Next To Acetal Of Polymerized Unsaturated Alcohol (e.g., Formal Butyral, Etc.) Patents (Class 428/437)
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Patent number: 8323797Abstract: A composite article comprises a first glass layer, a silicone layer, a second glass layer, and an organic layer. The silicone layer is disposed adjacent to the first glass layer. The silicone layer includes a cured silicone composition. The second glass layer is disposed adjacent to the silicone layer, spaced from and substantially parallel to the first glass layer. The organic layer is disposed adjacent to the second glass layer, spaced from and substantially parallel to the silicone layer. The organic layer includes a cured organic composition. A method of making a composite article including a first glass layer and a polymeric layer disposed adjacent to the first glass layer includes providing a dual-compartment chamber. The chamber includes a first compartment and a second compartment separated by a polymeric separator. The separator can be manipulated through pressure differentials between the compartments.Type: GrantFiled: February 21, 2008Date of Patent: December 4, 2012Assignee: Dow Corning CorporationInventors: Bizhong Zhu, Carl Allen Fairbank, Raymond Lee Tabler, Nathan P. Greer
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Publication number: 20120288722Abstract: The present invention provides an interlayer film for a laminated glass which can suppress bubble formation and bubble growth in the laminated glass, and an interlayer film for the laminated glass. An interlayer film for a laminated glass 1 includes a first layer 2, a second layer laminated on one face 2a of the first layer 2. Each of the first layer 3 and the second layer 3 contains a polyvinyl acetal resin and a plasticizer. The hydroxyl content of the polyvinyl acetal resin in the first layer 2 is lower than the hydroxyl content of the polyvinyl acetal resin in the second layer 3. The difference between the hydroxyl content of the polyvinyl acetal resin in the first layer 2 and the hydroxyl content of the polyvinyl acetal resin in the second layer 3 is at most 9.2 mol %. If the difference in the content is higher than 8.5 mol % and at most 9.2 mol %, a degree of acetylation of the polyvinyl acetal resin of the polyvinyl acetal resin in the first layer is at most 8 mol %.Type: ApplicationFiled: December 24, 2010Publication date: November 15, 2012Inventors: Tatsuya Iwamoto, Kohei Kani
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Patent number: 8304082Abstract: The present invention has its object to provide an interlayer film for a laminated glass, which is excellent in penetration resistance, moisture resistance, and sound insulation. The present invention relates to an interlayer film for a laminated glass, which comprises: a polyvinyl acetal resin; and a plasticizer, the plasticizer being represented by formula (1): wherein R1 represents a phenyl group, R2 represents an alkylene group having 2 to 4 carbon atoms, and n represents 4 to 6.Type: GrantFiled: July 16, 2009Date of Patent: November 6, 2012Assignee: Sekisui Chemical Co., Ltd.Inventors: Bungo Hatta, Takahiro Futamura, Minoru Inada, Hirofumi Kitano
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Publication number: 20120276374Abstract: The present invention relates to a laminated glass including a first glass substrate, a first adhesive layer, a heat reflective film, a second adhesive layer and a second glass substrate, laminated in this order, in which the heat reflective film includes a resin film having specific thermal shrinkages in a direction that a thermal shrinkage becomes maximum and in a direction orthogonal to the direction, and a heat reflective coating formed on the resin film; the first adhesive layer and the second adhesive layer include a polyvinyl butyral film having thermal shrinkages in a direction that a thermal shrinkage becomes maximum and in a direction orthogonal to the direction; and the direction that a thermal shrinkage becomes maximum, of the resin film and the direction that a thermal shrinkage becomes maximum, of the polyvinyl butyral film are orthogonal to each other.Type: ApplicationFiled: June 25, 2012Publication date: November 1, 2012Applicant: ASAHI GLASS COMPANY, LIMITEDInventor: Yuichi HINO
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Patent number: 8278379Abstract: The invention provides an interlayer film for a laminated glass and a laminated glass, which are protected against a slump in TL value through attenuation of said coincidence effect and adapted to display an outstanding sound insulation performance over a broad temperature range. An interlayer film for a laminated glass comprising a plasticizer and a polyacetal resin, which is a blend of a polyacetal resin having an average polymerization degree of 1,000 to 3,000 and a polyacetal resin having an average polymerization degree of 3,000 to 5,000, and which has an acetalization degree of 60 to 85 mol % and an acetyl group content of 8 to 30 mol %. An interlayer film for a laminated glass which shows a temperature dependence of loss tangent in which the lowest-temperature side maximum of loss tangent appears at 30° C. or lower when examined for dynamic viscoelasticity.Type: GrantFiled: September 16, 2011Date of Patent: October 2, 2012Assignee: Sekisui Chemical Co., Ltd.Inventors: Kiyofumi Toyama, Yoshio Aoshima, Chikao Shimizu
