Polyamide, Polyimide Or Polyester Patents (Class 428/395)
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Patent number: 4292365Abstract: A lofted mat of filaments is produced from process and apparatus including: supplying a plurality of streams of molten polymeric material; attenuating said streams of material into continuous filaments through the action of a stream of fluid moving from an attenuation means; said filaments being entrained in said fluid moving from said attenuation means, said filaments having non-uniform residual stresses established therein; moving said stream of fluid and filaments along a first surface positioned intermediate said attenuation means and a foraminous surface; establishing a vacuum at said foraminous surface; directing said stream of fluid and filaments into said foraminous surface obliquely oriented with respect to said first surface such that a first portion of said fluid separates from the filaments and passes through said foraminous surface and a second portion of said fluid moves said filaments along the foraminous surface; collecting said filaments in a randomly dispersed, substantially uniform layer haType: GrantFiled: January 21, 1980Date of Patent: September 29, 1981Assignee: Owens-Corning Fiberglas CorporationInventors: John L. Kane, Vikas M. Nadkarni
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Patent number: 4289824Abstract: Article of manufacture comprising alloy fibers having high fluid-holding capacity, the alloy fibers being comprised of a matrix of regenerated cellulose having carboxymethylcellulose uniformly dispersed therein, the latter being the sole additive for increasing the fluid holding capacity of the fibers.Type: GrantFiled: October 5, 1979Date of Patent: September 15, 1981Assignee: Avtex Fibers Inc.Inventor: Frederick R. Smith
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Patent number: 4289683Abstract: An aqueous alkaline dispersion of a rubbery graft low gel vinyl pyridine copolymer and a water soluble, heat reactive phenolic resin is useful in forming an adhesive for bonding polyamide or polyester reinforcing elements or cords to rubber compounds or stocks. After dipping the polyamide or polyester cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing polyamide or polyester cord is combined with, or laminated to (calendered), a curable rubber compound and the resulting assembly is cured to form a composite in which the polyamide or polyester cord is bonded to the rubber by means of said adhesive.Type: GrantFiled: October 16, 1980Date of Patent: September 15, 1981Assignee: The General Tire & Rubber CompanyInventor: Terry C. Neubert
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Patent number: 4281042Abstract: A fiberfill blend for making into a batt for heat-bonding, consisting essentially of three ingredients: (a) two of the ingredients are crimped polyester staple fiber; (1) one of these polyester fiberfill ingredients is slickened with a durable coating; (2) the other of these polyester fiberfill ingredients is unslickened; each of ingredients (1) and (2) constitutes 25 to 75% of the polyester fiberfill (a); (b) the third ingredient is crimped binder fiber of a polymer having a melting point lower than that of the (a) ingredients; the binder fiber is present in amount 10 to 30% of the blend; the remaining 70 to 90% of the blend is the polyester fiberfill. Such blends can be processed on conventional textile machinery, e.g., by carding and cross-lapping, and heated to activate the binder fibers and make a stable heat-bonded batt. Preferred batts, using polyester staple fibers of regular denier, have surprisingly high resilience, which makes them especially suitable for use in pillows and cushions.Type: GrantFiled: August 30, 1979Date of Patent: July 28, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Georges Pamm
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Patent number: 4275117Abstract: An integrated string primarily for use in connection with athletic rackets, such as tennis, badminton, squash and the like, but also usable for fishing line, musical strings, etc., said string in one embodiment comprising a thermoplastic core having a thermoplastic sheath covering same and integrated thereto, said core material and said sheath comprising strands therein having substantially different melting points, and in a second embodiment said string consisting of a braided sheath, with no inner core, said sheath comprising thermoplastic strands having substantially different melting points.Type: GrantFiled: May 22, 1978Date of Patent: June 23, 1981Assignee: Ashaway Line & Twine Mfg. Co.Inventor: Steven J. Crandall
