Abstract: A process for forming certain aqueous polymeric dispersions including a first emulsion polymer having an average particle diameter of 150 to 3000 nanometers and a second emulsion polymer having an average particle diameter of 40 to 600 nanometers where at least the first emulsion polymer particles, when dry, contain at least one void is provided. Also provided are the aqueous polymeric dispersions made by the process and paper or paperboard coatings and paints including the aqueous polymeric dispersions.

Abstract: The invention relates to a method for producing defined layers or layer systems made of polymers or oligomers on any solid surface and with a controlled structure, according to which the layers are chemically deposited on the solid surface by means of live/controlled free-radical polymerization. Said method comprises the following steps: a) bonding the compounds of the general formula (a) A—L—I to the solid surface via the active group A where A represents an active group, I is the initiating group for ATRP polymerization and L is the binding link between A and I; b) carrying out live/controlled free-radical polymerization by reacting the initiator group I with monomers, macromonomers or mixtures able to undergo free-radical polymerization, which produces the polymer layer on the solid surface. The invention also relates to solid surfaces with oligomer or polymer layers and initiators for carrying out the method.

Abstract: The invention relates to a multi-stage method for producing gas-filled microcapsules. In one stage of the method, the substance that forms the coat is polymerized. The microcapsules are formed in a physically and/or temporally separate stage, by means of a structuring process. The polymerization is carried out with moderate stirring, while the microcapsules are structured in dispersing conditions.

Abstract: A process is provided for producing a polymeric layer having a desired image thereon or a three dimensional article comprising a number of such layers in which a layer of a liquid photocurable composition which comprises photo colorable particles is cured by light and selected areas thereof are irradiated with light of a different dose, thereby forming the desired image which composition comprises particles dispersed in it which are micro-capsules containing a photosensitive color changing composition within a barrier layer which is substantially impermeable to the components of the color changing composition or are solid particles comprising an immobilized photosensitive color changing composition. The process permits the use of the same initiating mechanism to cure the resin and to change the color of the particles.

Abstract: A process for forming microcapsules having substantially impermeable microcapsule walls comprising the steps of: forming an emulsion of an internal phase in a continuous aqueous phase, the internal phase including a photosensitive composition and a polyvalent isocyanate, the continuous aqueous phase including a sulfonated polystyrene, at least one of the internal phase or the continuous aqueous phase further including a hydrophilic polymer; and enwrapping particles of the internal phase in an amine-formaldehyde condensation product produced by in situ condensation of an amine and formaldehyde is disclosed.

Abstract: A method forms self-sustaining particles that comprise a hydrophobic (oleophilic) phase in particulate form, with no need for a rigid shell to encapsulate the phase, and usually with no shell present. The oleophilic phase contains a gelation agent, and preferably an organogelation agent. The particles may be stored alone or in a minor amount (e.g., less than 40% by volume) of water to assist their stability and act as a barrier against their coalescence. These water-separated compositions are not necessarily dispersions or suspensions, but may be merely particles in an aqueous storage environment. The particles have prolonged stability and can be readily, simply, and inexpensively formed. A simple method of manufacture comprises forming a solution of the ingredients (e.g., at least the oleophilic material and gelation agent) at a temperature above their gelation temperature, forming droplets or molten, or liquid or flowable particles of the solutions, and cooling the droplets to form the particulates.

Abstract: An abrasion resistant coated film including a polyester film coated with a highly crosslinkable melamine coating with a crosslinking density of greater than about 50% and less than about 100%, wherein the coating is cured after transverse stretching and heat setting the film, a melamine coating having a crosslinking density between about 50% and about 100% containing between about 0.01% by weight and about 1.0% by weight of a colloidal particle selected from the group consisting of silica, TiO2, graphite and blends thereof, and a method of producing an abrasion resistant coated film including stretching a polyester film in the machine direction to form a uniaxially oriented film, applying a coating of highly crosslinkable melamine with a crosslinking density between about 50% and about 100% onto the uniaxially oriented film, heating and stretching the coated film in the transverse direction and curing the coating on the coated film.

