Abstract: Described are articles having a photochromic poly(meth)acrylic coating The coatings exhibit a Fischer microhardness of from 50 to 150 Newtons per mm2 and improved photochromic performance properties, i.e., the formation of darker activated colors and faster rates of photochromic activation and fade when irradiated with ultraviolet light.

Abstract: This invention comprises a method of refurbishing and removal of scratches from glass and a glass assembly which is resistant to scratches. The scratched glass is sanded to remove scratches and, after application of a bonding pumer and mounting of gasket a preheated acrylic is applied. After curing a polyvinyl sheet is applied to protect the acrylic. The process can be applied to “on board” repair of scratched glass on public vehicles.

Abstract: The present invention provides a porous titania, which has an anatase-form crystalline structure, an anatase-form crystallite diameter of 3 nm to 10 nm, a degree of anatase crystallinity of 60% or more, a BET specific surface area of 10 m2/g or more, a total pore volume of 0.05 cm3/g or more, and a volume for pores having a pore radius of 1 nm or more of 0.02 cm3/g or more, and the porous titania and the catalyst comprising the porous titania of the present invention exhibit an excellent catalytic activity for removal of nitrogen oxides, oxidation of organic substances, decomposition of dioxine compounds, as well as decomposition and removal of organic solvents, agricultural chemical and surfactant.

Abstract: An anti-fogging and anti-reflection optical article included a substrate, a first water-absorbing film provided on the substrate, a thin film of high refractive index provided on the first water-absorbing film, and a second water-absorbing film provided on the thin film of high refractive index. The first water-absorbing film contains a water-absorbing polymer and is provided on the substrate. The thin film of high refractive index includes a polycondensation product of a hydrolysate of a metal alkoxide, and the second water-absorbing film includes a water-absorbing polymer.

Abstract: A laminated glass comprising plural glass sheets and an interlayer interposed between the plural glass sheets, wherein the interlayer is an organic resin film having IR cutoff fine particles with diameters of at most 0.2 &mgr;m dispersed therein, the product of the solar transmittances of the respective glass sheets is from 0.3 to 0.6, and the content of the IR cutoff fine particles dispersed in the interlayer is from 0.1 to 0.5 parts by mass in relation to 100 parts by total mass of the interlayer.

Abstract: A laminar structure comprised of at least one layer of glass and a sheet of plasticized PVB containing an adhesion control agent is provided wherein delamination resulting from air being from air being dispersed or entrapped and dissolved in the PVB is controlled by use of a surface energy modifying agent, said surface energy modifying agent being selected to provide a total surface energy for the sheet of less than 52 dynes/cm.

Abstract: A transparent shock-absorbing laminate to be formed on a glass substrate for a display panel having a fracture strength such that it is fractured by a falling ball impact (drop height: 1.5 m; ball weight: 510 g) corresponding to 79,000 N, the transparent shock-absorbing laminate comprising a shatterproof layer having a shearing modulus of 2×108 Pa or more, at least two fracture-proof layers having a shearing modulus ranging from 1×104 to 2×108 Pa, each having different modulus, and a transparent pressure-sensitive adhesive layer.

Abstract: The aqueous dispersion of a peelable coating composition of the present invention is (a) a mixture containing 5-40% by weight of an emulsion of an acrylic copolymer having a glass transition temperature (hereinafter referred to as “Tg”) of not lower than 40° C., and 95-60% by weight of an emulsion of another acrylic copolymer having a Tg ranging from −20° C. through 5° C. The acrylic copolymer emulsion mixture (b) contains ethylenically unsaturated vinyl monomers having acid value in a total amount of 0.5-1.0% by weight, and (c) at least one of the acrylic copolymer emulsions is an acrylic copolymer which has been polymerized by use of a reactive surfactant, and (d) the particle size of the acrylic copolymer emulsions is not more than 200 nm.