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Patent number: 4275095Abstract: A method of making a composite article and a composite article specifically adapted for use in high temperature, corrosive and errosive environments comprising a carbon fibrous substrate, including a pyrolytic carbon sheath formed about each fiber of the substrate; a metallic carbide, oxide, or nitride compliant coating over the coated fibers of the substrate; and an impermeable metallic carbide, oxide or nitride outer protective layer formed about the entire periphery of the coated substrate. In accordance with the method of the invention, the compliant metallic coating is applied to the fibers in a manner such that any mechanical stresses built-up in the substrate due to a mismatch between the coefficient of thermal expansion of the fibrous substrate and the coating are effectively accommodated.Type: GrantFiled: July 31, 1979Date of Patent: June 23, 1981Assignee: Warren Consultants, Inc.Inventor: James W. Warren
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Patent number: 4273946Abstract: Lubricants and processing aids for synthetic fibers, particularly polyester and nylon fibers, are disclosed comprising compounds having the structural formulas: ##STR1## in which R is an aliphatic group generally having about 3 to about 22 carbon atoms; A is a mixture of residues from ethylene oxide and at least one other lower alkylene oxide, preferably a heteric mixture of oxyethylene and oxypropylene residues in the respective ratio by weight of 20:80 to 90:10; and n has a value to produce a molecular weight of about 300 to about 3000.Where liquid products are desired which contain the higher numbered carbon chain residues, low viscosity compounds can be obtained by oxyalkylating a glycerol-1,3-dialkylether with a mixture of ethylene oxide and 1,2-propylene oxide in the respective ratio as set forth above.Type: GrantFiled: October 10, 1979Date of Patent: June 16, 1981Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Robert B. Login
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Patent number: 4269883Abstract: A veneer sheet reinforced with at least one piece of cord is provided. The cord is thrust through the sheet at appropriate intervals and projects from either side of the sheet. The projecting portions are fastened by deforming the cord or applying an adhesive including a thermoplastic resin, a thermosetting resin, and a wet-setting resin.Type: GrantFiled: August 3, 1979Date of Patent: May 26, 1981Assignee: Meinan Machinery Works, Inc.Inventor: Katsuji Hasegawa
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Patent number: 4268645Abstract: A composition suitable for warp sizing polyester and polyester/cotton yarns comprising water soluble polyester resin having (1) a backbone portion comprising the reaction product of dihydroxy compound having a maximum molecular weight of 250 and dicarboxylic acid compound wherein the acid number of said backbone portion is less than 3 and (2) internal and pendant carboxylic acid moieties comprising an aromatic polycarboxylic acid compound having at least 3 acyl moieties which provides from 5 to 75 equivalent percent of the acyl moieties in the polyester, the said polyester resin having a molecular weight within the range of from 5000 to 35000 and an acid number within the range of from 15 to 55.Type: GrantFiled: March 24, 1980Date of Patent: May 19, 1981Assignee: Standard Oil Company (Indiana)Inventor: John C. Lark
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Patent number: 4267233Abstract: An electrically conductive fiber having an electric resistivity of 1.times.10.sup.12 ohm/cm or less under a D.C. voltage of 1 K.V., contains copper (I) iodide which has been deposited in the inside of at least the peripheral surface layer of an electrically non-conductive fiber matrix by contacting iodine with copper (I) ions therein.Type: GrantFiled: February 6, 1980Date of Patent: May 12, 1981Assignee: Teijin LimitedInventors: Hiroaki Tanaka, Kiyokazu Tsunawaki
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Patent number: 4265972Abstract: A composite fiber or filament comprising a core or substrate coated with a cellular foam, and an outer circumference characterized by a substantially continuous, microcellular breathable and abrasion-resistant aspect.Type: GrantFiled: March 9, 1979Date of Patent: May 5, 1981Inventor: Bernard Rudner
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Patent number: 4264484Abstract: Carpet is rendered soil resistant and stain repellant by contacting it with a carpet treating composition comprising a liquid containing a water-insoluble addition polymer derived from polymerizable ethylenically unsaturated monomer free of nonvinylic fluorine and having at least one major transition temperature higher than about 25.degree. C., and a water-insoluble fluoroaliphatic radical- and aliphatic chlorine-containing ester having at least one major transition temperature higher than about 25.degree. C.Type: GrantFiled: December 21, 1979Date of Patent: April 28, 1981Assignee: Minnesota Mining and Manufacturing CompanyInventor: Kalyanji U. Patel
