Abstract: A fast hardening clear coating composition for repairing a clearcoat/colorcoat finish of a vehicle, which composition is capable of being wet sanded, buffed or polished to a high gloss finish on the same day of application, comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl component comprising a hydroxyl-containing acrylic polymer and a hydroxyl-terminated polyester oligomer, and an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate, where the composition further contains, as a combined curing catalyst, at least one dialkyl tin aliphatic carboxylate, at least one tertiary aliphatic mono or diamine, and at least one aliphatic carboxylic acid, in an effective amount such that the clear coating composition on curing at ambient temperatures is in a water spot free and sufficiently hard state for sanding or buffing within about 4 hours after application or on cool down when baked under normal cond

Abstract: A fast hardening clear coating composition for repairing a clearcoat/colorcoat finish of a vehicle, which composition is capable of being wet sanded, buffed or polished to a high gloss finish on the same day of application, comprising a film forming binder and an organic liquid carrier, where the binder contains a hydroxyl component comprising a hydroxyl-containing acrylic polymer and a hydroxyl-terminated polyester oligomer, and an organic polyisocyanate crosslinking component, at least portion of which comprises a trimer of isophorone diisocyanate, where the composition further contains, as a combined curing catalyst, at least one dialkyl tin aliphatic carboxylate, at least one tertiary aliphatic mono or diamine, and at least one aliphatic carboxylic acid, in an effective amount such that the clear coating composition on curing at ambient temperatures is in a water spot free and sufficiently hard state for sanding or buffing within about 4 hours after application or on cool down when baked under normal cond

Abstract: The present invention relates to articles having a printed surface as well as flexible coating and film compositions that are printable in combination with exhibiting stain resistance. The composition comprises a hard component having an elongation of less than about 150%, a soft component having an elongation of greater than about 200%, and a cross-linking agent. The hard component preferably comprises a thermoplastic polyurethane, acrylic polymer, polymeric polyol or mixture thereof. The soft component preferably comprises a thermoplastic urethane, polymeric polyol, or mixture thereof; whereas the cross-linking agent is preferably an isocyanate.

Abstract: An article including a panel-like structure mountable in an automobile vehicle to form a part of the interior thereof, and a process for making the same are disclosed. According to this process, an outer layer defining at least a portion of the exposed exterior surface of the structure is prepared by applying a water-dispersed composition containing a thermoplastic polyurethane and a heat-activated crosslinking agent onto a mold surface and thereafter drying the composition. Next, a composition comprising (i) a poly(vinyl chloride) resin and at least one plasticizer and/or (ii) a thermoplastic polyurethane resin material is gelled onto an inner surface of the outer layer while on the outer layer is retained on the mold surface. The gelled composition is then fused to form an inner layer interfacially chemically bonded to the outer layer. The inner layer with the outer layer chemically bonded thereto is united with the rigid substrate so that the rigid substrate serves to reinforce the outer layer.

Abstract: Integrally bonded composite polyurethane foams substantially free from coalescence and with no discernable bond or structural interface layer when viewed at 50× magnification can be formed by wet casting a second foamed polyurethane composition onto a first wet cast foamed polyurethane composition and simultaneously curing the cast foams. In a preferred embodiment, one curable polyurethane composition forms a slow recovery foam and the other curable polyurethane composition forms a resilient foam.

Abstract: An apparatus and method to produce radiopaque medical implants such as catheters, stents, or other implants. A composition of a radiopaque brominated polyurethane coat and a polyurethane tubing core is formed. In one embodiment, the polyurethane coat includes a diisocyanate and a brominated diol having a bromine concentration of 30% or more. The coat is applied to the elastomeric polyurethane tubing core surface. The medical implant takes advantage of employing a brominated radiopaque polyurethane with the tensile properties, for example of flexibility and kink resistance, of the elastomeric thermoplastic polyurethane tubing core without degrading these desirable characteristics.

Abstract: A shoe sole structure includes at least two kinds of PU material and waste chips and a foaming agent are evenly mixed with the two kinds of PU material. The mixture is foamed and formed to be desired shapes.