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Publication number: 20120244364Abstract: The present invention provides an interlayer film for a laminated glass which can suppress bubble formation and bubble growth in the laminated glass. An interlayer film 1 for a laminated glass includes a first layer 2 and a second layer 3 laminated on one face 2a of the first layer 2. Each of the first layer 2 and the second layer 3 contains a polyvinyl acetal resin and a plasticizer. In the case of measuring viscoelasticity of a resin film (glass transition temperature: Tg (° C.)) formed from the first layer 2 or a resin film (glass transition temperature: Tg (° C.)) formed with 100 parts by weight of the polyvinyl acetal resin contained in the first layer 2 and 60 parts by weight of a plasticizer of triethylene glycol di-2-ethylhexanoate (3GO) , the resin film has an elastic modulus of G?(Tg+80) at (Tg+80)° C. and an elastic modulus of G?(Tg+30) at (Tg+30)° C., and provides a ratio (G?(Tg+80)/G?(Tg+30)) of 0.65 or higher.Type: ApplicationFiled: December 28, 2010Publication date: September 27, 2012Inventors: Tatsuya Iwamoto, Kohei Kani
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Patent number: 8268445Abstract: A composite article comprises a first glass layer, a silicone layer, a second glass layer, and an organic layer. The silicone layer is disposed adjacent to the first glass layer. The silicone layer includes a cured silicone composition. The second glass layer is disposed adjacent to the silicone layer, spaced from and substantially parallel to the first glass layer. The organic layer is disposed adjacent to the second glass layer, spaced from and substantially parallel to the silicone layer. The organic layer includes a cured organic composition. A method of making a composite article including a first glass layer and a polymeric layer disposed adjacent to the first glass layer includes providing a dual-compartment chamber. The chamber includes a first compartment and a second compartment separated by a polymeric separator. The separator can be manipulated through pressure differentials between the compartments.Type: GrantFiled: February 21, 2008Date of Patent: September 18, 2012Assignee: Dow Corning CorporationInventors: Bizhong Zhu, Carl Allen Fairbank, Raymond Lee Tabler, Nathan P. Greer
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Patent number: 8263208Abstract: The invention relates to a plastic film, at least one side of which is provided with a surface structure comprising parallel rows of elevations (a). Said elevations (a) are interconnected by means of webs (b) that are at least 10 percent lower than the elevations (a). The inventive films can be used for producing laminated glass.Type: GrantFiled: July 9, 2007Date of Patent: September 11, 2012Assignee: Kuraray Europe GmbHInventor: Holger Stenzel
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Publication number: 20120202070Abstract: It is an object of the invention to provide a plasticized polyvinyl acetal composition that is suitably used for an intermediate film of a laminated glass and other applications, specifically, the polyvinyl acetal composition being characterized in that in cases when a layer that is composed of the polyvinyl acetal composition and another resin layer such as a resin layer of a polycarbonate, a poly(meth)acrylic acid ester, or a styrene thermoplastic elastomer are laminated, the plasticizer does not migrate from the polyvinyl acetal layer. The present invention relates to a polyvinyl acetal composition including 100 parts by mass of a polyvinyl acetal and 0.5 to 100 parts by mass of an ester plasticizer or ether plasticizer that is amorphous or has a melting point of 30° C. or less, and has a hydroxyl value of 15 to 450 mgKOH/g.Type: ApplicationFiled: August 4, 2010Publication date: August 9, 2012Applicant: KURARAY CO., LTD.Inventors: Yoshiaki Asanuma, Koichiro Isoue
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Patent number: 8227079Abstract: A laminated vehicle glazing, suitable for use with an optical sensor (for example a LIDAR type sensor), comprises first and second plies of glazing material joined together by a ply of interlayer material between them, and either: a) the first ply is a pane of body-tinted glass having a colorant portion consisting of 0.70 to 1.00% by weight total iron (calculated as Fe2O3), 0 to 1.0% titania and 0 to 2.0% ceria, such that the glazing has a transmittance of at least 30% in the wavelength range 400 to 2100 nm, or b) the first ply of glazing material is a pane of body-tinted glass having a colorant portion consisting of 0.30 to 0.80 by weight total iron (calculated as Fe2O3), 0 to 1.0% titania (calculated as TiO2) and 0 to 2.0% ceria (calculated as CeO2), and the ply of interlayer material is a solar (IR) absorbing material, such that the glazing has a transmittance of at least 30% in the wavelength range 750 to 1300 nm.Type: GrantFiled: June 5, 2008Date of Patent: July 24, 2012Assignee: Pilkington Group LimitedInventors: Ashley Carl Torr, Neil Barton
