Next To Acetal Of Polymerized Unsaturated Alcohol (e.g., Formal Butyral, Etc.) Patents (Class 428/437)
-
Patent number: 5631088Abstract: A material used to fabricate sashes used by window assemblies. The material comprises a foam core covered by a cladding material. The foam core acts as a filler and provides insulation, while the cladding material protects the foam core from the environment and physical abuse. Often, a structural assembly or member is provided to stiffen the sash material. The cladding and structural assembly are placed into a mold and resin is injected into the mold between the cladding and the structural assembly. The resin cures to form the foam core. The foam core bonds the cladding and structural assembly together to form the sash material. The sash material is cut with woodworking tools to form a sash for a window assembly. The cladding is configured such that, when the window assembly is installed in a wall, interior vapor barrier material and exterior air barrier material applied to the wall overlap with the cladding material to reduce air flow through the wall around the window assembly.Type: GrantFiled: August 30, 1994Date of Patent: May 20, 1997Inventor: Ross Harper
-
Patent number: 5631315Abstract: Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.Type: GrantFiled: July 1, 1993Date of Patent: May 20, 1997Assignee: Monsanto CompanyInventor: John J. D'Errico
-
Patent number: 5631089Abstract: A glass/plastic laminate useful in glazing applications which has improved optical quality is provided by controlling the incidence of optical defects induced during manufacture by particulate contaminates by applying a soft plastic film to the outboard side of the plastic surface of the laminate and entrapping such contaminates during the lamination process in the soft plastic film.Type: GrantFiled: March 10, 1994Date of Patent: May 20, 1997Assignee: E. I. Du Pont de Nemours and CompanyInventors: Luther W. Center, Jr., Charles A. Smith
-
Patent number: 5620799Abstract: A glazing for an enclosed space includes at least one sheet of glass having a precisely delimited surface region and a transmitter and/or a receiver for electromagnetic radiation in a non-visible portion of the spectrum. The transmitter and/or receiver are positioned for respectively transmitting and receiving radiation in a non-visible portion of the spectrum via the precisely delimited surface region. The transmissivity of said precisely delimited surface region for electromagnetic radiation in said non-visible portion of the spectrum is higher than that of a remainder of the at least one sheet of glass for electromagnetic radiation in the non-visible portion of the spectrum.Type: GrantFiled: September 18, 1995Date of Patent: April 15, 1997Assignee: Saint-Gobain VitrageInventor: Gerd Sauer
-
Patent number: 5605591Abstract: The invention relates to a method for fabricating laminated glazing comprising at least one enamel layer, wherein is deposited an enamelled composition comprising an anti-adhesive frit, a medium and, optionally, a low melt point frit on a portion of the internal face of a glass sheet; the enamelled glass sheet is subjected to heat treatment at a temperature between 150.degree. C. and the glass deformation temperature, and a second glass sheet is placed on the enamelled side of the first glass sheet before simultaneous bending of the two glass sheets, final firing of the enamel taking place during bending.Type: GrantFiled: January 30, 1995Date of Patent: February 25, 1997Assignee: Saint-Gobain Vitrage InternationalInventors: Andre Beyrle, Walter Goerenz, Dieter K ustner, Wolfgang Schafer
-
Patent number: 5602457Abstract: A laminated windshield in which thin solar cells are sandwiched between the glass layer. The solar cell is electrically connected to a vehicle battery to provide recharging current to the battery from the electrical current generated by the solar cells. The solar cells may be formed of dendrite solar cells arranged in flexible strings. These solar cell strings may be positioned in the windshield proximate to an edge of the windshield and superimposed over windshield tinting or darkened border areas of the windshield.Type: GrantFiled: June 13, 1996Date of Patent: February 11, 1997Assignee: Exide CorporationInventors: Carl J. Anderson, Howard E. Mitchell
-
Patent number: 5595818Abstract: In preparing rough-surfaced sheet of polyvinyl butyral (PVB), a fraction of stiffly resilient particles of crosslinked PVB are present in the formulation which on exiting an extrusion die opening mechanically interfere with and roughen the surface of the sheet being formed.Type: GrantFiled: February 27, 1995Date of Patent: January 21, 1997Assignee: Monsanto CompanyInventors: Harold H. Hopfe, Aristotelis Karagiannis
-