Abstract: A process for adhering hydrophilic metal surfaces and rigid, thermosetting substrate compositions comprises contacting a hydrophilic metal surface with an adhesion promoter comprising an aqueous solution of zinc diacrylate, zinc dimethacrylate or a combination thereof and a carrier, drying the adhesion promoter solution to form an adhesion promoting layer, contacting the adhesion promoting layer with a curable thermosetting composition, and curing the thermosetting composition. The adhesion promoting solution contains from about 1.5 weight percent (wt. %) to about 20 wt. % of zinc diacrylate, zinc dimethacrylate or a combination thereof and from about 1 wt. % to about 20 wt. % of a carrier, preferably polyvinyl alcohol. Preferably the polyvinyl alcohol has a molecular weight of from about 7,000 to about 15,000 for maximum enhancement of the bonding. Quite unexpectedly, use of the aqueous adhesion promoting solution increased the peel strength (pli) by about 0.

Abstract: The invention provides a laminated glass and a method of producing the same. This laminated glass includes first and second transparent glass plates and an interlayer film interposed therebetween. This interlayer film has functional ultra-fine particles which have a particle diameter of up to 0.2 &mgr;m and are dispersed therein. Due to the incorporation of the ultra-fine particles thereinto, the interlayer film is provided with various additional functions such as heat insulation, ultraviolet ray absorption and the maintenance of a sufficient radio transmittance. Therefore, the laminated glass becomes suitable as an architectural or automotive laminated glass.

Abstract: A protective cover (13) for windscreens of vehicles comprises a single layer polypropylene base sheet (16) and an acrylate adhesive layer (18). The cover extends over the glazed windscreen and at least a portion of the surrounding frame. The film (13) serves to protect the windshield against damage during transport from factory to showroom and can be easily removed on arrival.

Abstract: The present invention relates to methods and compositions for the direct detection of analytes using observable spectral changes in biopolymeric systems. In particular, the present invention allows for the direct colorimetric detection of analytes using color changes that occur in glycopolythiophene polymer systems in response to selective binding of analytes.

Abstract: A process for adhering a layer of organic paint to the surface of a glass sheet, and the products produced thereby. The process comprises applying a layer of a water-based silicate paint to the surface of the glass sheet, heating to cure the paint, forming the glass sheet into a shape, sensitizing the water based paint with a layer of silane material, applying a layer of organic paint over the layer of sensitized water-based silicate paint, and curing the organic paint to provide organic paint adhered to the glass surface.

Abstract: A simple and effective method to bond a thin coating of poly(N-isopropylacylamide) (NIPAAm) on a glass surface by UV photopolymerization, and the use of such a coated surface in nano and micro technology applications. A silane coupling agent with a dithiocarbamate group is provided as a photosensitizer preferably, (N,N′-diethylamine) dithiocarbamoylpropyl-(trimethoxy) silane (DATMS). The thiocarbamate group of the sensitizer is then bonded to the glass surface by coupling the silane agent with the hydroxyl groups on the glass surface. The modified surface is then exposed to a solution of NIPAAm and a crosslinking agent which may be any organic molecule having an acrylamide group and at least two double bonds in its structure, such as N, N′-methylenebisacrylamide, and a polar solvent which may be any polar liquid which will dissolve the monomer and the crosslinking agent such as acetone, water, ethanol, or combinations thereof.

Abstract: The invention relates to a composite glazing material of the type including two sheets of glass and an interlayer of transparent plastic of greater thickness than the thickness of the sheets of glass, characterized in that the plastic is capable of adhering to the glass. The glazing material has a total thickness smaller than 5 mm, a ratio of the thickness of the interlayer to the thickness of the sheets of glass of between 1 and 10, a mass per unit area lower than 6 kg/m2 and a Young's modulus higher than 30 GPa at a total thickness of glazing material of 3 mm.

Abstract: The present inventions teaches an optically transparent film or sheet of an extruded acrylic copolymer or terpolymer and polyethylene having a melting point of less than 275° F. and a haze not more than 5%. The resin film can be used alone or in a lamination with other polymers or glass so that the combination has a haze less than 6%.

Abstract: Coatings are provided in which biopolymers may be covalently linked to a substrate. Such biopolymers include those that impart thromboresistance and/or biocompatibility to the substrate, which may be a medical device. Coatings disclosed herein include those that permit coating of a medical device in a single layer, including coatings that permit applying the single layer without a primer. Suitable biopolymers include heparin complexes, and linkage may be provided by a silane having isocyanate functionality.

