Abstract: The invention provides a sizing composition based on water-soluble polymers, intended for sizing warps of textile yarns and a process for obtaining such compositions and for the sizing of textile yarns. More particularly, provided are compositions comprising, 40 to 90% by weight of a polyester-urethane and 10 to 60% by weight of an acrylic and/or vinyl polymer especially suitable for sizing polyester yarns such as polyethylene terephthalate.

Abstract: The present invention relates to an adhesive for use in the manufacture of a composite yarn product, that results in the preparation of a product having improved strength and resistance to distortion and fracture in use, in combination with improved texture and appearance. The adhesive composition comprises a first component and a second component, the first component including a resin material selected from acrylonitrile-butadiene copolymers, and butadiene-styrene copolymers. The first component is prepared in an organic solvent system. The second component contains an epoxy resin such as a bisphenol A-derived diepoxide, and a vinylchloride-vinylacetate copolymer, prepared in a like organic solvent system.The adhesive composition is prepared by the individual mixture of the respective components followed by the addition of the first component to the second component under agitation.

Abstract: A fiber-reinforced composite material comprising a resin and 20 to 90% by weight, based on the composite material, of reinforcing fibers, said reinforcing fibers comprising fibers of a wholly aromatic polyamide consisting essentially of(1) structural units of the formula ##STR1## and (2) structural units of the formula ##STR2## and/or structural units of the formula ##STR3## wherein X represents a halogen atom and n is an integer of from 1 to 3.

Abstract: Composite fibrous products such as composite cloth, composite strings, composite knitted goods, etc., produced by using combination yarns obtained by twisting one or more aromatic polyamide continuous filament yarns and one or more continuous glass yarns have high rigidity and excellent reinforcing effects.

Abstract: A method and apparatus provides an essentially neutrally buoyant undersea ectronic data communications link. A bundle of continuous synthetic fibers each having a diameter of about ten microns has individualized metallized layers coated to a thickness of about one to three microns and the whole lot is covered by dielectric insulation. The synthetic fibers, aromatic polyamide fibers or graphite fibers, are relatively light-weight yet have high tensile strengths to assure a sufficient load bearing capability for the undersea use and the number of thin metallized coatings provide the electrical data transmission capability without unduly weighting down the cable. The dielectric insulation layer is disposed coaxially outwardly of the coated fibers and optionally is provided with an outer sheath of conductive material for a return path. However in some applications a seawater return path is better.

Abstract: Adhesion activation of aramid filaments is accomplished by subcoating with a reaction product of an epoxide resin and an aldehyde resin.

Abstract: Polyamide carpet fibers coated with a certain class of fluorine-containing addition polymer are described. The coating is chemically bonded to the fiber surface through amide linkages (--NHCO--) of the polyamide. The coating imparts antisoiling properties of a permanent nature to the fibers. Where applied to carpet yarn, the coating has good retention through carpet dyeing operations and does not significantly interfere with the ability of the carpet to take up dye, even in the case of foam dyeing which is particularly sensitive to fluorocarbon coatings.

Abstract: The original "finish" or the lubricating softener applied by the manufacturer to monofilament fishing line to modify its surface frictional properties can be replaced by the application to the line and/or the guide surfaces of the rod and reel of a small amount of an aqueous solution of a compound used heretofore to modify the frictional properties and hand of fibers prior to forming textiles, fabrics and carpeting therefrom.

Abstract: Combustible materials such as fiber is made flame retardant by treating the material with a methanol or water solution containing the newly discovered compound ammoniumtriborate (NH.sub.4.B.sub.3 O.sub.5.3CH.sub.3 --OH) or a methanolic solution of newly discovered methylborate ammonia adduct. These new flame retardants have the ability to penetrate the combustible material when applied as a solution and thereafter be converted in situ to ammoniumpentaborate to result in enhanced flame retardation over that achieved by merely the direct treatment with ammoniumpentaborate with other borate flame retardants.

Abstract: Relates to lubricating thermoplastic synthetic fibers comprising the application to said fibers of a modified polyoxyalkylene polyol which polyol is modified by capping all of the hydroxyl groups with benzyl, aryl, substituted benzyl or aryl groups or alkyl groups having 1 to 4 carbon atoms.

Abstract: A size for glass fibers is disclosed, the size comprising an oxidized polyolefin, a polymeric film former and an organic acid, preferably terephthalic acid or isophthalic acid.