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Patent number: 8221535Abstract: A dispersion of tin-doped indium oxide fine particles has tin-doped indium oxide fine particles, a plasticizer for an interlayer film, an organic solvent containing alcohols as a main component, and a dispersion stabilizer, wherein under measuring conditions of a concentration of tin-doped indium oxide fine particles of 0.7% by weight and an optical path length of a glass cell of 1 mm, a visible light transmittance is 80% or more, a solar radiation transmittance at a wavelength within a range from 300 nm to 2100 nm is ¾ or less of the visible light transmittance, a haze value is 1.0% or less, and a reflection yellow index is ?20 or more.Type: GrantFiled: June 11, 2004Date of Patent: July 17, 2012Assignees: Mitsubishi Materials Corporation, Jemco Inc., Sekisui Chemical Co., Ltd.Inventors: Masahiro Hagiwara, Takeshi Nakagawa, Juichi Fukatani, Tadahiko Yoshioka, Bungo Hatta
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Patent number: 8216683Abstract: The present invention includes polymer interlayers that are used in multiple layer glazing panels. Interlayers of the present invention comprise a thermoplastic polymer, a plasticizer, a tungsten oxide agent, and a stabilizing agent that prevents the degradation of the tungsten oxide agent. Interlayers incorporating such components have improved ultraviolet light blocking character, and also maintain optical quality over time.Type: GrantFiled: August 3, 2007Date of Patent: July 10, 2012Assignee: Solutia Inc.Inventor: William Keith Fisher
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Patent number: 8178206Abstract: Provided is a solar control composition comprising an infrared absorbing phthalocyanine compound or naphthalocyanine compound and a resin having a modulus from 20,000 psi (138 MPa) to 1000 psi (7 MPa) and solar control laminates comprising the solar control composition of the invention.Type: GrantFiled: December 22, 2009Date of Patent: May 15, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Richard Allan Hayes, Richard A. Fugiel, Thomas R. Phillips, Lee A. Silverman, Jason S. Wall
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Patent number: 8142894Abstract: A laminated glass (10) has a structure in which seven sheet glasses (20) and six PVB resin layers (30) are laminated alternately. A laminated region from a transparent surface (10a) on one side to 4.0 mm comprises two 0.7 mm-thick glass layers formed of two sheet glasses (20), one 0.8 mm-thick glass layer formed of the portion (20c) of one 1.5 mm-thick sheet glass (20) positioned in the laminated region, and two adhesion layers (30) with thicknesses of 1.3 mm and 0.5 mm. Each of the adhesion layers is interposed between the glass layers and is adhered to the glass layers. The laminated region with a depth of 4.0 mm from a transparent surface (10b) on the other side also has the same laminated structure as that in the above laminated region.Type: GrantFiled: September 25, 2008Date of Patent: March 27, 2012Assignee: Nippon Electric Glass Co., Ltd.Inventors: Narutoshi Shimatani, Seiji Hamada
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Publication number: 20120068083Abstract: The present invention relates to a laminated glazing for information display, of the automobile windshield or architectural glazing type, comprising an assembly of at least two transparent sheets of inorganic glass or of a strong organic material, joined together by an interlayer of a thermoformable material or by multilayer foils incorporating such an interlayer, said glazing being characterized in that a luminophore material of the hydroxyterephthalate type is integrated into said interlayer, allowing said display. The invention also relates to a device for displaying an image on transparent glazing, comprising laminated glazing of the above type and a source generating concentrated UV radiation of the laser type, the radiation of which is between 350 and 410 nm, the UV radiation being directed onto the area or areas of the glazing comprising the terephthalate-type luminophore layer.Type: ApplicationFiled: June 1, 2010Publication date: March 22, 2012Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Michael Labrot, Marie-Helene Breniaux, Jean Sablayrolles
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Patent number: 8137815Abstract: The present invention provides a color interlayer film for laminated glass, comprised of a resin composition containing a polyvinyl acetal resin, a coloring agent, and an infrared ray shielding agent and characterized in that the resin composition further contains a phosphoric acid ester compound at a ratio of 5 parts by weight or less to 100 parts by weight of the polyvinyl acetal resin, and also provides laminated glass using said interlayer film. The interlayer film of the present invention has characteristics that the film is excellent in the infrared ray shielding property and resistant against whitening in the interlayer film part even in the case of absorbing moisture while keeping the basic properties as an interlayer film for laminated glass.Type: GrantFiled: February 2, 2006Date of Patent: March 20, 2012Assignee: Sekisui Chemical Co., Ltd.Inventor: Tadashi Marumoto
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Patent number: 8129027Abstract: The present invention provides an interlayer film for a laminated glass comprising a polyvinyl acetal resin, which is able to be easily adhered to a glass and is capable of constituting a laminated glass excellent in transparency, and also provides a laminated glass using the interlayer film. An interlayer film for a laminated glass comprising 100 parts by weight of a polyvinyl acetal resin and 60 to 100 parts by weight of a plasticizer, wherein 50 to 100% by weight of the plasticizer is a diester compound represented by the formula (1) below. In the formula (1), R1 and R2 are each an organic group of 5 to 10 carbon atoms, R3 is —CH2—CH2—, —CH2—CH(CH3)—, —CH2—CH2—CH2— or —CH2—CH2—CH2—CH2—, and n is an integer of 4 to 10.Type: GrantFiled: May 30, 2007Date of Patent: March 6, 2012Assignee: Sekisui Chemical Co., Ltd.Inventor: Tadashi Marumoto
