Next To Addition Polymer From Unsaturated Monomers, Or Aldehyde Or Ketone Condensation Product Patents (Class 428/451)
  • Patent number: 5869185
    Abstract: A polycarbonate substrate coated with an acrylic coating containing at least one polybenzoylresorcinol, and optionally a silicone hardcoat on the acrylic coating, wherein said at least one polybenzoylresorcinol has the formula ##STR1## wherein each A is independently a substituted or unsubstituted monocyclic aromatic radical wherein any substituents are hydrogen, halogen, alkoxy, C.sub.1-8 alkyl, or hydroxy, and R is hydrogen or a linear or branched aliphatic radical having less that about 10 carbon atoms.
    Type: Grant
    Filed: June 21, 1996
    Date of Patent: February 9, 1999
    Assignee: General Electric Company
    Inventors: Steven Roger Bahr, James Edward Pickett, Karen Kueck Webb
  • Patent number: 5863650
    Abstract: An biologically compatible coating, enables an apparatus to which it is applied to resist to cell adhesion and/or protein adsorption. The coating comprises a polyacrylamide network grafted to a surface of the apparatus at polymerization sites on that surface and a poly(ethylene glycol) network interpenetrating the polyacrylamide network, and is prepared by sequentially polymerizing the polyacrylamide and poly(ethylene glycol) layers.
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: January 26, 1999
    Assignee: BioEngineered Materials, Inc.
    Inventors: Kevin E. Healy, Jane P. Bearinger
  • Patent number: 5858545
    Abstract: Free-radically polymerizable release coating compositions containing conductivity enhancers, which are capable of being electrosprayed onto a substrate. The compositions comprise (a) about 100 parts by weight of one or more free-radically polymerizable vinyl monomer(s), (b) from about 0.05 to about 250 parts by weight of one or more polydiorganosiloxane polymer(s) copolymerizable with the vinyl monomer(s), and (c) from about 0.10 to about 10 parts by weight, based on 100 parts by weight of (a) and (b), of one or more non-volatile conductivity enhancer(s), which are soluble in the monomer(s) and which do not interfere with polymerization, wherein the composition may be electrosprayed.The composition may further comprise from about 0.1 to about 5 parts by weight of one or more initiator(s) based on 100 parts by weight of monomer(s) and polydiorganosiloxane polymer(s).Another embodiment of the present invention further comprises at least 0.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: January 12, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Albert I. Everaerts, Mieczyslaw H. Mazurek, Albert E. Seaver
  • Patent number: 5858543
    Abstract: The present invention relates to the composition and preparation of composite films which exhibit low oxygen and flavor/aroma transmission rates. The film comprises a silane resin coated on a plastic substrate. The silane resin is formed from the mixture of a silane solution, an acrylate, a solvent, and optionally, either an additive, water or both. This invention teaches that a variety of silane solutions and acrylates may be mixed with different solvents to achieve the desired oxygen and flavor/aroma barrier characteristics.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: January 12, 1999
    Assignee: Dow Corning Corporation
    Inventors: Daniel Edward Futter, Ming-Hsiung Yeh
  • Patent number: 5858547
    Abstract: An improved method for forming planarization films which remain adhered to substrates upon exposure to heat comprising first applying a polymeric solution containing a low molecular weight novolac resin, a surfactant selected from the group consisting of a non-fluorinated hydrocarbon, a fluorinated hydrocarbon and combinations thereof, and an optional organic solvent to a substrate, followed by heating the substrate.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: January 12, 1999
    Assignee: AlliedSignal, Inc.
    Inventor: James Steven Drage
  • Patent number: 5856017
    Abstract: The present invention provides a gas barrier film including a plastic film and a thin film which is made of a composition containing an oxide as a main component and is formed on at least one surface of the plastic film. A specific gravity of the thin film is 55% or more and 100% or less of a specific gravity of the oxide in the form of a crystal generally present at room temperature and under atmospheric pressure. Thus, the invention provides a gas barrier film having an excellent gas barrier and retort properties and bending resistance; a gas barrier film suitably used in a wrapping material for dried food, liquid food or food containing liquids, frozen food and retort food; a gas barrier film that can be used in an electronic oven, can be sterilized by micro waves and can contain a free-oxygen absorber; a gas barrier film suitably used in a paper carton, a tube, a lid and the like; and a gas barrier film suitably used for cutting off gas for industrial use.