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Patent number: 4263370Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.Type: GrantFiled: July 23, 1979Date of Patent: April 21, 1981Assignee: BASF Wyandotte CorporationInventor: Robert B. Login
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Patent number: 4263337Abstract: Graft polyesters which are useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer.Type: GrantFiled: July 25, 1979Date of Patent: April 21, 1981Assignee: BASF Wyandotte CorporationInventor: Robert B. Login
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Patent number: 4263190Abstract: A cord dip composition comprising a styrene-butadiene-vinyl pyridine terpolymer latex and a mixture of an aldehyde condensate and a glyoxal reaction product, are disclosed.Type: GrantFiled: December 26, 1979Date of Patent: April 21, 1981Assignee: American Cyanamid CompanyInventor: Daniel M. Zavisza
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Patent number: 4259403Abstract: An acid of the formula A--COOH).sub.x, or an anhydride thereof, wherein x is an integer of 1 or 2, wherein the acid groups are vicinal if x is 2, and A is phenyl, C.sub.2 -C.sub.10 alkylene, C.sub.2 -C.sub.10 alkenylene, C.sub.6 -C.sub.10 bridged or nonbridged cycloalkylene or cylcoalkenylene, with the proviso that A is C.sub.1 -C.sub.6 alkyl if x is 1, renders ethylene-propylene-nonconjugated diene elastomers more adherent to fibers that have been treated with a resorcinol-formaldehyde-latex dip when said elastomers are cured directly onto said fibers.Type: GrantFiled: January 16, 1979Date of Patent: March 31, 1981Assignee: Uniroyal, Inc.Inventor: Richard W. Tomlinson
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Patent number: 4259405Abstract: There are disclosed lubricated synthetic yarn and processes therefore wherein heteric copolymers of tetrahydrofuran and at least one C.sub.3 to C.sub.4 alkylene oxide initiated with a polyhydric alcohol are utilized as lubricants. The copolymers have a molecular weight of about 500 to about 10,000 and are initiated with polyhydric alcohols having a total of not more than 20 carbon atoms which are free of elements other than carbon, hydrogen and oxygen. Said initiators have 2 to about 6 reactive hydrogen atoms. The heteric copolymers of the invention capped with at least one lower alkylene oxide residue are also useful as fiber lubricants.Type: GrantFiled: January 15, 1980Date of Patent: March 31, 1981Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Basil Thir
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Patent number: 4259400Abstract: PCT No. PCT/FR78/00001 Sec. 371 Date Feb. 8, 1979 Sec. 102(e) Date Feb. 8, 1979 PCT Filed June 2, 1978 PCT Pub. No. WO 78/00012 PCT Pub. Date Dec. 21, 1978A fibrous padding material simulating natural down for quilted articles.The material is in the form of an element of defined length and of low thickness relative to its width, which element comprises a central filiform core which is relatively dense and rigid compared with the whole of the material and to which are bonded fibers which are oriented substantially transversely relative to this core, the said fibers being entangled with one another so as to form a homogeneous thin web and being located on either side of the core, substantially in the same plane (FIG. 3).Type: GrantFiled: February 8, 1979Date of Patent: March 31, 1981Assignee: Rhone-Poulenc-TextileInventor: Robert Bolliand
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Patent number: 4259404Abstract: Rubber compounds are readily bonded to nylon or polyamides, particularly tire cords of polyamides in which a high proportion of the amide linkages are attached directly to aromatic rings, using a two-step dip process in which the first dip comprises a liquid dispersion or solution of an epoxide having an average of from about two to four epoxide groups per molecule and a molecular weight up to about 600 and the second dip comprises an aqueous dispersion of a mixture of a major amount of a rubbery vinyl pyridine copolymer and a minor amount of a heat reactable 2,6-bis(2,4-dihydroxy phenylmethyl)-4-chlorophenol composition. High H-adhesions are obtained with this process. It is particularly useful for the bonding to rubber compounds of crystalline polyamides having a large number of aromatic groups in the polymeric structure, e.g., "Fiber B".Type: GrantFiled: August 15, 1977Date of Patent: March 31, 1981Assignee: The General Tire & Rubber CompanyInventor: Gerard E. van Gils
