Solid-walled Microcapsule From Synthetic Polymer Patents (Class 428/402.21)
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Publication number: 20130185817Abstract: This disclosure is particularly directed to arthropodal compositions in the form of capsules containing an active arthropod agent, more particularly to capsules containing an active arthropod agent and methods of making and using the same. The active arthropod agent may be an insect repellent and/or an insecticide agent.Type: ApplicationFiled: January 14, 2013Publication date: July 18, 2013Inventors: Troy S. Massey, Jeffrey T. Langley
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Patent number: 8486531Abstract: The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: GrantFiled: January 23, 2012Date of Patent: July 16, 2013Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Ichiro Takahara, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Patent number: 8465778Abstract: Biocompatible intraocular microspheres include a tyrosine kinase inhibitor and a biodegradable polymer that is effective to facilitate release of the tyrosine kinase inhibitor into the vitreous of an eye for an extended period of time. The therapeutic agents of the microspheres can be associated with a biodegradable polymer matrix, such as a matrix that is substantially free of a polyvinyl alcohol. The microspheres can be placed into an eye to treat or reduce the occurrence of one or more ocular conditions.Type: GrantFiled: June 19, 2012Date of Patent: June 18, 2013Assignee: Allergan, Inc.Inventors: Patrick M. Hughes, Christian Sarrazin, Elisabeth Rossi, Michèle Boix
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Patent number: 8465835Abstract: A method of making core-shell capsules containing a water-immiscible liquid, comprising the steps of (a) dispersing into the water-immiscible liquid a crosslinking agent that is inactive under the conditions of the dispersion; (b) emulsifying the resulting dispersion into an aqueous solution of a crosslinkable hydrocolloid; and (c) activating the crosslinking agent to cause the hydrocolloid to crosslink at the dispersion/solution interface. The method is simple and provides capsules that can be cold-loaded. The capsule material may be made of vegetable-derived materials.Type: GrantFiled: August 31, 2007Date of Patent: June 18, 2013Assignee: Givaudan S.A.Inventor: Robert Guisinger
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Patent number: 8460792Abstract: A microcapsule which is able to stably retain a benefit agent such as a volatile substance for an extended period, and which is also suitable for encapsulating fragrances and the like. Such capsule encapsulates a mixture comprising a volatile substance, and an additive that has a higher melting point than the volatile substance and is able to undergo mutual dissolution with the volatile substance, wherein the mixture exhibits a melting point range, and a portion of, or all of, that melting point range falls within a range from ?20 to 60° C. The present invention also relates to consumer products including cleaning and/or treatment compositions comprising such microcapsules, and processes of making and using same.Type: GrantFiled: January 27, 2011Date of Patent: June 11, 2013Assignee: The Procter & Gamble CompanyInventors: Johan Smets, Radhakrishnan Janardanan Nair, An Pintens, Takuya Yasuhara, Takashi Iwasaki
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Patent number: 8461086Abstract: Disclosed is a microcapsule composition for inhibiting an ethylene response in plants, which comprises a plurality of microcapsules, each including an agent for blocking an ethylene binding site in plants in an oil droplet, and a coating encapsulating the oil droplet and the agent for blocking the ethylene binding site in plants. A method for preparing microcapsules of an agent for blocking the ethylene binding site in plants, and a method for inhibiting an ethylene response in plants are also disclosed.Type: GrantFiled: October 16, 2009Date of Patent: June 11, 2013Assignee: Lytone Enterprise, Inc.Inventors: William T. H. Chang, Hsi Ying Chen, Yi Chieh Wang
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Patent number: 8460791Abstract: The present invention concerns microcapsules comprising a capsule core and a capsule wall composed of thermoset polymer and also, disposed on the outer surface of the capsule wall, a polyelectrolyte having an average molecular weight in the range from 500 g/mol to 10 million g/mol, and also a process for their production and their use in bindered building materials, textiles, heat transfer fluids and dumped beds.Type: GrantFiled: July 5, 2007Date of Patent: June 11, 2013Assignee: BASF AktiengesellschaftInventors: Hans-Peter Hentze, Dieter Niederberger, Hans Willax, Joachim Burger, Daniel Pascual Gienap
