Silane, Silicone Or Siloxane In Coating Patents (Class 428/391)
-
Patent number: 4810576Abstract: Chemically treated glass fibers of the present invention perform well as wet chopped strands of glass fibers and are useful in producing glass fiber paper. In one aspect the chopped strands of glass fibers have an aqueous chemical treatment comprised of at least one water soluble, ungelled polymer having an effective viscosity, an effective film-forming capability and an effective molecular weight. In another aspect the chemically treated glass fibers have a chemical treating composition having a polyoxyethylene polymer as the water soluble and ungelled polymer with an effective film forming molecular weight along with water soluble, dispersible or emulsifiable aldehyde-condensate-reactable, polymeric agent, cationic lubricant or lubricating surfactant, aldehyde-condensate-reactable organo silane coupling agents and a carrier like water.Type: GrantFiled: July 31, 1987Date of Patent: March 7, 1989Assignee: PPG Industries, Inc.Inventors: Peter C. Gaa, Jerry C. Hedden, Donald L. Motsinger, H. Kenyon Watkins
-
Patent number: 4810577Abstract: A heat and oil-resistant electric insulated wire comprises a conductor coated with an insulating layer which is formed of a vinylidene fluoride-based fluororubber and a silicone rubber added thereto. The amount of silicone rubber added is in a range of 2 to 30 parts by weight, preferably 5 to 20 parts by weight per 100 parts of said fluororubber, said fluororubber being a vinylidene fluoride-propylene hexafluoride copolymer and/or a vinylidene fluoride-propylene hexafluoride-ethylene tetrafluoride terpolymer.Type: GrantFiled: January 12, 1987Date of Patent: March 7, 1989Inventor: Norio Ikegaya
-
Patent number: 4808478Abstract: Chemically treated glass fiber reinforcement for thermosetting polymers having a moisture reduced residue of an aqueous chemical treating composition consisting essentially of a vinyl acetate-organosilane copolymer, a vinyl silane coupling agent, an amino-organo silane coupling agent, at least one cationic lubricant, polyoxyethylene, an antistatic agent, an aqueous dispersible or emulsifiable wax with a surfactant and water.Type: GrantFiled: September 5, 1986Date of Patent: February 28, 1989Assignee: PPG Industries, Inc.Inventors: David E. Dana, Richard A. Davis, Howard J. Hudson, Steven J. Morris
-
Patent number: 4806424Abstract: The present invention relates to a polymer composition exhibiting high temperature oil resistance, while having improved modulus and tensile strength, as well as a novel insulated electrical conductor employing such material, said material comprising a polymeric constituent selected from the group consisting of copolymers of ethylene and propylene, polymers of same with other polymerizable materials, and mixtures of the foregoing, said constituent being in intimate mixture with from about 1 to about 150 parts by weight (per 100 parts by weight of polymer) of processing oil, and a calcined aluminum silicate clay filler containing less than about 0.5 percent by weight water (based on the weight of the clay) having an average particle size less than 1 micron with at least about 80 weight percent of the particles having size finer than 2 microns and with as much as 10 weight percent of the particles being more finely divided than 0.5 microns.Type: GrantFiled: October 30, 1986Date of Patent: February 21, 1989Assignee: Camco, IncorporatedInventor: Robert E. Schultz
-
Patent number: 4801627Abstract: Vinyl chloride (VC) resins, particularly poly(vinyl chloride) (PVC) and chlorinated poly(vinyl chloride) (CPVC) are reinforced with glass fibers which have been sized with a particular aminosilane coupling agent and a particularly characterized basic film former. At the processing temperature of VC resin, containing a stabilizer against degradation during thermoforming, for example in an extruder, or on a mixing mill used to blend the resin with sized glass fibers, a reaction occurs between an aminosilane coupling agent and the VC resin which reaction involves C.dbd.C bonds in the homopolymer, provided the polymer film former in the size is more basic than poly(vinyl acetate) ("PVA"). The film former catalyzes the thermal dehydrohalogenation of the VC homopolymer at the fiber-resin interface so as to generate allylic Cl moieties in chains of the homopolymer, which moieties react with the amine groups of the aminosilane.Type: GrantFiled: August 18, 1986Date of Patent: January 31, 1989Assignee: The B. F. Goodrich CompanyInventors: Douglas B. Rahrig, Angelo J. Magistro, Richard G. Parker
-
Patent number: 4800124Abstract: A composition which is curable to an elastomer comprising (1) a siloxane gum having a Williams plasticity of at least 100 mm/100 at 25.degree. C., (2) a reinforcing silica filler, (3) a copolymer of R.sub.3 SiO.sub.0.5 units and SiO.sub.2 units in which R represent a monovalent hydrocarbon group having less than 7 carbon atoms, (4) mica and (5) an organic peroxide curing agent.The compositions are useful for providing fire resistant insulation on electrical equipment.Type: GrantFiled: June 25, 1987Date of Patent: January 24, 1989Assignee: Dow Corning, Ltd.Inventors: James H. Davis, Michael J. Dams
-