Abstract: A composite structure including a polyurea show surface, or top layer, and a polyurethane backing layer is disclosed. Preferably, the show surface of the composite structure is substantially free of volatile organic compounds and is aliphatic such that it is ultraviolet light stable. Specifically, the show surface is the reaction product of an aliphatic polyisocyanate or aliphatic polyisocyanate blend, and of a resin component which is a polyamine. The resin component reacts with the aliphatic polyisocyanate to form a polyurea. The show surface has a Shore D hardness of 70. Like the show surface, the polyurethane backing layer of the composite structure is substantially free of volatile organic compounds. This backing layer is the reaction product of a second polyisocyanate component, such as polymeric diphenylmethane diisocyanate, and of a second-layer resin component, which comprises a polyol having a functionality of at least three.

Abstract: The present invention relates to a functional urethane resin film formed from a water based urethane resin dispersion (A), showing practically no stickiness per se, anti having a tensile elongation at breakage of 50 to 1000%; and a laminated film by use of the resin film.

Abstract: A multi-layered article comprising a first layer of a thermoset polyurethane. A second layer of a polymeric composition is bonded to the first layer. The polyurethane has available isocyanate groups prior to the application of the second layer. The second layer is applied onto the first layer in a pre-polymeric or polymeric state wherein the material has carboxyl groups and a cross-linking agent.

Abstract: Herein is disclosed an oxygen scavenging composition, comprising (i) an oxygen scavenging polymer comprising units having structure I: wherein R1 and R2 are independently selected from the group consisting of —O—, —NCO—, and —NR—, wherein R is selected from the group consisting of —H and —C1-C6 alkyls; (ii) a transition metal oxidation catalyst; and (iii) an energy-absorbing compound selected from the group consisting of microwave reactive materials and photoinitiators having a wavelength of maximum absorption of electromagnetic radiation from about 200 nm to about 750 nm. The oxygen scavenging composition can be used to form an oxygen scavenging packaging article.

Abstract: A method and process for treating wood. The steps include preparing isocyanate-based reactive prepolymer resins for impregnation, impregnating wood with these impregnation resins, curing the impregnated wood at elevated temperatures, preparing isocyanate resin-based coating materials and applying these coating materials on the cured impregnated wood and curing the coatings at room or elevated temperatures. The resulting treated wood has substantially improved de-contaminability of the chemical warfare agent VX both initially and after long exposure to degradation effects from sunlight.

Abstract: The present invention relates to membranes including a barrier layer which includes a blend of one or more aliphatic thermoplastic urethanes and one or more polar and partially crystalline materials. Under multi-layered embodiments, the barrier layer is laminated to at least one other layer formed from thermoplastic urethane, wherein the membranes are characterized in that hydrogen bonds are formed between the first layer of thermoplastic urethane and the second layer from the blend of aliphatic thermoplastic urethane and a copolymer of ethylene and vinyl alcohol.

Abstract: The present invention relates to shape deformable materials, which are capable of (1) being deformed, (2) storing an amount of shape deformation, and (3) recovering at least a portion of the shape deformation when exposed to a humid environment. The shape deformable materials can advantageously be in the form of films, fibers, filaments, strands, nonwovens, and pre-molded elements. The shape deformable materials of the present invention may be used to form products, which are both disposable and reusable. More specifically, the shape deformable materials of the present invention may be used to produce products such as disposable diapers, training pants, incontinence products, and feminine care products.

Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one fluid barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.

Abstract: A multi-component composite coating composition is provided which includes a basecoat deposited from an aqueous basecoat film-forming composition and a transparent topcoat applied over the basecoat. The basecoat film-forming composition includes at least one crosslinkable film-forming resin and at least one amphiphilic alcohol having the structural formula: HO—R, wherein R includes a linear hydrocarbon segment having at least seven contiguous carbon atoms. The amphiphilic alcohol is present in an amount ranging from about 0.01 to about 50 weight percent based upon total amount of resin solids of the basecoat film-forming composition. A coated substrate is also provided.

Abstract: An acrylic-free, waterborne coating composition is disclosed. The waterborne coating composition produces a waterborne paint film having improved chip resistance on a substrate. The waterborne coating composition comprises an aqueous polyurethane dispersion substantially free from co-solvents. The polyurethane dispersion has a glass transition temperature from 0° C. or less and at least one carboxyl group. The waterborne coating composition also includes a melamine reactive with the carboxyl group. The aqueous polyurethane dispersion and the water-soluble cross-linker form a binder component of the waterborne coating composition. The binder component includes from 60 to 90% by weight of the aqueous polyurethane dispersion based on 100% by weight of the binder component and from 10 to 40% by weight of the water-soluble cross-linker based on 100% by weight of the binder component. The waterborne coating composition is applied having a film build of 0.5 to 5.0 mils and produces a paint film loss of from 0.

