Refractory Metal Salt Or Oxide Patents (Class 428/472)
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Publication number: 20030113590Abstract: An article is coated with a multi-layer coating having the appearance of nickel. The coating comprises one or more electroplated layers on the surface of said article, and vapor deposited on the electroplated layers a stack layer comprised of alternating layers of refractory metal compound or refractory metal alloy compound alternating with refractory metal or refractory metal alloy, and on said stack layer a refractory metal nitride or metal alloy nitride color layer where the nitrogen content of said nitride is from about 6 to about 45 atomic percent, and which is vapor deposited under relatively low pressure.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventor: Guocun Chen
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Publication number: 20030113557Abstract: An article is coated with a multi-layer coating having the appearance of nickel. The coating comprises a polymeric basecoat layer on the surface of said article, vapor deposited on the polymeric layer, a stack layer comprised of alternating layers of refractory metal compound or refractory metal alloy compound alternating with refractory metal or refractory metal alloy, and vapor deposited at relatively low pressure on said stack layer a refractory metal or refractory metal alloy nitride color layer where the nitrogen content of said nitride is from about 6 to about 45 atomic percent.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventor: Guocun Chen
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Publication number: 20030113589Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymeric layer on the surface of said article and vapor deposited on the polymeric layer a stack layer containing layers of refractory metal or metal alloy alternating with layers containing refractory metal nitrogen containing compounds and refractory metal alloy nitrogen containing compounds. Vapor deposited at relatively low pressures on the stack layer is a protective and decorative color layer comprised of refractory metal nitrogen containing compounds or refractory metal alloy nitrogen containing compounds wherein the nitrogen content of the refractory metal nitrogen containing compounds and refractory metal alloy nitrogen containing compounds is from about 3 to about 22 atomic percent.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventor: Guocun Chen
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Patent number: 6579624Abstract: A functional film includes a transition layer having a first constituent having SiO as a dielectric material and at least one second constituent selected from aluminum (Al), silver (Ag), silicon (Si), germanium (Ge), yttrium (Y), zinc (Zn), zirconium (Zr), tungsten (W) and tantalum (Ta). The first and second constituents have corresponding gradual content gradients according to a thickness of the functional film.Type: GrantFiled: November 28, 2001Date of Patent: June 17, 2003Assignee: Samsung SDI Co., Ltd.Inventors: Chaun-gi Choi, Young-rag Do, Joon-bae Lee, Chang-won Park
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Patent number: 6579614Abstract: A method of treating structures (and the structure formed thereby), so as to prevent or retard the oxidation of a metal film, and/or prevent its delamination a substrate, includes providing a structure including a refractory metal film formed on a substrate, placing the structure into a vessel having a base pressure below approximately 10−7 torr, exposing the structure to a silane gas at a sufficiently high predetermined temperature and predetermined pressure to cause formation of a metal silicide layer on the refractory metal film, and exposing the structure to a second gas at a sufficiently high temperature and pressure to nitride the metal silicide layer into a nitrided layer.Type: GrantFiled: March 23, 2001Date of Patent: June 17, 2003Assignee: International Business Machines CorporationInventors: Kevin K. Chan, Erin C. Jones, Fenton R. McFeely, Paul M. Solomon, John J. Yurkas
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Publication number: 20030108752Abstract: The invention relates to a method for producing a wearing protection layer according to a CVD method. Said protection layer consists of a plurality of thin individual layers having a layer thickness of 1 to 100 nm respectively. The respective individual layers are successively deposited on a substrate body. The invention also relates to a correspondingly coated substrate body. According to the invention, the CVD method which is activated by means of a glow discharge plasma is carried out under a pressure of 50 Pa to 1,000 Pa and at a temperature of not more than 750 ° C.Type: ApplicationFiled: October 7, 2002Publication date: June 12, 2003Inventors: Udo Knig, Ralf Tabersky, Hendrikus Van Den Berg
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Patent number: 6576349Abstract: A heat treatable coated article (e.g., vehicle windshield, IG unit, etc.) is provided with a dual-silver low-E coating. Before and/or after heat treatment (HT), the coating and/or coated article has a visible transmittance of at least 70%, more preferably at least 75%. Moreover, the coating and/or coated article is designed so as to have approximately the same color when viewed over a wide range of viewing angles. In certain embodiments, at least one contact layer (e.g., of or including NiCrOx) that contacts an infrared (IR) reflecting layer (e.g., Ag) is oxidation graded so that it progressively becomes less oxidized through its thickness as it nears the IR reflecting layer. In still other embodiments, a Si-rich silicon nitride layer(s) may be utilized to reduce haze.Type: GrantFiled: February 28, 2001Date of Patent: June 10, 2003Assignees: Guardian Industries Corp., Centre Luxembourgeois de Recherches pour le Verra et la Ceramique S.A.(C.R.V.C.)Inventors: Philip J. Lingle, Anton Dietrich, Ronald E. Laird, Jean-Marc Lemmer