Patent number: 5587236Abstract: The present invention comprises a vehicle accessory mounting button, windshield arrangement and a method for making the same which uses nonelastomeric, thermosetting, structural adhesives, preferably in film form, to adhere the accessory mounting button to the interior surface of a windshield. The adhesives provide outstanding long-term adhesion and good accessory assembly vibration performance even under rigorous climate conditions while simultaneously being compatible with conventional autoclaving processes used in windshield manufacturing. Thermosetting structural adhesives suitable to achieve the objectives of this invention include modified epoxies, which have a cure temperature below 325.degree. F., a modulus of elasticity at 85.degree. C. of at least about 10,000 psi when cured, and are compatible with current windshield manufacturing processes.Type: GrantFiled: May 10, 1995Date of Patent: December 24, 1996Assignee: Donnelly CorporationInventors: Raj K. Agrawal, Niall R. Lynam, James K. Galer
-
Patent number: 5585188Abstract: The invention concerns a monolithic or laminated pane of glass or of plastic materials which contains at least one glass sheet (8, 9). The edge face of the glass sheet is at least partly covered with a protective strip (11, 12) of elastomeric material which has a hardness less than 90 shore A. The protected strip is adhered to the edge face. The strip serves to protect the sheet from any shock or impact it receives during processing prior to assembly into a pane for use in aircraft or transportation vehicles.Type: GrantFiled: May 30, 1995Date of Patent: December 17, 1996Assignee: Saint-Gobain Vitrage InternationalInventors: Jean Cheron, Pierre Chaussade
-
Patent number: 5573842Abstract: A plasticized polyvinylbutyral film comprising a plasticizer, polyvinylbutyral, and an optical brightener in an amount effective to improve the optical properties and reduce the yellowing of the film. The resulting films are useful as intermediate films in multilayer laminated glass panes, including silicate-containing panes.Type: GrantFiled: July 5, 1994Date of Patent: November 12, 1996Assignee: Hoechst AktiengesellschaftInventor: Matthias Gutweiler
-
Patent number: 5567529Abstract: A multilayered glass laminate having enhanced resistance to spalling and penetration by high velocity projectiles consists of at least three plies of glass (10, 12, 14) with layers of plasticized polyvinyl butyral (16, 18, 20) therebetween and having permanently bonded to an outer layer of one of said plies of glass (14) a thin composite consisting of an adhesive energy absorbing layer (22) and a dimensionally stable polyester film (24).Type: GrantFiled: November 15, 1994Date of Patent: October 22, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventor: Charles A. Smith
-
Patent number: 5547736Abstract: A plastic sheet, preferably of plasticized partial polyvinyl butyral, for a laminated safety glazing, having means dispersed on its surface, preferably comprising a multiplicity of spaced projections, capable of resisting adhesion to a rigid panel, such as glass, of such a glazing when the sheet is laminated to the panel, the area of the sheet surface without such dispersed means having high affinity for adhesion. The projections physically block adhesion of a dispersed area of the sheet to the panel in that the means on the sheet surface have no or weak interfacial adhesion. The multiplicity of space projections also have low or no affinity for adhesion when in blocking contact with each other or with another plasticized partial polyvinyl butyral surface and thereby increase blocking resistance.Type: GrantFiled: December 19, 1994Date of Patent: August 20, 1996Assignee: Monsanto CompanyInventors: Robert H. M. Simon, Peter H. Farmer
-
Patent number: 5540961Abstract: A process for the production of a laminated glass glazing having one or more wires within an intermediate thermoplastic layer and electrically connected to busbars, wherein the wires are heated by an adequate energy application locally limited to the connection points prior to the electrical connection to the busbars, to the extent that the surface layers adhering to the surface of the wires are eliminated. The application of a locally limited adequate energy supply takes place by use of laser rays, as a result of the fact that the focus of a beam of laser rays oriented perpendicular to the busbars is displaced in the longitudinal direction above and on the busbars. The wires are then welded to the busbars. The layers forming the laminated glass glazings are presently assembled in a conventional manner and joined to one another under heat and pressure.Type: GrantFiled: December 2, 1994Date of Patent: July 30, 1996Assignee: Saint-Gobain VitrageInventors: M. Bernard Reul, Stefan Immerschitt
-
Patent number: 5529848Abstract: Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.Type: GrantFiled: April 3, 1995Date of Patent: June 25, 1996Assignee: Monsanto CompanyInventor: John J. D'Errico
-
