow-molding-capable grade of PET; the second, interior layer comprises a barrier material, such as polyamide resin, EVOH, or a compatible oxygen scavenger; and the third layer comprises an extrusion blow-molding-capable grade of PET.
    Type: Application
    Filed: April 11, 2008
    Publication date: October 16, 2008
    Inventors: Mihaela Penescu, Jesse Wayne Barron
  • Patent number: 7416766
    Abstract: Bottles made of metallocene polypropylene (mPP) for storage and dispensing reservoirs for fragrance compositions, in particular fragrance oils, are described. The mPP bottles can be used in warmer units for slow release dispensing of the fragrance therein. The metallocene polypropylene bottles can be produced by extrusion or injection blow molding, injection molding, injection stretch blow molding (single or two stage), or other suitable molding process. The mPP bottles may optionally have at least one barrier coating layer and/or adhering layer. The mPP bottles may optionally be fluorinated. The mPP bottles have good clarity and possess the required physical properties needed when the bottles are filled on a production line.
    Type: Grant
    Filed: August 16, 2005
    Date of Patent: August 26, 2008
    Assignee: S.C. Johnson & Son, Inc.
    Inventors: John S. Trent, Francis J. Randall, Terry M. Kovara, James J. Runkel
  • Patent number: 7416767
    Abstract: A barrier composite having reduced blocking is disclosed. The composite may include a substrate, a barrier layer formed from polyvinylidene chloride disposed on the substrate, and an anti-blocking layer disposed on the barrier layer. The anti-blocking layer may be formed from polyvinyl alcohol, and optionally, colloidal silica, wax, or a combination thereof. Alternatively, the anti-blocking layer may be formed from a polymeric carrier material, colloidal silica, and a wax. Methods for forming such composites and for forming a roll of such composites are also disclosed.
    Type: Grant
    Filed: September 30, 2004
    Date of Patent: August 26, 2008
    Assignee: Graphic Packaging International, Inc.
    Inventors: Darrel Loel Wilhoit, John Cameron Files
  • Publication number: 20080199645
    Abstract: A RF weldable film is provided. The film has outer layer including a PVDF copolymer or an alpha-olefin polymer and backing layer including a TPU copolymer. The film may have a gas barrier layer attached to the backing layer. The backing layer may include an EVOH copolymer. A method of making such a film is also provided. Containers made from such film are further provided.
    Type: Application
    Filed: February 8, 2008
    Publication date: August 21, 2008
    Inventor: Christian Julien
  • Patent number: 7384674
    Abstract: A packaging laminate for a retortable packaging container, the packaging laminate (30) including a paper or paperboard layer (31), outer, liquid-tight coatings (32; 33) and an aluminium foil (34) serving as gas barrier between the paper or paperboard layer (31) and one of the two outer liquid-tight coatings (32). In order to compensate for or counteract possible loss of gas tightness because of crack formations or similar untightness in the tensile-sensitive aluminium foil (34), the packaging laminate (30) includes at least one additional layer (35) serving as gas barrier between the paper or paperboard layer (31) and the aluminium foil (34).
    Type: Grant
    Filed: October 18, 2002
    Date of Patent: June 10, 2008
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Thorbjörn Andersson, Ib Leth
  • Patent number: 7368153
    Abstract: The present invention relates to the non-invasive use of a luminescent compound to detect and measure concentrations of oxygen dissolved in a rigid container, especially a bottle, a tray, a carton, a lidstock associated with a tray, a stand up pouch, or a paperboard container. The measurement is made independent of the oxygen concentration of the surrounding atmosphere. The invention is especially useful as a quality assurance check to verify oxygen scavenger activation during the assembly of bottled products, and modified atmosphere and vacuum packages. The method according to the invention is faster and less wasteful than previous methods that rely on measuring oxygen concentration within the headspace of an assembled package.
    Type: Grant
    Filed: November 21, 2003
    Date of Patent: May 6, 2008
    Assignee: Cryovac, Inc.