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Publication number: 20030104221Abstract: A coated article, and a corresponding method of making the same are provided. The coated article includes a coating supported by a substrate, the coating including a thin metal or metal nitride contact layer (e.g., NiCr, Ni, Cr, CrNx, or NiCrNx) located directly between and contacting an infrared (IR) reflecting layer (e.g., Ag) and an oxide barrier layer (e.g., NiCrOx).Type: ApplicationFiled: November 13, 2001Publication date: June 5, 2003Inventor: Grzegorz Stachowiak
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Publication number: 20030104255Abstract: Chain parts and other steel articles are provided with hard, wear-resistant carbide coatings by tumbling them in a heated retort with a particulate mix which includes a source of vanadium and/or niobium. The steel substrate comprises a steel having at least 0.2% carbon, preferably 0.7-1.2%. Where the chromium content of the steel is 4-12%, preferably 4-8%, the chemical deposition process includes drawing a small amount of chromium from the steel substrate into the vanadium or niobium carbide coating, where it is distributed substantially homogeneously, helping to provide adhesion strength to the coating.Type: ApplicationFiled: October 28, 2002Publication date: June 5, 2003Inventors: Yumin Wang, Yoshito Hanayama, Doug Fornell, Naosumi Tada, Kunihiko Mishima
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Patent number: 6572940Abstract: A glass sheet includes a coating comprising at least one silver layer and inner and outer antireflection layers. The glass sheet is formed by a magnetron sputtering process. The inner antireflection layer is a multiple layer comprising a layer of a titanium oxide applied by medium frequency magnetron sputtering and a layer of a metal oxide between the titanium oxide layer and a silver layer.Type: GrantFiled: February 9, 2000Date of Patent: June 3, 2003Assignee: Flachglas AktiengesellschaftInventors: Axel Noethe, Michael Rissmann, Thomas Paul
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Patent number: 6572991Abstract: There is disclosed a coated body having as the outer layer a layer of &ggr;-Al2O3 deposited by chemical vapor deposition, preferably at a temperature of from 700-900° C. The &ggr;-Al2O3 layer is formed through the use of a gaseous mixture including H2S in amounts significantly higher than those presently used and at a temperature of from 700-900° C. The method is also disclosed.Type: GrantFiled: February 4, 2000Date of Patent: June 3, 2003Assignee: Seco Tools ABInventor: Sakari Ruppi
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Publication number: 20030099849Abstract: A method for forming an electrochromic material includes the steps of (a) forming a transparent conductive film on a transparent substrate, (b) forming a metal film on the transparent conductive film by electroless plating, and (c) oxidizing the metal film to form a metal oxide film, which exhibits electrochromic characteristics on the transparent conductive film.Type: ApplicationFiled: November 21, 2002Publication date: May 29, 2003Applicant: FENG CHIA UNIVERSITYInventors: Shu-Yii Wu, Wen-Feng Chen
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Patent number: 6565671Abstract: The present invention relates to a surface-treated steel sheet coated with a chromate layer having excellent corrosion resistance, fuel resistance and seam weldability, and a chromate solution used for preparing the surface-treated steel sheet. Specifically, the chromate solution of the present invention comprises (a) a main solution prepared by adding to a chrome solution having 0.4 to 0.8 of trivalent chrome composition and 7 to 50 g/l of dissolved chrome, on the basis of the chrome in the chrome solution, 50 to 80 w % of phosphate, 20 to 40 w % of fluoric acid, 300 to 2000 w % of colloidal silica, 5 to 15 w % of sulfuric acid, and 25 to 40 w % of sodium phosphate, and (b) a hardener solution containing added epoxy silane or glycidyl silane of 2 to 10 w % on the basis of total hardener solution, the pH of which is controlled between 2 and 3, wherein 10 to 60 w % of the hardener solution being added to the main solution.Type: GrantFiled: July 20, 2001Date of Patent: May 20, 2003Assignee: Pohang Iron & Steel Co., Ltd.Inventors: Jae-Ryung Lee, Sam-Kyu Chang, Sang-Geol Noh, Soo-Hyoun Cho