Abstract: A glazing made of at least one glass layer and at least one transparent layer of ionomer resin, wherein at least a portion of one face of the at least one transparent layer of ionomer resin is adhered to at least a portion of one face of another layer of the glazing using at least one metal chelate, preferably a metal chelate based primer composition, and the primer composition for use in such a glazing are described, to provide laminated glazings which have improved chock resistance, good optical properties, improved resistance to lamination even during cutting operations, and is economical to produce.

Abstract: An electrical circuit board fluoropolymer substrate and method of manufacture thereof, comprising a fluoropolymer matrix that includes a mixture of a granular first fluoropolymer resin and a dispersion second fluoropolymer resin. Preferably, the first and second fluoropolymer is polytetrafluoroethylene (PTFE). This mixture is suitable for forming unfilled or filled casting compositions to form thick films, or for dip-coating glass webs.

Abstract: A method for producing visco-elastic fluidic material flows by drawing a visco-elastic fluidic material with corresponding separate second fluid flows associated therewith to form a visco-elastic fiber vacillating in a repeating, generally omega-shaped pattern having a bowed portion with first and second side portions that first converge toward each other and then diverge outwardly in generally opposing directions. In one operation, the visco-elastic fiber vacillating in the repeating, generally omega-shaped pattern is an adhesive material deposited onto woven and non-woven fabric substrates and stretched elongated elastic strands in the manufacture of a variety of bodily fluid absorbing hygienic articles.

Abstract: An improved plasticized polyvinyl chloride interlayer for laminated safety glass, and an improved method of manufacturing a laminated safety glass including such plasticized polyvinyl chloride containing film is disclosed. An improved functional silane adhesion promoter is utilized in such a manner so as to impact energy dissipation is maximized while structural integrity is maintained. The plasticized polyvinyl chloride interlayer is formulated so as to provide improved long term heat stability at service use temperatures.

Abstract: A polyolefin composite for a printed circuit board or antenna base material, a base material including the composite and electronic modules including the base material. The base material includes at least one dielectric layer including a polyolefin composite and at least one electroconductive layer including an electroconductive material, the dielectric and electroconductive layers being intimately bonded to one another.

Abstract: High clarity optical and safety glass laminate interlayer films and optical laminates are described. The films and their laminates comprise very low density polyethylene and/or its copolymers, preferably polymerized with metallocene catalysts, and modified with additives, such as coupling agents, clarifying or nucleation agents, UV-light absorbers, pigment or color concentrate, and IR-light blockers. The very low density polyethylene is laminated to EVA film for improved bondability in optical laminates.

Abstract: The present invention provides stain-inhibiting protection to glass surfaces of stacked glass sheets utilizing one or more water-soluble organic acid dispersed in a matrix of a water-soluble polymer or mixtures thereof. Suitable water-soluble organic acids may be found in the groups consisting of hydroxy mono, di, tri and tetra carboxylic acids. In the preferred form of the invention, components such as humectants, bactericidal and bacteriostatic agents and surface active (wetting) agents may be included in the composition.

Abstract: A method for imparting water, oil or stain repellency to HARD SURFACES comprising application to the surface of an effective amount of a composition comprising monomers copolymerized in the following percentages by weight:(a) from about 40% to about 90% of at least one monomer of formula I:R.sub.f --Q--A--C(O)--C(R).dbd.CH.sub.2 IwhereinR.sub.f is a straight or branched-chain perfluoroalkyl group of 2 to about 20 carbon atoms,R is H or CH.sub.3,A is O, S, or NR.sub.1 wherein R.sub.1 is H or a C.sub.1 -C.sub.4 alkyl, and Q is alkylene of 1 to about 15 carbon atoms, hydroxyalkylene of 3 to about 15 carbon atoms,--(C.sub.n H.sub.2n) (OC.sub.q H.sub.2q).sub.m --, --SO.sub.2 --NR.sub.1 (C.sub.n H.sub.2n)-- or --CONR.sub.1 (C.sub.n H.sub.2n)-- wherein R.sub.1 is H or C.sub.1 -C.sub.4 alkyl, n is 1 to about 15, q is 2 to about 4, and m is 1 to about 15;(b) from about 2% to about 50% of a monomer of formula IIA or IIB or a mixture thereof:(CH.sub.2 .dbd.C(R)COZ(CH.sub.2).sub.r.sup.+ NR.sub.2 R.sub.3 R.sub.4)X.sup.