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Patent number: 8449981Abstract: The present invention concerns microcapsules comprising a capsule core and a capsule wall, the capsule wall being constructed from 30% to 90% by weight of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid, acrylic acid, methacrylic acid and/or maleic acid (monomers I), 10% to 70% by weight of a mixture of divinyl and polyvinyl monomers (monomers II), the fraction of polyvinyl monomers being in the range from 2% to 90% by weight based on the monomers II, and also 0% to 30% by weight of one or more miscellaneous monomers (monomer III), all based on the total weight of the monomers, a process for their production and their use in textiles, bindered building materials and heat transfer fluids.Type: GrantFiled: December 10, 2007Date of Patent: May 28, 2013Assignee: BASF SEInventors: Marc Rudolf Jung, Hans-Peter Hentze, Rainer Dyllick-Brenzinger, Dieter Niederberger, Hans Willax
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Patent number: 8404345Abstract: Microcapsules for smart textile materials, containing an active product and with reactive groups, with the objective of chemically binding the microcapsules to the fibers. The microcapsules contain active products such as PCM (phase change materials), or can be of controlled release of products such as fragrances, essential oils, antibacterial and others with the objective to add specific functional properties to the textile materials. They can be applied by padding and spraying followed by thermofixation. In case of products such as knitwear the application process can also be by exhaustion process, given that the microcapsules acquire affinity towards the fibers and react with the fibers during the process. The chemical bond of the controlled release microcapsules with the fibers confers them a higher resistance to washing than the existing microcapsules glued to the fabric by printing or padding.Type: GrantFiled: February 27, 2006Date of Patent: March 26, 2013Assignee: Devan-Micropolis SAInventors: Jamie Isidoro Naylor Rocha Gomes, Raquel Maria Magalhaes Vaz Vieira, Sandra Maria Pinto Cerqueira Barros
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Patent number: 8394497Abstract: Microencapsulated particles having improved resistance to moisture and extended release capabilities are produced by microencapsulating the particles in a film-forming, cross-linked, hydrolyzed polymer.Type: GrantFiled: August 19, 2011Date of Patent: March 12, 2013Assignee: Encap Technologies, LLCInventor: Robert G. Bayless
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Patent number: 8389605Abstract: A self-repairing concrete includes carbamide resin polymer micro-capsules, in which the carbamide resin polymer micro-capsules are mixed for a fixed function of micro-cracks. The quality mixture ratio is: concrete/micro capsules/water=100:1-15:15-50. The manufacturing method is weighing a full amount of water in a container, adding carbamide resin polymer micro-capsules, stirring, until fully dispersed microcapsules; pouring the water into the mixing container, adding the corresponding quality of cement; stirring; adding sand and gravel filling materials, conducting worksite watering, ? volume for each time, vibrating, and air exhausting; until the slurry filling mold.Type: GrantFiled: October 24, 2008Date of Patent: March 5, 2013Assignees: Shenzhen UniversityInventors: Feng Xing, Zhuo Ni
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Publication number: 20130053612Abstract: The water aeration capsules provide a quick and highly portable system for aerating polluted water. The capsules contain bubbles of air, oxygen, and/or other gas(es) surrounded by a water soluble membrane. The capsules are ballasted to sink. Magnetically attractive ballast elements may be provided, and a magnetic sheet may be placed on the bottom of a smaller body of water to enhance the settling of the capsules. The gas burial disposal capsules may be formed of non-degradable material for substantially permanent gas storage, or of degradable material to allow the gases to slowly permeate the surrounding earth for slow and relatively harmless release. The gas may be pressurized within the capsules to approximately the pressure of the surrounding earth.Type: ApplicationFiled: August 15, 2012Publication date: February 28, 2013Inventor: BADER SHAFAQA AL-ANZI
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Patent number: 8357318Abstract: A process of preparation of microcapsules having a shell and a core that includes a waxy solid, includes (a) dispersing particles of waxy solid material in a water-immiscible liquid in which the waxy solid material is insoluble; (b) emulsifying the resulting dispersion into an aqueous solution of a capsule wall-forming material to form an emulsion of droplets; (c) forming a coating of the capsule wall-forming material on the emulsified droplets containing the dispersed waxy solid particles to provide capsules; (d) heating the capsules to a temperature above the melting point of the waxy solid material; and (e) cooling the capsules to a temperature below the melting point of the waxy solid material.Type: GrantFiled: April 25, 2008Date of Patent: January 22, 2013Assignee: Givaudan S.A.Inventors: Robert E. Guisinger, Robert B. Wieland
