Abstract: The invention relates to a transparent substrate coated on at least one of its faces with a polymer layer deposited under vacuum. This polymer layer is provided with an adhesion prelayer of organic or organoinorganic nature. The invention also relates to the process for manufacturing such a coated substrate and to its applications.

Abstract: A device or an enclosed area that can cause or is sensitive to electromagnetic interference (EMI) is shielded by at least partially surrounding the device or the area with a visible light-transmissive film comprising a flexible support, an extensible visible light-transmissive metal or metal alloy layer and a visible light-transmissive crosslinked polymeric protective layer, and connecting at least one grounding electrode to the metal or metal alloy layer. The film has reduced susceptibility to fracture or corrosion compared to commercially available EMI shielding films.

Abstract: The present invention relates to the use, in a pre-coating process, of a flash plating, without a subsequent chromate seal, as a surface pre-treatment for a ferrous-alloy substrate prior to applying a corrosion-inhibiting coating to improve the overall corrosion protection of the pre-treatment component. Preferably the ferrous alloy is a heat-treatable, precipitation-hardenable stainless steel and the pre-treatement is a cadmium flash plate or a zinc-nickel alloy flash plate.

Abstract: The invention relates to a metal substrate with a corrosion-proofing bond coating containing adhesion-conferring polymers, based on organic compounds, as well as a method for applying the bond coating. The metal substrate may be that of a vehicle body. The bond coating contains polybismaleimides as the adhesion-conferring polymers, which may be homopolymers or copolymers of bismaleimides and/or maleimide-terminated oligomers or polymers, which can be copolymers of these compounds and organic compounds with polymerizable functional groups. The bond coating is applied as a solution, emulsion, or dispersion, and fixed by heating or irradiation.

Abstract: The invention relates to a radiation curable powder paint binder composition comprising a radiation curable compound being a mono or multi valent carboxylic ester of a &bgr;, &ggr;, &dgr;, or &egr;-hydroxyalkylamide group containing compound, in which the carboxylic ester is derived from an &agr;, &bgr;-ethylenically unsaturated carboxylic acid.

Abstract: The present invention relates to an electrodepositable coating composition having a resinous phase dispersed in an aqueous medium. The resinous phase includes (a) an ungelled, active hydrogen-containing, ionic salt group-containing resin; and (b) a curing agent reactive with the active hydrogens of the resin (a). The resinous phase has a covalently bonded halogen content based on total weight of resin solids present in the resinous phase such that when the composition is electrodeposited and cured, the cured film passes flame resistance testing in accordance with IPC-TM-650, and has a dielectric constant of less than or equal to 3.50. The invention also is directed to a method for forming a dielectric coating on an electroconductive substrate using the electrodepositable coating composition, as well as to a substrate coated with the electrodepositable composition.

Abstract: Electrical steel sheet can be produced by baking at low temperatures and is capable of stress relief annealing and has excellent solvent resistance and has an insulating coating containing substantially no chromium components harmful to environment; the electrical steel sheet has an insulating coating comprising a resin and an inorganic colloid which is silica, alumina or alumina-containing silica.

Abstract: Pyrimidine-based crosslinking agents for thermally curable compositions, especially thermally curing coating materials, adhesive, sealing compounds or compounds for producing moldings.

Abstract: The present invention provides a crosslinking agent which may have reactive benzoxazine groups prepared from (a) at least one aromatic compound, (b) at least one aminotriazine compound, and (c) at least one other compound having active hydrogen groups reactive with aminoplast compound (b). The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent, and a curable powder coating composition comprising a mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups having a glass transition temperature of at least 30° C.; and (B) the above crosslinking agent. Multilayer composite coating compositions are also provided including a basecoat deposited from a film-forming composition and a topcoat over the basecoat, deposited from the curable powder coating composition described above.