Patent number: 5529849Abstract: Plasticized polyvinyl butyral sheet containing epoxy resin in amount effective, after prolonged exposure to light, to counteract reduction of adhesion between the sheet and a photoreactive component with which it will be in potential contact. The photoreactive component is typically a dielectric such as a metal oxide layer of a heat-wave-reflective or electrically conductive multi-layer coating, which coating can optionally be supported on (a) a thermoplastic substrate sandwiched between two of such polyvinyl butyral sheets forming a prelaminate for use as a constituent of a laminated glazing panel or (b) a glass sheet component of such glazing panel.Type: GrantFiled: April 3, 1995Date of Patent: June 25, 1996Assignee: Monsanto CompanyInventor: John J. D'Errico
-
Patent number: 5506037Abstract: A heat reflecting and/or electrically heatable laminated glazing system having two single glass panes bonded together by a thermoplastic film such as polyvinyl butyral is disclosed. One of these two panes includes a layered construction, preferably of a conductive silver layer and an dielectric layer, preferably of zinc oxide, which is disposed on the silver layer. A bonding layer is utilized to improve the bond between the thermoplastic film and the dielectric layer. The bonding layer comprises one of the metals in groups IV, V, or VII of the periodic system or an oxide of these metals.Type: GrantFiled: May 7, 1993Date of Patent: April 9, 1996Assignee: Saint Gobain Vitrage InternationalInventor: Gunter Termath
-
Patent number: 5500274Abstract: Composite coatings are provided having a variable thickness and a gradient coloration in the cross-web direction using a premetered extrusion coating process wherein a pigmented coating composition and a non-pigmented coating composition are simultaneously extruded onto a carrier film. The composite coatings are useful in preparing laminated structures such as automobile windshields with a colored gradient band.Type: GrantFiled: March 22, 1994Date of Patent: March 19, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Debra C. Francis, Siva V. Vallabhaneni, Bert C. Wong
-
Patent number: 5496621Abstract: The invention relates to a transparent coating on a transparent glass pane which may be a laminated glass pane such as an automobile windshield. The present invention provides a two-layer coating including a first layer which is a transparent oxide film in direct contact with the major surface of the glass substrate and a second layer which is a transparent oxide film. The first layer has a thickness of 70-230 nm and a refractive index of 1.80-2.10 and includes a major portion and a minor portion which is exposed and adapted to be used as a combiner of a head-up display system. The second layer is formed on the major portion of the first layer so as to expose the minor portion of the first layer. The second layer has a thickness of 110-130 nm and a refractive index of 1.40-1.50. An additional film is optionally formed on the minor portion of the first layer so as to fully or partly cover the minor portion.Type: GrantFiled: April 15, 1994Date of Patent: March 5, 1996Assignee: Central Glass Company, LimitedInventors: Kensuke Makita, Atsushi Takamatsu, Katsuto Tanaka
-
Patent number: 5482767Abstract: A light-transmitting laminated panel having increased resistance to impact-induced rupture sequentially includes: a) a glass layer, b) an optically clear layer of a plasticized polyvinyl butyral matrix containing discrete particles of crosslinked polyvinyl butyral integrally randomly dispersed throughout the matrix which enhance the impact-resistance of the panel and are visually indistinguishable from the matrix polyvinyl butyral, and c) another glass layer, the laminated panel at a specific pummel adhesion having greater mean break height than that of a laminated panel containing layers a), b) and c) but without the impact-resistance-enhancing particles of crosslinked polyvinyl butyral in layer b). An amount up to 40 weight % of the particles is incorporated into the matrix polyvinyl butyral before preparing the laminated panel.Type: GrantFiled: September 29, 1994Date of Patent: January 9, 1996Assignee: Monsanto CompanyInventors: Aristotelis Karagiannis, Peter D. LaPorte
-
Patent number: 5478412Abstract: A plastic sheet, preferably of plasticized partial polyvinyl butyral, for a laminated safety glazing, having means dispersed on its surface, preferably comprising a multiplicity of spaced projections, capable of resisting adhesion to a rigid panel, such as glass, of such a glazing when the sheet is laminated to the panel, the area of the sheet surface without such dispersed means having high affinity for adhesion. The projections physically block adhesion of a dispersed area of the sheet to the panel in that the means on the sheet surface have no or weak interfacial adhesion. The multiplicity of space projections also have low or no affinity for adhesion when in blocking contact with each other or with another plasticized partial polyvinyl butyral surface and thereby increase blocking resistance.Type: GrantFiled: June 7, 1993Date of Patent: December 26, 1995Assignee: Monsanto CompanyInventors: Robert H. M. Simon, Peter H. Farmer