Abstract: Smooth, patterned substrates useful in producing decorative cookware are formed by coating a base with a mixture of fluoropolymer and magnetic flakes and magnetically inducing an image in the polymer coating composition. The baked fluoropolymer release coating contains magnetizable flakes, a portion of the flakes being oriented in the plane of the substrate and a portion of said flakes being magnetically reoriented to form a pattern in the coating which is observed in reflected light, the flakes having a longest dimension which is greater than the thickness of said coating. The patterned substrate is formed by applying magnetic force through the edges of a magnetizable die positioned under a coated base to induce an imaging effect or pattern. The coating composition is then cured resulting in a smooth surface, patterned nonstick finish on the substrate.

Abstract: A sound insulating membrane and processes for forming, particularly well suited for use in floor, ceiling and wall constructions. The membrane comprises at least one backing layer in contact with a layer of nonfoam polymeric material. The polymeric material has an elongation factor of about 500% to about 900% and a Shore A hardness of from about 65 to about 80 points, 5 seconds. In a preferred embodiment, the polymeric material comprises 40-70% chlorinated polyethylene, 20-30% ethylene vinyl acetate, and up to 10% polyvinyl chloride. Floor, ceiling and wall constructions and related methods utilizing the sound insulating membranes are also disclosed.

Abstract: The invention pertains to a separation device which is to be temporarily inserted between two sheet products, in particular between two plates of glass, and which has differentiated adhesion with these two sheet products. The separation device is essentially made of a thermofusible material which has an ability to absorb shocks and an ability to obtain for one of its two sides, a controlled and desirable adhesion with the sheets to be separated.

Abstract: The invention relates to a soundproofing window in which an intermediate film provides for damping of vibrations transmitted in particular by structure-borne conduction.

Abstract: A frangible tear strip for toner cartridges used in electro-photographic copying devices, in which bursting strength is increased without making it more difficult for the user to longitudinally tear the strip to create an opening for passage of toner prior to use. This is accomplished by providing multiple areas of transverse reinforcement of the strip either by increased local area fusing of the material, or the lamination of transversely extending reinforcements at spaced intervals. In a preferred embodiment, the reenforcing material extends the entire axial length of the seal. In a further embodiment, the reinforcing material includes a layer of foam material having a rectangular opening overlapping a corresponding opening in a toner cartridge.

Abstract: A transparent material for shielding undesired electromagnetic waves, in which a black mesh region is formed in a hydrophilic transparent resin layer on a transparent substrate. The present invention thus provides a transparent material for shielding undesired electromagnetic waves, which comprises:(a) a transparent substrate,(b) a hydrophilic transparent resin layer formed on the transparent substrate (a), which in certain areas contains metal particles finely dispersed therein to form a black region and in the other area does not contain metal particles, to form a transparent region, and(c) a metal layer formed on the black region in the hydrophilic transparent resin layer (b);and a production method therefor.

Abstract: The invention relates to a water-repellent glass plate. This glass plate has a glass substrate having a major surface and a water-repellent film formed on the major surface of the glass substrate. The water-repellent film is prepared by an application of a water-repellent agent which is in a liquid form, to the major surface of the glass substrate, while the glass substrate is heated at a temperature of from 90 to 200.degree. C. The glass plate is superior in water repellency duration even under severe environment.