    Inventors: Charles R. Barmore, Drew V. Speer, Thomas D. Kennedy, Marvin R. Havens
  • Patent number: 7364779
    Abstract: A plastic, easy-opening closure for a retortable container and a method for sealing are provided. The closure includes a plastic membrane having an outer layer of polypropylene, a first tie layer, an intermediate layer formed of EVOH, a second tie layer, an inner layer formed of polypropylene, and a peel-seal layer. The peel-seal layer can be formed of high density polyethylene or polypropylene with a contaminant dispersed therein so that the closure can be easily removed from the container for opening.
    Type: Grant
    Filed: September 2, 2003
    Date of Patent: April 29, 2008
    Assignee: Sonoco Development, Inc.
    Inventor: Srinivas Nomula
  • Patent number: 7335411
    Abstract: Vulcanizable elastomeric compositions and vulcanizates are prepared by employing a strong acid. The strong acid is believed to enhance the reaction between a silica particle and a silica-reactive compound.
    Type: Grant
    Filed: October 26, 2005
    Date of Patent: February 26, 2008
    Assignee: Bridgestone Corporation
    Inventors: Chenchy Jeffrey Lin, William L. Hergenrother
  • Patent number: 7332204
    Abstract: This invention relates to articles made of polyester, preferably polyethylene terephthalate (PET), having coated directly to at least one of the surfaces thereof one or more layers of thermoplastic material with good gas-barrier characteristics, and novel methods of making such articles. Preferably the barrier-coated articles take the form of preforms coated by at least one layer of barrier material and the containers blow-molded therefrom. Such barrier-coated containers are preferably of the type to hold beverages such as soft drinks, beer or juice. The preferred barrier materials have a lower permeability to oxygen and carbon dioxide than PET as well as key physical properties similar to PET. The materials and methods provide that the barrier layers have good adherence to PET, even during and after the blow molding process to form containers from preforms. Preferred barrier coating materials include poly(hydroxyamino ethers).
    Type: Grant
    Filed: January 24, 2003
    Date of Patent: February 19, 2008
    Assignee: Advanced Plastics Technologies Luxembourg S.A.
    Inventors: Gerald A. Hutchinson, Robert A. Lee
  • Patent number: 7303797
    Abstract: A water-borne gas barrier coating composition for polymeric films and shaped containers, including a two-layer coating system with a laminar layer mineral in the gas barrier layer, which is particularly well suit for spray application to biaxially oriented injection stretch blow molded PET bottles for carbonated beverages and beer.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: December 4, 2007
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Robert J. Barsotti, Derek John Winter
  • Patent number: 7291369
    Abstract: A multi-layer article includes a first polymer layer bonded to a barrier layer, which is bonded to a second polymer layer. The first polymer layer can include a fluoroelastomer. The second polymer layer can be a non-fluorinated polymer layer. The barrier layer can include a polymer derived from vinyl acetate.
    Type: Grant
    Filed: October 3, 2001
    Date of Patent: November 6, 2007
    Assignee: 3M Innovative Properties Company
    Inventor: Tatsuo Fukushi
  • Patent number: 7288586
    Abstract: A solid concentrate is provided having a combination of a transition metal present in an amount ranging from 1000 to 40,000 ppm (weight by metal) and a polyester polymer present in an amount of at least 40 wt. % based on the weight of the concentrate. Concentrates made with highly modified polyester polymers are easy to compound with transition metals forming less brittle polymer upon melt extrusion. Bottle preforms and oxygen scavenging bottles can be made from these concentrates by combining solid polyester particles, solid polyamide particles, and solid these concentrate particles c into an melt processing zone, forming a melt, and forming an article directly from the melt. The b* color and the L* color and the haze levels of the preforms are improved over the preforms made with liquid carriers instead of solid concentrates.