Abstract: Disclosed are a curable polyphenylene ether (PPE) resin composition comprising (a) a PPE resin and (b) a of a compound having a 3,4-dihydro-3-substituted-1,3-benzoxazine skeleton (DSBS compound), or a mixture of the DSBS compound and a ring-opening polymerization re-action product thereof; a cured PPE resin composition obtainable by curing the curable PPE resin composition; and a laminate structure obtained by using the curable or cured PPE resin composition. The curable PPE resin composition exhibits, after cured, excellent chemical resistance, moisture resistance, dielectric characteristics, heat resistance, flame retardancy and dimensional stability, so that it can be used as a dielectric, insulating or heat resistant material in the electrical, electronic, space and aircraft industries.

Abstract: Aqueous, lead-free cathodically depositable (CDL) coating compositions containing binders and, optionally, crosslinking agents, pigments, and/or additives conventionally employed in lacquers, as well as one or more sulfonic acid salts of the metals vanadium, manganese, iron, zinc, zirconium, silver, tin, lanthanum, cerium and/or bismuth and/or of organometallic compounds in a total amount of from 0.2 to 2 wt. %, calculated as metal and based on the resin solids.

Abstract: The present invention provides a crosslinking agent having reactive benzoxazine groups which is the ungelled reaction product of (a) at least one mono-hydroxy aromatic compound and (b) at least one aminotriazine compound having one or less non-alkylated NH group present in a molar ratio of reactant (a) to reactant (b) ranging from 1.0 to 3.0: 1.0, provided that where reactant (a) is a single ring monohydroxy aromatic compound, the molar ratio of reactant (a) to reactant (b) ranges from 1.0 to 1.8:1.0 and from 2.2 to 3.0:1.0. The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent.

Abstract: The invention relates to a laminate including a decorative layer, a first resin impregnated core layer, a radiation barrier layer and a second resin impregnated core layer. The laminate prevents the penetration of radiation therethrough and maybe used in the construction of ceiling and wall panels, flooring, furniture, fixtures, cabinet and door cladding, protective screens and other objects which will effectively prevent the passage of radiation from an isolated enclosure.

Abstract: A spacemesh structure for shoe making includes an upper mesh-texture layer, a lower mesh-texture layer and a reinforced structure in between. The reinforced structure comprises a plurality of supporting lumps arranged as a two dimensional array with gaps between two supporting lumps. A plurality of girders are disposed in the gaps in one direction leaving some gaps between every two adjacent lumps located between two adjacent girders.

Abstract: The present invention relates to a coating composition containing 8 to 130 parts by weight of (B) silica fine particles having an oil absorption in the range of 30 to 200 ml/100 g and a pore volume in the range of 0.05 to 1.2 ml/g per 100 parts by weight of (A) a coating film-forming resin, a cured coating film formed from the coating composition having a glass transition temperature in the range of 40 to 125° C.; and a coated metal plate having a coating film formed from the above coating composition on the surface of a metal plate.

Abstract: A primer or coating composition that includes (A) an aqueous dispersion of a phenolic resin that includes water and a reaction product of a phenolic resin precursor, a modifying agent and, optionally, a multi-hydroxy phenolic compound wherein the modifying agent includes at least one functional moiety that enables the modifying agent to react with the phenolic resin precursor and at least one ionic moiety, and (B) a flexibilizer. According to one embodiment the modifying agent is an aromatic compound. According to another embodiment the ionic moiety of the modifying agent is sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the dispersed phenolic resin reaction product has a carbon/sulfur atom ratio of 20:1 to 200:1.

Abstract: A reflective insulation system. The reflective insulation system includes a reflective layer such as aluminum, a layer of fiberglass, and a layer of vapor retarding material. A first side of the layer of fiberglass is bonded to the reflective layer by a deposit of hot melt glue. The second side of the layer of fiberglass is bonded to the layer of vapor retarding material by a second deposit of hot melt glue. The vapor retarding layer may be a plastic material, such as polypropylene or a reflective material, such as aluminum.

Abstract: The invention relates to the bonding of a phenolic resin impregnated core and a metal sheet into a high pressure laminate. A binding layer of a styrene-maleic anhydride copolymer is positioned between the core and the metal sheet to ensure bonding of the layers when a lay-up containing the desired layers is heated and pressed.