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Patent number: 4259457Abstract: There are disclosed graft polyesters useful as adhesives and coatings and especially useful in processes for sizing spun and continuous filament synthetic organic and inorganic fibrous yarn. One embodiment of the invention is a textile size composition having free carboxyl groups which is prepared in situ on a textile yarn by the application of heat or radiation to a mixture of an unsaturated polyester reactant and a monovinyl monomer reactant comprising an acidic monovinyl monomer having at least one carboxyl group or mixtures thereof with any monovinyl monomer. Desizing can be accomplished by partial neutralization of the size to a pH of at least 6 by reacting the size with a base to render the graft polyester water-dispersible or water-soluble.Type: GrantFiled: July 23, 1979Date of Patent: March 31, 1981Assignee: BASF Wyandotte CorporationInventor: Robert B. Login
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Patent number: 4255471Abstract: Disclosed is a solution including an aromatic bis (ether dicarboxylic acid) component, an organic diamine component and a solvent system including a water-soluble organic solvent component, which may be a dipolar aprotic solvent or a monoalkyl ether of ethylene glycol or of diethylene glycol, and optionally water. The solution may be coated on a substrate and polymerized to form high quality polyetherimide coatings.Type: GrantFiled: November 13, 1978Date of Patent: March 10, 1981Assignee: General Electric CompanyInventors: Edith M. Boldebuck, Eugene G. Banucci
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Patent number: 4255487Abstract: Finely divided, electrically conductive particles are uniformly suffused into a filamentary polymer substrate in an annular region located at the periphery of the filamentary polymer substrate and extending along the length thereof. The electrically conductive particles are employed in an amount sufficient to render the electrical resistance of the filamentary polymer substrate not more than about 10.sup.9 ohms/cm. The filamentary polymer substrate finds special utility in the fabrication of antistatic fabrics and floor coverings.Type: GrantFiled: May 10, 1977Date of Patent: March 10, 1981Assignee: Badische CorporationInventor: John H. Sanders
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Patent number: 4251409Abstract: An aqueous alkaline dispersion of a rubbery graft low gel vinyl pyridine copolymer and a water soluble, heat reactive phenolic resin is useful in forming an adhesive for bonding polyamide or polyester reinforcing elements or cords to rubber compounds or stocks. After dipping the polyamide or polyester cord in the one-step adhesive dip, the coated cord is heated to dry it and heat cure or heat set the adhesive on the cord. Thereafter, the adhesive containing polyamide or polyester cord is combined with, or laminated to (calendered), a curable rubber compound and the resulting assembly is cured to form a composite in which the polyamide or polyester cord is bonded to the rubber by means of said adhesive.Type: GrantFiled: April 23, 1979Date of Patent: February 17, 1981Assignee: The General Tire & Rubber CompanyInventor: Terry C. Neubert
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Patent number: 4251403Abstract: An improved warp size for filament yarn is provided consisting essentially of polyvinyl alcohol, urea, and mono- and di-saccharides, such as sucrose, which when applied to filament yarn from aqueous solution provides excellent abrasion resistance, low shedding, freedom from skinning, and outstanding ease of removal.Type: GrantFiled: December 5, 1979Date of Patent: February 17, 1981Assignee: E. I. Du Pont de Nemours and CompanyInventor: Richard W. Rees
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Patent number: 4248938Abstract: A process for preparing a polyester fiber composite material having an excellent bonding property to rubber, a proper softness and a high resistance to fatigue, comprises the steps of first impregnating a polyester fiber material much as fabric, cord or thread, with a first treating liquid containing (A) a polyepoxide compound having two or more epoxy groups per molecule of the compound, (B) a blocked polyisocyanate compound, for example, an addition product of a polyisocyanate compound with a phenol, tertiary alcohol or aromatic secondary amine compound and (C) a rubber latex such as vinyl pyridine-styrene-butadiene terpolymer latex; first drying and heat treating the first impregnated material at a temperature of, preferably, 180.degree. C.Type: GrantFiled: November 8, 1978Date of Patent: February 3, 1981Assignee: Teijin LimitedInventors: Tadahiko Takata, Masaya Kamiyoshi, Satoshi Tanaka
