Abstract: The invention relates to a sizing for the treatment of glass fibers, which are incorporated into thermoplastic materials as reinforcement. The sizing contains a Schiff's base, preferably in concentrations of 0.05 to 2% by weight, based on the dry matter. Through the use of a sizing with this component, the tensile and impact strength properties of the glass fiber-reinforced thermoplastic materials are improved significantly.Key WordsSizing, glass fibers, roving preparation, glass fiber reinforcement, thermoplastic materials, tensile properties, tenacity properties.

Abstract: Disclosed is a glass fiber reinforced polyolefin resin composition comprising 15-80% by weight of polypropylene, 20-60% by weight of polybutene-1 and 5-60% by weight of glass fiber. This resin composition is excellent in the balance of impact strength, stiffness, heat distortion temperature, surface hardness and processability. When this composition is molded, the molded products have no surface roughness and no color shade and have good appearance. The properties are further improved when a modified polyolefin alone or together with a crystal nucleating agent are added.

Abstract: A method for impregnating a strand of filaments during the strand manufacture with thermoplastic or thermoset polymer powder particles is disclosed. The method includes the steps of forming a strand of filaments, keeping the filaments separate, impregnating the filaments with an aqueous slurry containing the powder particles, and drying the filaments to remove the water and produce a strand impregnated with powder particles. The powder particles are present on the strand in an amount of between about 5 to 50 weight percent based on the weight of the impregnated strand. Glass fibers coated with the slurry according to the process of this invention are suitable for impregnation with thermoplastic powders.

Abstract: An aqueous size composition for glass fibers is disclosed which includes a coupling agent, a binder or film former material and a thermoplastic polymer resin powder, wherein said composition is applied to the glass fiber surfaces during the fiber forming process. A rheology modifier material may be added to the size composition. One embodiment of the composition includes an organosilane coupling agent, a polyethylene oxide binder material and a polyamide thermoplastic polymer resin.

Abstract: The invention relates to a surface treatment for silicon carbide filaments. A carbon-rich silicon carbide layer or coating is formed over the silicon carbide surface. The ratio of silicon to carbon in the carbon-rich silicon carbide layer varies from 1 (stoichiometric) at the silicon carbide filament interface to about 0.43 (70% carbon, 30% silicon) at the exterior surface of the carbon-rich layer. A preferred method of making the carbon-rich silicon carbide layer is also presented.

Abstract: Disclosed is glass fiber reinforced thermoplastic sheet material suitable for various compression molding applications. The glass fibers useful in this invention are described in detail, and the thermoplastic composition is poly(ethylene terephthalate), poly(cyclohexylene dimethylene terephthalate) or a blend of either of these polyesters with each other and/or polycarbonate.

Abstract: Microemulsions are provided in which the oil phase comprises a reaction product of an organosilicon compound having amino groups and an organosilicon compound having epoxy groups, wherein the reaction product has at least one amino group and two silicon-bond --OR groups. A method for making the microemulsions which comprises reacting the two organosilicon compounds sufficiently to allow the reaction of some of the amine groups with the epoxy groups, but avoiding the excessive crosslinking of the components and their application in the treatment of fibrous materials is also described.

Abstract: A high temperature PVC resin blend is made by blending from 60 to 85 parts PVC with no more than 40 parts of a ("alpha-SAN") copolymer of alpha-methyl styrene ("AMS"), styrene ("S") and acrylonitrile ("AN"), and less than 20 parts by wt additives including stabilizers, antioxidants, lubricants, and processing aids. In addition, an impact modifier may be added. The blend with particularly sized glass fibers, may be thermoformed at an elevated processing temperature and pressure, to provide a reinforced composite in which the PVC is covalently bonded to the glass fiber. The composite has a substantially higher HDT and equivalent tensile strength, compared to that of a similarly reinforced, unblended PVC composite, without sacrificing the novel composite's other desirable physical properties.

Abstract: Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch--O--(G).sub.m --(M)--.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.

