Abstract: The invention concerns copolyamides obtained by using multifunctional monomers. It consists in using at least one multifunctional monomer comprising at least three reactive functions and at least another multifunctional monomer, in amounts such that the terminal group concentrations are balanced. The copolyamides are more particularly high viscosity copolyamides. The invention also concerns compositions based on said copolyamides.

Abstract: A process for manufacturing continuous polyester filament yarn for technical applications from a polymer over 90% of the chains of which are composed of ethylene terephthalate units, via a one-step spinning process, with the undrawn filaments having a crystallinity smaller than 16% and the yarn being wound at a rate larger than 6000 m/min. The yarn obtained in this fashion is particularly suitable for use as reinforcing material in rubber articles, notably as reinforcing material in pneumatic tires for cars. The polyester filament yarn can be used to make cords of uncommonly high dimensional stability and a unique combination of breaking tenacity, shrinkage, and breaking toughness.

Abstract: Unique thermoplastic (polypropylene, specifically) monofilament and/or tape fibers and yarns that exhibit heretofore unattained physical properties are provided. Such fibers are basically manufactured through the extrusion of thermoplastic resins that include a certain class of nucleating agent therein, and are able to be drawn at high ratios with such nucleating agents present, that the tenacity and modulus strength are much higher than other previously produced thermoplastic fibers (particularly those produced under commercial conditions), particularly those that also simultaneously exhibit extremely low shrinkage rates. Thus, such fibers require the presence of certain compounds that quickly and effectively provide rigidity to the target thermoplastic (for example, polypropylene), particularly after heat-setting.

Abstract: A process for preparing a polymer, which comprises a) reacting a mixture (I) containing 6-aminocapronitrile and water in the presence of a catalyst to obtain a mixture (II) containing caprolactam, ammonia, water, high boilers and low boilers, then b) removing ammonia from mixture (II) to obtain a mixture (III) containing caprolactam, water, high boilers and low boilers, then c) removing all or some of the water from mixture (III) to obtain a mixture (IV) containing caprolactam, high boilers and low boilers and then d) feeding mixture (IV) to a polymerization reaction, and also the polymer obtainable by this process, the use of the polymer for producing fibers, sheetlike structures and moldings, and also fibers, sheetlike structures and moldings obtainable using such a polymer.

Abstract: Compositions with antimicrobial properties contain a fatty acid ester salt mixed with a bioabsorbable copolymer. These compositions are useful in forming coatings for surgical articles, including multifilament sutures.

Abstract: Microporous articles formed by thermally induced phase separation from a diluent in combination with a thermoplastic polymer and a fluorochemical additive providing novel fluid repellent articles. Such articles are useful in clothing, barrier membranes, optical films in electronic devices (such as light reflective and dispersive films), and protective garments.

Abstract: The present invention relates to a wrapped cord, to a method of making said wrapped cord, to a method of treating said wrapped cord with an adhesive treatment composition, to the treated wrapped cord obtainable by said method as well as to a reinforced rubber article comprising said treated cord, such as automotive tires.

Abstract: A polyester fiber containing polyethylene terephthalate at 90 mol % or higher of a whole repeating unit in a molecular chain thereof, the fiber having an intrinsic viscosity (IV) of 0.85 dl/g or higher and simultaneously meeting the following characteristics: (a) strength?6.0 cN/dtex; (b) strength×(breaking elongation)0.5?26.0 cN/dtex. %0.5; (c) monofilament linear density?5.0 dtex; and (d) main dispersion peak temperature of loss tangent (tan ?) in the measurement of dynamic viscoelasticity at 110 Hz?147.0° C.

Abstract: The present invention provides an improved fiber-reinforced article comprised of at least two plies. Each of the plies comprises (a) rubber and (b) cord made from melt-spinnable, non-metallic, multifilament fibers for which the cord has a twist multiplier of less than or equal to about 375, a stress at 1% strain greater than or equal to about 1.7 grams/denier, and an initial compressive modulus greater than or equal to about 7 grams/denier, and the at least two plies have a fiber orientation angle of greater than or equal to about 23°. The composite is useful as a tire belt in a passenger tire.