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Publication number: 20030091870Abstract: A liner and method of forming a liner for a tungsten plug in a semiconductor device which reduces cost and improves reliability. In one aspect, it has been discovered that by depositing an initial film of titanium using any conventional process such as CVD, PVD or IMP (ion metal plasma) and then heating the device in a nitrogen atmosphere to a temperature of about 450 degrees C., a thin protective layer of titanium nitride can be form on the surface of the initial film. The protective layer has been found to be uniform in density and avoids the irregularities occurring in deposited titanium nitride. The thickness of the TiN layer can be controlled by controlling the time duration of the annealing process and by controlling the pressure of the nitrogen in the annealing tool. Using this two step method, the integrity of the titanium nitride layer is preserved and the formation of volcanoes is avoided.Type: ApplicationFiled: November 15, 2001Publication date: May 15, 2003Inventors: Siddhartha Bhowmik, Sailesh Mansinh Merchant, Minesh Amrat Patel, Darrell L. Simpson
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Patent number: 6562490Abstract: A glazing panel carrying a coating stack comprises in sequence at least: a glass substrate a base antireflective layer an infra-red reflecting layer, and a top antireflective layer and is characterized in that at least one of the antireflective layers comprises at least one mixed oxide layer which comprises an oxide which is a mixture of Zn and at least one additional material X, in which the atomic ratio X/Zn is greater than or equal to 0.12 and in which X is one or more of the materials selected from the group comprising the elements of groups 2a, 3a, 5a, 4b, 5b, 6b of the periodic table. The glazing panel exhibits a combination of advantageous properties, particularly thermal stability.Type: GrantFiled: December 20, 1999Date of Patent: May 13, 2003Assignee: Asahi Glass Company Ltd.Inventors: Junichi Ebisawa, Nobutaka Aomine, Satoshi Takeda, Kazuyoshi Noda, Daniel Decroupet
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Publication number: 20030084969Abstract: A Ti-base wire rod for forming molten metal excellent both in rod Seeding smoothness and arc stability is disclosed. A wire rod 301 is composed of Ti metal, and has in the surficial portion including the surface thereof an oxygen enriched layer having an oxygen concentration higher than that in an inner portion. Ratio Tw/Dw of the thickness Tw of the oxygen enriched layer and the diameter Dw of the wire rod is adjusted within a range from 1×10−3 to 1×10−1, and the average oxygen concentration of the oxygen enriched layer is adjusted to 1 wt % or above.Type: ApplicationFiled: July 11, 2002Publication date: May 8, 2003Applicant: Daido Tokushuko Kabushiki KaishaInventors: Kazuhiro Toyoda, Makoto Chujoya, Shigeo Hanajima, Takashi Suzuki, Takashi Orii, Takao Shimizu, Toshiharu Noda, Bunji Naito, Kohachiro Ohashi
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Patent number: 6558800Abstract: A heat treatable coated article including an infrared (IR) reflecting layer (e.g., of or including Ag), the coated article being able to attain a &Dgr;E* (glass side) no greater than about 3.0, more preferably no greater than 2.5, and even more preferably no greater than 2.0, following or due to heat treatment (e.g., thermal tempering). Accordingly, low-E (i.e., low emissivity) coated articles of certain embodiments of this invention appear from the glass side thereof visually similar to the naked eye both before and after heat treatment. Coated articles herein may be used in the context of insulating glass (IG) window units, vehicle windshields, or any other suitable applications. In certain embodiments of this invention, an exemplary layer stack includes: glass/Si3N4/NiCr/Ag/NiCr/Si3N4. Other materials may instead be used without departing from the scope and/or spirit of the instant invention which is a low-E matchable product.Type: GrantFiled: September 19, 2002Date of Patent: May 6, 2003Assignee: Guardian Industries Corp.Inventor: Grzegorz Stachowiak
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Patent number: 6558816Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises a polymeric layer on the surface of said article and vapor deposited on the polymeric layer a stack layer containing layers of refractory metal or metal alloy alternating with layers containing the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the total nitrogen and oxygen content of these reaction products is from about 4 to about 32 atomic percent, with the nitrogen content being at least about 3 atomic percent.Type: GrantFiled: April 5, 2001Date of Patent: May 6, 2003Assignee: Vapor Technologies, Inc.Inventor: Guocun Chen
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Patent number: 6558807Abstract: To use a media agitating mill of a wet internal circulation type when grinding materials, and offer oxide magnetic materials and coils in which influences of ZrO2 and Y2O3 mixing when using partially stabilized zirconia as media beads are improved. The magnetic materials and coils are characterized in that Fe2O3, ZnO, NiO and CuO are main components, and Y2O3, ZrO2 and Bi2O3 are contained with respect to these main components, where an amount of Y2O3 is 0.007 to 0.028 wt % for the total amount, an amount of ZrO2 is 0.12 to 0.55 wt % therefor and an amount of Bi2O3 is 0.03 to 10.12 wt % for the same.Type: GrantFiled: January 19, 2001Date of Patent: May 6, 2003Assignee: TDK CorporationInventors: Ko Ito, Yukio Takahashi