-
Patent number: 5464693Abstract: This invention relates to a mirror base-installing structure for installing a mirror base on the surface of a glass plate, characterized in that said mirror base is bonded to the surface of said glass plate with a film-like or sheet-like heat-curable adhesive interposed between the mirror base and the glass plate, said adhesive having elasticity or plasticity after heat-cured, and a method for installing the same. The mirror base can be bonded simultaneously with the preparation of a bilayer glass, thereby simplifying the working process.Type: GrantFiled: May 28, 1992Date of Patent: November 7, 1995Assignee: Asahi Glass Company Ltd.Inventors: Michio Ono, Masaharu Kume, Takayuki Matsuo
-
Patent number: 5434207Abstract: Preparation of plasticizer-containing polyvinylbutyrals (PVB) which are suitable for the production of elastic interleaving films with improved adhesion-reducing properties for laminated glass panes of siliceous glass. They comprise, as adhesion-reducing additives, active amounts of salts of metals of groups Ia, IIa, IIb and IIIa of the periodic table of the elements and naturally occurring resin acids or derivatives of resin acids, and, if appropriate, customary stabilizers and auxiliaries. They are prepared by mixing the components and plasticizing the component mixtures. They can be shaped thermo-plastically by customary methods and are suitable for the production of plasticized PVB films which have advantageously improved adhesion-reducing properties with respect to siliceous glass panes and can advantageously be used for the production of siliceous laminated glass panes.Type: GrantFiled: March 23, 1994Date of Patent: July 18, 1995Assignee: Hoechst AktiengesellschaftInventor: Hannes Fischer
-
Patent number: 5427861Abstract: A laminated glazing panel having improved resistance to light exposure comprising: A) a glass sheet; B) an IR reflective or electrically conductive multi-layered coating on the glass sheet which includes a cap layer of Cr.sub.x O.sub.y where X.ltoreq.2 and y.ltoreq.5; and C) a plasticized sheet containing polyvinyl butyral in interfacial contact with the cap layer, such sheet containing one or more carboxylic acid metal salts wherein the metal is predominantly divalent, in amount effective to control the potential level of adhesion of said plasticized sheet to another glass sheet to which it is eventually laminated; such glazing panel when laminated with said another glass sheet exhibiting pummel adhesion, measured on the side of the plasticized sheet contacting component B), of at least 3 after at least 2000 hours exposure in a Fadeometer or Weatherometer.Type: GrantFiled: August 12, 1991Date of Patent: June 27, 1995Assignee: Monsanto CompanyInventor: John J. D'Errico
-
Patent number: 5418025Abstract: A window glass comprising at least one sheet of glass coated with an electroconductive ITO layer, pyrolyzed from powdered components, combined with a flexible plastic material of the PVB, PU, PVC type, with an index approaching more the index of the ITO layer than the index of air, with which the said layer is coated, and a sheet of glass dyed in the mass, with the same color as the ITO layer, and with properties of reduced energy transmission also entering advantageously into the composition of the window glass is provided. The invention particularly applies to the production of heated windshields for automobiles.Type: GrantFiled: May 9, 1994Date of Patent: May 23, 1995Assignee: Saint Gobain VitrageInventors: Helene Harmand, Vincent Sauvinet, Maurice Trouve
-
Patent number: 5415942Abstract: Abrasion resistant polyester film useful in glazing structures having improved adhesion of the abrasion resistant coating to the polyester film are provided by applying an acrylic based primer composition to the polyester film and an overlying coating of a polysiloxane containing less than 23.times.10.sup.-6 mole per gram of alkali metal cations.Type: GrantFiled: November 4, 1993Date of Patent: May 16, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: Jerrel C. Anderson
-
Patent number: 5413863Abstract: Holographic films are disclosed that contain a binder having the following formula:(M).sub.w (VAc).sub.x (VOH).sub.y (VOS).sub.zwherein M is a fluoromonomer; VAc is vinyl acetate; VOH is vinyl alcohol; and VOS is vinyl trimethylsilyl ether; and wherein w, x, y, and z are percentages by weight; w is 5 to 30, x is 40 to 80, y is 0 to 20, and z is 2 to 30; said copolymers containing 3 to 23% by weight fluorine. These imaged films are particularly suited for lamination to glass in head-up display applications.Type: GrantFiled: November 4, 1993Date of Patent: May 9, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventors: Andrew M. Weber, Aleksander Beresniewicz
-
