Including Free Carbon Or Carbide Or Therewith (not As Steel) Patents (Class 428/367)
  • Patent number: 5972447
    Abstract: Disclosed herein is a thermoformable film or sheet superior in gas barrier properties, mechanical properties, and appearance, a thermoformed container produced therefrom, and a resin composition suitable therefor. A thermoformable multilayer film with a total thickness of 50-300 .mu.m, comprising a layer of a resin composition with a thickness of 3-50 .mu.m, said resin composition comprising 60-99 wt % of ethylene-vinyl alcohol copolymer and 40-1 wt % of ethylene-(meth)acrylic acid copolymer, said ethylene-(meth)acrylic acid copolymer being dispersed in the form of particles in the matrix of said ethylene-vinyl alcohol copolymer, wherein said ethylene-vinyl alcohol copolymer having an ethylene content of 20-60 mol % and a degree of hydrolysis of not less than than 90%, and said ethylene-(meth)acrylic acid copolymer containing 1-30 wt % of (meth)acrylic acid.The EVOH may be a mixture of more than one kind of EVOH differing in ethylene content.
    Type: Grant
    Filed: September 11, 1997
    Date of Patent: October 26, 1999
    Assignee: Kuraray Co., Ltd.
    Inventors: Nobihiro Hata, Hiroyuki Shimo
  • Patent number: 5972499
    Abstract: A process and materials made by the process which includes a bicomponent fiber, made of a nonconductive first component, including a first fiber-forming polymer selected from the group consisting of polyethylene terephthalate, nylon 6, nylon 6,6, cellulose, polypropylene cellulose acetate, polyacrylonitrile and copolymers of polyacrylonitrile; a conductive second component, including carbon particles and a second fiber-forming polymer selected from the group consisting of polyethylene terephthalate, nylon 6, nylon 6,6, cellulose, polypropylene cellulose acetate, polyacrylonitrile and copolymers of polyacrylonitrile; and a conductive third component, including a polymer selected from the group consisting of polypyrrole and polyaniline, said polymer formed in situ and being interspersed among at least a portion of the carbon particles of the second component.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: October 26, 1999
    Assignee: Sterling Chemicals International, Inc.
    Inventors: Edgardo Rodriguez, John W. Lindsay, William E. Streetman
  • Patent number: 5968616
    Abstract: This invention relates to a compound container which can completely be separated into paper and plastics upon abandonment thereof, whose volume can substantially be reduced upon abandonment, which permits the reduction of the amounts of paper and plastics to be used, which exhibits excellent resistance to falling impact, which has a high oxygen gas barrier properties or water vapor barrier properties. This compound container comprises an inner container of a plastic and an outer container of paper or mainly comprising paper, wherein the inner container is produced by blow-molding or stretch blow-molding a resin composition comprising at least two resins including a barrier resin.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: October 19, 1999
    Assignee: Toppan Printing Co., Ltd.
    Inventors: Toshiaki Kakemura, Katsuyuki Ohno, Terutaka Iwasaki, Toshikazu Katoh, Takekuni Seki, Keiko Nakamura
  • Patent number: 5968650
    Abstract: The invention relates to an interpenetrating network of carbon fibrils and a polymer, which comprises a rigidized, three-dimensional macroscopic assemblage of a multiplicity of randomly oriented carbon fibrils and an innerpenetrating mass of an organic polymer. The invention also relates to methods of making and using such innerpenetrating networks.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: October 19, 1999
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: Howard G. Tennent, Chun Ming Niu, Robert Hoch, Alan B. Fischer
  • Patent number: 5968620
    Abstract: The present invention is a plastic container coated with a multi-layer barrier coating. The multi-layer barrier coating is useful for providing an effective barrier against gas permeability in containers and for extending shelf-life of containers, especially plastic evacuated blood collection devices.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: October 19, 1999
    Assignee: Becton Dickinson and Company
    Inventors: Noel G. Harvey, Yelena G. Tropsha, Susan L. Burkett, Richard P. Clarke, Bryan Soo Wong
  • Patent number: 5965223
    Abstract: The present invention is a composite layered protective fabric having an outer primary layer composed of an abrasive material and an inner primary layer composed of an inherently cut-resistant material positioned below the outer primary layer and when assembled into a garment is positioned proximate to the wearer's skin. In another preferred embodiment of the present invention, a secondary layer is added to the inner and outer layer framework. The secondary layer is composed of a material that provides additional protection against potential threats other than cuts, that increases comfort or that improves aesthetics. The invented composite fabric is continuously manufactured in a one-step process which plates the layers of yarn. Thus formed, the invented composite fabric can be formed into cut-resistant apparel and articles that provide a high level of protection against sharp objects.
    Type: Grant
    Filed: October 10, 1997
    Date of Patent: October 12, 1999
    Assignee: World Fibers, Inc.