Abstract: The invention provides low temperature thermally activatable water-dispersed adhesive compositions and adhesives made from the compositions by removing water. The adhesive compositions of the invention comprise a mixture of low modulus crystallizing polyester polyurethane, acrylic ester copolymer, one or more hydrophobically-modified associative polyurethanes, and a stabilizer system comprising a combination of carbodiimide and branched primary amino alcohol.

Abstract: Described are photochromic organic resin compositions and the impact resistant polymerizates and coating compositions made therefrom. The organic resin composition comprises the reaction product of at least one polyol having greater than 1.0 hydroxyl groups; at least one polyisocyanate having greater than 1.0 isocyanato groups; and at least one polyamine curing agent having greater than 1.0 amino groups. The polymerizates are made photochromic either by the addition of organic photochromic compounds to the reactants used to form the polymerizate or by methods that imbibe or transfer the photochromic compounds into the polymerizate. Optically clear photochromic and impact resistant articles such as ophthalmic lenses and articles having photochromic coatings prepared from the photochromic organic resin compositions are also described.

Abstract: To provide a transparent resin which is suitable in the process of producing a coating for electronic materials, a glass having both of the scattering-preventing function and the antireflective function, an adhesive agent, a shock-absorbing material, an ultraviolet-cutting sheet for televisions, a filter for VDTs and a high refractive index primer composition as well as the process for the production of primer-coated lenses using said primer composition, is excellent in a coatability, adhesive property, storage stability, durability, shock resistance and the like, and is particularly excellent in a transparency and adhesive property after curing of the same. A transparent resin having an adhesive property characterized by comprising a cured product of the polymerizing composition which comprises at least one of diallyl phthalate, diallyl isophthalate and diallyl terephthalate, and pentaerythritol tetra(3-mercaptopropionate).

Abstract: A multilayer film is described which has at least one first layer (1) of thermoplastic polyurethane, at least one second layer (2) of thermoplastic elastomer, and optionally a third layer (3) of thermoplastic polyurethane. The ratio of the water vapor permeability level of the first layer (1) to the water vapor permeability level of the second layer (2), of the multilayer film is at least two. When the optional third layer (3) is present in the multilayer film, the first and third layers enclose the second layer. Also described are filled articles (e.g., water beds and hot/cold pads), which are fabricated from the multilayer films of the present invention.

Abstract: An acrylic-free, waterborne coating composition is disclosed. The waterborne coating composition produces a waterborne paint film having improved chip resistance on a substrate. The waterborne coating composition comprises an aqueous polyurethane dispersion substantially free from co-solvents. The polyurethane dispersion has a glass transition temperature from 0° C. or less and at least one carboxyl group. The waterborne coating composition also includes a melamine reactive with the carboxyl group. The aqueous polyurethane dispersion and the water-soluble cross-linker form a binder component of the waterborne coating composition. The binder component includes from 60 to 90% by weight of the aqueous polyurethane dispersion based on 100% by weight of the binder component and from 10 to 40% by weight of the water-soluble cross-linker based on 100% by weight of the binder component. The waterborne coating composition is applied having a film build of 0.5 to 5.0 mils and produces a paint film loss of from 0.

Abstract: A method and process for treating wood. The steps include preparing isocyanate-based reactive prepolymer resins for impregnation, impregnating wood with these impregnation resins, curing the impregnated wood at elevated temperatures, preparing isocyanate resin-based coating materials and applying these coating materials on the cured impregnated wood and curing the coatings at room or elevated temperatures.

Abstract: Improvements for in-mold polyurethane foam and/or resin products and the ability to provide surface coatings of such products exhibiting bright coloration and reduced colorant migration through utilization of easy-to-use polymeric colorants in simplified and environmentally friendly processing methods are disclosed. The inventive surface coating formulations include polyurethane-reactive polymeric colorants admixed with prepolymer and excess amounts of certain isocyanate compounds. Such a composition is applied (by spraying, for example) to a polyurethane prepolymer (for the production of the internal polyurethane article) which is then introduced within a mold in order to form a particularly shaped or configured polyurethane article with a colored surface coating. Upon curing through exposure to heat, the coating composition reacts with the introduced polyurethane prepolymer to form a surface over the target internal polyurethane.