Patent number: 4797323Abstract: Very high levels of insulation resistance and of insulation resistance stability of insulating compositions having polyolefin bases and having polar organic additives are achieved in this invention. The polar organic additives can be organic halogenated flame retardants, such as decabromodiphenyl oxide. The surprising increase in insulation resistance and in insulation resistance stability is achieved by addition of certain antioxidants in combination and, particularly, the addition of a zinc salt of mercaptoimidazole and a sterically hindered ditertiary butyl phenol. The composition may be crosslinked by radiation or even by chemical means as through use or organic peroxides without loss of the surprisingly increased insulation resistance and insulation resistance stability.Type: GrantFiled: February 19, 1985Date of Patent: January 10, 1989Assignee: Vulkor, IncorporatedInventors: Alexander F. Wu, Robert B. Walters
-
Patent number: 4795678Abstract: Chemically treated glass fiber strands can have a reduced tendency for fiber breakage and fuzz ball production through the present invention. The present invention constitutes glass fiber strands where the glass fibers have a moisture-reduced, non-homogeneous residue having a lubricious phase, where the residue results from an aqueous chemical treating composition having: a lubricating system; an aqueous soluble, dispersible or emulsifiable film forming polymer that produces a non-rigid film; and water. The lubricating system has one or more polyoxyalkylene polyols and/or polyalkylene polyols with an effective high molecular weight in an effective amount of the solids of the aqueous chemical treating composition to form a lubricious phase and a cationic lubricant. The lubricating system can also have polyethylene glycol, wax, internally lubricated organo silane esters and mixtures thereof.Type: GrantFiled: March 14, 1988Date of Patent: January 3, 1989Assignee: PPG Industries, Inc.Inventor: Mikhail M. Girgis
-
Patent number: 4789593Abstract: Fast controlled wettability of glass fibers in a polymeric matrix is achieved by controlling the amount of unsaturation in the components of the chemical treatment present on the glass fibers. Glass fibers treated with an aqueous chemical treating composition having a polar thermoplastic film forming polymer, coupling agent and lubricant have these components with an amount of aliphatic unsaturation of less than 1.5 double bonds per mole of polymer or compound and a ratio of aliphatic unsaturation to aromatic unsaturation of not greater than 0.1. For the polar thermoplastic film forming polymer, the viscosity of the polymer is less than 10,000 centipoise and the aliphatic unsaturation can be controlled by limiting the amount of unsaturation on the monomer and also controlling the amount of solvent used in emulsifying the polymer in water. Also the components of the aqueous chemical treating composition have limited amounts of any component which is chain extension inducing or condensation reaction inducing.Type: GrantFiled: April 13, 1987Date of Patent: December 6, 1988Assignee: PPG Industries, Inc.Inventor: Balbhadra Das
-
Patent number: 4787709Abstract: The invention relates to an optical fiber of the step-index type using quartz glass or an inorganic optical glass as the core material and a fluorine-containing resin as the cladding material. A copolymer of vinylidene fluoride with hexafluoroacetone, preferably at a molar ratio in the range from 96:4 to 88:12, is employed as the cladding material. Using such a copolymer, a highly transparent and very strong and tough cladding layer can easily be formed by a solution coating method.Type: GrantFiled: February 6, 1986Date of Patent: November 29, 1988Assignee: Central Glass Company, LimitedInventors: Akira Kawada, Takashi Yasumura, Toshio Koishi
-
Patent number: 4786603Abstract: Hydrophilic glass fibers which have bonded to their surfaces a layer of silane molecules of the formula ##STR1## are useful for the separation of plasma from blood for haemostasiological testing. In the formula: the molecule is bonded at its end oxygen to a surface of a glass fibre; R.sub.1 is C.sub.2 -C.sub.6 alkylene; X is OH, C.sub.1 -C.sub.6 alkoxy, having n carbon atoms and up to (n-1) OH groups in which n is 1-6, or an amino acid or peptide residue; and each of R'.sub.3 and R".sub.3 is C.sub.1 -C.sub.6 alkyl, an oxygen bridge to the silicon atom of another silane molecule or an oxygen bridge to the glass surface. The fibres have an average diameter of from 0.2 to 5 microns and a density of 0.1 to 0.5 g/cm.sup.3.Type: GrantFiled: March 4, 1987Date of Patent: November 22, 1988Assignee: Boehringer Mannheim GmbHInventors: Hans Wielinger, Helmut Freitag
-
Patent number: 4783222Abstract: A surface treatment composition for glass fibers comprising an aqueous solution or emulsion of an organosilane which contains at least one isoimido group. The organosilane with the highest adhesion promotion is N-2-(isomaleimodo)aminoethyl-3-aminopropyl-trimethylsilane.Type: GrantFiled: November 17, 1987Date of Patent: November 8, 1988Assignee: International Business Machines CorporationInventor: Frank Druschke
-
Patent number: 4783364Abstract: Polyester fiberfill having spiral-crimp, especially in the form of an omega (.OMEGA.), that is randomly-arranged and entangled in the form of fiberballs with a minimum of hairs extending from their surface, and having a refluffable characteristic similar to that of down on account of the low cohesion between the balls. A process for making such fiberballs by repeatedly air-tumbling small tufts of such fiberfill against the wall of a vessel.Type: GrantFiled: October 21, 1986Date of Patent: November 8, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Marcus Ilan