Abstract: A composite material comprising a para-oriented aramide fiber sheet and a thermosetting resin matrix. The composite material is characterized in that the reinforcing para-oiented aramide fiber sheet is pre-treated with a reactive siloxane oligomer prior to impregnation with the thermosetting resin. The reactive siloxane oligomer is represented by the following general formula (1) of: ##STR1## wherein Z is ##STR2## CH.sub.2 --O--, HS, NH.sub.2 -- or CH.sub.2 .dbd.CH--; m is an integer of from zero to 4; n is an integer of from 1 to 9; and R.sub.1 is the same or different groups selected from methyl, ethyl and phenyl.The composite material is improved in electric resistance properties, particularly after being dipped in boiling water, and also improved in thermal resistance to soldering.

Abstract: An aqueous emulsion comprising a major amount of polydimethylsiloxane and a small amount of an ethoxylated long-chain alkyl alcohol provides an advantageous finish for spandex filaments.

Abstract: Glass fibers are disclosed having the residue thereon of an aqueous size formulation in which the size formulation includes a film forming system which is substantially free of epoxy groups and which film forming system includes as a film forming material, a substantially fully reacted, preformed reaction product of a diglycidyl ether of a bisphenol or a partially or fully halogenated bisphenol with one or more monocarboxylic acids, one or more monohydric alcohols or mixtures thereof. The fibers are especially well adapted for producing cured polyester panels for use in greenhouses.

Abstract: Melt processable halogen-free low smoke wire coating compositions are provided which utilize a polyimide-siloxane, an effective amount of a plasticizer and hydrated zinc borate. The melt processable halogen-free low smoke blends can satisfy the low smoke requirements for plenum wire as shown by an Ohio State University test value of total smoke after 5 minutes of less than 100.

Abstract: Polyolefin coatings and films having release characteristics, also known as release sheets, are disclosed. The release sheets are formed by treating a sheet formed from polyolefin and dimethyl polysiloxane having functional end groups with a corona discharge. In a preferred embodiment, the release sheet is formed from polyolefin, the dimethyl polysiloxane, vinyl silane, an agent to graft the vinyl silane onto the polyolefin and a moisture curing agent by extrusion in the form of sheet, treating the sheet with a corona discharge and then subjecting the sheet to moisture. The release sheets may be used, for instance, as the backing sheet for labels.

Abstract: Disclosed are a polysaccharide derivative having the structure: ##STR1## and a polysaccharide graft polymer having the structure: Sacch-O-(G).sub.m -(M)-.sub.n, wherein Sacch- is a polysaccharide; m is zero or one; G is the residue of a polymerizable, unsaturated monomer which is bonded to the polysaccharide in an ether or ester linkage; n is greater than one; M is the residue of one or more polymerizable, unsaturated, monomer(s), at least one of which is a siloxane-containing monomer, which have been grafted to the polysaccharide by free radical polymerization; R is an organic group which is bonded to the polysaccharide by an ether or ester linkage and to the silicon by a carbon-silicon linkage; R.sub.1 is a straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl group, or an aryl, aralkyl or alkaryl group; and R.sub.2 and R.sub.3 are, independently, straight or branched C.sub.1 -C.sub.6 alkyl or alkenyl groups, or aryl, aralkyl or alkaryl groups, or alkoxides of straight or branched C.sub.1 -C.sub.

Abstract: A method of manufacturing a sensing element, comprising bringing a first body in the form of an oil-free cross-linked matrix of flexible elastomeric material, the matrix containing electrically conductive particles, into contact with a second body of flexible elastomeric material that is electrically insulating and that contains an oil compatible with the elastomeric material of the first body, and allowing oil to migrate from the second to the first body so as to cause swelling of the first body, the migration continuing until a state of oil phase equalisation between the two bodies is reached.

Abstract: Optical glass fibers are provided with a primary coating of organo-polysiloxanes, containing acrylic acid ester groups, corresponding to the general formula: ##STR1## where the primary coating is free of inert components capable of migration.