Patent number: 5412279Abstract: An antistatic coating was provided on a substrate 10 by dispersing latex particles 12 from a polypyrrole compound in an aqueous solution of a hydrolyzed alkoxysilane compound, after which the dispersion was applied to the substrate. The hydrolyzed alkoxysilane compound was converted to silicon dioxide by means of a treatment at an increased temperature, thereby forming a matrix 14 in which the latex particles 12 are dispersed and by means of which the latex particles are adhesively secured to the substrate 10. The antistatic coating can particularly suitably be used on the display screen of a cathode ray tube, and, if desired, said coating can simultaneously be used to reduce the light transmission of the display screen.Type: GrantFiled: September 18, 1992Date of Patent: May 2, 1995Assignee: U.S. Philips CorporationInventor: Johannes De Boer
-
Patent number: 5384346Abstract: Polyvinyl butyrals (PVBs) with improved thermal stability and improved light resistance contain as stabilizers polynuclear phenols which phenolic radicals have a quaternary carbon atom in the para-position to the phenolic hydroxyl group and if desired in combination with synergistically acting, nitrogen-containing, sulfur-containing or phosphorus-containing co-stabilizers of the types a) to d). The use of the resulting films of low yellowness as interlayer films having substantially reduced yellowing for the production of laminated glasses and glass composites of silicate glass sheets is described.Type: GrantFiled: May 6, 1993Date of Patent: January 24, 1995Assignee: Hoechst AGInventors: Matthas Gutweiler, Ulrich Hutten, Gerhard Pfahler, Hermann Schindler
-
Patent number: 5380575Abstract: A vertically adjustable glass pane for automobiles, especially a door window pane, is of laminated glass consisting of two thermally toughened single glass sheets, each 1.5 to 3 mm thick, and of a thermoplastic intermediate layer. Both the glass sheets have, in their edge region, tensile stresses in the core having a value from 27 to 57 MN/m.sup.2 for a sheet thickness of 1.5 mm and 20 to 47 MN/m.sup.2 for a sheet thickness of 3 mm. In the middle area within the peripheral region the glass sheets have tensile stresses in the core which, in the case of a glass sheet of 1.5 mm thickness, have values of 25 to 42 MN/m.sup.2 and, with a glass thickness of 3 mm, values of 17.5 to 33 MN/m.sup.2. Laminated glass panes of this type have a comparatively high strength in the peripheral region and low strength in the middle area. They possess excellent properties both from a structural design standpoint and also from the standpoint of safety in case of accident.Type: GrantFiled: February 10, 1993Date of Patent: January 10, 1995Assignee: Saint-Gobain Vitrage InternationalInventors: Hans-Werner Kuster, Franz Kramling, Friedrich-Wilhelm Berndsen
-
Patent number: 5370913Abstract: A laminated ornamental glass article has two transparent glass substrates and three coating layers of opaque figures and crevices between the two transparent glass substrates. This allows a person at one side of the glass article to see through the glass article an object at the opposite side of the glass article, while another person on the opposite side may only see the opaque figures on the glass article. The three coating layers include a glaze figure layer, a white paint layer and a dark, ink layer. Each layer has the same figure patterns and the same crevices, the crevices being adapted to be filled with an adhesive material for bonding the two transparent glass substrates.Type: GrantFiled: October 26, 1992Date of Patent: December 6, 1994Inventor: Chii-Hsiung Lin
-
Patent number: 5350613Abstract: A safety windowpane and process of manufacture made of laminated glass. The windowpane includes two glasses made of annealed, hardened or quenched glass 1, 2 bonded to one another by an insert sheet of synthetic material 3 to the opposite faces of which the glasses are adhesively attached. The sheet includes in the material a line 4 of discontinuity in mechanical strength of relatively small width. The line defines an outline of preopening of a surface area such that after breaking of the glasses 1, 2 and rupture along the outline, it offers a sufficient passage for a human body.Type: GrantFiled: March 23, 1993Date of Patent: September 27, 1994Assignee: Vertal Nord EstInventors: Jean-Pierre Deprez, Christian de la Rochefoucauld
-
Patent number: 5348805Abstract: A solution of an organic compound of aluminum and tin or titanium is formed from, respectively, a nonhydrolyzable aluminum chelate and at least one organic compound of tin or a titanium chelate or alcoholate. The solution is then sprayed onto a heated glass substrate, thereby thermally decomposing and oxidizing the solution on the heated glass substrate to form, respectively, a layer of aluminum and tin or titanium oxides on the glass substrate. A semiconductive layer can be deposited upon the aluminum/tin or aluminum/titanium layer to form a coated glass structure which is useful for buildings or automobiles.Type: GrantFiled: February 5, 1993Date of Patent: September 20, 1994Assignee: Saint-Gobain Vitrage InternationalInventors: Georges Zagdoun, Bruno Cordier