    Type: Grant
    Filed: December 2, 2005
    Date of Patent: October 30, 2007
    Assignee: Eastman Chemical Company
    Inventors: Mark Edward Stewart, Emerson Eston Sharpe, Jr., Benjamin Bradford Gamble, Steven Lee Stafford, Robert Noah Estep, James Carl Williams, Thomas Roger Clark
  • Patent number: 7285314
    Abstract: A steam barrier film comprising at least one inorganic gas barrier layer on a polyalkylene naphthalate resin substrate film in which the glass transition temperature (Tg) of the polyalkylene naphthalate resin is from 70 to 150° C. and the steam barrier film comprises at least one conductive layer with a resistance of 1012 ? or less at 25° C. and 60% relative humidity.
    Type: Grant
    Filed: February 28, 2006
    Date of Patent: October 23, 2007
    Assignee: Fujifilm Corporation
    Inventors: Yasuo Mukunoki, Hiroshi Iwanaga
  • Patent number: 7267858
    Abstract: A packaging material is formed by a substrate, and an inner sealing layer comprising a polyolefin layer and an aqueous dispersion-type polyester resin layer successively disposed on the substrate. The aqueous dispersion-type amorphous polyester resin layer contains an anionic surfactant or an amphoteric surfactant and is substantially free from an organic solvent having a boiling point of at most 100° C. The thus-formed packaging material is excellent in aroma-retentivity, aroma non-adsorptivity, particulate non-adhesion, low residual solvent and sealability. The packaging material is also free from environmental problem and is therefore suitable as a packaging material for particulate medical supplies and health foodstuff.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: September 11, 2007
    Assignee: Kureha Corporation
    Inventors: Saichi Ono, Shinichi Hirakawa, Yoichiro Yotsuya, Hirofumi Okada
  • Patent number: 7264884
    Abstract: A stretch film presenting controlled permeability to gases, manufactured by process of balloon co-extrusion and consisting of outer layers (S2) of stretchable polmeric material and by one or two inner barrier layers (S3) of a EVOH based polymeric matrix, which is made stretchable by the addition of a suitable plasticizer in such a percentage as to conciliate the stretchablity with the desired barrier effect, said layers of different material being reciprocally secured by means of layers (S4) of adhesive material. The polymeric matrix which forms the barrier material and the plasticizer are intimately mixed inside a double-screw corotating extruder, immediately before the phase of co-extrusion, through a premelting of the polymeric matrix and the subsequent injection of the plasticizer in liquid phase.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: September 4, 2007
    Assignee: A.W.A.X. Progettazione e Ricerca
    Inventors: Renato Rimondi, Angelo Cappi, Carlo Nicoletti
  • Patent number: 7255902
    Abstract: A paper-like multilayer barrier film comprises a filled polypropylene layer and several unfilled layers. The filled layer contains 40-75% by wt. of inorganic fillers, forms one of the two outside layers of the film, and has a thickness of at least 40 ?m. The unfilled layers include a barrier layer, a sealing layer, and optionally at least one adhesive layer. The ratio of the total thickness of the unfilled layers to the thickness of the filled layer is in the range of 1:8 to 1:1.2.
    Type: Grant
    Filed: May 8, 2001
    Date of Patent: August 14, 2007
    Assignee: Convenience Food Systems B.V.
    Inventors: Ulrich Reiners, Erik Järund, Leif Linné
  • Patent number: 7255904
    Abstract: The present invention provides a resin composition having an oxygen scavenging function. The resin composition comprises 70 to 99.9 wt % of a polyvinyl alcohol resin (A) and 0.1 to 30 wt % of a thermoplastic resin (B) other than the polyvinyl alcohol resin (A), wherein the thermoplastic resin (B) has a carbon-carbon double bond and a functional group including a hetero atom, and an oxygen absorption rate of the resin composition is 0.001 ml/m2·day or more.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: August 14, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Shinji Tai, Hiroyuki Shimo, Masakazu Nakaya, Mizuho Maeda
  • Patent number: 7244484
    Abstract: The present invention provides compositions useful as a barrier layer in, for example, packaging products. The compositions generally comprise a blend of (i) a polyester resin, preferably an aromatic polyester resin such as polyethylene terephthalate (PET) and (ii) a polyamide material (e.g., MXD6). The blend optionally may further comprise (iii) an oxygen scavenging material. The present invention also provides containers (e.g., containers formed by expansion of preforms) having a multilayered body-forming portion including: a core layer comprising the aforementioned blend; and inner and outer layers of a formable polymer composition. The present invention also provides methods of making such containers.