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Patent number: 8349435Abstract: An asphalt-based sheet roofing material includes capsules on its upper surface. When struck, as by hailstones, the capsules break to release a film forming fluid that spreads over the surface to heal the damage created by the hailstones.Type: GrantFiled: March 26, 2008Date of Patent: January 8, 2013Assignee: CertainTeed CorporationInventors: Ming Liang Shiao, Keith C. Hong, Gregory F. Jacobs
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Patent number: 8349451Abstract: To provide capsular fine particles comprising an olefinic polymer which have a uniform particle size distribution and a uniform particle size, and which are spherical and free from the coagulation between particles. Capsular fine particles comprising the olefinic polymer, of which the ratio (L/M) of the outer diameter (L) to the inner diameter (M) is 1.1 to 6.0, and the average diameter is 0.6 to 40 ?m.Type: GrantFiled: April 7, 2006Date of Patent: January 8, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Yasushi Nakayama, Naoto Matsukawa, Junji Saito, Susumu Murata, Makoto Mitani, Terunori Fujita
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Patent number: 8329154Abstract: Compositions for providing controlled-release of an active material comprise a dispersant and microcapsules containing the active material. The compositions contain the dispersant and/or microcapsules at relatively low levels to avoid negatively impacting the surfaces treated with the compositions. The active material is preferably a perfume and the composition provides a controlled-release scent, along with controlling malodor when the compositions fuirther comprise optional odor control agent. Methods of providing a controlled-release of an active material on a surface comprise the step of contacting the surface with a composition comprising a dispersant and microcapsules containing an active material.Type: GrantFiled: July 14, 2006Date of Patent: December 11, 2012Assignee: The Procter & Gamble CompanyInventors: Hirotaka Uchiyama, Jonathan Robert Cetti, Mario Alonso, David Lee Montezinos, Daniel Scott Cobb
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Patent number: 8329298Abstract: A method that heat-expandable microspheres includes the use of a shell of thermoplastic resin and a non-fluorine blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin. The method includes, a step of dispersing an oily mixture containing a polymerizable component, the blowing agent, and a polymerization initiator containing a peroxydicarbonate in an aqueous dispersing medium to polymerize the polymerizable component contained in the oily mixture. The resultant heat-expandable microsphres have a shell which is less apt to become thinner than its theoretical value, contain minimum amount of resin particle inside their shell, and have excellent heat-expanding performance.Type: GrantFiled: October 4, 2006Date of Patent: December 11, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Toshiaki Masuda, Kenichi Kitano, Katsushi Miki, Takeshi Inohara, Takayuki Aoki
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Patent number: 8323794Abstract: Injectable hydrogel microspheres are prepared by forming an emulsion where hydrogel precursors are in a disperse aqueous phase and polymerizing the hydrogel precursors. In a preferred case, the hydrogel precursors are poly(ethylene glycol) diacrylate and N-isopropylacrylamide and the continuous phase of the emulsion is an aqueous solution of dextran and a dextran solubility reducer. The microspheres will load protein, e.g., cytokines, from aqueous solution.Type: GrantFiled: August 12, 2010Date of Patent: December 4, 2012Assignee: Cornell Research Foundation, Inc.Inventors: Chih-Chang Chu, Xian-Zheng Zhang, Da-Qing Wu
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Patent number: 8304075Abstract: The present invention relates to a coarsely divided microcapsule preparation with particles whose particle sizes are in the range from 200 ?m to 5 cm, comprising microcapsules with a capsule core of latent heat storage material and a thermosetting polymer as capsule wall and one or more polymeric binders whose binder polymer has thermoplastic properties and film-forming properties under processing conditions, where the binder content, calculated as solid, is 1-30% by weight, based on the total weight of the coarsely divided microcapsule preparation.Type: GrantFiled: August 2, 2005Date of Patent: November 6, 2012Assignee: BASF AktiengesellschaftInventors: Gabriele Lang-Wittkowski, Ekkehard Jahns, Marco Schmidt, Michael Senge, Markus Steffen, Karl Kolter
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Publication number: 20120258150Abstract: Particles containing a polymer and a volatile material, such as a perfume, and particle gas saturated solution (PGSS) processes for making such particles are provided.Type: ApplicationFiled: March 29, 2012Publication date: October 11, 2012Inventors: Holly Balasubramanian Rauckhorst, Vicenzo D'Acchioli, Andreas Josef Dreher