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Patent number: 6555252Abstract: Disclosed is a modulated grain-composition magnetic recording material with up to terabit areal density recording capacity which, preferably, is produced by sequential vacuum deposition and subsequent annealing procedures that allow selective fabrication of magnetic material with desired grain size and coercivity, and with desired longitudinal or perpendicular magnetic particle “c-axis” orientation. The preferred magnetic recording material has multiple layers of FePt/B2O3 and/or Fe/Pt/B2O3, with minimum grain size of approximately ten (10) nanometers, with perpendicularly oriented “c-axis”, and with coercivity (Hc) of up to twelve (12) K-Oe. The preferred fabrication procedure involves sequential sputter deposition of FePt and B2O3 layers, followed by an anneal step.Type: GrantFiled: March 12, 2001Date of Patent: April 29, 2003Assignee: Board of Regents of the University of NebraskaInventors: David J. Sellmyer, Chunping Luo
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Patent number: 6555241Abstract: A cylinder block of an internal combustion engine has several cylinder bores. The surfaces surrounding the cylinder bores have wear-resistant coatings which closely reproduce the surfaces. The coatings are formed by Plasma Vacuum Deposition.Type: GrantFiled: October 27, 2000Date of Patent: April 29, 2003Assignee: Vaw motor GmbHInventors: Hermann W. Erbslöh, Franz Josef Feikus, Erich Lugscheider, Frank Löffler, Christian Wolff
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Patent number: 6551722Abstract: An article is coated with a multi-layer coating having a stainless steel color. The coating comprises an electroplated layer or layers on the article surface, a refractory metal or refractory metal alloy strike layer on the electroplated layer or layers, a color layer containing a refractory metal oxide or refractory metal alloy oxide having a substoichiometric oxygen content on the strike layer, and a refractory metal oxide or refractory metal alloy oxide having a substantially stoichiometric oxygen content layer on said color layer.Type: GrantFiled: April 11, 2001Date of Patent: April 22, 2003Assignee: Masco Corporation of IndianaInventors: Patrick B. Jonte, James S. Lipe, Guocun Chen
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Publication number: 20030072974Abstract: According to an embodiment of the present invention, a decorative hard coating comprises zirconium-aluminium oxycarbonitride. According to another embodiment of the present invention, a decorative hard coating comprises an underlayer and an overlayer, wherein the underlayer comprises metal-rich oxycarbonitride, and the overlayer comprises aluminium in some form. According to another embodiment of the present invention, a method of making a metallic white decorative coating comprises providing a substrate and forming a layer of zirconium-aluminium oxycarbonitride over the substrate. According to another embodiment of the present invention, a method of making a metallic white decorative coating comprises providing a substrate, forming a layer of metal-rich oxycarbonitride over the substrate, and forming a layer of aluminium or aluminium-rich oxycarbonitride over the layer of metal-rich oxycarbonitride.Type: ApplicationFiled: October 16, 2001Publication date: April 17, 2003Inventors: Leo W.M. Lau, Wai Kwong Au
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Patent number: 6548161Abstract: Provided is high temperature equipment, such as gas turbine high temperature portion, usable in high temperature corrosion environment due to corrosive components and in erosion environment due to flying particles. Coating layer (2) in which Cr3C2 is finely dispersed in matrix MCrAlY, where weight ratio of MCrAlY/Cr3C2 is 1/1 to 3/1, is formed on base material (1) as sprayed coating and then diffusion heat treatment is added.Type: GrantFiled: May 18, 1999Date of Patent: April 15, 2003Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Taiji Torigoe, Hisataka Kawai, Yukiko Nishiura, Koji Takahashi, Katsuhiko Abe
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Patent number: 6548193Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a color layer comprised of the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the total nitrogen and oxygen content is from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.Type: GrantFiled: April 5, 2001Date of Patent: April 15, 2003Assignee: Vapor Technologies, Inc.Inventor: Guocun Chen
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Patent number: 6548192Abstract: An article is coated with a multi-layer decorative and protective coating having the appearance of stainless steel. The coating comprises one or more electroplated layers on the surface of said article and vapor deposited on the electroplated layers a stack layer containing layers of refractory metal or metal alloy alternating with layers containing the reaction products of refractory metal or refractory metal alloy, nitrogen and oxygen wherein the total nitrogen and oxygen content of these reaction products is from about 4 to about 32 atomic percent with the nitrogen content being at least about 3 atomic percent.Type: GrantFiled: April 5, 2001Date of Patent: April 15, 2003Assignee: Vapor Technologies, Inc.Inventor: Guocun Chen
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Publication number: 20030068509Abstract: A deposition process for coating a substrate with an ultrasonically generated aerosol spray is described. The resultant droplets are much smaller in size than those produced by conventional processes, thereby providing the present coating having an increased surface area. When the coated substrate is an electrode in a capacitor, a greater surface area results in an increased electrode capacitance. A preferred coating is of a ruthenium-containing oxide.Type: ApplicationFiled: November 8, 2002Publication date: April 10, 2003Inventors: Ashish Shah, Barry C. Muffoletto