    Type: Grant
    Filed: July 18, 1997
    Date of Patent: January 5, 1999
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shusei Matsuda, Kiyoshi Iseki, Yoshiharu Morihara, Toru Kotani, Toshiyuki Oya, Toshio Uno, Teizo Harima, Hideomi Kobe, Yozo Yamada
  • Patent number: 5853862
    Abstract: At least one side of a base film is successively covered with an anchor coat layer comprising (A) a chlorine-containing resin e.g. a vinyl chloride-vinyl acetate copolymer, (B) a polyisocyanate compound and (C) a saturated polyester resin having glass transition temperature of -10.degree. C. to 20.degree. C. and being substantially unreactive to the polyisocyanate compound, and an inorganic layer such as a silicon oxide. The component (C) includes a noncrystalline saturated polyesters each having a hydroxyl value of 0 to 15 mg KOH/g or acid value of 0 to 10 mg KOH/g. The anchor coat layer may comprise about 10 to 500 parts by weight of the component (B) and 1 to 50 parts by weight of the component (C) relative to 100 parts by weight of the component (A). Such composite film inhibits deterioration of the adhesive properties and barrier properties even when exposed to severe conditions such as retort treatment.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: December 29, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Takaaki Murai, Ryuta Miyake
  • Patent number: 5851640
    Abstract: A sealable, transparent, biaxially oriented multilayer polypropylene film comprising a core layer, optionally one or more intermediate layers located on one or both sides of the core layer, and at least one top layer on the one or more intermediate layers or on one or both sides of the core layer, wherein the core layer contains a polypropylene polymer or a polypropylene mixture; the optional intermediate layers consist essentially of a polypropylene polymer or a polypropylene mixture; and wherein at least one top layer is sealable, comprises a polyolefin copolymer or terpolymer, has a thickness of .ltoreq.0.4 .mu.m, and does not contain silicon dioxide or polydimethylsiloxane. The film is suitable as a packaging or wrapping film.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: December 22, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Detlef Erich Schuhmann, Herbert Peiffer, Gunter Schloegl
  • Patent number: 5834125
    Abstract: An anti-reflection coating is provided that has a barrier layer and an anti-reflective layer. The barrier layer stops reactions between the anti-reflective layer and underlying layers or substrates, does not make the anti-reflective layer reflective, and preferably does not react with either the reflective layer or the anti-reflective layer. In particular embodiments, the barrier layer is a thin layer of silicon dioxide SiO.sub.2 or silicon nitride Si.sub.3 N.sub.4, and the anti-reflective layer is titanium-tungsten TiW, titanium nitride TiN, or amorphous silicon.
    Type: Grant
    Filed: June 16, 1993
    Date of Patent: November 10, 1998
    Assignee: Integrated Device Technology, Inc.
    Inventor: Chuen-Der Lien
  • Patent number: 5824421
    Abstract: Condensation-curable coating compositions are prepared from a mixture of and organic resin (A) and a flurosilicone (B). Water or an organic solvent may be used to provide a vehicle for application of the composition. The cured coatings of the invention exhibit superior water and oil repellency.
    Type: Grant
    Filed: October 30, 1996
    Date of Patent: October 20, 1998
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Hideki Kobayashi, Toru Masatomi
  • Patent number: 5820994
    Abstract: A laminate using a polymeric molded article as a substrate and having a light transparency, gas barrier properties and an excellent alkali resistance. The laminate is obtainable by carrying out a surface treatment to deposit an oxide of at least one metal selected from the metal elements of groups 2, 8, 9, 10 and 11 of the periodic table, and then forming a gas barrier layer such as oxides of silicon, nitrides of silicon and carbides of silicon on the treated surface. The gas barrier layer is not peeled off from the polymeric molded article even after being immersed in an alkali solution of pH 12 or more. The amount of the metal on the treated surface is preferably in the range of 5.times.10.sup.14 atoms/cm.sup.2 to 3.times.10.sup.16 atoms/cm.sup.2 in terms of the metal atoms per unit area. The practical performance of the laminate is not deteriorated during the patterning, by alkali etching, of a transparent conductive layer formed on the laminate.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: October 13, 1998
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yumi Gotoh, Takehiro Miyashita, Tomoyuki Okamura, Fumiharu Yamazaki, Shin Fukuda, Nobuhiro Fukuda, Yoko Tajiri, Noboru Kawasaki
  • Patent number: 5817376
    Abstract: Compositions containing conductivity enhancers, which are capable of being coated onto a substrate by means of electrostatic assistance. The compositions comprise one or more free-radically curable monomer(s), and one or more non-volatile conductivity enhancer(s), having cationic and anionic portions, which are soluble in the monomer(s) and which do not interfere with free-radical polymerization, wherein said anionic portion is a non-coordinating organophilic carbon-containing anion. The compositions may further comprise one or more initiator(s), one or more dissociation enhancing agent(s), cross-linking agent(s), cationically polymerizable monomer(s), cationic initiator(s), leveling agents, oligomer(s) or polymer(s), preferably co-reactive, and other additives or adjuvants to impart specific properties to the cured coating.