    Inventors: Mark A. Andrews, James B. Miles
  • Patent number: 5965470
    Abstract: A method of oxidizing the surface of carbon microfibers that includes contacting the microfibers with an oxidizing agent that includes sulfuric acid and potassium chlorate under reaction conditions sufficient to oxidize the surface. The invention also features a method of decreasing the length of carbon microfibers that includes contacting the microfibers with an oxidizing agent under reaction conditions sufficient to decrease the length.
    Type: Grant
    Filed: May 23, 1995
    Date of Patent: October 12, 1999
    Assignee: Hyperion Catalysis International, Inc.
    Inventors: Robert C. Bening, Thomas J. McCarthy
  • Patent number: 5965268
    Abstract: A carbon-based composite is made by the steps of(1) impregnating a fibrous material with a phthalonitrile thermoset polymer precursor,(2) curing the product of step (1) to form a fiber-reinforced thermoset polymer and(3) pyrolyzing the product of step (2) to form the carbon-based composite. The carbon-based composite may be made with only one cycle of the steps (1), (2), and (3).
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: October 12, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Satya B. Sastri, James P. Armistead, Teddy M. Keller
  • Patent number: 5962093
    Abstract: A laminate structure comprises one or more layers of an organic polymer and one or more layers of a hydroxy-functionalized polyetheramine, wherein the hydroxy-functionalized polyetheramine layer is adhered directly to a contiguous organic polymer layer without an adhesive layer therebetween. The hydroxy-functionalized polyetheramine is prepared by reacting (1) a difunctional amine with (2) a diglycidyl ether or a diepoxy-functionalized poly(alkylene oxide) under conditions sufficient to cause the amine moieties to react with the epoxy moieties to form a polymer backbone having amine linkages, ether linkages and pendant hydroxyl moieties and then treating the reaction product with a monofunctional nucleophile which is not a primary or secondary amine.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: October 5, 1999
    Assignee: The Dow Chemical Company
    Inventors: Jerry E. White, Joe T. Sanford, Terry W. Glass
  • Patent number: 5962092
    Abstract: A multilayer film comprises: a first layer comprising a first homogeneous ethylene/alpha-olefin copolymer; a second layer comprising a polyolefin; and a third layer comprising a second homogeneous ethylene/aipha-olefin copolymer. The second layer is between the first layer and the third layer, the second layer is chemically different from the first layer and the third layer, and the multilayer film has an O.sub.2 -transmission rate of from about 500 to 50,000 cc/m.sup.2 /24 hr STP. One outer layer of the film comprises an antifog agent on the outer surface thereof. Also disclosed is a package made from the film. The film is especially suitable for the packaging of oxygen-sensitive products, such as lettuce, and resists fogging up on the inside surface of the film forming the package. Preferably, the package has printing on the outside surface of the film, with the print having good adhesion to the film.
    Type: Grant
    Filed: October 13, 1995
    Date of Patent: October 5, 1999
    Assignee: Cryovac, Inc.
    Inventors: Betsy P. Kuo, Mendy J. Walden
  • Patent number: 5962094
    Abstract: The present invention relates to a closure giving a tight mechanical seal and preferably made from metal or plastic, with an insert on its inner side as a sealing element for containers, in particular for bottles and glassware, where the insert is composed of at least one polyolefin which can be prepared using catalysts selected from the class consisting of the metallocenes.
    Type: Grant
    Filed: April 23, 1998
    Date of Patent: October 5, 1999
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Doris Osterkamp, Peter Nussen
  • Patent number: 5962348
    Abstract: The present invention discloses a method a method of making a material for thermal cores and the material so made. In particular, the present invention disclose a method including the steps of applying thermally conductive particles over at least a portion of a fiber layer, providing another fiber layer upon the fiber layer, and repeating the above steps as desired. In another aspect of the present invention is disclosed a method of making a thermally conductive material including applying thermally conductive particles upon at least a portion of a fiber prepreg layer, providing another fiber prepreg layer upon the fiber layer, repeating the above steps as desired, and bonding the fiber prepreg layers, including the thermally conductive particles, together. The material in accordance with the present invention includes a plurality of layers made of thermally conductive fibers bonded by a resin, and a plurality of interposed layers of resin having a high concentration of high conductivity particles therein.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: October 5, 1999
    Assignee: XC Associates
    Inventors: John D. Bootle, Frank Burzesi
  • Patent number: 5955161
    Abstract: The present invention is a plastic container coated with a multi-layer barrier coating. The multi-layer barrier coating is useful for providing an effective barrier against gas permeability in containers and for extending shelf-life of containers, especially plastic evacuated blood collection devices.
    Type: Grant
    Filed: January 30, 1996
    Date of Patent: September 21, 1999
    Assignee: Becton Dickinson and Company
    Inventor: Yelena G. Tropsha
  • Patent number: 5952069
    Abstract: The present invention is a plastic container coated with a multi-layer barrier coating. The multi-layer barrier coating is useful for providing an effective barrier against gas permeability in containers and for extending shelf-life of containers, especially plastic evacuated blood collection devices.