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Patent number: 6544666Abstract: A new processed steel sheet comprising of a steel base coated with a Zn or its alloy plating layer and a converted layer, which contains both of at least an insoluble or scarcely-soluble metal compound and at least a soluble metal compound. The insoluble or scarcely-soluble compound may be one or more of valve metal oxides or hydroxides, and the soluble compound may be one or more of valve metal fluorides. The converted layer may be also composed of one or more of complex compounds of Mn and Ti. The insoluble or scarcely-soluble compound acts as a barrier for insulation of a steel base from an atmosphere, while the soluble compound exhibits a self-repairing faculty to repair defective parts of the converted layer. Due to the converted layer, the processed steel sheet is remarkably improved in corrosion resistance, without the presence of chromium compounds which would put harmful influences on the environment.Type: GrantFiled: November 9, 2001Date of Patent: April 8, 2003Assignee: Nisshin Steel Co., Ltd.Inventors: Kouichiro Ueda, Shigeyasu Morikawa, Tadashi Nakano, Yasumi Ariyoshi, Keiji Izumi, Masanori Matsuno, Hirofumi Taketsu
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Patent number: 6544659Abstract: The object of the present invention is to provide a coated steel having an ability to form a high corrosion-resistant rust layer in an early stage even in a severely corrosive environment, for example one with a high amount of atmospheric salinity, by applying a surface treatment which is economical and easily applied onto surfaces of a weather resistant steel and normal steel or surfaces of rust layers over these steels. A surface of a steel or a surface of a rust layer over a steel is coated with an organic resin paint comprising, by weight, 0.2 to 60% of the total with a composition of (i) 0.1-30% calcium oxide, (ii) a metal sulfate whose solubility is 1 g or more in 100 g of water at 5 degrees C and (iii) at least one or more kind(s) of phosphoric acid, the dried coating film having a thickness between 1 &mgr;m and 200 &mgr;m.Type: GrantFiled: February 16, 2001Date of Patent: April 8, 2003Inventor: Masato Yamashita
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Patent number: 6541115Abstract: A metal-infiltrated polycrystalline diamond composite tool comprising a plurality of diamond grains forming a continuous polycrystalline diamond matrix, a metallic phase being substantially palladium-free and contiguous to the continuous polycrystalline diamond matrix, wherein the metallic phase interpenetrates the continuous polycrystalline diamond matrix and substantially wets an outer surface of the continuous polycrystalline diamond matrix; and a working surface. The metallic phase is formed from an infiltrant and a wetting-enhancement layer disposed on the outer surfaces of the diamond particles, with both the infiltrant and wetting-enhancement layer being substantially palladium-free and comprising at least one metal from the group consisting of cobalt, iron, and nickel.Type: GrantFiled: February 26, 2001Date of Patent: April 1, 2003Assignee: General Electric CompanyInventors: David Charles Pender, Charles Dominic Iacovangelo, Mark Philip D'Evelyn, Steven Alfred Tysoe
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Patent number: 6541133Abstract: A layer stack for the surface coating of transparent substrates, in particular panes of glass, has at least one metal oxide composite layer produced by reactive cathodic sputtering and contains Zn oxide and Sn oxide. Relative to the total amount of metal, this metal oxide composite layer contains from 0.5 to 6.5% by weight of one or more of the elements Al, Ga, In, B, Y, La, Ge, Si, P, As, Sb, Bi, Ce, Ti, Zr, Nb and Ta. In a layer stack which has a silver layer as a functional layer, the metal oxide composite layer may be used as an upper and/or lower antireflection layer, as a diffusion barrier layer, as a sublayer of an antireflection layer and/or as an upper cover layer.Type: GrantFiled: June 22, 2000Date of Patent: April 1, 2003Assignee: Saint-Gobain VitrageInventors: Heinz Schicht, Uwe Schmidt, Wilfried Kaiser, Herbert Schindler, Rolf Pfannkuchen
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Publication number: 20030059652Abstract: There is provided a reinforced superconducting tape. The reinforced tape includes a superconducting tape containing a superconducting ceramic material, a first metal reinforcing layer having a greater coefficient of thermal expansion than that of the superconducting tape, and a second metal reinforcing layer having a greater modulus of elasticity than the superconducting tape and the first reinforcing layer.Type: ApplicationFiled: September 25, 2001Publication date: March 27, 2003Inventors: Yu Wang, Evangelos Trifon Laskaris
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Publication number: 20030059634Abstract: A personal ornament having a white coating layer comprises a base article made of a metal, and a white-colored stainless steel coating layer formed by a dry plating process on at least a part of the surface of the base article. Another personal ornament having a white coating layer comprises a base article made of a nonferrous metal, an underlying plating layer formed on the surface of the base article, and a white-colored stainless steel coating layer formed by a dry plating process on at least a part of the surface of the underlying plating layer.Type: ApplicationFiled: February 26, 2002Publication date: March 27, 2003Inventors: Koichi Naoi, Akiyoshi Takagi, Yukio Miya, Fumio Tase, Kazumi Hamano