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Publication number: 20120052310Abstract: Plasticizer-containing films based on polyvinyl acetal containing a UV absorbers of the oxanilide type of formula (1) exhibit high UVA transmission while also exhibiting low UVB transmission, with reduced tendency to yellow.Type: ApplicationFiled: August 19, 2011Publication date: March 1, 2012Applicant: KURARAY EUROPE GMBHInventors: Uwe Keller, Andreas Karpinski, Jan Beekhuizen
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Patent number: 8114505Abstract: Improved methods for manufacturing silicon carbide rings using chemical vapor deposition. Cylindrical tubes are used as deposition substrates and the resulting material deposited on the inside surface of cylindrical tubes or on the outside surface of cylindrical mandrels, or both, is sliced or cut into the desired ring size and shape. The resulting rings have a crystal growth that is oriented substantially planar to the finished article. The invention also relates to nitrogen doped silicon carbide material, as well as to silicon carbide structures having axes of grain growth substantially parallel to the plane of the structure and to each other, and having rotational orientation that is substantially random with respect to the axes of grain growth of the grains.Type: GrantFiled: May 19, 2010Date of Patent: February 14, 2012Assignee: Morgan Advanced Ceramics, Inc.Inventors: David Thomas Forrest, Mark Wallace Schauer
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Publication number: 20120003482Abstract: The invention provides an interlayer film for a laminated glass and a laminated glass, which are protected against a slump in TL value through attenuation of said coincidence effect and adapted to display an outstanding sound insulation performance over a broad temperature range. An interlayer film for a laminated glass comprising a plasticizer and a polyacetal resin, which is a blend of a polyacetal resin having an average polymerization degree of 1,000 to 3,000 and a polyacetal resin having an average polymerization degree of 3,000 to 5,000, and which has an acetalization degree of 60 to 85 mol % and an acetyl group content of 8 to 30 mol %. An interlayer film for a laminated glass which shows a temperature dependence of loss tangent in which the lowest-temperature side maximum of loss tangent appears at 30° C. or lower when examined for dynamic viscoelasticity.Type: ApplicationFiled: September 16, 2011Publication date: January 5, 2012Applicant: Sekisui Chemical Co., Ltd.Inventors: Kiyofumi Toyama, Yoshio Aoshima, Chikao Shimizu
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Patent number: 8084129Abstract: Disclosed laminates particularly useful as safety glazings comprising a polymeric interlayer sheet, wherein the polymeric interlayer sheet comprises a blend composition of an ethylene copolymer A and an ethylene copolymer B, which has a melt flow rate of less than 100g/10 min, as determined in accordance with ASTM D1238 at 190° C. and 2.16 kg, and wherein the ethylene copolymer A comprises copolymerized units of ethylene and about 3 to about 20 wt % of an ester or anhydride of a C4-C8 unsaturated acid having two carboxylic acid groups and the ethylene copolymer B comprises copolymerized units of ethylene and about 6 to about 40 wt % of a polar monomer selected from the group consisting of vinyl acetate, alkyl(meth)acrylates, and mixtures thereof.Type: GrantFiled: November 24, 2008Date of Patent: December 27, 2011Assignee: E. I. du Pont de Nemours and CompanyInventor: Richard T. Chou
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Publication number: 20110287265Abstract: The present invention provides an interlayer for laminated glass which comprises at least one layer composed of an opaque ethylene-vinyl acetate copolymer resin composition or opaque polyvinyl acetal resin composition, and also provides the laminated glass using such interlayers. The interlayer for laminated glass and the laminated glass according to the present invention can offer excellent privacy protection.Type: ApplicationFiled: July 29, 2011Publication date: November 24, 2011Inventor: Tsuyoshi HASEGAWA
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Patent number: 8048530Abstract: According to at least one aspect of the present invention, a coated substrate surface is provided. In at least one embodiment, the coated substrate surface includes a substrate surface, and a high-velocity impact polymer reaction coating for promoting adhesive bonding, the coating having first and second opposing surfaces, the first opposing surface being adjacent to the substrate surface. In at least another embodiment, the high-velocity impact polymer reaction coating is formed by depositing a polymer reaction compound onto the substrate surface with a high-velocity impact device at a velocity in the range of 10 to 200 meters per second, the polymer reaction compound being formed from substantially random fragmentation of prepolymer molecules.Type: GrantFiled: February 25, 2009Date of Patent: November 1, 2011Assignee: Ford Global Technologies, LLCInventors: Larry Haack, Ann Straccia, Joseph Holubka