    Type: Grant
    Filed: March 26, 1996
    Date of Patent: October 6, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Albert I. Everaerts, William M. Lamanna, Albert E. Seaver, George V. Tiers
  • Patent number: 5807638
    Abstract: Provided herein is a waterproofing composition and a method for applying the same to the surface of a wall. The waterproofing composition is polymer-based and includes an improved solvent system containing heptane. Also provided is a wall having a surface coated with the waterproofing composition of the present invention.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: September 15, 1998
    Assignee: R.P.C., Inc.
    Inventor: Michael G. Roberts
  • Patent number: 5804300
    Abstract: In the production of a laminated packaging material formed of a laminate comprising a base film, a silicon oxide layer and a sealing medium layer, the sealing medium layer is formed by laminating a thermoplastic resin to the silicon oxide layer by extrusion coating in a thickness of 30 .mu.m or less. At this time, in addition to the thermoplastic resin layer formed by extrusion coating, an additional thermoplastic resin film may be laminated to its outside so that they are put together to form a layer serving as the sealing medium layer. In this case, lamination is carried out to extrude a thermoplastic resin between the silicon oxide layer and the thermoplastic resin film in a layer thickness of 30 .mu.m or less.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: September 8, 1998
    Assignee: Toppan Printing Co., Ltd.
    Inventors: Hideharu Maro, Hideki Kodaira, Hiroshi Iwase, Yuji Komiya
  • Patent number: 5804318
    Abstract: New and improved lubrifying coatings for reducing the coefficients of friction of surfaces on medical devices include hydrophilic copolymers derived monoethylenically-unsaturated monomers including some monomers having pendant primary amine functionality and some monomers having pendant tertiary amine functionality. The lubricious hydrogel coatings are covalently bondable to epoxy functionalized surfaces on the medical equipment to provide firmly adherent hydrogel coatings that are slippery when wet. Epoxy functionalized surfaces are provided by epoxy functional or epoxy group containing silane coupling agents. The pendant tertiary amine moieties are readily convertible at alkaline pH to quaternary ammonium cations to which anionic anti-thrombogenic agents may be bonded. Three dimensional copolymer matrices may also be provided as coatings on the surfaces by crosslinking the copolymers before or after attachment to the surface being treated.
    Type: Grant
    Filed: October 26, 1995
    Date of Patent: September 8, 1998
    Assignee: Corvita Corporation
    Inventors: Leonard Pinchuk, Yasushi P. Kato
  • Patent number: 5800926
    Abstract: A coating film having a refractive index of from 1.28 to 1.38 and a contact angle of water of from 90.degree. to 115.degree., adhered on a substrate surface, and prepared by reacting a particular tetraalkylsilicate, a particular fluorine-containing silicon compound, a particular hydroxy-containing compound, and oxalic acid in a particular range of ratios and in the absence of water, and under further specified reaction conditions.
    Type: Grant
    Filed: November 15, 1996
    Date of Patent: September 1, 1998
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Tatsuya Nogami, Takakazu Nakada, Rie Sakai, Takeshi Hosoya
  • Patent number: 5792812
    Abstract: A thermoplastic resin composition comprising 100 parts by weight of a thermoplastic resin and 2 to 12 parts by weight of a thermoplastic resin oligomer containing 0.1 to 35% by weight of an aliphatic unsaturated group is molded with silicone rubber to form an integrally molded part. The thermoplastic resin composition maintains the inherent properties of the thermoplastic resin and firmly bonds with silicone rubber.
    Type: Grant
    Filed: December 26, 1995
    Date of Patent: August 11, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Hironao Fujiki, Shigeki Shudo
  • Patent number: 5792554
    Abstract: Diblock (B-A) and triblock (B-A-B) polydiorganosiloxane-polyurea block copolymers comprise non-functional polydiorganosiloxane endblock B and polyurea block A. When used to provide release coatings, the block copolymers allow for easier release compared to traditional block copolymers of the (AB).sub.n type having comparable amounts of polydiorganosiloxane. Articles incorporating the copolymers as a release material are also disclosed.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: August 11, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Charles M. Leir, William R. Bronn, Patricia J. A. Brandt
  • Patent number: 5789082
    Abstract: A coating composition for eyeglasses and the like comprises a curable polymer precursor comprising a hydrolyzed epoxy-functional alkoxy silane and an imidazole curing agent therefor, a first colloid sol of a metal oxide colloid selected from the group consisting of the oxides of antimony, zirconium, cerium and tin, and optionally a second colloid sol of a metal oxide colloid different from the colloid of the first colloidal sol.