-
Patent number: 5346770Abstract: A laminated glass structure is provided containing at least one glass sheet, a plastic layer provided at the bonding surface of the glass sheet, and a functioning layer having single-or multi-layered films between the bonding surfaces of the glass sheet and the plastic layer, with the functioning layer having a controlling layer in contact with the plastic layer, which contains as the major component an oxide including Cr and at least one of Ti, Zn, Sn, Ni, Zr, Al, Si, Mg and Fe, and wherein the controlling layer has an atomic ratio of Cr to atoms other than oxygen of 60% or lower, and the film thickness of the controlling layer is 10 .ANG. to 500 .ANG..Type: GrantFiled: October 12, 1993Date of Patent: September 13, 1994Assignee: Asahi Glass Company Ltd.Inventors: Koichi Osada, Eiichi Ando, Akira Mitsui
-
Patent number: 5336565Abstract: In an automotive window glass having a pair transparent sheet glasses that are stuck to each other with a transparent resin film, the inner surface of one of the pair of sheet glasses, which faces the transparent resin film, is coated with a heat-ray intercepting film that is composed of any one of the following chemical formulas whose atomic ratios are defined.(A) ZrN.sub.x O.sub.y : 0.5.ltoreq.x.ltoreq.0.8, and 0.8.ltoreq.x+y.ltoreq.1.2(B) TiN.sub.x O.sub.y : 0.2.ltoreq.y.ltoreq.0.8, and 1.4.ltoreq.x+y.ltoreq.1.8(C) CrN.sub.x O.sub.y : 0.1.ltoreq.y.ltoreq.0.8, and 1.4.ltoreq.x+y.ltoreq.1.Type: GrantFiled: July 13, 1993Date of Patent: August 9, 1994Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Takashi Muromachi, Jun Kawaguchi, Hidemi Nakai
-
Patent number: 5320893Abstract: A method of protecting a metal layer of a solar reflecting coating on a heat-shrinkable substrate, which are components of a prelaminate for a laminated window, from atmospheric corrosion. The prelaminate is cut partially through its thickness adjacent the edge and when the region of the cut is later exposed to elevated temperature, preferably during the laminating process forming the window, the substrate shrinks to create a channel into which flows plasticized polyvinyl butyral (PVB) to block the edge wall of the coating inward of the channel from the surrounding atmosphere.Type: GrantFiled: December 31, 1992Date of Patent: June 14, 1994Assignee: Monsanto CompanyInventor: Brett W. Floyd
-
Patent number: 5318830Abstract: The invention relates to a transparent coating on a transparent glass pane which may be a laminated glass pane such as an automobile windshield. The invention provides a two-layer coating made up of a first oxide film, e.g. a TiO.sub.2 -SiO.sub.2 mixed oxide film, which is in contact with the glass pane and has a thickness of 70-100 nm and a refractive index of 1.80-1.90 and an outer second oxide film, e.g. a SiO.sub.2 film, which has a thickness of 110-130 nm and a refractive index of 1.40-1.50. With respect to visible light obliquely incident on the coating side of the glass pane at an angle of 50-70 degrees with the normal, the reflectance of the coated glass pane becomes lower than that of the glass pane without coating by 4.5-6.5%. To reduce the reflectance of perpendicularly incident light the two-layer coating can be modified into a three-layer coating by interposing another oxide film, e.g. a TiO.sub.2 film, having a thickness of 130-160 nm and a refractive index of 2.05-2.Type: GrantFiled: April 23, 1992Date of Patent: June 7, 1994Assignee: Central Glass Company, LimitedInventors: Atsushi Takamatsu, Kensuke Makita
-
Patent number: 5308706Abstract: Disclosed herein is a heat reflecting sandwich plate made up of a first and a second transparent plates bonded together with a transparent resin film. The first transparent plate is coated on the inside thereof with a heat reflecting film which is a laminate composed of two metal oxide layers, with a noble metal layer intervening between them. The noble metal layer has a sheet resistance of 4-10 ohms/square. The first and second metal oxide layers have thicknesses controlled such that their ratio is in the range of 1.1 to 1.6. The heat reflecting sandwich plate produces reflected rays which have a chromaticness specified by -1.ltoreq.a.ltoreq.1 and -1.ltoreq.b.ltoreq.1, where a and b denote the chromaticness indices of Hunter's color specification system, and has a visible light reflectivity lower than 10%.Type: GrantFiled: January 15, 1993Date of Patent: May 3, 1994Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Jun Kawaguchi, Tatsuya Hyodo, Takaharu Miyazaki
-