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Patent number: 8273699Abstract: A process for preparing a perfume composition, the process having the steps of; (a) contacting a perfume ingredient with a molten material to form a pre-mix; (b) contacting the pre-mix with a first solid material to form a soft-solid intermediate high active perfume material; (c) solidifying the molten material to form a hardened-solid intermediate high active perfume material; (d) contacting the hardened-solid intermediate high active perfume intermediate material with a second solid material to form a perfume composition, wherein the ratio of the wt % amount of perfume ingredient present in the hardened-solid intermediate high active perfume material to the wt % amount of perfume ingredient present in the perfume composition is greater than 1.5:1.Type: GrantFiled: September 23, 2010Date of Patent: September 25, 2012Assignee: The Procter & Gamble CompanyInventors: Nicolas Guillard, Stuart Andrew Caldwell, Edward Sayers
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Patent number: 8263432Abstract: A material composition having a core-shell microstructure suitable for manufacturing a varistor having outstanding electrical properties, the core-shell microstructure of the material composition at least comprising a cored-structure made of a conductive or semi-conductive material and a shelled-structure made from a glass material to wrap the cored-structure, and electrical properties of the varistors during low temperature of sintering process can be decided and designated by precisely controlling the size of the grain of the cored-structure and the thickness and insulation resistance of the insulating layer of the shelled-structure of material composition.Type: GrantFiled: May 17, 2007Date of Patent: September 11, 2012Assignee: Bee Fund Biotechnology Inc.Inventors: Ching-Hohn Lien, Cheng-Tsung Kuo, Jun-Nan Lin, Jie-An Zhu, Li-Yun Zhang, Wei-Cheng Lien
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Patent number: 8246869Abstract: Photoactivatable prepolymers and methods of use thereof are disclosed for microencapsulation of a substantially water-insoluble material within a nonporous shell. As provided herein, the microencapsulated material is released with no more than a slow release rate. Upon exposure of the nonporous shell to light, the nonporous shell is converted into a porous shell having an increased release rate for the microencapsulated material.Type: GrantFiled: October 30, 2006Date of Patent: August 21, 2012Assignee: Solarbre, Inc.Inventor: Michael H. B. Stowell
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Patent number: 8246868Abstract: A W/O emulsion is produced from an aqueous solution containing a substance to be entrapped in a vesicle in a dissolved or suspended state and an oil phase containing an emulsifier; subsequently, the W/O emulsion is cooled to a temperature at which the aqueous solution of the W/O emulsion becomes a frozen particle and the oil phase maintains a liquid state, and the oil phase is removed; thereafter, an oil phase containing a vesicle constituent lipid is added to the frozen particle, and the obtained mixture is then stirred, so as to substitute the emulsifier on the surface of the frozen particle with the vesicle constituent lipid; and thereafter, an external Water phase is added to the frozen particle coated with a lipid membrane, so as to hydrate the lipid membrane by the external water phase. This process achieves a high entrapment yield of a desired substance while controlling desired physical properties such as particle diameter.Type: GrantFiled: March 3, 2008Date of Patent: August 21, 2012Assignee: University of TsukubaInventors: Sosaku Ichikawa, Takashi Kuroiwa
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Patent number: 8216598Abstract: The present invention deals with an alternative interfacial polymerization process of microencapsulation, microcapsule's produced thereof, microencapsulated agrochemicals, pharmaceuticals, catalysts and phase transfer materials, and formulations thereof, by means of microcapsules and starting materials with much lower toxicological profile than customary microencapsulation materials, and with the participation of acetylene carbamide derivatives in the final structure of the microcapsules' wall.Type: GrantFiled: March 28, 2007Date of Patent: July 10, 2012Assignee: GAT Microencapsulation AGInventors: Victor Casaña Giner, Miguel Gimeno Sierra, Barbara Gimeno Sierra
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Patent number: 8206826Abstract: A production method for heat-expandable microspheres, which have high expanding ratio and are thermally expanded into hollow particulates having excellent repeated-compression durability, and application thereof are provided. The method produces heat-expandable microspheres a shell of thermoplastic resin and a blowing agent being encapsulated therein and having a boiling point not higher than the softening point of the thermoplastic resin.Type: GrantFiled: May 14, 2008Date of Patent: June 26, 2012Assignee: Matsumoto Yushi-Seiyaku Co., Ltd.Inventors: Hiroki Naito, Satoshi Kawanami, Katsushi Miki, Ikuo Yosejima, Kenichi Kitano