Abstract: Multicomponent superabsorbent gel particles are disclosed. The multicomponent particles comprise at least one acidic water-absorbing resin and at least one basic water-absorbing resin. Each particle contains at least one microdomain of the acidic resin covalently bound to at least one microdomain of the basic resin via an interfacial crosslinking agent. Blends of multicomponent superabsorbent gel particles with particles of a second water-absorbing resin, and improved diaper cores containing particles of the multicomponent superabsorbent gel particles also are disclosed.

Abstract: A novel adhesive formed in situ in a microcapsule and method for forming such a pressure sensitive or flowable adhesive in situ in a microcapsule is disclosed. The method for forming the novel adhesive comprises providing an aqueous mixture of wall material in water; adding a substantially water insoluble core material, free radical initiator, and a solvent for the pre-polymers to the aqueous mixture. The core material comprises a first addition polymerizable pre-polymer having a Tg of less than about 0° C., a flash point of at least 75° C., and a boiling point of at least 175° C. These are typically selected from acrylate or methacrylate type materials. Optionally included is a second addition polymerizable pre-polymer for providing cross-linking or interaction between polymer chains. High shear agitation is provided to the aqueous mixture to achieve a particle size of about 0.1 to 250 microns.

Abstract: A first heat-sensitive microcapsule of the present invention comprises a shell wall and a liquid coloring composition, and has such a temperature-breaking characteristic that the shell wall is broken by heating to a temperature equal to or higher than a boiling point of the liquid coloring composition. The first heat-sensitive microcapsule is stable to light and easy to handle. A second heat-sensitive microcapsule of the present invention comprises a shell wall, a coloring composition and a heat decomposition-type gas-developing agent, and has such a temperature-breaking characteristic that the shell wall is broken by heating to a temperature equal to or higher than a decomposition temperature of the gas-developing agent. The second heat-sensitive microcapsule can be sensitively broken even by heating in a short time.

Abstract: What is described is a polymeric hydrogel product of a stable, aqueous polymeric composition which composition forms a clear to translucent film upon application to a substrate, and includes, by weight, 5-75% of (a) a water-soluble polymer having (b) in situ-formed, substantially water-insoluble resinous particles of said polymer substantially uniformly dispersed therein, and (c) 25-95% of water, made by irradiating the composition with high energy electron beam or gamma-radiation.

Abstract: Crosslinked fine particles having a Tg of 100° C. or higher and an amount of remaining double bonds of 0.01 mmol/g or more, which are obtainable by polymerizing a compound (a1) having one or two radical-polymerizable ethylenic unsaturated groups in the molecule and a compound (a2) having three or more (meth)acryloyl groups in the molecule.

Abstract: The present invention relates to a coating for an optical fiber. The coating includes a monomer. The monomer includes an oxyglycidyl (meth)acrylate component. A coating with the monomeric component has exhibited an excellent polymerization rate. The present invention also relates to methods of making such optical fibers coated in accordance with the invention and the coated glass article.

Abstract: High concentration drag reducing agents may be prepared by microencapsulating and/or macroencapsulating polymer drag reducing agent. The encapsulation may be performed prior to, during, or after the polymerization of monomer into effective drag reducing polymer. If encapsulation is done before or during polymerization, a catalyst may be present, but little or no solvent is required. The result is very small scale bulk polymerization within the capsule. The inert capsule or shell may be removed before, during or after introduction of the encapsulated drag reducer into a flowing liquid. No injection probes or other special equipment is expected to be required to introduce the drag reducing slurry into the liquid stream, nor is grinding (cryogenic or otherwise) of the polymer necessary to form a suitable drag reducing agent.

Abstract: A one-part curable epoxy adhesive composition is provided. The adhesive comprises curable epoxy resin, a latent curative system comprising (a) at least one first curative encapsulated in thermoplastic polymeric microcapsules and (b) a second latent curative admixed in the curable epoxy resin, and sufficient particulate thermoplastic polymeric material to at least partially regionally plasticize the cured epoxy resin wherein up to all of the particulate thermoplastic polymeric material may be provided by the walls of the microcapsules. A method of curing the adhesive by heating the composition is also provided. A joint made by adhering members together with the adhesive composition and a method of making the joint are also provided.

Abstract: A method of forming, by polymerization in an aqueous dispersion at pressures in excess of one atmosphere, a plurality of porous particles having at least one polymeric phase and at least one pore filling phase, wherein the pore filling phase includes a pore filler and a fugitive substance, is disclosed. Replacement of the fugitive substance with a replacement gas is further disclosed. Porous particles having a polymeric phase and pores containing a pore filler, and, optionally, a gaseous phase are also disclosed, as are their aqueous dispersions.