Abstract: A sized textile warp yarn A for weaving on a loom is disclosed which includes a size coating S carried by fibers 26 on only one side 22 of the yarn bundle B.

Abstract: Fibers are coated with two (or more) layers. A first coating liquid is applied by an applicator having a die that provides for the formation of a gap between the die and the first coated layer. A second die is located at the exit of the first die, with the second coating liquid flowing onto the fiber through a relatively narrow clearance between the first and second dies. The clearance is formed by die surfaces perpendicular to the fiber axis. This second die also provides for a gap, so that the second layer is applied at a "free surface" at the point of contact with the first coated layer. This approach eliminates turbulence and coating nonuniformities associated with prior art multiple coating techniques.

Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.

Abstract: An elastomeric composite material formed from an artificial core fiber and an elastomeric polypeptide chemically bonded to the surface of the core fiber, where the polypeptide comprises tetrapeptide or pentapeptide repeating units or mixtures thereof, the repeating units comprise hydrophobic amino acid or glycine residues, and the amino acid residues of a given repeating unit exist in a conformation having a .beta.-turn. Also disclosed are elastomeric fabrics formed from the elastomeric composite and the use of such fabrics in vascular prosthesis, as well as a method of forming such elastomeric composite materials.

Abstract: An aramid reinforcing element is treated with a cold gas plasma of air, N.sub.2, He, Ne or Ar or mixture thereof at up to 300 watts power for a few seconds to several minutes to improve its adhesion to rubber compounds.

Abstract: A dyed polyester fiber composite structure having an enhanced brilliance and/or color depth, comprises (A) a dyed porous polyester fiber which has been produced (1) by preparing a polyester resin from a dicarboxylic acid component and a glycol component in the presence of a pore-forming agent containing 0.3 to 3 molar % of at least one phosphorus compound based on the molar amount of the dicarboxylic acid component, (2) by converting the polyester resin to a polyester fiber in which fine particles of the pore-forming agent are dispersed, by treating the polyester fiber with an aqueous alkali solution so that at least 2% of the weight of the fiber is removed and a number of fine pores are formed in the fiber and (4) by dyeing the porous polyester fiber; and (B) a coating layer on the peripheral surface of the dyed porous polyester fiber, comprising a polymeric material having a smaller refractive index than that of the porous polyester fiber.

Abstract: A latex is prepared by polymerizing (a) an addition polymerizable oxazoline (such as 2-isopropenyl-2-oxazoline) and (b) at least one other monomer (such as a mixture of styrene and butadiene). The latexes of this invention are useful for promoting adhesion between a polymeric elastomer and a substrate, especially for promoting adhesion between tire cords and tire rubber.

Abstract: Oriented polyamide monofilament exhibiting improved wet-state performance characteristics through the use of a surface coating having 2 to 10 weight percent of a copolymer of vinylidene chloride and at least one ethylenically unsaturated monomer copolymerizable therewith.

Abstract: A composite cord for reinforcing a tire or other elastomeric article having at least one high strength, substantially inextensible yarn spirally wrapped around a core. The core at room temperature has sufficient strength and elasticity to resist and recover from tension forces on the core required during the processing of the cord and building of the tire. The core is composed of material which loses its tensile strength when subjected to temperatures of vulcanization to permit stretching out of the yarn to allow for substantial elongation of a part or all of the tire and then provide reinforcement of the elongated tire by the stretched out, high strength yarn.

Abstract: Novel polyamide-imide resin compositions, useful for electrically insulating conductors, are prepared by polycondensing a tribasic acid anhydride compound and a diisocyanate in an inert organic solvent in the presence of a catalytic amount of an oxyanion or amine compound at a high solids content, and controlling the reaction to prevent a great increase in viscosity.

Abstract: Tetraesters of pyromellitic dianhydride are disclosed wherein two ester moieties are saturated hydrocarbon groups and two ester moieties are halohydroxyalkyl groups. The compounds may be used as diluents for fluorinated pyromellitates that are useful as soil and water repelling agents. Mixtures formed by dissolving the compounds of this invention and known fluorinated pyromellitates in a common solvent are capable of imparting soil and water repelling properties to various fibers that are essentially equivalent to soil and water repelling properties imparted to such fibers by fluorinated pyromellitates alone. Additionally, the hydrocarbon pyromellitates of this invention may be used alone as water repellents.