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Publication number: 20120141796Abstract: A microfluidic device to produce polymersomes having three coaxial passageways of increasing size with fluid flowing in one direction. The first and smallest passageway contains the content of the polymersome, the middle passageway contains a block copolymer, and the largest and outer passageway contains an aqueous medium or water. The device can produce polymersomes with control of size and membrane thickness. The device will allow quantitative loading of the polymersomes in high quantities. The device is robust and easily assembled and has the ability to independently control the three streams involved in making the polymersomes.Type: ApplicationFiled: August 12, 2011Publication date: June 7, 2012Applicant: UNIVERSITY OF CONNECTICUTInventors: Douglas H. Adamson, Michael Stredney, Robert K. Prud'homme, Mustafa Erhan Yildiz
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Publication number: 20120121907Abstract: The present invention provides heat-expanded microspheres having high packing efficiency, and a production method thereof. The heat-expanded microspheres are produced by expanding heat-expandable microspheres, which comprise shell of thermoplastic resin and a blowing agent encapsulated therein having a boiling point not higher than the softening point of the thermoplastic resin and have an average particle size from 1 to 100 micrometer, at a temperature not lower than their expansion initiating temperature, and the heat-expanded microspheres result in a void fraction not higher than 0.70.Type: ApplicationFiled: January 23, 2012Publication date: May 17, 2012Applicant: MATSUMOTO YUSHI-SEIYAKU CO., LTD.Inventors: Toshiaki MASUDA, Ichiro TAKAHARA, Kenichi KITANO, Katsushi MIKI, Takeshi INOHARA, Takayuki AOKI
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Patent number: 8163207Abstract: The invention described herein relates to a method of preparing microcapsules comprising a capsule core, a polymeric capsule wall and also, disposed on the outer surface of the capsule wall, a polyelectrolyte having an average molecular weight in the range from 500 g/mol to 10 million g/mol, the polymeric capsule wall being formed from specified monomers, where the microcapsules have an average particle size of 1.5-2.5 ?m and 90% of the particles have a particle size ?4 ?m, by microencapsulating a capsule core with a polymeric capsule wall and then contacting the polymeric capsule wall with one or more polyelectrolytes in water or an aqueous medium.Type: GrantFiled: October 17, 2007Date of Patent: April 24, 2012Assignee: BASF AktiengesellschaftInventors: Marc Rudolf Jung, Dieter Niederberger, Hans Willax, Hans-Peter Hentze
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Patent number: 8114517Abstract: A micronetwork made from microcapsules with or without nanomaterials and/or micromaterials such as microtubes, nanotubes and/or buckyballs; the micronetworks can be formulated to provide for unique properties such as reduction of crack propagation and/or corrosion.Type: GrantFiled: August 1, 2005Date of Patent: February 14, 2012Assignee: Battelle Memorial InstituteInventors: Jay R. Sayre, James L. White
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Patent number: 8105652Abstract: A decomposable thin film comprising a plurality of polyelectrolyte layers of alternating charge, wherein decomposition of the thin film is characterized by degradation of at least a portion of the polyelectrolyte layers.Type: GrantFiled: July 26, 2006Date of Patent: January 31, 2012Assignee: Massachusetts Institute of TechnologyInventors: Kris C. Wood, Helen F. Chuang, Robert D. Batten, David M. Lynn, Paula T. Hammond Cunningham
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Patent number: 8088482Abstract: Hollow thermoexpandable particles or microspheres are provided that contain hydrocarbon blowing agents and have a shell polymer that can be softened at the onset of the expansion temperature and solidified at a higher temperature (thermoset) in an expanded state. Preferably, the microspheres have a shell of thermally expandable and thermally crosslinkable polymer and a hollow interior that contains a hydrocarbon liquid that boils at a temperature below the heat activated crosslinking temperature of the polymer shell. The crosslinking of the shell polymer during or after expansion, which is heat activated at an elevated temperature, can solidify the shell polymer and, then, maintain the expanded volume of the microspheres. The thermoexpandable thermoset polymer particles are useful in insulation, packaging, for making foam materials such as polyurethane or polyisocyanurate rigid foams.Type: GrantFiled: May 24, 2002Date of Patent: January 3, 2012Assignee: IP Rights, LLCInventors: Sammie J. (Joey) Glorioso, Jr., James H. Burgess, Jiansheng Tang, Victoria L. Dimonie, Andrew Klein