    Type: Grant
    Filed: October 31, 2001
    Date of Patent: July 17, 2007
    Assignee: Valspar Sourcing, Inc.
    Inventors: Paul E. Share, Keith R. Pillage
  • Patent number: 7241481
    Abstract: An article, such as a polymeric film, sachet, purge control pad, or label, includes a sulfur scavenger. In some embodiments, an oxygen scavenger is also included. A method includes providing an article, including a sulfur scavenger and an oxygen scavenger; and subjecting the article to a dosage of actinic radiation effective to trigger the oxygen scavenger. A method of reducing the sulfur content of a package containing a food product includes either (1) providing a film including a layer including a zinc ionomer, and a layer including an oxygen scavenger; packaging the food product in the film; and storing the package for at least 24 hours; or (2) providing the food product at a temperature of ?40° F.; providing a film including a layer including a sulfur scavenger; packaging the food product in the film; and storing the package for at least 24 hours.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: July 10, 2007
    Assignee: Cryovac, Inc.
    Inventors: Drew V. Speer, Cynthia L. Ebner, Michael D. Grah
  • Patent number: 7235306
    Abstract: A heat sealable barrier layer for food and beverage cartons is provided, the barrier layer including an additive material which reduces the amount of essential oil scalping from citrus products. Additionally, a carton coating layer and process is provided for reducing a coefficient of friction of stacked carton blanks. An additional embodiment of the invention provides for a paperboard substrate having reduced water vapor transmission rates, the reduction in water vapor transmission rates being attributed to one or multiple extruded layers containing an effective amount of an inorganic additive.
    Type: Grant
    Filed: November 21, 2003
    Date of Patent: June 26, 2007
    Assignee: BRPP, LLC
    Inventor: Kevin Cable
  • Patent number: 7229678
    Abstract: A barrier laminate packaging material comprising from its outermost surface to the innermost surface contacting the contents of the container to be prepared therefrom, a first exterior layer of a low density polyethylene polymer, a paperboard substrate, a first interior layer laminate coating of nylon with a tie resin layer, a blown film layer comprising a first low density polyethylene polymer layer, a tie layer, a first interior layer of EVOH, a second tie layer, a second interior layer of EVOH, a third tie layer and a second interior layer of low density polyethylene polymer, and an innermost product contacting layer of low density polyethylene.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: June 12, 2007
    Assignee: Evergreen Packaging Inc.
    Inventors: Tricia Susan Reighard, Christopher S. Cleveland, Richard A. Tedford, Jr.
  • Patent number: 7228877
    Abstract: A flexible fuel hose having improved fuel vapor barrier properties wherein the fuel hose comprises a first fluoropolymer layer forming a first barrier tubular structure and a second fluoropolymer layer forming a second tubular structure around the first barrier tubular structure; and a method for the manufacture of such hose are described.
    Type: Grant
    Filed: April 13, 2004
    Date of Patent: June 12, 2007
    Assignee: Dayco Products, LLC
    Inventor: Jerry Shifman
  • Patent number: 7211307
    Abstract: A permeation resistant polymer fuel tank having a multilayer wall that includes a structural layer and a vapor barrier layer. A secondary barrier layer is attached to the multilayer wall wherein the vapor barrier layer and the second barrier layer have a permeation rate less than the structural layer. A protective coating may be applied over the secondary barrier layer to add durability and prevent degradation of the secondary barrier layer from environmental hazards that fuel tanks may be exposed to.
    Type: Grant
    Filed: October 23, 2002
    Date of Patent: May 1, 2007
    Assignee: Visteon Global Techologies, Inc.