Patent number: 5296296Abstract: Provided is a method for laminating PBZT/fusible sol-gel glass microcomposite film layers by applying an adhesive of fusible sol-gel glass to the bonding surfaces of such films and compressing the film layers and the so-formed adhesive layer therebetween, at sufficient temperature and pressure to laminate the film and adhesive layers together. The sol-gel glass infiltrant and adhesive may be of the same or different materials. Desirably, the bonding surfaces of such films are roughened before application of the adhesive layer therebetween. The invention also includes the laminates prepared by the above method which laminates exhibit good coherent bonding between layers, high tensile strength and good interlaminar strength between layers for fabrication into durable high-strength space-age structures.Type: GrantFiled: June 25, 1991Date of Patent: March 22, 1994Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: R. Ross Haghighat, Robert F. Koyar
-
Patent number: 5271994Abstract: An electrically heatable laminated glazing system is disclosed comprising two single glass panes (1,4) bonded together by a thermoplastic film of polyvinyl butyral (3). One of these two panes (1) bears a layered construction (2). The layered construction comprises a conducting silver layer (22), an anti-reflective cover layer (23) of zinc oxide disposed on the silver layer (22), and a bonding layer (24) utilized to improve a bond between the polyvinyl butyral film (3) and the anti-reflective covering layer (23). The bonding layer comprises one of the metals in groups IV, V, or VII of the periodic system or an oxide of these metals.Type: GrantFiled: December 7, 1990Date of Patent: December 21, 1993Assignee: Saint Gobain Vitrage InternationalInventor: Gunter Termath
-
Patent number: 5246764Abstract: A laminated glazing unit having improved impact strength comprising a), b) and c) in sequence: a) a glass layer; b) a plasticized layer containing partial polyvinyl butyral; c) another glass layer; and d) means, preferably a multiplicity of spaced projections, dispersed on the surface of at least one of the foregoing layers, preferably the plasticized layer, capable of resisting adhesion to the layer with which it is in contact, the area without said dispersed means (e.g. between projections) of the layer having such dispersed means having high affinity for adhesion to the layer with which it is in contact, such laminated glazing at a specific pummel adhesion having a greater mean break height than that of a laminated glazing containing layers a) b) and c) but without d). The dispersed means may be on the surface of a glass layer but is preferably on the plasticized layer.Type: GrantFiled: October 21, 1991Date of Patent: September 21, 1993Assignee: Monsanto CompanyInventors: Peter D. LaPorte, Robert H. M. Simon
-
Patent number: 5227241Abstract: The present invention relates to a laminated glass, more specifically to an airplane windshield. The present laminated glass offers excellent resistance to breakage, and particularly, to cleavage of the sheets of glass from plastic layer(s) laminated therewith.Type: GrantFiled: April 9, 1992Date of Patent: July 13, 1993Assignee: Saint-Gobain Vitrage InternationalInventors: Pierre Chaussade, Yves Naoumenko
-
Patent number: 5212014Abstract: A laminate comprising a sheet of polycarbonate laminated to another sheet comprising, on a weight basis, a) 30 to 90% polyvinyl butyral and b) 70 to 10% thermoplastic polyurethane, containing a plasticizing amount of one or more C.sub.2 -C.sub.5 alkanediols or diethylene glycol.Type: GrantFiled: November 8, 1991Date of Patent: May 18, 1993Assignee: Monsanto CompanyInventors: Donald J. David, Thomas F. Sincock
-
Patent number: 5208095Abstract: A glazing unit comprises a substrate ply and a laminating ply laminated to a surface of the substrate ply. A coating on a laminated surface of the substrate ply is a film stack comprising a film of electrically conductive material covered by a film of dielectric material. The film of dielectric material immediately adjacent the laminating ply comprises a layer of silicon dioxide immediately adjacent the laminating ply and a layer of dielectric material of refractive index greater than 1.5 between the silicon dioxide and the conductive material. Applications include, for example, glazing units for solar load reduction and electrically heated glazing units.Type: GrantFiled: August 28, 1991Date of Patent: May 4, 1993Assignee: Ford Motor CompanyInventor: Kenneth E. Nietering
-
Patent number: 5208080Abstract: A method is disclosed for producing superior optically clear laminates having a sheet of semi-rigid material encapsulated in a thermoplastic interlayer between layers of rigid material such as glass. Pre-cooled laminate elements are assembled at reduced temperature, allowing positioning of the sheet of semi-rigid material in the interlayer of the assembly with minimal wrinkling, formation of air bubbles or entrapment of moisture. Thereafter, the laminate assembly is maintained under vacuum for an extended period of time, substantially eliminating wrinkling, air bubbles and moisture from between the laminate elements as well as pre-forming the semi-rigid sheet. Bonding heat and pressure is then applied, first heating the assembly to "tack" the laminate elements together, and next applying heat and pressure for bonding the laminate elements.Type: GrantFiled: July 1, 1992Date of Patent: May 4, 1993Assignee: Ford Motor CompanyInventors: Kenneth J. Gajewski, John H. Meyer