Abstract: Epoxide resins which are reinforced with aramid fibers and in which the adhesion between fibers and resin is improved by means of a pretreatment of the fibers with organosilanes.

Abstract: A coherent fire-resisting flexible sheet material for aerospace applications is provided consisting of a layer of ceramic fibers embedded in a silicone rubber compound. The ceramic fibers may be in the form of a plain woven fabric of monofilament fibers of alumino-boro-silicate and the silicone rubber compound can be a curable non-foaming methylphenyl silicone compound. In production, the silicone compound is applied to the fabric as a thixotropic paste in sufficient quantity to entirely cover and impregnate the fabric and is forced through the interstices of the fabric by the application of pressure. The coated and impregnated fabric is then placed in an oven to cure the silicone compound.

Abstract: A stranded insulated wire and a method of producing the same. The stranded insulated wire is produced by applying a coating material containing polyvinyl butyral and a stabilized polyisocyanate to an enameled strands assembly and then by baking the assembly. The coating material contains about 1 to about 1000 parts by weight of the stabilized polyisocyanate per 100 parts by weight of the polyvinyl butyral.

Abstract: Fluorocarbonylimino biurets derived from a tris(isocyanotoalkane)biuret, a fluoroaliphatic alcohol and a modifier group imports oil/water repellency, soil-release properties.

Abstract: A covered lead wire for vehicles, comprising a cover comprising a composition containing;(A) 100 parts by weight of polyvinyl chloride resin;(B) 0.1 part to 10 parts by weight of polyorganosiloxane;(C) at least 30 parts by weight of a plasticizer; and(D) at least 1 part by weight of a stabilizer.The present covered lead wire can achieve good abrasion resistance and scrape resistance even with reduced thickness of the cover, and can meet the recent demands for the weight-saving and improvement of wiring workability.

Abstract: A metal-coated substrate, e.g., of glass, ceramic, or a hydroxy-functionalized material, wherein the improvement comprises a polysilicate, titania, or alumina interlayer between the substrate and the metal coating. The interlayer may have a porous microstructure, e.g., a polysilicate interlayer with an average pore size on the order of 50-150 Angstroms.Such articles, e.g., in the form of metal-coated fibers, may suitably be employed as reinforcing media in material composites having utility in structural applications, such as EMI shielding elements.Also disclosed is a corresponding method for forming a metal coating on a substrate by the provision of an interlayer of the above type. The interlayer may suitably be formed by applying to the substrate a sol gel dispersion of the polysilicate, titania, or alumina material, followed by drying of the applied dispersion.

Abstract: Flexible, composite tubular devices of the present invention include a flexible plastic tube and a reinforcing flexible, tubular member at least substantially embedded in the tube, the member having an outer side, an inner side opposing the outer side and surrounding a hollow interior of the member, and a multiplicity of macroscopic pores substantially uniformly distributed around and along the member and extending through the tubular member between the outer and inner sides before the tubular member is incorporated into the composite tubular device of the invention, and the plastic of the tube extending through the pores between the inner and outer sides of the tubular members.

Abstract: The method is intended to provide cables (10) having an optical fiber (1) and suitable for mechanically severe environments, while remaining small in section. Heretofore, the mechanical strength of optical fiber cables has been obtained by plastic structures of considerable cross-sectional area and reinforced by metal strands or by glass fibers. In the method of the present invention, the reinforcing is obtained by metal composites (3) having very high mechanical strength and very small diameter, said composites extending parallel to the fiber (1).

Abstract: The present invention is directed to an optical glass fiber with a primary coating of organo-polysiloxanes containing acrylic acid ester groups which coating is inter alia hydrolysis stable and rapidly curable.

Abstract: A fiber finish especially suitable for tire yarns having 50-95% lubricants with at least 40% of the lubricants comprising ditridecyl sebacate and the yarns containing the finish are disclosed.