Abstract: A magnetically active laminate is disclosed. The magnetically active laminate is composed of a resin impregnated layer bonded to a distinct, magnetically active sheet. The laminate is especially well suited for use in the construction of erasable markerboards and cubicle panels, although many applications are possible within the scope of the present invention.

Abstract: To provide a retroreflective sheet which is suitable for co-molding by injection molding or the like, wherein the retroreflective sheet can be laid within a mold and molded with a resin to form a molded product, and, after molding, the sheet retains a significant portion of its reflection luminance and appearance as compared with the reflection luminance value before molding. A retroreflective sheet used for a co-molding, comprising a metallic reflective layer, a microspherical lens layer disposed as a single layer, and a transparent focal resin layer disposed between the reflective layer and the microspherical lens layer, in which the focal resin layer comprises a mixture of cellulose ester and polyvinyl butyral resin.

Abstract: In a single-sided paper phenolic resin copper-clad laminate composed of a phenolic resin impregnated paper base having copper foils laminated on and resists applied on the face side thereof, resists formed of the same material as the resists on the face side are applied also on the reverse side of the phenolic resin impregnated paper base, so that the face side and the reverse side match approximately with each other in thermal expansibility. The single-sided paper phenolic resin copper-clad laminate warps only slightly even when the peak temperature is raised to a degree suitable for lead-free solder in the reflow process for mounting electronic components.

Abstract: A magnetically active laminate is disclosed. The magnetically active laminate is composed of a resin impregnated layer bonded to a distinct, magnetically active sheet. The laminate is especially well suited for use in the construction of erasable markerboards and cubicle panels, although many applications are possible within the scope of the present invention.

Abstract: An aluminum-alloy article such as a fastener is prepared by providing an aluminum-alloy article precursor that is not in its final heat-treated state, and in one form is in its solution treated/annealed state. A curable organic coating material is also provided. The method includes anodizing the article precursor, preferably in chromic acid solution and without chemical sealing during anodizing, applying the organic coating material to the aluminum-alloy article precursor, and precipitation heat-treating the coated aluminum article precursor to its final heat-treated state, thereby simultaneously curing the organic coating. If the aluminum alloy temper is of the naturally aging type, it is optionally lightly deformed prior to precipitation treatment aging.

Abstract: Disclosed are compositions of matter which include a thin metallic and/or metallic oxide, nitride, carbide, silicide, boride, or sulfide coating disposed directly upon a polymeric substrate, in the absence of a carrier layer for the thin coating. Also disclosed are methods to make the composition and an apparatus to practice the method.

Abstract: Coated metal bearing a coating on its surface that comprises phenol-, naphthol-, or bisphenol-formaldehyde resin comprising specific structural units, has a thickness from 5 to 500 nm, contains from 5 to 500 mg of carbon atoms present in the resin per m2 of surface coated, and covers at least 90% of the surface of the metal can be subjected to film lamination onto the coating to provide a composite that has an excellent formability, excellent corrosion resistance, excellent adherence between the laminated film and the metal, and excellent environmental safety.

Abstract: A process for forming a planarization film on a substrate that does not smoke or fume on heating includes applying a polymeric solution including a novolac resin having a weight average molecular weight between about 1000 and 3000 amu, which has been fractionated to remove molecules with molecular weight below about 350 amu, a surfactant selected from a group consisting of a non-fluorinated hydrocarbon, a fluorinated hydrocarbon and combinations thereof, and an optional organic solvent to a substrate, followed by heating the substrate.

Abstract: The present invention concerns a multilayered polymer film structure, which comprises at least one first layer (1) containing a thermoplastic polymer and at least one second layer (2), arranged adjacent to said first layer, containing a liquid crystalline polymer. According to the invention, the second layer (2) consists essentially of a compounded polymer blend formed by the liquid crystalline polymer and a thermoplastic polymer, the liquid crystalline polymer of the second layer forms a continuous phase, and the first and the second layers (1, 2) contain the same thermoplastic polymer. The oxygen transmission rate of the second layer is less than about 150 cm3/(m2·d·bar), determined according to the standard ASTM D 3985-81, and the water vapour transmission rate of the integral film structure is less than 10 g/(m2·24·h) at RH 80% 23° C., determined according to ASTM F 1249-90. The present structure can be used as a barrier layer in packages.