    Type: Grant
    Filed: June 18, 1997
    Date of Patent: September 14, 1999
    Assignee: Becton, Dickinson and Company
    Inventors: Yelena G. Tropsha, Christopher J. Knors, Susan L. Burkett, Bryan Soo Wong
  • Patent number: 5952065
    Abstract: Products in the form of cushioning devices made from flexible membranes employing at least one layer including thermoplastic urethane and at least one layer of a copolymer of ethylene and vinyl alcohol are inflatable to a relatively high pressure. The cushioning devices maintain the internal inflatant pressure for extended periods of time by employing a phenomenon referred to in the industry as diffusion pumping. Ideally, the cushioning devices of the present invention can be permanently inflated with gases such as nitrogen or air.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: September 14, 1999
    Assignee: Nike, Inc.
    Inventors: Paul H. Mitchell, James C. Sell, Jr., Henry W. Bonk
  • Patent number: 5952066
    Abstract: A substantially transparent package or preform made of a polymer composition including an aliphatic polyketone as an oxygen scavenger having the formula ##STR1## where n is the number of repeating units and R is hydrogen, an organic side chain, or a silicon side chain. The aliphatic polyketone may be advantageously combined with other thermoplastic polymers to provide the desired injection molding and stretch blow molding characteristics for making substantially amorphous injection molded preforms and substantially transparent biaxially oriented polyester containers. A multilayer container package may be provided having a core layer of the oxygen scavenging composition, and inner and outer layers of polyethylene terephthalate (PET). The container may further include layers of a high-oxygen barrier polymer such as ethylene vinyl alcohol (EVOH).
    Type: Grant
    Filed: October 28, 1997
    Date of Patent: September 14, 1999
    Assignee: Continental PET Technologies, Inc.
    Inventors: Steven L. Schmidt, Wayne N. Collette, Ernest A. Coleman, Suppayan M. Krishnakumar
  • Patent number: 5948503
    Abstract: A fine fiber-reinforced elastomer composition (A) having a high elastic modulus, mechanical strength and creep resistance includes (a) 100 parts by weight of elastic component having a glass-transition temperature of 0.degree. C. or less, (b) 30 to 500 parts by weight of a polyolefin component and (c) 10 to 500 parts by weight of a polyamide component dispersed in the fine fiber form in the matrix consisting of the components (a) and (b), these components (a), (b) and (c) being chemically bonded to each other through a binding agent (d), for example, a silane coupling agent, and is useful for producing an elastic material having a high elastic modulus, an excellent fatigue resistance and a high isotropy, by admixing an additional elastic component (B) to the elastomer composition (A).
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: September 7, 1999
    Assignee: UBE Industries, Ltd.
    Inventors: Shinji Yamamoto, Kazuyoshi Fujii, Hideo Kurihara, Tatsuo Wada
  • Patent number: 5942297
    Abstract: A package for oxygen sensitive goods is made using a barrier material, an oxygen scavenging system, and a polymeric base which is reactive with the by-products of oxygen scavenging. Such packages demonstrate improved product quality.
    Type: Grant
    Filed: March 7, 1996
    Date of Patent: August 24, 1999
    Assignee: Cryovac, Inc.
    Inventors: Drew Ve Speer, Charles Robert Morgan, Thomas Andrew Blinka, Ronald Lee Cotterman
  • Patent number: 5942298
    Abstract: A laminated film comprising a base film and a layer which contains an inorganic layered compound and a resin and is formed by gravure coating a coating fluid comprising the inorganic layered compound and the resin under the conditions satisfying the following equation:7<log?2((G/B).times.100).sup.2 .times.(B+G).sup.2 .times.(GM)!<13wherein G is a rotational speed of a gravure roll (m/min.), B is a rotational speed of a backing roll (m/min.) and GM is a mesh number of a gravure roll, which film has good transparency and gas barrier properties.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: August 24, 1999
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Taiichi Sakaya, Toshiya Kuroda
  • Patent number: 5939185
    Abstract: A bearing material of silicon carbide particularly useful for application in the hot water field is provided having improved corrosion resistance under increased thermal stresses wherein the bearing material is characterized by a predominantly course-grained silicon carbide matrix of pressureless sintered silicon carbide having a biamodal grain sized distribution wherein the biomodal grain size distribution is formed by from 50 to 90% by volume of prismatic, tabular, silicon carbide crystallites having a length of from 100 to 1500 .mu.m and from 10 to 50% by volume of prismatic tabular silicon carbide crystallites having a length of from 5 to <100 .mu.m.
    Type: Grant
    Filed: October 29, 1997
    Date of Patent: August 17, 1999
    Assignee: Elektroschmelzwerk Kempten GmbH
    Inventors: Jochen Greim, Hubert Thaler, Michael Fundus
  • Patent number: 5939205
    Abstract: A gas barrier film comprising a polyamide film and an inorganic deposited layer laminated thereon, wherein the maximum shrinkage percentage after boiling treatment at 95.degree. C. for 30 minutes is not more than 3.5%. The gas barrier film of the present invention has excellent gas barrier property and water vapor-proof property even after boiling or retort treatment. Hence, the film of the present invention can serve well as a wrapping material for a wide range of objects that require high gas barrier property, such as food, medical products, industrial materials and the like, and has great industrial value.