Abstract: A particle resistant to storage of at least one first and at least one second component, wherein said second component of at least one crosslinkable polymer as a shell at least partially envelops and/or encloses said first component as a core and said first component has at least one ascertainable property, obtainable by reacting said first component with the crosslinkable polymer and subsequently reacting the formed product with a crosslinking agent such that the first component with resistance to storage remains within the second component.

Abstract: A particle resistant to storage of at least one first and at least one second component, wherein

Abstract: A microencapsulated adhesive and a method for producing that microencapsulated adhesive is disclosed. The adhesive is produced from an alkyl acrylate or methacrylate monomer having about 4 to about 12 carbon atoms, or a mixture thereof. The monomer is encapsulated by interfacial polymerization, gelatin/gum arabic coacervation or melamine/formaldehyde encapsulation. The microcapsules may be polyamide or polyurea. The monomer is polymerized in the microcapsules by heating to form an adhesive that is non-tacky, but becomes tacky upon application of external forces, such as shearing. The microencapsulated adhesive composition may be used, among other applications, as an adhesive for stamps or envelopes.

Abstract: Described are compositions comprising core/shell particles and fluoropolymer, wherein the core comprises an ultraviolet absorber, as well as multiphase polymeric compositions comprising a polymeric core phase and a polymeric shelf phase, wherein the polymeric core phase comprises an ultraviolet absorber.

Abstract: A microbead comprising at least one thermoplastic polymers having distributed one or more compounds which are pigment precursors, the melting temperature of the lowest-melting polymer of the microbead being at least higher than the lowest temperature required to transform all pigment precursors in the microbead into the respective pigments.

Abstract: Described are compositions comprising core/shell particles and fluoropolymer, wherein the core comprises an ultraviolet absorber, as well as multiphase polymeric compositions comprising a polymeric core phase and a polymeric shell phase, wherein the polymeric core phase comprises an ultraviolet absorber.

Abstract: A heat-expandable microcapsule comprising a polymer shell formed by polymerizing (I) acrylonitrile, a main monomer component, (II) a monomer having carboxyl and (III) a monomer having groups reactive with the carboxyl of the monomer (II) and of a liquid having a boiling point lower than the softening point of the polymer and being encapsulated in the polymer shell. The heat-expandable microcapsules expand within high temperature range, 240° C. or above, and have heat-resistance.

Abstract: The invention is an encapsulated active agent comprising an active agent encapsulated in a crystallizable or thermoplastic polymer wherein the particle size of the encapsulated active agent is 3,000 microns or less wherein the active agent is not significantly extractable from the particles under ambient conditions. In another embodiment the invention is a process for preparing an encapsulated agent which comprises a) contacting an active agent with a crystallizable or thermoplastic polymer wherein the polymer is molten and the active agent in not volatile under the contacting conditions; b) forming particles of about 3000 microns or less; and c) exposing the particles to conditions such that the portion of the particle at and near the surface undergoes rapid solidification. The encapsulated active agents of the invention do not require washing in order for them to be stable in curable compositions. These encapsulated active agents can be designed to release the active agent at a desired temperature.

Abstract: This invention relates to suspension polymers having high swellability have low contents of soluble fractions prepared using aliphatic peroxyesters as polymerization initiators.

Abstract: Used as latent heat storage media of microcapsules I comprising as core materials one or more lipophilic substances whose solid/liquid phase transition is within the range from −20 to 120° C. and as shell a polymer obtainable by free-radical polymerization of a monomer mixture comprising from 30 to 100% by weight, based on the overall weight of the monomers, of one or more C1-C24-alkyl esters of acrylic and/or methacrylic acid (monomer I), from 0 to 80% by weight, based on the overall weight of the monomers, of a bi- or polyfunctional monomer (monomers II) which is insoluble or of low solubility in water, and from 0 to 40% by weight, based on the overall weight of the monomers, of other monomers (monomers III), and also novel microcapsules Ia, spray-dried microcapsules Ia′, processes for their preparation and shaped articles and coating compositions comprising these microcapsules.