Abstract: An organopolysiloxane with contains alkoxy radicals and epoxy-containing radicals on its molecular terminals has been found to be useful for treating fibers to provide a durable softness and flexibility, smoothness, wrinkle resistance, or rebound to fibrous material. The organopolysiloxane is substantially free of oligomers so that, during drying in the fiber treatment process, oil does not collect on exhaust fans and drip onto the treated material, causing oily spots.

Abstract: Deep-colored fibrous articles, such as fabrics colored in a deep black shade, having on it surfaces a film coating of a resin mixture comprising at least two resins that are mutually miscible but incompatible and in phase-separated conditions. Color-deepening effect is augmented by forming pits and/or recesses and projections on the surfaces of the film coating by using resins different in solvent-solubility and eluting the resin having a larger solubility with a solvent. The above effect is further augmented by using resins different in plasma etching resistance and subjecting the formed film coating to a low-temperature plasma etching treatment. The plasma etching is effectively conducted by placing the fibrous article within a plasma sheath, preferably contacting with an antenna electrode. The deep color can be made abrasion resistant by further depositing an abrasion resistant resinous film on the pit-formed resinous film coating without filling up the pits.

Abstract: A high strength silicon carbide monofilament which has a core and a stoichiometric bulk layer of silicon carbide deposited on the core having an exterior surface and a core bulk layer interface, the bulk layer having an average grain size of less than 200 nanometers which size varies continuously across the cross section of the bulk layer, the variation comprising a first average grain size at the interface which increases to a maximum average grain size intermediate the interface and the exterior surface and then decreases to the minimum at the exterior surface. In an alternate embodiment a surface layer is deposited on the bulk layer of silicon carbide. A preferred method of making the silicon carbide monofilament is also presented.

Abstract: Organopolysiloxanes with Bunte salt groups linked over carbon atoms are disclosed, as well as methods for the synthesis of these compounds by the reaction of organopolysiloxanes having epoxy groups with, in relation to the epoxy groups, equimolar amounts of Me.sub.2 S.sub.2 O.sub.3, in which Me is an alkali metal or an optionally substituted ammonium group. The compounds may be used for the permanent finishing of fibers or fiber products or for the treatment of hair.

Abstract: A light-curable ethylenically unsaturated liquid coating composition which cures to provide low modulus coatings adapted for the primary or single coat coating of optical glass fiber and having improved adhesion is disclosed. This composition comprises:(1) an acrylate-terminated polyurethane oligomer;(2) a monoethylenically unsaturated liquid having a glass transition temperature, measured on a homopolymer thereof, below about 0.degree. C. and which reduces the glass transition temperature of the coating; and(3) a silsesquioxane oligomer polyacrylate which is the condensation reaction product of about two moles of hydroxyalkyl acrylate in which the alkyl group contains from 2 to 4 carbon atoms, with about one mole of a silsesquioxane polysilanol, the proportion of the silsesquioxane oligomer polyacrylate is in the range of from about 2% to about 60% of the weight of the coating composition.

Abstract: A rob material includes an elongated matrix made of synthetic resin, a plurality of first elongated textile elements, and a plurality of second elongated textile elements, the first and second elements being embeded within the matrix, parallel to each other along the matrix, each of the first elements being composed of a plurality of yarns braided together, the second elements having a lower breaking elongation rate than said first elements. In such a rod material, the second elements have a substantially complete elasticity, and the first elements have such an elongation rate as to elongate further after the fracture of the second elements. Therefore, the stress-strain curve of the rod material shows a high elastic modulus in the elastic region and a high breaking elongation rate. In other words, the stress-strain behavior is similar to that of steel rods.