    Type: Grant
    Filed: April 15, 1997
    Date of Patent: August 17, 1999
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Seiichiro Yokoyama, Shigeru Komeda, Kiyoshi Iseki, Yozo Yamada, Chikao Morishige, Hideyuki Mitamura, Satoshi Osame, Shinji Fujita
  • Patent number: 5939033
    Abstract: A system to deliver gas/vapor from solid materials. Specifically, the delivery system for the use of gas or vapor released from a solid material, such as a non-aqueous/solid hydrogen peroxide complex. The system is comprised of a delivery system that is configured to receive a plurality of disks containing the solid material and provide these disks into an injector. The injector heats the disks to produce a gas or vapor that is then provided into a chamber. The sterilization process can be done by gas or vapor alone, or in combination with plasma or ultra violet radiation. In particular, a control system automatically induces the delivery system to provide the injector with a disk and then remove the disk once the injection sequence is complete.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: August 17, 1999
    Assignee: Johnson & Johnson Medical, Inc.
    Inventors: Richard Jed Kendall, Xiaolan Chen, Michael Hahs, Paul Taylor Jacobs, Szu-Min Lin, Robert M. Spencer, Harold R. Williams
  • Patent number: 5939158
    Abstract: A laminar shaped article which exhibits substantial improvement in the fluid barrier properties over the laminate of the prior art. The article comprises a heterogeneous blend of: (a) polyolefin with (b) a melt blend of a nylon and a polyvinyl alcohol component, and a compatibilizer(c), which is either: i) a mixture of two different alkylcarboxyl-substituted polyolefins which serves as a compatibilizer; or ii) a small amount of alkylcarboxyl-substituted polyolefin with a small amount of grafted maleic anhydride moieties; or iii) a high weight percent of alkylcarboxyl-substituted polyolefin with a high graft level of grafted maleic anhydride moieties.
    Type: Grant
    Filed: March 24, 1998
    Date of Patent: August 17, 1999
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: Irene Greenwald Plotzker
  • Patent number: 5935705
    Abstract: The present invention provides a novel crystalline material Si.sub.x C.sub.y N.sub.z possessing a direct optical band gap of 3.8 eV. Many optoelectronic applications, such as blue light emitting diode and laser diode, may utilize this property.
    Type: Grant
    Filed: October 15, 1997
    Date of Patent: August 10, 1999
    Assignee: National Science Council of Republic of China
    Inventors: Li-Chyong Chen, Kuei-Hsien Chen, Dhananjay Manohar Bhusari, Yang-Fang Chen, Ying-Sheng Huang
  • Patent number: 5935879
    Abstract: The present invention is a non-woven fiber mat suitable for reinforcing resilient sheet floor coverings, such as vinyl floor coverings. The non-woven fiber mat is in the form of a sheet of reinforcement fibers which at least includes semi-coiled fibers and can also include coiled fiber, with one or more turns, and even some relatively straight or slightly curved fibers. It is desirable for most, if not all, of the reinforcement fibers to be made from glass. However, it may also be desirable for the reinforcement fibers to include glass fibers and synthetic fibers. It may even be possible for the reinforcement fibers to include only non-glass fibers. At least one polymeric binder is used for bonding together the reinforcement fibers so as to make the fiber mat a suitable substrate for reinforcing resilient sheet floor coverings, such as an interlayer for vinyl floor coverings.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: August 10, 1999
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventors: Gregory S. Helwig, W. Scott Miller, Kimberley A. Householder
  • Patent number: 5932305
    Abstract: A sealed container obtained by forming into a container a sheet comprising (A) a polymer of three-component system of bisphenol A, diphenyl carbonate and 1,10-decanedicarboxylic acid, (B) polypropylene and (C) ethylene-vinyl alcohol copolymer or polyamide obtained by the polycondensation reaction of m-xylylenediamine with adipic acid so that these (A), (B) and (C) are in order of (A)-(B)-(C)-(B) with (A) as an innermost layer of the container and sealing the container by a lid having gas barrier properties. This container is excellent in preservability and sealability and does not spoil the flavor of various foods which are contained therein.