-
Patent number: 5198304Abstract: A vertically adjustable composite motor vehicle side glazing, particularly a door window glazing, is made from composite glass including two 1.5 to 3.5 mm thick thermally tempered individual glazings with a thermoplastic intermediate layer. Each individual glazing has in the marginal area tensile stresses in the core, which in the case of a glazing thickness of 2 mm amount to 54 to 76 MN/m.sup.2 and for a glazing thickness of 3 mm amount to 46.7 to 71.2 MN/m.sup.2. In the central zone within the marginal area the individual glazings have tensile stresses in the core, which in the case of a glazing thickness of 2 mm amount to 38 to 67 MN/m.sup.2, while for a glazing thickness of 3 mm amount to 33 to 60 MN/m.sup.2. Such composite glazings have high strength in the marginal area and a low strength in the central zone. Therefore they have excellent characteristics both from the static standpoint and from that of accident safety.Type: GrantFiled: August 27, 1991Date of Patent: March 30, 1993Assignee: Saint-Gobain Vitrage InternationalInventors: Franz Kramling, Friedrich-Wilhelm Berndsen
-
Patent number: 5190826Abstract: An interlayer for use in sound-insulating laminated glasses which is in the form of a laminated film of two kinds of resin films (A) and (B), each comprising a polyvinyl acetal acetalized with an aldehyde having 6 to 10 carbon atoms for the film (A) or with an aldehyde having 1 to 4 carbon atoms for the film (B), or is in the form of a resin film (C) comprising a mixture of the two kinds of polyvinyl acetal resins. The interlayer mitigates the coincidence effect to prevent the reduction of TL value without impairing the basic characteristics required of laminated glasses thereby permitting the interlayer to exhibit outstanding sound-insulating properties over a wide temperature range for a prolonged period of time.Type: GrantFiled: May 13, 1991Date of Patent: March 2, 1993Assignee: Sekisui Chemical Co., Ltd.Inventors: Kenichi Asahina, Naoki Ueda, Hirofumi Omura
-
Patent number: 5183705Abstract: This invention provides a normally tacky pressure-sensitive adhesive composition comprising (1) a radial teleblock copolymer having at least three monoalkenyl arene polymer blocks and a branched elastomeric conjugated diene polymer block, (2) a tackifying resin, and (3) from about 5 to about 20 parts by weight extending oil per 100 parts by weight of radial copolymer. The copolymer preferably has a molecular weight of about 180,000 to about 250,000, as expressed in polystyrene equivalent molecular weight units. The monoalkenyl arene polymer blocks preferably comprise from about 17% to about 23% by weight of the total molecular weight of the copolymer. The preferred polymer for the monoalkenyl arene block is polystyrene; the preferred polymer for the elastomeric conjugated diene block is polyisoprene.Type: GrantFiled: February 28, 1992Date of Patent: February 2, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Ronald B. Birkholz, Mark D. Glad
-
Patent number: 5169694Abstract: A composite multilayer glass sheet for use as a window glass in a motor vehicle includes an outer glass layer facing outside the motor vehicle, an inner glass layer facing inside the motor vehicle, the inner glass layer extending parallel to the outer glass layer and being spaced from the outer glass layer with an air layer defined therebetween, and an nonreflective film disposed on a surface of at least the outer glass layer which faces the air layer. A resin film is applied to a surface of the inner glass layer for making the inner glass layer mechanically stronger.Type: GrantFiled: January 16, 1990Date of Patent: December 8, 1992Assignee: Nippon Sheet Glass Co., Ltd.Inventors: Masaaki Endo, Masao Mizutani
-
Patent number: 5162145Abstract: A glazing for motor vehicles is provided with at least one zone, in particular in the form of a filtering band attenuating the light radiation and the heat radiation in the upper area of the glazing. The filtering band is made with a transparent coating of a bakable enamel, which contains at least one nobel metal present in colloidal dispersion. The coating has a constant layer thickness, is applied by silk-screening and exhibits a geometrically exact screening on its entire surface. The degree of coverage of the screen is 85-95% in the area close to the edge.Type: GrantFiled: April 25, 1990Date of Patent: November 10, 1992Assignee: Saint-Gobain Vitrage InternationalInventor: Wolfgang Schaefer
-
Patent number: 5160782Abstract: A wired glass having a wire mesh formed of wires each comprising a core and a decorative coating of different color to the core. The decorative coating provides the wired glass with an attractive visual appearance.Type: GrantFiled: September 28, 1989Date of Patent: November 3, 1992Assignee: Miller Construction LimitedInventor: James A. A. Hickman