-
Patent number: 4780369Abstract: The invention relates to a process for producing a tubular glass membrane with wall thicknesses between 5 and 30 microns and reproducible pore sizes between 11 A and 50 A. Alkali borosilicate glass is drawn into discrete hollow tubes and immediately cooled. The tubes are thermally treated to effect a phase separation into a coherent silicon dioxide phase and a boron oxide phase rich in alkali borate. The boron oxide phase is leached out with mineral acid. The tubes can be subsequently treated to give enlarged or reduced pores, asymmetric pores and coated surfaces.Type: GrantFiled: April 12, 1984Date of Patent: October 25, 1988Assignee: Jenaer Glaswerk, Schott & Gen.Inventors: Roland Schnabel, Alexander Holzel, Kurt Gotter
-
Patent number: 4775566Abstract: The present invention discloses a glass covered electrical insulation having an inner lining of glass fibers coated with a flexible, high temperature, electrically insulating silicon polymer, the electrically insulating layer then has a second layer of glass fibers overbraided on it and bonded to it by the use of a heat treating process. A further teaching is the method of making the flexible sleeving and a method of use. The sleeving is particularly adapted for use in VPI processing and has superior flexibility as well as higher temperature capabilities than sleeving of the prior art.Type: GrantFiled: August 15, 1986Date of Patent: October 4, 1988Assignee: Essex Group, Inc.Inventors: Louis G. Landry, Fabian Nunez
-
Patent number: 4769287Abstract: An electric cable having at least one conductor and at least one covering therefor obtained from the polymerization of a silanic monomer of a compound comprising a non-cross-linked base-polymer and a polymerizable silanic monomer present prior to polymerization in a quantity not less than 5 parts by weight with respect to 100 parts by weight of the base-polymer. Thepolymerization of the silanic monomer units forms a polymeric mesh which is closely interconnected and thoroughly compenetrated into the non-cross-linked base-polymer. In one embodiment the polymeric mesh may be grafted onto the base-polymer through the addition of an organic peroxide. Thus, there is provided an electric cable for use as building wires wherein the conductor covering is not cross-linked but is heat resistant to temperatures above the deformation temperature of the base-polymer.Type: GrantFiled: December 18, 1986Date of Patent: September 6, 1988Assignee: Societa' Cavi Pirelli S.p.A.Inventors: Antonio Zaopo, Flavio Casiraghi, Alessandro Secco
-
Patent number: 4767646Abstract: Aqueous overfinish compositions, yarns treated therewith, and methods of producing wet abrasion resistant cordage from the yarn are all disclosed. One of the compositions includes an oxidized polyethylene emulsified with a non-nitrogen, nonionic emulsifier and neutralized with an alkali hydroxide, and a compound selected from the group consisting of a siloxane of the comonomers dimethyl and 3-[(2-aminoethyl)aminopropyl], and an amide melamine wax. An alternate finish composition comprises an oxidized polyethylene, neutralized with ammonium hydroxide and emulsified with a non-nitrogen, nonionic emulsifier. Yarn treated with this alternate finish has enhanced wet abrasion resistance. Yarns of this invention are ideally suited for heavy ropes and other industrial cordage applications where wet and dry abrasion resistance and strength are desirable.Type: GrantFiled: October 24, 1985Date of Patent: August 30, 1988Assignee: Allied CorporationInventors: Colleen W. Cordova, Robert M. Marshall
-
Patent number: 4766181Abstract: Polyester resin is modified with siloxane block polymers in such a manner so as to form silicone-modified polyester copolymer domains of controlled size and distribution dispersed in the polyester matrix. These domains undergo microphase segregation and migration during the melt spinning and cold-drawing to the surface of the polyester fiber being formed so as to provide a silicone-sheathed polyester fiber.Type: GrantFiled: September 18, 1986Date of Patent: August 23, 1988Assignee: Union Carbide CorporationInventors: Robert L. Ostrozynski, George H. Greene, James H. Merrifield
-
Patent number: 4762750Abstract: More flexible bundles of high modulus, low elongation fibers are produced by the impregnated bundles and process of the present invention. The flexible bundle of fibers comprise a plurality of fibers having a first treatment of a moisture-reduced residue of an aqueous chemical composition and a second treatment of a moisture-reduced, partially cured impregnant of an aqueous chemical coating composition. The individual fibers in the impregnated bundle were first treated with an aqueous sizing composition having at least a fiber protectorant and optionally an antistatic agent and/or coupling agent. The impregnating composition has one or more water soluble, dispersible or emulsifiable elastomeric polymers that are essentially free of hydrocarbon diene and chlorine functionalities, and one or more crosslinking materials that are water soluble, emulsifiable or dispersible, and water.Type: GrantFiled: February 26, 1987Date of Patent: August 9, 1988Assignee: PPG Industries, Inc.Inventors: Mikhail M. Girgis, Ernest L. Lawton