    Type: Grant
    Filed: November 26, 1997
    Date of Patent: August 3, 1999
    Assignee: Sumitomo Bakelite Company, Limited
    Inventor: Seigo Akazawa
  • Patent number: 5928744
    Abstract: According to the invention, strong adhesion of the layers to each other and simple formation of a strong and leakproof connection with bags or connectors made from polypropylene or polycarbonate during steam sterilisation is achieved by the first plastic material containing at least one polymer which is dimensionally stable at temperatures of .gtoreq.121.degree. C., while the second plastic material contains at least one polymer which is no longer dimensionally stable at temperatures of .gtoreq.121.degree. C. A layer C) (2) is optionally present, the plastic material of which contains at least one polymer which is dimensionally stable at temperatures of .gtoreq.121.degree. C. The invention can be used for medical purposes, in particular as a fluid line in dialysis, infusion or artificial feeding, primarily in connection with connectors or medical bags.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: July 27, 1999
    Assignee: Fresenius AG
    Inventors: Klaus Heilmann, Thomas Nicola
  • Patent number: 5928745
    Abstract: The invention can comprise a thermoplastic fuel tank or container having a vapor barrier comprising a cyclodextrin composition. A modified cyclodextrin that is chemically modified with substituents that increase the compatibility of the cyclodextrin material in the fuel container material can be used. The improved fuel container obtains substantial barrier properties from the interaction between the cyclodextrin material in the fuel container materials with the fuel vapor permeant materials. The cyclodextrin in the fuel tank walls complexes or entraps fuel vapor that permeates through the materials making up the tank and are held within the tank material preventing the permeant fuel vapor from passing through the tank into the environment. The fuel vapor permeant can comprise a variety of well known materials including aliphatic and aromatic hydrocarbons, oxygenates such as tertiary butyl methyl ether, ethanol, methanol, and other combustible liquid fuel materials.
    Type: Grant
    Filed: September 16, 1997
    Date of Patent: July 27, 1999
    Assignee: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Neil J. Beaverson
  • Patent number: 5922460
    Abstract: A metal matrix composite material made of a fiber reinforcement having a coating of gadolinium and gadolinium boride, preferably as discrete layers, each having a thickness of 1 to 6 microns. This composite is made by coating reinforcing fibers with gadolinium using a deposition technique, further coating the fibers with gadolinium boride by a deposition technique and then consolidating the coated fibers into a metal matrix to form the metal matrix composite.
    Type: Grant
    Filed: May 21, 1997
    Date of Patent: July 13, 1999
    Assignee: The Secretary of State for Defence in her Britannic Majesty's Government of the United Kingdom of Great Britain & Northern Ireland of Defence Evaluation and Research Agency
    Inventors: Charles M. Ward-Close, Francis H. Froes, Deepak Upadhyaya, Panos Tsakiropoulos
  • Patent number: 5919547
    Abstract: A laminate comprising two or more films, at least one of the films being a coextruded, multilayer film, wherein the laminate delaminates within the coextruded, multilayer film when the laminate is subjected to a peel force ranging from 0.001 to 2.5 pounds per inch. The laminate advantageously provides the lid for a package and delaminates into a substantially gas-impermeable portion and a gas-permeable portion, with the gas-permeable portion being bonded directly to a product support member of the package. In this manner, the gas-impermeable portion may be peelably removed from the package to allow atmospheric oxygen to enter the interior of the package.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: July 6, 1999
    Assignee: Cryovac, Inc.
    Inventors: Patrick N. Kocher, Kimberly Ann Mudar, Walter Berndt Mueller, H. Walker Stockley
  • Patent number: 5914164
    Abstract: A thermoplastic multilayer packaging film is described which has a % free shrink at 100.degree..degree. C. lower than 30 in both directions and a % free shrink at 120.degree. C. higher than 45 in at least one direction, and comprises at least the following layers:(i) an oxygen barrier core layer comprising ethylene-vinyl alcohol copolymer;(ii) two outer or skin layers and(iii) two inner adhesive layers each adhering to opposite respective surfaces of the core layer,said film being characterized in that the outer layers (ii) essentially consist of a polymeric blend of a Component A and a Component B wherein Component A is used in a major amount and is selected from the group consisting of heterogeneous ethylene-.alpha.-olefin copolymers with a density .ltoreq.0.915 g/cc, homogeneous ethylene-.alpha.-olefin copolymers with a density .ltoreq.0.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: June 22, 1999
    Assignee: Cryovac, Inc.
    Inventors: Paolo Ciocca, Roberto Forloni
  • Patent number: 5910361
    Abstract: A hybrid yarn is made up of an intimate mixture of spun yarns of reinforcing fibers and spun yarns of thermoplastic matrix fibers. The spun yarns are obtained by cracking with slow, gradual stretching of the multifilaments. After stretching, parallel fibers are wrapped with a continuous thermoplastic filament. The invention may be used to produce hot-stamped parts.