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Patent number: 4247596Abstract: Electrical conductors for use in microelectronic circuitry are prepared from a flexible, polymeric fiber selected from the group of flexible, polymeric fibers consisting of silk, polyacrylonitrile, regenerated cellulose, polyester, and polyamide. The selected fiber is made conductive by coating by a method wherein the fiber is immersed for a predetermined time period of from about 30 minutes to about 60 minutes in a solution prepared from equal portions of a silver nitrate-aqueous ammonia solution and a silver nitrate-potassium-sodium tartrate solution. These solutions coat the selected polymeric fiber with metallic silver. The excess solution is washed off and the coated fiber is air dried or dried in a low temperature oven at about 50.degree. C. The process is repeated if a heavier coating of silver on the fibers is desired for better conductivity. For use, the metallic silver coated fiber is cut to required length and tested for resistivity which should be near one ohm.Type: GrantFiled: May 10, 1979Date of Patent: January 27, 1981Inventor: Tin B. Yee
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Patent number: 4245004Abstract: There are disclosed block copolymer lubricants for synthetic textile fibers which are compounds derived from tetramethylene oxide (tetrahydrofuran) and ethylene oxide of the formula:Y--(CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.sub.2 --O--)--(C.sub.2 H.sub.4 O)--H].sub.Type: GrantFiled: May 26, 1978Date of Patent: January 13, 1981Assignee: BASF Wyandotte CorporationInventors: Robert B. Login, David D. Newkirk
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Patent number: 4243713Abstract: A woven fabric having a textured, multicolor appearance is disclosed. The fabric is formed from a weave of expansible threads, wherein each thread comprises a core yarn, a first plastisol coating surrounding the core yarn, and a second plastisol coating surrounding the first coating and eccentric thereto. The first and second coatings are of different colors. The expansible threads are woven into a substantially planar fabric and then fused by heat activation. At the fusion temperature, the melt viscosity of the second coating is sufficiently high so that the first coating emerges through the second coating at the thin areas of the second coating. Preferably, the first coating has a substantially greater amount of blowing, or foaming, agent than the second coating so that the first coating expands to a greater degree than does the second coating.Type: GrantFiled: November 3, 1978Date of Patent: January 6, 1981Assignee: Engineered Yarns, Inc.Inventors: James D. Worrall, Suzanne M. Auger
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Patent number: 4234341Abstract: A s-Triazine of the formula ##STR1## wherein X, Y and Z are radicals of the formula ##STR2## and R are aromatic, cycloaliphatic or aliphatic radicals or hydrogen is provided. The process for the manufacture of such s-Triazines is also provided as well as a process for fireproofing polyester fibres with such s-Triazines. The s-Triazine may also be applied in the presence of a dispersant, a protective colloid and/or water. The composition of matter for performing this process is also provided.Type: GrantFiled: April 18, 1979Date of Patent: November 18, 1980Assignee: Ciba-Geigy CorporationInventors: Armin Hiestand, Peter Rohringer
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Patent number: 4230766Abstract: The fibers constituting the composite material are impregnated with a composition containing at least one unsaturated epoxy resin mixed with at least two ethylenic monounsaturation monomers, at least one ethylenic polyunsaturation monomer, a photoinitiator and an organic peroxide. The composition is prepolymerized by means of ultraviolet rays in a first step and then cross-linked either by ultraviolet rays or a temperature rise in a second step.Type: GrantFiled: September 13, 1978Date of Patent: October 28, 1980Assignee: Commissariat a l'Energie AtomiqueInventors: Gilbert Gaussens, Francis Lemaire, Bach Van Nguyen
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Patent number: 4219625Abstract: As an additive imparting oil and water repellency, durable against laundering and abrasion, to PET fibers: a partially or fully acylated polyol, especially pentaerythritol, glycerol, hydroquinone or ethylene glycol, acylated with a phthalic or terephthalic monoester having a perfluorinated alkyl or alkoxyalkyl C.sub.2 to C.sub.20 radical, especially C.sub.5 to C.sub.10 n-alkyl or (CF.sub.2).sub.n OR.sub.f where R.sub.f is C.sub.1 to C.sub.6 perfluoroalkyl, especially perfluoroisopropyl and (CF.sub.2).sub.n is a straight chain C.sub.2 to C.sub.10 diradical.Type: GrantFiled: December 16, 1977Date of Patent: August 26, 1980Assignee: Allied Chemical CorporationInventors: Frank Mares, Bryce C. Oxenrider, Cyril Woolf