    Type: Grant
    Filed: March 12, 1997
    Date of Patent: August 4, 1998
    Assignee: The Walman Optical Company
    Inventor: Gerald D. Treadway
  • Patent number: 5783299
    Abstract: A polarizer plate including a polarizer substrate formed of a polarizer layer and supporting layers disposed on opposite surfaces of the polarizer layer; an undercoat layer disposed on one surface of the polarizer substrate; an anti-reflection layer disposed on the undercoat layer; and an anti-staining layer including a fluorine-containing silane compound disposed on said anti-reflection layer. The undercoat layer preferably has a specular glossiness according to JIS Z 8741 of from 10 to 40 and a haze according to JIS K 6900 of from 5 to 30%.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: July 21, 1998
    Assignee: Seiko Epson Corporation
    Inventors: Satoru Miyashita, Kogo Endo, Etsuo Okaue, Mikito Nakajima, Takao Mogami, Satoshi Kubota
  • Patent number: 5780148
    Abstract: The invention relates to a hydrophilic thin film and a method of manufacturing the same in which the hydrophilic thin film is formed by incorporating or fixing molecules comprising hydrophilic groups to a chemically adsorbed film on a substrate surface.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: July 14, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Tadashi Ohtake, Norihisa Mino, Kazufumi Ogawa
  • Patent number: 5776565
    Abstract: Hybrid sol-gel barrier coatings are produced by hydrolyzing a tetrafunctional alkoxide silicate and a silane having one or two pendant crosslinkable groups in water or water plus a water miscible organic solvent and a catalytic amount a protic acid, Lewis acid, or metal chelate, until a viscosity of from about 2,600 to about 3,200 cps is obtained. The product is then diluted water or water plus a water miscible organic solvent, optionally containing a protic acid, Lewis acid, or metal chelate, until a viscosity of about 0.5 to about 10 cps is obtained. The diluted product is blended with a photoinitiator, coated onto a substrate, dried and irradiated to obtain oxygen barrier films having a very low oxygen transmission rate.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: July 7, 1998
    Assignee: International Paper Company
    Inventors: Raymond A. Volpe, Paul C. Lucas
  • Patent number: 5773134
    Abstract: Proposed is a thermoplastic resin-based film suitable as a wrapping material having good slipperiness of the surface without decreasing the high transparency and having high resistance against formation of scratches. The resin film is molded from a thermoplastic resin composition comprising a thermoplastic resin such as polypropylene and polycarbonate as the matrix and a specified amount of fine silicone-based composite particles each consisting of a core particle of a silicone rubber having a specified particle diameter and a coating layer thereon in a specified coating amount formed from a polyorganosilsesquioxane such as polymethylsilsesquioxane.
    Type: Grant
    Filed: November 1, 1996
    Date of Patent: June 30, 1998
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Yoshinori Inokuchi, Satoshi Kuwata
  • Patent number: 5770301
    Abstract: At least one side of a polyester or other base film is successively covered with an inorganic layer composed of a silicon oxide or the like and a coating layer comprising a silane coupling agent and a barrier resin (e.g. vinylidene chloride-based copolymer, ethylene-vinyl alcohol copolymer) to provide a barrier composite film. The amount of the silane coupling agent is about 0.05 to 10 parts by weight relative to 100 parts by weight of the barrier resin. A heat-sealing layer is optionally formed on the surface of the barrier resin coating layer or on the other side of the base film. Such barrier composite film has excellent transparency and retains high barrier properties and adhesive properties of covering layer despite its thin covering layer.
    Type: Grant
    Filed: October 25, 1996
    Date of Patent: June 23, 1998
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Takaaki Murai, Ryuta Miyake
  • Patent number: 5770316
    Abstract: Heat-stable, flexible polarizers with a polarizing layer of a polymer with conjugated double bonds with the exception of exclusively polyacetylene-containing polymer matrixes are obtained if their surfaces are sealed with silicate.
    Type: Grant
    Filed: November 26, 1996
    Date of Patent: June 23, 1998
    Assignee: Bayer Aktiengesellschaft
    Inventor: Karl-Heinz Aleksander Ostoja Starzewski
  • Patent number: 5766739
    Abstract: A panel is composed of synthetic resins and coated with an antifogging layer, the panel having a plastics substrate formed as a board or film or molded into any desired shape. The panel further has a heat generating pattern as the antifogging layer formed on the substrate and composed of a conductive paste, and a hard coat covering the layer and mainly composed of a silicone resin. The conductive paste is composed of a resinous binder, a conductive agent and a solvent, and the binder is selected from a group consisting of (i) a saturated polyester, (ii) a mixture of the polyester and a polyvinyl chloride, (iii) a mixture of the polyester and a copolymer of vinyl chloride and vinyl acetate, and (iv) a mixture of the polyester, the polyvinyl chloride and the copolymer. The heat generating pattern layer protects the resin panel from fogging, and the hard coat enhances scratch resistance and weather resistance to the panel.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: June 16, 1998
    Assignees: Nippon Arc Co., Ltd., Tsutsunaka Plastic Industry Co., Ltd., Nippin Sheet Glass Co., Ltd.