Abstract: A multi-layered protective finish for use on hardwood surfaces includes ceramic additives in selected layers. The finish is comprised of multiple sealant layers (preferably epoxy) and top coat layers (preferably polyurethane), some of which contain ceramic components, namely, aluminum oxide and zirconium oxide. The multi-layered, ceramic-based finish exhibits enhanced abrasion and stain resistance. The required concentrations of zirconium oxide provide enhanced hardness without sufficiently compromising flexibility which is important to maintain integrity of the finish.

Abstract: A polycarbonate composition featuring improved adhesion to polyurethane, preferably polyurethane foam is disclosed. The composition contains (A) an aromatic polycarbonate and/or polyester-carbonate, (B) a graft polymer and (C) a copolymer of styrene and a monomer containing carboxyl groups, the copolymer having a weight average molecular weight Mw of >10,500 g/mol. Composite materials containing layers of the inventive composition and polyurethane layer, preferably foam, are also disclosed.

Abstract: The invention provides a method of obtaining improvements in the appearance of articles having both vertically and horizontally orientated surfaces and a coating composition for use in said method. The coating composition of the invention has a film-forming component (a) and a rheology control agent (b) having substantially colorless, substantially inorganic microparticles (i) and a compound (ii) comprising the reaction product of an amine and an isocyanate. A particularly preferred method of the invention requires applying the coating composition of the invention to an article having at least one horizontally orientated surface and at least one vertically orientated surface so as to provide a coated horizontally orientated surface and a coated vertically orientated surface, wherein the coated vertically orientated surface has improved sag resistance, most preferably having a sag resistance of at least 1.2 mils.

Abstract: A resin-impregnated endless belt for a long nip press or calender of the shoe type, or for other papermaking and paper-processing applications, has a base support structure which includes coated elements, such as yarns, having a coating of a first polymeric resin material. The base support structure is in the form of an endless loop, at least one of the inner and outer surfaces of which is coated with a second polymeric resin material. The second polymeric resin material impregnates the structure of the base support structure, rendering it impermeable to oil and water. The first and second polymeric resin materials have an affinity for one another, so that the coating of second polymeric resin material on the base support structure as a whole establishes a chemical, as well as a mechanical, interlock with the coated yarns having the coating of first polymeric resin material.

Abstract: A multi-layered article comprising a first layer of a thermoset polyurethane. A second layer of a polymeric composition is bonded to the first layer. The polyurethane has available isocyanate groups prior to the application of the second layer. The second layer is applied onto the first layer in a pre-polymeric or polymeric state wherein the material has carboxyl groups and a cross-linking agent.

Abstract: A photochromic lens consists of a lens coated with an elastomeric film having a photochromic dye dispersed therein. The elastomeric provides abrasion resistance and some impact resistance to the lens. The photochromic lens is characterized by lower spectral transmission when activated, and shorter activation and deactivation times than previously known photochromic lenses. A method for making the photochromic lens consists of dissolving one or more photochromic dyes in an elastomeric pre-polymer solution, immersing the lens in the solution so that the lens becomes coated with the prepolymer solution, and treating the lens, for example, by heating, to cause said prepolymer to form an elastomeric film on the lens. Preferably, the pre-polymer solution is a polyurethane pre-polymer.

Abstract: A sprayable polymeric material and a process for preparing the material which contains a fibrous material, dispersed throughout the polymeric material. A restriction free spray nozzle is provided for mixing and spraying the polymeric material having a fibrous material, the nozzle having a restriction free check valve. A reinforced structure, and a method of making the structure are provided, the structure having layers of the polymeric material (both film and foam) containing the fibrous material. A flexible liner is provided of a porous geotextile fabric and a polyurethane composition comprising the fibrous material sprayed over the geotextile fabric.

Abstract: A multilayer composite comprising at least the following layers: I. a layer I of a polyamide molding composition and II. a layer II of a polyester molding composition, where the layers are firmly bonded to each other without use of an additional layer of bonding agent, wherein the polyester molding composition comprises a mixture of: a) from 80-99% by weight of a polyalkylene 2,6-naphthalate selected from the group consisting of polyethylene 2,6-naphthalate and polybutylene 2,6-naphthalate, and b) from 1-20% by weight of one or more compounds containing at least two isocyanate groups, wherein, in addition, the isocyanate groups from component IIb are present in layer II in a concentration of from 0.03-3% by weight.