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Patent number: 4217390Abstract: Lubricants and processing aids for synthetic fibers, particularly polyester and nylon fibers, are disclosed comprising compounds having the structural formulas: ##STR1## and ##STR2## in which R is an aliphatic group generally having about 3 to about 22 carbon atoms; A is a mixture of residues from ethylene oxide and at least one other lower alkylene oxide, preferably a heteric mixture of oxyethylene and oxypropylene residues in the respective ratio by weight of 20:80 to 90:10; and n has a value to produce a molecular weight of about 300 to about 3000.Where liquid products are desired which contain the higher numbered carbon chain residues, low viscosity compounds can be obtained by oxyalkylating a glycerol-1,3-dialkylether with a mixture of ethylene oxide and 1,2-propylene oxide in the respective ratio as set forth above.Type: GrantFiled: October 30, 1978Date of Patent: August 12, 1980Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Robert B. Login
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Patent number: 4215026Abstract: A polyester size composition for synthetic fibers useful in protecting the fibers from abrasion during the weaving process or to improve the adhesion to the fibers of conventional size compositions and especially useful with polyester fibers such as those based upon polyethylene terephthalate, comprises a branched water-dispersible polyester which is the reaction product of at least one polycarboxylic acid, at least one diol or polyglycol and an aromatic carboxylic acid containing a --SO.sub.3 M grouping which is attached to the aromatic nucleus of said carboxylic acid through an aliphatic chain and ester linkage and wherein said linkage contains about 2 to about 8 carbon atoms.Type: GrantFiled: January 2, 1979Date of Patent: July 29, 1980Assignee: BASF Wyandotte Corp.Inventor: Robert B. Login
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Patent number: 4210700Abstract: An improved multifilament polyethylene terephthalate yarn is prepared by first applying to the yarn a liquid composition comprising hexadecyl stearate, refined coconut oil, ethoxylated tallow amine, ethoxylated lauryl alcohol, sodium salt of alkylarylsulfonate, dinonyl-sodium-sulfosuccinate, and a mineral oil, and then applying to the yarn a liquid composition which is an oil-in-water emulsion, the oil portion of which comprises coconut oil, polyoxyethylene hydrogenated castor oil, and phosphated polyoxyethylated tridecyl alcohol neutralized with potassium hydroxide. The yarn is preferably used in tire cords for the construction of pneumatic passenger tires and results in excellent adhesion of tire cord to rubber.Type: GrantFiled: September 15, 1978Date of Patent: July 1, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4210690Abstract: A spun nonwoven fabric of polyester filaments for use as backing for a deep-drawable tufted carpet, wherein the polyester filaments hve uniformly distributed therethrough about 0.1 to 1% by weight of a diol-modified copolyester containing units of at least two different doils. For example, polyethylene terephthalate granulate is mixed with polyethylene butylene terephthalate copolymer and spun into a nonwoven web which is calendered and then tufted to form a carpet which can be deep-drawn with a three-dimensional shape. If desired, polyethylene terephthalte-adipate copolymer fibers can be co-spun into the web as binding fibers.Type: GrantFiled: September 29, 1978Date of Patent: July 1, 1980Assignee: Firma Carl FreudenbergInventors: Ludwig Hartmann, Ivo Ruzek
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Patent number: 4207376Abstract: An antistatic composite filament is disclosed, which has a three-layer structure including a core layer, a sheath layer and an intermediate layer, each of which is continuous in the axial direction of the filament. The core layer is composed of an oriented and crystallized, electrically non-conductive synthetic polymer. The sheath layer is composed of a synthetic polymer of the same kind as of the polymer constituting the core layer. The intermediate layer is composed of an electrically conductive synthetic polymer containing carbon black dispersed therein and is present in the entire intermediate area between the core layer and sheath layer. This filament is advantageously used as material for an antistatic carpet and/or dark color articles of wear such as uniforms or the like.Type: GrantFiled: June 14, 1979Date of Patent: June 10, 1980Assignee: Toray Industries, Inc.Inventors: Tadahito Nagayasu, Tomitake Higuchi