Abstract: To provide a retroreflective sheet which is suitable for co-molding by injection molding or the like, wherein the retroreflective sheet can be laid within a mold and molded with a resin to form a molded product, and, after molding, the sheet retains a significant portion of its reflection luminance and appearance as compared with the reflection luminance value before molding.

Abstract: Disclosed is a method for the preparation of a polymer-metal cluster composite material having usefulness as a non-linear optical material or high-modulus material. The method comprises bringing a polymeric resin into contact with vapor of a heavy metal compound such as an acetylacetonato complex compound of palladium, platinum or copper under a non-oxidizing atmosphere at a temperature higher than the glass transition temperature of the polymeric resin so that the metal compound vapor is dissolved into the polymeric resin in a glassy state and is in situ reduced into the form of an elementary metal forming clusters of the metal particles.

Abstract: A low-loss, diffuser film is provided for translucent surface(s) of lighted signage. The film has little absorptivity and has partial transmissivity and partial reflectivity. Luminance efficiency and brightness are significantly improved over conventional films used in backlit signage. A luminance efficiency prediction equation is also provided to aid in selection of diffuser films and interior surfaces of the lighted sign cavity. A combination of effects of diffuser films and a diffuse reflective films lining the interior surfaces of the lighted sign cavity is unexpectedly greater than their sum of effects operating alone.

Abstract: Olefin/CO linear alternating copolymers which are useful in hot melt adhesive applications are disclosed. The linear alternating copolymers have melting points ranging from 50 to 165° C. and exhibit a combination of properties which are desired for hot melt adhesives. Single olefins or combinations of olefins ranging from ethylene to C12 olefins can be used to form the linear alternating copolymer.

Abstract: A composite sheet including a first polymer layer laminated to the first major surface of a ferromagnetic substrate having opposing first and second major surfaces. A second polymer layer is laminated to the second major surface of the substrate, sandwiching the substrate between the first and second polymer layers. The substrate is preferably steel having a thickness preferably between about 1 to 3 mils. A significant advantage of the composite sheet is the increase in the utility of the composite sheet due to the composite structure.

Abstract: To provide a retroreflective sheet which is suitable for co-molding by injection molding or the like, wherein the retroreflective sheet can be laid within a mold and molded with a resin to form a molded product, and, after molding, the sheet retains a significant portion of its reflection luminance and appearance as compared with the reflection luminance value before molding. A retroreflective sheet used for a co-molding, comprising a metallic reflective layer, a microspherical lens layer disposed as a single layer, and a transparent focal resin layer disposed between the reflective layer and the microspherical lens layer, in which the focal resin layer comprises a mixture of cellulose ester and polyvinyl butyral resin.

Abstract: This invention provides a paint composition which comprises a film-forming resin component comprising from 65 to 95 parts by weight of a hydroxyl-containing polyester resin (A) having a number average molecular weight of from 1,500 to 35,000, a glass transition temperature of from −30° C. to 60° C. and a hydroxyl value of from 3 to 100 mg KOH/g; and 5-35 parts by weight of a melamine resin crosslinking agent (B) which is a methylolated melamine resin whose methylol groups are alkyl etherified, at least 20% of the total number of methylol groups therein having been etherified with a C6-C12 alkyl group; and (C) 0.1 to 2.0 parts by weight, per 100 parts by weight of the total resin component, of a curing catalyst. The paint composition excels in popping resistance, and can form paint film of favorable hardness, formability, curability (solvent resistance) and adhesion.

Abstract: The invention pertains to compositions which can be coated onto substrates. These compositions include a combination of a resin blend comprising a first polyester resin and a second polyester resin, wherein the first polyester is different from the second polyester, an aminoplast crosslinking resin, an acid catalyst, and a urea-aldehyde resin. Films prepared from coating compositions made in accordance with the present invention having improved stain resistance. In many instances, films prepared from coating compositions made in accordance with the present invention not only have improved stain resistance, but also have low temperature flexibility.