    Inventors: James F. Potter, Heather L. Knechtges
  • Patent number: 7208210
    Abstract: A fuel container with high fuel barrier properties is provided. The fuel container is a coextrusion blow-molded fuel container having a container body made of a layered structure. The layered structure comprises: a barrier layer made of a barrier resin (A); and an inner layer and an outer layer made of a thermoplastic resin (B) that is different from the barrier resin (A); wherein a ratio (X/Y) of a distance (X) between end portions of the barrier layer at a pinch-off part of the fuel container and an average thickness (Y) of the container body is at least 1/10000 and at most 1/10; and wherein a ratio (Y1/Y) between a total thickness (Y1) of the layers of the container body that are located on the inside with respect to the barrier layer and an average thickness (Y) of the container body is at least 3/10 and at most 7/10.
    Type: Grant
    Filed: March 10, 2004
    Date of Patent: April 24, 2007
    Assignee: Kuraray Co., Ltd.
    Inventors: Keizo Michihata, Nahoto Hayashi
  • Patent number: 7195803
    Abstract: The disclosure relates to a packaging laminate for a retortable packaging container comprising a core layer (11), outer, liquid-tight coatings (12 and 13) and a gas barrier (14) disposed between the one coating (12) and the core layer (11). Between the gas barrier (14) and the core layer (11), there is a layer (16) of a lamination or sealing agent of such a nature that the lamination or sealing agent has a melting point which is higher than the maximum temperature to which the retortable packaging container is to be subjected during a normal heat treatment in a retort. The lamination or sealing agent in the layer (16) may, for example, be a polypropylene with a melting point of above 130° C.
    Type: Grant
    Filed: October 1, 2001
    Date of Patent: March 27, 2007
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Thorbjörn Andersson, Tom Kjelgaard, Ib Leth
  • Patent number: 7169453
    Abstract: Described are structures comprising, successively: a first layer of high density polyethylene (HDPE), a layer of binder, a second layer of EVOH or of a mixture based on EVOH, optionally a third layer of polyamide (A) or of a mixture of polyamide (A) and polyolefin (B). Also described are devices for transferring or storing fluids and more particularly tubes, tanks, chutes, bottles and containers consisting of the above structure and in which the barrier layer (the second or the combination of the second and the third layer) is in direct contact with the fluid contained or transported.
    Type: Grant
    Filed: February 6, 2001
    Date of Patent: January 30, 2007
    Assignee: Arkema France
    Inventors: Christophe Le Roy, Joachim Merziger, Jerome Pascal
  • Patent number: 7160604
    Abstract: The invention relates to laminated high oxygen barrier films for packaging applications and especially for shrinkable lidding applications. The multilayer heat shrinkable plastic film of the present invention comprises a laminate of at least two films 1 and 2, wherein film 1 has a hot glycerine shrinkage of more than 20% at 110° C. for 5 seconds and at least one of MD, TD directions; and film 2 has a hot glycerine shrinkage of less than 20% at 110° C. for 5 seconds in at least one of MD, TD directions.
    Type: Grant
    Filed: May 17, 2005
    Date of Patent: January 9, 2007
    Assignee: Flexopack S.A.
    Inventor: Dimitris Ginossatis
  • Patent number: 7150902
    Abstract: Articles are coated by applying a coating composition of a high Tg phenoxy-type material having a Tg of at least about 75° C. to at least a portion of a surface of an article, and forming a dried/cured coating of the high Tg phenoxy-type material on the article surface, where the coating has the high Tg phenoxy-type material and a PHAE; or the article surface comprises a coating includes a PHAE; or the coating has the high Tg phenoxy-type material and a PHAE, and the article surface includes a coating layer of a PHAE.
    Type: Grant
    Filed: April 7, 2004
    Date of Patent: December 19, 2006
    Assignee: Pepsico, Inc.