-
Patent number: 4762392Abstract: There is provided a plastic optical fiber capable of exhibiting good light transmitting characteristics even at high temperatures, which comprises a core layer, a cladding layer, and a protective layer as basic consititutional units, wherein the protective layer has a heat distortion temperature [HDT] of at least 120.degree. C., a thickness of at least 10 .mu.m, and a cross-sectional area of at least 0.07 times the sum of cross-sectional areas of the core and cladding layers. There is also provided such a plastic optical fiber good in high-temperature light transmitting characteristics, which comprises a core layer, a cladding layer, and a protective layer as basic constitutional units and has a plastic coating layer having a silane-crosslinked structure provided as an outer layer thereof, wherein the protective layer has a heat distortion temperature [HDT] of at least 120.degree. C., a thickness of at least 10 .mu.m, and a cross-sectional area of at least 0.Type: GrantFiled: January 28, 1986Date of Patent: August 9, 1988Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takashi Yamamoto, Ryuji Murata, Yasuteru Tahara, Hiromu Terada, Kenichi Sakunaga
-
Patent number: 4762751Abstract: More flexible bundles of high modulus, low elongation fibers are provided by the impregnated bundles of the present invention. The flexible bundle of fibers comprise a plurality of fibers having a first treatment of a moisture-reduced residue of an aqueous chemical composition and a second treatment of a moisture-reduced, partially-cured impregnant of an aqueous chemical coating composition. The individual fibers in the impregnated bundle were first treated with an aqueous sizing composition having at least a fiber protectorant and optionally an antistatic agent and/or coupling agent. The impregnating composition has one or more elastomeric curable polyurethanes that are water soluble, emulsifiable or dispersible and one or more crosslinking materials that are water soluble, emulsifiable or dispersible and water. Optionally, there may be present one or more emulsifiable or dispersible lubricants, plasticizers, polymeric materials, and flame retardants.Type: GrantFiled: May 22, 1986Date of Patent: August 9, 1988Assignee: PPG Industries, Inc.Inventors: Mikhail M. Girgis, Ernest L. Lawton
-
Patent number: 4758637Abstract: Polyester resin is modified with siloxane block polymers in such a manner so as to form silicone-modified polyester copolymer domains of controlled size and distribution dispersed in the polyester matrix. These domains undergo microphase segregation and migration during the melt spinning and cold-drawing to the surface of the polyester fiber being formed so as to provide a silicone-sheathed polyester fiber.Type: GrantFiled: November 21, 1986Date of Patent: July 19, 1988Assignee: Union Carbide CorporationInventors: James H. Merrifield, George H. Greene
-
Patent number: 4755427Abstract: A method and apparatus for forming reinforcing fibers for composites. The fibers comprise bundles of non-crystalline glass or carbon fibers formed in a helix and cut to small lengths for inclusion in molded composites to render the composites substantially isotropic.Type: GrantFiled: December 23, 1985Date of Patent: July 5, 1988Assignee: Massachusetts Institute of TechnologyInventor: Craig L. Cartwright
-
Patent number: 4752527Abstract: Chemically treated glass fibers having good processability are useful in producing fiber reinforced polymeric matrices, wherein the glass fibers have good wettability and are not detrimental to the weatherability of the fiber reinforced polymeric matrices. The chemically treated fibers have the dried residue of an aqueous chemical treating composition having at least a bisphenol A polyester film forming polymer compatible with and soluble in the matrix polymer, acryloxy-containing or methacryloxy-containing organo coupling agent in an effective coupling agent amount, cationic fiberous lubricant in an effective lubricating amount, with an antistatic agent that is a cationic organic quaternary ammonium salt having alkoxy moieties, and water in an amount to give a total solids for the aqueous chemical treating composition in the range of about 1 to about 30 weight percent. The aqueous chemical treating composition is essentially free of inorganic antistatic agents.Type: GrantFiled: October 30, 1986Date of Patent: June 21, 1988Assignee: PPG Industries, Inc.Inventors: George V. Sanzero, Howard J. Hudson, David T. Melle
-
Patent number: 4748197Abstract: A high tenacity fiber for reinforcing plastic composites, the fiber being selected from the group consisting of polyester, aliphatic polyamide, and combinations thereof. The fiber is treated with a composition consisting essentially of an organofunctional silane in an amount sufficient to achieve 0.02 to 1.0 weight percent of the silane on the fiber, and a diluent which provides for the hydrolysis of the silane to a silanol. The fiber is used to reinforce a plastic composite additionally comprising a resin matrix.Type: GrantFiled: June 27, 1984Date of Patent: May 31, 1988Assignee: Allied CorporationInventors: David S. Cordova, David R. Coffin, Stanley D. Lazarus, Hugh H. Rowan, Robert M. Marshall