Abstract: A laminated safety glass is formed of an inboard glass sheet, an outboard glass sheet and a plasticized polyvinyl chloride containing interlayer therebetween. The outboard glass sheet has an average transmittance of radiation in the range of 300-340 nm of less than about 20%, and preferably less than about 1%. The outboard glass sheet also has an average transmittance of radiation in the range of 340 to 500 nm of more than about 50%. The outboard glass sheet may be formed of an ultraviolet radiation absorbing glass, such as an ultraviolet radiation absorbing green glass.

Abstract: A lipid bilayer with affinity to an analyte, which directly signals binding by a changes in the light absorption spectra. This novel assay means and method has special applications in the drug development and medical testing fields. Using a spectrometer, the system is easily automated, and a multiple well embodiment allows inexpensive screening and sequential testing. This invention also has applications in industry for feedstock and effluent monitoring.

Abstract: A coated abrasive sheet material comprising (a) a backing substrate having at least one major surface, (b) a plurality of abrasive grains, (c) a binder bonding said plurality of abrasive grains to said at least one major surface of the backing substrate, wherein the backing substrate comprises paper having a basis weight of less than about 200 g/m.sup.2 which is essentially free of latex saturants and has on said at least one major surface with the plurality of abrasive grains, one or more extruded layers of a thermoplastic polymer, and a method of making the coated abrasive sheet material.

Abstract: Optical and firescreening protective glazing laminates comprising fluoropolymer interlayer films are described. The films and their laminates comprise THV and blends of THV with FEP, ECTFE or ECCTFE, and modified with additives, such as coupling agents, pigment or color concentrates, and IR- or UV- light blockers, and may be subjected to a surface corona treatment. The films also may incorporate a fiber mesh for additional reinforcement.

Abstract: Copolymerizable benzophenone photoinitiators of the formula I ##STR1## wherein 1, k=0, 1, 2.R.sub.1 =divalent organic group having 1 to 25 carbon atoms;R.sub.2 =H or methyl; andR.sub.3, R.sub.4 =organic group having 1 to 25 carbon atoms.X, Y=hydrogen, halogen or (C.sub.1 -C.sub.25) groups containing N, S, and/or O;and method of making the photoinitiators.The photoinitiators overcome the leaching problem with prior photoinitiators in radiation curable polymer applications. Radiation curable polymers, cured polymers, and coated articles are also disclosed.

Abstract: A glazing made of at least one glass layer and at least one transparent layer of ionomer resin, wherein at least a portion of one face of the at least one transparent layer of ionomer resin is adhered to at least a portion of one face of another layer of the glazing using at least one metal chelate, preferably a metal chelate based primer composition, and the primer composition for use in such a glazing are described, to provide laminated glazings which have improved chock resistance, good optical properties, improved resistance to lamination even during cutting operations, and is economical to produce.

Abstract: This invention relates to a process for the preparation of an inorganic oxide gel comprising contacting at least one fluorinated inorganic oxide precursor with a fluorinated gelling agent in the presence of at least one fluorinated solvent to form a solution; allowing sufficient time for gelation to occur; and isolating the inorganic oxide gel. Gels made by this process are useful as coatings and as components in inorganic/organic hybrid materials.

Abstract: An improved method is provided for copolymerizing vinyl chloride with allyl glycidyl ether and a vinyl ester. The copolymers so formed include 70-99 weight % of vinyl chloride, 0.05-15 weight % of allyl glycidyl ether, and 0.05-15 weight % of a vinyl ester, preferably vinyl acetate. The copolymers of this invention can be compounded to provide films exhibiting improved heat stability, low haze, and good adhesion to solid surfaces such as glass and metal. The compounded resins thus obtained may be especially advantageously used in forming the interlayer of laminated safety glazings, such as vehicle windshields and architectural glazings.

Abstract: An article comprising substrate having a surface and a coating on the surface of the substrate, the coating comprising a fluoropolymer and a fluorochemical surfactant. The fluoropolymer and the fluorochemical surfactant are selected such that the article is anti-reflective, abrasion resistant and anti-fogging. Methods of making the same are also described.