Abstract: A flame-retardant composition is prepared by mixing 100 parts by weight of a rubber or plastics free from any halogen with about 50 to about 200 parts by weight of magnesium hydroxide having an average particle diameter of about 0.3 to about 2 .mu.m and about 5 to about 50 parts by weight of carbon black powder having an oil absorption of about 0.5 to about 2.0 ml/g, and then cross-linking the mixture with an organic peroxide, sulfur, or a sulfur compound as a vulcanizing agent. By forming an electrical insulation and/or a sheath of the flame-retardant composition, there is provided a flame-retardant cable of the type including a cable core composed of an electric conductor coated with the electrical insulation or a plurality of such cores twisted together and covered, together with a filler, with the sheath.

Abstract: A high temperature PVC resin blend is made by blending from 60 to 85 parts PVC with no more than 40 parts of a ("alpha-SAN") copolymer of alpha-methyl styrene ("AMS"), styrene ("S") and acrylonitrile ("AN") and less than 20 parts by wt additives including stabilizers, antioxidants, lubricants, and processing aids. In addition, an impact modifier may be added. The blend with particularly sized glass fibers, may be thermoformed at an elevated processing temperature and pressure, to provide a reinforced composite in which the PVC is covalently bonded to the glass fiber. The composite has a substantially higher HDT and equivalent tensile strength, compared to that of a similarly reinforced, unblended PVC composite, without sacrificing the novel composite's other desirable physical properties.

Abstract: Here is disclosed a glass fiber product for use in the reinforcement of fluororesin which is improved in the adhesiveness to fluororesin. Thus, a glass fiber product for use in the reinforcement of fluororesin pre-treated with perfluoroalkylsilane represented by the following formula:CF.sub.3 --CH.sub.2 --Ch.sub.2 --SiX.sub.3(X is a hydrolyzable group such as alkoxy groups having 1 to 4 carbon atoms) retains an excellent electrical insulation resistance.

Abstract: A coated, oriented polymer film laminate is provided which comprises:(a) an oriented core layer having an upper face and a lower face, said core layer being fabricated from a polypropylene homopolymer;(b) an oriented layer applied to the lower face, and optionally, to the upper face, of core layer (a), said layer being fabricated from a member of the group consisting of copolymer or blend of copolymers, homopolymer or blend of homopolymers, a blend of at least one copolymer and at least one homopolymer, terpolymer or blend of terpolymers, and a blend of at least one terpolymer and at least one homopolymer or at least one copolymer;(c) a coating layer applied to the upper face of core layer (a), or, where layer (b) has been applied thereto, to the exposed surface of said layer (b), and;(d) an adhesively bonded substrate or a coating composition applied directly to the exposed surface of layer (b) applied to the lower face of core layer (a).

Abstract: Ceramic fibers are prepared from improved preceramic fibers having a core comprising an organosilicon preceramic polymer and at least one co-spun sheath layer comprising a synthetic film-forming polymer.

Abstract: The flat electrical resistance heating element is intended principally for a household article having a heating surface.The heating element comprises a heating resistance cut out from a metal sheet (1) which is coated with a substrate (2) of electrically insulating material resistant to the heating temperature and adherent to the metal sheet (1) and to the material of which the support (5) of the heating surface of the article is made.Use principally in base-heated kitchen utensils and irons.

Abstract: A bis (alkoxysilyl) polyether is produced and utilized as a fabric sizing agent.

Abstract: A fiber-treatment composition based on a microemulsion, having an average particle size not larger than 0.15 micrometers, of a carboxyl-modified organopolysiloxane having a degree of polymerization of form 350 to 2000 and having at least two carboxyl groups in each molecule is characterized by an excellent mechanical stability, dilution stability, and blending stability, and can impart a durable softness, smoothness, wrinkle resistance, and compression recovery to fibrous material without the occurrence of oil spotting. Further stability of the microemulsion can be realized by adding a basic material to the microemulsion to adjust the pH of the microemulsion, preferably to a value of from 6.5 to 9.0.

Abstract: High-strength magnesium aluminosilicate glass fibers coated with the dried residue of a dilute aqueous sizing composition containing emulsified epoxy resin or emulsified epoxy resin solution, both 3-methacryloxypropyltrimethoxysilane and 3-aminopropyltriethoxysilane, and at least one lubricant, are compatible as reinforcing elements with unsaturated polyester, vinylester and epoxy resin matrixes.