-
Patent number: 4745028Abstract: Strands of chemically treated glass fibers of the present invention result in fiber reinforced polar thermosetting and thermoplastic polymers having good strength properties. The chemically treated glass fibers are treated with the an aqueous chemical treating composition having an epoxy polyurethane copolymer or a polyepoxide resin with blocked polyisocyanate functionality, and at least one or more organo coupling agents. The epoxy polyurethane copolymer or epoxy with polyisocyanate functionality can be chain extended with organic polyols. The blocked polyisocyanates can be either partially or fully blocked. Also the aqueous chemical treating composition can have one or more cationic and/or nonionic fiber lubricants, epoxy polyvinly acetate copolymer in conjunction with an ethylene vinyl acetate copolymer or an epoxy polymer and mixtures of the fiber lubricant with the polymeric materials.Type: GrantFiled: June 17, 1986Date of Patent: May 17, 1988Assignee: PPG Industries, Inc.Inventors: Balbhadra Das, Chester S. Temple, Carl A. Melle
-
Patent number: 4738509Abstract: The invention provides an optical glass fiber having a synthetic resin cladding, in which the first layer of the synthetic resin cladding is formed from a curable synthetic resin composition which comprises a polyurethane acrylate and a siloxane copolymer containing acrylate groups.The synthetic rubber obtained by curing has the suitable properties of polysiloxane claddings, and additionally a greater mechanical strength as well as a greater resistance to wear.Type: GrantFiled: May 28, 1985Date of Patent: April 19, 1988Assignee: U.S. Philips CorporationInventors: Dirk J. Broer, Grietje N. Mol
-
Patent number: 4735858Abstract: A heat-resistant prepreg uses at a substrate a heat-resistant material made of heat-resistant organic fibers, inorganic fibers, etc. and as a matrix a heat-resistant mixture containing at least 10% by weight of a borosiloxane resin composition. This heat-resistant prepreg is obtained by impregnating the substrate at a temperature in the range of 200.degree. to 300.degree. C. to such an extent that at least 20% of the amount of phenyl groups bonded to silicon atoms in the aforementioned borosiloxane resin composition prior to the impregnating and drying steps will remain after the heat treatment.Type: GrantFiled: July 18, 1986Date of Patent: April 5, 1988Assignee: Showa Electric Wire & Cable Co., Ltd.Inventors: Etsuo Hosokawa, Hiroshi Hashimoto
-
Patent number: 4734329Abstract: Shock absorbing missile launch pad for Mx type missiles having molded ethylene propylene diene terpolymer composition. Pad has curved resilient rubber pad with a Teflon-fiberglass laminate bonded to outer convex surface thereof, and has a support plate bonded to the inner concave surface thereof. Springs are provided to urge pad away from missile at launch to prevent damage to missile.Type: GrantFiled: May 29, 1984Date of Patent: March 29, 1988Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: George E. Rudd, Joseph F. Meier, John T. Siemon, James O. Bowden, David F. Weir
-
Patent number: 4733942Abstract: The coated optical fiber of the invention is prepared by providing a coating layer of an ultraviolet-curable organopolysiloxane or a composition comprising the same and irradiating the coating layer with ultraviolet. Specifically, each of the terminal silicon atoms of the organopolysiloxane, which preferably has a linear molecular structure, has two or more ethylenically unsaturated polymerizable groups bonded thereto through an oxygen atom, such as CH.sub.2 .dbd.CHCOOCH.sub.2 CH.sub.2 --, [CH.sub.2 .dbd.C(CH.sub.3)COOCH.sub.2 ].sub.3 C--CH.sub.2 --and (CH.sub.2 .dbd.CHCOOCH.sub.2).sub.2 C(C.sub.2 H.sub.5)CH.sub.2 --. By virtue of this unique molecular structure of the organopolysiloxane, the coating layer is rapidly cured by ultraviolet irradiation to give a cured coating layer exhibiting very low water absorption and small temperature dependency of the Young's modulus at low temperatures.Type: GrantFiled: November 12, 1986Date of Patent: March 29, 1988Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshinori Hida, Shohei Kozakai, Seiji Katayama, Noriyuki Meguriya
-
Patent number: 4728573Abstract: Glass fibers are prepared with a chemical treatment resulting in chemically treated glass fibers having utility in reinforcing thermoplastic polymers such as polyolefins. The chemically treated glass fibers have a dried residue of an aqueous chemical treating composition having one or more amino organo coupling agents, an aqueous emulsion of an acid or anhydride modified polyolefin having one or more surfactants, wherein the polyolefin is neutralized with an organic or inorganic base with a basicity less than the basicity of the amino moiety of the coupling agent, a binder stabilizer, one or more film forming polymers, and water. The aqueous chemical treating composition is essentially free of cationic lubricants that are amidated fatty acids and polyvinyl acetate homopolymer.Type: GrantFiled: May 7, 1986Date of Patent: March 1, 1988Assignee: PPG Industries, Inc.Inventor: Chester S. Temple
-