Abstract: A string binder is disclosed which is useful for making reinforcing articles for use in the manufacture of molded composite articles. The string binder comprises a fibrous substrate with chemical treatment, applied thereto, comprising a polyester resin, a curing agent, a film former, and a thickener. Additionally, the string binder may be co-roved with one or more ends of a separate fibrous pre-form material to make a product suitable for use in various molding applications.

Abstract: Polymeric structures produced with a controlled number and distribution of small, closed cells. The polymeric structures are characterized by an opaque, whitening appearance attributed, at least in part, to the distribution of closed cells and thus, at least in part, to light scattering resulting from the distribution of small, closed cells or voids. The light scattering thus provides an enhanced whitening effect. The whitening effect may be uniform or non-uniform along the length and width of the structure.

Abstract: A poly(trimethylene terephthalate)-based conjugate fiber characterized in that the fiber is composed of single filaments which are combined with two polyester components in a side-by-side manner or an eccentric sheath-core manner, that at least one of the two polyester components forming the single filaments is a poly(trimethylene terephthalate), and that the fiber satisfies the following conditions: (1) the stretch elongation of crimp manifested prior to boiling water treatment is 20% or less; (2) the breaking elongation is from 25 to 100%; and (3) the maximum stress value of a dry heat shrinkage stress is from 0.01 to 0.24 cN/dtex.

Abstract: The invention provides polyurethane containing a) a first additive comprising at least one mono-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; b) a second additive selected from the group consisting of i) condensation polymers of p-cresol and divinyl benzene and ii) compounds comprising at least one unsymmetrically di-hindered hydroxyphenyl group and having a molecular weight of at least about 300 Daltons; and c) an inorganic chlorine-resist additive. The polyurethane of the invention exhibits improved resistance to degradation by chlorine and by atmospheric fumes.

Abstract: A heat-resistant fiber paper sheet which is formed from staple fibers made from a heat-resistant organic polymer, undrawn or low ratio drawn para-aromatic polyamide staple fibers, and an organic resin binder and/or fibrids comprising a heat-resistant organic polymer as main components, wherein the amount of said staple fibers is 45 to 97 percent by weight based on the total amount of said heat-resistant fiber paper sheet; the total amount of said organic resin binder and/or said fibrids is 3 to 55 percent by weight based on the total amount of said heat-resistant fiber paper sheet; and said organic resin binder is cured, and/or said undrawn or low ratio drawn para-aromatic polyamide staple fibers and said fibrids are partially softened, deformed and/or melted to exhibit the actions of binders.

Abstract: The invention relates to a randomly branched polyamide comprising at least units derived from: 1. AB monomers, 2. at least one compound I, being a carboxylic acid (Av) having a functionality v≧2 or an amine (Bw) having a functionality w≧2, 3. at least one compound II, being a carboxylic acid (Av) having a functionality v≧3 or an amine (Bw) having a functionality w≧3, compound II being a carboxylic acid if compound I is an amine or compound II being an amine if compound I is a carboxylic acid and the amounts of all units derived from carboxylic acids and amines in the polyamide satisfying conditions as mentioned in claim 1. The composition of the randomly branched polyamide is such that it cannot form a crosslinked polyamide (and thus no gels, either), in particular during the prepolymerization, the polymerization, the post-condensation, the processing and the storage of the randomly branched polyamide, and this at a variety of ambient factors, for instance at elevated temperature and pressure.

Abstract: A spontaneously degradable fiber excellent in bulkiness, softness, stretchability and feeling, which comprises (A) a low heat-shrinkable fiber component comprising a high crystalline aliphatic polyester and (B) a high heat-shrinkable fiber component comprising an aliphatic polyester, e.g., a low crystalline or non-crystalline aliphatic polyester, and a block copolymer or a mixture the main component of which is an aliphatic polyester and which comprises a high-melting component and a low-melting component. Further, fibers excellent in self-crimpability or self-adhesion property and dividable fibers are obtained by suitably combining the fiber components (A) and (B) to form conjugated fibers or composite yarns.

Abstract: The invention pertains to cut-resistant articles, in particular to gloves. The articles comprise microfilaments of aromatic polyamides, more preferably p-aramid, wherein the titer of the microfilaments is equal to or smaller than 1.3 dtex (1.3×10−4 g/m). In a preferred embodiment the article is prepared from staple fibers with a length between 38 and 100 mm.