    Inventor: Said Farha
  • Patent number: 7115310
    Abstract: A packaging laminate (10) including a substrate film (15) coated with a carbon containing silicon oxide layer (16, 17) on both surfaces is disclosed herein. A method for producing the laminate (10), and blanks and packages fabricated from the laminate are also disclosed herein. The PECVD process of the present invention strains the substrate film (15) during deposition thereby creating a very thin oxide layer with superior durability, oxygen and aroma barrier properties. The carbon-containing silicon oxide coating (16, 17) has a stoichiometry of SiOxCy in which x is witin the range of 1.5–2.2 and y is within the range of 0.15–0.80. The substrate film (15) may include a core layer (12) of a material selected from the group consisting of paper, paperboard, a foamed core, polyethylene terephtalate, polyamide, polyethylene and polypropylene.
    Type: Grant
    Filed: October 27, 2003
    Date of Patent: October 3, 2006
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventor: Bertrand Jaccoud
  • Patent number: 7115309
    Abstract: The blow molded preform of a laminated wall structure comprises a bulging shoulder portion which has a diameter that widens slightly in the downward direction; a bottom shell portion for molding a bottom, which has been blow molded from a corresponding portion of a parison so as to have a widened and deformed shape; an inner overhang wall portion in any position starting from the opposite side of a neck ring and ending at the upper portion of a bulging shoulder portion, with an inner wall portion having a diameter that widens in the downward direction; and/or a radially widened connecting portion of an arced shape, which has a larger diameter than a barrel portion so that the entire bottom including a bottom shell portion takes a bulging spherical shape.
    Type: Grant
    Filed: December 20, 2001
    Date of Patent: October 3, 2006
    Assignee: Yoshino Kogyosho Co., Ltd.
    Inventors: Yoshio Akiyama, Hiroaki Tokuda, Makoto Busujima, Shuichi Koshio, Masaaki Sasaki
  • Patent number: 7087277
    Abstract: Herein is disclosed a modified ethylene vinyl alcohol polymer (EVOH) comprising an oxygen scavenging functional group. Preferably, the modified EVOH comprises structures IV, V, and VI: wherein x is an integer greater than or equal to 1, y is an integer greater than or equal to 1, z is an integer greater than or equal to 1, and R comprises a cycloalkenyl group. The modified EVOH is useful in oxygen barrier applications, such as a forming an oxygen barrier layer of a packaging article. Also disclosed are methods of modifying ethylene vinyl alcohol polymers, and using the modified EVOH to make packaging articles with a superior barrier to entry by atmospheric oxygen.
    Type: Grant
    Filed: June 19, 2003
    Date of Patent: August 8, 2006
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Hu Yang, Ta Yen Ching, Gangfeng Cai
  • Patent number: 7063873
    Abstract: A multiplayer tube comprising: an outer layer formed from a polyamide, a layer formed from a copolyamide, a layer formed from an EVOH, a layer formed from a copolyamide, and an inner layer formed from a polyamide, the layers being successive and adhering to one another in their respective contact region. Advantageously, the inner layer is formed by a compound based on a polyamide and electrically conducting carbon black, producing a surface resistivity of less than 106 ?. The tubes have a very low permeability to petrol, particularly to hydrocarbons and their additives, and in particular to alcohols, such as methanol and ethanol, or to ethers, such as MTBE or ETBE. These tubes also have good resistance to engine lubricating oils as well as fuels.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: June 20, 2006
    Assignee: Arkema
    Inventors: Gaëlle Bellet, Anthony Bonnet, Joachim Merziger
  • Patent number: 7056565
    Abstract: Rigid containers are provided comprising oxygen scavenger compositions that produce only low levels of volatiles or by-products as a consequence of oxygen scavenging. In particular, a family of polymers containing selected cyclic olefinic pendent groups are used in the rigid containers to achieve oxygen scavenging that is associated with minimal or no organoleptic by-products after oxidation.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: June 6, 2006
    Assignee: Chevron Phillips Chemical Company, LP
    Inventors: Gangfeng Cai, Ta Yen Ching, Hu Yang
  • Patent number: 7052753
    Abstract: Novel films, and processes for making them, are provided. The films are characterized by the inclusion of a layer of vinylidene chloride copolymer between at least two other layers which contain ethylene vinyl acetate, and optionally linear low density polyethylene. The films may be unoriented or oriented. Oriented films may optionally be cross-linked. The novel process of making the cross-linked films includes the step of cross-linking the film after assembly of the vinylidene chloride copolymer layer into the structure.