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Publication number: 20030059633Abstract: An article protected by a thermal barrier coating system includes a substrate having a substrate surface, and a thermal barrier coating system overlying the substrate. The thermal barrier coating system has a thermal barrier coating formed of a thermal barrier coating material arranged as a plurality of columnar grains extending generally perpendicular to the substrate surface and having grain surfaces. A sintering inhibitor is within the columnar grains, either uniformly distributed or concentrated at the grain surfaces. The sintering inhibitor is lanthanum oxide, chromium oxide, and/or yttrium chromate, mixtures thereof, or mixtures thereof with aluminum oxide.Type: ApplicationFiled: September 21, 2001Publication date: March 27, 2003Inventors: John Frederick Ackerman, Venkat Subramaniam Venkataramani, Irene Spitsberg, Ramgopal Darolia
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Patent number: 6537678Abstract: A non-carcinogenic corrosion inhibiting additive includes an anodic corrosion inhibitor and a cathodic corrosion inhibitor.Type: GrantFiled: September 20, 2000Date of Patent: March 25, 2003Assignee: United Technologies CorporationInventors: John William Putnam, Mark Jaworowski
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Patent number: 6534190Abstract: To provide a substrate material made of an aluminum/silicon carbide composite alloy which has a thermal conductivity of 100 W/m×K or higher and a thermal expansion coefficient of 20×10−6/° C. or lower and is lightweight and compositionally homogeneous. A substrate material made of an aluminum/silicon carbide composite ally which comprises Al—SiC alloy composition parts and non alloy composition part and dispersed therein from 10 to 70% by weight silicon carbide particles, and in which the fluctuations of silicon carbide concentration in the Al—SiC alloy composition parts therein are within 1% by weight. The substrate material is produced by sintering a compact of an aluminum/silicon carbide starting powder at a temperature not lower than 600° C. in a non-oxidizing atmosphere.Type: GrantFiled: May 6, 2002Date of Patent: March 18, 2003Assignee: Sumitomo Electric Industries, Ltd.Inventors: Shinichi Yamagata, Yugaku Abe, Makoto Imamura, Akira Fukui, Yoshishige Takano, Takatoshi Takikawa, Yoshiyuki Hirose
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Patent number: 6535321Abstract: A solid state device used to modulate the intensity of reflected or transmitted light by modulating with an external voltage the optical thickness of a thin film ferroelectric placed in an etalon cavity is disclosed. The device is constructed by selecting a generally planar supporting substrate, preferably silicon or sapphire in order to be compatible with silicon integrated circuits. A dielectric stack consisting of alternating layers of different index of refraction materials, also specifically selected to be compatible with later growth of the thin film ferroelectric, is deposited thereon to form a partially reflective and partially transmitting mirror, followed by a transparent electrically conductive layer. The thin film ferroelectric is deposited on the conductive layer, followed by a second transparent conductive layer and a second dielectric stack. Leads are connected to the conductive layers and in turn to a voltage generator.Type: GrantFiled: January 22, 2002Date of Patent: March 18, 2003Assignee: Corning Applied Technologies CorporationInventors: Feiling Wang, Gene H. Haertling
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Publication number: 20030049470Abstract: A ceramic material has particular utility as a thermal insulating or thermal barrier coating on metallic substrates. The ceramic material includes gadolinia and hafnia, preferably forming gadolinia-hafnia. This material exhibits chemical stability, thermal stability and thermal insulating properties superior to those of currently used thermal barrier ceramics, and also provides resistance to sintering and erosion comparable to currently used ceramics. A preferred material has between about 3-70 mol. % hafnia, balance hafnia.Type: ApplicationFiled: December 21, 2001Publication date: March 13, 2003Inventor: Michael J. Maloney
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Publication number: 20030049463Abstract: A heat treatable coated article includes an anti-migration or barrier layer(s) provided between a solar management layer (e.g., NiCr layer) and a dielectric layer (e.g., silicon nitride). In certain example embodiments, the anti-migration or barrier layer(s) may include a metal oxide, and functions to prevent element(s) from migrating between the solar management layer and the dielectric layer upon heat treatment (HT) of the coated article. As a result, the coated article has improved color stability (and thus a lower &Dgr;E* value) upon HT. For example, the coated article may have a &Dgr;E* value (transmissive and/or glass side reflective) upon HT of no greater than 5.0, more preferably no greater than 4.0. Coated articles herein may be used in the context of insulating glass (IG) window units, other architectural windows, vehicle windows, or the like.Type: ApplicationFiled: May 17, 2001Publication date: March 13, 2003Inventor: Hong Wang