Abstract: The invention provides a laminated glass and a method of producing the same. This laminated glass includes first and second transparent glass plates and an interlayer film interposed therebetween. This interlayer film has functional ultra-fine particles which have a particle diameter of up to 0.2 .mu.m and are dispersed therein. Due to the incorporation of the ultra-fine particles thereinto, the interlayer film is provided with various additional functions such as heat insulation, ultraviolet ray absorption and the maintenance of a sufficient radio transmittance. Therefore, the laminated glass becomes suitable as an architectural or automotive laminated glass.

Abstract: The present invention is directed to an anti-fogging coating that can be used for anti-fog applications. The coating is transparent, and comprises a hydroxyl group containing polymer, an aluminum containing crosslinker, and a surface active agent containing hydroxyl and/or siloxane groups. Additionally, the coatings possess a T.sub.fog of greater than about 30 minutes and a haze of less than about 5%, and can advantageously be used to provide to glass or plastic substrates an anti-fogging surface.

Abstract: The invention pertains to a separation device which is to be temporarily inserted between two sheet products, in particular between two plates of glass, and which has differentiated adhesion with these two sheet products. The separation device is essentially made of a thermofusible material which has an ability to absorb shocks and an ability to obtain for one of its two sides, a controlled and desirable adhesion with the sheets to be separated.

Abstract: A composite surface covering includes a substrate and an inorganic wear layer. The composite surface covering retains its performance characteristics after mechanical embossing. Preferably, the inorganic wear layer of the surface covering is deposited on the substrate by a reduced pressure environment vapor deposition technique. Preferably, the inorganic wear layer is aluminum oxide. The preferred substrate is a plastic material.

Abstract: The present inventions teaches an optically transparent film or sheet which is greater than or equal to 0.5 mm in thickness and includes an extrudable ionomer resin which comprises a carboxylic acid polymer and which is essentially free of amines. The ionomer resin film can be used alone or in a lamination with polycarbonate or glass. In certain embodiments, it is preferable to partially or fully neutralize the acid polymer with a metal cation.

Abstract: A light-reflecting and/or transmitting element for a motor vehicle light is provided. The light-reflecting or transmitting element is coated with a surface coating which includes a non-water soluble binder, selected from the group consisting of polyacrylic resins, polyester resins and mixtures thereof, which binder is internally cross-linked by methylol groups or externally cross-linked by amino resins, and from about 5% to about 60% by weight of at least one nonionic wetting agent.

Abstract: Laminated glass has sheets of plate glass with a bonding layer intervening therebetween for integration. The bonding layer is formed of a resin composition comprising (A) a terpolymer of ethylene, vinyl acetate, and an acrylate and/or methacrylate monomer, (B) a terpolymer of ethylene, vinyl acetate, and maleic acid and/or maleic anhydride, (C) a terpolymer of ethylene, an acrylate and/or methacrylate monomer, and maleic acid and/or maleic anhydride or (D) an ionomer resin in the form of an ethylene-methacrylic acid copolymer with a metal ion binding molecules thereof as a thermosetting resin, an organic peroxide, and a silane coupling agent. The resin composition is thermoset between the glass sheets.

Abstract: A method and material is disclosed for protecting glass surfaces in a stack of glass sheets by applying an interleaving material comprised of a high molecular weight polymer having a number average molecular weight of at least 200,000 to one or both major surfaces of the glass sheets. The glass sheets are then stacked in face-to-face relation for shipment or storage.

Abstract: A composite deposited film including (A) a polymeric film substrate; (B) a deposit of an inorganic material formed on at least one side of the polymeric film substrate (A); and (C) a water-resistant film laminated on the deposit (B) and formed from a mixture containing a polycarboxylic acid or a partially neutralized product thereof and a saccharide in a weight ratio of 95:5 to 20:80 is provided. A production process of a composite deposited film, which includes the steps of forming a deposit (B) of an inorganic material on at least one side of a polymeric film substrate (A); casting a solution of a mixture containing a polycarboxylic acid or a partially neutralized product thereof and a saccharide in a weight ratio of 95:5 to 20:80 on the deposit (B); drying the mixture to form a film; and then subjecting the resultant dry film to a heat treatment at a temperature not lower than 100.degree. C. (373 K), thereby forming a water-resistant film (C) on the deposit (B), is also provided.