    Type: Grant
    Filed: December 22, 1989
    Date of Patent: May 30, 2006
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Samuel W. Tse, Almar T. Widiger, Keith D. Lind
  • Patent number: 7052752
    Abstract: A blow molding multilayered resin container used for holding contents containing an oxidation dye which comprises a moisture barrier layer having a water vapor transmission rate of 0.4 g·mm/(m2·d) or lower and an oxygen barrier layer having an oxygen transmission rate of 10 cm3·mm/(m2·d·MPa) or lower, the oxygen barrier layer being closer to the outside of the container than the moisture barrier layer.
    Type: Grant
    Filed: September 16, 2003
    Date of Patent: May 30, 2006
    Assignee: Kao Corporation
    Inventors: Mitsugu Iwatsubo, Yuuji Yamaguchi, Takurou Ito
  • Patent number: 7048975
    Abstract: A pulp molded container comprising a pulp molded article (2) having on the inner surface and/or the outer surface thereof a resin layer (3) with a thickness of 5 to 300 ?m formed by applying a coating, wherein the thickness ratio of the resin layer (3) to the molded article (2) (former/latter) is 1/2 to 1/100, and the surface roughness profile of the outer or inner surface of the pulp molded article is such that a centerline average roughness (Ra) is 0.5 to 20 ?m.
    Type: Grant
    Filed: October 2, 2000
    Date of Patent: May 23, 2006
    Assignee: Kao Corporation
    Inventors: Takehiko Tojo, Yoshiaki Kumamoto, Masataka Ishikawa, Kunio Matsui, Eiki Kimura, Koichi Sagara, Kenichi Otani, Shingo Odajima, Tokihito Sono
  • Patent number: 7041351
    Abstract: Novel films, and processes for making them, are provided. The films are characterized by the inclusion of a layer of vinylidene chloride copolymer between at least two other layers which contain ethylene vinyl acetate, and optionally linear low density polyethylene. The films may be unoriented or oriented. Oriented films may optionally be cross-linked. The novel process of making the cross-linked films includes the step of cross-linking the film after assembly of the vinylidene chloride copolymer layer into the structure.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: May 9, 2006
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Samuel W. Tse, Almar T. Widiger, Keith D. Lind, James Musselman
  • Patent number: 7041352
    Abstract: The present invention relates to thermoplastic structures wherein the inner sealant layer of said structure comprises a polyethylene having a density from about 0.88 to about 0.96 and wherein the polyethylene is processed at a temperature ranging from about 150° F. to about 500° F. in order to prevent the release of extractable materials. The thermoplastic structures can be used independently to form a flexible packaging film or can be affixed to a second film structure or substrate to form a flexible packaging film. The flexible packaging films can be used for forming containers for the storing and transporting of organoleptic sensitive products.
    Type: Grant
    Filed: July 1, 2003
    Date of Patent: May 9, 2006
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Victor Jason Barber, Roberto Siu
  • Patent number: 7022388
    Abstract: There is provided a laminated polyester film which is improved in lubricity, transparency, dimensional stability, shock resistance and adhesion, and which comprises a polyester base film comprising polyester and to at least one direction, and a coating layer provided on at least one surface of the base film, wherein said coating layer contains polymer binder and inert particles, the refractive index of the inert particles being substantially same as that of the polymer binder, and wherein the laminated polyester film has a haze of 1.5% or less, a total light transmittance of 85% or more, 50% destructing energy per 100 ?m film thickness of 0.3 J or more, and a thermal shrinkage at 230° C. for 30 minutes of 4% or less.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: April 4, 2006
    Assignee: Teijin DuPont Films Japan Limited
    Inventors: Katsuyuki Hashimoto, Makoto Handa, Shinji Yano, Koji Kubo
  • Patent number: 7022391
    Abstract: The present invention provides a casing material for an electronic component which has a good adhesion with an aluminum foil and a resin layer, impermeability of steam, heat seal property, and corrosion resistance for an electrolyte. The present invention also provides a casing for an electronic component using the casing material. The present invention also provides an electronic component including the casing. The casing material comprises a heat resistant resin drawn film layer as an outer layer, a thermoplastic resin not-drawn film as an inner layer, and an aluminum foil layer provided between the layers. In particular, an acrylic polymer layer is provided between the aluminum foil layer and the not-drawn film layer.