    Type: Grant
    Filed: July 15, 1991
    Date of Patent: June 8, 1999
    Assignee: SA Schappe
    Inventors: Jean Guevel, Marc Francois, Guy Bontemps
  • Patent number: 5908676
    Abstract: An oxygen absorbing resin in which a deoxidizing composition is dispersed in a thermo-plastic resin mixture comprising (A) a thermoplastic elastomer and/or an ethylene propylene copolymer and (B) a thermo-plastic resin other than the above-mentioned (A), and having a flexural modulus of 600 MPa or less and an oxygen permeability of 130 cc.mm/m.sup.2.atm.day (23.degree. C., 50% RH) or more. The oxygen absorbing resin has an oxygen absorbing performance equal to that of a conventional deoxidizing agent in a small bag. A deoxidizing multi-layer structure which comprises a layer (I) comprising a thermoplastic resin layer having an oxygen permeability of 800 cc/m.sup.2.atm.day (23.degree. C., 50% RH) or more, a layer (II) comprising the oxygen absorbing resin, and a layer (III) having gas barrier properties. In addition, the deoxidizing multi-layer structure has a function of positively and efficiently absorbing oxygen.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: June 1, 1999
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Ryoji Otaki, Takashi Kashiba, Yoshiki Ito
  • Patent number: 5904983
    Abstract: An optical fiber protected from degradation caused by corrosion from environmental fluids. The optical fiber includes a core-cladding assembly surrounded with a thin quasi metal oxide film (preferably .about.10 nm in depth). Over time, particularly under the influence of the elevated temperatures, the initially deposited reagents of the thin film oxidize or hydrolyze, removing the organic components, and bonding a quasi metal oxide film on the surface of the cladding. The resulting film significantly retards corrosion by blocking the environmental fluids from reacting with flaws in the cladding surface of the fiber, thus improving the mechanical performance and reliability of the optical fiber. In addition, the thin film protects the fiber against incidental abrasions.
    Type: Grant
    Filed: May 23, 1997
    Date of Patent: May 18, 1999
    Assignee: Lucent Technologies Inc.
    Inventors: Maureen Gillen Chan, Daryl Inniss, Howard Edan Katz, Valerie Jeanne Kuck, Marcia Lea Schilling
  • Patent number: 5904980
    Abstract: Lightweight and strong electromagnetic interference (EMI) shielding and electrostatic discharge (ESD) reinforced degradable polymer and monomer material and plastic enclosure materials are provided for electronic devices and EMI shielded rooms. A degradable polymer or monomer (polylactic acid, starch and polycaprolactone, cellulose esters, zein, modified lesquerell and soybean oils, and glucaric acid) contain an EMIS/ESD additive of iron coated fibers, iron-carbone (Martensites), iron-nickel coated carbon fibers, stainless-steel fibers, aluminum fibers, conductive flakes, and conductive powders. Intrinsic conductive polymers such as polyparaphenylene, polyacetylene, polyanaline, polyquinoline and polythiophene are also used. By combining the degradable polymer/monomer and one or more of the additives, the enclosures meet the U.S. government requirements for electromagnetic interference (EMI) shielding and electrostatic discharge (ESD) on both consumer electronics and military application.
    Type: Grant
    Filed: May 13, 1997
    Date of Patent: May 18, 1999
    Inventor: Victor A. Rivas
  • Patent number: 5900297
    Abstract: The invention relates to the field of high temperature composites made by the chemical vapor infiltration and deposition of a binding matrix within a porous structure. More particularly, the invention relates to pressure gradient processes for forcing infiltration of a reactant gas into a porous structure, apparatus for carrying out those processes, and the resulting products. The invention is particularly suited for the simultaneous CVI/CVD processing of large quantities (hundreds) of aircraft brake disks.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: May 4, 1999
    Assignee: The B. F. Goodrich Company
    Inventors: James W. Rudolph, Mark J. Purdy
  • Patent number: 5897960
    Abstract: A laminate having a laminated structure of at least two layers includes a gas barrier film (A) formed from a mixture containing at least one poly(meth)acrylic acid polymer selected from the group consisting of poly(meth)acrylic acid and partially neutralized products thereof and a saccharide in a weight ratio of 95:5 to 20:80, and having an oxygen permeability constant of 5.00.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C. and 80% relative humidity, and a layer (B) formed from a thermoplastic resin. The film (A) and the layer (B) are laminated contiguously to each other. A process for the production of a laminate having a laminated structure of at least two layers comprises a step of forming a gas barrier film (A) having an oxygen permeability constant of 5.00.times.10.sup.-3 ml(STP).multidot.cm/m.sup.2 .multidot.h.multidot.atm{Pa} or smaller as measured under conditions of 30.degree. C.
    Type: Grant
    Filed: March 10, 1997
    Date of Patent: April 27, 1999
    Assignee: Kureha Kagaku Kogyo K.K.
    Inventors: Hiroyuki Oba, Hideaki Tanaka, Tomoaki Sato, Tomohisa Hasegawa
  • Patent number: 5895716
    Abstract: This invention relates to carbon--carbon (C--C) composite comprising carbon fibers or carbon fabric, carbon char on the carbon fiber or fabric and pyrolytic carbon on the carbon char, wherein the density of the carbon composite is at least 1.3 g/cc. The invention also relates to wet friction elements and power transmission devises containing the same. The invention also relates to methods of preparing the carbon--carbon (C--C) composites. These C--C composites and wet friction elements and power transmission devises made therefrom have improved friction properties desired by wet brakes and clutches. These C--C composites provide improvements in cost, and when run against metals, such as steel or iron, improvements in wear and frictional behavior compared to known C--C composites for wet friction applications. In one aspect, the carbon--carbon does not require bonding to a metal backing or core material.