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Patent number: 8080318Abstract: An image fixing member includes a substrate; an optional intermediate layer over the substrate; and an outermost layer over the intermediate layer; wherein at least one of the intermediate layer and the outermost layer comprises a healing material encapsulated within nano- or micro-capsules, wherein the healing material is capable of retaining the function of the imaging fixing member.Type: GrantFiled: March 7, 2008Date of Patent: December 20, 2011Assignee: Xerox CorporationInventors: Kathy L. De Jong, Nan-Xing Hu, Giuseppa Baranyi, Barkev Keoshkerian
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Patent number: 8070876Abstract: A fireproof insulating foamed cementitious composition with thermal energy storage capacity is provided for use in producing wall insulation boards, fireproof claddings for steel structures, inner cores of fire resistant wall or door panels, and the like. The composition demonstrates improved energy efficiency in which phase change materials, such as microencapsulates, are used in conjunction with a cementitious mixture of calcined gypsum and hydraulic cement, lightweight aggregates, a polymer latex, and a foaming solution to create stable air bubbles inside the cementitious matrix. The calcined gypsum and the hydraulic cement are present in a weight ratio range from about 1:3 to about 3:1. The composition may further include reinforced fibers, surfactants, inorganic flame retardants, and other additives.Type: GrantFiled: May 5, 2011Date of Patent: December 6, 2011Inventor: Haihong Jiang
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Patent number: 8071214Abstract: The invention discloses a population of selected permeability microcapsule particles comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material. The microcapsule wall material comprises the reaction product of a first composition in the presence of a second composition comprising an anionic emulsifier. The first composition comprises a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The anionic emulsifier comprises a water soluble or water dispersible acrylic acid alkyl acid copolymer, an optional initiator and an alkali or alkali salt. The reaction product of the first composition and second composition can result in the formation of a low permeability microcapsule wall. Optionally, one or both of the first composition initiator or water phase initiator is an energy-activated initiator, such as a UV initiator.Type: GrantFiled: August 6, 2008Date of Patent: December 6, 2011Assignee: Appleton Papers Inc.Inventor: Todd Arlin Schwantes
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Patent number: 8067089Abstract: The present invention teaches a cationically charged or neutral microcapsule particle comprising an oil soluble or dispersible core material and a wall material at least partially surrounding the core material, the microcapsule wall material comprising the reaction product of a first composition in the presence of a second composition comprising an emulsifier which is cationic or nonionic, the first composition comprising a reaction product of i) an oil soluble or dispersible amine with ii) a multifunctional acrylate or methacrylate monomer or oligomer, an oil soluble acid and an initiator. The cationic or nonionic emulsifier comprises a water soluble or water dispersible material and optionally a water phase initiator. The first composition initiator and the water phase initiator is an energy-activated initiator.Type: GrantFiled: March 27, 2009Date of Patent: November 29, 2011Assignee: Appleton Papers Inc.Inventor: Todd Arlin Schwantes
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Patent number: 8067355Abstract: The present invention relates to benefit agent containing delivery particles, compositions comprising said particles, and processes for making and using the aforementioned particles and compositions. When employed in compositions, for example, compositions for cleaning, fabric care, or coating onto various substrates, textiles or surfaces, such particles increase the efficiency of benefit agent delivery, thereby allowing reduced amounts of benefit agents to be employed. In addition to allowing the amount of benefit agent to be reduced, such particles allow a broad range of benefit agents to be employed.Type: GrantFiled: April 8, 2009Date of Patent: November 29, 2011Assignee: Appleton Papers Inc.Inventors: Johan Smets, Peggy Dorothy Sands, Sandra Jacqueline Guinebretiere, An Pintens, Jiten Odhavji Dihora