    Inventors: Masaaki Funaki, Hiroyoshi Nanri
  • Patent number: 5766771
    Abstract: A method of producing a layer which is friction-reducing on an elastomeric substrate includes (a) providing an elastomeric substrate; (b) forming a sol by hydrolysis and condensation of at least one silane having a formula :R.sup.1 Si (OR').sub.3 (I)where R.sup.1 is one of a glycidyloxy-functional residue or a mercapto-functional residue and R' is a residue of a lower alkyl group having 1-4 carbon atoms; (c) coating the elastomeric substrate with the sol to form a coating; and (d) curing the coating to form a gel. The method is particularly suited for the coating of rubber surfaces, e.g., wiper blades.
    Type: Grant
    Filed: October 28, 1996
    Date of Patent: June 16, 1998
    Assignee: Robert Bosch GmbH
    Inventors: Wilfried Merkel, Wolfgang Leutsch, Volker Gerhard, Frank Gross, Helmut Schmidt
  • Patent number: 5763061
    Abstract: An antireflection filter comprising a film- or sheet-form transparent substrate, an antireflection coating on at least one surface of the substrate, which coating contains an inorganic compound, and a stain proofing layer on the antireflection coating, which layer contains a specific silane compound having an average molecular weight of 5.times.10.sup.2 to 1.times.10.sup.5.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: June 9, 1998
    Assignees: Sumitomo Chemical Company, Limited, Daikin Industires, Ltd.
    Inventors: Shinsuke Ochiai, Yukio Yasunori, Yuji Tanaka, Hitoharu Hachisuka
  • Patent number: 5763088
    Abstract: An olefin resin-based article having good gas barrier properties is disclosed, comprising an .alpha.,.beta.-ethylenically unsaturated carboxylic acid-grafted polyolefin (e.g., maleic anhydride-grafted polypropylene) having formed thereon an inorganic oxide deposite film, wherein the grafted polyolefin has an unsaturated carboxylic acid unit concentration of from 0.01 to 10% by weight, with or without an anchor coat being provided between the grafted polyolefin and the inorganic oxide film. The article suffers from no reduction in gas barrier properties even when heat or stress is applied thereto and is therefore useful as a wrapping or packaging material in the production of pouch-packed foods and IC packages.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: June 9, 1998
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Tomomi Nakano, Masayuki Egami, Masafumi Hattori, Akira Mizuno, Junji Mayumi
  • Patent number: 5759643
    Abstract: A polarizer plate including a polarizer substrate formed of a polarizer layer and supporting layers disposed on opposite surfaces of the polarizer layer; an undercoat layer disposed on one surface of the polarizer substrate; an anti-reflection layer disposed on the undercoat layer; and an anti-staining layer including a fluorine-containing silane compound disposed on said anti-reflection layer. The undercoat layer preferably has a specular glossiness according to JIS Z 8741 of from 10 to 40 and a haze according to JIS K 6900 of from 5 to 30%.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: June 2, 1998
    Assignee: Seiko Epson Corporation
    Inventors: Satoru Miyashita, Kogo Endo, Etsuo Okaue, Mikito Nakajima, Takao Mogami, Satoshi Kubota
  • Patent number: 5756153
    Abstract: A multilayered cling signage sheet for use in conventional printers, including laser printers. The sheet includes a first layer to provide structural integrity to the sheet. A second print receptive layer is adhered to one side of the first layer. A third layer which is a low modulus cling elastomer is adhered to the other side of the first layer. The cling elastomer is characterized in that it will releasably adhere to a substantially flat surface.
    Type: Grant
    Filed: February 6, 1997
    Date of Patent: May 26, 1998
    Assignee: Furon Company
    Inventor: Roger P. Plourde
  • Patent number: 5756200
    Abstract: The invention relates to a photographic support material with a backlayer and to a coating composition for producing this backlayer. The layer is distinguished by excellent writing properties with pencils and is free of contaminations by aged developing baths. It is composed of carboxylated acrylate copolymer, organic polyacid, coarse-grained silica, thickener and, preferably, colloidal aluminium-modified silica.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: May 26, 1998
    Assignee: Felix Schoeller jr. Foto- und Spezialpapiere GmbH & Co. KG
    Inventors: Rolf Ebisch, Hans-Ulrich Berner, Hans-Udo Tyrakowski
  • Patent number: 5753373
    Abstract: A coating composition which imparts anti-reflective and anti-fog properties to substrates coated therewith. The coating composition utilizes an inorganic metal oxide in combination with particular polyhydroxy surfactants. The coating compositions are particularly useful in the manufacture of disposable surgical masks and face shields.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: May 19, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Matthew T. Scholz, William L. Kausch
  • Patent number: 5753346
    Abstract: The invention provides a radiation curable release coating composition comprising:(a) about 1 to about 50 percent by weight of a cationically reactive polydiorganosiloxane liquid rubber having the following formula: ##STR1## wherein R are monovalent moieties which can be the same or different selected from the group consisting of alkyl, substituted alkyl, aryl, and substituted aryl wherein at least about 50% of the total number of silicon atoms have two methyl groups bonded thereto;E is an organic monovalent functional group comprising from about 1 to about 20 carbon atoms having at least one cationically co-reactive functional group;a and b both represent integers, wherein the sum of a plus b is an integer of about 10 to about 1200;b has a value ranging from about 0 to about 0.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: May 19, 1998
    Assignee: Minnesota Mining & Manufacturing Company
    Inventors: Charles M. Leir, William R. Berggren, William R. Bronn, David J. Kinning, Olester Benson, Jr.