Abstract: An adhesion promoter comprises a polymeric strand with an epoxy-reactive group other than a phenolic hydroxyl group, and a crosslinking group that crosslinks the polymeric strand with a rubber in a crosslinking reaction, wherein the polymeric strand is water soluble in an amount of at least 10 g/l, and more preferably at least 100 g/l. Particularly contemplated adhesion promoters may further comprise styrene-butadiene-vinylpyridine copolymer, and may advantageously be employed as a replacement for resorcinol-formaldehyde latex in the fabrication of a rubber containing tire. Especially contemplated rubber compositions may additionally comprise maleinized polybutadiene to synergistically improve adhesion of the rubber to a polymeric fiber coupled via contemplated adhesion promoters.

Abstract: A string binder is disclosed which is useful for making reinforcing articles for use in the manufacture of molded composite articles. The string binder comprises a fibrous substrate with a chemical treatment, applied thereto, comprising an epoxy film former, a curing agent, a thickener, and water. Additionally, the string binder may be co-roved with one or more ends of a separate fibrous pre-form material to make a product suitable for use in various molding applications.

Abstract: A procedure for removing a water-insoluble finish from aramide fibers, wherein the aramide fibers are present as short-cut, random fibers or flat textile materials and are treated with an agent that contains at least one hydrophilic fluid.

Abstract: A spun polyester fiber, a drawn polyester yarn, and methods for making them. Polyethylene terephthalate yarn is prepared by extruding a molten melt-spinnable polyethylene terephthalate having an intrinsic viscosity of at least about 0.8 through a shaped extrusion orifice having a plurality of openings to form a molten spun yarn; solidifying gradually said molten spun yarn by passing said molten spun yarn through a solidification zone which comprises (i) a retarded cooling zone and (ii) a cooling zone adjacent said retarded cooling zone where, in said cooling zone, said yarn is rapidly cooled and solidified in a gaseous atmosphere; withdrawing at sufficient speed said solidified yarn from said solidification zone to form a crystalline partially oriented yarn; and hot drawing said crystalline partially oriented yarn at a total draw ratio between about 1.5/1 and about 2.

Abstract: A space-dyed yarn and textile construction formed therefrom is provided. The space-dyed yarn includes a multiplicity of discrete color segments arranged along the length of the yarn. The color segments are of finite lengths which may be in the range of less than about 2 inches. The yarns may have linear densities under about 500 denier. A process and apparatus for production of the space-dyed yarns are also provided.

Abstract: A package of polyester type conjugate fiber of either a side-by-side type or an eccentric sheath/core type in which two kinds of polyester components are adhered to each other to form a single filament, wherein at least one of the components consisting of the single filament is polytrimethylene terephthalate containing repeating units of trimethylene terephthalate of 90 mol % or more, which package is formed of 2 kg or more of the conjugate fiber and satisfies the following items (1) to (3): (1) the difference in diameter between a selvage portion and a central portion of the package is 10 mm or less, (2) a winding width of the package is in a range from 60 to 250 mm and a diameter of the package is in a range from 100 to 400 mm, and (3) the difference in dry-heat shrinkage stress value between the conjugate fibers layered in the selvage portion and the central portion of the package is 0.05 cN/dtex or less.

Abstract: Poly(p-phenylene-2,6-benzobisoxazole) (“PBO”) yarn or cord is first coated with a subcoat of a mixture of (a) an aliphatic polyglycidyl ether having a flash point greater than 150° C. with enough OH-groups to be substantially water-soluble and (b) a vinyl pyridine-styrene-butadiene rubber latex (VPSBRL), then coated in a conventional RFL dip, yields a twice-coated PBO yarn; this yarn provides adhesive strength in sulfur-vulcanizable rubber which is substantially the same as, or better than, that provided by aramid yarn having the same physical dimensions and construction, and coated with an aromatic polyglycidyl ether.

Abstract: The present invention is directed to highly attenuated fibers produced by melt spinning a composition comprising destructurized starch, a thermoplastic polymer, and a plasticizer. The present invention is also directed to highly attenuated fibers containing microfibrils which are formed within the starch matrix. Nonwoven webs and disposable articles comprising the highly attenuated fibers are also disclosed.