Patent number: 4722864Abstract: Application of hydrophobic silica to an anisotropic-melt forming polyester yarn reduces interfilament and intrafilament fusion during heat-strengthening. Improvements in adhesion of yarn to certain matrices are noted.Type: GrantFiled: March 25, 1987Date of Patent: February 2, 1988Assignee: E. I. Du Pont de Nemours and CompanyInventor: Abraham Matthews
-
Patent number: 4718748Abstract: The invention provides an optical glass fibre having a synthetic resin cladding and a method of manufacturing same, in which the first layer of the synthetic resin cladding is formed from a curable polysiloxane composition.The curing rate is increased by the presence of acrylate groups. The refractive index (exceeding 1.46) and the glass transition temperature (lower than -50.degree. C.) can be adjusted by the ratio of the dimethyl siloxane groups, methyl phenyl siloxane groups and diphenyl siloxane groups present. The curing rate can furthermore be increased by the addition of monomeric acrylate compounds.Type: GrantFiled: March 4, 1985Date of Patent: January 12, 1988Assignee: U.S. Philips CorporationInventors: Dirk J. Broer, Grietje N. Mol
-
Patent number: 4705722Abstract: A gland packing having increased compressibility, increased allowable limit of twist, increased tensile strength, and excellent serviceability and versatility characteristics is disclosed which comprises a plurality of flexible graphite sheets cut to a width of less than 5 mm and laid in superposed relation to one another, the laid-up cut sheets being covered with a fiber material by knitting or braiding to form a knitting thread, the knitting thread being twisted. Also, a gland packing having a further increased tensile strength is disclosed wherein a plurality of strands of the knitting thread are gathered and twisted or braided. In addition, a gland packing having improved contacting and sealing properties is disclosed wherein the covering fiber material exposed on the surface of the packing is removed at least in part.Type: GrantFiled: November 26, 1986Date of Patent: November 10, 1987Assignee: Nippon Pillar Packing Co., Ltd.Inventors: Takahisa Ueda, Tomikazu Shiomi
-
Patent number: 4704335Abstract: The present invention is directed toward a highly flexible, silicone rubber coated inorganic yarn based sleeving and a process for making the invention comprising an inorganic yarn sleeving, i.e., glass fibers, formed into a sleeving which is then coated with a highly flexible silicone rubber which has a Shore-A durometer reading of about 40 or less of the cured silicone material.Type: GrantFiled: October 26, 1984Date of Patent: November 3, 1987Assignee: Essex Group, Inc.Inventors: Louis G. Landry, Fabian Nunez
-
Patent number: 4702554Abstract: A coated optical fiber comprising an optical fiber for transmitting information having coated thereon a ring-opened (co)polymer of a norbornene derivative having a polar group. Due to the excellent moldability of the polymer, the coated optical fiber can be produced with high productivity. Even when the coated optical fiber is produced at high speeds, the molding strain on the coating is small, and the coated optical fiber has a reduced heat shrinkage.Type: GrantFiled: August 24, 1984Date of Patent: October 27, 1987Assignee: Mitsubishi Petrochemical Co., Ltd.Inventors: Hiroshi Takahashi, Tetsuji Kakizaki, Mitsuyoshi Kato, Koji Nishida
-
Patent number: 4697877Abstract: The surface-coated optical fiber of the invention is composed of a fibrous body of a vitreous material, e.g. fused quartz glass, and a coating layer thereon formed of a coating composition comprising an organosiloxane-modified organic polymer, of which the backbone is formed of recurring organic units such as a polybutadiene, an acrylic polymer and the like having modifying pendant groups containing an organosiloxane unit. The workability of the coating composition in the coating application is excellent so that a high uniformity is obtained in the coating layer in comparison with a coating composition comprising an unmodified organic polymer. The coating layer thus formed has a remarkably improved mechanical strength over a coating layer formed of an organopolysiloxane resin alone.Type: GrantFiled: March 6, 1985Date of Patent: October 6, 1987Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Yoshinori Hida, Noriyuki Meguriya, Akira Yoshida
-
Patent number: 4689267Abstract: This invention provides a composite hollow fiber comprising a porous hollow fiber substrate and a coating layer formed on at least one of the outer surface and the inner surface of said substrate. The coating layer comprises a polymer having at least one of the structural units represented by the formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom or a lower alkyl group; R.sup.2, R.sup.3 and R.sup.4, which may be identical or different, represent a hydrogen atom, a monovalent hydrocarbon group having 1 to 8 carbon atoms or a monovalent silicon-containing organic group.This composite hollow fiber is excellent in gas permeability and gas separation performance and has high heat resistance, humidity resistance and mechanical strength.Type: GrantFiled: July 26, 1985Date of Patent: August 25, 1987Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Minoru Takamizawa, Akira Yamamoto, Shigehiro Nagura
-