  • Patent number: 5753374
    Abstract: A method for forming a cap on an electronic device to prevent inspection. First, a silica-containing ceramic is applied to the surface the electronic device to planarize the surface. Next, a silicon carbide coating is applied to the surface of the silica containing ceramic to form a hermetic barrier. A layer of porous silica-containing ceramic is then formed on the surface of the silicon carbide coating. Finally, the porous silica-containing ceramic is impregnated with an opaque material.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: May 19, 1998
    Assignee: Dow Corning Corporation
    Inventors: Robert Charles Camilletti, Loren Andrew Haluska, Keith Winton Michael
  • Patent number: 5747158
    Abstract: A lubricating film of the invention is comprised of a chemically adsorbed monomolecular film, in which long-chain molecules are chemically bonded to at least one surface of a substrate via siloxane bonding, and layers of chemically adsorbed monomolecular film are formed on the surface of the previously formed chemically adsorbed monomolecular film after changing the groups at the end of chemical admolecules to monofunctional groups. The lubricating film has excellent endurance against sliding, with lubrication and anti-abrasion properties, and such properties of the film can be maintained for a long period. A chemically adsorbed monomolecular film can be formed on a substrate surface via covalent bonding (SiO--) by the dehydrochlorination reaction between active hydrogens on the substrate surface and the silane-based chemical adsorbent comprising dimethylsilyl groups.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: May 5, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Norihisa Mino, Kazufumi Ogawa
  • Patent number: 5744243
    Abstract: Describes a composition for producing durable coatings and a process for preparing a single-layer broad band antireflective coating on solid substrates, such as glass, ceramics, metals, and organic polymeric materials. The coating composition comprises, in combination, acid catalyzed hydrolysis and condensation products of water-silane monomer mixture and a film forming amount of a polymer having functional groups selected from amino, hydroxy and carboxy, hydroxy and amino, amino and carboxy, and amino, hydroxy and carboxy. The described process comprises applying the aforesaid coating composition (or an acid catalyzed sol-gel coating composition) substantially free of preformed oxide sol and water soluble metal salt to the surface of a solid substrate, curing the applied coating, and treating the cured coating with an aqueous electrolyte solution for a time sufficient to produce a coating having graded porosity which is antireflective over a broad band of the visible spectrum.
    Type: Grant
    Filed: September 10, 1996
    Date of Patent: April 28, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Huawen Li, Alan E. Wang, Suryya K. Das
  • Patent number: 5742943
    Abstract: In accordance with the present invention, there is provided a flexible article, such as a surgeon's glove, displaying slip properties with respect to damp and dry mammalian tissue without use of powder lubricants. The article is comprised of a substrate layer having an elastomeric material, the layer having a wearer-contacting surface and a damp slip-conferring amount of a lubricant composition applied to the wearer-contacting surface. The lubricant composition is selected from the group consisting of a first composition and a second composition. The first composition comprises an acetylenic diol and at least one compound selected from the group consisting of an organo-modified silicone, an amino-modified silicone, and a cationic surfactant. The second composition comprises a cationic surfactant and at least one compound selected from the group consisting of an organo-modified silicone, an amino-modified silicone, and an acetylenic diol.
    Type: Grant
    Filed: August 19, 1996
    Date of Patent: April 28, 1998
    Assignee: Johnson & Johnson Medical, Inc.
    Inventor: Mao C. Chen
  • Patent number: 5738943
    Abstract: The water-loving properties of an anodized aluminum lithographic surface are enhanced or restored by treatment with a solution containing a monomeric, organo-phosphonic acid chelating compound or salt thereof. Such treatment can take place following, during or in lieu of the treatment of anodized aluminum in web form with an alkali metal silicate in the process of manufacturing printing plates. Alternatively, the treatment can be carried out as a plate is developed and/or prepared for the press. In a third approach, an organo-phosphonic acid chelating compound can be incorporated into a fountain solution, ink or correction fluid.