Abstract: An aqueous phenolic resin dispersion that includes an aqueous continuous phase and, dispersed within the aqueous phase, the reaction product of a phenolic resin precursor and a modifying agent wherein the modifying agent includes at least one ionic group and at least one functional moiety that enables the modifying agent to undergo condensation with the phenolic resin precursor. The resulting dispersed phenolic resin reaction product includes at least one phenolic ring to which is bound the ionic group from the modifying agent. The pendant ionic group is a sulfate, sulfonate, sulfinate, sulfenate or oxysulfonate and the reaction-enabling moiety preferably is a hydroxy or hydroxyalkyl.

Abstract: The invention provides a process that includes a first step of reacting the hydroxyl groups of a acrylic resin having hydroxyl groups and carbamate groups with a compound that converts the hydroxyl groups to new groups unreactive with an aminoplast crosslinker; a second step of combining the acrylic resin reaction product with at least an aminoplast crosslinker to form a coating composition; and a third step of applying the coating composition to a substrate and curing the applied coating layer, in which substantially no ether linkages are formed. Aminoplast crosslinkers are desirable for other reasons such as providing high solids coatings having excellent appearance that cure under moderate conditions. Avoiding the ether linkages that could be formed by reaction of aminoplast crosslinkers with hydroxyl groups improves the resistance of the cured coating to environmental etch.

Abstract: An article is coated with a multi-layer coating comprising a polymeric layer deposited on the surface of the article, a zirconium compound, titanium compound or zirconium/titanium alloy compound layer deposited on the polymeric layer, and a silicone resin layer deposited on the zirconium compound or titanium compound layer.

Abstract: A coating method is disclosed, which comprises coating a base coating paint on a substrate, coating thereon a clear coating paint of a curing system different from that of the base coating paint in a wet-on-wet state, and then baking the resultant coatings, wherein a curing catalyst for curing the clear coating paint is incorporated into the base coating paint and wherein the curing catalyst has a boiling point of 150.degree. C. or higher under 760 mmHg. The base coating paint comprising such a curing catalyst is also disclosed.

Abstract: Process for making organic solvent-free aqueous crosslinkable polymer composition comprising: a) preparing an aqueous solution of an acid-functional oligomer with Tg 10 to 125.degree. C. and having crosslinker functional groups; b) conducting an aqueous emulsion polymerization to make an aqueous emulsion of an olefinic hydrophobic polymer in the presence of the aqueous oligomer solution, the hydrophobic polymer having Tg at least 25.degree. C. below that of the oligomer and optionally crosslinker functional groups, and c) combining with a crosslinking agent reactable with the crosslinker groups of the oligomer and polymer, said composition having Koenig hardness of .gtoreq.40 sec and minimum film forming temperature (MFFT) .ltoreq.55.degree. C. Also the aqueous composition so formed and its use in various applications. The aqueous composition has excellent properties and in particular an advantageous balance of MFFT and Koenig hardness.

Abstract: There is disclosed a resin-coated overlay for bonding to solid substrates, and which imparts improved waterproofing and chemical resistance to the resulting resin-coated overlaid solid substrate. Depending upon the desired end use of resin-coated overlaid solid substrate, the resin-coating may be modified to impart desirable surface features and/or characteristics. For example, additives such as waxes, oils, silicones, fluorocarbons and fatty acid compounds may be used to promote the release of concrete from forms made of solid substrates overlaid with the resin-coated overlays of the present invention. Moreover, resin-coated overlaid solid substrates may be produced having a surface which is suitable for painting and which accepts application of various tape products. Other modifications are disclosed which can be used to gain desirable cure speed, cost, and chemical/mechanical properties in the resin-coating.

Abstract: A constraint type vibration damping material, which exhibits a high vibration damping performance and can realize easiness of processing and a low cost at the same time, is provided, in which a polymer viscoelastic layer made of rubber, etc. is formed on at least one surface of a rigid body such as a metal plate, etc. and a hard cover layer having a rigidity modulus greater than that of the viscoelastic layer and smaller than that of the rigid body. Since the hard cover layer having a great rigidity modulus acts as a constraining material, which forms as the result a pair with the rigid body. Further, since the polymer viscoelastic layer and the hard cover layer can be formed by continuous fabrication steps, it can be advantageous from the point of view of the cost.