    Type: Grant
    Filed: October 12, 2001
    Date of Patent: April 4, 2006
    Assignees: Showa Denko Packaging Co., Nippon Shokubai Co., Ltd.
    Inventors: Hideo Kawai, Katsumi Tanaka, Takahiro Aoyama, Mitsuo Nakazaki
  • Patent number: 7011873
    Abstract: The invention relates to the use of a structure for manufacturing hermetical industrial or food packaging in direct contact with a humid or aqueous medium, the structure comprising at least one layer of polydimethyl ketone in direct contact with the most humid medium, (i) the latter being situated within the packaging when the packaging accommodates water or an aqueous or humid product and (ii) the most humid medium being situated outside the packaging when the packaging accommodates a product which is dry or which is to be protected from humidity. The food packaging comprises, for example, trays, sachets, bottles and flasks and the industrial packaging comprises, for example, pipes, containers and drums.
    Type: Grant
    Filed: July 31, 2003
    Date of Patent: March 14, 2006
    Assignee: Arkema
    Inventors: Benoit Brule, Reinhard Linemann
  • Patent number: 7009019
    Abstract: A hollow plastic article is described, with at least one opening and with a structure which has one or more layers, the hollow plastic article comprising at least one layer made from a polyolefin which was prepared using a fluorine-modified chromium catalyst. The use of hollow plastic articles of the invention as plastic fuel containers, gasoline canisters, plastic tanks, or plastic bottles or the like is also described.
    Type: Grant
    Filed: June 28, 2001
    Date of Patent: March 7, 2006
    Assignee: Basell Polyolefine GmbH
    Inventors: Shahram Mihan, Wolfgang Rohde, Ilka Beuermann, Bernhard Springholz
  • Patent number: 6979494
    Abstract: A dual ovenable film having a first layer comprising one or more polyamides and a second layer comprising one or more polyamides. The first layer forms the first outer surface of the film. The second layer has a melting point of at least about 210° C. The film is capable of forming a water-containing package by providing two 4 inch by 6 inch sheets of the film each having four perimeter sides, placing the sheets in superimposed, coextensive arrangement having the first layers of the films in contact with each other, and heat sealing three perimeter sides of the sheets together using a ?-inch wide sealing bar at a temperature of 290° F., a dwell time of 0.5 seconds, and a sealing pressure of 40 psig to form an open pouch having heat seals along three of the four perimeter sides. The open pouch can be filled with 100 milliliters of distilled water at a temperature of 73° F.
    Type: Grant
    Filed: August 27, 2002
    Date of Patent: December 27, 2005
    Assignee: Cryovac, Inc.
    Inventors: Arthur Leroy Berrier, Cynthia Louise Ebner
  • Patent number: 6964797
    Abstract: The present invention relates to a laminated packaging material suitable for use especially in heat-sealable packages for liquid food, such as milk, cream and juice cartons, and to a manufacturing method of the material, and to a food package manufactured of the material. The material comprises a core of paper or cardboard, and oxygen and aroma proof barrier layers of EVOH and polyamide. The EVOH layer and the polyamide layer are joined together directly without any intermediate adhesive layer, and the barrier layers and the core are interposed between polymeric heat-sealing layers on both sides of the material. The material is manufactured by extrusion so that at least the materials of the said barrier layers are placed against each other in a molten state and forwarded to the core in one web.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: November 15, 2005
    Assignee: Stora Enso OYJ
    Inventors: Matti Salste, Tapani Penttinen, Jalliina Järvinen, Risto Salminen, Terttu Heinonen, Tuomo Kuuppo