    Type: Grant
    Filed: January 8, 1997
    Date of Patent: April 14, 1998
    Assignee: Howard A. Fromson
    Inventors: Howard A. Fromson, Robert F. Gracia, Sean P. Evans, William J. Rozell
  • Patent number: 5736249
    Abstract: Articles of manufacture are provided with a low surface energy, permanently non-stick, non-fouling and ice-phobic surface by a system of coating comprising applying a primary coating having a surface energy of 22-28 dynes/cm.sup.2 comprising a novel polymeric material having non-stick and hardness properties and then applying a top coating having lower surface energy of from about 18-21 dynes/cm.sup.2 comprising a siliconic polymer and interdigitating means to make the top coating permanent, the means preferably comprising a bi- or polyfunctional organic compound adapted to wet the surface of the primary coating and chemically or physically bond thereto and to couple to the siliconic polymeric substance in the top coating. The coated substrates are resistant to marking by graffiti, to adherence by marine fouling organisms, and frozen ice on the surface is easily removed.
    Type: Grant
    Filed: August 16, 1994
    Date of Patent: April 7, 1998
    Assignee: Decora, Incorporated
    Inventors: John Ralph Smith, Nissim N. Garti
  • Patent number: 5736256
    Abstract: The water-loving properties of an anodized aluminum lithographic surface are enhanced or restored by treatment with a solution containing a monomeric, organo-phosphonic acid chelating compound or salt thereof. Such treatment can take place following, during or in lieu of the treatment of anodized aluminum in web form with an alkali metal silicate in the process of manufacturing printing plates. Alternatively, the treatment can be carried out as a plate is developed and/or prepared for the press. In a third approach, an organo-phosphonic acid chelating compound can be incorporated into a fountain solution, ink or correction fluid.
    Type: Grant
    Filed: May 23, 1996
    Date of Patent: April 7, 1998
    Assignee: Howard A. Fromson
    Inventors: Howard A. Fromson, Robert F. Gracia, Sean P. Evans, William J. Rozell
  • Patent number: 5736251
    Abstract: Lubricious silicone surface modifying treatments and/or coatings for modifying the frictional or slip surface characteristics of shaped elastomeric articles are provided in surface modifications including a coating or surface modifying composition comprising: ##STR1## wherein R is selected from unsubstituted and halogen-substituted aliphatic, cycloaliphatic, aromatic and alkyl aromatic groups having less than or equal to about ten carbon atoms, R.sup.1 is independently selected from hydrogen, hydroxyl, halogen, alkoxy and acyloxy groups, R.sup.2 is independently selected from hydrogen, alkyl and halogen-substituted alkyl groups, n is an integer of 1 to 3 inclusive, and m=3-n. The cured, highly crosslinked, three dimensional silicone coatings are effective at reducing the coefficient of friction of surfaces of shaped elastomeric articles, such as those frequently used in medical devices, by a factors of from about 50% to about 80% as compared with the same uncoated substrates.
    Type: Grant
    Filed: December 20, 1996
    Date of Patent: April 7, 1998
    Assignee: Corvita Corporation
    Inventor: Leonard Pinchuk
  • Patent number: 5733621
    Abstract: An adhesive roofing tape is based on a combination of brominated butyl rubber and EPDM. A non-diene block terpolymer is interspersed in the cross-linked polymer network. A plasticizer and tackifier are included to provide resiliency and permanent tack. An important aspect of the invention is to use a high molecular weight polyisobutylene plasticizer and a peroxide curing system. Rapid crosslinking without concomitant rapid degradation of the brominated butyl rubber occurs and some limited degradation of the plasticizer contributes to surface tack. A method of making the adhesive roofing tape is also provided.
    Type: Grant
    Filed: March 20, 1997
    Date of Patent: March 31, 1998
    Assignee: Carlisle Companies Incorporated
    Inventors: Daniel John Cotsakis, Ronald Lynn Senderling, Nicholas John Shears
  • Patent number: 5731092
    Abstract: A material useful for manufacturing food packagings is formed from a film covered with silicon oxide and a polyolefin film, such that the binder arranged between the film covered with silicon oxide and the polyolefin film is selected from the group consisting of polyolefins grafted with unsaturated alkoxysilanes, polyolefins grafted with unsaturated epoxides, and copolymers of ethylene with at least one unsaturated epoxide.
    Type: Grant
    Filed: February 27, 1996
    Date of Patent: March 24, 1998
    Assignee: Elf Atochem S.A.