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Patent number: 8048524Abstract: The present invention relates to a multilayer polymer latex comprising a seed, a rubbery core surrounding the seed, and a shell surrounding the rubbery core, in which the seed comprises a vinyl unit, a hydrophilic unit and a crosslinker unit, as well as a preparation method thereof. The present invention can provide an acrylic polymer latex and a diene polymer latex, depending on materials constituting the core and the shell. In the present invention, the seed containing a vinyl unit, a hydrophilic unit and a crosslinker unit, and the rubbery core, are used for the preparation of the polymer latex. This can increase the rubber content of the polymer latex, thus improving the impact resistance of the polymer latex, and at the same time, reduce the viscosity of the polymer latex so as to improve the long-term workability of the polymer latex upon spray drying. Thus, polymer powder prepared from the polymer latex is excellent in not only impact resistance but also flow properties.Type: GrantFiled: December 29, 2004Date of Patent: November 1, 2011Assignee: LG Chem, Ltd.Inventors: Jeong Heon Ahn, Byung Tae Yang, Chan Hong Lee
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Patent number: 8039015Abstract: Microcapsules possessing Lewis acid-Lewis base salt walls incorporate water-immiscible materials, such as N,N-diethyl-m-toluamide (DEET), as a core component. Such microcapsules, or similar microcapsules incorporating other core components, may be made by emulsifying a water-immiscible core component in an aqueous solution of one wall-forming reactant, such as the Lewis base, and then mixing that solution with the other wall-forming reactant, such as the Lewis acid. Various adjuvants may be included with the core component to contribute additional characteristics, such as enhancement of a controlled release characteristic or improved mechanical stability.Type: GrantFiled: December 7, 2005Date of Patent: October 18, 2011Inventor: Tycho J. Speaker
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Patent number: 8034450Abstract: Described herein are microcapsules and emulsions prepared from low Bloom gelatin and methods of making and using thereof.Type: GrantFiled: September 15, 2005Date of Patent: October 11, 2011Assignee: Ocean Nutrition Canada LimitedInventors: Jonathan Michael Curtis, Wei Zhang, Yulai Jin, Colin James Barrow
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Patent number: 8017047Abstract: Microcapsules wherein the capsule wall is formed from an organic polymer (capsule wall polymer for short) and the core of the microcapsules comprises compounds containing carbodiimide groups (carbodiimide compound for short).Type: GrantFiled: December 11, 2007Date of Patent: September 13, 2011Assignee: BASF SEInventors: Andre Burghardt, Maria Teresa Hechavarria Fonseca, Karl Haeberle, Oliver Hartz, Marc Rudolf Jung, Karl-Heinz Schumacher, Denise du Fresne von Hohenesche, Hans-Peter Hentze
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Patent number: 8003211Abstract: Microencapsulated particles having improved resistance to moisture and extended release capabilities are produced by microencapsulating the particles in a film-forming, cross-linked, hydrolyzed polymer.Type: GrantFiled: December 2, 2008Date of Patent: August 23, 2011Assignee: ENCAP Technologies, LLCInventor: Robert G. Bayless
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Patent number: 7985445Abstract: A novel method of forming water in oil microcapsules is disclosed. According to the invention microcapsules are obtained by steps comprising dispersing an oil soluble amine modified polyfunctional polyvinyl monomer and an oil soluble bi- or polyfunctional vinyl monomer along with a thermal or UV free radical initiator (optionally included in one or both of the oil or water phases) and an organic acid into an internal phase oil; heating or UV exposing for a time (and temperature) sufficient to oligomerize the amine modified polyfunctional polyvinyl monomer and oil soluble bi- or polyfunctional vinyl monomer forming a pre-polymer. Thereafter the process involves adding to the oil phase oil a water phase comprising a dispersion in water of an anionic emulsifier (and optionally initiator), and adding an emulsifying agent. Emulsifying the water phase into the oil phase (W/O) is controlled through the quantity of water employed.Type: GrantFiled: August 13, 2010Date of Patent: July 26, 2011Assignee: Appleton Papers Inc.Inventors: Todd Arlin Schwantes, Peggy Dorothy Sands
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Patent number: 7968510Abstract: The present invention relates to benefit agent containing delivery particles, compositions comprising said particles, and processes for making and using the aforementioned particles and compositions. When employed in compositions, for example, compositions for cleaning, fabric care, or coating onto various substrates, textiles or surfaces, such particles increase the efficiency of benefit agent delivery, thereby allowing reduced amounts of benefit agents to be employed. In addition to allowing the amount of benefit agent to be reduced, such particles allow a broad range of benefit agents to be employed.Type: GrantFiled: November 20, 2007Date of Patent: June 28, 2011Assignee: The Procter & Gamble CompanyInventors: Johan Smets, Peggy Dorothy Sands, Sandra Jacqueline Guinebretiere, An Pintens, Jiten Odhavij Dihora