Abstract: A product comprising two or more parts which are made of a metallic material having different characteristics bonded with a resin paint. The two or more parts are brought into contact and held together by the adhesive property of the resin. The two or more parts are then bonded together by baking the two or more parts with resin paint applied thereto.

Abstract: An improved position sensor printed circuit board (PCB) mounting structure for a commutatorless motor which includes a casing forming an outer housing of the motor includes a PCB holder having a convex shape and being integral with the casing, a sensor PCB having a plurality of position sensors and a plurality of sensor input/output terminal pads for lead wires provided on an upper surface thereof at mutually equal distances therebetween and mounting grooves provided on the PCB holder for detachably mounting the sensor PCB at the correct position thereon.

Abstract: A lead-free composition capable of being applied as a film and hardening to form a protective layer on the back of a mirror comprises a fluid organic resin and a corrosion inhibitor selected from a compound represented by the formula: ##STR1## wherein the individual radicals R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each hydrogen, an aliphatic, cycloaliphatic, araliphatic or aromatic radical, and can be substituted or unsubstituted; A is hydrogen or C.sub.z --CR.sup.5 R.sup.6 CN; X, Y and Z are independently selected from 0-5; and R.sup.5 and R.sup.6 are as defined for R.sup.1, R.sup.2, R.sup.3 and R.sup.4 above. To inhibit the corrosion of metallic film layers on mirrors, a mirror having a glass substrate layer and metallic film layer thereover should be obtained, after which the fluid organic resin coating system containing the aforementioned corrosion inhibitor is applied over the metallic film layer.

Abstract: Urethane-modified novolaks which are prepared by simultaneous reaction of a monohydric or polyhydric phenol (A) with an oxo compound (aldehyde or ketone) (B) and a urethane (C) in the presence of an acidic catalyst (D) at an elevated temperature of 60.degree. to 200.degree. C. and contain no interfering amounts of free starting phenol, and their use as adhesion improvers in rubbers, in particular rubbers containing reinforcing media such as steel cord or textile fibers.

Abstract: The present invention relates to a water-based coating composition suited for surface treatment of the metal sheets or plates to be used in building materials, household electric appliances, automobiles and so forth. The object of the present invention is to provide a water-based coating composition for the steel or metal coated steel surface treatment which gives coating films firmly adhering to metal plates and showing a high degree of hardening as well as excellent corrosion resistance, water resistance and weldability upon baking under low-temperature short-period conditions, has electric conductivity suited for electrodeposition coating and provides lubricating property in processing to thereby prevent powdering during processing as well as a method of forming coating films using said composition.

Abstract: A metallized laminate material for the manufacture of high performance, high density printed wiring boards and the like includes an ordered distribution of via holes electrically interconnecting opposing conductive layers on a dielectric polymeric film substrate. Furthermore, opposing photoresist layers substantially cover the conductive layers and vias. The conductive material in the conductive layers and the vias is bonded adhesivelessly to the substrate to provide a high degree of delamination resistance. The production of metallized laminate material is preferably carried out in a roll-to-roll process suitable for high volume, low cost production. In use, an end user may manufacture customized printed wiring boards in small volume runs from the laminate material with a reduced amount of equipment, expertise and cost.

Abstract: A metal-polypropylene-metal laminate, in which the metal sheets are steel or aluminum is provided which is suitable for cold-forming followed by heat treatment at at least 135.degree. C., e.g. for use in vehicle bodywork. To achieve this, the polypropylene of the core of the laminate has a yield stress at the heat treatment temperature of not less than 2 MPa, and has shape stability such that in a standard shape stability test at the heat treatment temperature it changes shape by not more than 0.5.degree.. A bonding agent between the polypropylene core and the metal sheets is suitably one having a thermosetting component and a polypropylene thermoplastic component.

Abstract: A coated metal sheet for use in a battery container is made up of a metal sheet, one side of which is coated with a coating that includes a resin having rubber elasticity, a plasticizer, a crosslinking agent, and a conductive powder. A battery container or battery is produced from such a coated metal sheet.