Patent number: 4681800Abstract: An impregnated, soft, flat sealing gasket and a method of manufacturing same which includes the steps of impregnating a fiber mat with a liquid, cross-linkable silicone impregnating agent which includes a cross-linking agent which forms radicals under the influence of heat; heating the silicone-impregnated fiber mat to cause at least partial cross-linking of the silicone impregnating agent; and irradiating the impregnated fiber mat with high energy radiation to cause cross-linking of the silicone impregnating agent present therein, whereby the silicone impregnating agent present in surface regions of the flat sealing gasket is cross-linked to a greater degree than obtainable by thermal treatment alone.Type: GrantFiled: January 17, 1986Date of Patent: July 21, 1987Assignee: Goetze AGInventors: Hans-Rainer Zerfass, Franz-Josef Giesen
-
Patent number: 4681805Abstract: Strands of starch-oil chemically treated glass fibers can have improved performance in high humidity environments. Such strands have a sole starch, film-former modifier which is a poly(oxypropylene) organic alcohol. Starch-oil sizings for treating glass fibers having polyethylene glycol are converted to improved starch-oil sizing compositions by substituting the poly(oxypropylene) organic alcohol for the polyethylene glycol. The strands of chemically treated glass fibers with improved high humidity performance are also made more lubricious by having a moisture-reduced residue of the starch-oil aqueous chemical treating composition with the poly(oxypropylene) organic alcohol. The more lubricious characteristic is effected by having present a starch mixture of a high amylose cationic starch and a highly crosslinked starch of approximately 50 percent amylose and wax in an amount less than the starch mixture but more than the oil and a cationic lubricant wetting agent and bacteriocide or fungicide.Type: GrantFiled: December 23, 1985Date of Patent: July 21, 1987Assignee: PPG Industries, Inc.Inventor: Garry D. Puckett
-
Patent number: 4680229Abstract: Halogen-free, flame-resistant hydrocarbon polymer compounds comprising an organopolysiloxane gum, and a lead compound, and electrical conductors insulated therewith.Type: GrantFiled: July 22, 1985Date of Patent: July 14, 1987Assignee: General Electric CompanyInventors: Joseph E. Betts, Fred F. Holub
-
Patent number: 4668578Abstract: Metallic filaments, esp., metal-coated fibers, are surface treated by a combination of silane and poly (vinyl acetate) and exhibit improved processability when used in the form of filaments, yarns or tows in knitting and weaving machines, and produce composites with thermosetting organic polymers, having enhanced physical properties.Type: GrantFiled: November 13, 1984Date of Patent: May 26, 1987Assignee: American Cyanamid CompanyInventor: Bruce A. Luxon
-
Patent number: 4663231Abstract: Coated fabrics produced with more flexible bundles of filaments -are possible with the flexible bundle of filaments of the present -invention. The flexible bundle of filaments comprise a plurality of -sized filaments having the moisture-reduced partially cured coating and -impregnant of an aqueous chemical coating composition. The composition -has a vinyl-containing interpolymer with one or more comonomers and a -self-crosslinking polymeric material and water. Optionally, there may be -present one or more aqueous emulsifiable or dispersible waxes, aqueous -dispersible or emulsifiable plasticizers and/or one or more aqueous -dispersible or emulsifiable diene-containing elastomers. The -diene-containing elastomer is always present when the comonomer of the -ethylene-containing interpolymer tends to decrease the noncrystallinity -of the interpolymer or increase the glass transition temperature of the -interpolymer.Type: GrantFiled: May 22, 1986Date of Patent: May 5, 1987Assignee: PPG Industries, Inc.Inventors: Mikhail M. Girgis, Ernest L. Lawton
-
Patent number: 4660927Abstract: The invention provides a novel silicone-coated, quartz glass-made optical fiber which is very advantageous in the high efficiency of the coating process as well as in the improved workability in the connecting works of the fiber terminals for extension of the communication lines by virtue of the excellent peelability of the coating layer from the surface of the quartz glass fiber even by mere drawing the coated fiber between fingers. The coating layer is formed of a radiation- or UV-cured silicone composition comprising (A-a) an organopolysiloxane having aliphatic unsaturation, e.g. vinyl, and/or (A-b) an organopolysiloxane having mercaptoalkyl groups, e.g. 3-mercaptopropyl groups, and (B) a curing accelerator.Type: GrantFiled: August 17, 1983Date of Patent: April 28, 1987Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Kiyohiro Kondow, Nobuo Takasaka, Yoshinori Hida
-
Patent number: 4661405Abstract: Compositions comprising higher alkyl modified epoxy silicone terpolymers having the general formula:MD.sub.x D'.sub.y D".sub.z M whereinM=R.sub.3 SiO.sub.1/2D=R.sub.2 SiOD'=E--C.sub.b H.sub.2b Si(R)OE is either ##STR1## D"=R'Si(R)O R+lower alkyl of 1 to 6 carbon atomsR'-high alkyl of at least 6 carbon atomsr=0 to 7b=2 to 12x=20 to 500y=4 to 15z=4 to 40 ##EQU1## said higher alkyl modified epoxy silicones are formed into aqueous emulsions using anionic and non-ionic emulsifiers. The resulting emulsions are useful as fiber and/or textile finishes.Type: GrantFiled: March 29, 1984Date of Patent: April 28, 1987Assignee: Union Carbide CorporationInventors: George H. Greene, Robert A. Daniele, Jr.