Abstract: A thermoformable polyurethane foam having excellent compression set resistance, and a thermoformable polyurethane foam having excellent compression set resistance and shape retention under load. In another embodiment, at least one additional layer of a polyurethane foam is integrally bonded to the thermoformable foam. A moisture management system for polyurethane foams is also described. The foams have particular utility as shoe sole inserts.

Abstract: A laminate comprising a printed layer, a transparent thermoplastic polyurethane layer and a layer forming a substrate of a thermoplastic material is disclosed. The laminate that is characterized in that the printed layer is interposed between the layer forming a substrate and the polyurethane layer is suitable for the preparation of a variety of articles.

Abstract: In order to obtain a charging member which is free of problems such as bleeding of a conductive agent and environment dependency, has little voltage dependency, and can be preferably used in a charging system of impressing only a DC voltage, there is provided a charging member comprising an elastic layer, a resistance regulation layer provided on the elastic layer, and a skin layer provided on the resistance regulation layer, wherein the resistance regulation layer is formed by use of a resin composition prepared by blending an ion conductive substance having a molecular weight of 30 to 800 as a conductive agent into a low-resistance resin matrix having a resistance of 1×104 to 1×1010 &OHgr;·cm.

Abstract: A plastic lens having a primer layer made from a polyurethane resin obtained through a reaction between a polyester polyol containing isophthalic acid as a main component and a polyisocyanate. A plastic lens having excellent resistance to scratch and impact resistance can be obtained by further forming a hard-coat layer and an anti-reflection layer on the primer layer.

Abstract: A polyurethane material, the coatings prepared therefrom, and methods of making the same are provided. A polyurethane material may be formed from components comprising at least one polyisocyanate, at least one active hydrogen-containing material, at least one material having at least one primary or secondary amino group and at least one hydroxyl group, and at least one acid functional material or anhydride having a functional group reactive with isocyanate or hydroxyl groups of other components from which the polyurethane material is formed. The polyurethane can provide improved physical properties, such as chip resistance, when incorporated into a coating composition.

Abstract: A colored coating for an article is provided including a first layer polymeric coating material with a transparent base which has been pigmented to a desired color and extruded, a second layer of transparent polymeric coating material which has been co-extruded with the first layer and a third layer of polymeric coating material co-extruded with the first layer opposite the second layer, the third layer being more opaque than the first layer. The invention, while having widespread application, is particularly suitable for use as a coating for an exterior surface of an automotive vehicle body panel.

Abstract: A metallized film comprises an opaque, continuous layer of metal on an aliphatic polyurethane substrate. The polyurethane substrate displays a glass transition temperature of about 25° to 110° C and a melting temperature greater than or equal to 200° C. Decorative articles can be made with the metallized film.

Abstract: A stimulable phosphor layer composed of a plurality of stimulable phosphor sublayers overlaid one upon another is overlaid upon a substrate. At least two adjacent stimulable phosphor sublayers are overlaid one upon the other such that a temporary substrate contact side surface of one of the two adjacent stimulable phosphor sublayers, which surface was in contact with a temporary substrate utilized when the one adjacent stimulable phosphor sublayer was formed, and a temporary substrate contact side surface of the other adjacent stimulable phosphor sublayer, which surface was in contact with a temporary substrate, stand facing each other. A top stimulable phosphor sublayer contains a polyurethane binder, which has a weight-average molecular weight falling within the range of 200,000 to 500,000, in a proportion falling within the range of 20% by weight to 90% by weight with respect to the total binder contained in the top stimulable phosphor sublayer.

Abstract: A method is provided of forming multilayer coating films having a high quality appearance while controlling interfacial bleeding or inversion between coating film layers otherwise found when a water-borne intermediate coating film and a water-borne metallic coating film are formed in that order.

Abstract: Compositions containing polyurethane dispersions and water reducible resins particularly suited for use as basecoats in low VOC basecoat/clearcoat vehicle coatings.