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Publication number: 20110135851Abstract: The invention relates to polymer granules suitable as infill material for artificial turf structures wherein the granules have one or more hollow spaces, wherein each hollow space occupies at least 10% of the total volume of a polymer granule. The invention further relates to artificial turf structures comprising a backing sheet with an upper surface provided with fibres of a selected length, the fibres extending upwardly from the upper surface and an infill layer of hollow polymer granules or an e-layer comprising said hollow granules.Type: ApplicationFiled: March 26, 2009Publication date: June 9, 2011Applicant: SO.F.TER.-S.P.A.Inventors: Albertus Otto Dozeman, Gert Johan Joly, Bart Gerardus Christiaan Johannes Wijers
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Patent number: 7947370Abstract: The invention relates to microcapsules made of a core which contains at least one rubber additive and of a shell made of a first polymer. At least one coating made of a second polymer, which differs from the first polymer, and/or of a low molecular inorganic or organic compound, is deposited on the surface of the microcapsules as sliding or wearing layer in order to reduce the static friction.Type: GrantFiled: September 4, 2003Date of Patent: May 24, 2011Assignee: Schill + Seilacher GmbHInventors: Monika Jobmann, Gerald Rafler, Jozef Sagala, Ingeborg Gross
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Patent number: 7943067Abstract: The present invention includes a method for preparing polymer hydrogel spherical particles on a nanometer scale (nanogels). The method includes encapsulating hydrogel-forming components into liposomes, diluting the large unilamellar liposomes suspension to prevent polymerization outside the liposomes, and polymerizing the encapsulated hydrogel-forming components. The lipid bilayer may be solubilized with detergent. The phospholipid and detergent molecules and their micelles may then be removed by dialysis. The resulting nanogels may then be dried by evaporation in a temperature gradient. Poly(acrylamide), poly(N-isopropylacrylamide), and poly(N-isopropylacrylamide-co-1-vinylimidazole) hydrogel particles with a diameter from 30 to 300 nm were detected and characterized by dynamic light scattering technique. The solvent, temperature, pH, and ionic sensitivities of the nanogels were studied.Type: GrantFiled: August 14, 2002Date of Patent: May 17, 2011Assignee: Polytechnic Institute of New York UniversityInventors: Sergey Kazakov, Marian Kaholek, Kalle Levon
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Patent number: 7938897Abstract: The present invention relates to microencapsulated compositions of isothiazolone derivatives and other water insoluble biocides or antifouling agents. In particular, the present invention relates to microencapsulated 4,5 dichloro 2 n-octyl-3(2H)-isothiazolone (DCOIT), useful in marine antifouling coatings and paints.Type: GrantFiled: April 1, 2009Date of Patent: May 10, 2011Assignee: Microtek Laboratories Inc.Inventors: Ronald Lee Hart, David Russell Virgallito, Dale Ellis Work
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Patent number: 7931967Abstract: The invention provides a thermally foamable microsphere having a structure with a foaming agent encapsulated in a shell formed of a polymer, wherein the shell contains an organosilicon compound, and a process for producing a thermally foamable microsphere having a structure with a foaming agent encapsulated in a shell formed of a polymer by suspension polymerization of a polymerizable mixture containing at least a foaming agent and a polymerizable monomer in an aqueous dispersion medium, wherein the polymerizable mixture is suspension polymerized in the presence of the organosilicon compound.Type: GrantFiled: June 10, 2002Date of Patent: April 26, 2011Assignee: Kureha CorporationInventors: Yasuhiro Tasaki, Genzo Asai, Yoshikatsu Satake
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Patent number: 7914714Abstract: The methods of the invention employ electrostatic atomization to form a compound droplet of at least two miscible fluids. The compound droplet comprises a core of a first fluid and a layer of a second fluid completely surrounding the core. The first fluid contains the agent to be encapsulated and the second fluid contains an encapsulating agent. The first and second liquids are miscible. The encapsulated droplets can contain a variety of materials including, but not limited to, polynucleotides such as DNA and RNA, proteins, bioactive agents or drugs, food, pesticides, herbicides, fragrances, antifoulants, dyes, oils, inks, cosmetics, catalysts, detergents, curing agents, flavors, fuels, metals, paints, photographic agents, biocides, pigments, plasticizers, propellants and the like and components thereof. The droplets can be encapsulated by a variety of materials, including, but not limited to, lipid bilayers and polymer shells.Type: GrantFiled: May 14, 2004Date of Patent: March 29, 2011Assignee: The Regents of the University of ColoradoInventors: Thomas J. Anchordoquy, Corinne Lengsfeld, Kelly Brinkley, Ryan Jones