Abstract: A spun yarn comprising poly(trimethylene terephthalate) staple fibers at a content of at least 15% by weight, the spun yarn having an elastic recovery percentage of elongation at 5% elongation (%) ≧0.1 X+70 (wherein X represents the content of poly(trimethylene terephthalate) staple fibers in the spun yarn (wt %)). The spun yarn is excellent in knitting and weaving characteristics, stretchability and stretch-back property and in shape stability and durability when worn for a prolonged period of time.

Abstract: A filament machine sewing thread comprising a spun combined filament yarn obtained by combining polyester filaments A having an intrinsic viscosity [&eegr;]F within the range of 0.7 to 1.2 with polyester filaments B having a lower intrinsic viscosity [&eegr;]F than that of the polyester filaments A by 0.2 to 0.7 and a higher elongation than that of the polyester filaments A in a spinning stage.

Abstract: A process for the preparation of novel polyamides, the use of such polyamides for the production of fibers, sheets and moldings, and fibers, sheets and moldings obtainable from such polyamides, are provided.

Abstract: PVA binder fibers having the following characteristics: a cross-section circularity of at most 30%, a degree of swelling in water at 30° C. of at least 100%, and a degree of dissolution in water of at most 20%, are capable of being processed even under low-energy drying condition, for example, in high-speed drying in a hot air drying system (e.g., air-through drier) or in low-temperature drying in a multi-cylinder system or the like to give paper and nonwoven fabrics of high strength.

Abstract: An adhesion promoter comprises a polymeric strand with an epoxy-reactive group other than a phenolic hydroxyl group, and a crosslinking group that crosslinks the polymeric strand with a rubber in a crosslinking reaction, wherein the polymeric strand is water soluble in an amount of at least 10 g/l, and more preferably at least 100 g/l. Particularly contemplated adhesion promoters may further comprise styrene-butadiene-vinylpyridine copolymer, and may advantageously be employed as a replacement for resorcinol-formaldehyde latex in the fabrication of a rubber containing tire. Especially contemplated rubber compositions may additionally comprise maleinized polybutadiene to synergistically improve adhesion of the rubber to a polymeric fiber coupled via contemplated adhesion promoters.

Abstract: Provide a manufacturing method for polyester yarn excellent in yarn transferring, packaging and loosing with no white powder occurred when weaving, which is heating polyester polymer of inherent viscosity (IV) 0.5˜0.7 and melting point of 245˜265° C. to melt, filter and extruding in constant amount by direct spin drawing of monofilament yarn or combining multi-tow of filaments, then splitting to obtain polyester yarn having high denier in monofilament, characterized in comprising the following steps: a. uniformly spinning said constant amount extruded polyester melt through spinneret orifices to obtain the filament tows, passing said spun filament tows under spinneret to uniformly cooled to solidify in the quenching air tube, wherein said quenching air tube is equipped with chilling water tubular coil to keep the temperature of quenching air at 10˜15° C.; b.

Abstract: A finishing composition containing a nonionic hydrophilic macromolecule can replace wax in sizing while providing lubrication to yarns during weaving. Softer yarns and fabrics are obtained than with conventional sized yarns while also providing improved adhesion and dyeability.

Abstract: A treated poly(trimethylene terephthalate) carpet prepared by applying a polyfluoroacrylate emulsion to a poly(trimethylene terephthalate) carpet and curing the polyfluoroacrylate.

Abstract: Polyimides having a desired combination of high thermo-oxidative stability, low moisture absorption and excellent chemical and corrosion resistance are prepared by reacting a mixture of compounds including (a) 3,3′,4,4′-benzophenonetetracarboxylic dianhydride (BTDA), (b) 3,4′-oxydianiline (3,4′-ODA), and (c) 5-norbornene-2,3-dicarboxylic anhydride (NA) in a high boiling, aprotic solvent to give 5 to 35% by weight of polyamic acid solution. The ratio of (a), (b), and (c) is selected to afford a family of polyimides having different molecular weights and properties. The mixture first forms a polyamic acid precursor. Upon heating at or above 300° C., the polyamic acids form polyimides, which are particularly suitable for use as a high temperature coating, adhesive, thin film, or composite matrix resin.