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Publication number: 20110256410Abstract: An improvement of fire-resistant laminated glass is provided, which serves to retard spreading fire and high heat in conflagration, and normally acts as crashworthy glass, wherein plural potash glass sheets are bound as a whole by means of PVB (polyvinyl butyral) and form the laminated glass, in which the PVB reinforces the potash glass by multiplying a crashworthiness thereof and the potash glass, as a product of processing soda-lime glass with the known chemical enhanced treatment, is high-temperature endurable.Type: ApplicationFiled: April 14, 2010Publication date: October 20, 2011Inventor: MAO SHENG WU
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Patent number: 8039536Abstract: The invention provides an interlayer film for a laminated glass and a laminated glass, which are protected against a slump in TL value through attenuation of said coincidence effect and adapted to display an outstanding sound insulation performance over a broad temperature range. An interlayer film for a laminated glass comprising a plasticizer and a polyacetal resin, which is a blend of a polyacetal resin having an average polymerization degree of 1,000 to 3,000 and a polyacetal resin having an average polymerization degree of 3,000 to 5,000, and which has an acetalization degree of 60 to 85 mol % and an acetyl group content of 8 to 30 mol %. An interlayer film for a laminated glass which shows a temperature dependence of loss tangent in which the lowest-temperature side maximum of loss tangent appears at 30° C. or lower when examined for dynamic viscoelasticity.Type: GrantFiled: November 19, 2010Date of Patent: October 18, 2011Assignee: Sekisui Chemical Co., Ltd.Inventors: Kiyofumi Toyama, Yoshio Aoshima, Chikao Shimizu
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Patent number: 8039112Abstract: Interlayer films useful for laminated glass contain a polyvinyl acetal (A), at least on plasticizer (B), fumed silica (C) and at least one basic compound (D), wherein the difference of refractive index between fumed silica (C) and plasticized polyvinyl acetal (A+B) is 0.015 or less, and the weight ratio of C/(A+B) is 2.7-60/100.Type: GrantFiled: April 4, 2008Date of Patent: October 18, 2011Assignees: Kuraray Europe GmbH, Kuraray Co., Ltd.Inventors: Uwe Keller, Martin Steuer, Takashi Wakui, Nobuhiro Moriguchi
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Patent number: 8033360Abstract: It is an object of the present invention to provide an interlayer film for a laminated glass excellent in a sound-insulating property, which is preferably usable for a head up display and the like wherein a driver can look at the front view and an instrument display simultaneously without requiring to look down, and to provide a laminated glass. The present invention is directed to interlayer film for a laminated glass, which comprises at least a pair of protection layers and a sound-insulating layer sandwiched between the pair of the protection layers, and which has ah wedge shape as a cross-sectional shape, a wedge angle ? of 0.1 to 0.7 mrad, the maximum thickness of 2000 ?m or thinner, and the minimum thickness of 400 ?m or thicker, the minimum thickness of the sound-insulating layer being 20 ?m or thicker.Type: GrantFiled: January 3, 2011Date of Patent: October 11, 2011Assignee: Sekisui Chemical Co., Ltd.Inventor: Jiro Miyai
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Patent number: 7985480Abstract: Disclosed herein are an interlayer film for glass laminate, which contains a polyvinyl acetal resin and can be easily bonded to glass sheets to produce a glass laminate having high transparency, and a glass laminate using such an interlayer film. The interlayer film for glass laminate includes 100 parts by weight of a polyvinyl acetal resin and 40 to 75 parts by weight of a plasticizer, wherein 4 to 40 wt % of the plasticizer is composed of an unsaturated fatty acid alkyl ester having 16 to 20 carbon atoms.Type: GrantFiled: April 23, 2007Date of Patent: July 26, 2011Assignee: Sekisui Chemical Co., Ltd.Inventor: Tadashi Marumoto
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Patent number: 7985481Abstract: The present invention provides an interlayer for a laminated glass, which contains a polyvinyl acetal resin, and can be easily bonded to a glass sheet to form a highly transparent laminated glass. And the present invention provides a laminated glass using the interlayer. The interlayer for a laminated glass contains 100 phr of a polyvinyl acetal resin and 42 to 60 phr of a plasticizer, wherein the plasticizer is unsaturated fatty acid alkyl ester having 16 to 20 carbon atoms.Type: GrantFiled: October 29, 2008Date of Patent: July 26, 2011Assignee: Sekisui Chemical Co., Ltd.Inventor: Tadashi Marumoto
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Publication number: 20110155205Abstract: The invention relates to polyvinyl acetals obtainable by reacting polyvinyl alcohol with at least one aldehyde with a degree of acetalisation of at least 75 mol %, characterised by an OH blockiness of the polyvinyl acetal, defined as a quotient from the number of methylene groups of two adjacent alcohol sequences (VV) and the sum of the number of methylene groups of adjacent alcohol/acetal sequences and acetal/acetal sequences (VB+BB), of more than 0.151, as well as a process for the preparation thereof.Type: ApplicationFiled: December 17, 2010Publication date: June 30, 2011Applicant: Kuraray Europe GMBHInventors: Martin STEUER, Masako Katayama