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Publication number: 20030044587Abstract: A method of fabricating a device is provided. A substrate having first conductive layer disposed thereon. An organic layer is fabricated over the first conductive layer. A second conductive layer is then fabricated over the organic layer such that the second conductive layer is in electrical contact with the first conductive layer during at least a portion of the step of depositing the second conductive layer. The electrical contact between the first conductive layer and the second conductive layer is then broken. A method of fabricating an active matrix array of organic light emitting devices is also provided. A substrate is obtained, having circuitry adapted to control the current flowing through each organic light emitting device, and having a first conductive layer disposed thereon, such that the first conductive layer is electrically attached to the circuitry. An organic layer is fabricated over the first conductive layer.Type: ApplicationFiled: August 20, 2001Publication date: March 6, 2003Inventors: Min-Hao Michael Lu, Michael S. Weaver, Michael Hack
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Publication number: 20030044624Abstract: An article protected by a thermal barrier coating system is fabricated by providing an article substrate having a substrate surface, thereafter depositing a bond coat on the substrate surface, the bond coat having a bond coat surface, and thereafter processing the bond coat to flatten the bond coat surface. A thermal barrier coating is deposited overlying the bond coat surface. The thermal barrier coating is yttria-stabilized zirconia having a yttria content of from about 3 percent by weight to about 5 percent by weight of the yttria-stabilized zirconia.Type: ApplicationFiled: August 31, 2001Publication date: March 6, 2003Inventors: Irene Spitsberg, Robert William Bruce
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Patent number: 6528171Abstract: The invention relates to a tool, especially a cutting insert for cutting metallic materials, which consist of a hard metal, cermet ceramics or steel base, especially of a high speed steel base, and at least one layer deposited thereon. The single layer, or in the case of several layers the outer layer or the layer underneath the outer layer, contains molybdenum sulfide. The aim of the invention is to improve the resistance to wear of the friction-reducing, molybdenum sulfide containing layer even at high pressures. To this end, the molybdenum sulfide containing layer consists of an alternating sequence of two layer that are different from one another. The first layer contains 51 to 100% by weight of metallic molybdenum and the second layer contains 21 to 100% by weight of MoS2 which substantially consists of hexagonal crystals that are at least substantially oriented in a plane parallel to the tool surface.Type: GrantFiled: July 25, 2001Date of Patent: March 4, 2003Assignee: Widia GmbHInventors: Ingolf Endler, Albrecht Leonhardt, Udo König, Hendrikus van den Berg, Volkmar Sottke
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Patent number: 6528172Abstract: The invention discloses a coating solution for use in forming Bi-based ferroelectric thin films containing Bi, metallic element A (at least one selected from the group consisting of Bi, Pb, Ba, Sr, Ca, Na, K and rare earth elements) and metallic element B (at least one selected from the group consisting of Ti, Nb, Ta, W, Mo, Fe, Co and Cr), wherein it contains metal alkoxides of Bi, metallic element A and metallic element B respectively, and an organometallic compound obtainable by hydrolyzing composite metal alkoxides, formed by any two or more of said metal alkoxides, with water alone or in combination with a catalyst, and contains Bi in a molar amount 1-1.1 times as great as the stoichiometric amount; a ferroelectric thin film (5), a ferroelectric capacitor (10) and a ferroelectric memory with the use of such a coating solution; and a method for producing the same.Type: GrantFiled: December 27, 2000Date of Patent: March 4, 2003Assignees: Tokyo Ohka Kogyo Co., Ltd., Oki Electric Industry Co., Ltd.Inventors: Yoshihiro Sawada, Akira Hashimoto, Ichiro Koiwa, Juro Mita, Yukihisa Okada, Takao Kanehara, Hiroyo Kato
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Publication number: 20030039842Abstract: The invention relates to a frequency selective plate having a radio wave transparent property. This frequency selective plate includes (a) a transparent substrate; (b) a mixture layer formed on the transparent substrate, the mixture layer containing a mixture of a metal nitride and Ag; and (c) Ag particles formed on the mixture layer, the Ag particles being two-dimensionally distributed on the mixture layer and being separated from each other.Type: ApplicationFiled: April 24, 2002Publication date: February 27, 2003Inventors: Hiroshi Nakashima, Motoh Asakura, Masaaki Yonekura, Hideo Omoto