Abstract: A process for the preparation of novel polyamides, the use of such polyamides for the production of fibers, sheets and moldings, and fibers, sheets and moldings obtainable from such polyamides, are provided.

Abstract: A polytrimethylene terephthalate (PTT) filament yarn capable of being produced by a high speed spinning method and having a high residual elongation and excellent draw-false twisting processability includes 0.5 to 4.0% by mass of filament elongation enhancing agent particles which are drawn-oriented in the filaments along the longitudinal direction thereof and have a thermal deformation temperature of 40° C. or more but less than 105° C., an average particle size D of 0.03 to 0.35 &mgr;m determined in the cross-sections of the filaments and a ratio L/D of the average particle length L in the filament longitudinal direction to the average cross-sectional particle size D of 2 to 20; and the filament yarn exhibits an increase in the residual elongation of 30% or more due to the presence of the filament elongation enhancing agent, a birefringence &Dgr;n of 0.02 to 0.07, a retaining elongation of 60 to 250% and a thermal stress peak value of 0.18 cN/dtex or less.

Abstract: A roof membrane and a roof system employing a EPDM membrance which is compatible with a bituminous adhesive. The membrance includes an outer layer of polymeric layer such as EPDM bonded to a polyester protective layer which is in turn bonded to a fleecy material. This can be adhered to a roof deck surface using hot asphalt or bitumen which bonds the fleecy material to the roof deck in turn holding the EPDM in place. The polyester layer prevents the asphaltic material from attacking and dissolving the EPDM with the fleecy material providing good adhesion between the polyester and the EPDM.

Abstract: A polyester fiber having improved dripping resistance during burning can be provided by a polyester fiber made of a polyester composition containing a layer compound treated with at least one kind selected from a polyether compound and a silane compound, and a thermoplastic polyester resin. The present invention also relates to a polyester fiber made of a polyester composition comprising a layer compound treated with a water-soluble or water-miscible phosphorus flame retardant, and a thermoplastic polyester resin.

Abstract: A textile article having flame resistant properties includes a plurality of inherently flame resistant polyester fibers formed into a fabric, and a finish on the fabric including a cyclic phosphonate flame retardant. The finish imparts a property selected from the group consisting of: a molecularly bound antimicrobial agent which is an organosilane, a fluorochemical soil and fluid repellant, and the finished textile article has a flame resistance that passes the standard method NFPA 701-1996 edition testing protocol.

Abstract: Disclosed is a high strength and low shrinkage polyester yarn, which has tenacity of 7.4 g/d or higher, elongation at break of 19 to 26%, shrinkage percentage of 2% or lower, and respective thermal-stress peaks of 3×10−2 to 7.5×10−2 g/d and 8.0×10−2 to 10.5×10−2 g/d at temperature ranges of 100 to 140° C. and 230 to 240° C., and process for its preparation. The high strength and low shrinkage polyester yarn is advantageous in that it has desirable resistance to external load and excellent dimensional stability, and is very useful as an industrial yarn with uniform shrinkage and excellent dimensional stability during a post-process for application to tarpaulin and truck covers.

Abstract: Disclosed is to provide a modified polyester filament, which is formed by spinning the polyester resin composed of ethylene terephthalate more than 85 mol % as main component repeating unit, and component A organic sulfonate shown as the formula listed below

Abstract: HMLS filaments consisting of a polyester, from 0.1 to 2.5% by weight of an incompatible, thermoplastic, amorphous, polymeric additive having a glass transition temperature of from 90 to 170° C. and a ratio of its melt viscosity to that of the polyester component of from 1:1 to 7:1, and from 0 to 5.0% by weight of conventional additives, where the polymeric additive is present in the filaments in the form of fibrils having a mean diameter of ≦80 nm. Process for the production of these HMLS filaments by static mixing with shearing of the polyester and of the polymeric additive and, optionally, of the additives, spinning of the mixture at a spinning take-off speed of from 2500 to 4000 m/min to give spun filaments which are stretched, heat-set and wound up, where the concentration of the polymeric additive is determined as a function of the pre-specified spinning take-off speed and the desired birefringence of the spun filaments.