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Patent number: 7968186Abstract: An acoustic solar control laminate comprising a multi-layer interlayer formed of a solar control film bonded between two polymeric sheets with at least one being an acoustic poly(vinyl acetal) sheet is provided.Type: GrantFiled: July 3, 2007Date of Patent: June 28, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Donald L. Rymer, Richard A. Hayes
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Patent number: 7960503Abstract: The present invention provides a method for continuously washing poly(vinyl butyral) in which a poly(vinyl butyral) slurry is passed through multiple continuous stirred tank reactors, each of which is adjusted to specific processing parameters that allow for continuous input, washing, and removal of poly(vinyl butyral). The resulting poly(vinyl butyral) can then be dried to form a powder resin that can be used in place of conventional poly(vinyl butyral) resin. In an alternative embodiment, a counter current screw washing unit is provided that passes wash water over the poly(vinyl butyral) in a direction opposite to the flow of the poly(vinyl butyral), thereby allowing the continuous washing of the poly(vinyl butyral) resin.Type: GrantFiled: May 26, 2009Date of Patent: June 14, 2011Assignee: Solutia, Inc.Inventors: Pol D'Haene, Nandan Ukidwe, Paul Van Lierde
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Publication number: 20110096555Abstract: The subject of the invention is laminated glazing comprising at least two glass sheets (1, 4) and at least one polymeric interlayer (2) made of polyvinyl butyral and binding said glass sheets together. The glazing is characterized in that at least one lacquer layer (3) is placed between the at least two glass sheets (1, 4).Type: ApplicationFiled: December 22, 2008Publication date: April 28, 2011Applicant: SAINT-GOBAIN GLASS FRANCEInventors: Isabelle Pires, Aurelien Gouy, Isabelle Bernheim
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Patent number: 7927706Abstract: The present invention is in the field of polymer sheets and multiple layer glass panels having adjustable tint, and, more specifically, the present invention is in the field of polymer sheets and multiple layer glass panels comprising agents that cause a change in light transmission properties when subjected to an electric field.Type: GrantFiled: February 2, 2007Date of Patent: April 19, 2011Assignee: Solutia Inc.Inventor: William Keith Fisher
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Patent number: 7919175Abstract: Provided is a transparent and light-weight ballistic resistant safety glazing comprising an ionomer sheet. The ionomer sheet comprises an ionomer derived from a parent acid copolymer that comprises copolymerized units of an ?-olefin having 2 to 10 carbon atoms and, based on the total weight of the acid copolymer, about 20 to about 30 wt % of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid having 3 to 8 carbon atoms. The ionomer is neutralized to a level of about 5% to about 90%, based on the total carboxylic acid content of the acid copolymer, and further comprises at least one cation. Further provided are articles comprising the light-weight ballistic resistant safety glazing.Type: GrantFiled: November 13, 2009Date of Patent: April 5, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: Stephen J. Bennison, David F. Kristunas, Andres Ovalle
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Patent number: 7919158Abstract: An insulated glazing unit is described and includes a first transparent substrate spaced apart from a parallel second transparent substrate, a sealed void space defined between the first transparent substrate, second transparent substrate, and the window mounting member, and an infrared radiation reflecting multilayer polymeric film disposed between the first transparent substrate and the second transparent substrate. The infrared radiation reflecting multilayer polymeric film includes a plurality of alternating polymeric layers of a first polymer material and a second polymer material. At least one of the alternating polymer layers is birefringent and oriented. The alternating, polymeric layers cooperate to reflect infrared radiation.Type: GrantFiled: May 31, 2007Date of Patent: April 5, 2011Assignee: 3M Innovative Properties CompanyInventors: Jayshree Seth, Raghunath Padiyath
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Patent number: 7892629Abstract: A laminated glazing material with properties of acoustic insulation and mechanical strength. The laminated glazing material including two glass sheets and a single-ply intermediate layer of a thickness having the form of a polymer film. The thickness of the intermediate layer being defined as a function of a variable which is specific to the material, and which defines the critical energy value of the intermediate layer and is representative of the energy necessary for propagation of a crack initiated in the intermediate layer.Type: GrantFiled: November 22, 2005Date of Patent: February 22, 2011Assignee: Saint-Gobain Glass FranceInventors: Marc M. Rehfeld, Boris M. Vidal