    Type: Grant
    Filed: January 19, 1996
    Date of Patent: April 20, 1999
    Assignee: The B.F. Goodrich Company
    Inventors: Robert A. Fiala, William L. Tarasen
  • Patent number: 5895694
    Abstract: The present invention relates to a chlorine-free multilayer film material comprisinga) a gas-barrier layer (1) comprising a non-chlorine containing organic polymer which is substantially impermeable to oxygen gas;b) two tie layers (2) each contacting one side of said barrier layer;c) an inner surface layer (3);d) an outer surface layer (4); ande) two intermediate layers (5) positioned between said surface layers (3,4) and said tie layers (2), said barrier layers (5) comprising an ethylene-propylene copolymer having a flexural modulus of less than 200 MPa and preferably less than 150 MPa. a process for the manufacture of this film material and its use for the manufacture of bags and pouches for ostomy/urostomy use.
    Type: Grant
    Filed: September 6, 1995
    Date of Patent: April 20, 1999
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Emil Zavadsky, Vittorio Perego
  • Patent number: 5888638
    Abstract: A sealing element is made up of a shut-off body with a sealing surface; a bonding layer component provided on the sealing surface of the shut-off body and containing silicon and carbon; and a sliding layer component provided on the bonding layer component and containing silicon and carbon. The bonding layer component has a silicon content greater than that of the sliding layer component so that the bonding layer component has more ductile properties than the sliding layer component. The sliding layer component is harder than the bonding layer component. The sliding layer component is thinner than the bonding layer component and less than one um so that the bonding layer component takes up stresses of the sliding layer component without impairing adhesion capability of the bonding layer component to the sealing surface.
    Type: Grant
    Filed: May 20, 1997
    Date of Patent: March 30, 1999
    Assignee: Friedrich Grohe AG
    Inventors: Werner Kleinhans, Veit Bechte, Friedrich Wagner
  • Patent number: 5888645
    Abstract: A fiber-reinforced composite material and articles of manufacture formed thereof are formed by the method comprising: forming a compound material comprising a mixture of curable matrix-forming binder, heat resistant reinforcing fibers, and at least one particulate material, wherein the curable matrix-forming binder is 5 to 50% by volume of the compound material; curing the curable binder under simultaneous application of externally applied pressure and ultrasonic energy. Articles according to the invention are useful in a multitude of applications, particularly in applications where the article must retain its shape and properties when subjected to temperatures above the melting point of usual thermoplastic materials, e.g. above 1000.degree. C. The method provides dense, thermally stable, coherent composite materials having a desired high density. Forming and curing times are typically 10 times shorter than conventional methods, e.g. for brake pads in about 3-5 seconds.
    Type: Grant
    Filed: May 10, 1993
    Date of Patent: March 30, 1999
    Assignee: Obtec A/S
    Inventors: Torben Lindgaard, David Morgan Thomas
  • Patent number: 5885673
    Abstract: Packaging material 10 for a sealable, easy opening, tear resistant pouch-like package 100 comprises a first layer 12 including an oriented polymeric material having a front side capable of receiving surface printed information. A second layer 16 bonded to the first layer 12 includes a light barrier and moisture impervious material. Bonded to the second layer is a third layer 18 comprising a a coextruded film comprising carbon black-loaded linear low density polyethylene-EVA-polybutylene or carbon black loaded linear low density polyethylene film with an EVA gel lacquer coating. The material 10 overwraps the photographic product in a pouch-like structure comprising a flap 120, having along its length, a lengthwise seal 123 projecting outwardly of a second side 114. Second side 114 along with a first side 116 of package 100, extend between opposed hermetically sealed rearward and forward end portions 116,118.
    Type: Grant
    Filed: November 8, 1995
    Date of Patent: March 23, 1999
    Assignee: Eastman Kodak Company
    Inventors: Susan L. Light, Michael Long, Ronald W. Horiszny, Peter J. Harissis, Donald L. Woodrich
  • Patent number: 5879807
    Abstract: graphite sheet or block anode material can be used for non-aqueous lithium secondary battery, which has the improved characteristics of battery charge-discharge, as well as a circuit substrate and a shield plate in which dopants should be intercalated. The graphite sheet or block can be made of graphitized polymer film or films and comprises: a) an electric conductive body having a surface, in which graphite crystals are oriented along the surface of the graphite sheet or block and b) interphase insertion potions uniformly distributed over the surface of the graphite sheet or block, in which graphite phases are built perpendicularly to the surface to permit dopant to be inserted into a gap between graphite phases.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: March 9, 1999
    Assignee: Matsushita Electric Industrial Co.,Ltd.