-
Patent number: 4643946Abstract: Silica-containing acrylic and modacrylic fibres are obtained without spinning defects in that an aqueous silica sol is reacted with a silane and with a polar organic solvent, the sequence in which the two agents are added being optional, the water is distilled off in a vacuum at a temperature of at most 60.degree. C., the thread-forming polymer is then added in a quantity which is sufficient to form a spinnable solution and the solution is spun.Type: GrantFiled: November 12, 1985Date of Patent: February 17, 1987Assignee: Bayer AktiengesellschaftInventors: Wolfgang Brauer, Bernd Willenberg, Siegfried Korte, Carlhans Suling
-
Patent number: 4642265Abstract: A silicone coating material of a vinyl containing polyorganosiloxane, a polyorganohydrogensiloxane, a platinum catalyst, and an amorphous silica powder with a primary particle size of less than 0.2 .mu.m is used to make optical communication glass fiber which has a cross-sectional structure of glass fiber core, a layer of the cured silicone coating material, and the exterior of the silicone coating material being covered with a thermoplastic resin material. The optical communication glass fiber made in this manner has a peelable coating such that the silicone coating material can be stripped from the glass fiber core.Type: GrantFiled: May 11, 1983Date of Patent: February 10, 1987Assignee: Toray Silicone Co., Ltd.Inventor: Toshio Suzuki
-
Patent number: 4640962Abstract: Polyester resin is modified with siloxane block polymers in such a manner so as to form silicone-modified polyester copolymer domains of controlled size and distribution dispersed in the polyester matrix. These domains undergo microphase segregation and migration during the melt spinning and cold-drawing to the surface of the polyester fiber being formed so as to provide a silicone-sheathed polyester fiber.Type: GrantFiled: September 11, 1985Date of Patent: February 3, 1987Assignee: Union Carbide CorporationInventors: Robert L. Ostrozynski, George H. Greene, James H. Merrifield
-
Patent number: 4637956Abstract: Strands of chemically treated glass fibers of the present invention result in fiber reinforced polar thermosetting and thermoplastic polymers having good strength properties. The chemically treated glass fibers are treated with the an aqueous chemical treating composition having an epoxy polyurethane copolymer or a polyepoxide resin with blocked polyisocyanate functionality, and at least one or more organo coupling agents. The epoxy polyurethane copolymer or epoxy with polyisocyanate functionality can be chain extended with organic polyols. The blocked polyisocyanates can be either partially or fully blocked. Also the aqueous chemical treating composition can have one or more cationic and/or nonionic fiber lubricants, epoxy polyvinyl acetate copolymer in conjunction with an ethylene vinyl acetate copolymer or an epoxy polymer and mixtures of the fiber lubricant with the polymeric materials.Type: GrantFiled: March 29, 1985Date of Patent: January 20, 1987Assignee: PPG Industries, Inc.Inventors: Balbhadra Das, Chester S. Temple, Carl A. Melle
-
Patent number: 4636437Abstract: A coating composition substantially prevents fraying of glass fiber yarn packages. The composition is composed of an aqueous solution of a resin formed of the hydrolysis product of a copolymer of vinyl aromatic monomer and maleic anhydride, an organo silane glass fiber anchoring agent and an effective amount of a water-soluble pyrrolidone-containing polymer sufficient to form a protective film over the glass fiber.Type: GrantFiled: November 5, 1984Date of Patent: January 13, 1987Assignee: Owens-Corning Fiberglas CorporationInventors: Donald J. Algrim, Donn R. Vermilion, Donald J. Hammond, Richard M. Haines