Abstract: A multifilament yarn of an aromatic polyamide, in particular poly-p-phenylene terephthalamide, having a tenacity of at least 15 cN/dtex and an initial modulus of at least 400 cN/dtex is provided with a water-soluble size, the filaments of the yarn having a cohesion corresponding to a Manra number not higher than 40. The yarn is made by subjecting a non-sized yarn having a moisture content which is lower than its equilibrium moisture content, while under a tension of at most 0.25 cN/dtex, to a continuous wetting treatment with an aqueous solution of a size and subsequently winding the treated yarn into a yarn package. The yarn package contains a single continuous length of the sized yarn. The sized yarn is suitable as warp and weft yarn in the weaving industry.

Abstract: A surface-modified synthetic fiber is provided by plasma irradiating a synthetic fiber containing fine particles. Recesses and projections are formed on the surface of the fiber. The recesses are formed by being etched with plasma in the portion not shielded by the fine particles; the projections are formed by not being etched in the portion shielded by the fine particles. The resulting fiber has an irregular surface such that the distance between the center points of adjacent projections is between approximately 0.03 and 1 microns and the number of projections is between approximately 1 and 200 per square micron.

Abstract: Laminar articles are disclosed comprising a heterogeneous melt of a polyolefin and a condensation polymer incompatible with the polyolefin along with an alkylcarboxyl-substituted polyolefin as a compatibilizing material.

Abstract: The invention provides an improved partially oriented polyester yarn finish which consists essentially of from about 50 to about 90 weight percent of one or more high molecular weight ethylene oxide/propylene oxide copolymers having an ethylene oxide content such that the ethylene oxide in the copolymer constitutes less than about 25 weight percent of the finish; from about 10 to about 35 weight percent of one or more alkyl chain based lubricants, a major amount of which has a smoke point within the range of from about 155.degree. C. to about 200.degree. C.; and an emulsifying amount of base neutralized fatty acid such as potassium oleate.

Abstract: The invention provides an improved multi-filament polyester fibrous material for incorporation into rubber which bears a topcoat comprising the combination of a dissolved, active isocyanate compound together with an endcapped silicone glycol copolymer. The multi-filament polyester material of the invention exhibits improved initial and long term adhesion to rubber and rubber articles prepared from the material of the invention exhibited improved endurance properties.

Abstract: The invention provides a polyester fibrous material for incorporation into rubber bearing an adhesive activator finish comprising as the active ingredient, an epichlorohydrin ether or ester derived from a polyhydric alcohol or polycarboxylic acid containing up to about 20 carbon atoms. Adhesive activated fibers of the invention can obtain a degree of adherence to rubber equal to or closely approaching adherence provided by epoxy adhesive activated polyester fibers.

Abstract: This invention relates to a heat retaining sheet comprising at least a web in which fibers containing polybutylene terephthalate as at least one of their components and having a substantially undrawn definite fiber length are mutually bonded, and which has small area shrinkage in boiling water. The present invention provides a heat retaining web which is particularly useful as the heat retaining material for batting or interlining for clothing, gloves, hats, bedclothes and so forth.

Abstract: An aqueous coating composition for filamentary materials that are to be used in reinforcing elastomeric matrix materials is provided that renders reinforced elastomeric materials having improved properties of flexibility and fatigue resistance. The aqueous adhesive coating composition has a vinyl-pyridine-containing copolymer or terpolymer latex, a phenolic aldehyde condensate polymer, and a non-self-crosslinkable elastomeric latex with a low gel content of less than around 40 weight percent and a low average particle size of less than around 2000 angstroms. The vinyl pyridine-containing elastomeric latex is produced from a vinyl pyridine-containing monomer, 1,3 diene hydrocarbon monomer or the terpolymer is produced in the same way with the addition of a vinyl containing monomer. In addition the aqueous adhesive coating composition may contain a wax emulsion, antioxidant, and carboxylated styrene butadiene copolymer latex.

Abstract: A woven or non-woven mat comprising natural or synthetic fibers bonded together with the residue formed by removing water from an aqueous composition comprising a thermoplastic emulsion and a melamine formaldehyde resin forms an underlay for asphalt paving for road surfaces.

Abstract: Nylon fibers having a soil-resistant coating comprising the reaction product of polymeric zirconium oxide and hydrocarboxylic acid or salt thereof, for example, sodium lactate. The coating is more durable than if the acid or salt thereof are omitted therefrom.