    Inventors: Patrice Breant, Philippe Tordjeman
  • Patent number: 5731087
    Abstract: Lubricious coatings comprising a binder polymer having a vinyl moiety and a carboxylic acid moiety and a hydrophilic polymer are disclosed. The coatings can be applied to a variety of substrates such as, for example, catheters, stents, dilatation balloons, guide wires, endotracheal tubes, instruments, implants and other biomedical devices and can provide exceptional lubricity and abrasion resistance. Processes for applying the lubricious coatings in either one or two coating steps are also disclosed.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 24, 1998
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: You Ling Fan, Lawrence Marlin, Lisa M. Bouldin, Isabel Maria Marino
  • Patent number: 5725960
    Abstract: A molded article having an adhesion of at least 50 squares per 100 squares in crosscut adhesion test and at least 40 squares per 100 squares even after kept in a warm water of 70.degree. C. for 1 hour, a haze value of 1.0% or less in Taber abrasion test and a pencil hardness of 2H or higher, said molded article being obtained by modifying the surface of a substrate formed of a thermoplastic norbornene resin to have a surface tension of 50 dynes/cm or greater by a treatment such as corona discharge treatment or the like or forming a preliminary primer layer of a modified product obtained by introducing a polar group into a copolymer of a vinyl aromatic compound and a conjugated diene, or the like; forming a primer layer for silicone hard coating agent on the modified surface or the preliminary primer layer, and then forming thereon a silicone hard coat layer, and a method for producing the molded article.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 10, 1998
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yuichiro Konishi, Tohru Hosaka, Mitsushi Tada, Tadao Natsuume, Nobukazu Takahashi, Teiji Kohara
  • Patent number: 5725958
    Abstract: The present invention provides a gas barrier film including a plastic film and a thin film which is made of a composition containing an oxide as a main component and is formed on at least one surface of the plastic film. A specific gravity of the thin film is 55% or more and 100% or less of a specific gravity of the oxide in the form of a crystal generally present at room temperature and under atmospheric pressure. Thus, the invention provides a gas barrier film having an excellent gas barrier and retort properties and bending resistance; a gas barrier film suitably used in a wrapping material for dried food, liquid food or food containing liquids, frozen food and retort food; a gas barrier film that can be used in an electronic oven, can be sterilized by micro waves end can contain a free-oxygen absorber; a gas barrier film suitably used in a paper carton, a tube, a lid and the like; and a gas barrier film suitably used for cutting off gas for industrial use.
    Type: Grant
    Filed: February 2, 1996
    Date of Patent: March 10, 1998
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Shusei Matsuda, Kiyoshi Iseki, Yoshiharu Morihara, Toru Kotani, Toshiyuki Oya, Toshio Uno, Teizo Harima, Hideomi Kobe, Yozo Yamada
  • Patent number: 5725959
    Abstract: An antireflection film is procided on a plastic optical element as follows. An undercoat composed principally of unsaturated silicon exide SiO.sub.x (2>x>1) with a thickness within a range of 200 to 300 nm is formed on the optical element. A multi-layered film of a repeating structure is formed on the undercoat. The multi-layerd film has antireflective characteristics. The undercoat has a refractive index within a range of 1.49 to 1.59. The multi-layered film is composed of alternate lamination of a layer of a material which has a high refractive index and which is composed principally of TiO.sub.2, ZrO.sub.2 or a mixture thereof, and a layer of a material which has a low refractive index and which is composed principally of SiO.sub.x (2.gtoreq.x.gtoreq.1).
    Type: Grant
    Filed: November 22, 1996
    Date of Patent: March 10, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Junji Terada, Makoto Kameyama, Junichi Sakamoto
  • Patent number: 5723214
    Abstract: A paper feed roll is formed of a rubber composition comprising (A) a composite material having a low molecular weight material retained in a medium material and (B) a rubber material. The low molecular weight material has a viscosity of up to 5.times.10.sup.5 centipoise at 100.degree. C. The difference in solubility parameter between the low molecular weight material and the medium material is up to 3.0. The weight ratio of the low molecular weight material to the medium material is at least 1.0. The difference in solubility parameter between the low molecular weight material and the rubber material is up to 4.0. A paper feed apparatus comprising the paper feed roll is also provided.
    Type: Grant
    Filed: May 17, 1995
    Date of Patent: March 3, 1998
    Assignee: Bridgestone Corporation
    Inventors: Hirotaka Yamazaki, Yasushi Imai, Shinichi Toyosawa, Yoshihide Fukahori
  • Patent number: 5721027
    Abstract: A package possessing superior tightness properties against gases, in particular oxygen gas, for the distribution of goods. The package, which, for example, may be a plastic bottle, has a coating applied on the outer walls of the package, the coating comprising a silicon oxide compound of the general chemical formula SiO.sub.x, where x may vary from 1.8 to 2.2. The silicon oxide coating is deposited on the package walls by vacuum deposition, preferably chemical plasma vapor deposition (CPVD), by means of which the coating is deposited in the form of a very thin but nevertheless extremely tight continuous coating of a thickness of less than 2000 .ANG.. After one occasion of use, the package may be cleaned using conventional washing and rinsing solutions which efficiently remove the preceding coating, whereafter the package is provided with a new coating prior to a new product filling.
    Type: Grant
    Filed: October 24, 1996
    Date of Patent: February 24, 1998
    Assignee: Tetra Laval Holdings & Finance S.A.
    Inventors: Peter Frisk, Bertrand Jaccoud, Anne Roulin, Hans Johansson