Abstract: A hydrophilic coating having a covalently cross-linked hydrophilic polymer suitable for coating medical devices or instruments for introduction into human cavities, the coating further having a water soluble compound, the water soluble compound being glucose, sorbitol, a halide, nitrate, acetate, citrate or benzoate of an alkali metal or alkaline earth metal or silver; acetic acid, glycine or urea. A medical device or instrument for introduction into human cavities having a hydrophilic coating and a method of producing such a medical device or instrument.

Abstract: A method is provided for manufacturing a painted plastic component having a badge, emblem or other ornamentation, such as air bag covers having a badge, or wherein the component is the badge itself. The method includes providing a painted film sheet and a one-piece thermoplastic elastomeric structural carrier. A bottom contact surface of the film sheet bonds with a front contact surface of the structural carrier by diffusion between the contact surfaces thereof within a mold cavity of an injection mold separate from the mold cavity of a vacuum mold which is utilized to vacuum-mold the film sheet to form the desired painted plastic component.

Abstract: A primer for the metallization of substrate surfaces by chemical reduction, comprising a) from about 3 to about 40% by weight of a film or matrix former, b) from about 0.1 to about 15% by weight of an additive having a molecular mass of 500 to 20,000, c) from about 0.1to about 15% by weight of an ionic and/or colloidal metal or its organometallic covalent compound or complex compound with organic ligands, d) from about 0.5 to about 30% by weight of an organic and/or inorganic filler, e) from about 0.05 to about 5% by weight of a hydrophilic swelling material comprising finely divided particles containing silanol groups and/or partly modified silanol groups having a diameter of from 7 to 40 nm and a specific surface area of 50 to 380 m2/g, and f) from about 50 to about 90% by weight of organic solvents, in which all amounts by weight being based on the overall primer formulation, offers advantages at low bath loadings.

Abstract: A compact veneer is based on a reaction mixture comprising

Abstract: A multi-component composite coating composition is provided which includes a pigmented base coat and a transparent topcoat composition applied over the base coat. The transparent topcoat is deposited from a substantially solvent free film-forming composition which includes a thermosettable dispersion of polymeric microparticles having functionality adapted to react with a crosslinking agent and a hydrophilic crosslinking agent reactive with the functionality of the microparticles. The microparticles are prepared from one or more reaction products of ethylenically unsaturated monomers, one or more hydrophobic polymers and one or more hydrophobic crosslinking agents. Pigmented film-forming compositions as well as curable compositions containing the above-described dispersions also are provided. A method of forming the dispersion of polymeric microparticles is provided.

Abstract: The invention relates to a pressure and vacuum deformable, grained bonding foil for linings of motor vehicle interiors with at least one support layer, a single or multi-layer bed of polyurethane, and also, if applicable, an adhesion facilitator layer, arranged in between, a primary layer and also additional conventional layers, whereby the layer of polyurethane has a Shore D Hardness of less than 50, specifically less than approximately 48. Subject of the invention is also a method for the manufacture of the bonding foil as well as its utilization for lining the interiors of motor vehicles. Said bonding foil demonstrates excellent manipulation properties and presents outstanding physical/mechanical properties, such as excellent breaking elongation, grain stability, scratch resistance, high resistance to wear and tear, high UV-resistance, excellent solvent resistance as well as very high thermal aging resistance.

Abstract: The present invention is directed to a barrier layer which has the ability to substantially prevent the diffusion of stains, such as plasticizers and dyes or other chemicals, onto a surface of a surface covering, from a surface or object in which the surface covering is placed upon. The barrier layer contains a polyamide or polyurethane and is preferably located above a substrate or base layer in a surface covering. The barrier layer preferably is located between a UV topcoat layer and a vinyl wear layer. The present invention also relates to a method of preventing stain migration onto a surface covering from a surface on which the surface covering is placed by use of the barrier layer of the present invention and also relates to methods of making surface coverings containing the barrier layer of the present invention.

Abstract: An intrusion resistant laminated glazing, suitable for automotive use, comprises an impact resistant ply of rigid thermoplastic polyurethane sensitive to ultra-violet radiation and, outside said ply, an ultra-violet absorbing or reflecting ply. The ultra-violet absorbing ply may be of thermoplastic polyurethane interlayer material which serves to bond the rigid thermoplastic polyurethane ply to outer glass plies. By using interlayer materials of low modulus to bond the rigid thermoplastic ply to outer glass plies, a product with good impact resistance and intrusion resistance is achieved.