Abstract: The invention relates to a method for producing ceramic composites obtained by oxidation of an aluminum parent metal to form a polycrystalline ceramic material by providing a filler having a coating of a silicon source on at least a portion of said filler different in composition from the primary composition of said filler, said silicon source possessing intrinsic doping properties. A body of molten parent metal, adjacent a mass of the filler material, reacts with an oxidant to form an oxidation reaction product which infiltrates the adjacent mass of filler thereby forming the ceramic composite.

Abstract: A high tenacity fiber for reinforcing plastic composites, the fiber being selected from the group consisting of polyester, aliphatic polyamide, and combinations thereof. The fiber is treated with a composition consisting essentially of an organofunctional silane in an amount sufficient to achieve 0.02 to 1.0 weight percent of the silane on the fiber, and a diluent which provides for the hydrolysis of the silane to a silanol. The fiber is used to reinforce a plastic composite additionally comprising a resin matrix.

Abstract: A silica fiber coated with an organosilsesquioxane polymer guide light and evidences excellent mechanical integrity under adverse conditions of temperature and humidity. The polymer serves as a suitable coating and cladding for silica-based fibers designed for low fabrication cost fiber optic applications, as a replacement for plastic coatings on silica-based fibers, and as a water barrier for fiber applications in humid environments. The polymeric material described evidences characteristics which are superior for both polymeric coatings (acrylate) and claddings (linear siloxanes).

Abstract: The silicone rubber obtained by curing in the presence of a platinum-containing catalyst a composition comprising an organopolysiloxane containing a plurality of lower alkenyl radicals and a organohydrogensiloxane consisting essentially of R.sub.3 SiO.sub.1/2 units, R.sub.2 SiO units, RHSiO units, and RSiO.sub.3/2 units in a specified molar ratio is uniquely suitable as the coating material for the press roll in the fixing assembly of an electrophotographic copier.

Abstract: A multicore optical fiber comprises a plurality of optical fiber elements disposed in parallel, each optical fiber element being equipped with a covering layer, a common covering layer integrally covering the plurality of optical fiber elements, and a peel layer provided on the outermost layer of each optical fiber element.

Abstract: Gas permselective membranes having a high selectivity and high flux are prepared by plasma polymerizing a coating onto the surface of a microporous membrane substrate. Two types of coatings are disclosed. Gas separatory modules utilize the novel membranes in the form of hollow fibers.

Abstract: A thermal insulation is formed by simultaneously spraying ceramic fibers and a binder at a surface to be covered. An aqueous binder is prepared prior to application to the fiber during the spraying operation. The binder includes an organic component which provides necessary wet and green adhesion to the substrate surface and wet and green cohesion to the newly formed lining prior to firing of the sprayed-on layer. The binder also includes an inorganic component which functions at and after exposure to a high temperature to secure the ceramic fibers to the substrate and to one another. Drying and firing of the layer develops strength in the inorganic binder. Known ceramic fibers such as alumina-silica amorphous fibers, alumina-silica-zirconia fibers, polycrystalline mullite fibers, alumina fibers, mineral fibers, or combinations thereof, and the like may be employed. The fiber may be precoated with the organic binder.

Abstract: The present invention relates to a polymer composition exhibiting high temperature oil resistance, while having improved modulus and tensile strength, as well as a novel insulated electrical conductor employing such material, said material comprising a polymeric constituent selected from the group consisting of copolymers of ethylene and propylene, polymers of same with other polymerizable materials, and mixtures of the foregoing, said constituent being in intimate mixture with a fully calcined aluminum silicate clay filler containing less than about 0.5 percent by weight water (based on the weight of the clay) having an average particle size less than 1 micron with at least about 80 weight percent of the particles having size finer than 2 microns and with at least about 10 weight percent of the particles being more finely divided than 0.5 microns.