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Patent number: 6524402Abstract: A passivation method for the metallic surface of a nickel and iron-based superalloy which is used as the constituent material of reactor or furnace walls is described, in which the superalloy is coated on at least one of its surfaces which comes into contact with a corrosive atmosphere containing either hydrocarbons at high temperature or containing oxidizing gases at high temperature, with at least two successive layers resulting from successive chemical vapour deposition of its one or more constituent elements, the external phase, resulting from chemical vapour deposition of at least one silicon compound and the layer(s) deposited between the superalloy surface, and the external layer resulting from chemical vapour deposition of at least one of a metal or metalloid.Type: GrantFiled: June 23, 1995Date of Patent: February 25, 2003Assignee: Institut Francais du PetroleInventors: Paul Broutin, Pascal Nisio, François Ropital
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Patent number: 6524718Abstract: A metallic object, having a metallic substrate of a valve metal or a valve metal alloy inclusive of intermetallic phases, and a thin polyphase oxide coating, is disclosed. The polyphase oxide coating has a metal oxide phase and at least one other organic and/or inorganic phase. The polyphase oxide coating is produced by bringing the metallic substrate into contact with an organic and/or inorganic component to be integrated into the polyphase oxide coating such that the inorganic and/or organic phases are present at or in the direct vicinity of the substrate surface and by simultaneously or subsequently anodically polarizing the substrate material in an electrolytic solution.Type: GrantFiled: June 21, 1999Date of Patent: February 25, 2003Assignee: Merck Patent GmbHInventors: Hartmut Worch, Michael Thieme, Dieter Scharnweber, Sophie Rössler, Martina Stölzel
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Patent number: 6524688Abstract: The present invention provides a coating for a transparent substrate which exhibits a “neutral” color through a wide range of angles of incidence of light. The coating employs a base coat adjacent the transparent substrate having a thickness of no more than about 275 Å and may include two reflective metal layers having an intermediate layer of an anti-reflective metal oxide therebetween and an outer anti-reflective layer of metal oxide over the second reflective metal layer. If so desired, the coating of the invention may include an abrasive-resistant overcoat as its outermost layer. This overcoat is desirably formed of an abrasive-resistant metal oxide, such as zinc oxide, applied at a thickness which does not significantly affect the optical properties of said coated substrate.Type: GrantFiled: March 11, 1997Date of Patent: February 25, 2003Assignee: Cardinal CG CompanyInventors: Eric Eby, Roger O'Shaughnessy, Robert Bond
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Publication number: 20030035945Abstract: A carbon deposit inhibiting thermal barrier coating for an internal element or component in a gas turbine engine. Such coating includes a layer of thermal barrier material coated onto the surface of an engine component that will be exposed to the flow of burning engine gases. Such coating further includes a layer of carbon deposit inhibiting material coated on top of the layer of thermal barrier material.Type: ApplicationFiled: August 16, 2001Publication date: February 20, 2003Applicant: Honeywell International, Inc.Inventors: Thomas E. Strangman, Dave Narasimhan, Jeffrey P. Armstrong, Keith R. Karasek
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Publication number: 20030035957Abstract: The present invention provides a superhard polycrystalline diamond or diamond-like element with greatly improved resistance to thermal degradation without loss of impact strength. Collectively called PCD elements, these elements are formed with a binder-catalyzing material in a high-temperature, high-pressure process. The PCD element has a plurality of partially bonded diamond or diamond-like crystals forming at least one continuous diamond matrix, and the interstices among the diamond crystals forming at least one continuous interstitial matrix containing a catalyzing material. The element has a working surface and a body, where a portion of the interstitial matrix in the body adjacent to the working surface is substantially free of the catalyzing material, and the remaining interstitial matrix contains the catalyzing material.Type: ApplicationFiled: November 1, 2002Publication date: February 20, 2003Inventors: Nigel Dennis Griffin, Peter Raymond Hughes
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Publication number: 20030035958Abstract: The present invention provides an earth boring drill bit with a superhard polycrystalline diamond or diamond-like element with greatly improved resistance to thermal degradation without loss of impact strength. Collectively called PCD elements, these elements are formed with a binder-catalyzing material in a high-temperature, high-pressure process. The PCD element has a plurality of partially bonded diamond or diamond-like crystals forming at least one continuous diamond matrix, and the interstices among the diamond crystals forming at least one continuous interstitial matrix containing a catalyzing material. The element has a working surface and a body, where a portion of the interstitial matrix in the body adjacent to the working surface is substantially free of the catalyzing material, and the remaining interstitial matrix contains the catalyzing material. This translates to higher wear resistance in cutting applications and has advantages in numerous other applications.Type: ApplicationFiled: November 4, 2002Publication date: February 20, 2003Inventors: Nigel Dennis Griffin, Peter Raymond Hughes