Abstract: A process of making a pigmented shaped article comprising: (a) providing polytrimethylene terephthalate chips and two or more colored pigmented chips each containing at least one different color pigment; (b) heating the polytrimethylene terephthalate chips and colored pigmented chips to a temperature of about 200-about 280° C. to melt the chips and form a polymer composition comprising the polytrimethylene terephthalate and at least one color pigment; and (c) forming a shaped article from the polymer composition.

Abstract: The present invention relates to multifilament crimped yarn comprising an aliphatic polyester and methods for producing thereof, and to carpets that are manufactured by using the crimped yarn. The present invention provides an aliphatic polyester multifilament crimped yarn for the carpets comprising an aliphatic polyester having a melting point of equal to or higher than 130° C., said multifilament crimped yarn having crimp elongation rate of the multifilament crimped yarn after being processed with boiling water of 3-35% and breaking strength of 1-5 cN/decitex.

Abstract: A space-dyed yarn of monofilament construction and textiles formed therefrom is provided. The space-dyed yarn includes a multiplicity of discrete color segments arranged along the length of the yarn. The color segments are of finite lengths which may be in the range of less than about 2 inches. A process and apparatus for production of the space-dyed yarns are also provided.

Abstract: Unique thermoplastic (polypropylene, specifically) monofilament and/or tape fibers and yarns that exhibit heretofore unattained physical properties are provided. Such fibers are basically manufactured through the extrusion of thermoplastic resins that include a certain class of nucleating agent therein, and are able to be drawn at high ratios with such nucleating agents present, that the tenacity and modulus strength are much higher than other previously produced thermoplastic fibers (particularly those produced under commercial conditions), particularly those that also simultaneously exhibit extremely low shrinkage rates. Thus, such fibers require the presence of certain compounds that quickly and effectively provide rigidity to the target thermoplastic (for example, polypropylene), particularly after heat-setting.

Abstract: Unique thermoplastic monofilament fibers and yarns that exhibit heretofore unattained physical properties are provided. Such fibers are basically manufactured through the extrusion of thermoplastic resins that include a certain class of nucleating agent therein, and are able to be drawn at high ratios with such nucleating agents present, that the tenacity and modulus strength are much higher than any other previously produced thermoplastic fibers, particularly those that also simultaneously exhibit extremely low shrinkage rates. Thus, such fibers require the presence of certain compounds that quickly and effectively provide rigidity to the target thermoplastic (for example, polypropylene), particularly after heat-setting. Generally, these compounds include any structure that nucleates polymer crystals within the target thermoplastic after exposure to sufficient heat to melt the initial pelletized polymer and allowing such an oriented polymer to cool.

Abstract: An enhanced fishing line has a unique combination of breaking strength and elongation properties to provide a high level of flexibility, a high ultimate knot breaking strength, and a high level of breaking toughness that is defined as the actual work per unit volume of material required to break the material. The line is a monofilament construction made of a synthetic polymeric material such as a polyamide, polyester, polyethylene, or fluropolymer and manufactured by an extrusion process followed by a drawing process where the extruded diameter is between 1.1 and 1.4 times the diameter of the finished line after drawing.

Abstract: An acid-dyeable polymer composition comprising (a) polymer and (b) polymeric additive comprising repeating units having the formula: or salts thereof, wherein A, B and Q, which may be the same or different, are selected from aliphatic or aromatic substituents provided that at least four carbon atoms separate any two nitrogen groups, R is an aliphatic or aromatic group, a is 1 to 5, and n is 3 to about 1,000. In addition, an acid-dyed composition prepared from the composition, a process of acid dyeing the composition and a process for preparing the composition.

Abstract: A process for antibacterially finishing a polymeric substrate involving: (a) providing a polymeric substrate made from a compound selected from the group consisting of a polyolefin, a polyester, and combinations thereof; (b) providing an antibacterial finish composition containing: (i) from about 0.1 to 10% by weight of at least one monoester of glycerol and a C6-14 fatty acid; and (ii) from about 0.01 to 10% by weight of chitosan, all weights being based on the weight of the composition; and (c) applying the composition onto the polymeric substrate.