Abstract: Filament-wound composite bodies are disclosed. These bodies contain filament-wound fibers and resin. The resin, when cured, has a density of less than 1.05 g/cc and exhibits a water pick up of less than 1% by weight. When uncured, the resin contains an aromatic vinyl hydrocarbon monomer and as its major component poly(1,2-butadiene), carboxy-terminated poly(1,2-butadiene) or mixtures thereof and has a viscosity of less than 2000 cps at 45.degree. C. These filament-wound bodies advantageously are embodied as rocket motor cases.

Abstract: A polyurethane polymer amine salt is used as a dyeing aid by pretreating a woven or non-woven textile material containing at least partially or wholly synthetic textile materials or by incorporating a solution of the polyurethane polymer amine salt into the dyeing bath.

Abstract: Coating of aramid filaments with certain polyfunctional aziridines increases interlaminar shear strength of unsaturated polyester matrix composites.

Abstract: Novel improved copolyester binder filaments and fibers consist essentially of the terephthalate of ethylene and diethylene glycols with the mol percent of the latter being in the range of 20 to 45 percent.

Abstract: A shaped polyester composite material having an excellent bonding property to rubber, comprises a shaped substrate comprising an aromatic linear polyester matrix and 0.3 to 15%, based on the weight of the matrix, of silicon dioxide fine particles having an average size of 5 to 100 millimicrons and dispersed in at least a surface portion of the substrate, and;a surface coating layer formed on the fine particle-containing surface portion of the substrate and comprising a surface-activating material consisting of at least one member selected from silane coupling compounds and organic titanium compounds, the surface coating layer having been heat treated at a temperature of 50.degree. C. or more but at least 10.degree. C. below the melting point of the polyester matrix.

Abstract: A process for the production of oligomeric mixtures useful as surfactants is disclosed. The initial step of the process comprises reacting pyromellitic dianhydride with a fluoroalcohol using a mole ratio of about one mole pyromellitic dianhydride per two moles of fluoroalcohol to produce an intermediate which contains two fluorinated ester moieties and two free acid moieties. Thereafter, the intermediate diester-diacid is reacted with an excess of an oxirane compound such as epichlorohydrin, epibromohydrin or propylene oxide wherein said oxirane compound reacts with the free acid moieties to produce ester moieties containing a primary or secondary alcohol moiety. In the final step of the process, additional pyromellitic dianhydride is added to the reaction mixture so that the alcohol moieties may react with anhydride moieties to produce ester linking groups (between pyromellitate nuclei) and additional free acid moieties capable of reacting with the oxirane compound.

Abstract: An aramid reinforcing element or cord is dipped in an aqueous adhesive composition of a phenolic-aldehyde resin and a vinyl pyridine latex and dried. The treatment is repeated again and preferably for three times. The repeatedly treated cord is then cured with a rubber compound to give improved H-adhesion values. If desired, a primer treatment with an epoxide may proceed the aqueous adhesive composition treatments.

Abstract: A formable viscid caulking member including a viscid medium; a flexible multifilament member saturated with the viscid medium; and a method of making such a caulking member.

Abstract: Polymers having a substantially completely fluorinated surface of low surface energy and substantially free of oxygen and having a thickness up to about 200 Angstroms, the remainder of the polymer comprising a non-fluorinated polymer.

Abstract: A polyester fiber composite material useful for reinforcing rubber articles, comprises a polyester fiber substrate impregnated with an impregnating composition containing (A) a polyepoxide compound, (B) a rubber latex, (C) a resorcin-formaldehyde prepolymer and a water-soluble polyurethane compound of the formula (I): ##STR1## wherein A=a tri-hepta valent radical, X=a monovalent residue of blocking compound capable of dissociating from the compound (c) at an elevated temperature, Y=a monovalent residue of an aminosulfonic acid having 2 to 6 carbon atoms or aminocarboxylic acid having 1 to 6 carbon atoms, n=5-30, m=1-5, l=1-5 and l+m=2-6, the impregnating composition having been heat-treated on the substrate at least once at a temperature of 120.degree. C. to the melting point of the polyester fiber.

Abstract: Various nylon filamentary materials, including twine, rope and other cordages, are rendered resistant to knot and other interlacement slippage by treatment with certain latex compositions that form a tightly-adhering, blockage-promoting and -assisting surface film on the treated filamentary product so as to enhance physical knot strength propensities and characteristics of the treated-twine and equivalent product insofar as particularly relates to mechanical undoing of the knot under pulling stresses (as distinct from "knot strength" break-point tests indicative of the tensile strength of the filamentary nylon product, per se). Styrene (i.e., "St")/butadiene (i.e., "Bu") and like and analogous synthetic resinous latices--especially those of the carboxylated variety--are particularly good for achievement of the anti-slippage in knot formation enhancement of the nylon filamentary goods involved.