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Patent number: 4207071Abstract: Fibrous substrates are durably modified by applying a polyoxyethylene-containing silane to the substrate and heating the substrate to cure the silane. Durability of the treatment is achieved by using a silane having the formula R(OCH.sub.2 CH.sub.2).sub.x OR'SR"SiZ.sub.3 where Z denotes a hydroxyl or a hydrolyzable radical, R' and R" are divalent aliphatic radicals of suitable size, R is hydrogen, lower alkyl or lower acyl and x has a value of at least 3. The silane is applied to the fibrous substrate, such as a hydrophobic fabric, as a homogeneous liquid composition comprising the silane, a volatile liquid carrier and a siloxane polymerization catalyst to provide a treated substrate having improved properties, such as hydrophilicity.Type: GrantFiled: February 1, 1979Date of Patent: June 10, 1980Assignee: Dow Corning CorporationInventors: Jonathan Lipowitz, Robert E. Kalinowski
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Patent number: 4204982Abstract: Rubber compounds are readily bonded to tire cords using a dip process in which the dip contains an alkaline aqueous dispersion of a mixture of a major amount by weight of a rubbery carboxylated conjugated diene copolymer and a minor amount of a lignin amine formaldehyde reaction product.Type: GrantFiled: November 13, 1978Date of Patent: May 27, 1980Assignee: The General Tire & Rubber CompanyInventor: Terry C. Neubert
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Patent number: 4204984Abstract: Rubber compounds are readily bonded to tire cords using a dip process in which the dip contains an alkaline aqueous dispersion of a mixture of a major amount by weight of a rubbery carboxylated conjugated diene copolymer and a minor amount of a lignin amine formaldehyde reaction product.Type: GrantFiled: October 17, 1977Date of Patent: May 27, 1980Assignee: The General Tire & Rubber CompanyInventor: Terry C. Neubert
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Patent number: 4199642Abstract: The horizontal burning rate of polyester fiberfill coated with cured polysiloxane and/or bonded with a synthetic resin is reduced by incorporating small amounts (2 to 20% by weight) of a synthetic organic filamentary material that maintains its physical integrity when exposed to a small flame. The preferred material is poly(p-phenylene terephthalamide). This has particular application to silicone-slickened polyester staple fibers used for fiberfill, and articles therefrom, but has application also to silicone-slickened polyester filler tow, to resin-bonded polyester staple fiber batts, whether silicone-slickened or not, and to resin-bonded polyester filler tow.Type: GrantFiled: May 5, 1977Date of Patent: April 22, 1980Assignee: E. I. Du Pont de Nemours and CompanyInventors: John L. Cooper, James A. Newnam
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Patent number: 4197350Abstract: Quaternized amine-amide condensation products which are obtained by condensation of an amine of the formulaR.sub.1 R.sub.2 N--(CH.sub.2).sub.n --NH.sub.2with a lower alkanecarboxylic acid, and subsequent quaternization with a trialkyl phosphate. These products are suitable as fiber preparation agents.Type: GrantFiled: October 19, 1978Date of Patent: April 8, 1980Assignee: Hoechst AktiengesellschaftInventors: Rolf Kleber, Wolfgang Wagemann
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Patent number: 4194940Abstract: Thermoplastic elastomeric materials are bonded to a variety of substrates over a broad range of temperatures and pressure by employing an adhesive system comprising thermoplastic polyether urethane.Type: GrantFiled: August 4, 1978Date of Patent: March 25, 1980Assignee: Lord CorporationInventors: Dennis J. Damico, Brian Martin
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Patent number: 4193880Abstract: A yarn finish composition is disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. The composition comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxyl-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: March 18, 1980Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4191656Abstract: A finish composition for polyamide yarn which comprises an oil in water emulsion and an effective amount of 2[(hydroxymethyl)amino]ethanol biocide resists bacteria growth and causes the treated yarn to resist yellowing under steam heat treatment. The oil in water emulsion and biocide most preferably form, respectively, 99.9 percent and 0.1 percent by weight of the finish composition. The preferred oil in water emulsion is about 10 to 20 percent by weight of the oil portion, the oil portion consisting essentially of from about 55 to 65 percent by weight of coconut oil, about 20 to 35 percent by weight of polyoxyethylene hydrogenated castor oil, and about 7 to 15 percent by weight of potassium salt of polyoxyethylene tridecyl phosphate. The finish composition is especially useful for application to polyamide yarn to be processed into either staple carpet yarn or bulked continuous filament carpet yarn.Type: GrantFiled: October 5, 1978Date of Patent: March 4, 1980Assignee: Allied Chemical CorporationInventor: Robert M. Marshall