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Patent number: 7886871Abstract: It is an object of the present invention to provide an interlayer film for a laminated glass excellent in a sound-insulating property, which is preferably usable for a head up display and the like wherein a driver can look at the front view and an instrument display simultaneously without requiring to look down, and to provide a laminated glass. The present invention is directed to interlayer film for a laminated glass, which comprises at least a pair of protection layers and a sound-insulating layer sandwiched between the pair of the protection layers, and which has a wedge shape as a cross-sectional shape, a wedge angle ? of 0.1 to 0.7 mrad, the maximum thickness of 2000 ?m or thinner, and the minimum thickness of 400 ?m or thicker, the minimum thickness of the sound-insulating layer being 20 ?m or thicker.Type: GrantFiled: May 11, 2007Date of Patent: February 15, 2011Assignee: Sekisui Chemical Co., Ltd.Inventor: Jiro Miyai
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Patent number: 7883761Abstract: The present invention provides multiple layer interlayers having a relatively soft inner layer and relatively stiff outer layers that can be laminated without unacceptable optical distortion and used in various multiple layer glass panel type applications. Multiple layer interlayers of the present invention have surface topography that is formed by embossing the exposed surface of the interlayer, or individual layers of the multiple layer interlayer, after formation of the interlayer or layers. The embossing process is carried out under temperature conditions that prevent the transfer of the embossing to inner layers of the interlayer. By precisely controlling the embossing of the interlayer, lamination of the interlayer with a rigid substrate does not lead to unacceptable optical distortion caused by the transfer of the surface topography through outer, stiffer layers into softer, internal layers of the interlayer.Type: GrantFiled: July 24, 2009Date of Patent: February 8, 2011Assignee: Solutia Inc.Inventors: David Paul Bourcier, John Joseph D'Errico, Jean-Pierre Etienne, Gary Matis, Vincent James Yacovone
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Patent number: 7867605Abstract: Composite laminate interlayers for adhering a glass laminate comprising two sheets of polyethylene terephthalate (PET) between layers of plasticized polyvinyl butyral (PVB) adhesive layers, wherein the two PET layers provide increased stiffness for the laminate without sacrificing the optical clarity of the laminate.Type: GrantFiled: November 18, 2004Date of Patent: January 11, 2011Assignee: Solutia Inc.Inventors: James R Moran, Jun Lu
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Patent number: 7867618Abstract: The present invention includes polymer interlayers that are used in multiple layer glazing panels. Interlayers of the present invention comprise a thermoplastic polymer, a plasticizer, and a fumed silica that has been modified to impart hydrophobic character. Interlayers incorporating such components have improved tensile modulus, moisture resistance, creep performance, anticorrosion effect, glass adhesion, and are well suited to a variety of applications, including, but not limited to, acoustic applications.Type: GrantFiled: January 28, 2008Date of Patent: January 11, 2011Assignee: Solutia IncorporatedInventor: Ping Yuan
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Patent number: 7858683Abstract: The invention provides an interlayer film for a laminated glass and a laminated glass, which are protected against a slump in TL value through attenuation of said coincidence effect and adapted to display an outstanding sound insulation performance over a broad temperature range. An interlayer film for a laminated glass comprising a plasticizer and a polyacetal resin, which is a blend of a polyacetal resin having an average polymerization degree of 1,000 to 3,000 and a polyacetal resin having an average polymerization degree of 3,000 to 5,000, and which has an acetalization degree of 60 to 85 mol % and an acetyl group content of 8 to 30 mol %. An interlayer film for a laminated glass which shows a temperature dependence of loss tangent in which the lowest-temperature side maximum of loss tangent appears at 30° C. or lower when examined for dynamic viscoelasticity.Type: GrantFiled: December 28, 2006Date of Patent: December 28, 2010Assignee: Sekisui Chemical Co., Ltd.Inventors: Kiyofumi Toyama, Yoshio Aoshima, Chikao Shimizu
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Patent number: 7854993Abstract: The present invention is in the field of polymer interlayers and multiple layer glass panels comprising polymer interlayers, and, more specifically, the present invention is in the field of polymer interlayers comprising multiple thermoplastic sheets.Type: GrantFiled: February 13, 2009Date of Patent: December 21, 2010Assignee: Solutia Inc.Inventor: Jun Lu
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Patent number: 7846532Abstract: The present invention is in the field of polymer interlayers and multiple layer glass panels comprising polymer interlayers, and, more specifically, the present invention is in the field of wedge shaped polymer interlayers.Type: GrantFiled: March 17, 2005Date of Patent: December 7, 2010Assignee: Solutia IncorporatedInventors: Jun Lu, Brian James Daer