Abstract: A fiber finish composition, a process for treating polyester yarn therewith and polyester yarn so treated are all disclosed. The fiber finish composition, which is preferably applied as an overfinish to the yarn subsequent to drawing of the yarn, comprises about 60 to 90 weight percent of water; about 0.3 to 10 weight percent of gamma-glycidoxypropyltrimethoxysilane; about 0.05 to 4.0 weight percent of a catalyst selected from the group consisting of urea and a solution of a cobalt, stannous, iron, nickel, zinc, manganese or chromium salt of 2-ethylhexoic acid or lauric acid in a carrier which is miscible in water; and about 6.5 to 38.6 weight percent of a compatible noncontinuous phase. The catalyst, alternatively, may form 0.00025 to 0.

Abstract: A carbon composite article and the method of making the article wherein selected carbon fibrous materials are formed into a basic starting substrate having a volume greater than the desired volume of the finished article. Very small amounts of a carbonaceous binder material are used to bond the fibrous materials together at a multiplicity of bonding sites. The basic substrate is then subjected to controlled temperatures and pressures to form a shaped substrate characterized by having a high degree of open porosity, a predetermined shape and structural integrity sufficient to withstand subsequent substrate processing. The carbonaceous binder is applied to the fibrous material in a manner whereby substantial encapsulation of the individual fibers is avoided so that the portions of the fibers disposed intermediate the bonding sites are free to move to accommodate and effectively distribute stresses which may be generated within the substrate due to material shrinkage or other process related causes.

Abstract: Taught is a method of sizing polyester yarn for weaving comprising the steps of applying thereto a latex having an acid pH and of a free radical initiated vinyl polymer having a weight average molecular weight of from about 300,000 to about 2,500,000, said polymer in dried film form being hydrophobic and not redispersible in a solution at a pH of from about 2 to 7 but redispersible by an aqueous alkaline medium, said polymer being prepared from monomers consisting essentially of by weight, 45-65% butyl acrylate a total of 28-45% styrene and/or methyl methacrylate and a total of 8-14% acrylic acid and/or methacrylic acid, and drying the yarn.

Abstract: Crosslinkable graft copolymers of poly(oxyalkylene) are provided which comprise from about 1 percent by weight of a substituted N-methylol derivative of acrylamide grafted onto a poly(oxyalkylene)-polymer.

Abstract: A cycloaliphatic diester of the formula ##STR1## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 --, HO(C.sub.3 H.sub.6 O).sub.n C.sub.3 H.sub.6 --, HO(CH.sub.2 CH.sub.2 O).sub.p (C.sub.3 H.sub.6 O).sub.q C.sub.3 H.sub.6 --, or HO(C.sub.3 H.sub.6 O).sub.p (C.sub.2 H.sub.4 O).sub.q C.sub.2 H.sub.4 -- or phosphated polyoxyalkylene, wherein n is 2-22 and the sum of p+q is n, in combination with a high boiling aromatic ester, is useful in fiber treating and textile processing compositions. Corresponding cycloaliphatic diesters wherein R is Ar'COO(CH.sub.2 CH.sub.2 O).sub.n CH.sub.2 CH.sub.2 --, Ar'COO(C.sub.3 H.sub.6 O).sub.n C.sub.3 H.sub.6 --, Ar'COO(C.sub.2 H.sub.4 O).sub.p (C.sub.3 H.sub.6 O).sub.q C.sub.3 H.sub.6 --, or Ar'COO(C.sub.3 H.sub.6 O).sub.p --(C.sub.2 H.sub.4 O).sub.q C.sub.2 H.sub.

Abstract: A string for sports rackets consists of a gut core covered with filamentary aramid and impregnated with at least one coating of water-resistant, vapor-impermeable, flexible smooth adhesive polymeric resin, which adheres the filamentary aramid to the gut core.

Abstract: Disclosed is the preparation of water-dissipatable polyesters and polyesteramides wherein at least a part of one of the monomeric components from which it is derived is a polycarboxylic acid or polyhydric alcohol which contains a sulfonic acid salt moiety derived from a nitrogen-containing base having an ionization constant in water at 25.degree. C. of 10.sup.-3 to 10.sup.-10. Also disclosed is the use of such polymers as sizes for fibers of glass, ceramics, etc., where the size is removed by burning and little or no ash residue is important.