    Inventors: Takao Inoue, Naomi Nishiki, Junji Ikeda
  • Patent number: 5876814
    Abstract: A method of preventing a container from becoming colored by contents of the container in a packaging process comprising filling and sealing colored contents in a packaging container having an inner surface comprising a plastic material and then disinfecting and sterilizing the contents by heat treatment, wherein said inner surface plastic material comprises a thermoplastic resin having a glass transition temperature (Tg) 10.degree. C. or more higher than the temperature of said heat treatment and a coefficient of moisture permeability at 40.degree. C. and 90% RH of 2.0 g.mm/m.sup.2.24 hr or less.
    Type: Grant
    Filed: August 6, 1996
    Date of Patent: March 2, 1999
    Assignee: Toyo Seikan Kaisha, Ltd.
    Inventors: Yasuhiro Oda, Yoshitsugu Maruhashi
  • Patent number: 5871844
    Abstract: A carbon-carbon part is provided comprising a composite substrate having a plurality of discontinuous filamentized fibers and a binder that binds said filaments together to form a composite substrate, and a plurality of carbon atoms deposited onto the filaments at a predetermined temperature so that the binder is removed completely from said filaments and replaced by said carbon atoms to form a dense carbon-carbon part. A method for producing the dense carbon-carbon part is also provided.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: February 16, 1999
    Assignee: Fiberite, Inc.
    Inventors: William Theys, Donald E. Wantock, Jeffrey J. Rose, Martin T. Choate
  • Patent number: 5866229
    Abstract: A textile composite material is used as tuft backing for tufted carpets, the composite material having at least one nonwoven fabric on which exclusively parallel-running, straight, load-absorbing, plastic, continuous filaments are rascheled, and a thin binding yarn serving as a knitting chain fixing the continuous filaments in position.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: February 2, 1999
    Assignee: Firma Carl Freudenburg
    Inventors: Rudolf Gartner, Bernhard Klein, Ararad Emirze, Christoph Josefiak
  • Patent number: 5866254
    Abstract: A reinforcement-containing metal-matrix composite material is formed by dispersing pieces of reinforcement material throughout a melt of a bulk-solidifying amorphous metal and solidifying the mixture at a sufficiently high rate that the solid metal matrix is amorphous. Dispersing is typically accomplished either by melting the metal and mixing the pieces of reinforcement material into the melt, or by providing a mass of pieces of the reinforcement material and infiltration of the molten amorphous metal into the mass. The metal preferably has a composition of about that of a eutectic composition, and most preferably has a composition, in atomic percent, of from about 45 to about 67 percent total of zirconium plus titanium, from about 10 to about 35 percent beryllium, and from about 10 to about 38 percent total of copper plus nickel.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: February 2, 1999
    Assignee: Amorphous Technologies International
    Inventors: Atakan Peker, William L. Johnson, Robert Schafer, David M. Scruggs
  • Patent number: 5863846
    Abstract: A slurry is molded from ceramic fibers and/or microparticles to form a soft felt mat which is impregnated with a sol prior to drying the mat. A catalyst for the sol is caused to diffuse into the mat by exposing the mat to the catalyst and subjecting the mat to a soak time during which the catalyst diffuses into the mat and causes the sol to gel. The sol-gel binder forms bonds so that the mat is dimensionally stabilized. The mat is dried to produce ceramic insulation.Ceramic insulation having a consistent microstructure and a fully gelled sol-gel binder through its entire thickness is also provided.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: January 26, 1999
    Assignee: The Boeing Company
    Inventors: Michael E. Rorabaugh, Darryl F. Garrigus, Juris Verzemnieks
  • Patent number: 5858537
    Abstract: In one embodiment the article includes a metal support having a top surface, a well provided in the top surface of the support and extends downwardly into the support, the well is defined by a floor at the bottom thereof, second fibers anchored in spaced relationship in the floor of the well and extending therefrom to a level short of the top surface of the support, a diamond substrate disposed over and covering the well, the substrate is larger than the well and has portions thereof in direct or indirect contact with the support, a metal layer adhering to the substrate, first fibers anchored in spaced relationship in the metal layer and extending therefrom into the well to a level short of said well floor, the substrate being smaller than the support.
    Type: Grant
    Filed: May 31, 1996
    Date of Patent: January 12, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Michael A. Brown, Nelson Hyman
  • Patent number: 5858530
    Abstract: A flexible, ignition resistant, biregional fiber is disclosed, wherein the fiber is preferably derived from a single homogeneous polymeric precursor composition, said biregional fiber comprising an inner core region of a thermoplastic polymeric composition and a surrounding outer sheath region of a thermoset carbonaceous material. The biregional fiber is particularly characterized by having a ratio of the radius of the core region with respect to the total radius of the fiber (r:R) of from about 1:4 to about 1:1.05, an LOI value of greater than 40, a breaking twist angle of from 4 to 13 degrees, and a bending strain value of from greater than 0.01 to less than 50%.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: January 12, 1999
    Inventor: Francis P. McCullough, Jr.