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Patent number: 7842395Abstract: The present invention provides multiple layer interlayers that can be used in multiple layer glass panel type applications to reduce the amount of sound transmitted through the panel while also providing a colored region within a gradient region. The acoustic effect can be achieved by using two or more polymer sheets having differing compositions that have been combined into a single multiple layer interlayer, and the gradient region effect is achieved by forming a colored region in one or more gradient regions of the individual layers.Type: GrantFiled: November 1, 2006Date of Patent: November 30, 2010Assignee: Solutia Inc.Inventors: Jun Lu, Marcin Wardak, Andrew Neil Smith, Gary Matis, Aristotelis Karagiannis, John Joseph D'Errico, David Paul Bourcier
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Patent number: 7829192Abstract: Laminated glazing (2) comprising a viscoelastic plastic insert (3) comprising at least two damping films (30, 31) each having a loss factor tan ? greater than 0.6 and a shear modulus G? less than 2×107 Pa over two temperature ranges tA et tB respectively, characterized in that the film which has, at a frequency of 200 Hz, the highest loss factor tan ? over a given temperature range included within the temperature range tA or tB, has an equivalent shear modulus G?eq less than the equivalent shear modulus or moduli of the other film or films, with G eq ? = G ? ? e tot e where G? is the shear modulus of the material constituting the film, e is the thickness of the film and etot the total thickness of the insert.Type: GrantFiled: May 10, 2007Date of Patent: November 9, 2010Assignee: Saint-Gobain Glass FranceInventors: Jean-Philippe Boure, Julien Charlier, Eloi Gaudry, Marc Rehfeld
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Patent number: 7829183Abstract: Improved methods for manufacturing silicon carbide rings using chemical vapor deposition. Cylindrical tubes are used as deposition substrates and the resulting material deposited on the inside surface of cylindrical tubes or on the outside surface of cylindrical mandrels, or both, is sliced or cut into the desired ring size and shape. The resulting rings have a crystal growth that is oriented substantially planar to the finished article. The invention also relates to nitrogen doped silicon carbide material, as well as to silicon carbide structures having axes of grain growth substantially parallel to the plane of the structure and to each other, and having rotational orientation that is substantially random with respect to the axes of grain growth of the grains.Type: GrantFiled: December 6, 2004Date of Patent: November 9, 2010Assignee: Morgan Advanced Ceramics, Inc.Inventors: David Thomas Forrest, Mark Wallace Schauer
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Publication number: 20100273012Abstract: Provided is a thermoplastic polymer composition, including a thermoplastic elastomer (A) and a polyvinyl acetal (B), wherein the thermoplastic elastomer (A) is a styrene-based thermoplastic elastomer or an olefin-based thermoplastic elastomer. Thus, a thermoplastic polymer composition is provided that has good flexibility as a thermoplastic elastomer composition, is excellent in mechanical properties and formability, and also itself has excellent adhesion to a ceramic, a metal, or a polar polymer. In addition, provided is a shaped article in which the thermoplastic polymer composition is adhered to a ceramic, a metal, or a polar polymer, in particular a shaped article adhered to a glass.Type: ApplicationFiled: December 19, 2008Publication date: October 28, 2010Applicant: KURARAY CO., LTD.Inventors: Nobuhiro Moriguchi, Shinichi Torigoe, Kazuki Tokuchi
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Publication number: 20100233453Abstract: [Problem to be Solved] The object of the present invention is to provide an intermediate film for a laminated glass having excellent transparency, adhesion, impact resistance and penetration resistance as well as excellent light resistance and weather resistance, and scarcely turning yellow in a heating treatment during its preparation. [Means for Solving Problem] An intermediate film for a laminated glass comprising a laminate consisting of a layer (PVB layer) of a composition comprising polyvinyl butyral and a layer (EVA layer) of a composition comprising ethylene/vinyl acetate copolymer containing an organic peroxide, wherein the composition comprising polyvinyl butyral contains a benzophenone compound as an ultraviolet absorber; a laminated glass; and a process for the preparation of the same.Type: ApplicationFiled: March 22, 2007Publication date: September 16, 2010Applicant: BRIDGESTONE CORPORATIONInventor: Masao Hashimoto
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Patent number: 7794818Abstract: A self-supporting adhesive web 10 having a uniform thickness profile across at least 20% of its width as shown by areas A and B and a wedge-shaped thickness profile in areas C and D. As shown in FIG. 2, a laminate comprises sheets of glass 12 and 14 having sandwiched therebetween adhesive interlayer 16. Interlayer 16 has a uniform thickness profile extending from edge 18 to point 20 and a wedge-shaped thickness profile from point 20 to edge 22.Type: GrantFiled: April 25, 2007Date of Patent: September 14, 2010Assignee: E. I. du Pont de Nemours and CompanyInventors: Jimmy K. Travis, Randall A. Hollingsworth