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Patent number: 4190545Abstract: Several spin finishes are disclosed for incorporation with synthetic organic polymer yarn or yarn products to render the same oil repellent and resistant to soiling. All of the spin finishes include a yarn finish composition which comprises (a) a nonhomogeneous mixture of a salt of dinonyl sulfosuccinate, a salt of dimethyl naphthalene sulfonate, and ammonium perfluoroalkyl carboxylate, and (b) a fluorochemical compound consisting of polycarboxybenzene esterified with certain partially fluorinated alcohols and with hydroxy-containing organic radicals such as 2-hydroxyethyl, glyceryl, and chlorohydryl or bromohydryl.Type: GrantFiled: March 30, 1979Date of Patent: February 26, 1980Assignee: Allied Chemical CorporationInventors: Robert M. Marshall, Kimon C. Dardoufas
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Patent number: 4187349Abstract: An adhesive system for coating polyester cord to effect the bonding of rubber thereto in preparing vulcanized reinforced structures, especially pneumatic tires, which system consists of a first heat-cured coating of an admixture of a polyepoxide and a linear carbon-to-carbon addition polymer containing pendent aminimide and N-pyrrolidonyl groups and a second heat-cured coating of a RFL composition.Type: GrantFiled: March 26, 1975Date of Patent: February 5, 1980Assignee: Ashland Oil, Inc.Inventors: Heimo J. Langer, William J. McKillip
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Patent number: 4187347Abstract: Rovings impregnated with solid or preferably semi solid thermosetting resin and which can be handled in textile processing equipment are provided by overcoating the impregnated roving with a thermoplastic resin dispersed in a volatile liquid medium which does not dissolve the thermosetting resin to form an encapsulating membrane of thermoplastic resin around the impregnated roving to thereby provide the strength, flexibility, and surface properties needed for textile handling without degrading the properties desired in the final cured molded product.Type: GrantFiled: April 5, 1976Date of Patent: February 5, 1980Assignee: DeSoto, Inc.Inventor: Richard L. Brook
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Patent number: 4179543Abstract: A composition for short cut, synthetic polymeric staple fibers that are u in a wet lay application for the production of nonwovens is disclosed and claimed herein along with a fiber having the finish thereon and the process for dispersing the fiber in an aqueous medium. Synthetic polymeric filaments are cut into staple lengths, generally in a range of from about 1/4 to about 3 inches in length, and are dispersed in an aqueous medium in conjunction with a composition that includes as an essential ingredient, an ethoxylated primary emulsifier that contains at least five moles of ethylene oxide, and exhibits a surface tension of at least 30 dynes per centimeter in a 0.10 weight percent aqueous solution at 25 degrees Centigrade plus or minus 2 degrees Centigrade. Optionally, a lubricant may be added to the finish composition to improve processability of the fiber during manufacture. The lubricant should be compatible with the primary emulsifier.Type: GrantFiled: August 19, 1976Date of Patent: December 18, 1979Assignee: Hoechst Fibers Industries, Division of American Hoechst CorporationInventor: Roland L. Hawkins
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Patent number: 4179544Abstract: A fiber finish composition, consisting of a mixture of a major amount of lubricant and a minor amount of a stabilizer of said fiber finish and a process for employment thereof.Type: GrantFiled: December 5, 1977Date of Patent: December 18, 1979Assignee: BASF Wyandotte CorporationInventors: David D. Newkirk, Basil Thir, Robert B. Login
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Patent number: 4177231Abstract: Process for improving the sliding properties of linear polyester material in spinning operations, which comprises treating this material after the drawing with a mixture of the following components:(a) 50 to 90% by weight of a condensation product of formula I ##STR1## in which R.sub.1 is C.sub.10 -C.sub.22 alkyl or alkenyl, y is a number of from 20 to 40, and x plus z have a weight of less than 20% by weight of the polypropylene oxide portion, and(b) 50 to 10% by weight of a compound of formulae II and/or III ##STR2## in which R.sub.2 and R.sub.3 are C.sub.8 -C.sub.18 alkyl or alkenyl, and x and/or y are numbers of from 5 to 20.Type: GrantFiled: March 7, 1978Date of Patent: December 4, 1979Assignee: Hoechst AktiengesellschaftInventors: Rolf Kleber, Ulrich Cuntze